3 - 大阪大学 産業科学研究所 - Osaka University

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[㝃㸯] ྛ◊✲㒊㛛ࡢ⤌⧊࡜άື
[㝃㸰] ྛ㝃ᒓ◊✲᪋タ➼ࡢ⤌⧊࡜άື
[㝃㸱] ඹ㏻᪋タ➼ࠊᢏ⾡ᐊࠊ஦ົ㒊ࡢ⤌⧊࡜άື
[㝃㸲] ྛ◊✲㒊㛛ࠊ㝃ᒓ᪋タ࡟࠾ࡅࡿάືᐇ⦼ࣜࢫࢺ
ᮏᖺḟሗ࿌᭩ࡣࠊᖹᡂ 26 ᖺᗘ㸦ᖹᡂ 26 ᖺ㸦2014㸧4 ᭶ 1 ᪥࠿ࡽᖹᡂ 27 ᖺ㸦2015㸧3 ᭶ 31 ᪥ࡲ࡛㸧
ࢆᑐ㇟࡜ࡋࡓࡶࡢ࡛࠶ࡿࠋ
㸯㸬ࡣࡌࡵ࡟
ᡤ㛗 ୰㇂࿴ᙪ
኱㜰኱Ꮫ⏘ᴗ⛉Ꮫ◊✲ᡤ௨ୗ⏘◊ࡣࠊࠕ⮬↛⛉Ꮫ࡟㛵ࡍࡿ≉Ṧ஦㡯࡛⏘ᴗ࡟ᚲせ࡞ࡶࡢࡢᇶ♏ⓗᏛ
⌮࡜ࡑࡢᛂ⏝ࡢ◊✲ࠖ࡟ᑐࡍࡿ㛵すࡢ⏘ᴗ⏺ࡢᙉ࠸ᮇᚅ࡜せᮃࢆ⫼ᬒ࡟ࠊ᫛࿴ ᖺ࡟ㄌ⏕ࡋࡲࡋࡓࠋ
タ❧௨᮶ࠊ㛵ಀྛ఩ࡢᚚᨭ᥼࡟ࡼࡾࠊ᫬௦ࡢኚ㑄࡜ඹ࡟Ⓨᒎࡋࠊ⌧ᅾࡶ᪂ࡓ࡞⏘ᴗ๰ᡂࡢ※Ἠ࡜࡞ࡿ
ᇶ♏⛉Ꮫࢆᴟࡵࠊࡑࡢᡂᯝ࡟❧⬮ࡋ࡚ᛂ⏝⛉Ꮫࢆᒎ㛤ࡍࡿࡇ࡜ࢆ┠ⓗ࡟ࠊᮦᩱࠊ᝟ሗࠊ⏕యࡢ 㡿ᇦࡢ
◊✲࡜ࢼࣀࢸࢡࣀࣟࢪ࣮࣭ࢼࣀࢧ࢖࢚ࣥࢫศ㔝ࡢ◊✲ࢆ᥎㐍ࡍࡿ⥲ྜ⌮ᕤᏛᆺ◊✲ᡤ࡜ࡋ࡚Ṕྐࢆ้ࢇ
࡛࠸ࡲࡍࠋ
≉࡟ࢼࣀࢧ࢖࢚ࣥࢫ࡛ࡣࠊ඲ᅜࡢᅜ❧኱Ꮫ࡟ඛ㥑ࡅ࡚⏘ᴗ⛉Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮ࢆタ❧ࡋࠊ
ᡃࡀᅜ࡟࠾ࡅࡿࢼࣀࢧ࢖࢚ࣥࢫ◊✲ࡢඛᑟⓗᙺ๭ࢆᯝࡓࡋ⥆ࡅ࡚࠸ࡲࡍࠋࡲࡓࠊ໭ᾏ㐨኱Ꮫ㟁Ꮚ⛉Ꮫ◊
✲ᡤࠊᮾ໭኱Ꮫከඖ≀㉁⛉Ꮫ◊✲ᡤࠊᮾிᕤᴗ኱Ꮫ㈨※໬Ꮫ◊✲ᡤࠊ኱㜰኱Ꮫ⏘ᴗ⛉Ꮫ◊✲ᡤࠊ஑ᕞ኱
Ꮫඛᑟ≀㉁໬Ꮫ◊✲ᡤࡢ ኱Ꮫ㝃⨨◊✲ᡤ࡟ࡼࡿ඲ᅜࢿࢵࢺ࣮࣡ࢡᆺࠕ≀㉁࣭ࢹࣂ࢖ࢫ㡿ᇦඹྠ◊✲ᣐ
ⅬࠖࢆᙧᡂࡋࠊࡑࡢᣐⅬᮏ㒊࡜ࡋ࡚ࠊᡃࡀᅜ࡛ࡣ๓౛ࡢ࡞࠸᪂ࡋ࠸ຠ⋡ⓗ࡞ඹྠ◊✲ࢩࢫࢸ࣒ࢆᵓ⠏ࠊ
Ⓨᒎࡉࡏ࡚ཧࡾࡲࡋࡓࠋࡇࡢඹྠ◊✲ᣐⅬࡣᖹᡂ ᖺᗘᩥ㒊⛉Ꮫ┬ࡀᐇ᪋ࡋࡓᮇᮎホ౯࡟࠾࠸࡚ࠊ≉
➹ࡍ࡭ࡁᡂᯝࡸຠᯝࡀぢࡽࢀࠊ㛵㐃ࢥ࣑ࣗࢽࢸ࢕࡬ࡢ㈉⊩ࡶከ኱࡛࠶ࡗࡓᣐⅬ࡜ࡋ࡚ࠊ᭱㧗ࣛࣥࢡࡢ 6
༊ศ࡜ࡋ࡚ホ౯ࡉࢀ࡚࠸ࡲࡍࠋ
⏘◊࡛⏕ࡲࢀ࡚ࡃࡿᡂᯝࢆ⏘ᴗ࡟⏕࠿ࡍࡓࡵࠊ࢖ࣥࢲࢫࢺ࣮ࣜ࢜ࣥ࢟ࣕࣥࣃࢫࢆᐇ⌧ࡍࡿ࢖ࣥ࢟ࣗ࣋
࣮ࢩࣙࣥᲷࢆᖹᡂ ᖺ࡟᏶ᡂࡉࡏࠊ௻ᴗࣜࢧ࣮ࢳࣃ࣮ࢡࡀ✌ാࡋ࡚࠸ࡲࡍࠋࡇࢀࡽ࡟ຍ࠼ࠊᖹᡂ ᖺ
ᗘ࡟ࡣࠊୡ⏺᭱኱ࡢࢼࣀࢸࢡ◊✲ᶵ㛵 LPHF ࡜⏘◊࡜ࡢ㛫࡛ໟᣓⓗ࡞ඹྠ◊✲ዎ⣙ࡀ⥾⤖ࡉࢀࡲࡋࡓࠋ
௻ᴗࣜࢧ࣮ࢳࣃ࣮ࢡཧ⏬௻ᴗࡢᐇ⏝໬ࢽ࣮ࢬ࡜⏘◊ࡢᣢࡘᮦᩱࠊ᝟ሗࠊ⏕యࠊࢼࣀࢸࢡࣀࣟࢪ࣮ࡢࢩ࣮
ࢬ࣏ࢸࣥࢩࣕࣝࢆᅜ㝿⯙ྎ࡛⤖ࡧ௜ࡅࡿ⥲ྜⓗ◊✲㛤Ⓨ᥎㐍ࣉࣟࢢ࣒ࣛࡢᥦ౪ࢆ┠ᣦࡋ࡚࠸ࡲࡍࠋ
኱Ꮫ࡟࠾ࡅࡿᇶ♏◊✲ࡶࠊ♫఍ࡢせㄳࢆⓗ☜࡟ᢕᥱࡋࠊᅜẸࡢᮇᚅ࡟ᛂ࠼ࡿ⛉Ꮫࡢ๰ฟࡀồࡵࡽࢀࡲ
ࡍࠋ⚾ඹࡣࠊࠕฟཱྀࢆぢᤣ࠼ࡓᇶ♏◊✲ࠖࢆ◊✲ࢫ࣮ࣟ࢞ࣥ࡜ࡋ࡚ࠊ⏘ᴗ⏺࡜ࡢ㐃ᦠࢆᙉ໬ࡍࡿ᪋⟇ࢆ
❧࡚ࡓ࠸࡜⪃࠼࡚࠾ࡾࡲࡍࠋ⏘◊ࡣࠊṔྐ࡜ఏ⤫ࢆ⫼ᬒ࡟ࠊ᪂ࡋ࠸᫬௦ࢆ࣮ࣜࢻࡍ࡭ࡃࠊ௒ᚋࡶ⎔ቃ࣭
࢚ࢿࣝࢠ࣮࣭་⒪࣭Ᏻ඲Ᏻᚰ࡟㛵ࡍࡿㄢ㢟ࢆゎỴࡍࡿࡇ࡜ࢆ୰ᚰ࡟ࠊ⊂⮬ᛶࡢ㧗࠸ୡ⏺᭱ඛ➃ࡢᇶ┙⛉
Ꮫᢏ⾡๰ฟࡢດຊࢆ⥆ࡅ࡚ཧࡾࡲࡍࠋ
ᮏሗ࿌᭩ࡣࠊ⏘◊࡟ࡼࡿᖹᡂ ᖺᗘࡢ◊✲࣭ᩍ⫱࣭♫఍㈉⊩ࡢᡂᯝࡢグ㘓࡛ࡍࠋⓙࡉࡲ࡟ࡈ୍ㄞ
࠸ࡓࡔࡁࠊ⏘◊ࡢࡼࡾ୍ᒙࡢⓎᒎࡢࡓࡵ࡟ࠊࡈྏṇࠊࡈᢈุࢆ㡬ࡅࢀࡤᖾ࠸࡛ࡍࠋ௒ᚋ࡜ࡶⓙᵝࡢ ࠿
࠸ࡈᨭ᥼࡜ࡈ༠ຊ࣭ࡈ㠴᧡ࢆᚰࡼࡾ࠾㢪࠸࠸ࡓࡋࡲࡍࠋ
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࣭ᶵᵓᅗ㸦ᖹᡂ㸰㸵ᖺ㸱᭶㸱㸯᪥⌧ᅾ㸧
ᡤ 㛗
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ࢼࣀຍᕤᐊ
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ࢼࣀࢸࢡඛ➃ᶵჾᐊ
ບ㉳ศᏊ໬Ꮫ◊✲ศ㔝
ࢼࣀࢸࢡࣀࣟࢪ࣮タഛ౪⏝ᣐⅬ
ᶵ⬟≀㉁໬Ꮫ◊✲ศ㔝
⢭ᐦไᚚ໬Ꮫ◊✲ศ㔝
㝃ᒓ⥲ྜゎᯒࢭࣥࢱ࣮
་⸆ရ໬Ꮫ◊✲ศ㔝
㝃ᒓ㔞Ꮚࣅ࣮࣒⛉Ꮫ◊✲᪋タ
⏕యゐ፹⛉Ꮫ◊✲ศ㔝
㝃ᒓ⏘ᴗ⛉Ꮫ㐃ᦠᩍ⫱᥎㐍ࢭࣥࢱ࣮
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⏕యศᏊᶵ⬟⛉Ꮫ◊✲ศ㔝
ࢼࣀ࣐ࢡࣟ≀㉁࣭ࢹࣂ࢖ࢫ࣭ࢩࢫࢸ࣒࢔ࣛ࢖࢔ࣥࢫ
ḟୡ௦࢚ࣞࢡࢺࣟࢽࢡࢫ
᪂⏘ᴗ๰ᡂ◊✲㒊㛛
᪂࢚ࢿࣝࢠ࣮ᮦᩱ࣭ࢹࣂ࢖ࢫ
᪂⏘ᴗண ◊✲ศ㔝
་⒪ᮦᩱ࣭ࢹࣂ࢖ࢫ
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⎔ቃㄪ࿴ᮦᩱ࣭ࢹࣂ࢖ࢫ
▱ⓗ㈈⏘◊✲ศ㔝
ඹ㏻᪋タ
≉ูࣉࣟࢪ࢙ࢡࢺ◊✲㒊㛛
ヨసᕤሙ
➨㸯ࣉࣟࢪ࢙ࢡࢺ◊✲㒊㛛
ᨺᑕᛶྠ఩ඖ⣲ᐇ㦂ᐊ
➨㸰ࣉࣟࢪ࢙ࢡࢺ◊✲㒊㛛
㟁Ꮚࣉࣟࢭࢫᐇ㦂ᐊ
ᴟᚤᮦᩱࣉࣟࢭࢫ◊✲ศ㔝
᝟ሗࢿࢵࢺ࣮࣡ࢡᐊ
ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ᮦᩱ◊✲ศ㔝
⏘Ꮫ㐃ᦠᐊ
➨㸱ࣉࣟࢪ࢙ࢡࢺ◊✲㒊㛛
ᗈሗᐊ
⏕య㜵ᚚᏛ◊✲ศ㔝
௻⏬ᐊ
᪋タ⟶⌮ᐊ
࢔ࣛ࢖࢔ࣥࢫࣛ࣎
ᅗ᭩ᐊ
㔞Ꮚ᝟ሗࣇ࢛ࢺࢽࢡࢫ◊✲ศ㔝
㜰኱⏘◊࣭໭኱㟁Ꮚ◊࢔ࣛ࢖࢔ࣥࢫࣛ࣎
ᢏ⾡ᐊ
⑌ᝈ⢾㙐ࢆ୰ᚰ࡜ࡋࡓࢣ࣑࢝ࣝࣂ࢖࢜ࣟ
ࢪ࣮◊✲ศ㔝
஦ົ㒊 㜰኱⏘◊࣭⌮◊࢔ࣛ࢖࢔ࣥࢫࣛ࣎
―2―
࣭ᩍဨ⤌⧊ 㸦ᖹᡂ㸰㸵ᖺ㸱᭶㸱㸯᪥⌧ᅾ㸧
‫✲◊ ➨ڦ‬㒊㛛᝟ሗ࣭㔞Ꮚ⛉Ꮫ⣔
㔞Ꮚࢩࢫࢸ࣒๰ᡂ◊✲ศ㔝
ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
኱ᒾ 㢧
෸ᩍᤵ
ᕤᏛ༤ኈ
㛗㇂ᕝ⦾ᙪ
ຓᩍ
⌮Ꮫ༤ኈ
Ụᮧ ಟ୍
≉௵◊✲ဨ㸦ᖖ໅㸧
ಟኈ㸦ᕤᏛ㸧
ᮌᒣ ἞ᶞ
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ᩍᤵ
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ᯇᮏ ࿴ᙪ
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⌮Ꮫ༤ኈ
஭ୖ ᜏ୍
ຓᩍ
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ຓᩍ
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ᑠ㔝 ᑲ⏕
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ᩍᤵ
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≉௵ㅮᖌ㸦ᖖ໅㸧
༤ኈ㸦ᕤᏛ㸧
ᮧᯇ ኱࿃
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦ᕤᏛ㸧
୰⃝ ‶
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦᝟ሗ⛉Ꮫ㸧
୹⩚ ┿㝯
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦᝟ሗ⛉Ꮫ㸧
+D]HP0*(O$OI\
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦᝟ሗᏛ㸧
/L:HL
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦᝟ሗ⛉Ꮫ㸧
⏣ᕝ ⪷୍
▱⬟᥎ㄽ◊✲ศ㔝
ᩍᤵ
ᕤᏛ༤ኈ
㮖ᑿ 㝯
෸ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
ΎỈ ᫀᖹ
෸ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
Ἑཎ ྜྷఙ
ຓᩍ
༤ኈ㸦᝟ሗᏛ㸧
ᮡᒣ 㯢ே
▱㆑⛉Ꮫ◊✲ศ㔝
ᩍᤵ
༤ኈ㸦᝟ሗᏛ㸧
㥖㇂ ࿴⠊
෸ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
౗ᮧ ᚨಙ
෸ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
ྂᓮ ᫭ྖ
ຓᩍ
༤ኈ㸦᝟ሗᏛ㸧
Ṋ⏣ 㱟
≉௵ຓᩍ㸦ᖖ໅㸧
ಟኈ㸦་⛉Ꮫ㸧
ᒣ⦩ ཭⣖
ᩍᤵ
ᕤᏛ༤ኈ
἟ᑿ ṇ⾜
ຓᩍ
༤ኈ㸦ᕤᏛ㸧
᳃ᒣ ⏥୍
ຓᩍ
༤ኈ㸦᝟ሗ⛉Ꮫ㸧
⚟஭ ೺୍
▱⬟࢔࣮࢟ࢸࢡࢳࣕ◊✲ศ㔝
‫✲◊ ➨ڦ‬㒊㛛㸦ᮦᩱ࣭ࣅ࣮࣒⛉Ꮫ⣔㸧
㔞Ꮚᶵ⬟ᮦᩱ◊✲ศ㔝
ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
Ᏻ⸨ 㝧୍
෸ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
℩ᕝ ⪔ྖ
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
బࠎᮌ ⪽
―3―
ຓᩍ
3K'㸦≀⌮Ꮫ㸧
7DVNLQ$
༙ᑟయᮦᩱ࣭ࣉࣟࢭࢫ◊✲ศ
㔝
ᩍᤵ
⌮Ꮫ༤ኈ
ᑠᯘ ග
෸ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
ᯇᮏ ೺ಇ
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
௒ᮧ ೺ኴ㑻
ඛ➃ࣁ࣮ࢻᮦᩱ◊✲ศ㔝
ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
㛵㔝 ᚭ
෸ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
ከ᰿ ṇ࿴
ຓᩍ
༤ኈ㸦ᕤᏛ㸧
ᚋ⸨ ▱௦
ඛ➃ᐇ⿦ᮦᩱ◊✲ศ㔝
ᩍᤵ
ᕤᏛ༤ኈ
Ⳣ἟ ඞ᫛
ຓᩍ
༤ኈ㸦ᕤᏛ㸧
Ⳣཎ ᚭ
≉௵෸ᩍᤵ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
㛗ᑿ ⮳ᡂ
≉௵ຓᩍ㸦ᖖ໅㸧
༤ኈ㸦໬ᏛᕤᏛ㸧
㓇 㔠፱
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦ᮌᮦ⛉Ꮫ㸧
ᓲ ఍᪲
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦ᛂ⏝໬Ꮫ㸧
6LQJK 0DQMHHW
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦ᕤᏛ㸧
ᮔ ⪷※
≉௵◊✲ဨ㸦ᖖ໅㸧
ῦ㇂ ⣖ኵ
≉௵◊✲ဨ㸦ᖖ໅㸧
ᮌᮏ ᖾ἞
ບ㉳≀ᛶ⛉Ꮫ◊✲ศ㔝
ᩍᤵ
ᕤᏛ༤ኈ
㇂ᮧ ඞᕫ
෸ᩍᤵ
⌮Ꮫ༤ኈ
⏣୰ ៅ୍㑻
༤ኈ㸦⌮Ꮫ㸧
㔠㷂 㡰୍
⌮Ꮫ༤ኈ
☾ᒣ ᝅᮁ
෸ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
ຍ⸨ 㱟ዲ
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
ᕝ℩ ၨᝅ
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
ධ⃝ ᫂඾
㔞Ꮚࣅ࣮࣒≀㉁⛉Ꮫ◊✲ศ㔝 ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
ྂ⃝ Ꮥᘯ
෸ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
ᐊᒇ ⿱బ
ຓᩍ
ᕤᏛ༤ኈ
ᑠᯘ ୍㞝
ຓᩍ
༤ኈ㸦ᕤᏛ㸧
ᒣᮏ ὒ᥹
෸ᩍᤵ
㔞Ꮚࣅ࣮࣒Ⓨ⏕⛉Ꮫ◊✲ศ㔝 ᩍᤵ
‫✲◊ ➨ڦ‬㒊㛛㸦⏕య࣭ศᏊ⛉Ꮫ⣔㸧
ບ㉳ศᏊ໬Ꮫ◊✲ศ㔝
ᩍᤵ
ᕤᏛ༤ኈ
┿ᔱ ဴᮁ
෸ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
⸨ሯ Ᏺ
෸ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
ᕝ஭ Ύᙪ
ᶵ⬟≀㉁໬Ꮫ◊✲ศ㔝
ຓᩍ
༤ኈ㸦ᕤᏛ㸧
ᑠ㜰⏣ ὈᏊ
ᩍᤵ
ᕤᏛ༤ኈ
➲஭ ᏹ᫂
෸ᩍᤵ
༤ኈ㸦⸆Ꮫ㸧
⃝ ᚸ
ຓᩍ
⌮Ꮫ༤ኈ
ᕷཎ ₶Ꮚ
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
➉୰ ࿴ᾈ
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
0RKDQWD6XPDQ&
⢭ᐦไᚚ໬Ꮫ◊✲ศ㔝
ᩍᤵ
⌮Ꮫ༤ኈ
୰㇂ ࿴ᙪ
෸ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
ᇽ㔝 ୺⛯
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
Ṋ஭ ྐᜨ
ຓᩍ
༤ኈ㸦⏕࿨⛉Ꮫ㸧
ᮧ⏣ ளἋᏊ
―4―
≉௵ຓᩍ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
≉௵◊✲ဨ㸦ᖖ໅㸧
3K'㸦᭷ᶵ໬Ꮫ㸧 0XNKHUMHH6
་⸆ရ໬Ꮫ◊✲ศ㔝
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
ᒣ⏣ ๛ྐ
ᩍᤵ
⌮Ꮫ༤ኈ
ຍ⸨ ಟ㞝
෸ᩍᤵ
⌮Ꮫ༤ኈ
࿴⏣ ὒ
ຓᩍ
⌮Ꮫኈ
᪂⏣ Ꮧ
ຓᩍ
⌮Ꮫ༤ኈ
ᒣཱྀ ಇ㑻
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
ᵽཱྀ 㞝௓
≉௵෸ᩍᤵ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
㛤ⓐ 㑥ᏹ
⏕యゐ፹⛉Ꮫ◊✲ศ㔝
෸ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
ᒸᓥ ಇⱥ
ຓᩍ
ಟኈ㸦ᕤᏛ㸧
❧ᯇ ೺ྖ
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
୰஭ ᛅᚿ
⏕య᝟ሗไᚚᏛ◊✲ศ㔝
෸ᩍᤵ
༤ኈ㸦⸆Ꮫ㸧
す㔝 㑥ᙪ
෸ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
≉௵◊✲ဨ㸦ᖖ໅㸧㸦ᐈ
༤ኈ㸦་Ꮫ㸧
ဨᩍᤵ㸧
⏕యศᏊᶵ⬟⛉Ꮫ◊✲ศ㔝
┦ᕝ ᫓ኵ
す Ẏ
ᯇᮏ ెᕭ
ᩍᤵ
༤ኈ㸦་Ꮫ㸧
Ọ஭ ೺἞
෸ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
ᯇ⏣ ▱ᕫ
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
᪂஭ ⏤அ
ຓᩍ
≉௵෸ᩍᤵ㸦ᖖ໅㸧
≉௵ຓᩍ㸦ᖖ໅㸧
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
༤ኈ㸦⌮Ꮫ㸧
༤ኈ㸦⌮Ꮫ㸧
3K'㸦⏕⌮Ꮫ㸧
୰㔝 㞞⿱
࿴ἑ 㕲୍
ᒾ㔝 ᝴
3HUH].ROGHQNRYD9
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
ྜྷ⏣ 㑥ே
‫▱ڦ‬ⓗ㈈⏘◊✲ศ㔝
≉௵ᩍᤵ㸦ᖖ໅㸧
‫✲◊ࢺࢡ࢙ࢪࣟࣉู≉ڦ‬㒊㛛
ᕤᏛ༤ኈ
ΎỈ ⿱୍
➨㸰ࣉࣟࢪ࢙ࢡࢺ◊✲ศ㔝
≉௵ຓᩍ㸦ᖖ໅㸧
༤ኈ㸦ᕤᏛ㸧
㛗ᓥ ୍ᶞ
ᴟᚤᮦᩱࣉࣟࢭࢫ
➨㸰ࣉࣟࢪ࢙ࢡࢺ◊✲ศ㔝
෸ᩍᤵ
༤ኈ㸦㎰Ꮫ㸧
⬟ᮌ 㞞ஓ
㺜㺷㺹㺎㺛㺣㺧㺪㺅㺐㺨㺼㺎ᮦᩱ
≉௵ຓᩍ㸦ᖖ໅㸧
༤ኈ㸦㎰Ꮫ㸧
ྂ㈡ ኱ᑦ
➨㸱ࣉࣟࢪ࢙ࢡࢺ◊✲ศ㔝
≉௵ᩍᤵ㸦ᖖ໅㸧
⸆Ꮫ༤ኈ
ᒣཱྀ ᫂ே
⏕య㜵ᚚᏛ
≉௵෸ᩍᤵ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
୰ᓥ Ⰻ௓
≉௵ຓᩍ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
Ḉ஭ ၨ௓
㔞Ꮚ᝟ሗࣇ࢛ࢺࢽࢡࢫ◊✲ศ
㔝㸦໭኱㟁Ꮚ◊࢔ࣛ࢖࢔ࣥࢫ
ࣛ࣎㸧
ᣍ࡬࠸ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
➉ෆ ⦾ᶞ
ᣍ࡬࠸ᩍဨ
༤ኈ㸦ᕤᏛ㸧
ᒸᮏ ு
ᣍ࡬࠸ᩍဨ
༤ኈ㸦⌮Ꮫ㸧
⸨ཎṇ⃈
⑌ᝈ⢾㙐ࢆ୰ᚰ࡜ࡋࡓࢣ࣑࢝
ࣝࣂ࢖࢜ࣟࢪ࣮◊✲ศ㔝㸦㜰
኱⏘◊࣭⌮◊࢔ࣛ࢖࢔ࣥࢫࣛ
࣎㸧
ᣍ࡬࠸ᩍᤵ
༤ኈ㸦་Ꮫ㸧
㇂ཱྀ ┤அ
ᣍ࡬࠸ᩍᤵ
༤ኈ㸦⸆Ꮫ㸧
኱ᆤ ࿴᫂
ᣍ࡬࠸ᩍဨ
༤ኈ㸦་Ꮫ㸧
㧗 ྀ➗
ᣍ࡬࠸ᩍဨ
༤ኈ㸦་Ꮫ㸧
᫝㔠 ᏹ᫛
‫ڦ‬᪂⏘ᴗ๰ᡂ◊✲㒊㛛
‫࣎ࣛࢫࣥ࢔࢖ࣛ࢔ڦ‬
―5―
‫ڦ‬㝃ᒓ⏘ᴗ⛉Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮
ࢼࣀᶵ⬟ᮦᩱࢹࣂ࢖ࢫ◊✲ศ
㔝
ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
⏣୰ ⚽࿴
෸ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
⚄ྜྷ ㍤ኵ
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
᭹㒊 ᱻ
ຓᩍ
༤ኈ㸦⛉Ꮫ㸧
⸨ཎ ᏹᖹ
ࢼࣀᴟ㝈ࣇ࢓ࣈࣜࢣ࣮ࢩࣙࣥ
◊✲ศ㔝
ᩍᤵ
ᕤᏛ༤ኈ
ྜྷ⏣ 㝧୍
෸ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
᳿ 㔠ᓠ
ຓᩍ
ಟኈ㸦⌮Ꮫ㸧
㏆⸨ Ꮥᩥ
ຓᩍ
༤ኈ㸦ᕤᏛ㸧
Ⳣ ᫭୍
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
⚄ᡞ ṇ㞝
⌮Ꮫ༤ኈ
➉⏣ ⢭἞
෸ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
ྜྷ⏣ ⚽ே
ຓᩍ
༤ኈ㸦ᕤᏛ㸧
⚄ෆ ┤ே
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
㯞⏕ ுኴ㑻
ࢼࣀᶵ⬟ண ◊✲ศ㔝
ᩍᤵ
༤ኈ㸦⌮Ꮫ㸧
ᑠཱྀ ከ⨾ኵ
෸ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
ⓑ஭ ග㞼
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
ᒣෆ 㑥ᙪ
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
⢄⏣ ᾈ⩏
≉௵◊✲ဨ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
㇏⏣ 㞞அ
ࢯࣇࢺࢼࣀ࣐ࢸࣜ࢔ࣝ◊✲ศ
㔝
ᩍᤵ
⌮Ꮫ༤ኈ
Ᏻ⸽ ⰾ㞝
෸ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
ᐙ ⿱㝯
ຓᩍ
༤ኈ㸦㎰Ꮫ㸧
㎞ᕝ ㄔ
ຓᩍ
༤ኈ㸦ᕤᏛ㸧
஧㇂ ┿ྖ
ࣂ࢖࢜ࢼࣀࢸࢡࣀࣟࢪ࣮◊✲
ศ㔝
ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
㇂ཱྀ ṇ㍤
෸ᩍᤵ
༤ኈ㸦ᕤᏛ㸧
⟄஭ ┿ᴋ
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
⏣୰ ⿱⾜
ຓᩍ
༤ኈ㸦⌮Ꮫ㸧
ᶓ⏣ ୍㐨
≉௵ຓᩍ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
኱ᇛ ᩗே
≉௵◊✲ဨ㸦ᖖ໅㸧
Ụᓮ ⿱Ꮚ
ࢼࣀࢸࢡࣀࣟࢪ࣮タഛ౪⏝ᣐ
Ⅼ
≉௵ຓᩍ㸦ᖖ໅㸧
༤ኈ㸦ᮦᩱ⛉Ꮫ㸧
໭ᓥ ᙲ
≉௵ຓᩍ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
ἲ⃝ බᐶ
≉௵◊✲ဨ㸦ᖖ໅㸧
ಟኈ㸦ᕤᏛ㸧
ᵽཱྀ ᏹ஧
≉௵◊✲ဨ㸦ᖖ໅㸧
᯽಴ ⨾⣖
≉௵ㅮᖌ㸦ᖖ໅㸧
3K'㸦⌮Ꮫ
<XUWVHYHU$
≉௵ㅮᖌ㸦ᖖ໅㸧
༤ኈ㸦⌮Ꮫ㸧
ᒣ㷂 リ㑻
෸ᩍᤵ
༤ኈ㸦⸆Ꮫ㸧
㕥ᮌ ೺அ
ຓᩍ
༤ኈ㸦ᕤᏛ㸧
࿘ ኱ᥭ
ຓᩍ
ಟኈ㸦⌮Ꮫ㸧
ᮅ㔝 ⰾ⧊
෸ᩍᤵ
ᕤᏛ༤ኈ
㄃⏣ ⩏ⱥ
ຓᩍ
ᕤᏛಟኈ
⸨஌ ᖾᏊ
ࢼࣀᵓ㐀࣭ᶵ⬟ホ౯◊✲ศ㔝 ᩍᤵ
ࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮
‫ڦ‬㝃ᒓ⥲ྜゎᯒࢭࣥࢱ࣮
‫ڦ‬㔞Ꮚ㺩㺼㺎㺯⛉Ꮫ◊✲᪋タ
―6―
࣭ᩍဨࡢᖺ㱋ᵓᡂ㸦ᖹᡂ ᖺ ᭶ ᪥⌧ᅾࠋ≉௵ᩍဨ㸦ᖖ໅㸧ࢆྵࡴࠋࡓࡔࡋࠊే௵ࠊව௵⪅ࡣ㝖ࡃࠋ㸧
ᩍ ᤵ
෸ᩍᤵ
ຓ ᩍ
࣭ᩍဨࡢฟ㌟኱Ꮫ㸦ᖹᡂ ᖺ ᭶ ᪥⌧ᅾࠋ≉௵ᩍဨ㸦ᖖ໅㸧ࢆྵࡴࠋࡓࡔࡋࠊే௵ࠊව௵⪅ࡣ㝖ࡃࠋ㸧
ᩍ ᤵ
෸ᩍᤵ
ຓ ᩍ
⫋ဨ඲య࡛ࡣࠊᖹᡂ ᖺ ᭶ ᪥⌧ᅾ࡛ᩍဨ ྡࠊ஦ົ⫋ဨ ྡࠊᢏ⾡⫋ဨ ྡཬࡧ㠀ᖖ໅⫋ဨ
ྡࢆྵࡳࠊྜィ ྡ࡛࠶ࡿࠋ඲⫋ဨࡢ࠺ࡕእᅜேࡣ ྡࠊዪᛶࡣ ྡ࡛࠶ࡿࠋ
࣭ᖹᡂ ᖺ ᭶ ᪥࠿ࡽᖹᡂ ᖺ ᭶ ᪥ࡲ࡛ࡢே஦␗ື㸦ᖖ໅㸧ࡣḟࡢ࡜࠾ࡾ࡛࠶ࡿࠋ
␗ື᪥
␗ື஦㡯
Ặྡ➼
᥇⏝
ᩍᤵ㔞Ꮚࢩࢫࢸ࣒๰ᡂ
኱ᒾ 㢧
᥇⏝
ᩍᤵඛ㐍㟁Ꮚࢹࣂ࢖ࢫ
㛵㇂ Ẏ
᥇⏝
ᩍᤵ▱㆑⛉Ꮫ
㥖㇂ ࿴⠊
᥇⏝
ᩍᤵඛ➃ࣁ࣮ࢻᮦᩱ
㛵㔝 ᚭ
᥇⏝
ຓᩍ㸦▱⬟᥎ㄽ㸧
ᮡᒣ 㯢ே
᥇⏝
ຓᩍ⏕యศᏊᶵ⬟⛉Ꮫ
୰㔝 㞞⿱
᥇⏝
ຓᩍ㸦ࢼࣀᵓ㐀࣭ᶵ⬟ホ౯㸧
㯞⏕ ுኴ㑻
᥇⏝
≉௵ᢏ⾡⫋ဨ༙ᑟయᮦᩱ࣭ࣉࣟࢭࢫ
㯮㷂 ༓㤶
᪼௵
◊✲㐃ᦠㄢ㛗
ྜྷᓮ ⣧Ꮚ
᪼௵
୺௵㸦◊✲༠ຊಀ㸧
⚄⏣ ᖾ௦
㓄⨨᥮ ◊✲㐃ᦠㄢ㛗
すἙ ༤⨾
㓄⨨᥮ ⥲ົಀ㛗
ᒣཱྀ ⃈❶
㓄⨨᥮ ⥲ົಀ㛗
㯮ᮺ ⿱
᥇⏝
≉௵෸ᩍᤵᖖ໅⏕యศᏊᶵ⬟⛉Ꮫ
࿴ἑ 㕲୍
᥇⏝
≉௵ຓᩍᖖ໅⏕యศᏊᶵ⬟⛉Ꮫ
ᒾ㔝 ᝴
᥇⏝
≉௵◊✲ဨᖖ໅㔞Ꮚࢩࢫࢸ࣒๰ᡂ
ᮌᒣ ἞ᶞ
―7―
᥇⏝
ᡤᒓ᥮
᥇⏝
᪼௵
᪼௵
㏥⫋
᥇⏝
㓄⨨᥮
᥇⏝
㏥⫋
㏥⫋
㏥⫋
㏥⫋
᥇⏝
᥇⏝
᥇⏝
㓄⨨᥮
㓄⨨᥮
㏥⫋
㏥⫋
㏥⫋
㏥⫋
᥇⏝
᥇⏝
㏥⫋
᥇⏝
᥇⏝
᥇⏝
᥇⏝
᪼௵
᥇⏝
᥇⏝
㏥⫋
㓄⨨᥮
᥇⏝
ᐃᖺ㏥⫋
ᐃᖺ㏥⫋
ᐃᖺ㏥⫋
ᐃᖺ㏥⫋
ᐃᖺ㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
≉௵◊✲ဨᖖ໅㸦」ྜ▱⬟࣓ࢹ࢕࢔㸧
≉௵ຓᩍᖖ໅㸦ࣂ࢖࢜ࢼࣀࢸࢡࣀࣟࢪ࣮㸧
ຓᩍບ㉳ศᏊ໬Ꮫ
෸ᩍᤵ」ྜ▱⬟࣓ࢹ࢕࢔
෸ᩍᤵ༙ᑟయᮦᩱ࣭ࣉࣟࢭࢫ
≉௵஦ົ⫋ဨ◊✲㐃ᦠㄢ◊✲༠ຊಀ
≉௵◊✲ဨᖖ໅」ྜ▱⬟࣓ࢹ࢕࢔
◊✲༠ຊಀ୺௵
≉௵◊✲ဨᖖ໅⢭ᐦไᚚ໬Ꮫ
≉௵ຓᩍᖖ໅ບ㉳ศᏊ໬Ꮫ
≉௵◊✲ဨᖖ໅㸦ࣂ࢖࢜ࢼࣀࢸࢡࣀࣟࢪ࣮㸧
෸ᩍᤵ༙ᑟయ㔞Ꮚ⛉Ꮫ
≉௵ᩍᤵᖖ໅ࣂ࢖࢜ࢼࣀࢸࢡࣀࣟࢪ࣮
ຓᩍඛ㐍㟁Ꮚࢹࣂ࢖ࢫ
ຓᩍ▱㆑⛉Ꮫ
≉௵஦ົ⫋ဨ௻⏬ᐊ
㈈ົಀ୺௵
㈈ົಀ୺௵
≉௵෸ᩍᤵᖖ໅༙ᑟయ㔞Ꮚ⛉Ꮫ
≉௵ຓᩍᖖ໅㸦」ྜ▱⬟࣓ࢹ࢕࢔㸧
෸ᩍᤵ➨㸰ࣉࣟࢪ࢙ࢡࢺᴟᚤᮦᩱࣉࣟࢭࢫ
≉௵◊✲ဨᖖ໅ᶵ⬟≀㉁໬Ꮫ
ຓᩍ༙ᑟయ㔞Ꮚ⛉Ꮫ
≉௵◊✲ဨᖖ໅ᶵ⬟≀㉁໬Ꮫ
≉௵◊✲ဨᖖ໅」ྜ▱⬟࣓ࢹ࢕࢔
≉௵◊✲ဨᖖ໅ࣂ࢖࢜ࢼࣀࢸࢡࣀࣟࢪ࣮
≉௵෸ᩍᤵᖖ໅ඛ㐍㟁Ꮚࢹࣂ࢖ࢫ
≉௵◊✲ဨᖖ໅ඛ➃ᐇ⿦ᮦᩱ
≉௵◊✲ဨᖖ໅ඛ➃ᐇ⿦ᮦᩱ
ᩍᤵ⏕యศᏊไᚚ⛉Ꮫ
ຓᩍ」ྜ▱⬟࣓ࢹ࢕࢔
ຓᩍඛ➃ࣁ࣮ࢻᮦᩱ
ຓᩍບ㉳≀ᛶ⛉Ꮫ
≉௵◊✲ဨᖖ໅ᐈဨᩍᤵ⏕యศᏊไᚚ⛉Ꮫ
ຓᩍඛ㐍㟁Ꮚࢹࣂ࢖ࢫ
ᩍᤵບ㉳≀ᛶ⛉Ꮫ
ຓᩍ㔞Ꮚࢩࢫࢸ࣒๰ᡂ
ຓᩍ་⸆ရ໬Ꮫ
஦ົ㒊㛗
ィ ⌜㛗ᢏ⾡ᐊ
෸ᩍᤵ▱㆑⛉Ꮫ㸧
෸ᩍᤵ㸦㔞Ꮚᶵ⬟ᮦᩱ㸧
෸ᩍᤵ㔞Ꮚࣅ࣮࣒Ⓨ⏕⛉Ꮫ
ຓᩍ▱⬟࢔࣮࢟ࢸࢡࢳࣕ
ຓᩍ㸦㔞Ꮚᶵ⬟ᮦᩱ㸧
ຓᩍ㸦⢭ᐦไᚚ໬Ꮫ㸧
ຓᩍ㸦ࢼࣀᶵ⬟ᮦᩱࢹࣂ࢖ࢫ㸧
≉௵஦ົ⫋ဨບ㉳≀ᛶ⛉Ꮫ
≉௵෸ᩍᤵᖖ໅⏕యศᏊไᚚ⛉Ꮫ
―8―
⏣ᕝ ⪷୍
኱ᇛ ᩗே
ᑠ㜰⏣ ὈᏊ
ᵐཎ 㟹
ᯇᮏ ೺ಇ
㇂⃝ ⨾ዉ
ᮤ 㻵/,:HL
⚄⏣ ᖾ௦
ᒣ⏣ ๛ྐ
ᓲ ṇḒ&+2,-XQJNZHRQ
+(<XKXL
๓ᶫ ව୕
ᕝྜ ▱஧
Ⲩᮌ ᚭᖹ
Ṋ⏣ 㱟
す⏣ ᙬ
⏣௰ ⿱୍
භὠ஭ ὈᏊ
኱㔝 ᜤ⚽
0$1685$O
ᰗ⏣ ๛
'$63UL\DEUDWD
ᑠ㔝 ᑲ⏕
02+$17$6XPDQ&KDQGUD
08+$00$'5DV\LG$TPDU
Ụᓮ ⿱Ꮚ
᳜ᮧ 㝯ᩥ
ῦ㇂ ⣖ኵ
ᮌᮏ ᖾ἞
す㔝 㑥ᙪ
኱಴ ྐ⏕
ᚋ⸨ ▱௦
ᡂ℩ ᘏᗣ
ᯇᮏ ెᕭ
ྜྷᮏ ⚽㍜
㇂ᮧ ඞᕫ
Ụᮧ ಟ୍
᪂⏣ Ꮧ
୕⏣ ᩄኵ
ᯇᕝ ༤᫛
౗ᮧ ᚨಙ
℩ᕝ ⪔ྖ
ຍ⸨ 㱟ዲ㸦
᳃ᒣ ⏥୍
బࠎᮌ ⪽
Ṋ஭ ྐᜨ
⸨ཎ ᏹᖹ
ΎỈ ᐇబᏊ
<$1$L[LQ
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
㏥⫋
≉௵ㅮᖌᖖ໅」ྜ▱⬟࣓ࢹ࢕࢔
≉௵ㅮᖌᖖ໅ࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮
≉௵ㅮᖌᖖ໅ࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮
≉௵ຓᩍᖖ໅➨ ࣉࣟࢪ࢙ࢡࢺᴟᚤᮦᩱࣉࣟ
ࢭࢫ
≉௵ຓᩍᖖ໅㸦ࣂ࢖࢜ࢼࣀࢸࢡࣀࣟࢪ࣮㸧
≉௵ຓᩍᖖ໅㸦ࢼࣀࢸࢡࣀࣟࢪ࣮タഛ౪⏝ᣐⅬ㸧
≉௵◊✲ဨᖖ໅㔞Ꮚࢩࢫࢸ࣒๰ᡂ
≉௵◊✲ဨᖖ໅」ྜ▱⬟࣓ࢹ࢕࢔
≉௵◊✲ဨᖖ໅ඛ➃ᐇ⿦ᮦᩱ㸧
≉௵◊✲ဨᖖ໅ඛ➃ᐇ⿦ᮦᩱ㸧
≉௵◊✲ဨᖖ໅ඛ➃ᐇ⿦ᮦᩱ㸧
≉௵◊✲ဨᖖ໅ᶵ⬟≀㉁໬Ꮫ㸧
≉௵◊✲ဨᖖ໅㸦⏕యศᏊᶵ⬟⛉Ꮫ㸧
ᮧᯇ ኱࿃
<8576(9(5$\KDQ
ᒣ㷂 リ㑻
㛗ᓥ ୍ᶞ
኱ᇛ ᩗே
ἲ⃝ බᐶ
ᮌᒣ ἞ᶞ
+D]HP0RKDPHG*DEU(/$/)<
6,1*+0DQMHHW
ᓲ ఍᪲&8,+XLZDQJ
ᮔ ⪷※3$5.6XQJZRQ
02+$17$6XPDQ&KDQGUD
3(5(=.ROGHQNRYD9DGLP
㸰㸧㐠Ⴀ
⏘ᴗ⛉Ꮫ◊✲ᡤ඲⯡ࡢ⟶⌮㐠Ⴀࡣᡤ㛗ࡀ⾜ࡗ࡚࠸ࡿࠋᡤ㛗ࡣࠊᙜ◊✲ᡤࡢᑓ௵ᩍᤵ࡛❧ೃ⿵ࡋࡓ⪅
ࡢ୰࠿ࡽ㑅ᣲ࡟ࡼࡗ࡚㑅⪃ࡉࢀࡿࠋ㑅ᣲࡣ➨୍ḟ㑅ᣲ࡜➨஧ḟ㑅ᣲ࠿ࡽ࡞ࡾࠊᙜ◊✲ᡤࡢᑓ௵ᩍဨࠊ
஦ົ⫋ဨࠊᢏ⾡⫋ဨࠊᅗ᭩⫋ဨ࡟ࡼࡿ➨୍ḟ㑅ᣲ࡟࠾࠸࡚㸱ྡࡢೃ⿵⪅ࡀ㑅ࡤࢀࠊࡑࡢ୰࠿ࡽࠊᑓ௵
ᩍᤵࠊ஦ົ㒊㛗ཬࡧᢏ⾡ᐊ㛗࡟ࡼࡿ➨஧ḟ㑅ᣲ࡟࠾࠸࡚㸯ྡࡢೃ⿵⪅ࡀ㑅ࡤࢀࡿࠋ᭱⤊ⓗ࡟ࡣࠊᩍᤵ
఍࡟ࡼࡗ࡚ᡤ㛗ೃ⿵⪅ࡀỴᐃࡉࢀࡿࠋᡤ㛗ࡢ௵ᮇࡣ㸰ᖺ࡛ࠊ෌௵ࡣྍ⬟࡛࠶ࡿࡀࠊᘬࡁ⥆ࡁ㸲ᖺࢆ㉸
࠼ࡿࡇ࡜ࡣ࡛ࡁ࡞࠸ࠋ
⏘ᴗ⛉Ꮫ◊✲ᡤࡢᩍဨே஦ࠊண⟬➼ࡢ㔜せ஦㡯ࡣࠊᡤ㛗ཬࡧᑓ௵ᩍᤵ࡛⤌⧊ࡉࢀࡿᩍᤵ఍࡟࠾࠸࡚
ᑂ㆟ࡉࢀࡿࠋᩍᤵ఍ࡢ㆟㛗࡟ࡣᡤ㛗ࡀ࡞ࡾࠊ㏻ᖖẖ᭶㸯ᅇணࡵỴࡵࡽࢀࡓ᪥᫬࡟㛤ദࡉࢀࡿࠋᩍᤵḞ
ဨศ㔝ࡲࡓࡣᩍᤵḞᖍࡢศ㔝࡛ࡣࠊணࡵᢎㄆࡉࢀ࡚࠸ࡿᩍဨࡀ௦⌮ฟᖍࡍࡿࡇ࡜ࡀ࡛ࡁࡿࠋ ࡓࡔࡋࠊᑂ㆟࡟ຍࢃࡿࡇ࡜ࡣ࡛ࡁ࡞࠸ࠋ
ྛ㝃ᒓ◊✲᪋タ࡟ࡣࠊ෇⁥࡞㐠Ⴀࢆᅗࡿࡓࡵ࡟㐠Ⴀጤဨ఍ࢆタ⨨ࡋ࡚࠸ࡿࠋ
➨㸯◊✲㒊㛛㸦᝟ሗ࣭㔞Ꮚ⛉Ꮫ⣔㸧
➨ ◊✲㒊㛛㸦ᮦᩱ࣭ࣅ࣮࣒⛉Ꮫ⣔㸧
➨ ◊✲㒊㛛㸦⏕య࣭ศᏊ⛉Ꮫ⣔㸧
㝃ᒓ⏘ᴗ⛉Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮
㝃ᒓ⥲ྜゎᯒࢭࣥࢱ࣮
㝃ᒓ㔞Ꮚࣅ࣮࣒⛉Ꮫ◊✲᪋タ
㝃ᒓ⏘ᴗ⛉Ꮫ㐃ᦠᩍ⫱᥎㐍ࢭࣥࢱ࣮
㝃ᒓᅜ㝿ඹྠ◊✲ࢭࣥࢱ࣮
ࡑࡢ௚ࠊᡤෆ࡟ࡣࠊつ⛬ࡲࡓࡣ⏦ࡋྜࢃࡏ࡟ᚑࡗ࡚✀ࠎࡢጤဨ఍ࢆタ⨨ࡋάືࡋ࡚࠸ࡿࠋࡑࡢ୰࡛
୺࡞ࡶࡢࡣࠊ௨ୗࡢ࡜࠾ࡾ࡛࠶ࡿࠋ
㸦 㸧ෆࡣࠊጤဨ఍ࡢᵓᡂࢆ♧ࡍࠋ
ᙺဨ఍㸦ᡤ㛗ࠊ๪ᡤ㛗㸦㝃ᒓ⏘ᴗ⛉Ꮫ㺣㺧㺡㺖㺧㺹㺚㺼㺎㺜㺻㺞㺎㛗ࢆྵࡴ㸧ࠊ஦ົ㒊㛗ࠊᡤ㛗⿵బ㸧
㐠Ⴀ༠㆟఍㸦ᡤ㛗ࠊ๪ᡤ㛗㸦㝃ᒓ⏘ᴗ⛉Ꮫ㺣㺧㺡㺖㺧㺹㺚㺼㺎㺜㺻㺞㺎㛗ࢆྵࡴ㸧ࠊᏛእࡢᏛ㆑⤒㦂⪅࡞࡝㸧
ホ౯ጤဨ఍㸦ᡤ㛗ࠊ⥲ົ࣭ປົᢸᙜࡢᙺဨ఍ᵓᡂဨࠊ㝃ᒓ⏘ᴗ⛉Ꮫ㺣㺧㺡㺖㺧㺹㺚㺼㺎㺜㺻㺞㺎㛗ࠊྛ◊✲㒊
㛛࣭ࢼࣀࢸࢡࢭࣥࢱ࣮ࡢᑓ௵ᩍᤵࠊ஦ົ㒊㛗㸧
―9―
◊✲௻⏬ጤဨ఍㸦ᡤ㛗ࠊ◊✲᥎㐍ᢸᙜࡢᙺဨ఍ᵓᡂဨࠊྛ◊✲㒊㛛࣭ࢼࣀࢸࢡࢭࣥࢱ࣮ࡢᑓ௵ᩍ
ᤵࠊ஦ົ㒊㛗௚㸧
ᅜ㝿஺ὶ᥎㐍ጤဨ఍㸦ᡤ㛗ࠊ๪ᡤ㛗㸦㝃ᒓ⏘ᴗ⛉Ꮫ㺣㺧㺡㺖㺧㺹㺚㺼㺎㺜㺻㺞㺎㛗ࢆྵࡴ㸧ࠊ஦ົ㒊㛗௚㸧
㈈ົጤဨ఍㸦ᡤ㛗ࠊ㈈ົ࣭᪋タᢸᙜࡢᙺဨ఍ᵓᡂဨࠊ㝃ᒓ◊✲᪋タ㛗ࠊඹ㏻᪋タ㐠Ⴀጤဨ఍ጤဨ
㛗ࠊྛ◊✲㒊㛛࣭ࢼࣀࢸࢡࢭࣥࢱ࣮ࡢᑓ௵ᩍᤵࠊ஦ົ㒊㛗௚㸧
᪋タጤဨ఍㸦ᡤ㛗ࠊ㈈ົ࣭᪋タᢸᙜࡢᙺဨ఍ᵓᡂဨࠊᏛෆ᪋タ࣐ࢿࢪ࣓ࣥࢺጤဨ఍ጤဨࠊ㝃ᒓ◊
✲᪋タ㛗ࠊඹ㏻᪋タ㐠Ⴀጤဨ఍ጤဨ㛗ࠊྛ◊✲㒊㛛࣭ࢼࣀࢸࢡࢭࣥࢱ࣮ࡢᑓ௵ᩍᤵࠊ
஦ົ㒊㛗௚㸧
ᗈሗᐊ఍㆟㸦ᩍ⫱㐃ᦠ࣭ᗈሗᢸᙜࡢᙺဨ఍ᵓᡂဨࠊྛ◊✲㒊㛛࣭ࢼࣀࢸࢡࢭࣥࢱ࣮ࡢᑓ௵ᩍᤵ௚㸧
ࡲࡓࠊᙜ◊✲ᡤ࡛ࡣᏛෆࡢ௚㒊ᒁࡢᩍᤵ࡜ඹྠ◊✲ࢆ⾜࠺ࡓࡵ࡟ව௵ᩍᤵไᗘࢆ᥇⏝ࡋ࡚࠸ࡿࠋᖹᡂ
ᖺᗘࡣᏛෆ࠿ࡽ ྡࡢᩍဨ㸦すᔱⱱᏹᩍᤵ㸦ᕤᏛ◊✲⛉㸧ࠊᕷᕝ⪽≉௵෸ᩍᤵᖖ໅㸦ࢼࣀࢧ࢖࢚ࣥ
ࢫࢹࢨ࢖ࣥᩍ⫱◊✲ࢭࣥࢱ࣮㸧
ࠊྜྷ⏣༤ᩍᤵ㸦ᇶ♏ᕤᏛ◊✲⛉㸧ࠊኩ⏣༤୍ᩍᤵ㸦ᇶ♏ᕤᏛ◊✲⛉㸧㸧ࢆ
ව௵ᩍᤵ࡟௵⏝ࡋࡓࠋ
㸱㸧◊✲㈝
ᙜ◊✲ᡤࡢ୺࡞⤒㈝ࡣࠊ㐠Ⴀ㈝஺௜㔠ࠊ⛉Ꮫ◊✲㈝⿵ຓ㔠➼ࡢእ㒊㈨㔠࡛࠶ࡿࠋࡇࢀࡽ◊✲㈝ࡢᖹ
ᡂ ᖺᗘ࠿ࡽ ᖺ㛫ࡢ᥎⛣ࡣ௨ୗࡢ࡜࠾ࡾ࡛࠶ࡿࠋ
ே௳㈝
≀௳㈝
⛉Ꮫ◊✲㈝⿵ຓ㔠
ࡑࡢ௚⿵ຓ㔠
ዡᏛᐤ㝃㔠
ཷク◊✲
Ẹ㛫➼࡜ࡢඹྠ◊✲
ཷク஦ᴗ➼
ᖺᗘ
ᖺᗘ
ᖺᗘ
༢఩㸸ⓒ୓෇
࣭ண⟬㸦ᖹᡂ 㹼 ᖺᗘ㸧 㸦༢఩㸸༓෇㸧
㸰㸲ᖺᗘ
㸰㸴ᖺᗘ
⛉Ꮫ◊✲㈝⿵ຓ㔠㸦௳ᩘ㸧
ࡑࡢ௚⿵ຓ㔠➼㸦௳ᩘ㸧
ዡᏛᐤ㝃㔠㸦௳ᩘ㸧
ཷク◊✲ 㸦௳ᩘ㸧
Ẹ㛫➼࡜ࡢඹྠ◊✲㸦௳ᩘ㸧
㐠Ⴀ㈝஺௜㔠
ே௳㈝
㸰㸳ᖺᗘ
≀௳㈝
ཷク஦ᴗ➼㸦௳ᩘ㸧
ྜ ィ
㸦ὀ㸧ඹ㏻⤒㈝ࡣ㝖ࡃ
― 10 ―
࣭እ㒊㈨㔠
ዡᏛᐤ㝃㔠ࠊඹྠ◊✲ࠊཷク◊✲࡟ࡘ࠸࡚ࡣ⏦ࡋ㎸ࡲࢀࡓෆᐜ࡟ࡘ࠸࡚ࠊᡤෆࡢᙺဨ఍㸦⏘Ꮫᐁ
㐃ᦠၥ㢟ጤဨ఍㸧࡟࠾࠸࡚ᑂᰝࡋࡓ࠺࠼࡛ཷࡅධࢀࡀỴᐃࡉࢀࡿࠋᖹᡂ ᖺᗘ࡟ཷࡅධࢀࡽࢀࡓ
ዡᏛᐤ㝃㔠ࡣḟࡢ࡜࠾ࡾ࡛࠶ࡿࠋ
༢఩㸸༓෇
ᖹᡂ ᖺᗘ ➨ ◊✲㒊㛛
➨ ➨ 㺣㺧㺡㺖㺧㺹㺚㺼㺎
≉ู㺪㺽㺹㺚㺼㺈
◊✲㒊㛛
◊✲㒊㛛
㺜㺻㺞㺎
㺖㺢◊✲㒊㛛
ࡑࡢ௚
ྜィ
㸦㸧
㸦㸧
㸦㸧
㸦㸧
㸦㸧
㸦㸧
㸦㸧
㸦 㸧ෆࡣ௳ᩘ
㸲㸧ᅜ㝿◊✲ࣉࣟࢪ࢙ࢡࢺ
ᙜ◊✲ᡤࡀᖹᡂ ᖺᗘ࡟ᐇ᪋ࡋࡓᅜ㝿ඹྠ◊✲ࡣḟࡢ࡜࠾ࡾ࡛࠶ࡿࠋ
◊✲ศ㔝
┦ᡭᶵ㛵
ᅜ ྡ
ෆ ᐜ
Indian Institute of Chemical
࢖ࣥࢻ ᭷ᶵ㟁Ꮚ࢔ࢡࢭࣉࢱ࣮ࡢ⏕໬Ꮫᛂ⏝
ࢯࣇࢺࢼࣀ࣐ࢸ Biology
㧗ᛶ⬟ Q ᆺ᭷ᶵ㟁⏺ຠᯝࢺࣛࣥࢪࢫࢱࡢ
ࣜ࢔ࣝ
imec
࣋ࣝࢠ࣮
㛤Ⓨ◊✲
㔞Ꮚᶵ⬟ᮦᩱ ࣁࢵࢭࣝࢺ኱Ꮫ
࣋ࣝࢠ࣮ Q ᆺ᭷ᶵ༙ᑟయᮦᩱࡢ㛤Ⓨ◊✲
㔞Ꮚࣅ࣮࣒ 㡑ᅜཎᏊຊ◊✲ᡤ ඛ➃ᨺᑕ⥺
㡑ᅜ
㔞Ꮚࣅ࣮࣒⛉Ꮫ◊✲
Ⓨ⏕⛉Ꮫ ᢏ⾡◊✲ᡤ
㉸㧗ឤᗘᣦ♧⸆࡟ࡼࡿ⣽⬊ᛶ⢓⳦Ⓨ⏕㐣
Indian Institute of Technology
࢖ࣥࢻ
Madras
⛬ࡢ᫬✵㛫࢝ࣝࢩ࣒࢘࢖࢜ࣥほᐹ
Weatherall Institute of Molecular
࢖ࢠࣜࢫ ㉸ゎീ㢧ᚤ㙾ࡢỗ⏝ᛶ
Medicine, University of Oxford
⣽⬊ෆ⏕⌮ᶵ⬟ࢆࣉ࣮ࣟࣈࡍࡿࡓࡵࡢศ
Department of Chemistry,
࢔࣓ࣜ࢝
Ꮚࢶ࣮ࣝ
⏕యศᏊᶵ⬟ University of Alberta
⛉Ꮫ
ḟඖ့ங㢮⣽⬊ཬࡧ᳜≀࡟࠾ࡅࡿ ศᏊ
Technische Universität Darmstadt
ࢻ࢖ࢶ
࢖࣓࣮ࢪࣥࢢ
᱁Ꮚ≧ගࢩ࣮ࢺ㢧ᚤ㙾࡛࡜ࡽ࠼ࡿ⏕࿨ື
Academia Sinica
ྎ‴
ែ
EMBL(European Molecular
ࢻ࢖ࢶ ⣽⬊ᶵ⬟ࢆ᧯సࡍࡿศᏊࢶ࣮ࣝ
Biology Laboratory)
࢔࢖ࣥࢺ࣮࣍ࣇ࢙ࣥᕤ⛉኱Ꮫ
་⸆ရ໬Ꮫ
⥲ྜゎᯒ
ࢭࣥࢱ࣮
ඛ㐍㟁Ꮚ
ࢹࣂ࢖ࢫ
࢜ࣛࣥࢲ ࡓࢇࡥࡃ㉁ࡢᶵ⬟ไᚚ
៞⇊኱Ꮫᰯ
㡑ᅜ
៏ᛶ㦵㧊ⓑ⾑⑓࡟ᑐࡍࡿ࢝ࢸ࢟ࣥㄏᑟయ
ࢆ௓ࡋࡓຠ⋡ⓗ࡞⣽⬊ࣉࣟࢢ࣒ࣛṚㄏᑟ
࣮࢝ࢿࢠ࣮◊✲ᡤ
࢔࣓ࣜ࢝ 6U7L2 ࡢ㟁Ꮚᐦᗘゎᯒ
࢖ࣥ࣌ࣜ࢔ࣝ࢝ࣞࢵࢪࣟࣥࢻࣥ
࢖ࢠࣜࢫ ⷧ⭷ࡢ㓟໬≀ 7)7 ࡢస〇࡜㞟✚໬
Sunmoon ኱Ꮫ
ඛ➃ࣁ࣮ࢻᮦᩱ
Hanyang University
ࢼࣀᴟ㝈ࣇ࢓ࣈ ࣂ࣮ࣂཎᏊຊ◊✲ࢭࣥࢱ࣮
ࣜࢣ̿ࢩࣙࣥ
ࢳ࢙ࢥ⛉Ꮫ࢔࢝ࢹ࣑࣮
㡑ᅜ
㡑ᅜ
࢖ࣥࢻ
ࢳ࢙ࢥ
― 11 ―
࢚ࢥࣇࣞࣥࢻ࣮ࣜ࡞ᛂ⏝ࡢࡓࡵࡢከᶵ⬟
ᛶࢼࣀᮦᩱ࠾ࡼࡧࣉࣟࢭࢫᢏ⾡㛤Ⓨ
ࢼࣀ໬ᏛᕤᏛ࡟ᇶ࡙ࡃ᪂つ࡞ᶵ⬟ᛶᮦᩱ
࡟㛵ࡍࡿᏛ⾡஺ὶ
㉸㧗㏿ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫࢆ⏝࠸ࡓᨺᑕ
⥺໬Ꮫึᮇ㐣⛬ࡢ◊✲
; ⥺ࣅ࣮࣒ࣛ࢖ࣥ⏝⥺㔞ィࡢ㛤Ⓨ
ࢼࣀᴟ㝈ࣇ࢓ࣈ
ࣀ࣮ࢺࣝࢲ࣒኱Ꮫ
ࣜࢣ̿ࢩࣙࣥ
⏕యศᏊ཯ᛂ
ࣃࣛࢶ࣮࢟኱Ꮫ
⛉Ꮫ
ᛂ⏝࢜ࣥࢺࣟࢪ࣮◊✲ᡤ
▱㆑⛉Ꮫ ࢹࣝࣇࢺᕤ⛉኱Ꮫ
ࣝࣈࣜࣥ࢝ࢯࣜࢵࢡ኱Ꮫ
ࢩ࣮ࣕࣈࣝࢵࢡ኱Ꮫ
ࣃࣜ༡኱Ꮫ
ࣀ࣮ࢺࣝࢲ࣒኱Ꮫ
㔞Ꮚࣅ࣮࣒≀㉁
⛉Ꮫ
ࣃࣜ༡኱Ꮫ
ࣂ࣮࣑࣒ࣥ࢞኱Ꮫ
ࢡ࢖࣮ࣥࢬࣛࣥࢻ኱Ꮫ
ᶵ⬟≀㉁໬Ꮫ
ࣅ࣮ࣞࣇ࢙ࣝࢺ኱Ꮫ
ࣃࣜ༡኱Ꮫ
ࢼࣀᶵ⬟ண 㡑ᅜ❔ᴗᢏ⾡◊✲ᡤ
༙ᑟయᮦᩱ࣭
ࣉࣟࢭࢫ
ෆⵚྂᕷ㈍኱Ꮫ
ࢫࣟࣂ࢟࢔⛉Ꮫ࢔࢝ࢹ࣑࣮
༙ᑟయ㔞Ꮚ⛉Ꮫࣃࢹ࣮ࣗ኱Ꮫ
ᅜ❧ྎ‴኱Ꮫ
ບ㉳ศᏊ໬Ꮫ
3267(&+
࣍ࣝࢫࢺࢭࣥࢱ࣮
ඛ➃ᐇ⿦ᮦᩱ
࢔࢖࣓ࢵࢡ ࢤࣥࢺ኱Ꮫ
㤶 ኱Ꮫ
ࣇࣛࣥࢫᅜ❧㎰Ꮫ◊✲ᡤ
⏕యศᏊไᚚ
ࢤࣥࢺ኱Ꮫ
⛉Ꮫ
ࣁࣀ࣮ࣇ࢓࣮⋇་⛉኱Ꮫ
࣐ࣝࢸ࢕࣭ࣥࣝࢱ࣮኱Ꮫ
ࣁ࣭ࣦࣞ࢕ࢵࢸࣥ࣋ࣝࢡ
Uppsala University
ࣂ࢖࢜ࢼࣀࢸࢡ
Rutgers University
ࣀࣟࢪ࣮
University College London
▱ⓗ㈈⏘
୰ᅜす໭㎰ᯘ⛉ᢏ኱ᏛᯘᏛ㝔
࢔࣓ࣜ࢝ Ỉࡢᨺᑕ⥺໬Ꮫ
ࢳ࢙ࢥ
ࣛࢪ࢝ࣝ 6$0 㓝⣲཯ᛂᶵᵓࡢゎ᫂
࢖ࢱࣜ࢔ ேᕤ≀ࡢᐃ⩏㸪ᶵ⬟ࡢ⤫୍ⓗⓗᐃ⩏
࢜ࣛࣥࢲ ேᕤ≀ࡢᐃ⩏㸪ᶵ⬟ࡢ⤫୍ⓗⓗᐃ⩏
࣏࣮ࣛࣥࢻ ேᕤ≀ࡢᐃ⩏㸪ᶵ⬟ࡢ⤫୍ⓗⓗᐃ⩏
ࣔࣥࢸ࢝ࣝࣟἲ࡟ࡼࡿᴟᛶ⁐፹ࡢᴟ㝈≧
࢝ࢼࢲ
ែୗ࡟࠾ࡅࡿᨺᑕ⥺ศゎ཯ᛂᶵᵓ
㉸㧗㏿㺨㺽㺷㺛㺵㺚㺼㺓㺶㺚㺛࡟ࡼࡿᴟᛶ⁐፹ࡢᴟ㝈
ࣇࣛࣥࢫ
≧ែୗ࡟࠾ࡅࡿᨺᑕ⥺ศゎ཯ᛂ◊✲
࢔࣓ࣜ࢝ Ỉ୰ࡢ㟁Ꮚ⇕໬㐣⛬ࡢ⌮ㄽⓗ◊✲
7+)ࠊ3*0($ ⁐፹୰࡛ࡢ㔠ᒓࢼࣀ⢏Ꮚࡢᨺ
ᑕ⥺ㄏ㉳ྜᡂ
ࢺࢵࣉࢲ࣭࢘ࣥ࣎ࢺ࣒࢔ࢵࣉ⼥ྜᆺᚤ⣽ຍ
࢖ࢠࣜࢫ
ᕤᢏ⾡࡟㛵ࡍࡿ◊✲
࣮࢜ࢫࢺ ࣜࢯࢢࣛࣇ࢕ᛂ⏝ࡢࡓࡵࡢ᪂つࣈࣟࢵࢡ
ࣛࣜ࢔ ඹ㔜ྜయࡢྜᡂ
⏕యゐ፹࡜໬Ꮫゐ፹ࡢ⼥ྜ࡟ࡼࡿ᪂つ஧
ࢻ࢖ࢶ
㔜άᛶ໬ᆺゐ፹⣔ࡢᵓ⠏
ࣇࣛࣥࢫ ᪂つ⎔ቃㄪ࿴ᆺ཯ᛂࡢ㛤Ⓨ
㡑ᅜ
㧗⼥Ⅼࢭ࣑ࣛࢵࢡࢫᮦᩱࡢᶵᲔⓗᛶ㉁
◪㓟㓟໬ἲࢆ⏝࠸ࡿ༙ᑟయࢹࣂ࢖ࢫࡢ㧗
୰ᅜ
ᛶ⬟໬
໬Ꮫⓗ㌿෗ἲࢆ⏝࠸ࡿ⤖ᬗࢩࣜࢥࣥኴ㝧
ࢫࣟࣂ࢟࢔
㟁ụࡢ㧗ຠ⋡໬
࢔࣓ࣜ࢝ ࢢࣛࣇ࢙ࣥࢹࣂ࢖ࢫస〇ᢏ⾡ࡢ⩦ᚓ
ྎ‴
㉸ศᏊࡢග໬Ꮫ
㡑ᅜ
ගゐ፹ࡢ཯ᛂᶵᵓ
࢜ࣛࣥࢲ ࢫࢺࣞࢵࢳࣕࣈࣝᑟ㟁ᛶ㓄⥺
࣋ࣝࢠ࣮ ࢫࢺࣞࢵࢳࣕࣈࣝ᥋ྜ
ࢺࣛࣥࢫ࣏࣮ࢱ࣮ไᚚ࡟ࡼࡿ⣽⳦ᜏᖖᛶ
୰ᅜ
⥔ᣢᶵᵓࡢゎ᫂࡜᪂つ἞⒪ᡓ␎ࡢ㛤Ⓨ
⫹Ồ࡟ࡼࡿࢧࣝࣔࢿࣛከ๣᤼ฟ࣏ࣥࣉ㑇
ࣇࣛࣥࢫ
ఏᏊⓎ⌧ㄏᑟᶵᵓ
ࢧࣝࣔࢿࣛከ๣᤼ฟ࣏ࣥࣉ࡟ࡼࡿ࢜࣎ࢺ
࣋ࣝࢠ࣮ ࣛࣥࢫࣇ࢙ࣜࣥ⏤᮶ᢠ⳦࣌ࣉࢳࢻ⪏ᛶᶵ
ᵓࡢゎ᫂
ࢧࣝࣔࢿࣛࡢከ๣᤼ฟ࣏ࣥࣉ࡟ࡼࡿࢺࣜ
ࢻ࢖ࢶ
ࢡࣟ㓟⪏ᛶᶵᵓ
⣽⳦ከ๣⪏ᛶ໬࡟㛵୚ࡍࡿከ๣᤼ฟࢩࢫ
ࢻ࢖ࢶ
ࢸ࣒ࡢᵓ㐀࠾ࡼࡧᶵ⬟ࡢゎ᫂
ࢫ࢙࣮࢘ࢹࣥ '1$ ᧯స࡟㛵ࡍࡿ⌮ㄽⓗ◊✲
࢔࣓ࣜ࢝ '1$ ᧯స࡟㛵ࡍࡿ⌮ㄽⓗ◊✲
࢖ࢠࣜࢫ ගㄏ㉳ᵓ㐀┦㌿⛣ᶵᵓࡢゎ᫂
ኳ↛࣏࣐࣮ࣜࡢ᭷ࡍࡿᮭ௰Ⲕᡂศࡢ⬺╔
୰ᅜ
≉ᛶ࡟㛵ࡍࡿ◊✲
ࣇࣛࣥࢫ
― 12 ―
ࢣࣥࢱࢵ࣮࢟኱Ꮫ
ࣘࢺࣞࣄࢺ኱Ꮫ
ࢼࣀᵓ㐀࣭ ࣮ࣟࣞࣥࢫ࣭ࣂ࣮ࢡ࣮ࣞᅜ❧◊✲
ᶵ⬟ホ౯ ᡤ
࢚ࣇ࢖࣮࢔࢖♫
ࢺࣟࣥࢺᏊ౪⑓㝔
⢭ᐦไᚚ໬Ꮫ
࣐࢝࢜⌮ᕤ኱Ꮫ
ࢫ࢖ࢫᕤ⛉኱Ꮫ
࢖ࣥࢻᕤ⛉኱Ꮫࣁ࢖ࢹࣛࣂ࣮ࢻ
ࢼࣀᶵ⬟ᮦᩱ
ᰯ
ࢹࣂ࢖ࢫ
᲍ⰼዪᏊ኱Ꮫ
࢔࣓ࣜ࢝ ゐ፹཯ᛂୗ࡟࠾ࡅࡿࢼࣀᮦᩱࡢ (7(0 ほᐹ
࢜ࣛࣥࢲ 㔠ࢼࣀࣟࢵࢻࡢẼయ୰࡟࠾ࡅࡿᙧ≧ኚ໬
㔠ᒓ㓟໬≀࡟ᢸᣢࡉࢀࡓ㔠ࢼࣀ⢏Ꮚࡢ㧗
࢔࣓ࣜ࢝
ศゎ⬟ 7(0 ほᐹ
㧗ศゎ⬟⎔ቃไᚚᆺ㏱㐣㟁Ꮚ㢧ᚤ㙾ࡢ㛤
࢔࣓ࣜ࢝
Ⓨ
పศᏊ᭷ᶵ໬ྜ≀࡟ࡼࡿࢺࣜࢾࢡࣞ࢜ࢳ
࢝ࢼࢲ
ࢻࣜࣆ࣮ࢺఙ㛗ᢚไ
㉁㔞ศᯒἲࢆ⏝࠸ࡓ &8*ࣜࣆ࣮ࢺ⤖ྜศ
୰ᅜ
Ꮚࡢゎᯒ
㉮ᰝᆺ⇕ὶ㢧ᚤ㙾࡟ࡼࡿ㓟໬≀ࢼࣀᵓ㐀
ࢫ࢖ࢫ
ほᐹ
࢖ࣥࢻ
ࢫࢬ㓟໬≀࢞ࢫࢭࣥࢧ࣮࡟㛵ࡍࡿ◊✲
ࢣࣝࣅࣥࣇ࢛࣮ࢫ㢧ᚤ㙾࡟ࡼࡿࢻ࣓࢖ࣥ
ほᐹ
ࢪ࢙ࣀࣂ኱Ꮫ
࢖ࢱࣜ࢔ ᶵ⬟ᛶ㓟໬≀ 0(06
㡑ᅜཎᏊຊ⛉Ꮫ◊✲ᡤ
㡑ᅜ
➨ ᅇ㔞Ꮚࣅ࣮࣒⛉Ꮫ࡟ࡘ࠸࡚
㔞Ꮚࣅ࣮࣒᪋タ
ඛ➃ᨺᑕ⥺ᢏ⾡◊✲ᡤ
㡑ᅜ
➨ ᅇ㔞Ꮚࣅ࣮࣒⛉Ꮫ࡟ࡘ࠸࡚
໭ி኱Ꮫ
୰ᅜ
ࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ
࣐࢖ࢡࣟࢯࣇࢺࣜࢧ࣮ࢳ࢔ࢪ࢔
୰ᅜ
ࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ
」ྜ▱⬟ ࢻࣞࢡࢭࣝ኱Ꮫ
࢔࣓ࣜ࢝ ࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ
࣓ࢹ࢕࢔
ࣂࣥࢢࣛ
ࣛࢪࢩࣕࣄ኱Ꮫ
ࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ
ࢹࢩࣗ
ࣆ࢝ࣝࢹ࢕ࢪ࣮ࣗࣝ࣋ࣝࢾ኱Ꮫ
ࣇࣛࣥࢫ ࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ
࣮࢜ࢫࢺ
࣮࢜ࢫࢺࣛࣜ࢔㐃㑥኱Ꮫ
ࢹ࣮ࢱ㉁㔞࡟ᇶ࡙ࡃᶵᲔᏛ⩦ᡭἲࡢ㛤Ⓨ
ࣛࣜ࢔
ࢹ࣮ࢱࣈࣟࢵࢡ࣐࢖ࢽࣥࢢᡭἲ࡜ࣟࢢゎ
࣮ࣚࢮࣇ࣭ࣇ࣮࢚ࣜ኱Ꮫ
ࣇࣛࣥࢫ
ᯒ࡬ࡢᛂ⏝
⤫ィⓗ௬ㄝ࣐࢖ࢽࣥࢢᡭἲࡢ㏲ḟ᳨ᐃ࡬
࣮ࣚࢮࣇ࣭ࣇ࣮࢚ࣜ኱Ꮫ
ࣇࣛࣥࢫ
ࡢᣑᙇ
ᶵᲔᏛ⩦࡟࠾ࡅࡿຎࣔࢪࣗࣛ᭱㐺໬࢔ࣝ
࣡ࢩࣥࢺࣥ኱Ꮫ
࢔࣓ࣜ࢝
ࢦࣜࢬ࣒ࡢ㛤Ⓨ
ᶵᲔᏛ⩦ᢏ⾡ࡢ⬻⏬ീࢆ⏝࠸ࡓࢥࣥࣆࣗ
໭ி኱Ꮫ
୰ᅜ
࣮ࢱ࣭ࣅࢪࣙࣥ࡬ࡢᛂ⏝
ᶵᲔᏛ⩦ᢏ⾡ࡢΰ㞧ࢩ࣮ࣥື⏬ゎᯒ࡬ࡢ
▱⬟᥎ㄽ ༡ὒ⌮ᕤ኱Ꮫ
ࢩ࣏࣮ࣥ࢞ࣝ
ᛂ⏝
ᶵᲔᏛ⩦ࢆ⏝࠸ࡓ㑇ఏᏊࢹ࣮ࢱゎᯒࡢࡓ
ࢳ࣮ࣗࣜࢵࣄᕤ⛉኱Ꮫ
ࢫ࢖ࢫ
ࡵࡢ᭱㐺໬࢔ࣝࢦࣜࢬ࣒ࡢ㛤Ⓨ
⤫ィⓗ᭷ពᛶࢆࡶࡘࣃࢱ࣮ࣥⓎぢᡭἲࡢ
ࢳ࣮ࣗࣜࢵࣄᕤ⛉኱Ꮫ
ࢫ࢖ࢫ
㛤Ⓨ
⤫ィⓗ᭷ពᛶࢆࡶࡘࣃࢱ࣮ࣥⓎぢᡭἲࡢ
ࢥ࣌ࣥࣁ࣮ࢤࣥ኱Ꮫ
ࢹ࣐࣮ࣥࢡ
㛤Ⓨ
ࣀ࣮ࢫ࢝ࣟࣛ࢖ࢼ኱Ꮫࢳࣕ࣌ࣝ
࢔࣓ࣜ࢝ ₯ᅾඹ㏻ཎᅉࡀ࠶ࡿሙྜࡢᅉᯝ᪉ྥ᥎ᐃ
ࣄࣝᰯ
ࣘࢽࣂ࣮ࢩࢸ࢕࣭࢝ࣞࢵࢪ࣭ࣟࣥ
᫬⣔ิࢹ࣮ࢱ࡟࠾ࡅࡿ₯ᅾඹ㏻ཎᅉࡀ࠶
࢖ࢠࣜࢫ
ࢻࣥ
ࡿሙྜࡢᅉᯝ᪉ྥ᥎ᐃ
㡑ᅜ
― 13 ―
ࢳࣗࣛࣟࣥࢥࣥ኱Ꮫ
ࢹ࣭࣭ࣛࢧ࣮ࣝ኱Ꮫ
࣏ࣝࢺ኱Ꮫ
࣮ࣝ࣋ࣥ࢝ࢺࣜࢵࢡ኱Ꮫ
▱⬟
imec
࢔࣮࢟ࢸࢡࢳࣕ
ࣂࣥ࣋ࣝࢡ኱Ꮫ
ࢸࣞࢥ࣒࣭ࣃࣜ
࣮࢜ࢡࣛࣥࢻ኱Ꮫ
࣮࢝ࢿࢠ࣮࣓ࣟࣥ኱Ꮫ
ࢱ࢖
ࣇ࢕ࣜࣆࣥ
࣏ࣝࢺ࢞ࣝ
࣋ࣝࢠ࣮
࣋ࣝࢠ࣮
ࢻ࢖ࢶ
ࣇࣛࣥࢫ
ࢽ࣮ࣗࢪ࣮
ࣛࣥࢻ
࢔࣓ࣜ࢝
ᶵᲔᏛ⩦
ඹឤィ⟬
ࢹ࣮ࢱ࣐࢖ࢽࣥࢢ
ᶵᲔᏛ⩦
⬻ࡢಙྕゎᯒ
ࢹ࣮ࢱ࣮࣋ࢫࢩࢫࢸ࣒
ᨃே໬࢚࣮ࢪ࢙ࣥࢺ
᝟ሗ᥎⸀
᝟ሗ᥎⸀
㸳㸧Ꮫ⾡ㅮ₇఍࣭◊✲㞟఍࣭◊✲ᡤ㛫஺ὶࣉࣟࢢ࣒ࣛ
ᙜ◊✲ᡤࡀᖹᡂ ᖺᗘ࡟࠾࠸࡚ᐇ᪋ࡋࡓ◊✲ᡤ㛫஺ὶ࠾ࡼࡧ୺ദࡲࡓࡣඹദ࡜ࡋ࡚ᐇ᪋ࡋࡓᏛ⾡
ㅮ₇఍࣭◊✲㞟఍ࡣḟࡢ࡜࠾ࡾ࡛࠶ࡿࠋ
㛤ദᮇ㛫
ࢸ࣮࣐ྡ➼
ᖹᡂ ᖺᗘ➨ ᅇࣉࣜࣥࢸࢵࢻ࣭࢚ࣞࢡࢺࣟࢽࢡࢫ◊✲఍
➨ ᅇ㸦ᖹᡂ ᖺᗘ➨ ᅇ㸧⏘◊ࢸࢡࣀࢧࣟࣥ
ᖹᡂ ᖺᗘ➨ ᅇ༙ᑟయ᪂つ໬Ꮫࣉࣟࢭࢫ◊✲఍
᪥㡑ከᶵ⬟ࢼࣀ࣐ࢸࣜ࢔ࣝࢭ࣑ࢼ࣮ࠕඛ➃ᮦᩱ࡜ࢹࣂ࢖ࢫࡢ࢖ࣥࢱ࣮ࢥࢿࢡࢩࣙࣥࠖ
ࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ࡟㛵ࡍࡿㅮ₇఍
ேᕤ▱⬟ᇶᮏၥ㢟◊✲఍
,6,5DQG,15$ᅜ㝿ࢪࣙ࢖ࣥࢺࢩ࣏ࣥࢪ࣒࢘
-636DQG'$$'ᅜ㝿ࢪࣙ࢖ࣥࢺࢩ࣏ࣥࢪ࣒࢘
ᖹᡂ ᖺᗘ➨ ᅇࣉࣜࣥࢸࢵࢻ࣭࢚ࣞࢡࢺࣟࢽࢡࢫ◊✲఍
➨ ᅇ㸦ᖹᡂ ᖺᗘ➨ ᅇ㸧⏘◊ࢸࢡࣀࢧࣟࣥ
᪂⏘ᴗᨭ᥼࢖ࣥࢱ࣮࣐ࢸࣜ࢔ࣝㅮ₇࣭஺ὶ఍ࠕୡ⏺ࢆᩆ࠺ᮦᩱࡢ᪂ࡋ࠸どⅬࠖ
➨ ᅇ᪥ᮏ⏕≀≀⌮ᖺ఍ࢩ࣏ࣥࢪ࣒࣭࢘ᑡᩘᛶࠊᩘᦂࡽࡂࡀ๰ฟࡍࡿᶵ⬟ࡢࢩࢼ
ࣜ࢜
ேᕤ▱⬟ᇶᮏၥ㢟◊✲఍
ᖹᡂ ᖺᗘ➨ ᅇࣉࣜࣥࢸࢵࢻ࣭࢚ࣞࢡࢺࣟࢽࢡࢫ◊✲఍
➨ ᅇ㸦ᖹᡂ ᖺᗘ➨ ᅇ㸧⏘◊ࢸࢡࣀࢧࣟࣥ
๰❧ ࿘ᖺグᛕ⏘◊ࢸࢡࣀࢧ࣭ࣟࣥࢫ࣌ࢩࣕࣝ
ᖹᡂ ᖺᗘ➨ ᅇ༙ᑟయ᪂つ໬Ꮫࣉࣟࢭࢫ◊✲఍
኱㜰኱Ꮫ⏘ᴗ⛉Ꮫ◊✲ᡤ๰❧㸵㸳࿘ᖺグᛕ➨㸵㸮ᅇᏛ⾡ㅮ₇఍
ࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ࡟㛵ࡍࡿㅮ₇఍
ࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ࡟㛵ࡍࡿㅮ₇఍
➨ ᅇ ᑡᩘᛶ⏕≀Ꮫウㄽ఍
➨ ᅇගᏛⓗࢫࣆࣥኚ᥮࣑࣮ࢸ࢕ࣥࢢ
ேᕤ▱⬟ᇶᮏၥ㢟◊✲఍
ᖹᡂ ᖺᗘ➨ ᅇࣉࣜࣥࢸࢵࢻ࣭࢚ࣞࢡࢺࣟࢽࢡࢫ◊✲఍
ࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ࡟㛵ࡍࡿㅮ₇఍
➨ ᅇ㸦ᖹᡂ ᖺᗘ➨ ᅇ㸧⏘◊ࢸࢡࣀࢧࣟࣥ
㧗ᶵ⬟ࢼࣀࢭࣥࢧᮦᩱ๰〇࡜ᶵ⬟໬◊✲఍
ᖹᡂ ᖺᗘ➨ ᅇ༙ᑟయ᪂つ໬Ꮫࣉࣟࢭࢫ◊✲఍
ேᕤ▱⬟ᇶᮏၥ㢟◊✲఍
㧗ḟඖ኱つᶍၥ㢟࡟㛵ࡍࡿ 1,, ࢭ࣑ࢼ࣮
㡑ᅜ❔ᴗᢏ⾡㝔࡜኱㜰኱Ꮫ⏘ᴗ⛉Ꮫ◊✲ᡤྜྠࢭ࣑ࢼ࣮
― 14 ―
➨㸰ᅇ୕㔜኱ᏛѸ ኱㜰኱Ꮫࢪࣙ࢖ࣥࢺ◊✲఍
➨ ᅇ⏘◊ᅜ㝿ࢩ࣏ࣥࢪ࣒࢘㸭➨ ᅇ⏘◊ࢼࣀࢸࢡࣀࣟࢪ࣮ࢩ࣏ࣥࢪ࣒࢘
ඖ⣲ᡓ␎ &5(67 ྜྠ◊✲఍
᪥ᮏࢣ࣑࢝ࣝࣂ࢖࢜ࣟࢪ࣮Ꮫ఍➨஑ᅇᖺ఍
➨ ᅇᑡᩘᛶ⏕≀Ꮫࢺ࣮ࣞࢽࣥࢢࢥ࣮ࢫ
➨ ᅇࢥࣥࣆࣗࢸ࣮ࢩࣙࢼ࣭࣐ࣝࢸࣜ࢔ࣝࢬ࣭ࢹࢨ࢖࣮ࣥ࣡ࢡࢩࣙࢵࣉ
኱㜰኱Ꮫ⏘ᴗ⛉Ꮫᡤ Ꮫෆඹྠ◊✲఍
➨ ᅇࢥࣥࣆࣗࢸ࣮ࢩࣙࢼ࣭࣐ࣝࢸࣜ࢔ࣝࢬ࣭ࢹࢨ࢖࣮ࣥ࣡ࢡࢩࣙࢵࣉ
࢔ࢪ࢔ࢥࣥࣆࣗࢸ࣮ࢩࣙࢼ࣭࣐ࣝࢸࣜ࢔ࣝࢬ࣭ࢹࢨ࢖࣮ࣥ࣡ࢡࢩࣙࢵࣉ
ࣞ࢔࢖࣋ࣥࢺࢧࣥࣉࣜࣥࢢ࡜㛵㐃ࢸ࣮࣐◊✲఍
ୖグ௨እ࡟ࡶࠊእ㒊ㅮᖌࢆᣍ࠸࡚ࡢࢭ࣑ࢼ࣮➼ࡶ㝶᫬㛤ദࡋ࡚࠾ࡾࠊࡑࢀࡽࡢྜィࡣ ௳㸦࠺ࡕእ
ᅜேࢆㅮᖌ࡟㏄࠼࡚ࡢࡶࡢࡣ ௳㸧࡛࠶ࡗࡓࠋ
᪥௜
ㅮᖌྡ
ᡤᒓᶵ㛵
Robert E.
