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16. 学位授与 - 千歳科学技術大学
㧚ቇਈ ቇਈ ቇ⺰ᢥ㗴⋡৻ⷩ ቇ჻ ᐔᚑ 21 ᐕᐲਛޔశ⑼ቇㇱ 4 ᐕᰴߦ☋ߒޔቇ჻ภࠍขᓧߒߚቇ↢ߩ⎇ⓥቶᲤߩቇ⺰ᢥ ࠲ࠗ࠻࡞ߪᰴߩߣ߅ࠅߢߔޕ 㧔1㧕‛⾰శ⑼ቇ⑼ ⧃㜞⎇ⓥቶ 2nd Grubbs ⸅ᇦߦࠃࠆ 2-ࡁ࡞ࡏ࡞ࡀࡦߩ㊀วߦ㑐ߔࠆ⎇ⓥ ࠪࠢࡠࠝࡈࠖࡦࡐࡑTOPAS ߩ⠴ᾲᕈశࡈࠔࠗࡃ↪᧚ᢱߣߒߡߩᕈ⢻⹏ଔߦ㑐ߔࠆ⎇ⓥ ♻⁁శ⎬ൻᕈ᮸⢽ᶧߩ⎬ൻᴺߦࠃࠆశࡈࠔࠗࡃߩㅧ 1',3',3'-trimethyl-6-hydroxyspiro-(2H-1-benzopyran-2,2'-indoline)ߩวᚑߣࡎ࠻ࠢࡠࡒ࠭ࡓߦ㑐ߔࠆ⎇ⓥ ࠢࠨࠡࠞࡔࡓࠪߩ㚟㒰ᣇᴺߦ㑐ߔࠆ⎇ⓥޕ㔚⏛ᵄޔ㖸ᵄߦࠃࠆലᨐ 㞱⊕ሶ߆ࠄ⚂ 10kbps ߩ㜞⚐ᐲ DNA ߩ♖ᴺߣ㔚᳇ᵒേᴺߩᬌ⸛ ࡐࠝࠢ࠲ࡈ࡞ࠝࡠ࠻ࠪࠢࡠ࠺ࡦࡈࠔࠗࡃߩㅘᕈߩᡷༀ ⍹↰㧔ብ㧕⎇ⓥቶ LED ߣᢔ᧼ࠍ↪ߚ㕙ဳᾖߩ߮ᬌ⸛ LED ᾖߩṶ⦡ᕈะߩ⎇ⓥ LED ߣᢔ᧼ࠍ↪ߚ㕙ဳᾖߩ߮ᬌ⸛ LED ࿁〝ߩ㚟േᣇᑼߩᬌ⸛ LED ࠍ↪ߚ≹ߒᾖᚑߩ⎇ⓥ శ⸅ᇦߦࠃࠆ᳓⾰ᵺൻߩ⎇ⓥ శ⸅ᇦߦࠃࠆޔ㒐ᳪ㒐Ⴒലᨐߩ⎇ⓥ ⊕ᾲ㔚ߣᄙ⦡ LED ߩ⦡⋧ߩ⋧㆑ߦ㑐ߔࠆ⎇ⓥ㩷 㧔ᢅ㧕⎇ⓥቶ ࠢࡠࡠࡇࠫࡦ㘃ߩࡈ࠺࡞ࠢࡈ࠷ဳᔕᕈߩᬌ⸛ࠍࠇߘ߮ࠃ߅ޔ↪ߒߚⰯశ࠰࡞ࡃ࠻ࠢ ࡠࡒ࠶ࠢ⦡⚛ߩวᚑߣ⹏ଔ Karthaus ⎇ⓥቶ 䊶ᯏṁᇦ䉕↪䈇䈢䉫䊤䊐䉢䊮䈱䉮䊷䊁䉞䊮䉫㩷 䊶䊂䉞䉡䉢䉾䊁䉞䊮䉫䉕↪䈇䈢ᯏ䊃䊤䊮䉳䉴䉺䈱㩷 䊶㜞ಽሶ䊙䉟䉪䊨᭴ㅧ䈮䉋䉎ᶧ᥏䈱䊤䊮䉻䊛㈩ะ㩷 䊶䊊䊆䉦䊛᭴ㅧ䉕↪䈇䈢ήᯏൻว‛䈱䊙䉟䉪䊨⚿᥏䈱䈫ๆ⌕㩷 䊶㉄ൻ㋕䊊䊆䉦䊛䊐䉞䊦䊛䈱⫾ᾲ䈮䉋䉎ᾲ㔚ല₸䈱⎇ⓥ㩷 䊶䊂䉞䉡䉢䉾䊁䉞䊮䉫䉕↪䈇䈢 LC 䉶䊮䉰䊷䈱ᔕ↪䈮䈧䈇䈩㩷 㧙 163 㧙 㧚ቇਈ ⷺ↰⎇ⓥቶ ࠗࠝࡦᶧ♽ᯏᄥ㓁㔚ᳰߩ⎇ⓥ OPC-EL ⚛ሶߦ߅ߌࠆ OPC ᧚ᢱߩᲧセ ᯏ⭯⤑ᄥ㓁㔚ᳰߩ⎇ⓥ ᶧ᥏ಽሶߩࡦ࠳ࡓ㈩ะߩᬌ⸛ ⦡⚛Ⴧᗵᄥ㓁㔚ᳰߩၮ␆⎇ⓥߣ⫾㔚ᯏ⢻ઃਈߩᬌ⸛ ࡃ࠽࠽ဳᶧ᥏᧚ᢱߩวᚑߣ․ᕈ᷹ቯ ട⮮⎇ⓥቶ LiIO3 ⚿᥏ߦࠃࠆ BBO/OPO ߩ⋥ធ╙ਃ㜞⺞ᵄ⊒↢ CLBO ⚿᥏ߩ✢ᒻ߅ࠃ߮㕖✢ᒻశቇ․ᕈߦߟߡ KBe2BO3F2 KBBFߩశቇ․ᕈ Ꮉㄝ⎇ⓥቶ ⯻ߦ߅ߌࠆ᭴ㅧ⦡ߩಽశቇ⊛⎇ⓥ ࡙࠙ࡠࡇ࠙ࡓࠗࠝࡦࠍ࠼ࡊߒߚ࠱࡞ࠥ࡞ᴺߦࠃࠆ⊒శࠪࠞࠟࠬߩߣ․ᕈ DNA ߣ⦡⚛ߩⶄวߦ߅ߌࠆੑశሶๆ․ᕈߩ⎇ⓥ Ꮧ㘃ࠍ࠼ࡊߒߚࠟࡀ࠶࠻⚿᥏ߩ⊒శ․ᕈ߮ߘࠇࠄߩ⊒శࠬࡍࠢ࠻࡞ߩ᷹ቯ ᯏ⭯⤑ߦ߅ߌࠆ⁜Ꮺၞశߩ⊒↢ߦߟߡ C#ࠍ↪ߚಽశ↹ಣℂࡊࡠࠣࡓߩᚑߣ↢‛ቇ߳ߩᔕ↪ ⏛᳇㕖✢ᒻశቇߦ߅ߌࠆ࠹ࡦ࠰࡞⸘▚ߣኻᔕ㑐ଥߦߟߡ LaAlO3 ߩశቇ․ᕈߦߟߡ ဈ⎇ⓥቶ ❗วᄙⅣ⧐㚅ᣖൻว‛ߩ㔚ሶ⁁ᘒߦ㑐ߔࠆ㊂ሶൻቇ⊛⠨ኤ ࡊࡠ࠻ࡦ⒖േᔕࠍ␜ߔ㋦㍲ߩ᭴ㅧߣ⊒శ․ᕈ ࠨ࠴࡞ࠕࡒ࠼ဳ PT ⦡⚛ߩశቇ․ᕈߣᯏήᯏጀ⁁ࡍࡠࡉࠬࠞࠗ࠻߳ߩዉ ࡊࡠ࠻ࡦ⒖േဳ⦡⚛ࠍ⊒శጀߦ↪ߚᯏ EL ߩ ࡊࡠ࠻ࡦ⒖േဳ⦡⚛ࠍ↪ߚᯏ࿕ࠩߩ㜞ᓧൻ ࡊࡠ࠻ࡦ⒖േဳ⦡⚛ߩ⭯⤑ൻߣ ASE ․ᕈ PT ⦡⚛ࠍ↪ߒߚᵴᕈ㉄⚛ࡦࠨߩ㐿⊒ ࠗࠝࡦᕈಽሶߩ⤑․ᕈߣ⊒శ࠺ࡃࠗࠬ߳ߩᔕ↪ ㌃ࠗࡒ࠳࠱࡞㍲ߩ‛ᕈ⎇ⓥ 㓴ㇱ⎇ⓥቶ ♧㎮㧙ࡐࡠ࠲ࠠࠨࡦ⚿วࠍ↪ߚᣂⷙ࠹࠶ࠢࠬ㕙ߩ᭴▽ߣߘߩࠢ࠴ࡦ⼂․ᕈ ࠙ࠛ࠶࠻ࡊࡠࠬࠍ↪ߚࡐࠫࠕ࠴ࡦ OFET ߩߣ⹏ଔ ࡕࡁࠪ࠶ࠢࡈࠜ࠻ࡈࠢ࠹ࠖࡉ᧚ᢱߦࠃࠆᄙ㊀↹⸥㍳㩷 ⼱የ⎇ⓥቶ శቇࡐࡑߩࠛࠗࠫࡦࠣߦ߁ዮ᛬₸ᄌൻ శቇࡐࡑߩዮ᛬₸ᓮዮ᛬₸੍᷹ 㧙 164 㧙 㧚ቇਈ శቇࡐࡑߩశ‛ᕈ୯੍᷹ࠪࠬ࠹ࡓ శቇࡐࡑߩൻቇ᭴ㅧߣዮ᛬₸ಽᢔᓮ ࡊ࠭ࡓࠞ࠶ࡊࡦࠣᴺߦࠃࠆశቇࡐࡑߩⶄዮ᛬᷹ቯ శቇࡐࡑߩಽሶ㎮ࡄ࠶ࠠࡦࠣ⁁ᘒߣዮ᛬₸ 㕖᥏᭴ㅧᓮߦࠃࠆశቇࡐࡑߩ㜞ㅘൻ ኹᧄ⎇ⓥቶ ⓨ㑆㕖৻᭽ᕈߦࠃࠆ㔀㝼ߩ⊹ᮨ᭽ߩㅪ⛯ᄌൻ ጊਛ⎇ⓥቶ ࠪࡦ࠴࠲↪ Re -GG න⚿᥏ߩߣ⹏ଔ Cr ࠍ࠼ࡊߒߚ Ga2O3 න⚿᥏ߩ⊒శᕈߩ⎇ⓥ Ti ࠍ࠼ࡊߒߚ㉄ൻࠕ࡞ࡒ࠾࠙ࡓ Al2O3ߩ㕍⦡⊒శᯏ᭴ߩ⎇ⓥ MgAl2O4 ߩ Mg ᰳ៊ߦࠃࠆᓇ㗀ߣߘߩᛥ Ti-MgAl2O4 ࠬࡇࡀ࡞ߩᤨ㑆ಽ⸃ಽశ ᧘⎇ⓥቶ ࡄ࡞ࠬࠩࠍ↪ߚ↢ㅘㆊᕈߩၮ␆⎇ⓥ SHG ⥄Ꮖ⋧㑐ᴺࠍ↪ߚࡈࠚࡓ࠻⑽ fsࡄ࡞ࠬࠩߩࡄ࡞ࠬߩ᷹ቯ 3 ⚦⢩㓚ኂലᨐߦࠃࠆశᗵฃᕈ‛⾰ߩ⹏ଔ శᗵฃᕈ‛⾰ Talaporfin ߩ⚦⢩㓚ኂലᨐ⊒↢ㆊ⒟ߩࠗࡔࠫࡦࠣ 㧔2㧕శᔕ↪ࠪࠬ࠹ࡓቇ⑼ 㧔㗅㧕⎇ⓥቶ ࠺ࠫ࠲࡞ࡍࡦࠍᵴ↪ߒߚቇ⠌ᡰេߦ㑐ߔࠆ⎇ⓥ ࠗࡦ࠲ࠢ࠹ࠖࡉࡑ࡞࠴ࡔ࠺ࠖࠕࠦࡦ࠹ࡦ࠷ߦࠃࠆᬺᡰេߦ㑐ߔࠆ⎇ⓥ e ࠾ࡦࠣᢎ᧚ߦ߅ߌࠆ㖸ჿဳࠦࡦ࠹ࡦ࠷ߦ㑐ߔࠆ⎇ⓥ ࠺ࠫ࠲࡞ࡍࡦࠍᵴ↪ߒߚቇ⠌࠺ࠩࠗࡦߦ㑐ߔࠆ⎇ⓥ e ࠾ࡦࠣᢎ᧚ߦ߅ߌࠆᤋࠦࡦ࠹ࡦ࠷ߦ㑐ߔࠆ⎇ⓥ ᳯญ⎇ⓥቶ ╬ଔዮ᛬₸ᴺߩࡎࡈࠔࠗࡃ⸃ᨆ߳ߩᔕ↪ߦ㑐ߔࠆ⎇ⓥ Java ࠍ↪ߚછᗧᢿ㕙ᒻ⁁శࡈࠔࠗࡃ⸃ᨆࠪࠬ࠹ࡓߩജࠗࡦ࠲ࡈࠚࠗࠬߩ㐿⊒ߦ㑐ߔࠆ⎇ⓥ ╬ଔዮ᛬₸ᴺࠍ↪ߚⶄዮ᛬ࡎࡈࠔࠗࡃ⸃ᨆߦ㑐ߔࠆ⎇ⓥ ዊ↰⎇ⓥቶ ⷞⷡࡦࠨࠍ↪ߒߚੑ⿷ᱠⴕࡠࡏ࠶࠻ߩᱠⴕቯൻᓮ 㔚േゞሶߦ߅ߌࠆૐㅦၞߩㅦᐲផቯߩߚߩࠞࡔᆫߩᬌ⸛ ࠞࡔⷞ㊁นᠲᐲኻ⽎‛ㅦᐲࠍ⠨ᘦߒߚࡠࡏ࠶࠻ࠕࡓߩⷞⷡㅊᓥᓮ ࠝࡊ࠹ࠖࠞ࡞ࡈࡠࠍ↪ߚ౬㐳ࡑ࠾ࡇࡘ࠲ߩᆫቯൻߣ㓚ኂ࿁ㆱ․ᕈߩᬌ⸛ ࠣ࠺ࠖࠛࡦ࠻ᴺߦࠃࠆࠝࡊ࠹ࠖࠞ࡞ࡈࡠࡌࠢ࠻࡞ߩ▚߮♖ᐲᬌ⸽ ࠗࡦ࠹ࠫࠚࡦ࠻ࠬࡍࠬⅣႺߦ߅ߌࠆ⒖േࡠࡏ࠶࠻ߩ㓚ኂ‛࿁ㆱᓮߩឭ᩺ 㧙 165 㧙 㧚ቇਈ ࠝࠢ࡞࡚ࠫࡦࠍ⠨ᘦߒߚ⒖േࡠࡏ࠶࠻ߩⷞⷡࡈࠖ࠼ࡃ࠶ࠢᓮߩឭ᩺ ᲑᏅ㓚ኂߦኻߔࠆੑ⿷ᱠⴕࡠࡏ࠶࠻ߩᱠⴕቯᕈߩታ㛎⊛ᬌ⸛ ↹ࡈࠖ࠼ࡃ࠶ࠢߦࠃࠆ྾ベ⒖േࡠࡏ࠶࠻ߩࡆࠫࡘࠕ࡞࠻࠶ࠠࡦࠣᓮ ໊Ỉ⎇ⓥቶ ࡈࠜ࠻࠾࠶ࠢ⚿᥏ࡈࠔࠗࡃ߆ࠄߩᄙ⦡นⷞశߩ⊒↢ ࠗ࠶࠹࡞ࡆ࠙ࡓࡈࠔࠗࡃࠩߩࠪࡒࡘ࡚ࠪࡦ⸘▚ Ⱟశࠦࡅࡦࠬ࠻ࡕࠣࡈࠖߦ㑐ߔࠆ⎇ⓥ ࠰࠻ࡦࡄ࡞ࠬࠍ↪ߚశࠦࡅࡦࠬ࠻ࡕࠣࡈࠖ Ꮉἑ⎇ⓥቶ ࡊࠬ࠴࠶ࠢశࡈࠔࠗࡃߩવㅍᏪၞ․ᕈ⹏ଔߦ㑐ߔࠆ⎇ⓥ MPLS ࠻ࡈࠖ࠶ࠢᓮࡀ࠶࠻ࡢࠢߩ․ᕈ⹏ଔߦ㑐ߔࠆ⎇ⓥ ࠬࡍࠢ࠻࡞ࠬࠗࠬశḮߩ․ᕈ⹏ଔߦ㑐ߔࠆ⎇ⓥ WDM ࡀ࠶࠻ࡢࠢ↪ OTDR ߦ㑐ߔࠆ⎇ⓥ శḮࠬࡍࠢ࠻࡞ߣ WDM ࡀ࠶࠻ࡢࠢ․ᕈߦ㑐ߔࠆ⎇ⓥ ᵄ㐳࡞࠹ࠖࡦࠣࡀ࠶࠻ࡢࠢᓮߦ㑐ߔࠆ⎇ⓥ ዊᨋ㧔ჽ㧕⎇ⓥቶ శዉᵄ〝࿁᛬ᩰሶ M-Z ᐓᷤᒻߦࠃࠆࡃࡦ࠼ࡄࠬࡈࠖ࡞࠲ߩ⎇ⓥ ࡕ࠼ᓮဳ࠹ࡄశࡈࠔࠗࡃߩૐ៊ᄬൻߩ⎇ⓥ ⚡ᄖ✢ᐓᷤ㔺శᴺߦࠃࠆశዉᵄ〝࿁᛬ᩰሶᴺߩ⎇ⓥ 㜞ജࠩశࠟࠗ࠼↪శࡈࠔࠗࡃᴺߩ⎇ⓥ ᶧᇦ⾰ዮ᛬₸᷹ቯ↪࠹ࡄశࡈࠔࠗࡃᴺߩ⎇ⓥ ࡈࠜ࠻࠾࠶ࠢ⚿᥏ࡈࠔࠗࡃᴺߩ⎇ⓥ ࡈࠜ࠻࠾࠶ࠢ⚿᥏ࡈࠔࠗࡃ SC శᐢᏪၞ․ᕈߦ㑐ߔࠆ⎇ⓥ Yb ࡈࠔࠗࡃࠩ↪ബశല₸ൻߩ⎇ⓥ ࠩ⋥ធឬ↹ߦࠃࠆࡑ࡞࠴ࡕ࠼శዉᵄ〝ᴺߩ⎇ⓥ శࡈࠔࠗࡃᝄേࡦࠨࡀ࠶࠻ࡢࠢൻߩ⎇ⓥ ⚡ᄖ✢ࠩ⋥ធឬ↹ߦࠃࠆࡈࡀ࡞ࡦ࠭ᴺߩ⎇ⓥ㩷 ዊᨋ㧔ᄢ㧕⎇ⓥቶ ኅᐸ↪ e-࠾ࡦࠣߩ↹㕙ࠗࠕ࠙࠻ߦ㑐ߔࠆታ㛎⊛⎇ⓥ ⓨ᷼ౝߦ߅ߌࠆ↪⠪ߩ⒖േߦ᩺ౝ᧼߇߷ߔᓇ㗀 ៤Ꮺ┵ᧃߦ㈩ାߔࠆߚߩㆱ㔍↪㒐ἴࡑ࠶ࡊߩታ㛎⊛⹏ଔ ⥄ᴦߩ Web ࡍࠫߦኻߔࠆ࡙ࠩࠛࠢࠬࡍࠛࡦࠬߦᓇ㗀ࠍ߷ߔⷐ࿃ߩ ዊ᧻Ꮉ⎇ⓥቶ ೋ╬ਛ╬ᢎ⢒ะߌ e ࠾ࡦࠣߦ߅ߌࠆቇ⠌ࡐ࠻ᯏ⢻ߩ㐿⊒ ⟵ോᢎ⢒ߦ߅ߌࠆ ICT ᵴ↪ᢎ⢒ߢߩലᨐ⊛ࠦࡦ࠹ࡦ࠷ᵴ↪ᣇᴺߦ㑐ߔࠆ⎇ⓥ ࠝࡊࡦ࠰ࠬࠍᵴ↪ߒߚኻဳࠗࡦ࠲ࡈࠚࠬࠛࠫࠚࡦ࠻ߩታ⸽㐿⊒ ၞࠦࡒࡘ࠾࠹ࠖߢߩ↪ࠍᗐቯߒߚࡔࡦࠣࠬ࠻ࠪࠬ࠹ࡓߩታ⸽㐿⊒ 㧙 166 㧙 㧚ቇਈ ᬺᡰេဳࡐ࠲࡞ߢߩද⺞ቇ⠌ᡰេᯏ⢻ߦ㑐ߔࠆ⎇ⓥ 㜞╬ᢎ⢒ߢߩ⾰⸽ߦะߌߚ⍮⼂ಽᨆဳቇ⠌ࠞ࡞࠹ࠪࠬ࠹ࡓߩ⎇ⓥ ᄢቇၮ␆ᢎ⢒⑼⋡ߢߩቇ⠌ࠪ࠽ࠝߦၮߠߊࡕࡃࠗ࡞࠾ࡦࠣߩታ⸽⹏ଔ ᒛ⎇ⓥቶ ㅘㆊࠬࡍࠢ࠻࡞ߦࠃࠆ⭯⤑ߩశቇቯᢙߩ᷹ቯ ᯏࡈࠜ࠻ࡈࠢ࠹ࠖࡉലᨐߦࠃࠆ↹⸥㍳․ᕈ ⦡⚛Ⴧᗵဳశ㔚ജ⚛ሶߩ⹏ଔ ࡐࡑࡈࠜ࠻࠾࠶ࠢ⚿᥏ࡈࠔࠗࡃߩ↹ࠗࡔࠫࡦࠣ㩷 㐳⼱Ꮉ⎇ⓥቶ LED ⽶⩄࿁〝ߦ߅ߌࠆធὐߩធ⸅ା㗬ᕈߦ㑐ߔࠆ⎇ⓥ ࠩᄌ⸘ࠍ↪ߒߚࠨࡦࡊ࡞ᒻ⁁⹏ଔࠪࠬ࠹ࡓߩ᭴▽ߦ㑐ߔࠆ⎇ⓥ శࡈࠔࠗࡃశߦ߅ߌࠆࠬࡍ࠶ࠢ࡞ࡄ࠲ࡦߩࡦࠪࡦࠣ߳ߩᔕ↪ߦ㑐ߔࠆ⎇ⓥ శಾᢿᴺࠍ↪ߒߚ㔚ᭂ㕙ᒻ⁁⹏ଔࠪࠬ࠹ࡓߩ᭴▽ߦ㑐ߔࠆ⎇ⓥ ࡢࠗࡉ࡞ಽᏓ㑐ᢙࠍ↪ߒߚធ⸅ᛶ᛫࠺࠲⸃ᨆ࠰ࡈ࠻࠙ࠚࠕߩ㐿⊒ߦ㑐ߔࠆ⎇ⓥ ធὐߩធ⸅ᛶ᛫․ᕈߣ㔚ᭂ㕙⁁ᘒߣߩ㑐ଥߦ㑐ߔࠆ⎇ⓥ㩷 ᵿਛ⎇ⓥቶ Al2O3:Ce Ⱟశ⭯⤑ߩ⎇ⓥ ⓸ൻ࠲ࡦ࠲࡞⭯⤑ᛶ᛫ߩ ZnO Alㅘ㔚ᭂ⤑ߩ⎇ⓥ ⓸ൻ࠲ࡦ࠲࡞⭯⤑ᛶ᛫ߩ ↰⎇ⓥቶ LED ࠍബశḮߦ↪ߚ࿕ൻ⦡⚛ࠩߦ㑐ߔࠆ⎇ⓥ ਃ⋧ࡄ࡞ࠬ㔚ᵹߦࠃࠆ 3 ⦡ LED 㚟േ࿁〝ߩ⸳⸘ ࠨࠗ࠼ࡆࡘLED ࠍ↪ߚ⊕⦡శḮߩ⹜ Lumogen F Orange 240 ࠍ࠼ࡊߒߚ࿕ൻ⦡⚛ࡦࠣࠩߩ⹜ ᦼ᭴ㅧࠍ↪ߚࡑࠗࠢࡠᵄࡈࠖ࡞࠲ߩ ࿁ォߦ㔚ജࠍଏ⛎ߔࠆᣇᴺߩᬌ⸛ ጊᨋ⎇ⓥቶ శ᳓㕙ᬌࠕ࡞ࠧ࠭ࡓߩᬌ⸛ ࡎࡠࠣࡈࠖ࠶ࠢࡈࡀ࡞ࡦ࠭ߩ߅ࠃ߮⹏ଔᴺߦ㑐ߔࠆ⎇ⓥ ࡑ࡞࠴ࡕ࠼ࡈࠔࠗࡃߩၮᧄࡕ࠼ബᝄߦࠃࠆ㜞ㅦ࠺ࠫ࠲࡞વㅍ⹏ଔᛛⴚߩ⎇ⓥ ࡈࠔࠗࡃဳ࠺ࡃࠗࠬࠍ↪ߚⴣ᠄ࡦࠨߩ⎇ⓥ ࡑࠣࡀࠪ࠙ࡓ↪ࡂࠗࡉ࠶࠼㚟േࠪࠬ࠹ࡓߦ߅ߌࠆࡑࠣࡀࠪ࠙ࡓΆᣇᴺߩᬌ⸛ ࡑ࡞࠴ࡕ࠼ࡈࠔࠗࡃߩၮᧄࡕ࠼ബᝄ↪శዉᵄ࠺ࡃࠗࠬߩ⎇ⓥ ࡑࠣࡀࠪ࠙ࡓ↪ࡂࠗࡉ࠶࠼㚟േࠪࠬ࠹ࡓߦ߅ߌࠆࠬ࠲ࡦࠣࠛࡦࠫࡦߦ㑐ߔࠆၮ␆ᬌ⸛ ࡃ࠶ࡈࠔࠬశ࡞࠲↪⥄Ꮖᜬဳశࠬࠗ࠶࠴࿁〝᭴ᚑᴺߩ⎇ⓥ ᵄ㐳ಾᦧࠩㆊᷰᔕ╵ߦኻߔࠆ࠻ᣇ⒟ᑼߦࠃࠆ⸘▚ᯏࠪࡒࡘ࡚ࠪࡦ 㧙 167 㧙 㧚ቇਈ ศ↰⎇ⓥቶ ਔ㕙ฃశဳᄥ㓁㔚ᳰߩ⊒㔚㊂ߣ⸳⟎ⷺᐲߩ㑐ଥߦ㑐ߔࠆ⎇ⓥ ⸳⟎㕙᧦ઙߣਔ㕙ฃశဳᄥ㓁㔚ᳰߩ⊒㔚㊂ߩ㑐ଥߦ㑐ߔࠆታ㛎⊛⎇ⓥ ࡉࡠ࠶ࠦࠬࡊ࠙࠻ߩࡆ࠲ࡒࡦ C ㊂ߣ LED శᾖߩ㑐ଥߦ㑐ߔࠆ⎇ⓥ ᬀ‛ᩱၭ↪ LED ߩᾲ․ᕈߦ㑐ߔࠆ⎇ⓥ ᬀ‛ᩱၭ↪ LED శḮࡄࡀ࡞ߩశ㊂⥄േᓮߦ㑐ߔࠆ⎇ⓥ ୃ჻ ᐔᚑ 21 ᐕᐲਛޔඳ჻೨ᦼ⺖⒟ 2 ᐕᰴߦ☋ߒୃޔ჻ภࠍขᓧߒߚቇ↢߅ࠃ߮ᜰዉᢎຬޔ ୃ჻⺰ᢥ࠲ࠗ࠻࡞ߪᰴߩߣ߅ࠅߢߔޕ ⋧Ỉ⋥᮸㧔ዊ↰ ዏ㧕 ⅣႺᄌൻߦኻᔕߒߚࡄࡢࠕࠪࠬ࠻ゞሶߩࡕ࡚ࠪࡦᓮ ⋧ේஜᴦ㧔ዊ᧻Ꮉ㧕 ᬺᡰេဳࠦࠬࡑࡀࠫࡔࡦ࠻ࠪࠬ࠹ࡓߦ߅ߌࠆද⺞ቇ⠌ᡰេᯏ⢻ߦ㑐ߔࠆ⎇ⓥ ⑺ጊᘮㅧ㧔ዊ᧻Ꮉ㧕 ೋ╬ਛ╬ᢎ⢒ߢߩ ICT ᵴ↪ဳቇ⠌ࠨࡆࠬߦ㑐ߔࠆ⎇ⓥ ᳰ↰ᖘ᮸㧔ዊ᧻Ꮉ㧕 ⍮⼂ࠍ↪ߚቇ⠌ࠞ࡞࠹ࠪࠬ࠹ࡓߦ㑐ߔࠆ⎇ⓥ ⍹ᯅస㧔ዊᨋ ჽ㧕 ᵄ㐳นᄌ Er ᷝടࡈࠔࠗࡃࠩ᭴ᚑᴺߩ⎇ⓥ દ⮮ᱜ♿㧔ዊ↰ ዏ㧕 ᨵエߥ⿷㚂㑐▵ࠍߔࠆੑ⿷ᱠⴕࡠࡏ࠶࠻ߩቯᱠⴕᓮ ጤ↰㧔᧘㧕 ⚦⢩㓚ኂലᨐߦࠃࠆశᗵฃᕈ‛⾰ߩ⹏ଔߣశ✢ജቇ⊛ᴦ≮ߩࡔࠞ࠾࠭ࡓ⸃ ᄢỈ⥋㧔ศ↰㧕 e-Learning ဳ⻠⟵ߦ߅ߌࠆᚑ❣ߣቇ⠌࠺࠲߆ࠄ⠨߃ࠄࠇࠆ࠼ࡠ࠶ࡊࠕ࠙࠻ᣧ ᦼ⊒ᚻᴺߩ⎇ⓥ ᄥ↰ᔀ㧔↰㧕 ࿁ォߦ㕖ធ⸅ߢ㔚ജࠍଏ⛎ߔࠆᣇᴺ 㐳ო㘧㠽㧔ട⮮㧕 0.6ȝm㨪6mmߦ߅ߌࠆ GaSe ߩ࡞ࡑࠗࡗᣇ⒟ᑼߣߘߩᔕ↪ ዊᐈߪࠆߥ㧔⼱የ㧕 㕖᥏᭴ㅧᓮߦࠃࠆశቇࡐࡑߩ㜞ㅘൻ ㊄ᥓᴺ㧔Ꮉἑ㧕 WDM ࡀ࠶࠻ࡢࠢ↪ OTDR ߦ㑐ߔࠆ⎇ⓥ Ꮉᜏ㧔ዊᨋ ჽ㧕 㓸శ↪࠹ࡄశࡈࠔࠗࡃߩ៊ᄬૐᷫൻߩ⎇ⓥ ⩵ᳰᐘᄥ㧔↰㧕 ✛⦡ࡂࠗࡄࡢLED ߦࠃࠆ࿕ൻ⦡⚛ߩബ ⮮ᦸ㧔 ᢅ㧕 1࠴࠙ࡓࠗࠝࡦ߅ࠃ߮ࡊࡠ࠻ࡦャㅍࡏ࠻ࠥ࡞᧚ᢱ 2࠰࡞ࡃ࠻ࠢࡠࡒ࠶ࠢ⦡⚛ߦࠃࠆᯏṁᇦߩ᳓₸ቯ㊂ 3 ⦡⚛ᄙ♧ⶄว᧚ᢱߩ⺞ᢛߣᔕ↪ߩ⹜ߺ ᔒ⮮㧔ട⮮㧕 E-BaB2O4 ߦࠃࠆ 0.193ȝm శ⊒↢ߣ᷷ᐲ․ᕈ 㜞၂ల㧔ዊ↰ ዏ㧕 ࠝࡊ࠹ࠖࠞ࡞ࡈࡠࠍᵴ↪ߒߚ㓚ኂ‛࿁ㆱ⢻ജࠍߔࠆ౬㐳ࡑ࠾ࡇࡘ࠲ߩ ᆫቯൻᓮ ↰㧔⼱የ㧕 శቇࡐࡑߩൻቇ᭴ㅧߣㅘᕈ੍᷹ ᚑἑኡፄ㧔ጊਛ㧕 Ti ࠍ࠼ࡊߒߚ㉄ൻࠕ࡞ࡒ࠾࠙ࡓߩߣߘߩ㕍⦡⊒శ․ᕈߩ⹏ଔ 㐳⼱Ꮉℂ㧔ዊ᧻Ꮉ㧕 ⍮⼂࠺࠲ࡌࠬࠍߒߚࠦࠬቇ⠌ߦ߅ߌࠆ⥄ᓞቇ⠌ᡰេߩߚߩᢎ᧚ផ⮈ ࠪࠬ࠹ࡓߦ㑐ߔࠆ⎇ⓥ 㧙 168 㧙 㧚ቇਈ ⇌ἑ৻ੱ㧔ᳯญ㧕 2 ᰴరછᗧᢿ㕙ᒻ⁁ዉᵄ〝ߩᄙጀಽഀᴺࠍ↪ߚ╬ଔዮ᛬₸ᴺ⸃ᨆߦ㑐ߔࠆ⎇ⓥ ⮮↰ᓆ㧔ዊ᧻Ꮉ㧕 ࠦࠬ࠙ࠚࠕߦ߅ߌࠆቇ⠌ᡰេࡔ࡞ߩ⥄േ↢ᚑߦ㑐ߔࠆ⎇ⓥ ’㊁⅃ሶ㧔᧘㧕 ⿒ᄖಽశᴺߦࠃࠆࠣ࡞ࠦࠬỚᐲ᷹ቯߣࠟࡦ⚦⢩ߩ್ ඳ჻ ᐔᚑ 21 ᐕᐲਛޔඳ჻ᓟᦼ⺖⒟ߦ☋ߒޔඳ჻ภࠍขᓧߒߚቇ↢߅ࠃ߮ᜰዉᢎຬޔඳ჻⺰ ᢥ࠲ࠗ࠻࡞ߪᰴߩߣ߅ࠅߢߔޕ ᧖↰ㄖ㧔ጊਛ㧕 ᵄ㕙Ꮕ⸃ᨆ࡞࠻ࠢࡌޔ࿁᛬ല₸⸃ᨆߦࠃࠆ࠴ࡖࡊဳ࿁᛬ᩰሶߩ㜞ᕈ⢻ൻ ߮ߘߩᔕ↪ߦ㑐ߔࠆ⎇ⓥ ች↰ᙗᄥ㇢㧔ട⮮㧕 BIBO ࠍ↪ߚᦨవ┵㕖✢ᒻᵄᢙᄌ឵ ⊕㌁㧔㓴ㇱ㧕 శ✢ജቇ⊛⸻ᢿᴦ≮↪శᗵฃᕈ‛⾰ Talaporfin ߩశ‛ᕈߣബశߩ⚵❱ㅘㆊᕈ ߅ࠃ߮⚦⢩⥄ኅⰯశߩ⎇ⓥ ஜ৻㧔㩀㨺㩎㩔㨽㩇㧕 ήᯏࡐࠬࡈࠖ࡞ࡓߩߣశ⸅ᇦ߳ߩᔕ↪ ᧻ਅஜᴦ㧔ᵿਛ㧕 ਇဋ৻વㅍ✢〝ࠍ↪ߚᦼ᭴ㅧࡃࡦ࠼ࠬ࠻࠶ࡊࡈࠖ࡞࠲ߦ㑐ߔࠆ⎇ⓥ 㧙 169 㧙 㧚ቇਈ ቇ㧔ඳ჻㧕ਈ ඳ჻ᓟᦼ⺖⒟ߩቇ↢ 5 ฬ߇ᐔᚑ 21 ᐕᐲߦୃੌߒߡ߹ߔޕቇߦߟߡߪᰴߩߣ߅ࠅߢ ߔޕ ߔ ߉ ߚ ߚߟ ߿ ᳁ ฬ 㧔 ᧄ ☋ 㧕 ᧖↰ ㄖ㧔⨙ၔ⋵㧕 ቇ ߩ ⒳ 㘃ඳ჻㧔ℂᎿቇ㧕 ቇ ⸥ ⇟ ภ ↲╙ 9 ภ ቇਈߩ᧦ઙ ቇⷙೣ╙ 4 ᧦╙ 1 㗄ᒰ ቇਈᐕᣣ ᐔᚑ 21 ᐕ 9 2 ᣣ ቇ ⺰ ᢥ 㗴 ⋡ 㨬ᵄ㕙Ꮕ⸃ᨆ࡞࠻ࠢࡌޔ࿁᛬ല₸⸃ᨆߦࠃࠆ࠴ࡖࡊဳ࿁᛬ᩰሶߩ㜞 ᕈ⢻ൻ߮ߘߩᔕ↪ߦ㑐ߔࠆ⎇ⓥ㨭 ⺰ ᢥ ክ ᩏ ᆔ ຬ ਥᩏ ᢎ ጊਛ ↢ ᆔຬ ᢎ ⍹↰ ብม ᆔຬ ᢎ Ꮉἑ ᱜ ߺ ߿ ߚ ߌࠎߚࠈ߁ ᳁ ฬ 㧔 ᧄ ☋ 㧕 ች↰ ᙗᄥ㇢㧔ർᶏ㧕 ቇ ߩ ⒳ 㘃 ඳ჻㧔ℂᎿቇ㧕 ቇ ⸥ ⇟ ภ ↲╙ 10 ภ ቇਈߩ᧦ઙ ቇⷙೣ╙ 4 ᧦╙ 1 㗄ᒰ ቇਈᐕᣣ ᐔᚑ 21 ᐕ 9 2 ᣣ ቇ ⺰ ᢥ 㗴 ⋡ ޟBIBO ࠍ↪ߚᦨవ┵㕖✢ᒻᵄᢙᄌ឵ޠ ⺰ ᢥ ክ ᩏ ᆔ ຬ ਥᩏ ᢎ ട⮮ ᵘ ᆔຬ ᢎ ጊਛ ↢ ᆔຬ ᢎ Ꮉㄝ ⼾ 㧙 170 㧙 㧚ቇਈ ߒࠈ߇ߨ ࠇ ᳁ ฬ 㧔 ᧄ ☋ 㧕 ⊕㌁ 㧔ർᶏ㧕 ቇ ߩ ⒳ 㘃 ඳ჻㧔ℂᎿቇ㧕 ቇ ⸥ ⇟ ภ ↲╙ 11 ภ ቇਈߩ᧦ઙ ቇⷙೣ╙ 4 ᧦╙ 1 㗄ᒰ ቇਈᐕᣣ ᐔᚑ 22 ᐕ 3 20 ᣣ ቇ ⺰ ᢥ 㗴 ⋡ ޟశ✢ജቇ⊛⸻ᢿᴦ≮↪శᗵฃᕈ‛⾰ Talaporfin ߩశ‛ᕈߣബశߩ ⚵❱ㅘㆊᕈ߅ࠃ߮⚦⢩⥄ኅⰯశߩ⎇ⓥޠ ⺰ ᢥ ክ ᩏ ᆔ ຬ ਥᩏ ᢎ 㓴ㇱ ඳਯ ᆔຬ ᢎ Ꮉㄝ ⼾ ᆔຬ ᢎ Olaf Karthaus ᆔຬ ಎᢎ ᧘ 㤡 ߎࠎ ߌࠎߜ ᳁ ฬ 㧔 ᧄ ☋ 㧕 ஜ৻㧔ർᶏ㧕 ቇ ߩ ⒳ 㘃 ඳ჻㧔ℂᎿቇ㧕 ቇ ⸥ ⇟ ภ ↲╙ 12 ภ ቇਈߩ᧦ઙ ቇⷙೣ╙ 4 ᧦╙ 1 㗄ᒰ ቇਈᐕᣣ ᐔᚑ 22 ᐕ 3 20 ᣣ ቇ ⺰ ᢥ 㗴 ⋡ ޟήᯏࡐࠬࡈࠖ࡞ࡓߩߣశ⸅ᇦ߳ߩᔕ↪ޠ ⺰ ᢥ ክ ᩏ ᆔ ຬ ਥᩏ ᢎ Olaf Karthaus ᆔຬ ᢎ 㓴ㇱ ඳਯ ᆔຬ ᢎ Ꮉㄝ ⼾ ߹ߟߒߚ ߌࠎ ߓ ᳁ ฬ 㧔 ᧄ ☋ 㧕 ᧻ਅ ஜᴦ㧔ᾢᧄ⋵㧕 ቇ ߩ ⒳ 㘃 ඳ჻㧔ℂᎿቇ㧕 ቇ ⸥ ⇟ ภ ↲╙ 13 ภ ቇਈߩ᧦ઙ ቇⷙೣ╙ 4 ᧦╙ 1 㗄ᒰ ቇਈᐕᣣ ᐔᚑ 22 ᐕ 3 20 ᣣ ቇ ⺰ ᢥ 㗴 ⋡ ޟਇဋ৻વㅍ✢〝ࠍ↪ߚᦼ᭴ㅧࡃࡦ࠼ࠬ࠻࠶ࡊࡈࠖ࡞࠲ߦ㑐ߔࠆ ⎇ⓥޠ ⺰ ᢥ ክ ᩏ ᆔ ຬ ਥᩏ ᢎ ᵿਛ ብ৻ ᆔຬ ᢎ Ꮉἑ ᱜ ᆔຬ ᢎ ጊᨋ ↱ ᆔຬ ಎᢎ ↰ ⺈ 㧙 171 㧙 㧚ቇਈ 0Q 㧙 172 㧙 㧚ቇਈ 0Q 㧙 173 㧙 㧚ቇਈ 0Q 㧙 174 㧙 㧚ቇਈ 0Q 㧙 175 㧙 㧚ቇਈ 0Q 㧙 176 㧙 㧚ቇਈ 0Q 㧙 177 㧙 㧚ቇਈ 0Q 㧙 178 㧙 㧚ቇਈ 0Q 㧙 179 㧙 㧚ቇਈ 0Q 㧙 180 㧙 㧚ቇਈ 0Q 㧙 181 㧙 㧚ቇਈ ඳ჻ᓟᦼ⺖⒟⎇ⓥਛ㑆⊒ ඳ჻ᓟᦼ⺖⒟☋ቇ↢ߦࠃࠆ⎇ⓥᚑᨐ߇ޔᲤᐕ㐿ߐࠇࠆ⎇ⓥਛ㑆⊒ળߦ߅ߡႎ๔ ߐࠇߡ߹ߔޕᐔᚑ 21 ᐕᐲߩ⎇ⓥਛ㑆⊒ߩⷐᣦࠍᰴࡍࠫએ㒠ߦឝタߒ߹ߔޕ ஜ৻㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯183 ᧄศᄢ゠㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯185 ᧻ਅஜᴦ㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯187 ਃᜏ㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯㨯189 㧙 182 㧙 㧚ቇਈ ࡐࠬࡈࠖ࡞ࡓߩߣᔕ↪ Production and Application of Micro-Porous Films