University of Alberta
Campbell
࿴ᡞ ᘯᖾ ᰴᘧ఍♫ࢹࣥࢯ࣮
ᮾி኱Ꮫ
ὠ⏣ ᏹ἞
᪂㡿ᇦ๰ᡂ⛉Ꮫ◊✲⛉
ྂ㈡ ಙᗣ ศᏊ⛉Ꮫ◊✲ᡤ
ᕥ ᐜᪿ
₎㝧኱Ꮫ
㒯 Ὃ᰿
㔩ᒣᅜ❧኱Ꮫ
Aixin Yan
㤶 ኱Ꮫ
Patricia
Kooyman
ᙺ⫋
ෆᐜ
Molecular engineering to build new tools to
ᩍᤵ
probe cellular physiology
ᐊ㛗 ⮬ື㌴⏝ࢭࣥࢧ࣮
࣐ࢸࣜ࢔ࣝࢬ࣭࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫ࡟࠾ࡅࡿ
ᩍᤵ
࣋࢖ࢬ᭱㐺໬
෸ᩍᤵ ๰ࡗ࡚ศ࠿ࡿࢱࣥࣃࢡ㉁ศᏊࡢ௙⤌ࡳ
ࣃ࣮ࢥ࣮ࣞࢩࣙࣥ࡟❧⬮ࡋࡓ⇕⏺㠃ࢼࣀᮦ
ᩍᤵ
ᩱ
ࢭ࣑ࣛࢵࢡࢫ࠾ࡼࡧࢭ࣑ࣛࢵࢡࢫᇶᮦᩱࡢ
ᩍᤵ
㸱' ༳ๅᢏ⾡
⣽⳦஧ᡂศ᝟ሗఏ㐩⣔ࡀ⭷ࢆ௓ࡋ࡚ࢩࢢࢼ
෸ᩍᤵ
ࣝࢆఏ࠼ࡿ᪉ἲ
෸ᩍᤵ TEM ࡟࠾ࡅࡿᅽຊࢠࣕࢵࣉࡢඞ᭹
ࢹࣝࣇࢺᕤ⛉኱Ꮫ
ᑎ಴ Ύஅ ⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ
ⴱ ᏛṊ
୰ᅜ⛉Ꮫᢏ⾡኱Ꮫ
ứ 寇峆
୰ᅜ⛉Ꮫᢏ⾡኱Ꮫ
Tobias Meckel
Technische Universitat
Darmstadt
ྡ㄃ࣜࢧ࣮
ᙉㄏ㟁య࡟࠾ࡅࡿ㟁Ꮚศᴟࡢᶵᵓ
ࢳ࣮ࣕ
࣐࢞ࣥ⥺↷ᑕ࡟ࡼࡿ࣏࢚ࣜࢳࣞࣥࢸࣞࣇࢱ
ᩍᤵ
࣮ࣛࢺࡢࢢࣛࣇࢺ㔜ྜ࡜ᛂ⏝
㧗ศᏊᚤᑠ⌫యࡢᨺᑕ⥺ᢏ⾡࡟ࡼࡿฎ⌮࡜
ᩍᤵ
ᙧែไᚚ
Single molecule microscopy in mammalian 3D
PD
cell cultures and plants -Same challenge. Same
solution?
࢝ࣜࣇ࢛ࣝࢽ࢔኱Ꮫ
ᩍᤵ My life in Microbiology
ࣂ࣮ࢡ࣮ࣞᰯ
࣐ࣝࢸ࢕࣭ࣥࣝࢱ࣮኱
Caroline Haupt Ꮫࣁ࣭ࣦࣞ࢕ࢵࢸࣥ࣋ ༤ኈ◊✲ဨ ⣽⳦ከ๣᤼ฟࢩࢫࢸ࣒ 0GW()7RO&
ࣝࢡ
Jean-Jacques ࣮ࣚࣟࢵࣃ໬Ꮫ⏕≀Ꮫ
ᡤ㛗࣭ᩍᤵ Aptamers for diagnostic and analytical purposes
Toulmé
◊✲ᡤࠊ࣎ࣝࢻ࣮኱Ꮫ
࣐ࢵࢡࢫࣉࣛࣥࢡ◊✲ ୖ⣭◊✲
Kun Zhang
ᅉᯝࣔࢹࣜࣥࢢ࡜ᶵᲔᏛ⩦
ᡤ
⛉Ꮫ⪅
࢖ࣥ࣌ࣜ࢔ࣝ࢝ࣞࢵ
Thomas D.
Advanced materials & devices concepts for
ᩍᤵ
plastic opto/electronics
Anthopoulos ࢪࠊࣟࣥࢻࣥ
⣽⳦஧ḟ௦ㅰ⏘≀࡛࠶ࡿ࢖ࣥࢻ࣮ࣝࡀࠊ⥳⮋
Aixin Yan
㤶 ኱Ꮫ
෸ᩍᤵ
⳦ $7&& ᰴࡢࣆ࢜ࢩ࢔ࢽࣥ⏘⏕࣭ࣂ࢖࢜
஧㝵ᇽ⁅
― 15 ―
㧗ᐩ ಇ࿴
㧗࢚ࢿࣝࢠ࣮ຍ㏿ჾ◊
✲ᶵᵓ
ᢏᖌ
ࣇ࢕࣒ࣝᙧᡂ࣭⸆๣⪏ᛶୖ᪼ࢆಁ㐍ࡉࡏࡿ
5) 㟁Ꮚ㖠࠾ࡼࡧඛ➃ຍ㏿ჾ࡟࠾ࡅࡿຍ㏿✵
Ὕࡢ㉸⢭ᐦຍᕤ
Assistant
Lattice light sheet microscopy captures life in
Research
action
Fellow
㤫ᗞ ⤮㔛Ꮚ 㟁Ẽ㏻ಙ኱Ꮫ
ຓᩍ ࣆ࢔ࢽࢫࢺ࡜ࣆ࢔ࢽࢫࢺࡢ⪥
࣮ࣘࣜࢵࣄ◊✲ࢭࣥࢱ
ࣂࣝࢡ࠾ࡼࡧ⾲㠃࡟࠾ࡅࡿ ࣇ࣮ࣜࢹࣝ᣺
Peter H.
ᩍᤵ
Dederichs
࣮
ື
,U 㘒య࠾ࡼࡧࢪ࢔ࣜ̿ࣝ࢔࣑ࣀȧ࢝ࣝ࣎
㉿ ኱※
⏘ᴗ⛉Ꮫ◊✲ᡤ
ᩍᤵ
࣮ࣞࢺࡢග໬Ꮫ
ඛ➃ࢩࢫࢸ࣒ࡢࡓࡵࡢᮦᩱࡢಙ㢗ᛶ࡜ᶆ‽
Yong-Nam
㡑ᅜヨ㦂◊✲ᡤ
୺௵◊✲ဨ
Kim
໬
ᅛయ⇞ᩱ㟁ụᛂ⏝ࡢࡓࡵࡢ㓟໬≀࣌ࣟࣈࢫ
Hee Soo Lee 㔩ᒣᅜ❧኱Ꮫ
ᩍᤵ
࢝࢖ࢺࡢタィ࡜≉ᛶ
Christian
Associate The versatility of optical super-resolution
University of Oxford
Eggeling
Professor microscopy
࣐ࣝࢸ࢕࣭ࣥࣝࢱ࣮኱
ࢢ࣮ࣝࣉ ⑓ཎ⳦⸆๣᤼ฟࢺࣛࣥࢫ࣏࣮ࢱ࣮ࡢᇶ㉁㍺
⏣㎶ ᖿ㞝 Ꮫࣁ࣭ࣦࣞ࢕ࢵࢸࣥ࣋
࣮ࣜࢲ࣮ ㏦࣓࢝ࢽࢬ࣒ゎ᫂࡬ࡢᵓ㐀Ꮫⓗ࢔ࣉ࣮ࣟࢳ
ࣝࢡ
Bi-Chang
Chen
Academia Sinica
㸴㸧ᗈሗάື
ᙜ◊✲ᡤ࡛ࡣࠊᗈሗάືࡢ୍⎔࡜ࡋ࡚ḟࡢฟ∧≀➼ࢆⓎหࡋࡓࠋ
࣭⏘ᴗ⛉Ꮫ◊✲ᡤせぴ㸦᪥ᮏㄒ࣭ⱥㄒేグ㸧
࣭⏘ᴗ⛉Ꮫ◊✲ᡤࣃࣥࣇࣞࢵࢺ㸦᪥ᮏㄒ∧࠾ࡼࡧⱥㄒ∧㸧
࣭0HPRLUVRIWKH,QVWLWXWHRI6FLHQWLILFDQG,QGXVWULDO5HVHDUFK2VDND8QLYHUVLW\
࣭ᖺḟሗ࿌᭩
࣭⏘◊ࢽ࣮ࣗࢫࣞࢱ࣮㸦ᖺ㸱ᅇⓎ⾜㸧
࣭⏘◊ࢸࢡࣀࢧࣟࣥㅮ₇㘓࣭㈨ᩱ
࣭⏘◊⤂௓ '9'
ࡇࢀࡽࡣࠕ⏘◊࣮࣒࣮࣍࣌ࢪࠖ㸦85/KWWSZZZVDQNHQRVDNDXDFMS㸧࡛ࡶ㜀ぴྍ⬟ࠋ
ࡲࡓࠊ኱㜰኱Ꮫึࡢヨࡳ࡜ࡋ࡚ࠊሗ㐨㛵ಀ⪅ࢆᑐ㇟࡟ࠊ᭶࡟ ᗘᐃ౛グ⪅఍ぢࢆ⾜ࡗ࡚࠸ࡿࠋ
㸵㸧ཷ㈹≧ἣ 㸦ᖹᡂ ᖺ ᭶ ᪥㹼ᖹᡂ ᖺ ᭶ ᪥㸧
ᕝྜ
ᰗ⏣
㛗ᓥ
⸨ᕝ
ඵᮌ
ᵐཎ
Ⳣ἟
➲஭
⃝
Ặྡ
ཷ㈹ྡ
▱஧
๛➨ ᅇᛂ⏝≀⌮Ꮫ఍᫓Ꮨ኱఍ ࣏ࢫࢱ࣮㈹
୍ᶞ
㯞⏤
᪥ᮏ໬Ꮫ఍➨ ᫓Ꮨᖺ఍Ꮫ⏕ㅮ₇㈹
ᗣྐ
ᩥ㒊⛉Ꮫ኱⮧⾲ᙲ⛉Ꮫᢏ⾡㈹◊✲㒊㛛
㟹
ᩥ㒊⛉Ꮫ኱⮧⾲ᙲ⛉Ꮫᢏ⾡㈹◊✲㒊㛛
ඞ᫛
୍⯡♫ᅋἲே࢚ࣞࢡࢺࣟࢽࢡࢫᐇ⿦Ꮫ఍Ꮫ఍㈹
ᏹ᫂ ࢩ࣏ࣥࢪ࣒࣮࢘ࣔࣞ࢟ࣗࣛ࢟ࣛࣜࢸ࢕࣏ࢫࢱ࣮㈹
ᚸ
― 16 ―
ཷ㈹᪥
ᅵ஭
ྜྷ⏣
ᑠᑎ
బྂ
㈗⿱
Ὀᚿ
⣧ᖹ
┿
Ᏻ⸨ 㝧୍
㛵㇂ Ẏ
➲஭ ᏹ᫂ ⃝ ᚸ ᓊ 㕲㤿 㕥ᮌ ㏻ᜤ Fernando A.
Arteaga
T.M.N.Nguyen
ࢩ࣏ࣥࢪ࣒࣮࢘ࣔࣞ࢟ࣗࣛ࢟ࣛࣜࢸ࢕࣏ࢫࢱ࣮㈹
ࢺ࣒ࢯࣥࣟ࢖ࢱ࣮㧗⿕ᘬ⏝◊✲⪅
ࢺ࣒ࢯࣥࣟ࢖ࢱ࣮㧗⿕ᘬ⏝◊✲⪅
࢚ࣝࢮࣅ࢔ ࣋ࢫࢺ࣏ࢫࢱ࣮㈹
ᯘ ඞᙪ
➨ ᅇḟୡ௦ࢆᢸ࠺ⱝᡭࡢࡓࡵࡢࣇ࢕ࢪ࣭࢝ࣝࣇ࢛࣮࣒ࣛⱝᡭ◊✲
⪅ዡບ㈹
す㔝㑥ᙪ
ᖹᡂ ᖺᗘ≉ู◊✲ဨ➼ᑂᰝ఍ᑓ㛛ጤဨཬࡧᅜ㝿஦ᴗጤဨ఍᭩㠃ᑂ
ᰝဨࡢ⾲ᙲ
ᮌᮧ ༟ᘯ
ඵᮌ ᗣྐ
ᵐཎ 㟹 ᮧᯇ ኱࿃
➲஭ ᏹ᫂
⃝ ᚸ ᖹ⏣ ಟ୍
ᓊ 㕲㤿 Fernando A.
Arteaga
┿ᔱ ဴᮁ
⸨ཎ ᏹᖹ
㛗ᓥ ୍ᶞ
Ⳣཎ ᚭ
㇂ཱྀ ṇ㍤
ᕝྜ ▱஧
⟄஭ ┿ᴋ
㏆⸨ Ꮥᩥ
Ᏻ⸨ 㝧୍
➲஭ ᏹ᫂
➉୰ ࿴ᾈ
ᯘ ㈼௒
Ᏻ⸽ ⰾ㞝
㛤ⓐ 㑥ᏹ
ᵐཎ㟹
ඵᮌ ᗣྐ
ᯇᮧ 㝯ᘯ
➨ ᅇ⏬ീࡢㄆ㆑࣭⌮ゎࢩ࣏ࣥࢪ࣒࢘0,58Ꮫ⏕ඃ⚽㈹
ᖹᡂ ᖺᗘࠕ᭷ᶵྜᡂⱝᡭࢭ࣑ࢼ࣮࣏ࠖࢫࢱ࣮㈹
᪥ᮏᨺᑕ⥺໬Ꮫ఍ᨺᑕ⥺໬Ꮫ㈹
7KH0DWHULDOV5HVHDUFK6RFLHW\RI-DSDQ$ZDUGIRU(QFRXUDJHPHQW
RI5HVHDUFKLQ,8056,&$6\PSRVLXP&&
බ┈♫ᅋἲேᛂ⏝≀⌮Ꮫ఍ ㅮ₇ዡບ㈹
୍⯡♫ᅋἲே᪥ᮏ⇕㟁Ꮫ఍ ㅮ₇ዡບ㈹
➨ ᅇබ┈㈈ᅋἲேᛂ⏝≀⌮Ꮫ఍⛅ᏘᏛ⾡ㅮ₇఍ ᖺ࣏ࢫࢱ࣮㈹
➨ ᅇ㟁㞳ᨺᑕ⥺࡜㧗ศᏊᅜ㝿఍㆟࣋ࢫࢺ࣏ࢫࢱ࣮㈹
኱㜰⛉Ꮫ㈹
࣮ࣔࣞ࢟ࣗࣛ࢟ࣛࣜࢸ࢕࢔ࢪ࢔ ࣏ࢫࢱ࣮㈹
ᖺᗘ᭷ᶵȧ㟁Ꮚ⣔Ꮫ఍㈹
᪥ᮏ࢝ࢸ࢟ࣥᏛ఍࣏ࢫࢱ࣮Ⓨ⾲ ඃ⚽Ⓨ⾲㈹
࣐ࣝࢳ࣓ࢹ࢕࢔࡟㛵ࡍࡿ➨ ᅇ⎔ኴᖹὒ఍㆟ඃ⚽ᰝㄞ⪅㈹
➨ ᅇࣟࣂࢫࢺࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ࡟㛵ࡍࡿᅜ㝿࣮࣡ࢡࢩࣙࢵࣉ
,:5&9 ࣋ࢫࢺ࣏ࢫࢱ࣮㈹
ᩥ㒊⛉Ꮫ┬ ⛉Ꮫᢏ⾡࣭Ꮫ⾡ᨻ⟇◊✲ᡤ ⛉Ꮫᢏ⾡࡬ࡢ㢧ⴭ࡞㈉⊩
㇂ཱྀ ṇ㍤
㸦ࢼ࢖ࢫࢫࢸࢵࣉ࡞◊✲⪅㸧
⸨ཎᏹᖹ
᪥ᮏ 056 ዡບ㈹
― 17 ―
⬟ᮌ㞞ஓ
⚄ྜྷ ㍤ኵ
㛤ⓐ 㑥ᏹ
ྂᓮ ᫭ྖ
➉୰ ࿴ᾈ
ᒣᓮ ⪷ྖ
ᮅ᪥ 㛵すࢫࢡ࢚࢔㈹
᝟ሗࢩࢫࢸ࣒ᩍ⫱ࢥࣥࢸࢫࢺዡບ㈹
ⲔᏛ⾡◊✲఍ ࣏ࢫࢱ࣮㈹
኱㜰࠿ࡽ⪃࠼ࡿ &LYLF7HFK ࢔ࣉࣜࢥࣥࢸࢫࢺ࢔ࣉ࣭ࣜ:HE ࢧ࣮ࣅࢫ
㒊㛛 ඃ຾㸦ࢢࣛࣥࣉࣜ㸧
᪥ᮏ໬Ꮫ఍ⱝ࠸ୡ௦ࡢ≉ูㅮ₇
➨ ᅇ᪥ᮏ⣽⳦Ꮫ఍⥲఍ඃ⚽Ⓨ⾲㈹
㸱㸬ᩍ⫱࡬ࡢ㛵୚㸦ᖹᡂ ᖺᗘ㸧
㸯㸧኱Ꮫ㝔◊✲⛉ࡢᡤᒓඛ
ᙜ◊✲ᡤࡢᩍဨࡣࠊ኱㜰኱Ꮫ኱Ꮫ㝔⌮Ꮫ◊✲⛉ࠊᕤᏛ◊✲⛉ࠊᇶ♏ᕤᏛ◊✲⛉ࠊ⸆Ꮫ◊✲⛉ࠊ᝟ሗ⛉
Ꮫ◊✲⛉ࠊ⏕࿨ᶵ⬟◊✲⛉࡟ࡶᡤᒓࡋࠊྛᑓᨷࡢ኱Ꮫ㝔⏕ࡢㅮ⩏࠾ࡼࡧ◊✲ᣦᑟࢆ⾜ࡗ࡚࠸ࡿࠋ
◊✲⛉
ᑓᨷ
ᩍᤵ
෸ᩍᤵ
⌮Ꮫ
☾ᒣ ᝅᮁ
㛗㇂ᕝ ⦾ᙪ
ᑠཱྀከ⨾ኵ
஭ୖ ᜏ୍
≀⌮Ꮫ
ⓑ஭ ග㞼
ຍ⸨ 㱟ዲ
ᑠᯘ ග
ᇽ㔝 ୺⛯
➲஭ ᏹ᫂
⃝ ᚸ
໬Ꮫ
୰㇂ ࿴ᙪ
㕥ᮌ ೺அ
ຍ⸨ ಟ㞝
㇂ཱྀ ṇ㍤
ᕤᏛ
ᑠཱྀ ከ⨾ኵ
㡲⸨ Ꮥ୍
⢭ᐦ⛉Ꮫ࣭ᛂ⏝≀⌮Ꮫ ⓑ஭ ග㞼
㮖ᑿ 㝯
㛗㇂ᕝ ⦾ᙪ
㟁Ẽ㟁Ꮚ᝟ሗᕤᏛ
㥖㇂ ࿴⠊
౗ᮧ ᚨಙ
኱ᒾ 㢧
ྂᓮ ᫭ྖ
➉⏣ ⢭἞
ྜྷ⏣ ⚽ே
࣐ࢸࣜ࢔ࣝ⏕⏘⛉Ꮫ
㛵㔝 ᚭ
ከ᰿ ṇ࿴
Ᏻ⸨ 㝧୍
℩ᕝ ⪔ྖ
┿ᔱ ဴᮁ
⸨ሯ Ᏺ
ᛂ⏝໬Ꮫ
ྂ⃝ Ꮥᘯ
ᕝ஭ Ύᙪ
Ᏻ⸽ ⰾ㞝
ᐊᒇ ⿱బ
ᐙ ⿱㝯
㇂ᮧ ඞᕫ
㔠ᓮ 㡰୍
ྜྷ⏣ 㝧୍
⏣୰ ៅ୍㑻
⎔ቃ࣭࢚ࢿࣝࢠ࣮ᕤᏛ
㄃⏣ ⩏ⱥ
᳿ 㔠ᓠ
Ⳣ἟ ඞ᫛
⬟ᮌ 㞞ஓ
▱⬟㺃ᶵ⬟๰ᡂᕤᏛ
㛗ᑿ ⮳ᡂ
ࣅࢪࢿࢫ࢚ࣥࢪࢽ࢔ࣜࣥࢢ
⏕࿨ඛ➃ᕤᏛ
ᇶ♏ᕤᏛ
≀㉁๰ᡂ
㮖ᑿ 㝯
Ọ஭ ೺἞
ᯇ⏣ ▱ᕫ
ᯇᮏ ࿴ᙪ
ᑠཱྀ ከ⨾ኵ
⏣୰ ⚽࿴
஭ୖ
๓ᶫ
ⓑ஭
⚄ྜྷ
― 18 ―
ᜏ୍
ව୕
ග㞼
㍤ኵ
⸆Ꮫ
᝟ሗ⛉Ꮫ
⏕࿨ᶵ⬟
᝟ሗᩘ⌮Ꮫ
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ
⏕࿨ᶵ⬟
἟ᑿ ṇ⾜
ඵᮌ ᗣྐ
Ọ஭ ೺἞
す Ẏ
す㔝 㑥ᙪ
ᒸᓥ ಇⱥ
࿴⏣ ὒ
㸰㸧኱Ꮫ㝔ᢸᙜᤵᴗ୍ぴ
◊✲⛉
⛉┠
⌮Ꮫ
ࢼࣀࣉࣟࢭࢫ࣭≀ᛶ࣭ࢹࣂ࢖ࢫᏛ ㉸ศᏊࢼࣀࣂ࢖࢜ࣉࣟࢭࢫᏛ ࢼࣀᵓ㐀࣭ᶵ⬟ィ ゎᯒᏛ ᨺᑕග≀⌮Ꮫ ຍ㏿ჾ⛉Ꮫ ᅛయ㟁Ꮚㄽϩ
༙ᑟయ໬Ꮫ ,
≀ᛶ⌮ㄽࢭ࣑ࢼ࣮ϩ
≀ᛶ⌮ㄽ≉ูࢭ࣑ࢼ࣮ϩ
㺣㺧㺭㺡㺶㺏㺷㺃㺣㺧㺡㺼㺨㺼㺐㺛㺡㺼㺙㺼㺐㺻Ꮫ
༙ᑟయ༙ᮇࢭ࣑ࢼ࣮
༙ᑟయ≉ูࢭ࣑ࢼ࣮
༙ᑟయ≀⌮Ꮫ
ᨺᑕග༙ᮇࢭ࣑ࢼ࣮
ᨺᑕග≉ูࢭ࣑ࢼ࣮ ゐ፹໬Ꮫ
኱Ꮫ㝔᭷ᶵ໬Ꮫ ྜᡂ᭷ᶵ໬Ꮫ,
༙ᑟయ໬Ꮫࢭ࣑ࢼ࣮Ϩ ༙ᑟయ໬Ꮫࢭ࣑ࢼ࣮ϩ ᶵ⬟ᛶศᏊ໬Ꮫࢭ࣑ࢼ࣮Ϩࠊϩ ໬Ꮫ࢔ࢻࣂࣥࢫࢺᐇ㦂
໬Ꮫ࢔ࢻࣂࣥࢫࢺᐇ㦂㸦⛅ධᏛ⪅⏝㸧
ࢤࣀ࣒໬Ꮫ ࢤࣀ࣒໬Ꮫࢭ࣑ࢼ࣮Ϩࠊϩ ࢤࣀ࣒໬Ꮫ≉ูࢭ࣑ࢼ࣮ ྜᡂ᭷ᶵ໬Ꮫࢭ࣑ࢼ࣮Ϩࠊϩ ༙ᑟయ໬Ꮫ≉ูࢭ࣑ࢼ࣮ ྜᡂ᭷ᶵ໬Ꮫ≉ูࢭ࣑ࢼ࣮ ᶵ⬟ᛶศᏊ໬Ꮫ≉ูࢭ࣑ࢼ࣮ ⏕యᶵ⬟≀㉁Ꮫࢭ࣑ࢼ࣮
⏕యᶵ⬟≀㉁Ꮫ≉ูࢭ࣑ࢼ࣮ ⏕≀⛉Ꮫ≉ㄽ ,;
ᵓ㐀≀ᛶ໬Ꮫ㸦Ϩ㸧
ᵓ㐀≀ᛶ໬Ꮫ༙ᮇࢭ࣑ࢼ࣮Ϩ
ᵓ㐀≀ᛶ໬Ꮫ༙ᮇࢭ࣑ࢼ࣮ϩ
ᵓ㐀≀ᛶ໬Ꮫ≉ูࢭ࣑ࢼ࣮
ᕤᏛ
㟁Ꮚᶵ⬟ศᏊ໬Ꮫ Chemistry of Advanced Functional Materials
― 19 ―
ᢸᙜᩍဨ
ᯇᮏ ࿴ᙪ
┿ᔱ ဴᮁࠊ⸨ሯ Ᏺࠊᕝ஭ Ύᙪࠊ❧ᕝ ㈗ኈ
➉⏣ ⢭἞
☾ᒣ ᝅᮁ
☾ᒣ ᝅᮁ
ᑠཱྀ ከ⨾ኵ
ᑠᯘ ගࠊᯇᮏ ೺ಇ
ᑠཱྀ ከ⨾ኵࠊⓑ஭ ග㞼
ᑠཱྀ ከ⨾ኵࠊⓑ஭ ග㞼
ᑠཱྀ ከ⨾ኵࠊⓑ஭ ග㞼
㛗㇂ᕝ ⦾ᙪ
㛗㇂ᕝ ⦾ᙪ
㛗㇂ᕝ ⦾ᙪ ☾ᒣ ᝅᮁࠊ஭ୖ ᜏ୍ࠊຍ⸨ 㱟ዲ
☾ᒣ ᝅᮁࠊ஭ୖ ᜏ୍ࠊຍ⸨ 㱟ዲ ➲஭ ᏹ᫂ࠊ㕥ᮌ ೺அࠊ⃝ ᚸ
➲஭ ᏹ᫂
ຍ⸨ ಟ㞝
ᑠᯘ ගࠊᯇᮏ ೺ಇ
ᑠᯘ ගࠊᯇᮏ ೺ಇ
➲஭ ᏹ᫂ࠊ㕥ᮌ ೺அ
㕥ᮌ೺அ
㕥ᮌ೺அ
୰㇂ ࿴ᙪࠊᇽ㔝 ୺⛯
୰㇂ ࿴ᙪ
୰㇂ ࿴ᙪ
ຍ⸨ ಟ㞝
ᑠᯘ ග
ຍ⸨ ಟ㞝
➲஭ ᏹ᫂
ᒸᓥ ಇⱥࠊ୰஭ ᛅᚿࠊ❧ᯇ ೺ྖ
ᒸᓥ ಇⱥࠊ୰஭ ᛅᚿࠊ❧ᯇ ೺ྖ
ᒸᓥ ಇⱥࠊ୰஭ ᛅᚿ
㇂ཱྀ ṇ㍤
㇂ཱྀ ṇ㍤
㇂ཱྀ ṇ㍤
㇂ཱྀ ṇ㍤
Ᏻ⸽ ⰾ㞝ࠊᐙ ⿱㝯
Ᏻ⸽ ⰾ㞝ࠊᐙ ⿱㝯
ᕤᏛ
ບ㉳཯ᛂ໬Ꮫ ศᏊ๰ᡂ໬Ꮫࢮ࣑ࢼ࣮ࣝ Applied Chemistry Adv. I
Applied Chemistry Adv. II
ศᏊ๰ᡂ໬Ꮫ◊✲ㄢ㢟௻⏬ࢮ࣑ࢼ࣮ࣝ
ศᏊ๰ᡂ໬Ꮫඛ➃◊✲᝟ሗࢮ࣑ࢼ࣮ࣝ
◊✲௻⏬ࢮ࣑ࢼ࣮ࣝ
ග≀ᛶ࣭ග࢚ࣞࢡࢺࣟࢽࢡࢫ 㟁Ẽ㟁Ꮚ᝟ሗᕤᏛࢭ࣑ࢼ࣮ 㟁Ẽ㟁Ꮚ᝟ሗᕤᏛ₇⩦࣭ᐇ⩦ 㟁Ẽ㟁Ꮚ᝟ሗᕤᏛ≉ูㅮ⩏ϫ ඛ➃㺒㺸㺖㺢㺹㺤㺖㺛㺡㺼㺨㺼㺐㺛ᕤᏛ≉ㄽϩ
㔞ᏊศᏊᕤᏛ ᅛయ≀ᛶ໬Ꮫ ≀㉁ᶵ⬟໬Ꮫࢮ࣑ࢼ࣮ࣝ
≀㉁ᶵ⬟໬Ꮫ◊✲ㄢ㢟௻⏬ࢮ࣑ࢼ࣮ࣝ
≀㉁ᶵ⬟໬Ꮫඛ➃◊✲᝟ሗࢮ࣑ࢼ࣮ࣝ
᭷ᶵ༙ᑟయࢹࣂ࢖ࢫ≀⌮
๰ᡂᕤᏛࢮ࣑ࢼ࣮ࣝ
ᇶ┙๰ᡂᕤᏛ ▱⬟๰ᡂᕤᏛ ᶵ⬟๰ᡂᕤᏛ ᇶ┙ 33
⼥ྜ⛉Ꮫᢏ⾡๰ᡂ
♫఍⼥ྜᕤᏛ
ᅜ㝿⼥ྜᕤᏛ
ඛᑟ⼥ྜᕤᏛ
ᮦᩱタィㄽ
ᴟᚤᵓ㐀ゎᯒᏛ
㔞Ꮚࣅ࣮࣒໬Ꮫ
ࢹ࣮ࢱ࣐࢖ࢽࣥࢢᕤᏛ
▱ⓗ᝟ሗฎ⌮ㄽ
▱⬟ࢩࢫࢸ࣒ᕤᏛ≉ㄽ
ཎᏊຊᕤᏛࢭ࣑ࢼ࣮㸯
ཎᏊຊᕤᏛࢭ࣑ࢼ࣮㸰
ཎᏊຊᕤᏛࢭ࣑ࢼ࣮
ࢼࣀᕤᏛ
⎔ቃ࢚ࢿࣝࢠ࣮ᕤᏛࢭ࣑ࢼ࣮㸯
⎔ቃ࢚ࢿࣝࢠ࣮ᕤᏛࢭ࣑ࢼ࣮㸰
ཎᏊຊᕤᏛࢭ࣑ࢼ࣮
― 20 ―
┿ᔱ ဴᮁࠊ⸨ሯ Ᏺࠊᕝ஭ Ύᙪ
┿ᔱ ဴᮁࠊᏳ⸽ ⰾ㞝ࠊ⸨ሯ Ᏺࠊᕝ஭
ᐙ ⿱㝯
┿ᔱ ဴᮁࠊᏳ⸽ ⰾ㞝ࠊ⸨ሯ Ᏺࠊᕝ஭
ᐙ ⿱㝯
┿ᔱ ဴᮁࠊᏳ⸽ ⰾ㞝ࠊ⸨ሯ Ᏺࠊᕝ஭
ᐙ ⿱㝯
┿ᔱ ဴᮁࠊᏳ⸽ ⰾ㞝ࠊ⸨ሯ Ᏺࠊᕝ஭
ᐙ ⿱㝯
┿ᔱ ဴᮁࠊᏳ⸽ ⰾ㞝ࠊ⸨ሯ Ᏺࠊᕝ஭
ᐙ ⿱㝯
┿ᔱ ဴᮁࠊᏳ⸽ ⰾ㞝ࠊ⸨ሯ Ᏺࠊᕝ஭
ᐙ ⿱㝯
኱ᒾ 㢧ࠊ㛗㇂ᕝ ⦾ᙪ
㮖ᑿ 㝯ࠊ኱ᒾ 㢧ࠊ㥖㇂ ࿴⠊ࠊἙཎ
ΎỈ ᫀᖹࠊ㛗㇂ᕝ⦾ᙪࠊྂᓮ ᫭ྖ
㮖ᑿ 㝯ࠊ኱ᒾ 㢧ࠊ㥖㇂ ࿴⠊ࠊἙཎ
ΎỈ ᫀᖹࠊ㛗㇂ᕝ⦾ᙪࠊྂᓮ ᫭ྖ
㮖ᑿ 㝯ࠊ኱ᒾ 㢧ࠊ㥖㇂ ࿴⠊ࠊἙཎ
ΎỈ ᫀᖹࠊ㛗㇂ᕝ⦾ᙪࠊྂᓮ ᫭ྖ
኱ᒾ 㢧ࠊ㛗㇂ᕝ ⦾ᙪ
ྂ⃝ Ꮥᘯࠊᐊᒇ ⿱బ
Ᏻ⸨ 㝧୍
Ᏻ⸨ 㝧୍
Ᏻ⸨ 㝧୍ࠊྂ⃝ Ꮥᘯ
Ᏻ⸨ 㝧୍ࠊྂ⃝ Ꮥᘯ
㡲⸨ Ꮥ୍
Ⳣ἟ ඞ᫛ࠊ⬟ᮌ 㞞ஓ
Ⳣ἟ ඞ᫛ࠊ⬟ᮌ 㞞ஓࠊ㛗ᑿ ⮳ᡂ
Ⳣ἟ ඞ᫛ࠊ⬟ᮌ 㞞ஓ
Ⳣ἟ ඞ᫛ࠊ⬟ᮌ 㞞ஓ
Ⳣ἟ ඞ᫛ࠊ⬟ᮌ 㞞ஓࠊ㛗ᑿ ⮳ᡂ
Ⳣ἟ ඞ᫛ࠊ⬟ᮌ 㞞ஓࠊ㛗ᑿ ⮳ᡂ
Ⳣ἟ ඞ᫛ࠊ⬟ᮌ 㞞ஓ
Ⳣ἟ ඞ᫛ࠊ⬟ᮌ 㞞ஓ
Ⳣ἟ ඞ᫛ࠊ⬟ᮌ 㞞ஓ
㛵㔝 ᚭࠊከ᰿ ṇ࿴
➉⏣ ⢭἞