ஜ৻(Kenichi KON ) E-mail: [email protected] Porous film were produced by using honeycomb films produced by evaporation of organic solvents at high humidity. Inorganic honeycombs were prepared by formation of honeycombs from zinc acetylacetonate, followed by calcination. The purpose is for application as photocatalysts, which was evaluated by the absorbance change of a dye solution upon UV irraddiation. Furthermore, polstyrene beads can be arranged into the holes of porous honeycomb films. 㧨✜⸒㧪 ࡊ࠶ࠕࡓ࠻ࡏޔᚻᴺߣߒߡಽሶ⥄り߇ᜬߟ㈩ޔ㓸Ⓧᕈߣߞߚ‛ℂ⽎ ߢࠆ⥄Ꮖ⚵❱ൻࠍ↪ߚࡑࠗࠢࡠࡄ࠲࠾ࡦࠣ߇ടᎿᛛⴚߣߒߡᵈ⋡ߐࠇߡࠆߩߘޕ ⥄Ꮖ⚵❱ൻߦࠃࠅ᭽ߥޘᯏ⢻ᕈࠍᜬߞߚࡄ࠲࠾ࡦࠣߩ߇ⴕࠊࠇߡࠆޕታ㛎ߢߪ⥄ Ꮖ⚵❱ൻࠍ↪ߡశ⸅ᇦ߳ߩᔕ↪ߩߚࡐࠬࡈࠖ࡞ࡓߩࠍⴕߞߚޕ 㧨ታ㛎ᣇᴺ㧪 ታ㛎ߢߪޔZinc acetylacetonate ߣ᳓Ṣࠍቯൻߐߖࠆߚߦዋ㊂ߩ Poly ion complex ࠍട߃ߚṁᶧࠍߒߡࡐࠬ᭴ㅧߩࠍⴕߞߚޕߒߚࡈࠖ࡞ࡓࠍ 450͠ ߢࠕ࠾ࡦࠣࠍⴕ㉄ޔൻ㋦ࡐࠬࡈࠖ࡞ࡓࠍߒߚߩߎޕߒߚ㉄ൻ㋦ࡐ ࠬࡈࠖ࡞ࡓࠍ↪ߡ⦡⚛ߩಽ⸃ߦࠃࠆశ⸅ᇦലᨐߩ⹏ଔࠍⴕߞߚޕᰴߦ㉄ൻ㋕ࡐ ࠬࡈࠖ࡞ࡓߩࠍⴕߞߚޕᣇᴺߪޔPoly(styrene-co-maleic anhydride)㧦Poly ion Complex ࠍ 10㧦1 ߩഀวߢᯏṁᇦߦṁ⸃ߐߖߚ㜞ಽሶṁᶧࠍߒߡߩࡓ࡞ࠖࡈࠬࡐޔ ࠍⴕߞߚޕߒߚࡐࠬࡈࠖ࡞ࡓࠍ Ethanol amine ߣ Daimio octane ࠍ↪ߡࡓ࡞ࠖࡈޔ ࠍ᨞ᯅⷫޔ᳓ൻߒߚޕᰴߦ㉄ޔൻ㋕ߩ࠽ࡁ☸ሶࠍࠛ࠲ࡁ࡞ߦಽᢔߐߖߚṁᶧࠍߒߡޔ ߘߩṁᶧߦ᨞ᯅⷫޔ᳓ൻࡈࠖ࡞ࡓࠍ 24 ᤨ㑆ᶐߌߎߺ㉄ޔൻ㋕ࠍๆ⌕ߐߖߚޕߒߚ㉄ൻ ㋕ๆ⌕ࡈࠖ࡞ࡓࠍࠕ࠾ࡦࠣ 450͠ߢࠕ࠾ࡦࠣࠍⴕࠍࡑࡐޔಽ⸃ߒ㉄ൻ㋕ࡐ ࠬࡈࠖ࡞ࡓࠍߒߚޕᰴߦࡐࠬࡈࠖ࡞ࡓߩሹߦ PS ࡆ࠭ࠍ㈩ߐߖࠆታ㛎ࠍⴕߞ ߚޕ⸥ߣห᭽ߦ Poly(styrene-co-maleic anhydride)㧦Poly ion Complex ࠍ 10㧦1 ߩഀวߢ ߒߚ㜞ಽሶṁᶧࠍ↪ߡࠍࡓ࡞ࠖࡈࠬࡐޔߒߡ Ethanol amine ߣ Daimio octane ߢ 㕙ಣℂࠍⴕߞߚޕPS ࡆ࠭ߩࠛ࠲ࡁ࡞ಽᢔᶧߦޔ㕙ಣℂᷣߩࡐࠬࡈࠖ࡞ࡓࠍ 24 ᤨ 㑆ᶐߌߎߺሹߦ PS ࡆ࠭ࠍ㈩ߐߖߚޕ 㧨⚿ᨐ㧪 ㉄ൻ㋦ࡐࠬࡈࠖ࡞ࡓߩߢߪࠍࡓ࡞ࠖࡈࠬࡐߥࠇ߈ޔߔࠆ ߎߣ߇ߢ߈ߩߘޔశ⸅ᇦലᨐߪࡈ࠶࠻ࡈࠖ࡞ࡓߦߊࠄߴߡ 2 ߩലᨐ߇ߞߚޕPS ࡆ 㧙 183 㧙 㧚ቇਈ ࠭ߩ㈩ታ㛎ߢߪࡐࠬࡈࠖ࡞ࡓߩሹߦࡆ࠭ࠍ㈩ߐߖࠆߎߣ߇ߢ߈ߚ㉄ޕൻ㋕ࡐ ࠬࡈࠖ࡞ࡓߩߢߪ㉄ޔൻ㋕ࠍ߈ࠇߦๆ⌕ߐߖࠆߎߣ߇ߢ߈ߚޕએਅߦߘࠇߙࠇߩ ⷰኤ౮⌀ߣ㉄ൻ㋦ࡐࠬࡈࠖ࡞ࡓߩశ⸅ᇦ⹏ଔ⚿ᨐࠍ␜ߔޕ 5㱘m 10㱘m 2 ࡐࠬࡈࠖ࡞ࡓߩ PS ࡆ࠭ ࿑ 1 ㉄ൻ㋦ࡐࠬࡈࠖ࡞ࡓ ࿑ 10 㱘 ࿑ 3 ㉄ൻ㋕ࡐࠬࡈࠖ࡞ࡓ ࿑ 4 ㉄ൻ㋦ࡐࠬࡈࠖ࡞ࡓߩశ⸅ᇦലᨐ 1㧚Solvent Resistant Honeycomb Films from Photo-Crosslinkable Polycinnamate O. Karthaus, Y. Hashimoto, K. Kon, Y. Tsuriga Macromol. Rapid Commun., 28, 962-965 (2007) 2㧚Polymer Honeycomb Templated Microporous TiO2 Films with Enhanced Photocatalytic Activity K. Kon, K. Nakajima, O. Karthaus e-J. Surf. Sci. Nanotech., 6, 161-163 (2008) 㧙 184 㧙 㧚ቇਈ ᄙᵄ㐳శḮ↪ࡐࠪࡦశዉᵄ〝ᄖㇱᝄེߩ⎇ⓥ Study of polysilane optical waveguides external oscillator for multi wavelength light source ᧄศᄢ゠㧔Daiki MOTOYOSHI㧕 E-mail: [email protected] Polysilane waveguides present advantages of ease in processing using photo-bleaching technology for drawing Bragg grating on the polysilane film. In this study we present the tunable lasers (TLs) composed of the LD module optical switches and grating circuits, and those characteristics. The TLs are oscillating at the reflected wave with the grating. The switches and gratings are fabricated on the polysilane waveguide. ࡉࡠ࠼ࡃࡦ࠼߇᥉ߒߎߎᢙᐕ㑆ߢㅢା࠻ࡈࠖ࠶ࠢߩჇട߇ỗߒߊޔߩㅢାᣇ ᑼߢߪᡰ߃߈ࠇߥߊߥࠆน⢻ᕈ߇ࠆޕᓥ᧪ࠃࠅ߽㜞ㅦߥㅢାᣇᑼߢࠆ AWG-STAR ࡀ࠶ ࠻ࡢࠢ߿ WDM-PON ࠪࠬ࠹ࡓߦߪᵄ㐳นᄌࠩ߇↪ߢࠅޔDFB ඨዉᵄ㐳นᄌࠕ ࠗࠩߪᵄ㐳ㆬᛯ▸࿐߇ᐢߊޔ࡞࠻ࠢࡍࠬ⁜ޔ㜞ㅦᔕ╵ߢࠆ߇㜞ଔߢࠆ⎇ᧄޕⓥ ߢߪޔᵄ㐳ㆬᛯ▸࿐߇ᐢߊޔዊဳߢૐࠦࠬ࠻ൻ߇ᦸࠆᵄ㐳นᄌࠩߩᄖㇱᝄེߦߟ ߡޔᚲᦸߩ✢ߩࠩశࠍᓧࠆߚࡦࠪࡐޔశࠬࠗ࠶࠴ࠍߔࠆᄖㇱᝄེߩࡕ ࡁࠪ࠶ࠢൻࠍ⋡⊛ߣߒߡࠆ[1]ޕ ᵄ㐳นᄌࠩ↪ᄖㇱᝄེߪ 1×N శࠬࠗ࠶࠴߮ࠣ࠹ࠖࡦࠣߢ᭴ᚑߐࠇࠆ[2][3]ޕ శࠬࠗ࠶࠴ߣࠣ࠹ࠖࡦࠣߪࡐࠪࡦ⤑ߦᒻᚑߐࠇ⚡ߪࡦࠪࡐޔᄖ✢ᾖߦࠃ ࠅዮ᛬₸߇ਅ߇ࠆ․ᕈ㧔ࡈࠜ࠻ࡉ࠴ࡦࠣ⽎㧕ࠍᜬߟ[4]ࠅࠃߦ⽎ߩߎޕᚑ⤑ߒߚࡐ ࠪࡦߦࡈࠜ࠻࠰ࠣࡈࠖࠍ↪ߡ⋥ធ࿁〝ࡄ࠲ࡦࠍน⢻ߢࠆߚޔశዉᵄ 〝ࡊࡠࠬ߇ઁߩ᧚ᢱࠃࠅ◲ଢߢࠅޔૐࠦࠬ࠻ൻ߇ᦸࠆ[5]ޕ శࠬࠗ࠶࠴ߪᣇะᕈ⚿วེဳߢ⚿ޔวㇱߦ㊄ዻ⭯⤑ࠍᒻᚑߒࡅ࠲ߣߒߡࠆޕශടߔ ࠆߣᾲశቇലᨐߦࠃࠅዮ᛬₸߇ਅ߇ࠅቢో⚿ว㐳߇ᄌൻߒജࡐ࠻߇ࠬࠗ࠶࠴ߔࠆޕ ߹ߢᚒߪޘశࠬࠗ࠶࠴ߣࠣ࠹ࠖࡦࠣࠍߦߒߡ߈ߚ߇ޔਔ࿁〝ࠍࡕࡁࠪ ࠶ࠢߦߔࠆߢޔశࠬࠗ࠶࠴ㇱߣࠣ࠹ࠖࡦࠣㇱߩធ⛯៊ᄬ߇ߥߊߥࠅޔᄖㇱᝄ ེߩዊဳൻ߽น⢻ߣߥࠆ [6-8]ߪࠇߎޕశࠬࠗ࠶࠴࿁〝ࡄ࠲ࡦࠍᓟߦ✢⋥ޔዉᵄ〝ㇱ ߦੑశ᧤ᐓᷤ㔺శࠍⴕ߁ߎߣߢ߇น⢻ߢࠆޕ࿑ 1 ߦ 1×3 శࠬࠗ࠶࠴ߣࠣ࠹ࠖࡦ ࠣࠍߔࠆࡕࡁࠪ࠶ࠢᄖㇱᝄེ࿁〝ࠍ␜ߔ ࠻ࡐޕ1 ߩᝌ៊ᄬߪ-6.3dB ߢࠆࠣޕ ࠹ࠖࡦࠣߪੑశ᧤ᐓᷤ㔺శᴺࠍ↪ߡߒߡ߅ࠅ ࠻ࡐޔ1 ߩࠬࡍࠢ࠻࡞ࠍ࿑ 2 ߦ␜ߔޕᵄ㐳ߪ 1560.25nmޔඨ୯ోߪ 0.6nm એਅޔS/N Ყߪ 9dB એߢࠆޕ ࿑ 3 ߇ߒߚᄖㇱᝄེߩࡐ࠻ 1 ߦࠃࠆࠩ⊒ᝄࠬࡍࠢ࠻࡞ߢࠆޕਛᔃᵄ㐳߇ 1560.17nm߇ࡢࡄࠩޔ-9dBmޔඨ୯ో߇⚂ 0.1nmޔS/N Ყ߇⚂ 30dB ߢߞߚߩߘޕ ઁߩࡐ࠻ߢߪ᷹ቯߢ߈ߥ߆ߞߚޕ 㧙 185 㧙 㧚ቇਈ Port3 Heater 2 Port2 Heater 1 Port1 㪦㫇㫋㫀㪺㪸㫃㩷㫇㫆㫎㪼㫉㩷㩿㪻㪙㫄㪀 㪦㫇㫋㫀㪺㪸㫃㩷㫇㫆㫎㪼㫉㩷㩿㪸㪅㫌㪅㪀 ࿑ 1㧚ᣇะᕈ⚿วེဳశࠬࠗ࠶࠴ߣࠣ࠹ࠖࡦࠣࠍߔࠆᄖㇱᝄེ 㪈㪌㪋㪇 㪈㪌㪌㪇 㪈㪌㪍㪇 㪈㪌㪎㪇 㪈㪌㪏㪇 㪇 㪄㪈㪇 㪄㪉㪇 㪄㪊㪇 㪄㪋㪇 㪄㪌㪇 㪄㪍㪇 