ྜྷ⏣ 㝧୍ࠊ᳿ 㔠ᓠࠊ㄃⏣ ⩏ⱥ
㮖ᑿ 㝯ࠊἙཎ ྜྷఙࠊΎỈ ᫀᖹ
㥖㇂ ࿴⠊ࠊྂᓮ ᫭ྖ
㥖㇂ ࿴⠊ࠊྂᓮ ᫭ྖ
㇂ᮧ ඞᕫ
ྜྷ⏣ 㝧୍
ྜྷ⏣ 㝧୍ࠊ᳿ 㔠ᓠࠊ㄃⏣ ⩏ⱥ
㇂ᮧ ඞᕫ
ྜྷ⏣ 㝧୍ࠊ᳿ 㔠ᓠࠊ㏆⸨ ᏕᩥࠊⳢ
ྜྷ⏣ 㝧୍ࠊ᳿ 㔠ᓠࠊ㏆⸨ ᏕᩥࠊⳢ
ྜྷ⏣ 㝧୍ࠊ᳿ 㔠ᓠࠊ㏆⸨ ᏕᩥࠊⳢ
Ύᙪࠊ
Ύᙪࠊ
Ύᙪࠊ
Ύᙪࠊ
Ύᙪࠊ
Ύᙪࠊ
ྜྷఙࠊ
ྜྷఙࠊ
ྜྷఙࠊ
᫭୍
᫭୍
᫭୍
ᕤᏛ
㔞Ꮚࣅ࣮࣒໬Ꮫ
ᚠ⎔ᆺᮦᩱ㈨※ࢩࢫࢸ࣒ㄽ
ࢼࣀᕤᏛ
ࢼࣀࣂ࢖࢜ࢸࢡࣀࣟࢪ࣮≉ㄽ
ࢮ࣑ࢼ࣮ࣝ,9
⏕≀ᕤᏛࢮ࣑ࢼ࣮ࣝ
⏕≀ᕤᏛᐇ㦂
≀⌮໬Ꮫᐇ㦂
ᇶ♏ᕤᏛ ༙ᑟయ≀ᛶ
ඛ➃≀㉁タィㄽ
ྜྷ⏣ 㝧୍ࠊ᳿ 㔠ᓠࠊ㄃⏣ ⩏ⱥ
᳿ 㔠ᓠ
ྜྷ⏣ 㝧୍
Ọ஭ ೺἞ࠊᯇ⏣ ▱ᕫ
Ọ஭ ೺἞
Ọ஭ ೺἞
Ọ஭ ೺἞ࠊᯇ⏣ ▱ᕫ
ᯇ⏣ ▱ᕫࠊ᪂஭ ⏤அ
ᯇᮏ ࿴ᙪࠊ஭ୖ ᜏ୍
ⓑ஭ ග㞼
ᯇᮏ ࿴ᙪࠊ஭ୖ ᜏ୍ࠊᑠཱྀ ከ⨾ኵࠊ⏣୰ ⚽
ࢮ࣑ࢼ࣮ࣝϨࠊϩ ࿴ࠊ⚄ྜྷ ㍤ኵ
ᯇᮏ ࿴ᙪࠊ஭ୖ ᜏ୍ࠊᑠཱྀ ከ⨾ኵࠊ⏣୰ ⚽
≀⌮⣔◊✲Ϩࠊϩ ࿴ࠊ⚄ྜྷ ㍤ኵ
⾲㠃࣭⏺㠃 ㉸ⷧ⭷≀ᛶ
⏣୰ ⚽࿴ࠊ⚄ྜྷ ㍤ኵ
⸆Ꮫ
≉ู₇⩦
す Ẏ
๰ᡂ⸆Ꮫ≉ู◊✲㸯
す Ẏ
⣽⬊⏕≀Ꮫ㸯
す Ẏ
๰ᡂ⸆Ꮫ≉ู◊✲㸱
す Ẏ
⣽⬊⏕≀Ꮫ㸱
す Ẏ
᝟ሗ⛉Ꮫ ᝟ሗᩘ⌮Ꮫࢭ࣑ࢼ࣮Ϩ ἟ᑿ ṇ⾜
᝟ሗᩘ⌮Ꮫࢭ࣑ࢼ࣮ϩ ἟ᑿ ṇ⾜
᝟ሗᩘ⌮Ꮫ₇⩦Ϩ
἟ᑿ ṇ⾜
᝟ሗᩘ⌮Ꮫ₇⩦ϩ
἟ᑿ ṇ⾜
᝟ሗᩘ⌮Ꮫ◊✲Ϩ
἟ᑿ ṇ⾜
᝟ሗᩘ⌮Ꮫ◊✲ϩ
἟ᑿ ṇ⾜
᝟ሗᩘ⌮Ꮫᴫㄽ
἟ᑿ ṇ⾜
▱⬟࡜Ꮫ⩦
἟ᑿ ṇ⾜
▱⬟࢔࣮࢟ࢸࢡࢳࣕ
἟ᑿ ṇ⾜
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫࢭ࣑ࢼ࣮Ϩ
ඵᮌ ᗣྐࠊᵐཎ 㟹
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫࢭ࣑ࢼ࣮ϩ
ඵᮌ ᗣྐࠊᵐཎ 㟹
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ₇⩦Ϩ
ඵᮌ ᗣྐࠊᵐཎ 㟹
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ₇⩦ϩ
ඵᮌ ᗣྐࠊᵐཎ 㟹
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫᇶ♏ㄽ
ඵᮌ ᗣྐࠊᵐཎ 㟹
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ࢖ࣥࢱ࣮ࣥࢩࢵ ඵᮌ ᗣྐࠊᵐཎ 㟹
ࣉ
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ࢖ࣥࢱ࣮ࣥࢩࢵ ඵᮌ ᗣྐࠊᵐཎ 㟹
ࣉ '
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ◊✲ϨD
ඵᮌ ᗣྐࠊᵐཎ 㟹
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ◊✲ϨE
ඵᮌ ᗣྐࠊᵐཎ 㟹
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ◊✲ϩD
ඵᮌ ᗣྐࠊᵐཎ 㟹
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ◊✲ϩE
ඵᮌ ᗣྐࠊᵐཎ 㟹
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ࢔ࢻࣂࣥࢫࢺࢭ ඵᮌ ᗣྐࠊᵐཎ 㟹
࣑ࢼ࣮Ϩ
ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ࢔ࢻࣂࣥࢫࢺࢭ ඵᮌ ᗣྐࠊᵐཎ 㟹
࣑ࢼ࣮ϩ
▱⬟ࢩࢫࢸ࣒ᴫㄽ
ඵᮌ ᗣྐࠊᵐཎ 㟹
᝟ሗᩘ⌮Ꮫ࢖ࣥࢱ࣮ࣥࢩࢵࣉ
἟ᑿ ṇ⾜
᝟ሗᩘ⌮Ꮫ࢖ࣥࢱ࣮ࣥࢩࢵࣉ '
἟ᑿ ṇ⾜
― 21 ―
⏕࿨ᶵ⬟ ⌮ᕤ་Ꮫϩ㹄
ᒸᓥ ಇⱥ
㸱㸧኱Ꮫ㝔⏕ࡢཷධᩘᖹᡂ ᖺ
㸦◊✲⛉㸧 㸦ᑓᨷ㸧 㸦༤ኈ๓ᮇ㸧㸦༤ኈᚋᮇ㸧 㸦ᑠィ㸧
⌮ Ꮫ ≀⌮Ꮫ ໬ Ꮫ 㸦ᑠ ィ㸧 ᕤ Ꮫ ᛂ⏝໬Ꮫ ▱⬟࣭ᶵ⬟๰ᡂᕤᏛ ࣐ࢸࣜ࢔ࣝ⏕⏘⛉Ꮫ
㟁Ẽ㟁Ꮚ᝟ሗᕤᏛ
⎔ቃ࣭㺒㺦㺷㺕㺼㺎ᕤᏛ ⏕࿨ඛ➃ᕤᏛ 㸦ᑠ ィ㸧 ᇶ♏ᕤᏛ ≀㉁๰ᡂ 㸦ᑠ ィ㸧
⸆ Ꮫ ๰ᡂ⸆Ꮫ 㸦ᑠィ㸧 ᝟ሗ⛉Ꮫ᝟ሗᩘ⌮Ꮫ ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ 㸦ᑠィ㸧 ⏕࿨ᶵ⬟ ⏕࿨ᶵ⬟ ᑠ ィ 㸳ᖺ୍㈏ไ㸧 ྜ ィ
㸲㸧Ꮫ㒊ࠊඹ㏻ᩍ⫱ᢸᙜᤵᴗ୍ぴ㸦ᖹᡂ ᖺᗘ㸧
࣭Ꮫ㒊ᢸᙜᤵᴗ
Ꮫ㒊
⛉┠
ᕤ ▱㆑᝟ሗฎ⌮
᝟ሗᩘ⌮Ꮫ₇⩦ ,
᝟ሗᇶ♏
㔞Ꮚࣅ࣮࣒ᕤᏛ
㔞Ꮚࣅ࣮࣒ᕤᏛ
⎔ቃ࣭࢚ࢿࣝࢠ࣮≉ูㅮ⩏ ,
㔞Ꮚ໬Ꮫ
㟁☢ẼᏛ
ඛ➃ィ ᕤᏛ₇⩦
ᇶ♏ᕤ ᅛయ㟁Ꮚㄽ %
▱㆑ᕤᏛ
ィ⟬ᶵ᥼⏝ᕤᏛ %
ᢸᙜᩍဨ
἟ᑿ ṇ⾜
᳃ᒣ ⏥୍ࠊ⚟஭ ೺୍
⚟஭ ೺୍
ྜྷ⏣ 㝧୍
ྜྷ⏣ 㝧୍
᳿ 㔠ᓠ
ྜྷ⏣ 㝧୍ࠊ᳿ 㔠ᓠ
᳿ 㔠ᓠ
Ọ஭ ೺἞ࠊᯇ⏣ ▱ᕫ
ᑠཱྀ ከ⨾ኵ
ඵᮌ ᗣྐࠊྥᕝ ᗣ༤
ඵᮌ ᗣྐࠊྥᕝ ᗣ༤
― 22 ―
ᇶ♏ᕤ ᝟ሗ⛉Ꮫࢮ࣑ࢼ࣮ࣝ $
᝟ሗ⛉Ꮫࢮ࣑ࢼ࣮ࣝ %
ࣉࣟࢢ࣑ࣛࣥࢢ &
ࣉࣟࢢ࣑ࣛࣥࢢ %
᝟ሗ⛉Ꮫ₇⩦ '
ࢭ࣑ࣛࢵࢡࢫ≀ᛶ
༙ᑟయ≀⌮ %
໬Ꮫᴫㄽ
⸆ ᢠ⏕≀㉁Ꮫ
⣽⬊⏕≀Ꮫ≉ㄽ
ඵᮌ ᗣྐࠊྥᕝ ᗣ༤
ඵᮌ ᗣྐࠊྥᕝ ᗣ༤
ᵐཎ 㟹
‶ୖ ⫱ஂ
‶ୖ ⫱ஂ
⏣୰ ⚽࿴
ᯇᮏ ࿴ᙪࠊ๓ᶫ ව୕
㇂ཱྀ ṇ㍤ࠊ⟄஭ ┿ᴋ
す Ẏ
す㔝 㑥ᙪࠊす Ẏ
࣭ඹ㏻ᩍ⫱ᢸᙜᤵᴗ
༊ศ
⛉┠
ᇶ♏ࢭ࣑ࢼ࣮
࢚ࣞࢡࢺࣟࢽࢡࢫ࡜᭷ᶵ໬Ꮫ
᭱᪂ࢼࣀࢸࢡࣀࣟࢪ࣮ධ㛛
ศᏊ࡜⏕࿨
ᢸᙜᩍဨ
Ᏻ⸽ ⰾ㞝ࠊ୰㇂ ࿴ᙪࠊ➲஭ ᏹ᫂ࠊ┿ᔱ ဴᮁࠊ
ຍ⸨ ಟ㞝ࠊ⃝ ᚸࠊ㕥ᮌ೺அࠊ⸨ሯ Ᏺࠊᕝ஭ Ύᙪࠊ
ᐙ ⿱㝯ࠊᇽ㔝 ୺⛯
ᯇᮏ ࿴ᙪࠊᑠཱྀ ከ⨾ኵࠊ⏣୰⚽࿴ࠊ㛗㇂ᕝ ⦾ᙪࠊ
஭ୖ ᜏ୍ࠊ㡲⸨ Ꮥ୍ࠊⓑ஭ ග㞼ࠊ⚄ྜྷ㍤ኵ
Ọ஭ ೺἞
ᇶ♏ࢭ࣑ࢼ࣮
▱⬟࡜ࢥࣥࣆ࣮ࣗࢱ࣮
ඵᮌᗣྐࠊ㮖ᑿ 㝯ࠊ἟ᑿ ṇ⾜ࠊ౗ᮧ ᚨಙࠊྂᓮ ᫭ྖࠊ
Ἑཎ ྜྷఙࠊΎỈ ᫀᖹ
┿ᔱ ဴᮁࠊ☾ᒣ ᝅᮁࠊྂ⃝ Ꮥᘯࠊྜྷ⏣ 㝧୍
Ᏻ⸽ ⰾ㞝ࠊ㇂ཱྀ ṇ㍤ࠊᐙ ⿱㝯ࠊ⟄஭ ┿ᴋ
ຍ⸨ ಟ㞝
ྂ⃝ Ꮥᘯࠊᐊᒇ ⿱బ
୰㇂ ࿴ᙪࠊᇽ㔝 ୺⛯ࠊ㕥ᮌ ೺அ
ᑠཱྀ ከ⨾ኵࠊ⏣୰ ៅ୍㑻ࠊ
᳿ 㔠ᓠࠊ㄃⏣ ⩏ⱥ
☾ᒣ ᝅᮁࠊຍ⸨ 㱟ዲࠊⓑ஭ ග㞼
ඛ➃ᩍ㣴⛉┠ඛ➃ࣅ࣮࣒⛉Ꮫ
ᑓ㛛ᇶ♏ᩍ⫱ ໬Ꮫᴫㄽ
⛉┠
໬Ꮫせㄽ
ศᏊ໬Ꮫ $
ᇶ♏᭷ᶵ໬Ꮫ
≀⌮Ꮫᴫㄽ ,
㟁☢ẼᏛ ,
⇕Ꮫ࣭⤫ィຊᏛせㄽ
㸲㸬ᅜ㝿஺ὶ
㸯㸧άື≧ἣ
ᙜ◊✲ᡤ࡛ࡣࠊᅜ㝿஺ὶࡢ᥎㐍ࡀ◊✲ᡤࡢάື࡟࡜ࡗ࡚ࡦ࡜ࡘࡢ㔜せ࡞せᅉ࡛࠶ࡿ࡜࠸࠺ㄆ㆑࡟ࡓ
ࡗ࡚ࠊᖹᡂ㸰ᖺ࠿ࡽᅜ㝿஺ὶ᥎㐍ጤဨ఍ࢆタ⨨ࡋࡓࠋጤဨ఍ࡣࠊᡤ㛗ࠊ๪ᡤ㛗➼ᙺဨ఍ᵓᡂဨ
ࡀࡘ࡜ࡵ࡚࠾ࡾࠊᇳ⾜㒊ࡀᅜ㝿஺ὶࡢ᥎㐍࡟✚ᴟⓗ࡟㛵୚ࡋ࡚࠸ࡿࠋ
ᙜ◊✲ᡤࡣࠊእᅜ◊✲ᶵ㛵࡜Ꮫ⾡஺ὶ༠ᐃࢆ⤖ࢇ࡛࠾ࡾࠊࢩ࣏ࣥࢪ࣒࣭࢘ㅮ⩏ࡢᐇ᪋ࠊ◊✲⪅➼ࡢ
஺ὶࠊ᝟ሗ஺᥮࡞࡝ࢆ⾜ࡗ࡚࠸ࡿࠋ⏘◊࡟࠾ࡅࡿᖹᡂ ᖺᗘࡢࠊ༠ᐃ⥾⤖ᶵ㛵ࡣ௨ୗࡢ࡜࠾ࡾ࡛࠶
ࡿࠋ
㸦ྜィ ᶵ㛵㸸ᙜ◊✲ᡤ⫋ဨࡀࢥࣥࢱࢡࢺࣃ࣮ࢯࣥࢆࡘ࡜ࡵࡿ኱Ꮫ㛫༠ᐃࡶྵࡴ㸧
ᅜྡ
ࢻ࢖ࢶ
㡑ᅜ
ࢻ࢖ࢶ
◊✲ᶵ㛵ྡ
⥾⤖᪥
࣐ࢢࢹࣈࣝࢢ࣭࢜ࢵࢺ࣮ࣇ࢛ࣥࢤ࣮ࣜࢵࢡ኱Ꮫ⮬↛⛉Ꮫ㒊
ᖹᡂ㹼
㔩៞኱Ꮫᰯᇶ♏⛉Ꮫ◊✲ᡤ
ᖹᡂ 㹼
࣮ࣘࣜࢵࣄ◊✲ࢭࣥࢱ࣮
ᖹᡂ 㹼
― 23 ―
࢖ࢠࣜࢫ
ࣘࢽࣂ࣮ࢩࢸ࢕࢝ࣞࢵࢪࣟࣥࢻࣥ
ᖹᡂ 㹼
㡑ᅜ
㔩ᒣᅜ❧኱Ꮫᰯ⮬↛⛉Ꮫ኱Ꮫ
ᖹᡂ 㹼
㡑ᅜ
₎㝧኱Ꮫᰯ
ྎ‴
ᅜ❧ྎ‴኱Ꮫ
ࣇࣛࣥࢫ
ࢻ࢖ࢶ
ᖹᡂ 㹼
㸦+㹼኱Ꮫ㛫༠ᐃ㸧
ᖹᡂ 㹼
㸦+㹼኱Ꮫ㛫༠ᐃ㸧
ࣇࣛࣥࢫᅜ❧⛉Ꮫ◊✲ࢭࣥࢱ࣮
࢔࣮࣊ࣥᕤ⛉኱Ꮫ᭷ᶵ໬Ꮫ◊✲ᡤ
ᖹᡂ 㹼
㸦኱Ꮫ㛫༠ᐃ㸧
ᖹᡂ 㹼
㸦+㹼኱Ꮫ㛫༠ᐃ㸧
୰ᅜ
໭ி኱Ꮫ᝟ሗ⛉Ꮫᢏ⾡Ꮫ㝔
ᖹᡂ 㹼
㡑ᅜ
ᛅ༡ᅜ❧኱Ꮫᰯ⮬↛⛉Ꮫ኱Ꮫ
ᖹᡂ 㹼
ྎ‴
ᅜ❧ྎ‴ᖌ⠊኱Ꮫ⌮Ꮫ㒊
ᖹᡂ 㹼
ࢪࣗࢿ࣮ࣈ኱Ꮫ⌮Ꮫ㒊
ᖹᡂ 㹼
ෆⵚྂᖌ⠊኱Ꮫ໬Ꮫ࣭⎔ቃ⛉ᏛᏛ㝔
ᖹᡂ 㹼
ࢫ࢖ࢫ
୰ᅜ
ࢻ࢖ࢶ
㡑ᅜ
ᖹᡂ 㹼
࢔࢘ࢢࢫࣈࣝࢢ኱Ꮫ
኱Ꮫ㛫༠ᐃ
㧗㯇኱Ꮫᰯ⛉Ꮫᢏ⾡኱Ꮫ
ᖹᡂ 㹼
࢖ࣥࢻᕤ⛉኱Ꮫࢹ࣮ࣜᰯ⏘ᴗ⛉Ꮫ◊✲ᡤ
ᖹᡂ 㹼
㡑ᅜ
᭄ᅬ኱Ꮫ჆Ἠࣂ࢖࢜ࢼࣀ◊✲ᡤ
ᖹᡂ 㹼
㡑ᅜ
ᾆ㡯ᕤ⛉኱Ꮫᰯ⎔ቃᕤᏛ㒊໬ᏛᕤᏛ⛉
ᖹᡂ 㹼
࢖ࣥࢻ
ࣇ࢕ࣜࣆࣥ ࢹ࣭࣭ࣛࢧ࣮ࣝ኱Ꮫࢥࣥࣆ࣮ࣗࢱ⛉Ꮫ㒊
㡑ᅜ
ᖹᡂ 㹼
㡑ᅜඛ➃⛉Ꮫᢏ⾡኱Ꮫ໬Ꮫ⛉
ᖹᡂ 㹼
࢚ࢪࣉࢺ
࢔ࢩ࣮ࣗࢺ኱Ꮫ⌮Ꮫ㒊
ᖹᡂ 㹼
࣋ࣝࢠ࣮
ỗ኱Ꮫ࣐࢖ࢡ࢚ࣟࣞࢡࢺࣟࢽࢡࢫࢭࣥࢱ࣮
ࣇࣛࣥࢫ
࣎ࣝࢻ࣮➨㸯኱Ꮫ
ࢻ࢖ࢶ
ᖹᡂ 㹼
㸦+㹼኱Ꮫ㛫༠ᐃ㸧
ᖹᡂ 㸦㸧㹼
㸦኱Ꮫ㛫༠ᐃ㸧
ࣅ࣮ࣞࣇ࢙ࣝࢺ኱Ꮫ໬Ꮫ⛉
ᖹᡂ 㸦㸧㹼
࣑ࢿࢯࢱ኱Ꮫࣂ࢖࢜ࢸࢡࣀࣟࢪ࣮◊✲ᡤ
ᖹᡂ 㸦㸧㹼
㡑ᅜ
㡑ᅜ❔ᴗᢏ⾡㝔
ᖹᡂ 㸦㸧㹼
㡑ᅜ
㡑ᅜཎᏊຊ◊✲ᡤ㸭㧗ᗘᨺᑕ⥺ᢏ⾡◊✲ᡤ
ᖹᡂ 㸦㸧㹼
࢔࣓ࣜ࢝
ᙜ◊✲ᡤ࡟ᡤᒓࡍࡿእᅜேࡣࠊྜィ ྡ࡛ࠊෆヂࡣࠊ෸ᩍᤵ㸦≉௵෸ᩍᤵᖖ໅ྵࡴ㸧 ྡࠊ≉௵ㅮ
ᖌ㸦ᖖ໅㸧 ྡࠊຓᩍ㸦≉௵ຓᩍ㸦ᖖ໅㸧ྵࡴ㸧 ྡࠊ≉௵◊✲ဨ㸦ᖖ໅㸧 ྡࠊ≉௵ᢏ⾡⫋ဨ ྡࠊ㠀
ᖖ໅ᩍ⫋ဨ ྡࠊ኱Ꮫ㝔༤ኈᚋᮇㄢ⛬ ྡࠊ༤ኈ๓ᮇㄢ⛬ ྡࠊ≉ู◊✲⏕ ྡࠊ◊✲⏕ ྡ࡛࠶
ࡿࠋᅜูࡣḟࡢ࡜࠾ࡾ࡛࠶ࡿࠋ
୰ᅜ㸦㸧ࠊ㡑ᅜ㸦㸧ࠊࢱ࢖㸦㸧ࠊ࢖ࣥࢻࢿࢩ࢔㸦㸧ࠊࣂࣥࢢࣛࢹࢩࣗ㸦㸧ࠊ࢖ࣥࢻࠊࣇࣛࣥࢫ㸦㸧ࠊ
― 24 ―
࢜ࣛࣥࢲࠊ࣋ࢺࢼ࣒㸦㸧ࠊࣟࢩ࢔㸦㸧ࠊྎ‴ࠊࣇ࢕ࣜࣆࣥ㸦㸧ࠊ࣓࢟ࢩࢥࠊ࣐࣮ࣞࢩ࢔㸦㸧ࠊ
࢚ࢪࣉࢺ㸦㸧ࠊ࢔࣓ࣜ࢝㸦㸯㸧ࠊࢥࢫࢱࣜ࢝ࠊࢺࣝࢥࠊ࢖ࢠࣜࢫࠊ
㸰㸧ᅜእ࡜ࡢ◊✲⪅ ᮶㸦ᖹᡂ ᖺᗘ㸧
◊✲⪅ࡢᾏእὴ㐵ࡣࠊྜィ ௳࡛࠶ࡗࡓࠋゼၥඛࡣࠊ࢔ࢪ࢔ࠊ໭⡿ࠊ࣮ࣚࣟࢵࣃࠊ࢜ࢭ࢔ࢽ࢔ࠊ
୰ᮾ࡞࡝ከᒱ࡟Ώࡗ࡚࠸ࡿࠋ
ᅜእ࠿ࡽᣍ࡬࠸ࡋࡓ◊✲⪅ࡣྜィ ྡ࡛࠶ࡾࠊෆヂࡣḟࡢ࡜࠾ࡾ࡛࠶ࡿࠋ
࢔࣓ࣜ࢝㸦㸧ࠊ୰ᅜࠊ㡑ᅜ㸦㸧ࠊࢱ࢖ࠊ㤶 ࠊࢫࣟࣂ࢟࢔ࠊ࢖ࢠࣜࢫࠊࢻ࢖ࢶࠊ
ࣇࣛࣥࢫ㸦㸧ࠊ࢖ࢱࣜ࢔㸦㸧ࠊ࢖ࣥࢻ㸦㸧ࠊࢫ࢖ࢫࠊ࢜ࣛࣥࢲࠊྎ‴
㸳㸬⏘ᴗ⏺࡜ࡢ஺ὶ
ᙜ◊✲ᡤ࡜⏘ᴗ⏺࡜ࡢ஺ὶࡣࠊྛᩍဨ࡟ࡼࡗ࡚ඹྠ◊✲ࠊཷク◊✲ࠊᢏ⾡┦ㄯ࡞࡝ࢆ㏻ࡌ࡚ಶู࡟ά
Ⓨ࡟⾜ࢃࢀ࡚࠸ࡿࠋᖹᡂ ᖺᗘ࠿ࡽࡣ⤌⧊ⓗ࡟ࡶ◊✲ᡤ࡜ࡋ࡚ᐃᮇⓗ࡞఍ྜ࡛࠶ࡿࠕ⏘◊ࢸࢡࣀࢧࣟ
ࣥࠖࢆ㛤ദࡋࠊㅮ₇ࠊぢᏛ࡜஺ὶ఍ࢆ୰ᚰ࡟௻ᴗࡢ⤒Ⴀ⪅ࠊ◊✲⪅ࠊᢏ⾡⪅ࡢ᪉ࠎ࡜⏘◊◊✲⪅࡜ࡢ஺
ὶࢆᅗࡗ࡚࠸ࡿࠋᖹᡂ ᖺᗘࡣ ᅇࡢᐃᮇ఍ྜࢆ㛤ദࡋࡓࠋ◊✲ᡂᯝࢆᗈࡃヲࡋࡃ▱ࡗ࡚ࡶࡽ࠺࡜ྠ
᫬࡟⏘◊ഃࡶ⏘ᴗ⏺ࡢᢪ࠼࡚࠸ࡿၥ㢟ࢆ▱ࡾࠊ◊✲ࢸ࣮࣐ࡢⓎ᥀࡟ᙺ❧࡚ࡼ࠺࡜࠸࠺㊃᪨ࡢࡶ࡜ࠊ⥅⥆
ⓗ࡞஺ὶࡢሙ࡜ࡋ࡚ẖᅇከᩘࡢཧຍ⪅ࡀ࠶ࡾࠊάⓎ࡟᝟ሗࠊពぢࡢ஺᥮ࢆ⾜ࡗ࡚࠸ࡿࠋࡉࡽ࡟ᖹᡂ ᖺᗘ࠿ࡽࡣࠊᙜ◊✲ᡤࡢಶูࡢᢏ⾡ࢩ࣮ࢬࢆ㛤♧ࡋࠊ㛵ᚰࡢ࠶ࡿ௻ᴗ࡟ࡼࡿ఍ဨไࡢ◊✲఍ࢆ⤌⧊ࡋ࡚
஦ᴗ໬ࢆ┠ᣦࡍ┠ⓗ࡛ࠕ᪂⏘ᴗ๰㐀◊✲఍ࠖࢆタ⨨ࡋάືࢆ⾜ࡗ࡚࠸ࡿࠋᖹᡂ ᖺᗘࡣ༙ᑟయ᪂つ໬
Ꮫࣉࣟࢭࢫ◊✲఍࡜ࣉࣜࣥࢸࢵࢻ࣭࢚ࣞࢡࢺࣟࢽࢡࢫ◊✲఍ࢆࡑࢀࡒࢀ ᅇ࡜ ᅇ㛤ദࡋࡓࠋࡇࢀࡽࡢ
஦ᴗࡣࠊ⏘◊ࡢ⏘Ꮫ㐃ᦠᨭ᥼⤌⧊࡛࠶ࡿ୍⯡㈈ᅋἲே኱㜰኱Ꮫ⏘ᴗ⛉Ꮫ◊✲༠఍࡜ࡢඹྠ࡛㛤ദࡋ࡚࠸
ࡿࠋ
࠙⏘◊ࢸࢡࣀࢧࣟࣥࠚ
఍ྜ
㛤ദ᪥
➨㸯ᅇ ᖹᡂ ᖺ ᭶ ᪥
➨㸰ᅇ ᖹᡂ ᖺ ᭶ ᪥
➨㸱ᅇ ᖹᡂ ᖺ ᭶ ᪥
➨㸲ᅇ ᖹᡂ ᖺ ᭶ ᪥
࠙᪂⏘ᴗ๰㐀◊✲఍ࠚ
◊✲఍
༙ᑟయ᪂つ໬Ꮫࣉࣟࢭࢫ◊
✲఍
ࣉࣜࣥࢸࢵࢻ࣭࢚ࣞࢡࢺࣟࢽ
ࢡࢫ◊✲఍
఍ྜ
➨㸯ᅇ
➨㸰ᅇ
➨㸱ᅇ
➨㸯ᅇ
➨㸰ᅇ
➨㸱ᅇ
ࢸ࣮࣐
ࠕ⏘ᴗ⛉Ꮫࡢ᪂ࡓ࡞ᒎ㛤㸫Ᏻ඲࣭Ᏻᚰࢆᨭ࠼ࡿ㸫ࠖ
ࠕ኱Ꮫᩍᤵࡀㄒࡿᮍ᮶ࢆ㛤ࡃ᪂⛉Ꮫᢏ⾡ࠖ
ࠕᮍ᮶ࢆᢸ࠺⏘ᴗ⛉Ꮫࡢ㌍㐍ࢆ┠ᣦࡋ࡚ࠖ
ࠕ♫఍ࢆኚ࠼ࡿ᪂ᮦᩱࠖ
㛤ദ᪥
ᖹᡂ ᖺ ᭶ ᪥
ᖹᡂ ᖺ ᭶ ᪥
ᖹᡂ ᖺ ᭶ ᪥
ᖹᡂ ᖺ ᭶ ᪥
ᖹᡂ ᖺ ᭶ ᪥
ᖹᡂ ᖺ ᭶ ᪥
➨㸲ᅇ ᖹᡂ ᖺ ᭶ ᪥
― 25 ―
఍ሙ
⏘ᴗ⛉Ꮫ◊✲ᡤ
⏘ᴗ⛉Ꮫ◊✲ᡤ
⏘ᴗ⛉Ꮫ◊✲ᡤ
⏘ᴗ⛉Ꮫ◊✲ᡤ
ᮾி኱Ꮫ
኱㜰኱Ꮫ୰அᓥࢭࣥࢱ࣮
ᅜ❧࢜ࣜࣥࣆࢵࢡグᛕ㟷ᑡᖺ⥲ྜ
ࢭࣥࢱ࣮
㸴㸬ࡲ࡜ࡵㄢ㢟࡜ᒎᮃ
㸯㸧⤌⧊࣭㐠Ⴀ
ᙜ◊✲ᡤࡣࠊᖹᡂ ᖺ ᭶ ᪥࡟ᨵ⤌ࢆ⾜࠸ࠊ ᑓ௵◊✲ศ㔝ࢆࠊࡑࢀࡒࢀ㸵ศ㔝ࡢ➨㸯◊✲㒊
㛛㸦᝟ሗ࣭㔞Ꮚ⛉Ꮫ⣔㸧
ࠊ➨㸰◊✲㒊㛛㸦ᮦᩱ࣭ࣅ࣮࣒⛉Ꮫ⣔㸧ࠊ➨㸱◊✲㒊㛛㸦⏕య࣭ศᏊ⛉Ꮫ⣔㸧
࡜ࠊ㸴ᑓ௵◊✲ศ㔝࠿ࡽ࡞ࡿ⏘ᴗ⛉Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮࡟෌⦅ࡋࡓࠋ᪂ࡓ࡟ࠊ⏘ᴗ⛉Ꮫ㐃ᦠ
ᩍ⫱᥎㐍ࢭࣥࢱ࣮ࠊᅜ㝿ඹྠ◊✲ࢭࣥࢱ࣮ࢆタࡅࠊᅜ㝿ඹྠ◊✲ࢭࣥࢱ࣮ࡢୗ࡟ࡣᅜ㝿㐃ᦠ◊✲ࣛ࣎
ࡢタ⨨ࢆ㐍ࡵࠊ᪤࡟ⱥᅜࠊ୰ᅜࠊ㡑ᅜࠊࣇ࢕ࣜࣆ࣭ࣥࢻ࢖ࢶࡢ㸵኱Ꮫ࡜ࡢ㛫࡛ᅜ㝿㐃ᦠ◊✲ࣛ࣎ࡀタ
⨨ࡉࢀ࡚࠸ࡿࠋᮦᩱゎᯒࢭࣥࢱ࣮࡜㟁Ꮚ㢧ᚤ㙾ᐊࢆ⤫ྜࡋࠊ᝟ሗࡸ⏕యࡢゎᯒࡶྵࡴ⥲ྜゎᯒࢭࣥࢱ
࣮࡬࡜ᣑ඘ࡍࡿ࡜࡜ࡶ࡟ࠊᖹᡂ ᖺᗘࡢ⿵ṇண⟬࡟ࡼࡾࠊ㉁㔞ศᯒ⿦⨨ࠊ105 ⿦⨨ࠊ; ⥺ᅇᢡ⿦⨨➼
ࡀ୍᪂ࡉࢀࠊ⏕≀⣔㸱ḟඖࢺࣔࢢࣛࣇ࢕࣮㟁Ꮚ㢧ᚤ㙾ࡀ᪂ࡓ࡟タ⨨ࡉࢀࡿ࡞࡝ࠊ㣕㌍ⓗ࡟タഛࡀྥୖ
ࡋࡓࠋࡲࡓࠊ㔞Ꮚࣅ࣮࣒ᐇ㦂ᐊࢆࢼࣀࢸࢡࢭࣥࢱ࣮࠿ࡽ⊂❧ࡉࡏࠊ㔞Ꮚࣅ࣮࣒⛉Ꮫ◊✲᪋タ࡜ࡋ࡚ࠊ
ඹྠ◊✲ࡢ฼౽ᛶࢆྥୖࡉࡏࡓࠋ
ᨵ⤌࡟ࡼࡾ⏘◊ࡣࡍ࡭࡚ࡢᑓ௵◊✲ᐊࡀᩍᤵ࣭෸ᩍᤵ࣭ຓᩍ㸯㸸㸯㸸㸰ࡢయไ࡟෌⦅ࡉࢀࡓࠋࡇࡢ
ࡼ࠺࡞ࣇࣝࢧ࢖ࢬ◊✲ᐊไࡣࠊ◊✲ᡤ࡟࠾ࡅࡿୡ⏺ⓗࣞ࣋ࣝࡢ◊✲㐙⾜࡟ࡣ኱ኚ᭷ຠ࡞యไ࡛࠶ࡿࡀࠊ
୍᪉࡛ࠊ᭷⬟࡞ⱝᡭࡢ⊂❧ࡀ㐜ࢀࡿၥ㢟ࡀ࠶ࡿࠋࡇࢀࢆゎỴࡍࡿࡓࡵ࡟ࠊᡤෆබເ㑅ᢤ࡟ࡼࡾඃ⚽࡞
ຓᩍࢆ௵ᮇ௜ࡁ෸ᩍᤵ࡟Ⓩ⏝ࡋࠊ⊂❧ࡋࡓ◊✲ᐊ࣭ண⟬࣭ࢫࢱࢵࣇࢆ㓄⨨ࡍࡿ≉ูࣉࣟࢪ࢙ࢡࢺ◊✲
㒊㛛ࢆᖹᡂ ᖺᗘ࡟タ⨨ࡋࠊ⌧ᅾ㸱◊✲ศ㔝ࡀάືࡋ࡚࠸ࡿࠋ
ᖹᡂ ᖺ ᭶࡟ࡣࠊ㜰኱ึࡢ͆,QGXVWU\RQ&DPSXV͇ࢆᐇ⌧ࡍࡿࡓࡵࠊ⏘◊࢖࣮ࣥ࢟ࣗ࣋ࢩࣙࣥ
Ჷࡀ❹ᕤࡋࠊ⏘◊ࡢ᪂ࡓ࡞⏘Ꮫ㐃ᦠࡢᣐⅬ࡜ࡋ࡚኱ኚᮇᚅࢆ㞟ࡵ࡚࠸ࡿࠋ࢖࣮ࣥ࢟ࣗ࣋ࢩࣙࣥᲷࢆά