㪈㪌㪌㪐 㪮㪸㫍㪼㫃㪼㫅㪾㫋㪿㩷㩿㫅㫄㪀 㪈㪌㪌㪐㪅㪌 㪈㪌㪍㪇 㪈㪌㪍㪇㪅㪌 㪈㪌㪍㪈 㪮㪸㫍㪼㫃㪼㫅㪾㫋㪿㩷㩿㫅㫄㪀 ࿑ 2㧚ࠬࡍࠢ࠻࡞ ࿑ 3 ⊒ᝄࠬࡍࠢ࠻࡞ ේ࿃ߪࠣ࠹ࠖࡦࠣߩല₸߇ૐ߆ߞߚߎߣߣࠬࠗ࠶࠴៊ᄬ߇㜞ߊߦ࠲ࡅޔ㒢⇇ એߩශടࠍⴕߞߚߚࡅ࠲߇⎕៊ߒߡߒ߹ߞߚ߆ࠄߢࠆߩࠣࡦࠖ࠹ࠣޕല ₸ߦ㑐ߒߡߪࡕࡁࠪ࠶ࠢߦߔࠆߚߦޔ㓸Ⓧൻߐࠇߚ⋥✢ዉᵄ〝ㇱߦੑశ᧤ᐓᷤ㔺 శࠍⴕߞߚߚޔ㓞ធߔࠆዉᵄ〝߳⚡ᄖ✢߇ᾖߐࠇߡߒ߹ޔዮ᛬₸ᓮ߇ਇቢోߢ ߞߚߣ⠨߃ࠄࠇࠆޕᓟߪޔ㓞ធࡐ࠻߳ߩ⚡ᄖ✢ࠍㆤᢿߒߚ⹜ᢱߩࠍⴕᄙᵄ㐳⊒ ᝄ߇น⢻ߥᄖㇱᝄེߩࠍ⋡ᜰߔޕ ෳ⠨ᢥ₂ 1. S.Kobayashi et.al., (Invited) Proc. of SPIE, vol.6775, 67750H, 2007 2. M.C.Oh et.al., Appl.Phs. Lett., vol.73, pp2543-2545, 1998 3. D.Mechin et.al., J.Lightwave Tech. vol.19, no.9, pp.1282-1286, 2001 4. H.Tsushima et.al., (Invited) in SPIE Conference, Orange County, CA, September 7-11 2003 5. S.Kobayashi et.al., OECC2006, July 3-7 2006 6. S.Kobayashi et.al., LEOS 2005, Sydney, Australia 2005 paper ThJ4 7. S.Kobayashi et.al., IEEE Photon. Technol. Lett. vol.19, no.6, pp.363-365, 2007 8. D.Motoyoshi et.al., SPIE Photonic West 2009, San Jose, CA, USA, January 25-29 2009 㧙 186 㧙 㧚ቇਈ ᄌൻߦࡈࠚ࡞ࡒ㑐ᢙࠍ↪ߚਇဋ৻વㅍ✢〝ᦼ᭴ㅧࡈࠖ࡞࠲ Filter circuit with periodically arranged tapered microstriplines with linewidths determined by Fermi-Dirac distribution function ᧻ਅஜᴦ㧔Kenji Matsushita㧕 E-mail: [email protected] In this paper, a broadband bandstop filter consisting of periodically arranged nonuniform microstriplines is presented. The Fermi-Dirac distribution function is used for determining the linewidth of the microstriplines. The advantage of using this function is that the shape of the transmission line can be varied by varying a parameter of the function. Calculation and measurement results show that the filter designed using the Fermi-Dirac function provides frequency characteristics between a filter designed using a step function and a linear function. As a result, broadband bandstop filter with a center frequency of 5.25 GHz and bandwidth of 3.58 GHz was obtained. ਇဋ৻વㅍ✢〝㧔non-uniform