⏝ࡋࡓ⏘Ꮫ㐃ᦠࡢ᥎㐍࡜௻ᴗࣜࢧ࣮ࢳࣃ࣮ࢡࡢ⟶⌮㐠Ⴀࡢࡓࡵࠊ⏘Ꮫ㐃ᦠᐊࢆᙉ໬ࡍࡿ࡜࡜ࡶ࡟ࠊ࢜
࣮ࣉࣥࣛ࣎ࠊᡤෆࣉࣟࢪ࢙ࢡࢺࢫ࣮࣌ࢫ࡜௻ᴗࣞࣥࢱࣝࢫ࣮࣌ࢫࢆ⤫୍ⓗ࡟⟶⌮ࡍࡿࡓࡵࠊࡇࢀࡲ࡛
ࡢ࣮࢜ࣉࣥࣛ࣎⟶⌮ᐊࢆ᪋タ⟶⌮ᐊ࡬࡜ᨵ⦅ࡋࡓࠋ
ᖹᡂ ᖺ ᭶࡟ࡣࠊᡃࡀᅜึࡢ㸳኱Ꮫ㝃⨨◊࡟ࡼࡿ඲ᅜ⦪᩿ࢿࢵࢺ࣮࣡ࢡᆺ◊✲ᣐⅬࡀⓎ㊊ࡋࠊ
⏘◊ࡣࡇࡢᣐⅬᮏ㒊࡜ࡋ࡚㔜㈐ࢆᢸࡗ࡚࠸ࡿࠋ
⏘◊ࡢ㐠Ⴀࡣࠊᩍᤵ࡛ᵓᡂࡉࢀࡿᩍᤵ఍࡜ࠊᡤ㛗ࡢୗ࡟ᙺဨ఍ࢆタ⨨ࡋࠊ㸲ேࡢ๪ᡤ㛗ࡀࡑࢀࡒࢀࠊ
ே஦࣭ປົࠊ◊✲࣭ᅜ㝿ࠊ㈈ົ࣭᪋タࠊᩍ⫱࣭ᗈሗࢆᢸᙜࡋࠊ㎿㏿࡞ពᚿỴᐃ࡜ᰂ㌾࡞㐠Ⴀࢆྍ⬟࡟
ࡋ࡚࠸ࡿࠋࡇࡢ㐠Ⴀࡢㅎၥᶵ㛵࡜ࡋ࡚ࠊእ㒊ࡢ᭷㆑⪅ࢆຍ࠼ࡓ㐠Ⴀ༠㆟఍ࡀタ⨨ࡉࢀຓゝࢆᚓ࡚࠸ࡿࠋ
ࡲࡓࠊᣐⅬᮏ㒊ࡢ㐠ႠࡣࠊᣐⅬᮏ㒊఍㆟ࠊᣐⅬ㐠Ⴀጤဨ఍࣭ඹྠ◊✲᥎㐍ጤဨ఍ࡀ⏘◊࡟タ⨨ࡉࢀ 㝃⨨◊✲ᡤ࡛⥭ᐦ㐃ᦠࡋ㐠Ⴀࡋ࡚࠸ࡿࠋ
㸰㸧◊✲㸦ண⟬࣭タഛ࣭άື㸧
⏘◊ࡣࠊ㺀ᮦᩱ㺁㺂㺀᝟ሗ㺁㺂㺀⏕య㺁ࢆ࣮࣮࢟࣡ࢻ࡟ࠊ᭱ඛ➃ࡢ⛉Ꮫࢆ⏘ᴗ࡟⏕࠿ࡍࡇ࡜ࢆ┠ᣦࡋ࡚ࠊᑓ
㛛ศ㔝ࡢቨࢆ㉺࠼ࡓᏛ㝿⼥ྜ◊✲ࢆᒎ㛤ࡋ࡚࠸ࡿࠋᡤဨಶࠎࡢ◊✲㠃࡟࠾ࡅࡿᐇ⦼ࡣࠊእ㒊㈨㔠⋓ᚓࠊ
ᩥ㒊⛉Ꮫ኱⮧㈹➼ࢆึࡵ࡜ࡍࡿྛ✀ࡢཷ㈹ࠊ≉チฟ㢪➼࡟཯ᫎࡉࢀ࡚࠸ࡿࠋ≉࡟ⱝᡭᩍဨ࡛ࠕࡉࡁࡀ
ࡅࠖࠊ
ࠕⱝᡭ㹑ࠖ࡞࡝࡟᥇ᢥࡉࢀࡿᩘࡀከࡃࠊᩥ㒊⛉Ꮫ኱⮧㈹ⱝᡭ⛉Ꮫ⪅㈹ࡢཷ㈹⪅ࡶከ࠸ࠋ኱Ꮫ㝔⏕
࡛ࠊ᪥ᮏᏛ⾡᣺⯆఍≉ู◊✲ဨ࡟᥇⏝ࡉࢀ࡚࠸ࡿẚ⋡ࡢ㧗࠸ࡇ࡜ࡶ≉➹ࡉࢀࡿࠋࡲࡓࠊ᭱ඛ➃◊✲㛤
Ⓨᨭ᥼ࣉࣟࢢ࣒ࣛ࡟࠾࠸࡚ࡶࠊ඲ᅜ ㄢ㢟㸦㜰኱࡛㸰௳㸧࡟᥇ᢥࡉࢀࡓ࠺ࡕࠊ⏘◊ࡢᕝྜ▱஧≉௵
ᩍᤵᖖ໅ࢆ࣮ࣜࢲ࣮࡜ࡍࡿࠕ㠉᪂ࢼࣀࣂ࢖࢜ࢹࣂ࢖ࢫࡢ㛤Ⓨ◊✲ࠖࣉࣟࢪ࢙ࢡࢺࡀ᥇ᢥࡉࢀ࡚࠸ࡿࠋ
ࡉࡽ࡟ࠊᡤ඲య࡜ࡋ࡚ࡶࠊᖹᡂ ᖺ࡟඲ᅜ࡟ඛ㥑ࡅ࡚⏘ᴗ⛉Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮ࢆタ⨨ࡋࠊ
ᖹᡂ ᖺᗘ࡟ࡣࢼࣀࢸࢡࣀࣟࢪ࣮タഛ౪⏝ᣐⅬ࡞࡝ࡶᩚഛࡉࢀࠊ᪥ᮏࡢࢼࣀࢧ࢖࢚ࣥࢫ◊✲ࡢ୰ᚰ
ࡢ୍ࡘ࡜࡞ࡗ࡚࠸ࡿࠋᖹᡂ ᖺᗘ࡟ᮾ໭኱Ꮫከඖ≀㉁⛉Ꮫ◊✲ᡤ࡜ࡢ㛫࡛ࠊ᪂⏘ᴗ๰㐀≀㉁ᇶ┙ᢏ
⾡◊✲ࢭࣥࢱ࣮ࢆタ⨨ࠊࡉࡽ࡟ᖹᡂ ᖺᗘ࡟ࡣࠊ໭኱㟁Ꮚ◊ࠊᮾᕤ኱㈨※◊ࢆຍ࠼࡚㸲኱Ꮫ㝃⨨◊
― 26 ―
✲ᡤ࢔ࣛ࢖࢔ࣥࢫࢆᙧᡂࡋࠊ㝃⨨◊✲ᡤ㛫㐃ᦠࢆ᥎㐍ࡋࡓࠋࡑࡢᐇ⦼ࡀㄆࡵࡽࢀࠊᖹᡂ ᖺᗘ࡟ࡣ
ୖグ㸲◊✲ᡤ࡟஑኱ඛᑟ◊ࢆຍ࠼ࡓ㸳㝃⨨◊✲ᡤ㛫㐃ᦠࠕࢼࣀ࡜࣐ࢡࣟࢆࡘ࡞ࡄ≀㉁ࢹࣂ࢖ࢫ࣭ࢩࢫ
ࢸ࣒๰〇ᡓ␎ࣉࣟࢪ࢙ࢡࢺࠖࡀⓎ㊊ࡋࡓࠋ
◊✲⎔ቃࡢᨵၿ࡟ࡘ࠸࡚ࡣࠊ➨஧◊✲Ჷᖹᡂ ᖺᗘࠊࢼࣀࢸࢡࣀࣟࢪ࣮⥲ྜ◊✲Ჷᖹᡂ ᖺ
ᗘࡢ❹ᕤࠊ➨୍◊✲Ჷࡢᨵಟ㸦ᖹᡂ ᖺᗘᮎ㸧ࠊ⟶⌮Ჷࡢᨵಟ࡜⏘Ꮫ㐃ᦠࡢ᪂ࡓ࡞ᣐⅬ࡜ࡋ࡚࢖ࣥ
࣮࢟ࣗ࣋ࢩࣙࣥᲷ㸦ᖹᡂ ᖺᗘ㸧ࡀ❹ᕤࡋࠊᖹᡂ ᖺᗘ࡟ࡣඹ㏻ᐇ㦂Ჷࡢ⪏㟈ᨵಟࠊࢥࣂࣝࢺᲷࡢ
ᨵಟࠊ⏘◊࡬ࡢ࢔ࣉ࣮ࣟࢳࡀ㛤ᨺⓗ࡟ࣜࢽ࣮ࣗ࢔ࣝࡉࢀࡓࠋ
⏘◊ࡢタഛࡣࠊ ᖺᗘ⿵ṇண⟬࡟࠾࠸࡚ࠊ⥲ྜゎᯒࢭࣥࢱ࣮࡟᭱ඛ➃ゎᯒᶵჾࡀᑟධࡉࢀࡓࡢ࡟ຍ
࠼࡚ࠊࠕపⅣ⣲♫఍ᵓ⠏࡟ྥࡅࡓ◊✲ᇶ┙ࢿࢵࢺ࣮࣡ࢡᩚഛ஦ᴗࠖࡀ᥇ᢥࡉࢀࠊࢼࣀࢸࢡࣀࣟࢪ࣮᭱
ඛ➃ᶵჾࡸ㧗ᛶ⬟㟁Ꮚ㢧ᚤ㙾ࢆタ⨨ࠊᖹᡂ ᖺᗘ࡟ࡣᙉຊⷧ⭷ X ⥺ᅇᯒ⿦⨨ࠊᖹᡂ 25 ᖺᗘ࡟ࡣࢼࣀ
ࢸࢡࣀࣟࢪ࣮タഛ౪⏝ᣐⅬ࡟㞟᮰࢖࢜ࣥࣅ࣮࣒⿦⨨ࡸࢫࣃࢵࢱ⿦⨨➼ࡀ᪂ࡓ࡟タ⨨ࡉࢀࠊ㣕㌍ⓗ࡞ᣑ
඘ࡀᐇ⌧ࡋࡓࠋ
㸱㸧ᩍ⫱
ᙜ◊✲ᡤࡢᩍဨ㝕ࡣࠊ⌮ࠊᕤࠊ㎰ࠊ⸆ࠊᇶᕤ࡜ࣂ࢚ࣛࢸ࢕࣮࡟ᐩࢇࡔᩍဨࡢࡳ࡞ࡽࡎࠊ⏘ᴗ⏺ࡢ◊
✲⪅ࡢ༠ຊࡶᚓ࡚࠸ࡿࡓࡵࠊᏛ㝿ⓗࠊᑓ㛛ⓗ࡞ᩍ⫱ࡀ⾜ࢃࢀ࡚࠸ࡿࠋྛᩍဨࡣ◊✲⛉ࡢᩍ⫱ࡸ඲Ꮫඹ
㏻ᩍ⫱࡟ࡶ༠ຊࡍࡿ࡜࡜ࡶ࡟ࠊᕤᏛ◊✲⛉⎔ቃ࣭࢚ࢿࣝࢠ࣮ᕤᏛᑓᨷࡢ༠ຊࢆᚓ࡚ࠊࠕࢼࣀᕤᏛࠖࡢ
㞟୰ㅮ⩏ࢆ⏘◊⊂⮬ࡢ኱Ꮫ㝔ࣉࣟࢢ࣒ࣛ࡜ࡋ࡚ᐇ᪋ࡋ࡚࠸ࡿࠋᏛ⏕࡟࠾࠸࡚ࡣࠊᏛ㒊⏕ࠊ኱Ꮫ㝔⏕⣙
ྡࡀ ࡘᒇ᰿ࡢୗ࡛◊✲ࠊຮᏛ࡟ບࢇ࡛࠸ࡿࠋ≉ᚩⓗ࡞ࡢࡣࠊ⌮ᏛࠊᕤᏛࠊᇶ♏ᕤᏛࠊ⸆Ꮫࠊ⏕
࿨ᶵ⬟ࠊ᝟ሗ⛉Ꮫ࡞࡝ᵝࠎ࡞ศ㔝ࡢᏛ⏕ࢆཷࡅධࢀ࡚࠸ࡿࡇ࡜࡛࠶ࡾࠊᯟ࡟࡜ࡽࢃࢀ࡞࠸⮬⏤࡞Ⓨ
᝿࣭ᛮ⪃ࢆ㣴࠺࡜ඹ࡟ࠊ◊✲ࡢ⌧ሙ࡟࠾ࡅࡿ኱Ꮫ㝔ᩍ⫱ࢆ㔜どࡋ࡚࠸ࡿࠋࡲࡓࠊ5$ ࢆཷࡅධࢀࠊ࣏ࢫ
ࢻࢡ᥇⏝ࡶᖺࠎቑ࠼ࠊ㝔⏕࡜ࡋ࡚◊✲࡟᭦࡟ᐦ╔࡛ࡁࡿయไ࡜࡞ࡗ࡚࠸ࡿࠋ
ୡ⏺࡛ά㌍࡛ࡁࡿ◊✲⪅⫱ᡂࡢࡓࡵࠊᅜ㝿Ꮫ఍ฟᖍ᥼ຓࡸⴭྡእᅜேࡢᣍᚅࢭ࣑ࢼ࣮ࠊᅜ㝿ࢩ࣏ࣥ
ࢪ࣒࢘࡞࡝ࢆ㏻ࡌ࡚㝔⏕ᩍ⫱ࡢᅜ㝿໬ࢆᅗࡿ࡜࡜ࡶ࡟ࠊᖹᡂ ᖺ࡟ᩍ⫱㈉⊩άືࢆ୍ᒙ᥎㐍ࡍࡿࡓ
ࡵࠊ⏘ᴗ⛉Ꮫ㐃ᦠᩍ⫱᥎㐍ࢭࣥࢱ࣮ࢆタ⨨ࡋࡓࠋᐇ㊶ⓗ࡞ሙ࡜ࡋ࡚ࠊᅜ㝿㐃ᦠ◊✲ࣛ࣎ࢆ㏻ࡌࡓᏛ⏕
஺ὶࡸࠊᅜ㝿ᶵ㛵࡛ࡢ࢖ࣥࢱ࣮ࣥࢩࢵࣉࢆ✚ᴟⓗ࡟ᐇ᪋ࡋ࡚࠸ࡿࠋ
㸲㸧♫఍࡜ࡢ㐃ᦠ࣭♫఍㈉⊩
ᖹᡂ ᖺ࡟⏘Ꮫ㐃ᦠᐊࢆタ⨨ࡍࡿ࡜࡜ࡶ࡟ࠊ᪂⏘ᴗ๰ᡂ◊✲㒊㛛ࢆタ⨨ࡋࠊ⏘Ꮫ㐃ᦠ࡟ྲྀࡾ⤌ࢇ࡛
࠸ࡿࠋ
㸦㈈㸧኱㜰኱Ꮫ⏘ᴗ⛉Ꮫ◊✲༠఍ࡣࠊ⏘◊࡜ࡣ⊂❧ࡋ࡚タ⨨ࡉࢀࡓእ㒊ᅋయ࡛࠶ࡿࡀࠊ⏘◊࡜༠
ຊࡋࠊ⏘◊ࢸࢡࣀࢧࣟࣥࠊ᪂⏘ᴗ๰㐀◊✲఍࡞࡝ࡢ⏘Ꮫ㐃ᦠάື࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿࠋ
ᖹᡂ ᖺᗘ࡟❹ᕤࡋࡓ࢖࣮ࣥ࢟ࣗ࣋ࢩࣙࣥᲷ࡟ࡣࠊ௻ᴗࣜࢧ࣮ࢳࣃ࣮ࢡࢆタࡅࠊ௻ᴗࡢࢧࢸࣛ࢖ࢺ
◊✲ᐊ㸦ᖹᡂ ᖺ ᭶⌧ᅾ ♫㸧ࢆㄏ⮴ࡋ࡚ࡉࡽ࡟ᐇ㊶ⓗ࡞⏘ᴗ໬◊✲࡟ྲྀࡾ⤌ࡴయไࢆᩚ࠼ࡓࠋ
ࡇࡇࢆ⯙ྎ࡟ࠊ⏘◊࡜௻ᴗࡢඹྠ◊✲࡟ࡼࡿ࣮࢜ࣉࣥ࢖ࣀ࣮࣋ࢩࣙࣥࢆ┠ᣦࡍࠋ
ᆅᇦ࡬ࡢ㈉⊩άື࡜ࡋ࡚≉➹ࡍ࡭ࡁྲྀࡾ⤌ࡳࡀࠊᢏ⾡ᐊ࡟ࡼࡿࡶࡢ࡙ࡃࡾᩍᐊ࡛࠶ࡾࠊཧຍ⪅ࢆᢳ
㑅࡛ไ㝈ࡍࡿ⛬ࡢேẼ௻⏬࡛࠶ࡿࠋ
㸳㸧ᅜ㝿஺ὶ
እᅜே◊✲⪅ࡢཷࡅධࢀ࡟ຍ࠼ࠊእᅜ◊✲ᶵ㛵࡜Ꮫ⾡஺ὶࢆ⥾⤖ࡋࠊᅜቃࢆ㉺࠼ࡓ஺ὶ࣭᝟ሗ஺᥮
ࢆ⾜ࡗ࡚࠸ࡿࠋᖹᡂ ᖺᗘ࡟ࡣୡ⏺᭱኱ࡢࢼࣀࢸࢡ◊✲ᶵ㛵࡛࠶ࡿ LPHF ࡜ඹྠ◊✲ዎ⣙ࢆ⥾⤖ࡋࠊ
௒ᖺᗘࡶ✚ᴟⓗ࡟ඹྠ◊✲ࡸ◊✲⪅ࡢ஺ὶࢆ⾜ࡗ࡚࠸ࡿࠋẖᖺ ᩘྡࡢእᅜே␃Ꮫ⏕ࢆཷධࢀࡿ࡜
― 27 ―
࡜ࡶ࡟ࠊእᅜே◊✲⪅ࠊእᅜேᐈဨᩍᤵࡀ⏘◊ࡢ◊✲࡟ᦠࢃࡗ࡚࠾ࡾࠊᅜ㝿஺ὶࣃ࣮ࢸ࢕࣮➼࡛␃Ꮫ
⏕ࡢኌࢆ┤᥋཯࡛ᫎࡁࡿሙࡶタࡅ࡚࠸ࡿࠋࡲࡓࠊᙜ◊✲ᡤ୺ദࡢᅜ㝿఍㆟ࢆ㛤ദࡋ࡚࠸ࡿࠋ
⏘ᴗ⛉Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮࡟ࡣᖖ᫬እᅜே◊✲⪅ࢆᣍ⪸ࡍࡿࡓࡵࡢᐈဨᩍᤵࠊ෸ᩍᤵ࣏ࢫ
ࢺࢆ㸰ࡘ⏝ពࡋ࡚࠸ࡿ࡯࠿ࠊᅜ㝿ඹྠ◊✲ࢭࣥࢱ࣮ࢆタ⨨ࡋ࡚⥅⥆ⓗ࡞஺ὶࢆᅗࡗ࡚࠸ࡿࠋ㸴㸫㸦㸯㸧
࡟࠶ࡿ࡜࠾ࡾࠊ㏻ᖖࡢࢭࣥࢱ࣮࡜ࡣ␗࡞ࡾࠊᏛ⾡஺ὶ༠ᐃࢆ⥾⤖ࡋࡓ┦ᡭඛࡢ◊✲ᐊࢆ㐃ᦠ◊✲ࣛ࣎
࡜ࡋ࡚┦஫࡟ཷࡅධࢀࠊ㐃ᦠ◊✲ࣛ࣎ࡢ㞟ྜయ࡜ࡋ࡚ࢭࣥࢱ࣮ࢆᵓᡂࡋ┒ࢇ࡟஺ὶࢆ⾜ࡗ࡚࠸ࡿࠋ
ᖹᡂ ᖺᗘ࡟ࡣ -636 㢌⬻ᚠ⎔ࢆຍ㏿ࡍࡿⱝᡭ◊✲⪅ᡓ␎ⓗᾏእὴ㐵ࣉࣟࢢ࣒ࣛ㸦 ᖺ㛫㸧ࡀ᥇ᢥ
ࡉࢀࠊⱝᡭ◊✲⪅ࡢࢢ࣮ࣟࣂ࣐ࣝ࢖ࣥࢻࡢ⫱ᡂࢆ⾜ࡗ࡚࠸ࡿࠋᖹᡂ ᖺᗘ࡟ࡣ -636 ◊✲ᣐⅬᙧᡂ஦
ᴗ㸦$ඛ➃ᣐⅬᙧᡂᆺ㸧࡟᥇ᢥ㸦 ᖺ㛫ࡢணᐃ㸧
ࠊᖹᡂ ᖺᗘ࡟ࡣ -636 ஧ᅜ㛫஺ὶ஦ᴗ࡟ ௳᥇ᢥࡉ
ࢀࡓࠋ
㸴㸧ࡲ࡜ࡵ
⏘ᴗ⛉Ꮫ◊✲ᡤࡣࠊ᫬௦ࡢኚ໬࡜♫఍ࡢࢽ࣮ࢬ࡟ᛂࡌࡓ◊✲ࡢ᥎㐍࡜㺂㛗ᮇⓗ࡞ࣅࢪࣙࣥ࡟❧ࡗࡓ
ᇶ♏◊✲࣭ᛂ⏝◊✲ࢆ⾜࠺ࠋタ❧ᙜึࡼࡾ⏘ᴗ࡬ࡢ㈉⊩ࢆ┠ᣦࡋࡓ⊂๰ᛶࡢ㧗࠸◊✲ࡀ⾜ࢃࢀ࡚ࡁࡓ
ࡀࠊࡑࡢఏ⤫ࢆཷࡅ⥅ࡂ࡞ࡀࡽࡶࠊࠕᮦᩱࠖࠕ᝟ሗࠖࠕ⏕యࠖࡢ㸱㡿ᇦࢆᇶ♏࡜ࡋࡓᏛ㝿⼥ྜᆺ◊✲ࢆ
᥎㐍ࡋࠊ≉࡟᫬௦ࡢせㄳ࡜ࡋ࡚ࡢ⎔ቃࠊ࢚ࢿࣝࢠ࣮ࠊ་⒪ࠊᏳᚰ࣭Ᏻ඲࡟㛵ࡍࡿ◊✲ㄢ㢟࡟㍈㊊ࢆ⨨
ࡁࠊ◊✲ᡂᯝࢆ⏘ᴗ࡬㑏ඖ࡛ࡁࡿ㐺ᛂ⬟ຊ࡜ࠊ⏘◊⊂⮬ࡢ◊✲ࢆවࡡഛ࠼ࡓ㨩ຊ࠶ࡿ◊✲ᡤࢆ┠ᣦࡋࠊ
ୡ⏺ࢺࢵࣉࣞ࣋ࣝࡢ⥲ྜ⌮ᕤᏛ◊✲ᡤ࡜ࡋ࡚᫬௦ࢆ࣮ࣜࢻࡋ࡚࠸ࡃࠋ
௒ᚋࡶࠊ኱㜰኱Ꮫࡢ୍ဨ࡜ࡋ࡚኱Ꮫ㝔ྛ◊✲⛉࡜ᐦ᥋࡟༠ຊࡋࠊ᪥ᮏ࡜ୡ⏺ࢆ࣮ࣜࢻࡍࡿ୍ὶࡢே
ᮦࢆ⫱ᡂࡍࡿࠋࡲࡓࠊ௻ᴗࣜࢧ࣮ࢳࣃ࣮ࢡ➼ࢆ㏻ࡌ࡚⏘ᴗ⏺࡜ࡢ㐃ᦠࢆᙉ໬ࡋࠊ⏘◊ࡢ◊✲ᡂᯝࢆ✚
ᴟⓗ࡟㛤ᨺࡍࡿ࡜࡜ࡶ࡟ࠊࢿࢵࢺ࣮࣡ࢡᆺඹྠ◊✲ᣐⅬࡢᣐⅬᮏ㒊࡜ࡋ࡚ࠊ඲ᅜ࡛ࣞ࣋ࣝࡢ≀㉁ࢹࣂ
࢖ࢫࡢ◊✲ࢆ᥎㐍ࡍࡿࠋࡲࡓࠊᅜቃࢆ㉺࠼࡚᝟ሗࢆⓎಙࡋࠊୡ⏺ࡢ◊✲⪅࡜ࡢᅜ㝿ඹྠ◊✲ࢆಁ㐍ࡋࠊ
⏘◊Ⓨࡢࢢ࣮ࣟࣂࣝࢫࢱࣥࢲ࣮ࢻࢆ┠ᣦࡍࠋ
௒ᚋࡶࠊከ✀ከᵝ࡞࢚࢟ࢫࣃ࣮ࢺࡀཿᬛࢆ㞟⤖ࡋࠊ▱⾜ྜ୍ࡢ⢭⚄࡛ࠊ⏘ᴗ࡟⏕࠿ࡍ⛉Ꮫࠊฟཱྀࢆ
ぢᤣ࠼ࡓᇶ♏◊✲ࢆ᥎㐍࡛ࡁࡿࡼ࠺ࠊ᪥ࠎ㑌㐍ࡍࡿࠋࡑࢀࡀࠊ⏘ᴗ⛉Ꮫ◊✲ᡤ࡛࠶ࡿࠋ
― 28 ―
㸦ᗈሗᐊ఍㆟ᵓᡂဨ㸧
ጤဨ㛗 㸦ᩍ ᤵ㸧ͤྜྷ⏣ 㝧୍
ጤ ဨ 㸦ᩍ ᤵ ኱ᒾ 㢧
㸦ᩍ ᤵ㸧 ☾ᒣ ᝅᮁ
㸦ᩍ ᤵ㸧 ┿ᔱ ဴᮁ
㸦ᩍ ᤵ㸧ͤᏳ⸽ ⰾ㞝
㸦෸ᩍᤵ㸧 㛗ᑿ ⮳ᡂ
㸦෸ᩍᤵ㸧 ᳿ 㔠ᓠ
㸦෸ᩍᤵ㸧ͤከ᰿ ṇ࿴
㸦෸ᩍᤵ㸧ͤᒸᓥ ಇⱥ
㸦ຓ ᩍ㸧ͤ⚟஭ ೺୍
㸦ຓ ᩍ㸧ͤᮡᒣ ☻ே
㸦ຓ ᩍ㸧 ᵽཱྀ 㞝௓
㸦ຓ ᩍ㸧ͤᶓ⏣ ୍㐨
ィ ࣭᝟ሗࢩࢫࢸ࣒ಀ㛗ͤ┦ཎ ༓ᑜ
㸦ᗈሗᐊဨ㸧ͤዟᮧ ⏤㤶
㸦ᗈሗᐊဨ㸧ͤᯇᮏ ⣖Ꮚ
࢜ࣈࢨ࣮ࣂ࣮㸦⥲ົㄢ㛗 ୰ᕝ ṇ
௻⏬ᐊ㛗ᘯὠ ⚞ᙪ
௻⏬ᐊဨͤす⏣ ᙬ
ͤࡣࠊ⦅㞟ᢸᙜ
㹙㝃㸯㹛ྛ◊✲㒊㛛ࡢ⤌⧊࡜άື
㹙㝃㸰㹛ྛ㝃ᒓ◊✲᪋タ➼ࡢ⤌⧊࡜άື
㹙㝃㸱㹛ඹ㏻᪋タࠊᢏ⾡ᐊࠊ஦ົ㒊ࡢ⤌⧊࡜άື
㹙㝃㸲㹛ྛ◊✲㒊㛛ࠊ㝃ᒓ᪋タ࡟࠾ࡅࡿάືᐇ⦼ࣜࢫࢺ
㸦ὀ㸧ྛ◊✲ศ㔝➼ࡢᡤᒓ⪅࡟ࡘ࠸࡚ࡣࠊᖹᡂ 26 ᖺᗘ࡟ᅾ⡠ࡋࡓ⪅ࢆ඲࡚཰㘓ࡋࡓࠋ
― 29 ―
［ 附１ ］
各研究部門の組織と活動
➨㸯◊✲㒊㛛㸦᝟ሗ࣭㔞Ꮚ⛉Ꮫ⣔㸧
ᴫせ
⭾኱࡞ࢹࢪࢱࣝ᝟ሗࡀୡ⏺୰ࢆ㣕ࡧ஺࠺ࢿࢵࢺ࣮࣡ࢡ᝟ሗ໬♫఍࡟࠾࠸࡚ࠊ㧗ᗘ᝟ሗฎ⌮ࡣ♫఍ࡢ࠶
ࡽࡺࡿ㠃࡛ᚲ㡲࡞ᢏ⾡࡜࡞ࡗ࡚࠸ࡿࠋᮏ◊✲㒊㛛ࡣࠊ᝟ሗ⛉Ꮫ⣔㸦▱㆑⛉Ꮫ◊✲ศ㔝ࠊ」ྜ▱⬟࣓ࢹ࢕
࢔◊✲ศ㔝ࠊ▱⬟࢔࣮࢟ࢸࢡࢳࣕ◊✲ศ㔝ࠊ▱⬟᥎ㄽ◊✲ศ㔝㸧
ࠊ㔞Ꮚ⛉Ꮫ⣔㸦ග࣭㟁Ꮚᮦᩱ◊✲ศ㔝ࠊ
༙ᑟయ㔞Ꮚ⛉Ꮫ◊✲ศ㔝ࠊඛ㐍㟁Ꮚࢹࣂ࢖ࢫ◊✲ศ㔝ࠊࡢ 7 ࡘࡢ◊✲ศ㔝࠿ࡽᵓᡂࡉࢀ࡚࠾ࡾࠊ๓ 4 ◊
✲ศ㔝ࡣ▱⬟᝟ሗฎ⌮ཎ⌮࡜࢔ࣝࢦࣜࢬ࣒࡜࠸࠺ࢯࣇࢺ㠃࠿ࡽࠊࡲࡓᚋ 3 ◊✲ศ㔝ࡣ㧗ᗘ᝟ሗฎ⌮ࡢࡓ
ࡵࡢࢹࣂ࢖ࢫ࡜࠸࠺ࣁ࣮ࢻ㠃࠿ࡽࠊ㧗ᗘ᝟ሗฎ⌮♫఍ࢆᨭ࠼ࡿᇶ┙ᢏ⾡ࡢ☜❧ࢆ┠ᣦࡋ࡚࠸ࡿࠋ๓⪅࡟
ࡘ࠸࡚ࡣࠊே㛫ࡢ▱⬟ࢆ⛉Ꮫࡋࠊ㧗ᗘ࡞▱㆑᝟ሗฎ⌮ᶵ⬟ࢆィ⟬ᶵ࡟௜୚ࡋᗈࡃᕤᏛⓗㅖၥ㢟ࡢゎỴࡸ
▱ⓗάືᨭ᥼඲⯡࡬ᛂ⏝ࡍࡿࡇ࡜ࢆ┠ᣦࡋ࡚࠸ࡿࠋᚋ⪅࡟ࡘ࠸࡚ࡣࠊ⾲㠃≀⌮ࠊ㟁Ꮚ࣭ගศගἲࠊⷧ⭷࣭
⤖ᬗᡂ㛗ࠊ༙ᑟయ≀⌮ࠊ᭷ᶵᮦᩱ࣭⏕యศᏊ࡞࡝ࢆ࣮࣋ࢫ࡜ࡋ࡚ࠊ୺࡜ࡋ࡚༙ᑟయࢆ୰ᚰ࡟ࠊࢼࣀ࣓࣮
ࢺࣝࣞ࣋ࣝࡢᵓ㐀࣭᪂ᮦᩱࡢ๰〇࣭ホ౯࡟㛵ࡍࡿ◊✲ࢆ⾜࠸ࠊ㔞Ꮚᶵ⬟ࢆ฼⏝ࡋࡓ㧗ᛶ⬟⣲Ꮚࡸ᪂ࡋ࠸
ࢭࣥࢧ࣭࣓ࣔࣜ⣲Ꮚࡢᐇ⌧ࢆ┠ᣦࡋ࡚࠸ࡿࠋ
ࡇࢀࡽࡢ◊✲ศ㔝ࡣࠊ஫࠸࡟᭷ᶵⓗ࡟㛵㐃ࡋ࡚ୡ⏺ⓗᡂᯝࢆᣲࡆࡿࡇ࡜ࢆ┠㏵࡜ࡋ࡚◊✲࡟ྲྀࡾ⤌ࢇ
࡛࠸ࡿ࡜ྠ᫬࡟ࠊᡤෆ௚㒊㛛ࡢࡳ࡞ࡽࡎࠊᏛෆእࠊ᭦࡟ࡣᅜෆእࡢ኱Ꮫࠊ◊✲ᶵ㛵ࠊẸ㛫௻ᴗ࡜✚ᴟⓗ
࡟ඹྠ◊✲ࢆᒎ㛤ࡋ࡚࠸ࡿࠋࡲࡓࠊ⌮Ꮫ◊✲⛉㸦≀⌮Ꮫᑓᨷ㸧ࠊᕤᏛ◊✲⛉㸦㟁Ẽ㟁Ꮚ᝟ሗᕤᏛᑓᨷࠊ
ᛂ⏝≀⌮Ꮫᑓᨷ㸧
ࠊᇶ♏ᕤᏛ◊✲⛉㸦≀㉁๰ᡂᑓᨷ㸧
ࠊ࠾ࡼࡧ᝟ሗ⛉Ꮫ◊✲⛉㸦ࢥࣥࣆ࣮ࣗࢱࢧ࢖࢚ࣥࢫ
ᑓᨷࠊ᝟ሗᩘ⌮Ꮫᑓᨷ㸧࠿ࡽ኱Ꮫ㝔Ꮫ⏕ࢆཷࡅධࢀ࡚࠾ࡾࠊ㧗ᗘ࡞▱㆑࡜ᗈ࠸ど㔝ࢆවࡡഛ࠼ࡓ◊✲⪅
ࡢ⫱ᡂࢆ┠ᣦࡋ࡚࠸ࡿࠋ
ᡂᯝ
࣭ᐊ ᙉ☢ᛶ༙ᑟయࢼࣀᵓ㐀ࡢస〇࣭ホ౯࡜༙ᑟయࢫࣆࣥࢺࣟࢽࢡࢫࢹࣂ࢖ࢫᛂ⏝
࣭ࢢࣛࣇ࢙ࣥ࡜ࢼࣀࢳ࣮ࣗࣈࢆ⏝࠸ࡓ㔞Ꮚࢼࣀࢹࣂ࢖ࢫࡢ㛤Ⓨ࡜ࣂ࢖࢜ࢭࣥࢧ࣮ᛂ⏝
࣭㞧㡢࡟㡹೺࡞㡢ኌᑐヰࣟ࣎ࢵࢺࡢ㛤Ⓨࠊᑐヰࢆ㏻ࡌࡓ▱㆑⋓ᚓ
࣭㧗ᐦᗘࣛ࢖ࣥࣃࢱ᳨࣮ࣥฟ࡟ࡼࡿ㧗㏿ືయࡢ 3 ḟඖィ ᡭἲ
࣭ᵓᡂⓗ㐺ᛂ࢖ࣥࢱࣇ࢙࣮ࢫ࡬ࡢࢭࣥࢧ࣮ࡢᑟධࠊ▱ⓗࣘࣅ࢟ࢱࢫࢭࣥࢧ࣮ࢿࢵࢺ࣮࣡ࢡ
࣭㧗ḟඖ」㞧ࢹ࣮ࢱ࠿ࡽࡢ▱㆑Ⓨぢࠊᅉᯝᵓ㐀ゎᯒἲࡢ㛤Ⓨࠊ⤌ྜࡏㄽⓗィ⟬࡟ࡼࡿ▱㆑Ⓨぢ
࣭༢୍ගᏊࣞ࣋ࣝ㠀⥺ᙧ⣲Ꮚࢆ⤖ྜࡋࡓග㔞Ꮚᅇ㊰ࡢᐇ⌧ࠊࢼࣀࣇ࢛ࢺࢽࢡࢫࢹࣂ࢖ࢫࡢ㛤Ⓨ
― 33 ―
㔞Ꮚࢩࢫࢸ࣒๰ᡂ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
≉௵◊✲ဨ
኱Ꮫ㝔Ꮫ⏕
Ꮫ㒊Ꮫ⏕
஦ົ⿵బဨ
኱ᒾ 㢧
㛗㇂ᕝ ⦾ᙪ
Ụᮧ ಟ୍
ᮌᒣ ἞ᶞ
Ⳣ⏣ ዲேࠊฟཎ ೺ኴ㑻ࠊᖹᒣ Ꮥᚿ
ᮌᮧ ோ඘ࠊᩜᓥ ⛸⣖
Ώ㑓 ᫂Ꮚ㸦ᖹᡂ 26 ᖺ 8 ᭶ 16 ᪥᥇⏝㸧
a) ᴫせ
ᮏ◊✲ศ㔝࡛ࡣࠊග࡜㟁Ꮚ࡟ຍ࠼ࢫࣆࣥࡢᣢࡘ㔞ᏊຊᏛⓗᛶ㉁ࢆไᚚࡋ࡚ືసࡍࡿ㔞Ꮚࢹࣂ࢖ࢫࡸࢫ
ࣆࣥࢺࣟࢽࢡࢫࢹࣂ࢖ࢫࡢ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋ༢୍㟁Ꮚࢫࣆࣥࡣ㔞ᏊຊᏛ࡟ᇶ࡙ࡃ㔞Ꮚィ⟬ᶵࢆᐇ⌧ࡍ
ࡿⰋ࠸ೃ⿵࡛࠶ࡿࠋࡑࡇ࡛పḟඖ㔞Ꮚఏᑟ࡜ᚤ⣽ຍᕤᢏ⾡ࢆ⏝࠸࡚ࠊ༢୍㟁Ꮚࢫࣆࣥࢆไᚚࡍࡿ㔞Ꮚࣅ
ࢵࢺ࡞࡝㔞Ꮚ᝟ሗฎ⌮⣲Ꮚࡸ㛗㊥㞳㔞Ꮚ᝟ሗ㏻ಙ࡛୙ྍḞ࡞༢୍ගᏊ࡜㔞Ꮚࢻࢵࢺࡢ୰ࡢ༢୍㟁Ꮚࢫ
ࣆࣥࡢ㛫࡛㔞Ꮚ≧ែࢆኚ᥮ࡍࡿ㔞Ꮚ࢖ࣥࢱ࣮ࣇ࢙࣮ࢫࡢ㛤Ⓨࢆ⾜ࡗ࡚࠸ࡿࠋࡲࡓ㠀☢ᛶ༙ᑟయ࡟☢ᛶయ
ࢆῧຍࡋ࡚☢ᛶࢆⓎ⌧ࡍࡿ☢ᛶ༙ᑟయࡸࠊᙉ☢ᛶయ࠿ࡽ༙ᑟయ࡬ࢫࣆࣥࢆὀධࡋ࡚⏕ࡎࡿࢫࣆࣥὶࡢ◊
✲ࢆ⾜ࡗ࡚࠸ࡿࠋ㧗ရ㉁ᮦᩱࡢ๰〇࠿ࡽホ౯ࠊࡑࡋ࡚⢭ᐦ࡞㔞Ꮚ㍺㏦ ᐃࡲ୍࡛㈏ࡋ࡚⾜࠸ࠊගࠊ㟁Ꮚࠊ
ࢫࣆࣥࡢ⮬⏤ᗘࢆ⮬⏤࡟᧯ࡿ㔞Ꮚࢼࣀᵓ㐀ࡀࡶࡓࡽࡍ᪂ࡋ࠸⌧㇟ࡢⓎぢࢆ┠ᣦࡋ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭InAs ⮬ᕫᙧᡂ㔞Ꮚࢻࢵࢺࡢస〇࡜㔞Ꮚ㍺㏦ࡢ◊✲
InAs ⮬ᕫᙧᡂ㔞Ꮚࢻࢵࢺࡣ኱ࡁ࡞ g ᅉᏊࡸᙉ࠸ࢫࣆࣥ㌶㐨┦஫స⏝ࢆᣢࡕࠊእ㒊☢ሙࢆไᚚࡋ࡞ࡃ࡚
ࡶ㟁ሙ࡛㧗㏿ືస࡛ࡁࡿࢫࣆࣥ㔞Ꮚࣅࢵࢺ࡜ࡋ࡚᭷ᮃ࡞⣔࡛࠶ࡿࠋᅗ 1 ࡢࡼ࠺࡟⾲㠃࡟ᯒฟࡋࡓ⮬ᕫᙧ
ᡂࢻࢵࢺ࡟┤᥋ Ti/Au ࢯ࣮ࢫ࣭ࢻࣞ࢖ࣥ㟁ᴟࢆྲྀࡾ௜ࡅࠊ㔞Ꮚࢻࢵࢺࢺࣛࣥࢪࢫࢱࢆస〇ࡋࡓࠋࡉࡽ࡟
ᶓ᪉ྥ࠿ࡽ㟁ሙࢆ༳ຍࡍࡿࢧ࢖ࢻࢤ࣮ࢺࢆస〇ࡋࡓࠋࡲࡓᇶᯈ࡟ࡣ㧗⃰ᗘ㔠ᒓⓗ GaAs ᒙࡀ࠶ࡾࠊࣂࢵ
ࢡࢤ࣮ࢺ࡜ࡋ࡚ࢻࢵࢺ࡟ᑐ⛠࡞࣏ࢸࣥࢩࣕࣝኚㄪࢆ୚࠼ࠊ୺࡟㟁Ꮚᩘࢆኚ࠼ࡿࠋࡲࡓࡇࢀࡲ࡛ࡢ◊✲࡛
ࢧ࢖ࢻࢤ࣮ࢺ࡟ࡼࡿ㠀ᑐ⛠࡞㟁ሙ࡟ࡼࡾᶓ᪉ྥࡢ㛢ࡌ㎸ࡵ࣏ࢸࣥࢩࣕࣝࢆኚㄪ࡛ࡁࠊ㔞Ꮚࢻࢵࢺࡢᵝࠎ
࡞ࣃ࣓࣮ࣛࢱࢆไᚚ࡛ࡁࡿ᭷ຠ࡞᪉ἲ࡛࠶ࡿࡇ࡜ࡀࢃ࠿ࡗ࡚࠸ࡿࠋࡇࢀࡽࡢ㔞Ꮚࢻࢵࢺࡢప ࡟࠾ࡅࡿ