transmissionline㧕ߪฎߊ߆ࠄ⎇ⓥ߇ߥߐࠇߡ߈ߚኻ⽎ߢࠆޕ ਇဋ৻વㅍ✢〝ߪࡊࡦ࠻ၮ᧼߿ICౝㇱߩ㈩✢ߥߤߦ߹ࠇߡ߅ࠅߩߎޔવㅍ․ᕈࠍᓧࠆ ߎߣߦࠃߞߡࠅࠃޔᱜ⏕ߥ࿁〝․ᕈߩ⸃ᨆ㧔ࠪࡒࡘ࡚ࠪࡦ㧕߇น⢻ߣߥࠆޔߚߩߘޕ ߦ߅ߡ߽ߘߩવㅍ․ᕈࠍᓧࠆߚߦᣂߒᣇᴺ߇ឭ᩺ߐࠇߡࠆ[1]ޔߚ߹ޕᦼ᭴ㅧ ࡈࠖ࡞࠲ߦߟߡ߽ޔฎߊߪዉᵄ▤ࠍ↪ߚࡈࠖ࡞࠲ߥߤ߇⍮ࠄࠇߡ߅ࠅޔવㅍ✢〝ߩᒻ ⁁ࠍᄌൻߐߖࠆߎߣߦࠃߞߡࠍ࠲࡞ࠖࡈࡊ࠶࠻ࠬ࠼ࡦࡃޔታߒߡࠆࠄࠇߎޔߢߎߘޕ ߩࠪࡒࡘ࡚ࠪࡦᛛⴚࠍᦼ᭴ㅧࡈࠖ࡞࠲⸃ᨆߦᔕ↪ߒޔછᗧߩ․ᕈࠍᜬߟࡃࡦ࠼ࠬ࠻ ࠶ࡊࡈࠖ࡞࠲ࠍ⸳⸘ߔࠆߎߣࠍ⋡⊛ߣߒߡޔ߹ߢߦ৻ᰴ㑐ᢙࠍ↪ߡᒻ⁁ࠍᄌൻߐߖ ߚਇဋ৻✢〝ࠍ↪ߚࡈࠖ࡞࠲ߦߟߡ⎇ⓥࠍⴕߞߡ߈ߚ[2]ߩߎޔߒ߆ߒޕᒻ⁁ߩࡈࠖ࡞࠲ ߪޔᐢ┵ߩ✢〝w1ߣ⁜┵ߩ✢〝w2ߩᲧ․ߜࠊߥߔޔᕈࠗࡦࡇ࠳ࡦࠬᲧࠍᄌൻߐߖࠆ ߎߣߦࠃߞߡߩߺ․ᕈ߇ᄌൻߔࠆߩߘޔߚߩߘޕᲧ߇ታน⢻ߢࠆ▸࿐ߪࠆߔ↪ޔ ၮ᧼ߩ‛ℂ⊛ኸᴺ߿⺃㔚₸ߦࠃߞߡ㒢߇ቯߐࠇߡߒ߹߁ߩߎޕ㗴ࠍ⸃ߔࠆߚߦޔ ᧄ⎇ⓥߢߪࡒ࡞ࠚࡈޔ㧙࠺ࠖ࠶ࠢ㑐ᢙࠍ✢〝ࠍቯߔࠆ㑐ᢙߣߒߡណ↪ߒ․ޔᕈࠗࡦ ࡇ࠳ࡦࠬᲧߛߌߢߪߥߊޔᒻ⁁ࠍᓮߔࠆଥᢙࠍࡄࡔ࠲ߣߒߡዉߒߚޕ࿑㧝ߦࡈ ࠚ࡞ࡒ㧙࠺ࠖ࠶ࠢ㑐ᢙߩࡄࡔ࠲ࠍᄌൻߐߖߚߣ߈ߩਇဋ৻વㅍ✢〝ߩᒻ⁁ᄌൻࠍ␜ ߔߡߞࠃߦࠇߎޕછᗧߩᏪၞߣᷫ₸ࠍߔࠆࡃࡦ࠼ࠬ࠻࠶ࡊࡈࠖ࡞࠲ࠍߔࠆߎߣ ߇ߢ߈ࠆߣ⠨߃ߚޕᦼ᭴ㅧࡈࠖ࡞࠲ߪࠣ࠶ࡉࠆࠁࠊޔ᭴ㅧࠍߒߡ߅ࠅ․ޔቯ ߩᵄᢙߦ߅ߡ㔚ജࠍߔࠆࡃࡦ࠼ࠬ࠻࠶ࡊࡈࠖ࡞࠲ߣߒߡേߔࠆࠖࡈߩߎޕ ࡞࠲ߩᦼ/ߣࠬ࠻࠶ࡊࡃࡦ࠼ߩਛᔃᵄᢙfmߣߩ㑐ଥߪޔታലᲧ⺃㔚₸Hreffߣ⌀ⓨਛߩశㅦ c0ࠍ↪ߡޔᰴߩࠃ߁ߦߔߎߣ߇ߢ߈ࠆޕ 㧙 187 㧙 㧚ቇਈ / c0 2 f m H reff ታ㓙ߦࡈࠖ࡞࠲ࠍߔࠆၮ᧼ߦߪ᧻ޔਅ㔚ᎿߩࠟࠬᾲലᨐPPO᮸⢽㌃ᒛⓍጀ᧼R-4726 ࠍㆬᛯߒߚߩߎޕၮ᧼ߩ⺃㔚₸Hrߪ2GHzߦ߅ߡ3.4ߢࠆޔߣࠆߔޕਛᔃᵄᢙfmࠍ5.2GHz ߣ⸳ቯߒߚ႐วߩ࠲࡞ࠖࡈޔᦼ/ߪߘࠃ߅ޔ17.6mmߣߥࠆޔߚ߹ޕࠍቯߔࠆ㑐ᢙwi(x) ࠍߩߎޔᦼ/ߣࡈࠚ࡞ࡒ㧙࠺ࠖ࠶ࠢ㑐ᢙࠍߞߡᰴߩࠃ߁ߦ⸳ቯߔࠆޕ wi x 1 § wd x · ¨ 1¸w1 w2 w2 , wd x 2 ¨© wd 0 ¸¹ 1 ª ln 99 ½º 1 exp « A® x ln 99¾» ¿¼ ¬ ¯/ 4 ߚߛߒޔxߪવㅍᣇะߩ㐳ߐޔAߪᒻ⁁ࠍቯߔࠆଥᢙߢࠆߩߎޕଥᢙAࠍᄌൻߐߖࠆߎߣ ߦࠃߞߡࡦ࠲ࡄߩ࠲࡞ࠖࡈޔᒻ⁁ߪ৻ᰴ㑐ᢙ߆ࠄࠬ࠹࠶ࡊ㑐ᢙ߹ߢᄌൻߒޔવㅍ․ᕈߢ ࠆS21ߦߟߡ߽ޔᣇߩ․ᕈߩ㑆ߢᄌൻߔࠆߣ⠨߃ࠄࠇࠆߩߎޕଥᢙAߦኻߔࠆવㅍ․ᕈ ߩᄌൻߦߟߡ⚿▚⸘ޔᨐߣ᷹ቯ⚿ᨐࠍ࿑2ߦ␜ߔޕ㤥⦡ߩ✢߇᷹ቯ⚿ᨐߢࠅޔἯ⦡ߩ✢ ߇⸘▚⚿ᨐߢࠆ߷߶ߣ⸘⸳ޔߦ߁ࠃߩߎޕหߓ5.25GHzߩਛᔃᵄᢙߢޔᏪၞ߇3.58GHz ߩࡃࡦ࠼ࠬ࠻࠶ࡊࡈࠖ࡞࠲ࠍᓧࠆߎߣ߇ߢ߈ߚޔߚ߹ޕଥᢙAࠍᄌൻߐߖࠆߎߣߦࠃߞߡޔ ࡈࠚ࡞ࡒ㧙࠺ࠖ࠶ࠢ㑐ᢙᒻ⁁ࡈࠖ࡞࠲ߪ৻ޔᰴ㑐ᢙᒻ⁁ߣࠬ࠹࠶ࡊ㑐ᢙᒻ⁁ࠍ↪ߚࡈ ࠖ࡞࠲ߩ․ᕈߩ㑆ߢᄌൻߔࠆࠍ⏕ߔࠆߎߣ߇ߢ߈ߚޕ ᓟߪࠅࠃޔᐢᏪၞߢᄢ߈ߥᷫ߇ᦼᓙߢ߈ࠆޔਃዉ♽ߦ߅ߌࠆᦼ᭴ㅧࡈࠖ࡞࠲ߦ㑐 ߒߡ⎇ⓥࠍⴕ߁੍ቯߢࠆޕ w2 w1 |S21| [dB] 0 í20 í40 linear A = 0.5 A=1 A=2 Step 2 ࿑㧝 ଥᢙ A ߦኻߔࠆᒻ⁁ߩᄌൻ linear A=0.5 A=1 A=2 step 4 6 Frequency [GHz] 8 ࿑㧞 ଥᢙ A ߦኻߔࠆ|S21|ߩᄌൻ ෳ⠨ᢥ₂ 㧝㧚M.H.Eghlidi, K.Mehrany, and B.Rashidian, IEEE Trans. MTTs-54, No.12, Dec (2006). 㧞㧚K. Matsushita, and M.Fukuda, IEEJ Trans. Electrical and Electronic Engineering, Vol.5, No.1, (2009). 㧙 188 㧙 㧚ቇਈ 㧙 189 㧙 㧚ቇਈ 㧙 190 㧙