㔞Ꮚ㍺㏦⌧㇟ࢆ ᐃࡋࡓࠋᅗ 2 ࡣ㔞Ꮚࢻࢵࢺ࡜ࡋ࡚඾ᆺⓗ࡞㟁Ẽఏᑟ࡛࠶ࡿࢡ࣮ࣟࣥࢲ࢖ࣖࣔࣥࢻࢆ♧
ࡋ࡚࠸ࡿࠋࡉࡽ࡟ࢧ࢖ࢻࢤ࣮ࢺ㟁ᅽ࡟ࡼࡾࠊ㔞Ꮚࢻࢵࢺ࡜㟁ᴟࡢ㛫ࡢࢺࣥࢿࣝ⤖ྜࢆไᚚࡍࡿࡇ࡜࡟ᡂ
ຌࡋ࡚࠸ࡿࠋ
3
15
2
10
5
1
0
dISD/dVSD [̭6@
VSG [V]
20
0
-1
VSG =-0.1V
-0.4
0.0
0.2
0.4
VSD [mV]
ᅗ㸯 InAs ⮬ᕫᙧᡂ㔞Ꮚࢻࢵࢺࢺࣛࣥ
ࢪࢫࢱࡢ㟁Ꮚ㢧ᚤ㙾෗┿ࠋ
-0.2
ᅗ㸰 InAs ⮬ᕫᙧᡂ㔞Ꮚࢻࢵࢺࡢࢡ࣮ࣟࣥࢲ࢖ࣖࣔࣥࢻࠋ
ᐃࡣ 0.5K ࡛ࢮࣟ☢ሙࠋ
― 34 ―
Intensity (arb. units)
࣭GaN ࣮࣋ࢫᕼⷧ☢ᛶ༙ᑟయࡢ⤖ᬗᡂ㛗࡜ࢫࣆࣥࢺࣟࢽࢡࢫࢹࣂ࢖ࢫᛂ⏝
༙ᑟయ࡜☢ᛶయ࡜࠸࠺㸰ࡘࡢᛶ㉁ࢆྜࢃࡏᣢࡘᕼⷧ☢ᛶ
༙ᑟయࡣ᪂ࡋ࠸ᶵ⬟ࢆⓎ⌧࡛ࡁࡿᮦᩱ࡜ࡋ࡚ὀ┠ࡉࢀ࡚࠸
4
G5/2 ĺ 6H5/2
ࡿࠋࡇࢀࡲ࡛࡟ࠊ❅໬≀༙ᑟయ࣮࣋ࢫࡢ☢ᛶ༙ᑟయ GaCrNࠊ
GaGdN ࡞࡝ࢆࣉࣛࢬ࣐ᨭ᥼ศᏊ࢚ࣆࢱ࢟ࢩ࣮ἲ࡛ᡂ㛗ࡋࠊᙉ
☢ᛶయࡢ≉ᚩ࡛࠶ࡿࣄࢫࢸࣜࢩࢫࡀ☢໬᭤⥺࡟ᐊ ࡛ࡶ⌧
4G
6
5/2 ĺ H7/2
ࢀࡿࡇ࡜࡞࡝ࢆሗ࿌ࡋ࡚ࡁࡓࠋ௒ᖺᗘࡣࠊn ᆺᙉ☢ᛶ༙ᑟయ
๰ᡂࢆ┠ᣦࡋ࡚ࠊ
GaN(0001)ࢸࣥࣉ࣮ࣞࢺୖ࡛ࡢ Sm ῧຍ GaN
4G
6
5/2 ĺ H9/2
ⷧ⭷ࡢᡂ㛗ࢆ⾜࠸ࠊࡑࡢ⤖ᬗᵓ㐀ࠊගᏛ≉ᛶ࡞ࡽࡧ࡟☢Ẽ≉
ᛶࡢホ౯ࢆ⾜ࡗࡓࠋࡑࡢ⤖ᯝࠊc ㍈᪉ྥࡢ᱁Ꮚᐃᩘࡀ Sm ῧ
ຍ㔞࡟ẚ౛ࡋ࡚኱ࡁࡃ࡞ࡿࡇ࡜ࠊ4f ෆẆ㑄⛣Ⓨග࠿ࡽ Sm3+
࢖࢜ࣥ࡜ࡋ࡚ῧຍࡉࢀ࡚࠸ࡿࡇ࡜࡞࡝ࡀ᫂ࡽ࠿࡜࡞ࡾࠊ࢘ࣝ
ࢶ㖔ᆺ Ga1-xSmxN ࢚ࣆࢱ࢟ࢩࣕࣝⷧ⭷ࡀࢥࣄ࣮ࣞࣥࢺ࡟ᡂ㛗
550
600
650
700
Wavelength (nm)
ࡋ࡚࠸ࡿࡇ࡜ࢆ♧ࡋ࡚࠸ࡿࠋࡲࡓࠊࡑࡢⷧ⭷ࡣᐊ ࡛ࡶࣄࢫ
ࢸࣜࢩࢫࡢ࠶ࡿ☢໬᭤⥺ࢆ♧ࡋࠊ㣬࿴☢໬ࡸಖ☢ຊࡶ Sm ῧ
ᅗ㸱 Ga1-xSmxN ⷧ⭷ࡢࣇ࢛ࢺ࣑ࣝࢿࢭࣥࢫࢫ
ຍ㔞࡟౫Ꮡࡋ࡚ኚ໬ࡍࡿࡇ࡜ࢆ᫂࠿࡜ࡋࡓࠋ
࣌ࢡࢺࣝ
࣭ᙉ☢ᛶ㔠ᒓ࡟ࡼࡿ❅໬≀༙ᑟయ࡬ࡢࢫࣆࣥὀධ࡜ࢼࣀ☢ᛶホ౯
ᙉ☢ᛶ㔠ᒓ࡟ࡼࡿ❅໬≀༙ᑟయ࡬ࡢࢫࣆࣥὀධ⌧㇟ࡣࠊ༙ᑟయࢫࣆࣥࢺࣟࢽࢡࢹࣂ࢖ࢫᙧᡂୖࠊ㔜せ
࡛࠶ࡿࠋࡇࢀࡲ࡛࡟ࠊGaN ୖ࡟ Fe ࡸ Co ࢆᡂ㛗ࡉࡏ࡚ࠊࡑࡢ⤖ᬗᵓ㐀ࠊᡂ㛗ᵝᘧࠊ࠾ࡼࡧ☢Ẽ≉ᛶࢆㄪ
࡭࡚ࡁࡓࠋࡲࡓࠊCo 㟁ᴟ࡟ࡼࡿ 4 ➃Ꮚ㠀ᒁᡤ㟁Ẽఏᑟ ᐃ⏝ࡢࢫࣆࣥࣂࣝࣈ⣲Ꮚࢆస〇ࡋࠊᐊ ࡛ GaN
࡬ࡢࢫࣆࣥὀධࡀྍ⬟࡞ࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋ࡚ࡁࡓࠋ௒ᖺᗘࡣࠊࣁ࣮ࣇ࣓ࢱࣝⓗࣁࣥࢻᵓ㐀ࢆ᭷ࡍࡿ
Ȗ’-Fe4N ࡢ GaN ୖ࡬ࡢᡂ㛗ࢆ⾜࠸ࠊࡑࡢ⤖ᬗᛶࠊࣔࣇ࢛ࣟࢪ࣮࠾ࡼࡧ☢Ẽ≉ᛶࡢⰋዲ࡞ⷧ⭷ࡀᚓࡽࢀࡿ
᮲௳ࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
࣭᪂ཎ⌮ኴ㝧㟁ụ
p – n ᥋ྜࢆ᭷ࡋ࡞࠸᪂ືసཎ⌮࡟ᇶ࡙ࡃኴ㝧㟁ụ࡟ࡘ࠸࡚ࡣࠊ26 ᖺᗘࡣᐇドࢭࣝࡢ〇స୪ࡧ࡟ᐇド
ᐇ㦂ࢆ⾜ࡗࡓ㸦⏘⥲◊࡜ࡢඹྠ◊✲㸧ࠋ୪⾜ࡋ࡚➨୍ཎ⌮࡟ᇶ࡙ࡃኚ᥮ຠ⋡ண ࡶ⾜ࡗࡓ㸦ᕤᏛ㒊ࠊబ
⸨෸ᩍᤵ࡜ࡢඹྠ◊✲㸧
ࠋᐇドᐇ㦂࡟᪊࠸࡚ࡣࠊᮏ᮶᥇⏝ࡍ࡭ࡁ In/InGaN/InN ⣔ࡣ⌧᫬Ⅼ࡟࠾࠸࡚Ⰻዲ
࡞ᡂ⭷࡟㞴Ⅼࡀ࠶ࡿࡓࡵ࡟ࠊGaN/AlGaN/GaN ࢆ⏝࠸࡚ 1SUN ᮲௳ୗࡢࡶ࡜࡛⾜ࡗࡓࠋࡑࡢ⤖ᯝࠊኴ㝧
㟁ụ࡜ࡋ࡚ࡢືసᶵ⬟ࢆ☜ㄆฟ᮶ࡓࠋ୍᪉ࠊኚ᥮ຠ⋡ண ࡣ InN/GaN/InN ⣔࡛㸯eV ࡢࣂࣥࢻࢠࣕࢵࣉ
ࢆ᝿ᐃࡋ࡚ぢ✚ࡶࡗࡓࠋ60%ᙅࡢኚ᥮ຠ⋡ࢆᚓࡓࠋࡇࢀࡣࠊ㐶࠿࡟ p – n ᥋ྜ࡛ࡢ Shockley-Queisser limit
(30%ᙉ)ࢆ㉸࠼ࡿຠ⋡࡛࠶ࡾࠊࡲࡉ࡟ hot electron ຠᯝ࡟ࡼࡿࡶࡢ࡛࠶ࡿࠋྠ᪂ཎ⌮࡛ືసࡍࡿඛ⾜ኴ㝧
㟁ụ࡟࣌ࣟࣈࢫ࢝࢖ࢺ⣔ኴ㝧㟁ụࡀ࠶ࡿࡀࠊ⌧ᅾ 20%㏆ࡃࡢኚ᥮ຠ⋡ࡀල⌧ࡉࢀࡓࡇ࡜ࡀሗ࿌ࡉࢀ࡚࠸
ࡿࠋ
࣭XAFS
GaN:Gd ࡟ᘬࡁ⥆ࡁ GaN:Dy ࡟ࡘ࠸࡚ࡶ೫ග౫Ꮡ XANES ࢫ࣌ࢡࢺࣝࡢゎᯒࡼࡾ❅⣲✵᱁ᏊⅬࡢྠᐃ
୪ࡧ࡟❧య㓄఩⎔ቃࡢྠᐃࢆ࠾ࡇ࡞ࡗࡓࠋGaN:Gd ࡟㛵ࡋ࡚ࡣࠊከ㔜ᩓ஘⌮ㄽ࡟ࡼࡿゎᯒࡢ࡯࠿࡟➨୍
ཎ⌮࡟ᇶ࡙ࡃ XANES ࢫ࣌ࢡࢺࣝࡢࢩ࣑࣮ࣗࣞࢩࣙࣥࢆ⾜ࡗࡓ㸦ⓑ஭෸ᩍᤵ࡜ࡢඹྠ◊✲㸧ࠋ
― 35 ―
༙ᑟయ㔞Ꮚ⛉Ꮫ◊✲ศ㔝
ᩍᤵ
ᯇᮏ ࿴ᙪ
෸ᩍᤵ
஭ୖ ᜏ୍ࠊ๓ᶫ ව୕㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥ᣍ⪸ᩍᤵ㸧
≉௵෸ᩍᤵ
኱㔝 ᜤ⚽㸦ᖹᡂ 26 ᖺ 11 ᭶ 1 ᪥ᣍ⪸෸ᩍᤵ㸧
ຓᩍ
㔠஭ ᗣࠊᑠ㔝 ᑲ⏕㸦ᖹᡂ 27 ᖺ 1 ᭶ 1 ᪥᥇⏝㸧
ᣍ⪸◊✲ဨ
୕Ꮿ 㞞ே
኱Ꮫ㝔Ꮫ⏕
⏕⏣ ᪸ࠊዟ⏣ ⪽ᚿࠊ㯞᳜ ୔ྐࠊΎᐙ ᗣᖹࠊ୰ᮧ ோಇ
▼ᶫ ♸㍜ࠊᒸ㔝 ㄔஅ
Ꮫ㒊Ꮫ⏕
㙊⏣ ᯝṌࠊᯘ ுኴࠊ᳃ ♸ᶞ
஦ົ⿵బဨ
ᒣෆ ⋹Ꮚࠊᴮᮏ Ṍ
a) ᴫせ
㟁Ꮚ࣭ගᏊ➼ࡀ㔞ᏊຊᏛⓗຠᯝ࡟ࡼࡾ⊂≉࡞᣺⯙࠸ࢆࡍࡿᴟᚤ⣽༙ᑟయᵓ㐀㸦㔞Ꮚᵓ㐀㸧ࡣඃࢀࡓᛶ
㉁ࢆᣢࡘ࡜ᮇᚅࡉࢀࡿࠋࡑࡢࡓࡵ࡟ཎᏊⓗᑻᗘ࡛㔞Ꮚᵓ㐀ࢆᙧᡂࡋࠊホ౯ࡍࡿᢏ⾡ࢆ☜❧ࡍࡿࠋྠ᫬࡟
ࢥࣄ࣮ࣞࣥࢺ࡞㟁ᏊἼࡢఏ᧛ࠊගᏊ࡜㟁ᏊἼࡢ㔞Ꮚ┦஫స⏝➼ࡢ㔞Ꮚ≀ᛶ࡟ࡶ࡜࡙ࡃ᪂ࡋ࠸ᴫᛕࡢ༙ᑟ
య⣲Ꮚࡢ๰ฟࢆ┠ᣦࡋࡓ◊✲ࢆ⾜࠺ࠋ
࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈࡸࢢࣛࣇ࢙ࣥࡣࠊ㔞Ꮚᵓ㐀ࢹࣂ࢖ࢫࡢస〇࡟᭷ᮃ࡞≀㉁࡛࠶ࡿࠋ࣮࢝࣎ࣥࢼࣀ
ࢳ࣮ࣗࣈࡢ୍ḟඖⓗ≉ᚩࡸࢢࣛࣇ࢙ࣥࡢ≉ᛶࢆ⏕࠿ࡋ࡚ࠊ㟁⏺ຠᯝࢺࣛࣥࢪࢫࢱࡸ༢୍㟁Ꮚࢺࣛࣥࢪࢫ
ࢱࢆస〇ࡋࠊ༢୍ࡢศᏊࠊ㟁Ꮚࠊ࠾ࡼࡧࢫࣆࣥࢆࢭࣥࢩࣥࢢࡍࡿ⣲Ꮚࢆ㛤Ⓨࡍࡿࠋ⌧ᅾࠊ⇕ CVD ᡂ㛗
ἲࠊ࣐ࣛࣥศගἲࠊཎᏊ㛫ຊ㢧ᚤ㙾ࠊࣇ࢛ࢺ࣑ࣝࢿࢭࣥࢫἲࢆ୰ᚰᢏ⾡࡜ࡋ࡚ࠊ࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈ
ࡢᇶᮏ≉ᛶไᚚࠊ࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈࢹࣂ࢖ࢫࡸࢢࣛࣇ࢙ࣥࢹࣂ࢖ࢫࡢ≉ᛶ㺃ࣉࣟࢭࢫไᚚࠊࡑࡋ࡚
ࡑࢀࡽࡢࢭࣥࢧ࣮ᛂ⏝ࢆࡵࡊࡋࡓ◊✲ࢆ㐍ࡵ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭㧗ឤᗘ࢖ࣥࣇ࢚ࣝࣥࢨ࢘࢖ࣝࢫ᳨▱ჾ㛤Ⓨࡢࡓࡵࡢ⢾㙐ಟ㣭ࢢࣛࣇ࢙ࣥ㟁ゎຠᯝࢺࣛࣥࢪࢫࢱ
㸦GFET㸧࡟ࡼࡿࣞࢡࢳࣥࡢ㑅ᢥⓗ᳨ฟ
ேᆺ࠾ࡼࡧ㫽ᙧ࢖ࣥࣇ࢚ࣝࣥࢨ࢘࢖ࣝࢫࢆ
᳨▱ࡋࡑࡢ࡝ࡕࡽ࠿ࡶุᐃࡍࡿࢹࣂ࢖ࢫࡢ㛤
Ⓨࡢࡓࡵࠊ2 ✀㢮ࡢ sialylglycopeptides(SGPs)࡟
ࡼࡾࢢࣛࣇ࢙ࣥࢆಟ㣭ࡋࡓ GFET ࢆస〇ࡋࠊ
Sambucus-sieboldiana(SSA) ࣞ ࢡ ࢳ ࣥ ࡜
Maackia-amurensis(MAM)ࣞࢡࢳࣥࡢ㑅ᢥⓗ᳨
ฟࢆ◊✲ࡋࡓࠋࡑࡢ⤖ᯝࠊ≉␗ⓗ࡟⤖ࡧࡘࡃ
ࣞࢡࢳࣥࡢࡳࡢ㈇㟁Ⲵ⵳✚ࢆឤࡌࡓ⣲Ꮚ㟁ὶ
ࡢኚ໬ࢆほ ࡍࡿࡇ࡜ࡀ࡛ࡁࡓࠋSGP ࢆಟ㣭ࡋ
ࡓࢢࣛࣇ࢙ࣥࡣ࢖ࣥࣇ࢚ࣝࣥࢨ࢘࢖ࣝࢫࢆ㑅
ᢥⓗ࡟ឤᗘⰋࡃ᳨▱ࡍࡿ⬟ຊࡀ࠶ࡿࡇ࡜ࡀࢃ
࠿ࡗࡓࠋ
ᅗ㸯 D66$ ࡜ 0$0 ࢆ༊ูࡋ᳨࡚ฟࡍࡿࡓࡵࡢࢢࣛࣇ࢙ࣥಟ㣭ࡢᴫᛕᅗ
E࠸ࢁ࠸ࢁ࡞ࣞࢡࢳࣥ⃰ᗘୗ࡟࠾ࡅࡿ 66$ ᳨▱ᆺ *)(7 ⣲Ꮚࡢ㟁ὶ
― 36 ―
࣭GFET ࢞ࢫࢭࣥࢩࣥࢢᛶ⬟ࡢᇶᯈ⾲㠃౫Ꮡᛶ
GFET ࢆ㧗ឤᗘ࢞ࢫࢭࣥࢧ࣮࡜ࡋ࡚ᛂ⏝ࡍࡿࡓ
ࡵࠊᇶᯈ⾲㠃≧ែࡢຠᯝࢆㄪ࡭ࡓࠋGFET ࢆస〇
ࡍࡿࡢ࡟ඛࡔࡗ࡚ࠊḟࡢ㸱㏻ࡾࡢ๓ฎ⌮ࢆ SiO2/Si
ᇶᯈࡢ⾲㠃࡟⾜ࡗࡓࠋ (1)Ỉ⣲࢞ࢫ㞺ᅖẼ୰࡛࢔
ࢽ࣮ࣝࡍࡿࠋ(2)࢔࣑ࣝࢼࡢⷧ⭷࡛そ࠺ࠋ(3)⾲㠃ࢆ
ᅄࣇࢵ໬Ⅳ⣲࢖࢜ࣥ࡟ࡼࡿ཯ᛂᛶ࢚ࢵࢳࣥࢢ࡟
ࡼࡾฎ⌮ࡍࡿࠋ✵Ẽࡸ㓟⣲࢞ࢫ࡟ᭀ㟢ࡋࡓ࡜ࡁࠊ
GFET ≉ᛶࡢ㟁Ⲵ୰ᛶⅬ㸦CNP㸧ࡀ᫬㛫࡟౫Ꮡࡋ
࡚ኚ໬ࡍࡿᵝᏊࢆㄪ࡭ࡓࠋࡑࡢ⤖ᯝࠊᅄࣇࢵ໬Ⅳ
⣲࢖࢜ࣥ࡟ࡼࡿฎ⌮ࢆࡋࡓヨᩱࡀ᭱ࡶ㧗ឤᗘ࡛
࠶ࡗࡓࠋࡲࡓ㓟⣲⃰ᗘ౫Ꮡᛶ࡟ࡘ࠸࡚ࡶ๓ฎ⌮ࡢ
㐪࠸࡟ࡼࡗ࡚᫂░࡞㐪࠸ࡀぢࡽࢀࡓࠋ
ᅗ 2 D ✵Ẽ࡟ᭀ㟢ࡋࡓ࡜ࡁࡢ 14 ᫬㛫࡟ࢃࡓࡿ GFET ≉ᛶࡢኚ໬ࠋE&13
ࢩࣇࢺࡢ᫬㛫౫Ꮡᛶࠋ⾲㠃ฎ⌮࡟ࡼࡿ㐪࠸ࡀࡳࡽࢀࡿࠋ
࣭㟁Ⲵ⵳✚ᒙࡢ࠶ࡿ࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈ༢㟁Ꮚࢺࣛࣥࢪࢫࢱ㸦CNTSET㸧
༢㟁Ꮚ࣓࣮ࣔࣜ࡜ࡋ࡚ CNTSET ࢆ౑
࠺ࡇ࡜ࡀྍ⬟࠿࡝࠺࠿ࢆㄪ࡭ࡿࡓࡵࠊ
࢔࣑ࣝࢼ〇ࢤ࣮ࢺ⤯⦕⭷ࡢ୰࡟㔠ࡢᾋ
㐟ࢻࢵࢺࢆసࡾ㎸ࢇࡔ CNTSET ࢆస〇
ࡋࡓࠋࣂࢵࢡࢤ࣮ࢺ㟁ᅽࢆ–0.2 ࠿ࡽ
0.5V ࡢ㡿ᇦ࡛ᤲᘬࡋࠊఏ㐩≉ᛶ᭤⥺ࢆ
ᐃࡍࡿ࡜ࠊࢡ࣮ࣟࣥ᣺ື࡜࿧ࡤࢀࡿ
㟁ὶ᣺ື࡟ᤲᘬࡢྥࡁ࡟౫Ꮡࡋࡓ㢧ⴭ
࡞ࢩࣇࢺࡀほ ࡉࢀࡓࠋࡇࡢࢩࣇࢺࡣ
CNT ࡢࢳࣕࢿࣝ࠿ࡽ㔠ᾋ㐟ࢻࢵࢺ࡬
㟁Ⲵࡀὀධࡉࢀࡓࡇ࡜࡟㉳ᅉࡍࡿࠋࡉ
ࡽ࡟ࣆ࣮ࢡ఩⨨࡜⵳✚㟁ᅽ࡜࡟ࡣ㝵ẁ
≧ࡢ㛵ಀࡀぢࡽࢀࡓࠋࡇࡢ㝵ẁ㛵ಀࡢ
㟁ᅽࡼࡾぢ✚ࡶࡿ࡜ࠊ1 㟁Ꮚ༢఩ࡢ㟁
Ⲵ⵳✚ࡀ㔠ࡢࢻࢵࢺ࡟㉳ࡇࡗ࡚࠸ࡿࡇ
࡜ࡀศ࠿ࡗࡓࠋࡇࡢࢹࣂ࢖ࢫࡣ
CNTSET ࡟ࡼࡿ༢㟁Ꮚ࣓࣮ࣔࣜࡢೃ⿵
ᅗ 3 (a)⣲Ꮚᵓ㐀ࡢᴫᛕᅗࠋ(b)⣲Ꮚࡢఏ㐩≉ᛶࠋ
࡛࠶ࡾࠊࢹࢪࢱࣝືసࡢపᾘ㈝㟁ຊ⣲
(c)⵳✚㟁ᅽ࡜ࢡ࣮ࣟࣥࣆ࣮ࢡ఩⨨࡜ࡢ㝵ẁ≧ࡢ㛵ಀ
Ꮚ࡜࡞ࡾᚓࡿ࡜ᮇᚅࡉࢀࡿࠋ
― 37 ―
ඛ㐍㟁Ꮚࢹࣂ࢖ࢫ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
≉௵෸ᩍᤵ
ຓᩍ
ຓᩍ
≉௵◊✲ဨ
ᢏ⾡⿵బဨ
஦ົ⿵బဨ
஦ົ⿵బဨ
஦ົ⿵బဨ
㛵㇂ Ẏ
㡲⸨ Ꮥ୍
᳜ᮧ 㝯ᩥ㸦ᖹᡂ 27 ᖺ 2 ᭶ 1 ᪥᥇⏝㸧
Ⲩᮌ ᚭᖹ㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥᥇⏝㸧
ྜྷᮏ ⚽㍜㸦ᖹᡂ 27 ᖺ 3 ᭶ 16 ᪥᥇⏝㸧
ᯇᮏ Ꮥ඾㸦ᖹᡂ 27 ᖺ 2 ᭶ 1 ᪥᥇⏝㸧
ᒸ ⌔ᮌ 㸦ᖹᡂ 26 ᖺ 12 ᭶ 1 ᪥᥇⏝㸧
᳜⏣ ⨾▱㸦ᖹᡂ 26 ᖺ 11 ᭶ 1 ᪥᥇⏝㸧
㧗ᶫ ▱Ꮚ㸦ᖹᡂ 26 ᖺ 11 ᭶ 1 ᪥᥇⏝㸧
ᮏᦶ ከ⣖㸦ᖹᡂ 26 ᖺ 11 ᭶ 1 ᪥᥇⏝㸧
a) ᴫせ
ᮏ◊✲ศ㔝࡛ࡣࠊ㟁Ꮚᶵ⬟ᛶ࡟ඃࢀࡓᮦᩱࡢᵓ㐀ࠊ㟁Ꮚ≧ែࠊ≀ᛶࢆ㧗ᗘ࡟ไᚚࡋࠊࣇࣞ࢟ࢩࣈ࢚ࣝ
ࣞࢡࢺࣟࢽࢡࢫࠊࣇ࢛ࢺࢽࢡࢫ࡬࡜᪼⳹ࡉࡏ࡚࠸ࡃࡓࡵࡢᇶ♏⛉Ꮫ࡜ඛ➃ᢏ⾡ࡢ⼥ྜ⛉Ꮫࢆ◊✲ࡋ࡚࠸
ࡲࡍࠋᩘᏛࠊ≀⌮Ꮫࠊࢹࣂ࢖ࢫࣉࣟࢭࢫࠊᅇ㊰࣭ࢩࢫࢸ࣒タィࠊ᝟ሗ⛉Ꮫ࡞࡝ࡢᇶ♏⛉Ꮫ࡟᰿ࡊࡋࡓᏛ
⾡࠿ࡽᐇ♫఍࡟㈉⊩ࡍࡿ࢚ࣞࢡࢺࣟࢽࢡࢫࢩࢫࢸ࣒ࢆ๰ฟࡍࡿྲྀࡾ⤌ࡳࢆ⾜ࡗ࡚࠸ࡲࡍࠋ
b) ᡂᯝ
࣭Cyber-Physical Systems ࡢᐇ⌧ࢆ┠ᣦࡋࡓ኱㠃✚ࣇࣞ࢟ࢩࣈ࢚ࣝࣞࢡࢺࣟࢽࢡࢫࢭࣥࢧࡢ㛤Ⓨ
௒ᖺᗘࡣࠊࣇࣞ࢟ࢩࣈࣝ኱㠃✚࡞ࢭࣥࢧࢩ࣮࡜ࡢ㛤Ⓨࢆ㐍ࡵࠊࡇࢀࢆ⏕యಙྕィ ⏝ࢭࣥࢧࠊ⎔ቃࣔࢽ
ࢱࣜࣥࢢࢭࣥࢧ࡟⏝࠸ࡿྲྀࡾ⤌ࡳࢆ㐍ࡵ࡚ࡁࡓࠋࡉࡽ࡟ࠊࡇࡢࢭࣥࢧᢏ⾡ࡢᇶᮏせ⣲࡜࡞ࡿᮦᩱྜᡂ࡜
ࡑࡢᶵ⬟㞟✚໬ࠊᮦᩱࢆᗄ㔜࡟ࡶ✚ᒙࡋࡓࢹࣂ࢖ࢫ໬ࠊ኱㠃✚໬ࠊࡇࢀࢆ༠ㄪືసࡉࡏࡿࡇ࡜࡛࢚ࣞࢡ
ࢺࣟࢽࢡࢫ࡜ࡋ࡚ືసࡉࡏࡿࡓࡵࡢᅇ㊰タィ࣭ࢩࢫࢸ࣒タィࠊࡉࡽ࡟ࡣ᝟ሗ⛉Ꮫࡲ࡛ࢆྲྀࡾ㎸ࢇࡔ᪂ࡋ
࠸┦⿵ⓗ⼥ྜ◊✲㛤Ⓨࢆ㐍ࡵ࡚ࡁࡓࠋࡇࡢ᪂ࡋ࠸࢖ࣥࢱ࣮ࣇ࢙࣮ࢫࢆࠊᐇ✵㛫ࡢ᝟ሗࢆⓗ☜࡟ᤊ࠼ࡿᡭ
ẁ࡜ࡋ࡚ࡢ◊✲ࢆ㐍ࡵ࡚ࡁࡓࠋ
ࡑࡢ୍౛ࢆḟ࡟♧ࡍࠋேࢆྵࡴ͆࠶ࡽࡺࡿᐇୡ⏺ࡢࣔࣀ͇ࡀ࢖ࣥࢱ࣮ࢿࢵࢺ࡟ࡘ࡞ࡀࡿ᫬௦“Internet of
Things (IoT)/Cyber-Physical Systems(CPS)”ඖᖺࡀᖥࢆ㛤ࡅࡓ࡜ゝࢃࢀ࡚࠸ࡿࠋ౛࠼ࡤࠊ᭱㏆ࡢ࢚ࣞࢡࢺࣟ
ࢽࢡࢫࢩ࣮࡛ࣙࡣࠊ㟁Ꮚࢹࣂ࢖ࢫ༢య࡛ᶵ⬟ࡢඃ఩ᛶࢆᐉఏࡍࡿࡶࡢࡣ࡯࡜ࢇ࡝࡞ࡃࠊࡑࡢ㟁Ꮚࢹࣂ࢖
ࢫ࡜࿘ᅖ࡜ࡢ㐃ᦠࠊ࠾ࡼࡧ࢔ࣉࣜࢣ࣮ࢩࣙࣥ࡜ࡢ㐃ᦠࡀ㔜せ࡛࠶ࡾࠊ
ࠕ࢚ࣞࢡࢺࣟࢽࢡࢫࡢࢯ࣮ࣜࣗࢩ
ࣙࣥ໬ࠖࠊ࡜⛠ࡉࢀࡿࠋ࢚ࣞࢡࢺࣟࢽࢡࢫࡀ஫࠸࡟༠ㄪࡋྜ࠸ࠊᐇୡ⏺ࡢ᝟ሗࢆṇ☜࡟ィ ࡛ࡁࢀࡤࠊ
ࡑࡢ≧ែࢆ▱ࡿࡇ࡜ࡀ࡛ࡁࡿࠋࡑࡇ࡟ㄢ㢟ࡀ࠶ࢀࡤࠊࢧ࢖ࣂ࣮✵㛫㸦᝟ሗฎ⌮ࠊ᝟ሗศᯒࡀ࡛ࡁࡿࢡࣛ
࢘ࢻ㸧࡟࠾࠸࡚ࠊࡑࢀ࡟ᑐࡋ࡚
᭱㐺࡞ゎࠊᑡ࡞ࡃ࡜ࡶ㐺ษ࡞ゎ
ࢆ‽ഛࡍࡿࡇ࡜ࡀ࡛ࡁࡿࠋ͆ṇ
☜࡟≧ែࢆ▱ࡿ͇࡜࠸࠺άືࡣ
IoT/CPS ࡢ᰿ᖿ࡛࠶ࡾࠊᴟࡵ࡚
㔜せ࡛࠶ࡿࡀࠊᐇୡ⏺ࡣᗈ࠸㠃
✚ࢆᣢࡕࠊ᭤ࡀࡗࡓࡾࠊఙࡧࡓ
ࡾ࡜」㞧࡞ᙧ≧ࢆࡋ࡚࠸ࡿࡓ
ࡵࠊࡑࡢ⾲㠃࡟ᐦ╔ࡋࠊ᝟ሗࢆ
㝰↓ࡃᚓࡿࡇ࡜ࡣᐜ࡛᫆ࡣ࡞
࠿ࡗࡓࠋ኱㠃✚ࢆそ࠺ࡇ࡜ࡀ࡛
ࡁࡿ኱ࡁ࡞ࢭࣥࢧࢩࢫࢸ࣒ࢆ
స〇࡛ࡁࡿࣉࣜࣥࢸࢵࢻ࢚ࣞ
― 38 ―
ࢡࢺࣟࢽࢡࢫᢏ⾡ࠊᰂ㌾ᛶࢆᣢࡗࡓᶵ⬟ᛶ࢚ࣞࢡࢺࣟࢽࢡࢫࢆᐇ⌧࡛ࡁࡿࣇࣞ࢟ࢩࣈ࢚ࣝࣞࢡࢺࣟࢽࢡ
ࢫᢏ⾡ࡣࠊ኱㠃✚࠿ࡘࢥࢫࢺຠ⋡ࡀ㧗ࡃ࢚ࣞࢡࢺࣟࢽࢡࢫࢆ〇㐀࡛ࡁࡿࡓࡵࠊ⏘ᴗ⏺࡟࠾ࡅࡿ㔜せᛶࡣ
ㄆࡵࡽࢀ࡚࠸ࡿࡶࡢࡢࠊ࡞࠿࡞࠿ࡑࡢฟཱྀ㸦࣮࢟ࣛ࢔ࣉࣜࢣ࣮ࢩࣙࣥ㸧ࡀぢࡘ࠿ࡽࡎ࡟࠸ࡓࠋ࡜ࡇࢁࡀ
ࡇࡇ᭱㏆࡛ࡣࠊࣉࣜࣥࢸࢵࢻ࢚ࣞࢡࢺࣟࢽࢡࢫᢏ⾡ࠊࣇࣞ࢟ࢩࣈ࢚ࣝࣞࢡࢺࣟࢽࢡࢫᢏ⾡࡟ࡼࡿ኱㠃✚
ࢭࣥࢧࠊࣇࣞ࢟ࢩࣈࣝࢭࣥࢧࡣࠊᐇ✵㛫ࡢࢭࣥࢩࣥࢢ࡟㐺ࡋ࡚࠾ࡾࠊSi-LSI ᢏ⾡࡛ࡣᐇ⌧ࡀᅔ㞴࡞᪂ࡋ
࠸ࢭࣥࢧࢆ๰ฟ࡛ࡁࡿ࡜ࡢ⪃࠼࡟⮳ࡾࠊࡇࢀࢆᐇ⌧ࡍࡿࡓࡵࡢྲྀࡾ⤌ࡳࢆ㐍ࡵ࡚ࡁࡓࠋࡼࡾලయⓗ࡟ࡣࠊ
⿦╔ឤࡢ࡞࠸⏕యಙྕ࢔ࣥࣉ࡞࡝ࡢ㛤Ⓨ࡟ᡂຌࡋࠊࡇࢀࡽࢆ⏝࠸ࡓࢭࣥࢧࢩࢫࢸ࣒ࡢᐇ⌧ࢆࡵࡊࡋ࡚࠸
ࡿࠋࡲࡓࠊ⏕యィ ࡢࡳ࡞ࡽࡎࠊ⎔ቃࣔࢽࢱࣜࣥࢢࢭࣥࢧ࡞࡝ࡢ㛤Ⓨ࡟ࡶྲྀࡾ⤌ࢇ࡛ࡁࡓࠋ
[1] S. Lee, et. al., Nature Communications 5, 5898 (2014). [2] M. Melzer, et. al., Nature Communications 6, 6080
(2015).
― 39 ―
」ྜ▱⬟࣓ࢹ࢕࢔◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
≉௵ㅮᖌ
≉௵ຓᩍ
༤ኈ◊✲ဨ
኱Ꮫ㝔Ꮫ⏕
◊✲⏕
Ꮫ㒊Ꮫ⏕
஦ົ⿵బဨ
ᢏ⾡⿵బဨ
ඵᮌ ᗣྐ
ᵐཎ 㟹㸦ᖹᡂ 26 ᖺ 6 ᭶ 1 ᪥᥇⏝㸧
ᵐཎ 㟹㸦ᖹᡂ 26 ᖺ 4 ᭶ 1 ᪥㹼ᖹᡂ 26 ᖺ 5 ᭶ 31 ᪥㸧
ࠊ‶ୖ ⫱ஂࠊ
኱಴ ྐ⏕㸦ᖹᡂ 27 ᖺ 2 ᭶ 16 ᪥᥇⏝㸧
ᮧᯇ ኱࿃
࢔ࣝ ࣔࣥࢫ࣮ࣝ㸦ᖹᡂ 26 ᖺ 4 ᭶ 1 ᪥㹼ᖹᡂ 26 ᖺ 10 ᭶ 31 ᪥㸧
୰⃝ ‶ࠊࣛࢩࢵࢻ ࢔ࢡ࣐ࣝ㸦ᖹᡂ 26 ᖺ 4 ᭶ 1 ᪥㹼ᖹᡂ 27 ᖺ 1 ᭶ 15 ᪥㸧
ࠊ
୹⩚ ┿㝯ࠊࣁࢮ࣒ ࢚ࣝ࢔ࣝࣇ࢕ࠊ⏣ᕝ ⪷୍㸦ᖹᡂ 26 ᖺ 4 ᭶ 1 ᪥᥇⏝㸧
ࠊ
࢙࢘࢖ ࣜ㸦ᖹᡂ 26 ᖺ 7 ᭶ 1 ᪥᥇⏝㸧
ୖᮧ ᣅ▮ࠊ㜰ୗ ࿴ᘯࠊ஭ୗ ᬛຍࠊ࿘ ᡂ⳥ࠊ
࢔ࣥࢻࣞ࢖ ࢢࣝࢩࣔࣇࠊⓑ⚄ ᗣᖹࠊ⏣୰ ㈼୍㑻ࠊᗺ ⱝ㎮ࠊ
ࢨࢩ࣒ ࢔ࢵࢹ࢕ࣥ㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥ධᏛ㸧
ࠊ஭ᮧ ♸‶ࠊᒸ⏣ ඾ࠊ
⏣ୖ ᣅᘺࠊᯇᮧ 㝯ᘯࠊụ⏣ ኴ㑻ࠊụᮏ ⚈ࠊ⳥ụ ࿴㤿ࠊᮌᮧ ༟ᘯࠊ
ᶫᮏ ▱඾
ࢨࢩ࣒ ࢔ࢵࢹ࢕ࣥ㸦ᖹᡂ 26 ᖺ 4 ᭶ 1 ᪥㹼ᖹᡂ 26 ᖺ 9 ᭶ 30 ᪥㸧
ࠊ
ࠊ
ன ὒ㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥ධᏛ㸧
⨶ ∖ภ㸦ᖹᡂ 26 ᖺ 4 ᭶ 1 ᪥㹼ᖹᡂ 27 ᖺ 3 ᭶ 31 ᪥㸧
㟷ᮌ ༓ᑜࠊ⏕⇃ Ἃ⤢ࠊୖᮧ ⣧୍ࠊᰘ⏣ ೺సࠊ㕥ᮌ அࠊ
ᐙᮧ 㞞ᏊࠊᏳ஭ ⣖Ꮚࠊᮡᮏ 㞞Ꮚ㸦ᖹᡂ 26 ᖺ 7 ᭶ 16 ᪥᥇⏝㸧ࠊ
୰ᕝ ஂ⨾Ꮚ㸦ᖹᡂ 26 ᖺ 9 ᭶ 16 ᪥᥇⏝㸧
㣤ᒣ ளᘺࠊධỤ ὒᏊࠊ኱Ἑෆ Ⰻ⨾ࠊ஭ཱྀ ⨾㤶ࠊ
㒔⏥ ඃ⨾㸦ᖹᡂ 26 ᖺ 7 ᭶ 16 ᪥㹼ᖹᡂ 27 ᖺ 2 ᭶ 28 ᪥㸧
a) ᴫせ
ᮏ◊✲ศ㔝࡛ࡣࠊࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ࡜ᫎീ࣓ࢹ࢕࢔ฎ⌮࡟㛵ࡍࡿ◊✲ࢆࡋ࡚࠸ࡲࡍࠋࢭࣥࢧ㛤
Ⓨ࡞࡝ࡢᇶ♏ᢏ⾡࠿ࡽࠊࣟ࣎ࢵࢺ࡟㧗ᗘ࡞どぬᶵ⬟ࢆ୚࠼ࡿࡇ࡜ࢆ┠ᣦࡋࡓ▱⬟ࢩࢫࢸ࣒ࡢ㛤Ⓨࡲ࡛ࠊ
どぬ᝟ሗฎ⌮࡟㛵ࡍࡿᖜᗈ࠸ࢸ࣮࣐ࢆᢅࡗ࡚࠸ࡲࡍࠋ౛࠼ࡤࠊ࿘ᅖ 360 ᗘࢆ᧜ᙳ࡛ࡁࡿ඲᪉఩どぬࢭ
ࣥࢧࠊෆど㙾ᫎീࡢ་⏝⏬ീฎ⌮ࠊே㛫ࡢṌࡁ᪉࡟ᇶ࡙ࡃಶேㄆ㆑ࡸពᅗ࣭ឤ᝟᥎ᐃࠊ཯ᑕ≉ᛶࡢィ
࡜ CG ࡬ࡢᛂ⏝ࠊ࢙࢘࢔ࣛࣈ࣓ࣝ࢝ࣛࢆ⏝࠸ࡓ㜵≢ࢩࢫࢸ࣒ࠊ㏆㉥እගࢆ⏝࠸ࡓேయィ ࠊ3 ḟඖ
ᙧ≧ィ ᢏ⾡ࡢ㛤Ⓨ࡞࡝ࡢ◊✲࡛ࡍࠋ
b) ᡂᯝ
࣭ගᏛⓗ࡟⃰࠸፹యࡢ༙㏱᫂≀య࡟ᑐࡍࡿ↷ᗘᕪࢫࢸࣞ࢜
ᮏ◊✲࡛ࡣࠊ⾲㠃໬ᩓ஘ࢆ࿊ࡍࡿගᏛⓗ࡟⃰࠸፹
యࡢ༙㏱᫂≀య࡟ᑐࡍࡿ↷ᗘᕪࢫࢸࣞ࢜ἲࢆᥦ᱌
ࡍࡿࠋᥦ᱌ᡭἲࡣࠊᚑ᮶◊✲࡛♧ࡉࢀ࡚࠸ࡿ⾲㠃໬
ᩓ஘ࡀࠊࡰࡅ࣮࢝ࢿࣝ࡟ࡼࡿ␚ࡳ㎸ࡳ࡟ࡼࡗ࡚㏆ఝ
ࡉࢀࡿࠊ࡜࠸࠺ほ ࡟ᇶ࡙࠸࡚ᵓ⠏ࡉࢀ࡚࠸ࡿࠋ
ᡃࠎࡣࡇࡢほ ࢆᣑᙇࡋ࡚ࠊඖࡢ≀య⾲㠃ࡢἲ⥺ࢆ
⾲㠃໬ᩓ஘࣮࢝ࢿࣝ࡟ࡼࡗ࡚␚ࡳ㎸ࢇࡔࡶࡢࡀࠊᚑ
᮶ࡢ↷ᗘᕪࢫࢸࣞ࢜ἲ࡟ࡼࡗ࡚ᚓࡽࢀࡿࠊࡰࡅࡓ⾲
㠃ἲ⥺࡟ᑐᛂࡍࡿࡇ࡜ࢆ♧ࡍࠋࡇࢀ࡟ࡼࡾࠊගᏛⓗ
࡟⃰࠸፹యࡢ༙㏱᫂≀య࡟ᑐࡍࡿ↷ᗘᕪࢫࢸࣞ࢜
ἲࢆࡰࡅ᚟ඖࡢၥ㢟࡜ぢ࡞ࡋ࡚ࠊ㧗⢭ᗘ࡟⾲㠃ἲ⥺
ᅗ㸯
― 40 ―
ᐇࢩ࣮ࣥࡢཎ⏬ീᕥ࡜᥎ᐃࡉࢀࡓἲ⥺࣐ࢵࣉྑ
ࢆ᚟ඖࡍࡿᡭἲࢆ㛤Ⓨࡋࡓࠋࢩ࣑࣮ࣗࣞࢩࣙࣥࢹ࣮ࢱཬࡧᐇࢩ࣮ࣥࡢࢹ࣮ࢱࢆ⏝࠸ࡓᐇ㦂࡟ࡼࡾࠊᡭἲ
ࡢ᭷ຠᛶࢆ☜ㄆࡋࡓࠋ
࣭ከἼ㛗ࢫ࣌ࢵࢡࣝ┦㛵࡟ᇶ࡙ࡃᒙᵓ㐀ࡢ῝ࡉ᥎ᐃ
ୡࡢ୰࡟ࡣࠊືⓗ㡿ᇦࡀ㟼ⓗ㡿ᇦ࡟⿕ࢃࢀࡓࡼ࠺࡞ᒙᵓ㐀ࢆᣢ
ࡘ≀యࡀᏑᅾࡍࡿࠋᮏ◊✲࡛ࡣࠊࢫ࣌ࢵࢡࣝゎᯒ࡟ࡼࡗ࡚ࡑࡢࡼ
࠺࡞≀యࡢືⓗ㡿ᇦࡢ῝ࡉࢆ᥎ᐃࡍࡿ᪂ࡋ࠸ヨࡳࢆᥦ᱌ࡍࡿࠋࢫ
࣌ࢵࢡࣝࡣࢥࣄ࣮ࣞࣥࢫ࣮ࣞࢨࡢ┦஫ᖸ΅࡟ࡼࡗ࡚⏕ࡌࠊᮏ◊✲
࡛ࡣࡑࡢࢫ࣌ࢵࢡࣝࡢ஧ࡘࡢ≉ᛶࢆ฼⏝ࡍࡿࠋ୍ࡘࡣࠊࢫ࣌ࢵࢡ
ࣝࣃࢱ࣮ࣥࡢ᫬㛫ⓗᏳᐃᛶ࡛࠶ࡾࠊࡶ࠺୍ࡘࡣࠊ࣮ࣞࢨࡢ㏱㐣⋡
ࡢἼ㛗౫Ꮡᛶ࡛࠶ࡿࠋᡃࠎࡣࠊከἼ㛗࣮ࣞࢨࢆ⏝࠸ࡓࢫ࣌ࢵࢡࣝ
ࣃࢱ࣮ࣥࡢ┦㛵ࢆィ⟬ࡍࡿࡇ࡜࡛῝ࡉࢆ᥎ᐃࡍࡿࠋேࡢ⫙ࢆᶍࡋ
ࡓࣇ࢓ࣥࢺ࣒ࢆ⏝࠸ࡓᐇ㦂࡟ࡼࡾࠊከἼ㛗ࢫ࣌ࢵࢡࣝ┦㛵ࡀᒙᵓ
㐀ࡢゎᯒ࡟฼⏝ྍ⬟࡛࠶ࡿࡇ࡜ࢆ♧ࡋࡓࠋ
ᅗ㸰 ィ ⿦⨨
࣭Ṍᐜ࣭㢌㒊࣭㌟㛗࡟ࡼࡿ࣐ࣝࢳ࣮ࣔࢲࣝ⏕యㄆドࡢࡓࡵࡢရ㉁౫Ꮡࢫࢥ࢔ࣞ࣋ࣝ⤫ྜ
୍ࡘࡢ࣓࢝ࣛᫎീࡔࡅ࡛ᐇ⌧ྍ⬟࡞Ṍᐜࠊ㢌㒊ࠊ
㌟㛗࡟ࡼࡿ࣐ࣝࢳ࣮ࣔࢲࣝㄆドࡣ⢭ᗘ࡜ࢥࢫࢺࡢ୧
᪉ࡢⅬ࡛᭷ຠ࡞᪉ἲ࡛࠶ࡿࠋࡑࡢ୍᪉࡛ࠊࡑࡢ⢭ᗘ
ࡣ✵㛫ゎീᗘࡸ᫬㛫ゎീᗘ࡜࠸ࡗࡓ᧜ᙳ⎔ቃ࡟ࡼࡿ
ᙳ㡪ࢆཷࡅࠊࡲࡓࠊṌᐜࠊ㢌㒊ࠊ㌟㛗ࡑࢀࡒࢀࡢ≉
ᚩ࡟ࡼࡗ࡚ࡑࡢᙳ㡪ࡣ␗࡞ࡿࠋࡑࡢࡓࡵࠊࡼࡾ㧗࠸
⢭ᗘࢆᐇ⌧ࡍࡿࡓࡵ࡟ࡣࠊ✵㛫ゎീᗘ࡜᫬㛫ゎീᗘ
࡟ᛂࡌ࡚ࡑࢀࡒࢀࡢ≉ᚩ࠿ࡽᚓࡽࢀࡿࢫࢥ࢔࡟㐺ษ
࡞㔜ࡳ௜ࡅࢆࡍࡿࡇ࡜ࡀ㔜せ࡛࠶ࡿࠋᮏ◊✲࡛ࡣࠊ
ࡲࡎ 1,935 ேࡢබ㛤Ṍ⾜ᫎീࢹ࣮ࢱ࣮࣋ࢫࢆ⏝࠸࡚ࠊ
ࡑࢀࡒࢀࡢ≉ᚩ࡟ࡘ࠸࡚ᵝࠎ࡞ゎീᗘࡢࢫࢥ࢔ࢹ࣮ ᅗ㸱 ရ㉁౫Ꮡࡢࢫࢥ࢔ࣞ࣋ࣝ⤫ྜ
ࢱ࣮࣋ࢫࢆసᡂࡋࡓࠋࡑࡋ࡚ࡑࡢࢹ࣮ࢱ࣮࣋ࢫࢆ⏝
࠸࡚ᛶ⬟ホ౯ࢆ⾜࠸ࠊṌᐜࠊ㢌㒊ࠊ㌟㛗ࡑࢀࡒࢀ࡟
ࡘ࠸࡚᫬✵㛫ゎീᗘ࡟ᛂࡌࡓᛶ⬟ࡢኚ໬ࢆゎᯒࡋࡓࠋࡉࡽ࡟ࠊᵓ⠏ࡋࡓࢫࢥ࢔ࢹ࣮ࢱ࣮࣋ࢫ࡟ᇶ࡙࠸࡚ࠊ
᫬✵㛫ゎീᗘ࡟ᛂࡌࡓ᭱㐺࡞㔜ࡳ௜ࡅࡢ್ࢆ⥺ᙧࣟࢪࢫࢸ࢕ࢵࢡᅇᖐ࡟ࡼࡗ࡚ィ⟬ࡋࡓࠋࡲࡓࠊᏛ⩦ࢹ
࣮ࢱ࡟ྵࡲࢀ࡞࠸᫬✵㛫ゎീᗘࡢ⤌ࡳྜࢃࡏ࡟ᑐࡍࡿࢸࢫࢺࢹ࣮ࢱ࡟ᑐࡋ࡚ࡣࠊ࢞࢘ࢫ㐣⛬ᅇᖐ࡟ࡼࡿ
㔜ࡳࡢ᥎ᐃࢆ⾜࠸ࠊ⢭ᗘホ౯ࢆ⾜ࡗࡓࠋ⢭ᗘホ౯ࡢ⤖ᯝࠊᏛ⩦ࢹ࣮ࢱ࡜ྠࡌ᫬✵㛫ゎീᗘࡢ⤌ࢆ⏝࠸ࡓ
ࢸࢫࢺࢹ࣮ࢱࡢ⢭ᗘࠊࡘࡲࡾࡑࡢ᫬✵㛫ゎീᗘ࡟࠾ࡅࡿᛶ⬟ࡢୖ㝈࡜࡯ࡰྠ➼ࡢ⤖ᯝࡀᚓࡽࢀࡓࠋ
࣭Ṍ⾜ほ ࡟ࡼࡿ㢌㒊᪉ྥ᥎ᐃ
ᮏ◊✲࡛ࡣࠊṌ⾜⪅ࡢ㢌㒊᪉ྥࢆ᥎ᐃࡍࡿᡭἲࢆᥦ᱌
ࡍࡿࠋᚑ᮶ࠊ㢦ࡢࢸࢡࢫࢳࣕ࡟ᇶ࡙ࡃ㢌㒊᪉ྥ᥎ᐃࡢ◊
✲ࡀᩘከࡃ⾜ࢃࢀ࡚ࡁࡓࡀࠊ㐲᪉ࡢ㜵≢࣓࢝ࣛ࠿ࡽ᧜ᙳ
ࡉࢀࡓపゎീᗘ⏬ീࡢሙྜ࡟ࡣࠊࡑࢀࡽࡢᡭἲࢆ㐺⏝ࡍ
ࡿࡇ࡜ࡀᅔ㞴࡛࠶ࡿࠋࡑࡇ࡛ࠊᮏ◊✲࡛ࡣ㢦ࢸࢡࢫࢳࣕ
࡛ࡣ↓ࡃࠊపゎീᗘ⏬ീ࠿ࡽ࡛ࡶᚓࡽࢀࡿṌᐜ≉ᚩ࡟ᇶ
࡙ࡃᡭἲࢆ㛤Ⓨࡋࡓࠋࡲࡎࠊ᧜ᙳ⏬ീ࠿ࡽṌ⾜⪅ࡢ㧗ࡉ
ࢆṇつ໬ࡋࡓࢩ࢚ࣝࢵࢺ⏬ീࢆྲྀᚓࡋࠊḟ࠸࡛ࠊṌᐜ≉
ᚩ࡜ࡋ࡚Ṍᐜ࢚ࢿࣝࢠ࣮⏬ീࢆᢳฟࡍࡿࠋ᭱ᚋ࡟ࠊ㢌㒊
᪉ྥ࡟㛵ࡍࡿุูࣔࢹࣝࢆ⏕ᡂࡍࡿࠋᐇ㦂࡛ࡣࠊ100 ྡ
ࡢ⿕㦂⪅ࡀᵝࠎ࡞㢌㒊᪉ྥ࡛Ṍ⾜ࡍࡿపゎീᗘᫎീࢆ
⏝࠸ࠊᡭἲࡢ᭷ຠᛶࢆ☜ㄆࡋࡓࠋ
ᅗ㸲 Ṍ⾜ほ ࡟ࡼࡿ㢌㒊᪉ྥ᥎ᐃࡢᯟ⤌
― 41 ―
▱⬟᥎ㄽ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
ᣍ࡬࠸◊✲ဨ
኱Ꮫ㝔Ꮫ⏕
Ꮫ㒊Ꮫ⏕
≉௵஦ົ⫋ဨ
ᢏ⾡⿵బဨ
㮖ᑿ 㝯
ΎỈ ᫀᖹࠊἙཎ ྜྷఙ
ᮡᒣ 㯢ே
᳜㔝 ๛
Wang Luࠊ⏣୰ ┤ᶞࠊᤲ㒊 ೺
㤿ሙ 㷋ேࠊᒸ ⁞
ᒸ⏣ ᣑᏊ
ὸ㔝 ᭷⣖
a) ᴫせ
ே㛫ࡣࢹ࣮ࢱࢆ═ࡵࠊᵝࠎ࡞ᛮ⪃ࡸ⡆༢࡞⤫ィィ⟬ࢆྵࡴ᥎ㄽࢆ⾜ࡗ࡚ࠊࢹ࣮ࢱ࠿ࡽ▱㆑ࢆㄞࡳྲྀࡿ
ࡇ࡜ࡀ࡛ࡁࡿࠋࡋ࠿ࡋࠊ⌧௦♫఍࡛ࡣࠊࢥࣥࣆ࣮ࣗࢱࢿࢵࢺ࣮࣡ࢡࡸࣘࣅ࢟ࢱࢫࢭࣥࢩࣥࢢᢏ⾡㸦࠸ࡘ
࡛ࡶ࡝ࡇ࡛ࡶᵝࠎ࡞᝟ሗࢆィ ࡛ࡁࡿᢏ⾡㸧ࡢⓎ㐩࡟ࡼࡗ࡚ࠊ⭾኱࡞ࢹ࣮ࢱࢆ୍ᗘ࡟ධᡭࡍࡿᶵ఍ࡀቑ
࠼࡚࠸ࡿࠋࡲࡓࠊࡑࢀࡽࢹ࣮ࢱࡢ୰㌟ࡶ༢⣧࡞ᙧᘧ࡛ࡣ࡞ࡃࠊ᫬⣔ิࡸࢢࣛࣇࠊ⮬↛ᩥ࡞࡝ࠊ」㞧࡞ෆ
ᐜ࡟࡞ࡗ࡚ࡁ࡚࠸ࡿࠋࡇࡢࡼ࠺࡞࠸ࢃࡺࡿࣅࢵࢢࢹ࣮ࢱࢆࠊே㛫ࡢ⬟ຊࡔࡅ࡛ࡍ࡭࡚ฎ⌮ࡍࡿࡢࡣ↓⌮
ࡀ࠶ࡾࠊࢥࣥࣆ࣮ࣗࢱ࡟ࡼࡿゎᯒᨭ᥼ࡸゎᯒ⮬ື໬ࡢᚲせᛶࡀቑࡋ࡚࠸ࡿࠋࡑࡇ࡛ࠊᡃࠎࡢ◊✲ᐊ࡛ࡣࠊ
ࢥࣥࣆ࣮ࣗࢱ࡟ࣅࢵࢢࢹ࣮ࢱ࠿ࡽࡢ▱㆑ࡢㄞࡳྲྀࡾࡸⓎぢࢆࡉࡏࡿࡓࡵࠊࢹ࣮ࢱ࣐࢖ࢽࣥࢢཬࡧᶵᲔᏛ
⩦࡜࿧ࡤࢀࡿゎᯒ᪉ἲࡸᢏ⾡ࡢ◊✲㛤Ⓨࢆࡋ࡚࠸ࡿࠋࡇࢀ࡟ࡣᵝࠎ࡞᥈⣴ࠊ᳨⣴ࠊ⤫ィࠊ☜⋡ィ⟬ࠊࢹ
࣮ࢱ࣮࣋ࢫࠊࡑࢀࡽࢆ⼥ྜࡋࡓ⌮ㄽࠊᡭἲࠊᢏ⾡ࠊࢩࢫࢸ࣒ࢶ࣮ࣝࡀྵࡲࢀࡿࠋࡑࡋ࡚᭦࡟ࠊࡑࢀࡽᇶ
♏◊✲ᡂᯝࢆ⛉Ꮫࠊ᝟ሗࢿࢵࢺ࣮࣡ࢡࠊရ㉁࣭ࣜࢫࢡ⟶⌮ࠊ་⒪ࠊࢭ࢟ࣗࣜࢸ࢕࣮ࠊ࣐࣮ࢣࢸ࢕ࣥࢢࠊ
㔠⼥࡞࡝ࠊᵝࠎ࡞ศ㔝࡟ᙺ❧࡚ࡿᛂ⏝◊✲ࡶ⾜ࡗ࡚࠸ࡿࠋ௒ᖺᗘࡣࠊ᫖ᖺᗘ࡟ᘬࡁ⥆ࡃ㉸㧗ḟඖࢹ࣮ࢱ
࠿ࡽࡢ᝟ሗ᥎ᐃ࣭▱㆑Ⓨぢࠊᅉᯝᵓ㐀᥈⣴ࡢࡓࡵࡢࢹ࣮ࢱゎᯒἲࡢ㛤Ⓨࠊ⤌ྜࡏㄽⓗィ⟬࡟ࡼࡿ㧗ḟඖ
ࢹ࣮ࢱ࠿ࡽࡢ▱㆑Ⓨぢ࡟ຍ࠼࡚ࠊ኱つᶍࢹ࣮ࢱ࠿ࡽࡢ⤫ィⓗ᳨ᐃ௬ㄝⓎぢᡭἲࡢ㛤Ⓨࢆ᪂ࡓ࡞◊✲ࢸ࣮
࣐࡜ࡋ࡚㛤ጞࡋࠊ௨ୗࡢᡂᯝࢆᚓࡓࠋ
― 42 ―
b) ᡂᯝ
࣭㉸㧗ḟඖࢹ࣮ࢱ࠿ࡽࡢ᝟ሗ᥎ᐃ࣭▱㆑Ⓨぢ
⛉Ꮫⓗ ᐃᢏ⾡ࠊࢥࣥࣆ࣮ࣗࢱࢿࢵࢺ࣮࣡ࢡ࡜ࣘࣅ࢟ࢱࢫࢭࣥࢩࣥࢢᢏ⾡࡞࡝Ⓨ㐩࡟ࡼࡗ࡚ࠊ౛࠼ࡤ
⑓㝔࡟࠾ࡅࡿྛᝈ⪅࡟㛵ࡍࡿ᳨ᰝࠊデ᩿ࠊ἞⒪ࠊᢞ⸆ࡢෆᐜࡸࡑࡢᒚṔ࡜࠸ࡗࡓࡓࡃࡉࢇࡢ஦᯶࣭஦㇟࣭
≧ែ࡟㛵ࡍࡿ⭾኱࡞ኚᩘࡢ ᐃࢹ࣮ࢱ㸦㉸㧗ḟඖࢹ࣮ࢱ㸧ࡀ཰㞟࡛ࡁࡿࡼ࠺࡟࡞ࡗ࡚᮶࡚࠸ࡿࠋࡲࡓࠊ
ࢢ࣮ࣟࣂࣝ࡞ᆅ⌫⎔ቃኚ໬ࡸ㑇ఏᏊ㛫┦஫స⏝ࢿࢵࢺ࣮࣡ࢡ࡞࡝ࠊᕧ኱࡞ᵓ㐀≧ែࡢ ᐃ⤖ᯝࡶ㉸㧗ḟ
ඖᵓ㐀໬ࢹ࣮ࢱ࡜ࡋ࡚཰㞟ࡉࢀ࡚࠸ࡿࠋᡃࠎࡣࠊࡇࡢࡼ࠺࡞㧗ḟඖ࡛」㞧࡞ᑐ㇟ࢹ࣮ࢱࢆゎᯒࡋ࡚ࠊࡑ
ࡢ࣓࢝ࢽࢬ࣒࡟㛵ࡍࡿ᝟ሗࡢ᥎ᐃࡸ▱㆑ࢆⓎぢࡍࡿᢏ⾡ࡢ◊✲࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿࠋᮏᖺᗘࡶᘬࡁ⥆ࡁࠊ
ᩘ༑࠿ࡽᩘ༓ḟඖࡢࢹ࣮ࢱ✵㛫ෆ࡛ᑐ㇟ࢆ⾲⌧ࡍࡿࣔࢹࣝࡢ᥈⣴࡜ࡑࢀࢆ⏝࠸ࡓ᥎ㄽࢆ⾜࠺㧗ᗘ࡞ᶵ
ᲔᏛ⩦ᡭἲࠊࢹ࣮ࢱ࣐࢖ࢽࣥࢢᡭἲࡢ◊✲ࢆ⾜ࡗࡓࠋࡲࡓࠊࡇࢀࢆᇶ࡟ࢡࣛࢫࢱࣜࣥࢢࡸศ㢮ࠊ᥎ᐃࢆ
⾜࠺ᡭἲࡢ㛤Ⓨࢆ⾜࠸ࠊ」㞧ࠊ኱つᶍ࡞ᑐ㇟࡟ࡘ࠸࡚ᚑ᮶ᡭἲࡼࡾ㧗ຠ⋡ࠊ㧗⢭ᗘ࡞⤖ᯝࢆᚓࡿぢ㏻ࡋ
ࢆᚓࡓࠋ
࣭ᅉᯝᵓ㐀᥈⣴ࡢࡓࡵࡢࢹ࣮ࢱゎᯒἲࡢ㛤Ⓨ
ࢹ࣮ࢱ࡟₯ࡴᅉᯝᵓ㐀ࢆ᥎ᐃࡍࡿࡓࡵࡢ⤫ィⓗ᪉ἲࢆ㛤Ⓨ࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿࠋ᥎ᐃࡉࢀࡓᅉᯝᵓ㐀ࡣ
ࢢࣛࣇ࢕࢝ࣝ࡟ᅗ࡜ࡋ࡚⾲⌧ྍ⬟࡞ࡢ࡛ࠊ⤫ィ⛉Ꮫࡢᑓ㛛ᐙ࡛࡞࠸ᛂ⏝◊✲ࡢᑓ㛛ᐙ࡟ࡶ⤖ᯝࢆ⌮ゎࡋ
ࡸࡍ࠸฼Ⅼࡀ࠶ࡿࠋ◊✲࡛ࡣࠊᩘᏛࢆ౑ࡗ࡚࢔ࣝࢦࣜࢬ࣒ࡢṇࡋࡉࢆド᫂ࡋࠊࡑࡢࢯࣇࢺ࢙࢘࢔࡬ࡢᐇ
⿦ࠊ᳨ドࢆ⾜ࡗ࡚࠸ࡿࠋࡲࡓࠊࢯࣇࢺ࢙࢘࢔ࢆබ㛤ࡍࡿࡇ࡜࡛ࠊㄡ࡛ࡶ฼⏝࡛ࡁࡿࡼ࠺࡟ᚰࡀࡅ࡚࠸ࡿࠋ
ࡇࡢᡭἲࡢ᭷ᮃ࡞ᛂ⏝ศ㔝࡜ࡋ࡚ࡣࠊࣂ࢖࢜࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫࠊࢽ࣮ࣗࣟ࢖ࣥࣇ࢛࣐ࢸ࢕ࢡࢫࠊ⤒῭
Ꮫࠊᚰ⌮Ꮫࠊ♫఍Ꮫ࡞࡝ࡀᣲࡆࡽࢀࡿࠋᮏᖺᗘࡣࠊࢹ࣮ࢱࡢ㠀࢞࢘ࢫᛶࢆ฼⏝ࡍࡿࡇ࡜࡛ࠊ⬻άືィ ࢹ࣮ࢱࢆ౑ࡗ࡚ࠊ⬻㡿ᇦ㛫ࡢᅉᯝᵓ㐀ࢆ᥈⣴ࡋࠊ⿕㦂⪅ࡢᒓᛶࢆண ࡍࡿィ⟬࢔ࣝࢦࣜࢬ࣒࡟㛵ࡍࡿ◊
✲ࢆ⾜ࡗࡓࠋࡲࡓࠊᮍほ ᅉᯝᵓ㐀᥈⣴࡟࠾ࡅࡿ㞴㢟ࡢ୍ࡘᮍほ ஺⤡ኚᩘࡢၥ㢟ࢆ⫯ᐃⓗ࡟ゎỴࡍࡿ
ࢹ࣮ࢱゎᯒࣇ࣮࣒࣮ࣞ࣡ࢡࢆ㛤Ⓨࡋࡓࠋ
࣭⤌ྜࡏㄽⓗィ⟬࡟ࡼࡿ㧗ḟඖࢹ࣮ࢱ࠿ࡽࡢ▱㆑Ⓨぢ
㏆ᖺࡢࢹ࣮ࢱྲྀᚓ࣭⵳✚ᢏ⾡ࡢⴭࡋ࠸ྥୖࢆ⫼ᬒ࡟ࠊᵝࠎ࡞ሙ㠃࡟࠾࠸࡚ࠊ኱つᶍ࣭㧗ḟඖ࡞ࢹ࣮ࢱ
ࢆ⏝࠸ࡓ▱⬟᝟ሗฎ⌮ᢏ⾡㸦࠸ࢃࡺࡿࣅࢵࢢࢹ࣮ࢱᢏ⾡㸧ࡢᚲせᛶࡀᙉࡃㄆ㆑ࡉࢀࡿࡼ࠺࡟࡞ࡗ࡚ࡁࡓࠋ
ࡑࡢฎ⌮࡟࠾࠸࡚ࡣࡋࡤࡋࡤࠊࢹ࣮ࢱ୰࡟฼⏝ྍ⬟࡞㸦⤌ྜࡏⓗ㸧ᵓ㐀ࡀෆᅾࡍࡿሙྜࡀከ࠸ࠋᡃࠎࡣࠊ
ຎࣔࢪࣗࣛᛶ࡜࿧ࡤࢀࡿ⤌ྜࡏⓗฝᛶ࡟ᇶ࡙ࡁࡇࡢࡼ࠺࡞ᵓ㐀ࢆィ⟬୰࡛⏝࠸ࡿ஦࡛ࠊゎ㔘ᛶࡸ⢭ᗘࡢ
㧗࠸▱ⓗฎ⌮ࢆᐇ⌧ࡍࡿ㧗㏿࢔ࣝࢦࣜࢬ࣒ࡢ㛤Ⓨ࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿࠋᮏᖺᗘࡣ≉࡟ࠊᵓ㐀ṇ๎໬Ꮫ⩦࡜
࿧ࡤࢀࡿࠊࢹ࣮ࢱ୰ࡢᵓ㐀ࢆ⏝࠸ࡓᶵᲔᏛ⩦ᡭἲ࡬ࡢ㧗㏿࢔ࣝࢦࣜࢬ࣒ࡢ㛤Ⓨࢆ⾜ࡗࡓࠋࡑࡋ࡚ࠊࡇࢀ
ࢆ㑇ఏᏊࢹ࣮ࢱゎᯒࡸࢥࣥࣆ࣮ࣗࢱ࣭ࣅࢪࣙࣥࡢㅖၥ㢟࡟ᑐࡋ࡚㐺⏝ࢆ⾜࠸ࠊྛᛂ⏝࡟࠾ࡅࡿ㧗࠸᭷⏝
ᛶ࡟ࡘ࠸࡚☜ㄆࢆ⾜ࡗࡓࠋ
࣭኱つᶍࢹ࣮ࢱ࠿ࡽࡢ⤫ィⓗ᳨ᐃ௬ㄝⓎぢᡭἲࡢ㛤Ⓨ
኱つᶍࢹ࣮ࢱ࡟₯ࡴ⤌ྜࡏⓗᵓ㐀㸦ࣃࢱ࣮ࣥ㸧ࡢⓎぢࡣࠊ๰⸆࠿ࡽ࣐࣮ࢣࢸ࢕ࣥࢢࡲ࡛ᵝࠎ࡞ศ㔝࡛
ά⏝ࡉࢀ࡚࠸ࡿࠋ≉࡟ࠊ⤫ィⓗ࡟᭷ព࡟㢖ฟࡍࡿࣃࢱ࣮ࣥࡢⓎぢࡣࠊᵝࠎ࡞⌧㇟ࡢ⌮ゎ࡟Ḟ࠿ࡏ࡞࠸ゎ
ᯒᡭẁ࡜ࡋ࡚ࠊከࡃࡢศ㔝࡛ᚲ㡲ࡢせㄳ࡜࡞ࡗ࡚࠸ࡿࠋᡃࠎࡣࠊࣃࢱ࣮ࣥิᣲࡀィ⟬㔞⇿Ⓨࢆ㉳ࡇࡍၥ
㢟࡜ࠊ⤫ィⓗ௬ㄝ᳨ᐃࡢ⧞ࡾ㏉ࡋ࡟㉳ᅉࡋ࡚ഇ㝧ᛶࡢࣃࢱ࣮ࣥࡀቑຍࡋ࡚ࡋࡲ࠺ၥ㢟ࢆྠ᫬࡟ゎỴࡍࡿ
ࡇ࡜࡛ࠊ኱つᶍࢹ࣮ࢱ࠿ࡽ⤫ィⓗ࡟᭷ព࡟⌧ࢀࡿࣃࢱ࣮ࣥࢆຠ⋡ࡼࡃ᳨ฟࡍࡿᢏ⾡ࢆ㛤Ⓨࡋ࡚࠸ࡿࠋᮏ
ᖺᗘࡣࠊ๰⸆࡞࡝࡛⏝࠸ࡽࢀࡿࢢࣛࣇᵓ㐀ࢆᣢࡘࢹ࣮ࢱ࡟╔┠ࡋࠊ⤫ィⓗ࡟᭷ព࡞ࢢࣛࣇࡢ㒊ศᵓ㐀ࢆ
Ⓨぢࡍࡿ㧗㏿࢔ࣝࢦࣜࢬ࣒ࡢ㛤Ⓨࢆ࠾ࡇ࡞࠸ࠊࡑࡢᛶ⬟ࢆᐇ㝿ࡢ໬ྜ≀ࢹ࣮ࢱࡸࢱࣥࣃࢡࢹ࣮ࢱ࡛☜ㄆ
ࡋࡓࠋ
― 43 ―
▱㆑⛉Ꮫ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
≉௵ຓᩍ
≉௵◊✲ဨ
኱Ꮫ㝔Ꮫ⏕
Ꮫ㒊Ꮫ⏕
஦ົ⿵బဨ
㥖㇂
౗ᮧ
Ṋ⏣
ᒣ⦩
➲ᔱ
すᮧ
ᑠᯘ
ᒾᮏ
ᮏⷵ
࿴⠊
ᚨಙࠊྂᓮ ᫭ྖ
㱟㸦2014 ᖺ 10 ᭶ 1 ᪥᥇⏝㸧
཭⣖
᐀ᙪ㸦2014 ᖺ 10 ᭶ 31 ᪥ࡲ࡛㸧
ᝅྐࠊᮡᒣ ㈗᫛ࠊᒣ⦩ ཭⣖㸦2014 ᖺ 10 ᭶ 1 ᪥࠿ࡽ㸧
ࠊቑ⏣ ኊᚿࠊ
㝧ࠊከ⏣ ᜤᖹ
ಇ㍜ࠊ㫽ᮧ ໶ࠊ୰㔝 㡿♸ࠊᰗ⏣ ⯗ᖹ
༓㭯Ꮚ㸦2014 ᖺ 5 ᭶ 16 ᪥᥇⏝㸧
a) ᴫせ
㏆ᖺࠊࢥࣥࣆ࣮ࣗࢱࡢィ⟬⬟ຊࡸࣟ࣎ࢵࢺࡢ㐠ື⬟ຊࡣ㣕㌍ⓗ࡟ྥୖࡋ࡚࠸ࡿ୍᪉࡛ࠊே㛫࡜㈼ࡃヰ
ࡍ࡜࠸ࡗࡓ▱⬟ࡢ㒊ศࡣᮍࡔⓎᒎ㏵ୖ࡛࠶ࡿࠋᶵᲔࡀே㛫࡟࡜ࡗ࡚㌟㏆࡛౑࠸ࡸࡍ࠸Ꮡᅾ࡜࡞ࡿ࡟ࡣࠊ
ே㛫ࡀ⏕᮶ഛ࠼࡚࠸ࡿ㡢ኌᑐヰᶵ⬟ࡀᚲ㡲࡛࠶ࡿࠋᮏ◊✲ศ㔝࡛ࡣࠊ㡢㡪ಙྕฎ⌮࠿ࡽ♫఍ⓗ࢖ࣥࢱࣛ
ࢡࢩࣙࣥࡲ࡛ࢆᗈࡃど㔝࡟ධࢀࠊ㡢ኌㄆ㆑ᢏ⾡ࢆ⏝࠸࡚ே㛫࡜ᑐヰࡍࡿࢩࢫࢸ࣒ࡢᇶ♏ᢏ⾡ࢆ◊✲ࡋ࡚
࠸ࡿࠋࡲࡓ㈼࠸ࢩࢫࢸ࣒࡟ࡣ▱㆑ࡀ୙ྍḞ࡛࠶ࡿࡇ࡜࠿ࡽࠊே㛫ࡀᣢࡘ▱㆑ࢆᩚ⌮ࡋ࡚ィ⟬ᶵྍㄞ࡞ᙧ
ᘧ࡛グ㏙ࡍࡿ࢜ࣥࢺࣟࢪ࣮ᕤᏛ࡟ࡶྲྀࡾ⤌ࢇ࡛࠸ࡿࠋࡇࢀࡽࢆ㏻ࡌ࡚ࠊே࡜ᑐヰ࡛ࡁࡿ▱ⓗ࡞ࢥࣥࣆࣗ
࣮ࢱࡢᐇ⌧ࢆ┠ᣦࡋ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭㞧㡢࡟㡹೺࡞㡢ኌᑐヰࣟ࣎ࢵࢺࡢᵓ⠏
ᐇ⎔ቃ࡛㡢ኌᑐヰࢆ⾜࠺ࣟ࣎ࢵࢺ࡟ᚲせ࡞ᶵ⬟࡜ࡋ࡚ࠊ㞧㡢࡟ᑐࡋ࡚ㄗືసࡋ࡞࠸ࡇ࡜ࡀᣲࡆࡽࢀࡿࠋ
ᮏ◊✲࡛ࡣࠊ1) ⫼ᚋ࠿ࡽࡍࡿ㡢ࡢᲠ༷ࠊ2) 㞧㡢ࡢᲠ༷ࠊ3) Ⓨヰ⪅ࡢ㏣ᚑࠊࢆ⾜࠺ࡇ࡜࡛ࣟ࣎ࢵࢺࡢ⪏
㞧㡢ᛶࢆྥୖࡉࡏࡿࠋึࡵࡢ㡯┠࡟㛵ࡋ࡚ࡣࠊ㡢※᪉ྥࢆṇࡋࡃ᳨ฟࡋࠊ᪉ྥ᝟ሗ࡟ᇶ࡙࠸࡚ࣇ࢕ࣝࢱ
ࣜࣥࢢࡍࡿࡇ࡜࡛㐩ᡂࡍࡿࠋලయⓗ࡟ࡣ㡢※᪉ྥ࡜ࣟ࣎ࢵࢺࡢྛ࣐࢖ࢡ㛫ࡢ㡢㡪ఏ㐩㛵ᩘࢆ↓㡪ᐊ࡛ ᐃࡋࠊࣟ࣎ࢵࢺࡢᙧ≧ࡢᐃ఩࡬ࡢᙳ㡪
ࢆṇࡋࡃᤊ࠼ࡿࠋࡉࡽ࡟ࠊࣟ࣎ࢵࢺ⮬
㌟࠿ࡽⓎࡏࡽࢀࡿ㞧㡢ࡢ≉ᛶ࡜㡢㡪
ఏ㐩㛵ᩘ࡬ࡢᙳ㡪ࢆ⪃៖ࡋࡓᐃ఩ᡭ
ἲࢆ㛤Ⓨࡋࠊᚑ᮶ᢏ⾡ࡼࡾࡶ㡢ࡢㄗ᳨
ฟࢆపῶࡋ࡚࠸ࡿࠋ2 ࡘ┠ࡢ㡯┠ࡣࠊ
ே ࡢ ኌ ࡜ 㞧 㡢 ࢆ Gaussian Mixture
Model ࡟ᇶ࡙ࡃ㆑ูჾࢆ⏝࠸࡚ᐇ⌧ࡋ
ࡓࠋ᭱ᚋࡢ㡯┠࡟㛵ࡋ࡚ࡣࠊIntraFace
ࢆ⏝࠸ࡓ㢦ㄆ㆑࡟ᇶ࡙࠸࡚ヰ⪅ࢆ㏣
ᚑ࡛ࡁࡿࡇ࡜ࢆ☜ㄆࡋ࡚࠸ࡿࠋ
ᅗ ࣟ࣎ࢵࢺ࡜ࡢᑐヰ㸦ᕥ㸧࡜㡢※ᐃ఩౛㸦ྑ㸧
࣭ᑐヰࢆ㏻ࡌࡓ▱㆑⋓ᚓ
┦ᡭࡢヰࢆ⪺ࡁࠊࡑࡇ࠿ࡽ᪂ࡓ࡞▱㆑ࢆ⋓ᚓࡍࡿࡢࡣࠊே㛫ࡀᣢࡘ▱ⓗ࡞ᶵ⬟ࡢࡦ࡜ࡘ࡛࠶ࡿࠋ⌧≧
ࡢᑐヰࢩࢫࢸ࣒࡛ࡣࠊࢩࢫࢸ࣒㛤Ⓨ⪅ࡢタィ࡟ᇶ࡙࠸࡚ᑐヰࢆ⾜࠺ࡇ࡜ࡣ࡛ࡁࡿࡀࠊᑐヰࢆ㏻ࡌ࡚᪂ࡓ
࡞▱㆑ࢆ⋓ᚓࡍࡿ࡜࠸࠺ᶵ⬟ࡣᣢࡗ࡚࠸࡞࠸ࠋ≉࡟ಶࠎࡢࢻ࣓࢖ࣥ࡟࠾ࡅࡿᒁᡤⓗ࡞▱㆑ࢆࢩࢫࢸ࣒㛤
Ⓨ⪅ࡀᙜึ࠿ࡽ᏶඲࡟グ㏙ࡍࡿࡢࡣᅔ㞴࡛࠶ࡿࡓࡵࠊ▱㆑ࢆ౑⏝ᐇែ࡟ᛂࡌ࡚⋓ᚓࡍࡿᢏ⾡ࡀᚲせ࡛࠶
ࡿࠋ
― 44 ―
ᮏᖺᗘࡣࠊᑐヰ୰࡟⌧ࢀࡓᮍ▱ㄒ࡟㛵ࡍ
ࡿ▱㆑ࡢ⋓ᚓ࡟ྲྀࡾ⤌ࢇࡔࠋᮍ▱ㄒࡣࠊࢩ
ࢫࢸ࣒ࡢ࢜ࣥࢺࣟࢪ࣮ෆ࡟఩⨨࡙ࡅࡽࢀ
࡚࠸࡞࠸ㄒ࡜ࡋࠊ࠿ࡘࠊ࢜ࣥࢺࣟࢪ࣮ෆࡢ
᭱ୗ఩ࢡࣛࢫࡢ࢖ࣥࢫࢱࣥࢫ࡜ࡋࡓࠋࡇࢀ
ࡀᡤᒓࡍࡿࢡࣛࢫࢆྠᐃࡍࡿࡓࡵ࡟ࠊ࢜ࣥ
ࢺࣟࢪ࣮ࡢᮌᵓ㐀ࢆ฼⏝ࡋࡓ㉁ၥࢆ㑅ᢥ
ᅗ ᮍ▱ㄒࡢᡤᒓࢡࣛࢫࢆ⋓ᚓࡍࡿ㉁ၥࡢ౛
ࡋࠊࡑࡢ㉁ၥᅇᩘࡢຠ⋡໬ࢆ≺ࡗࡓࠋ
ࡉࡽ࡟ࠊࡇࢀࢆ㡢ኌᑐヰࢩࢫࢸ࣒࡟㐺⏝ࡋࡓሙྜ࡟ᚲせ࡜࡞ࡿࠊ㡢㡪ࣔࢹࣝࡸゝㄒࣔࢹࣝࡢ⋓ᚓ࡟ࡘ
࠸࡚ࡶ᳨ウࢆ㐍ࡵࡓࠋ
࣭་⒪ࠊᶵ⬟ࠊ⾜Ⅽ࡞࡝ࡢྛ✀࢜ࣥࢺࣟࢪ࣮ࡢᵓ⠏࡜ᛂ⏝ࢩࢫࢸ࣒ࡢ㛤Ⓨ
ィ⟬ᶵ࡛▱㆑ࢆ㐺ษ࡟ᢅ࠺ࡓࡵࡢᇶ♏⌮ㄽࢆᥦ౪ࡍࡿ࢜ࣥࢺࣟࢪ࣮ᕤᏛࡢ⌮ㄽ࡜ᐇ㊶࡟㛵ࡍࡿ◊✲
ࢆ⾜ࡗ࡚࠸ࡿࠋලయⓗ࡟ࡣࠊ1)࢜ࣥࢺࣟࢪ࣮ᵓ⠏࣭฼⏝࡟㛵ࡍࡿᇶ♏⌮ㄽࠊ2)ࡑࢀࡽࡢ⌮ㄽ࡟ᇶ࡙࠸ࡓ
࢜ࣥࢺࣟࢪ࣮࡜ᛂ⏝ࢩࢫࢸ࣒ᵓ⠏ࡢࡓࡵࡢᇶ┙ࢶ࣮ࣝࠕἲ㐀ࠖࡢ㛤Ⓨࠊ3)ᵝࠎ࡞㡿ᇦ࡟࠾ࡅࡿ࢜ࣥࢺࣟ
ࢪ࣮ࡢᵓ⠏࡜ࡑࢀࢆ⏝࠸ࡓᛂ⏝ࢩࢫࢸ࣒ࡢ㛤Ⓨࠊࢆᐇ᪋ࡋ࡚࠸ࡿࠋ⌧ᅾࡣࠊ⑌ᝈࢆ୰ᚰ࡜ࡋࡓ་⒪▱㆑ࠊ
ேᕤ≀ࡢᶵ⬟ࢆ୰ᚰ࡜ࡋࡓᕤᏛ▱㆑ࠊ௓
ㆤ࣭་⒪ศ㔝ࢆ୰ᚰ࡜ࡋࡓே㛫ࡢ⾜Ⅽࠊ⏕
≀ࡢᶍೌ࡟ࡼࡿ〇ရ㛤Ⓨࢆ┠ᣦࡍࣂ࢖࢜
࣑࣓ࢸ࢕ࢡࢫ㸦biomimetics㸧ࠊࢆᑐ㇟࡜ࡋ
ࡓ࢜ࣥࢺࣟࢪ࣮ࡢᵓ⠏࠾ࡼࡧࢩࢫࢸ࣒㛤
Ⓨࢆ㐍ࡵ࡚࠸ࡿࠋ౛࠼ࡤࠊ⑌ᝈࢆᅉᯝ㐃㙐
ࡢ⥲య࡜ࡋ࡚ᤊ࠼ࡿࡇ࡜࡛ᵓ⠏ࡉࢀࡓ⑌
ᝈ࢜ࣥࢺࣟࢪ࣮ࢆࠊWeb ୖ࡛࣮࢜ࣉࣥ࡞ࢹ
࣮ࢱ࣮࣋ࢫ࡜ࡋ࡚බ㛤ࡉࢀ࡚࠸ࡿ Linked
Open Data㸦LOD㸧ࡸゎ๗Ꮫ㒊఩ࡢ 3D ⏬ീ
ࢹ࣮ࢱ࡜㐃ಀࡋ࡚㜀ぴ࡛ࡁࡿࢩࢫࢸ࣒ࢆ
㛤Ⓨࡋࡓ㸦ᅗ 3㸧ࠋࡑࡢࢩࢫࢸ࣒ࡢ᭷⏝ᛶ
ࡀ㧗ࡃホ౯ࡉࢀࠊLinked Open Data ࢳࣕࣞ
ᅗ ⑌ᝈ࢜ࣥࢺࣟࢪ࣮࡜ /LQNHG'DWD ࡟ᇶ࡙ࡃ⑌ᝈ▱㆑ࡢ㜀ぴࢩࢫࢸ࣒
ࣥࢪ Japan2013 ࡟࠾࠸࡚ࠕ࢔ࣉࣜࢣ࣮ࢩࣙ
㸦KWWSORGFPHGRQWRORJ\MS㸧
ࣥ㒊㛛ඃ⚽㈹ࠖࢆཷ㈹ࡋࡓࠋ
― 45 ―
▱⬟࢔࣮࢟ࢸࢡࢳࣕ◊✲ศ㔝
ᩍᤵ
ຓᩍ
኱Ꮫ㝔Ꮫ⏕
Ꮫ㒊Ꮫ⏕
◊✲⏕
஦ົ⿵బဨ
἟ᑿ ṇ⾜
᳃ᒣ ⏥୍ࠊ⚟஭ ೺୍
Danaipat SodkomkhamࠊIra Puspitasariࠊᒸ⏣ ెஅࠊᆏᮏ ᝆ㍜ࠊGraciela Nunez Narvaezࠊ
Nattapong Thammasanࠊ኱ᵳ Ⰻ♸ࠊWasin KalinthaࠊJuan Lorenzo Hagad
ὸᒣ ࿴ᐉ
⸨⏣ ΅ࠊWu Hongle㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥ࠥ㸧
ࠊ
Sopchoke Sirawit㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥ࠥ㸧
⏣㎶ ࡵࡄࡳࠊᖹᯘ ࠶࡙ࡉࠊ᪥ୗ㒊 ⨾ెࠊ኱ሯ ග௦㸦ᖹᡂ 27 ᖺ 2 ᭶ 15 ᪥ࠥ㸧
ࠊ
ᒣᮏ ளᕼᏊ㸦ᖹᡂ 27 ᖺ 2 ᭶ 15 ᪥ࠥ㸧
a) ᴫせ
ࣃࢯࢥࣥࢆึࡵ࡜ࡍࡿ᝟ሗ⎔ቃࡀᬑཬࡍࡿ࡟ࡘࢀ࡚ࠊ࢖ࣥࢱࣇ࢙࣮ࢫࡢᝏࡉ࡟㉳ᅉࡍࡿࢸࢡࣀࢫࢺࣞ
ࢫࡸࠊࢫࣃ࣒࣓࣮ࣝࠊከ㔞ࢹ࣮ࢱ࡟ࡼࡿ᝟ሗὥỈࡢၥ㢟࡟♫఍ࡢ㛵ᚰࡀ㞟ࡲࡗ࡚࠸ࡿࠋᮏ◊✲㒊㛛࡛ࡣࠊ
ࡇࢀࡽࡢཎᅉࡀࢥࣥࣆ࣮ࣗࢱࢩࢫࢸ࣒ࡢᰂ㌾ᛶࡢḞዴ࡟࠶ࡿࡇ࡜ࢆ᪩ࡃ࠿ࡽᣦ᦬ࡋࠊࡑࡢᑐ⟇࡜ࡋ࡚㐺
ᛂ⬟ຊࢆᣢࡗࡓࢥࣥࣆ࣮ࣗࢱࡢ㛤Ⓨࢆᥦၐࡋ࡚ࡁࡓࠋᚰ⌮ᐇ㦂࡜㧗ᗘ࡞ᶵᲔᏛ⩦ᢏ⾡ࡢ⤌ྜࡏ࡟ࡼࡾࠊ
ࡇ࠺ࡋࡓㄢ㢟ࡢඞ᭹ࢆ┠ᣦࡋ࡚࠸ࡿࠋලయⓗ࡞◊✲ㄢ㢟ࡣࠊ௨ୗࡢ㏻ࡾ࡛࠶ࡿࠋ
࠙◊✲ㄢ㢟ࠚ
1㸬ᵓᡂⓗ㐺ᛂ࢖ࣥࢱࣇ࢙࣮ࢫ
2㸬Intelligent Tutoring System
3㸬▱ⓗࣘࣅ࢟ࢱࢫࢭࣥࢧ࣮ࢿࢵࢺ࣮࣡ࢡ
b) ᡂᯝ
࣭ᵓᡂⓗ㐺ᛂ࢖ࣥࢱࣇ࢙࣮ࢫ
ᇶᮏⓗ࡞◊✲ࢸ࣮࣐࡜ࡋ࡚ࠊᏛ⩦ᶵ⬟ࢆᣢࡗࡓࢥࣥࣆ࣮ࣗࢱࡢ㛤Ⓨࢆ㐍ࡵ࡚࠾ࡾࠊ㧗ຠ⋡໬ࡢࡓࡵࡢ
࢔ࣝࢦࣜࢬ࣒ࠊᏛ⩦ࡢࡓࡵࡢ⫼ᬒ▱㆑ࡢ⋓ᚓࠊITS (Intelligent Tutoring System)࡬ࡢᛂ⏝࡞࡝ࠊᩘࠎࡢ᪂
ᢏ⾡ࢆ㛤Ⓨࡋࠊ᝟ሗ⎔ቃࡢᩚഛࢆᨭ᥼ࡋ࡚ࡁ࡚࠸ࡿࠋࡇࢀࡽࡣࠊ㐺ᛂ࣮ࣘࢨ࢖ࣥࢱࣇ࢙࣮ࢫࡢᢏ⾡࡜ࡋ
࡚ᐃ╔ࡋࡘࡘ࠶ࡿࠋࡇࢀࡲ࡛ࡢ㐺ᛂ࣮ࣘࢨ࢖ࣥࢱࣇ࢙࣮ࢫࡣࠊ࠶ࡽ࠿ࡌࡵ⏝ពࡉࢀ࡚࠸ࡿ཯ᛂࡢ୰࠿ࡽ
㐣ཤࡢ࣮ࣘࢨࡢ᣺ࡿ⯙࠸࡟㐺ᛂࡋ࡚ࠊ㐺ษ࡞཯ᛂࢆ㑅ᢥࡍࡿࡶࡢ࡛࠶ࡗࡓࠋࡇࢀࡔࡅ࡛ࡶ⌧ᅾࡢ」㞧࡛
ᢅ࠸࡟ࡃ࠸࣮ࣘࢨ࢖ࣥࢱࣇ࢙࣮ࢫࠊࡓ࡜࠼ࡤࢼࣅࢤ࣮ࢩࣙࣥࢩࢫࢸ࣒࡞࡝ࢆ┦ᙜ࡟ᨵⰋ࡛ࡁࡿࠋࡋ࠿ࡋࠊ
ே㛫ࡢ▱ᛶࡸ๰㐀ᛶࢆ่⃭ࡍࡿ࡟ࡣࠊ୙༑ศ࡛࠶ࡿࠋࡑࡇ࡛㐺ษ࡞཯ᛂࢆ㑅ᢥࡍࡿࡔࡅ࡛ࡣ࡞ࡃࠊ᪂ࡓ
࡞ࢥࣥࢸࣥࢶࢆᵓᡂࡍࡿ
ᡭἲࡢ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋ
ࡑࡢᢏ⾡ࢆ⫼ᬒ࡜ࡋ࡚ࠊ
ᴟࡵ࡚ࣘࢽ࣮ࢡ࡞◊✲ࢸ
࣮࣐࡜ࡋ࡚ࠊឤᛶ⋓ᚓᶵ
ᵓࢆᥦ᱌ࡋࠊ࣮ࣘࢨࡢಶ
ᛶ࡜ឤ᝟࡟㐺ᛂࡋ࡚⮬ື
స᭤ࢆ⾜࠺ࢩࢫࢸ࣒ࢆ㛤
Ⓨࡋࡓࠋࡉࡽ࡟ࠊ⏕యࢭ
ࣥࢧࢆ⏝࠸ࡓ࿴㡢㐍⾜ࡢ
ホ౯ᐇ㦂ࢆ㐍ࡵࡓࠋ
― 46 ―
࣭Intelligent Tutoring System
ᣦᑟࣉࣛࣥ࡟Ꮫ⩦㐣⛬ࡢᣦ㔪ࢆᣢࡓࡏࡿࡇ࡜ࡣᵝࠎ࡞ᩍ⫱᪉ἲ࡟࡜ࡗ࡚᭷ຠ࡛࠶ࡾࠊITS ࡟࠾࠸࡚㔜
せ࡞ㄢ㢟࡛࠶ࡿࠋࡇࡢㄢ㢟࡟ᑐࡋ࡚ᵝࠎ࡞ྲྀࡾ⤌ࡳࡀ࡞ࡉࢀࡓࡀࠊITS ࡟࡜ࡗ࡚ᴟࡵ࡚ᚲせ࡜࡞ࡗ࡚ࡃ
ࡿࡢࡣࠊືⓗ࡟❧࡚ࡽࢀࡓࣉࣛࣥࢆ⮬ᕫᨵၿࡍࡿࡇ࡜࡛࠶ࡿࠋᏛ⩦⪅ࡢ࢝ࢸࢦ࣮ࣜ࠿ࡽᚓࡽࢀࡓ▱㆑ࢆ
฼⏝ࡍࡿࡇ࡜ࡀࠊITS ഃ࠿ࡽࡢࣉࣛࣥࡢᨵၿ࡟ᴟࡵ࡚᭷⏝࡛࠶ࡿ࡜௬ᐃࡋ࡚࠸ࡿࠋࡘࡲࡾ࢝ࢸࢦ࣮ࣜ▱
㆑࡟ࡼࡗ࡚ຠᯝⓗ࡞ࣉࣛࣥࡀᚓࡽࢀࡿࠋᡃࠎࡣࠊᏛ⩦⪅ࡢ࢝ࢸࢦ࣮ࣜ࠿ࡽᏛ⩦ࡋࡓ▱㆑ࢆ฼⏝ࡋ࡚ࣉࣛ
ࣥࢆ⮬ᕫᨵၿࡍࡿࣉࣛࣥࢼ࣮(CSPM)ࢆᥦ᱌ࡍࡿࠋCSPM ࡢᏛ⩦ࡣࠊᩍᖌ࡞ࡋᶵᲔᏛ⩦࡜⤒㦂࠿ࡽᏛ⩦ࡍ
ࡿࡓࡵࡢ▱㆑⋓ᚓࣄ࣮ࣗࣜࢫࢸ࢕ࢡࢫࢆ⏝࠸࡚⾜ࢃࢀࡿࠋグ㘓ࡉࢀࡓᩍ⫱ィ⏬ࢆ⏝࠸࡚ CSPM ࡢྍ⬟ᛶ
ࢆ☜࠿ࡵࡿᐇ㦂ࢆ⾜ࡗࡓࠋ
࣭▱ⓗࣘࣅ࢟ࢱࢫࢭࣥࢧ࣮ࢿࢵࢺ࣮࣡ࢡ
㏆ᖺࡢࣘࣅ࢟ࢱࢫྛ✀ᢏ⾡ࡸ RFID ࡞࡝ࡢࢱࢢᢏ⾡ࡢⓎᒎ࡟క࠸ࠊ⌧≧࡟࠾࠸࡚ࡶ᪤࡟᝟ሗ㐣ከࡢၥ
㢟࡟┤㠃ࡋ࡚࠸ࡿ࢖ࣥࢱ࣮ࢿࢵࢺࢆ୰ᚰ࡜ࡍࡿ᝟ሗ✵㛫࡟ᑐࡋࠊᐇ✵㛫࠿ࡽࡢ᝟ሗࡲ࡛ࡶࡀ኱㔞࡟ὶࢀ
㎸ࡶ࠺࡜ࡋ࡚࠸ࡿࠋࡑ࠺࡞ࡿ࡜ࠊࡶࡣࡸࠕ᳨
⣴ⓗᡭἲ࡛ࠖࡣࡍ࡭࡚ࡢ᝟ሗࢆ⥙⨶ࡍࡿࡇ࡜
ࡣᅔ㞴࡞ࡶࡢ࡜࡞ࡾ㸦⌧≧࡛ࡶ᪤࡟ࡑࡢ≧ἣ
࡟࠶ࡿ㸧
ࠊࡇࢀ࠿ࡽࡣࠕⓎぢⓗᡭἲࠖࡀᮃࡲ
ࢀࡿࠋࡇࢀࡲ࡛ࡶ᝟ሗⓎぢᡭἲ࡜ࡋ࡚ࢹ࣮ࢱ
࣐࢖ࢽࣥࢢ◊✲࡞࡝⢭ຊⓗ࡞◊✲ࡀ࡞ࡉࢀ
࡚᮶࡚࠸ࡿࡶࡢࡢࠊ
ࠕ᝟ሗ✵㛫㸩ᐇ✵㛫ࠖ࡜
࠸࠺ࠊᕧ኱࡛」㞧࠿ࡘືⓗ࡞ୡ⏺࠿ࡽࡢ᭷⏝
࡞᝟ሗᢳฟᢏ⾡࡟ᑐࡋ࡚ࠊࡇࢀࡲ࡛ࡢᢏ⾡ࡀ
ࡑࡢࡲࡲ㐺⏝࡛ࡁࡿ࡜᩿ゝࡍࡿࡇ࡜ࡣฟ᮶
࡞࠸ࠋ
୍᪉ࠊᡃࠎࡣ┦ᡭ࡜௨ᚰఏᚰࡸ㜿࿂ࡢ࿧྾
ࡢ㛵ಀࡀฟ᮶࡚࠸ࡿ᫬ࠊ୍యឤࢆឤࡌࡿ࡞࡝ᚰᆅࡼࡃឤࡌࡿࠋࡇࢀࡣ࠾஫࠸ࡀ࠾஫࠸ࡢពᅗࡸ⩦័ⓗ࡞
⾜ືࢆண ࡛ࡁࡿ࠿ࡽ࡛࠶ࡾࠊᑐヰࡸ஬ឤࢆ㏻ࡋ࡚㛗࠸᫬㛫ࢆ࠿ࡅࡓᏛ⩦࡟ࡼࡿࡶࡢ࡛࠶ࡿࠋࡇࡢࡼ࠺
࡞ࣄࢺ࡜ࣄࢺ࡛ࡢ㛵ಀࢆࠊࣄࢺ࡜⎔ቃ࡜ࡢ㛫࡟࠾࠸࡚ࡶᵓ⠏ࡍࡿࡇ࡜ࡀฟ᮶ࡿ࡜ࠊ᪥ᖖ⏕άࡀࡼࡾຠ⋡
ⓗ࡟࡞ࡾࠊࡲࡓᑠࡉ࡞␗ኚ࡞࡝ࢆ⮬ືⓗ࡟Ⓨぢ࡛ࡁࡿࡇ࡜࠿ࡽࣜࢫࢡᅇ㑊ࡢࡓࡵࡢᢏ⾡࡜ࡋ࡚ࡶ᭷⏝࡞
ࡶࡢ࡜࡞ࡿࠋ
ࡇࡢࡼ࠺࡟ࠊࡇࢀ࠿ࡽࡢࣘࣅ࢟ࢱࢫ♫఍࡛ࡣ༢࡟᝟ሗ✵㛫ࡸᐇ✵㛫࠿ࡽࢹ࣮ࢱࢆᢳฟࡍࡿࡔࡅ࡛࡞ࡃࠊ
ᚓࡽࢀࡓ᭷⏝࡞᝟ሗࢆ⬟ືⓗ࡟ே࡟ᑐࡋ࡚⎔ቃഃ࠿ࡽ࢖ࣥࢱࣛࢡࢩࣙࣥࢆ㉳ࡇࡍࡓࡵࡢࣇ࣮࣒࣮ࣞ࣡
ࢡࢆ๰ฟࡍࡿࡇ࡜ࡶ᭷⏝࡛࠶ࡾࠊලయⓗ࡟ࡣࠊ
(1)⎔ቃ࡬ࡢࣄࢺࡢ⾜ືࢆ▱ぬࡍࡿࢭࣥࢩࣥ
ࢢ⬟ຊࡢ௜ຍࠊ(2)ࢭࣥࢧ࣮ࢹ࣮ࢱ࣐࢖ࢽࣥࢢ
࡟ࡼࡿࣄࢺࡢ⩦័ⓗ⾜ືࣃࢱࣥࡢᢳฟࠊ୪ࡧ
࡟ᢳฟ⤖ᯝࢆ⏝࠸ࡓࣄࢺࡢ⾜ືண ࢆ⾜࠺
࢔ࣝࢦࣜࢬ࣒ࡢ๰ฟࠊࡑࡋ࡚(3)ண ⤖ᯝ࡟ᇶ
࡙ࡃࣄࢺ࡬ࡢ࢖ࣥࢱࣛࢡࢩࣙࣥ⬟ຊࡢ⎔ቃ
࡬ࡢ௜ຍࢆ⾜࠺ᚲせࡀ࠶ࡿࠋᮏᖺᗘࡣ(2)ࡢ࣐
࢖ࢽࣥࢢᢏ⾡๰ฟ࡟࠾࠸࡚ࠊ᫬⣔ิࢹ࣮ࢱ࠿
ࡽࡢࣃࢱࣥᢳฟᡭἲࠊ୪ࡧ࡟(3)ࡢ࢖ࣥࢱࣛࢡ
ࢩࣙࣥ࠾࠸࡚ಶே࡟㐺ᛂࡋࡓ࢖ࣥࢱࣛࢡࢩ
ࣙࣥࢆᙉ໬Ꮫ⩦࡟࡚⋓ᚓࡍࡿᡭἲࢆ୰ᚰ࡜
ࡋ࡚◊✲ࢆᒎ㛤ࡉࡏࠊࡑࢀࡒࢀ⊂⮬ࡢᡭἲࢆ
ᥦ᱌ࡍࡿ࡟⮳ࡗ࡚࠸ࡿࠋ
― 47 ―
➨㸰◊✲㒊㛛㸦ᮦᩱ࣭ࣅ࣮࣒⛉Ꮫ⣔㸧
ᴫせ
ᮏ◊✲㒊㛛ࡣࠊ㔞Ꮚᶵ⬟ᮦᩱࠊඛ➃ᐇ⿦ᮦᩱࠊ༙ᑟయᮦᩱ࣭ࣉࣟࢭࢫࠊඛ➃ࣁ࣮ࢻᮦᩱࠊບ㉳≀ᛶ
⛉Ꮫࠊ㔞Ꮚࣅ࣮࣒Ⓨ⏕⛉Ꮫࠊ㔞Ꮚࣅ࣮࣒≀㉁⛉Ꮫࠊࡢ ◊✲ศ㔝࠿ࡽ࡞ࡿࠋ௒ᚋࡢᛴ㏿࡞⛉Ꮫᢏ⾡ࡢⓎ
ᒎࢆᨭ࠼ࡿࡓࡵ࡟ࡣࠊ᪂つ࡞㧗ḟᶵ⬟ࢆᣢࡘᮦᩱࡢ๰ᡂࡀ୙ྍḞ࡛࠶ࡾࠊࡑࡢᒎ㛤ࡣࠊㅖᶵ⬟Ⓨ⌧ᶵᵓ
࡟㛵ࡍࡿ῝ࡃ㇏࠿࡞▱ぢ࡜ᮦᩱᵓ㐀ไᚚᢏ⾡࣭๰〇ᡭἲࡢ㠉᪂ⓗ㧗ᗘ໬࡟ࡼࡗ࡚㐩ᡂࡉࢀࡿࠋࡑࡢࡓࡵ
࡟ࠊ᪤Ꮡࡢ㔠ᒓ࣭↓ᶵ࣭᭷ᶵᮦᩱ◊✲ࡢᯟࢆ㉸࠼ࡓ㧗ḟࣉࣟࢭࢵࢩࣥࢢ࡟ᇶ࡙ࡃᮦᩱタィ࣭㛤Ⓨ࣭ᛂ⏝
ࢆඹ㏻ࡢᣦ㔪࡜ࡋ࡚ࠊ᪂つ࡞ᵓ㐀࣭ᶵ⬟ࢆࡶࡘ᝟ሗᮦᩱࠊ࢚ࢿࣝࢠ࣮ᮦᩱࠊ་⒪ᮦᩱ࡞࡝ࢆ๰〇ࡋࠊࡑ
ࡢᵓ㐀ゎᯒ࣭≀ᛶゎ᫂࡜ᗈ⠊࡞♫఍ⓗせㄳ࡟ࡇࡓ࠼ࡿᛂ⏝ࢆ┠ᣦࡍ◊✲ࢆᒎ㛤ࡋ࡚࠸ࡿࠋࡲࡓࠊ㸰㸮ୡ
⣖ࡢ⛉Ꮫᢏ⾡ࢆᨭ࠼࡚ࡁࡓࣅ࣮࣒⛉Ꮫࢆ᭦࡟ⓎᒎࡉࡏࡿⅭ࡟ࠊ᪂ࡋ࠸㧗㍤ᗘ࣭㧗ရ㉁ࡢ㔞Ꮚࣅ࣮࣒ࡢⓎ
⏕࣭ไᚚ࣭ィ ࡟㛵ࡍࡿ◊✲࡜ࠊ㔞Ꮚࣅ࣮࣒ㄏ㉳⌧㇟ࡢṇ☜࡞⌮ゎ࡟ᇶ࡙࠸ࡓඛ➃ࣅ࣮࣒ᛂ⏝◊✲ࢆ᥎
㐍ࡋ࡚࠸ࡿࠋᮏ◊✲㒊㛛ࡣࠊ⏘ᴗ⛉Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮࠾ࡼࡧ㔞Ꮚࣅ࣮࣒⛉Ꮫ◊✲᪋タ࡜ᐦ᥋
࡞༠ຊ㛵ಀࢆᣢࡕ࡞ࡀࡽ◊✲ࢆ⾜ࡗ࡚࠾ࡾࠊ᭦࡟ࡣࠊศ㔝࣭㒊㛛㛫ࡢඹྠ◊✲ࡢࡳ࡞ࡽࡎࠊᅜබ❧◊✲
ᶵ㛵ࠊẸ㛫௻ᴗ࡞ࡽࡧ࡟ᅜ㝿ⓗ࡞ඹྠ◊✲࡟ࡶ✚ᴟⓗ࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿࠋ
ᡂᯝ
࣭ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࡢᮦᩱ㛤Ⓨ࡜≀ᛶゎ᫂
࣭ࢺ࣏ࣟࢪ࢝ࣝ㉸ఏᑟయ࡞࡝᪂ወ࡞㉸ఏᑟయࡢ᥈⣴࡜≀ᛶゎ᫂
࣭໬Ꮫⓗᵓ㐀㌿෗ἲ࡟ࡼࡿᴟప཯ᑕከ⤖ᬗࢩࣜࢥࣥᇶᯈࡢᙧᡂ
࣭Si ษ⢊࠿ࡽ๰〇ࡋࡓ Si ࢼࣀ⢏ᏊࡢⓎගᮦᩱࡸ㟁ụᮦᩱ࡬ࡢᛂ⏝
࣭⮬ᕫ⤌⧊໬ࣉࣟࢭࢫ࡟ᇶ࡙ࡃ㓟໬≀༙ᑟయ࣊ࢸࣟ」ྜᵓ㐀ࢭ࣑ࣛࢵࢡࢫࡢ๰ᡂ࡜ᶵᵓゎ᫂
୍࣭᪉ྥ࣏࣮ࣛࢫ࣐ࢢࢿࢩ࣒࢘ࡢረᛶኚᙧᣲືࡢゎ᫂
࣭㖟ሷ࢖ࣥࢡࡢ㛤Ⓨ࡜ࡑࡢᇶ♏≉ᛶࡢゎ᫂
࣭㧗 ࡣࢇࡔ㛤Ⓨ࣭Sn ࢘࢕ࢫ࢝Ⓨ⏕࣓࢝ࢽࢬ࣒ࡢゎ᫂
࣭ࣇ࢙࣒ࢺ⛊᫬㛫ศゎ㟁Ꮚᅇᢡ⿦⨨࡟ࡼࡿ↓ᶵ⤖ᬗࡢගㄏ㉳ᵓ㐀┦㌿⛣㐣⛬ࡢ┤᥋ᵓ㐀ほᐹ
࣭ࣇ࢙࣒ࢺ⛊᫬㛫ศゎ㸰ගᏊග㟁Ꮚศග࡟ࡼࡿ༙ᑟయ⤖ᬗࡢ࢟ࣕࣜ࢔㉸㧗㏿ືຊᏛࡢゎ᫂
࣭ࢥࣄ࣮ࣞࣥࢺ㟁Ꮚບ㉳Ἴ᮰࡟ࡼࡿࢢࣛࣇ࢓࢖ࢺࡢගㄏ㉳┦㌿⛣ᶵᵓࡢゎ᫂
࣭L ࣂࣥࢻ RF 㟁Ꮚ㖠ࡢ㛤Ⓨ࡜⮬⏤㟁Ꮚ࣮ࣞࢨ࣮ගࡢࢥࣄ࣮ࣞࣥࢫ≉ᛶィ ࣭ᴟ➃⣸እගࣜࢯࢢࣛࣇ࢕ࣉࣟࢭࢫࡢ㛤Ⓨ
࣭จ⦰┦࡟࠾ࡅࡿ㔞Ꮚࣅ࣮࣒ㄏ㉳཯ᛂࡢゎ᫂
― 48 ―
㔞Ꮚᶵ⬟ᮦᩱ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
≉௵◊✲ဨ
኱Ꮫ㝔Ꮫ⏕
஦ົ⿵బဨ
Ᏻ⸨ 㝧୍
℩ᕝ ⪔ྖ
బࠎᮌ ⪽ࠊTASKIN Alexey
᳿ ᕹࠊNOVAK Marioࠊ⋤⛛೧ࠊGHATAK Subhamoy
బ⸨ ுኴࠊ㢗 ᬂࠊ๓ᕝ ཭⌮ࠊ㓇஭ ಇ᫂
୰ᮧ ࡺ࠿ࡾ
a) ᴫせ
ᮏ◊✲ศ㔝࡛ࡣࠊヨᩱస〇࠿ࡽ≀ᛶ ᐃࡲ࡛ࢆ୍㈏ࡋ࡚⾜࠺ࡇ࡜
࡟ࡼࡾ᪂ወ࡞ᮦᩱࡀ♧ࡍ≉ᚩⓗ࡞㟁Ꮚᶵ⬟≀ᛶࡢⓎ⌧ᶵᵓࢆ᥈✲
ࡋࠊࡑࡢ▱ぢ࡟ᇶ࡙࠸ࡓ⏬ᮇⓗ᪂ᮦᩱࡢ๰〇ࢆ┠ᣦࡋ࡚࠸ࡿࠋ⌧ᅾ
≉࡟ὀ┠ࡋ࡚࠸ࡿࡢࡀࠊࣂࣝࢡ࡟ࡣ⤯⦕య࡛࠶ࡿࡀ㟁ᏊἼື㛵ᩘࡀ
ᣢࡘࢺ࣏ࣟࢪ࢝ࣝ࡞ᛶ㉁࡟ࡼࡗ࡚⾲㠃࡟࣊ࣜ࢝ࣝ࡞ࢫࣆࣥ೫ᴟࢆ
ᣢࡗࡓ㔠ᒓ≧ែࡀ⌧ࢀࡿࠕࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࠖ࡜࿧ࡤࢀࡿᮦᩱ࡛
࠶ࡿࠋࡇࡢᮦᩱࡣ 2008 ᖺ࡟Ⓨぢࡉࢀࠊ௨᮶ᡃࠎࡣ䛣䛾ศ㔝䛷᪥ᮏ䛻
䛚䛡䜛ඛᑟ⪅䛾ᙺ๭䜢ᯝ䛯䛧䛶䛔䜛䚹
b) ᡂᯝ
ᅗ㸯ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࢆ≉ᚩ௜
ࡅࡿ≉␗࡞⾲㠃≧ែ
࣭ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య࣭㉸ఏᑟయ
᭱㏆ࠊ≀ᛶ≀⌮Ꮫࡢศ㔝࡛኱ࡁ࡞ὀ┠ࢆ㞟ࡵ࡚࠸ࡿࠕࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࠖࡣࠊᙉ࠸ࢫࣆࣥ㌶㐨┦஫
స⏝࡟ࡼࡗ࡚౯㟁Ꮚᖏࡢ㔞ᏊຊᏛἼື㛵ᩘࡢࣃࣜࢸ࢕ࡀ㏻ᖖ࡜཯ᑐ࡟࡞ࡗ࡚࠸ࡿ⤯⦕య≀㉁࡛࠶ࡿࠋἼ
ື㛵ᩘࡢࣃࣜࢸ࢕ࡣࠕZ2 ᩘࠖ࡜࠸࠺ࢺ࣏ࣟࢪ࢝ࣝ୙ኚ㔞࡛⾲⌧ࡉࢀࡿࡀࠊࡇࡢ Z2 ࢺ࣏ࣟࢪ࣮࡟㛵ࡋ࡚
ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࡣࠕᬑ㏻ࡢ⤯⦕య࡛ࠖ࠶ࡿ┿✵࡜␗࡞ࡗ࡚࠸ࡿࡓࡵࠊ๓⪅࠿ࡽᚋ⪅࡬㐃⥆ⓗ࡟㑄⛣
ࡍࡿࡇ࡜ࡣ࡛ࡁࡎࠊࡑࡢ㛫࡟ࡣ୍ᗘࠊ⤯⦕య௨እࡢ≧ែࠊࡘࡲࡾ㔠ᒓ≧ែࢆ⤒࡞ࡅࢀࡤ࡞ࡽ࡞࠸ࠋࡇࡢ
ཎ⌮࡟ࡼࡗ࡚ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࡢ⾲㠃࡟ࡣᚲࡎ㔠ᒓⓗ≧ែࡀ⌧ࢀࠊࡋ࠿ࡶࡑࡢ୰ࡢ㟁Ꮚࡣ㉁㔞ࢮࣟࡢ
ࢹ࢕ࣛࢵࢡ⢏Ꮚ࡜࡞ࡗ࡚࠸ࡿ㸦ᅗ 1㸧
ࠋࡉࡽ࡟ࡑࡇ࡛ࡣࢫࣆࣥ㌶㐨┦஫స⏝ࢆ཯ᫎࡋࡓࢫࣆ࣭ࣥࢸࢡࢫࢳ
ࣕࡢࡓࡵ࡟↓ᩓ㐓ࡢࢫࣆࣥὶࡀ⏕ࡌ࡚࠸ࡿࠋࡇࡢ⾲㠃≧ែࢆ⯙ྎ࡟ࡋ࡚ࠊᩘࠎࡢ᪂ወ࡞ࢺ࣏ࣟࢪ࢝ࣝ㔞
Ꮚ⌧㇟ࡢฟ⌧ࡀண᝿ࡉࢀ࡚࠸ࡿࡢ࡟ຍ࠼ࠊࡇࡢ≉ᚩ࠶ࡿ⾲㠃≧ែࢆ฼⏝ࡋࡓ㉸┬࢚ࢿᆺ᝟ሗฎ⌮ࢹࣂ࢖
ࢫࡢྍ⬟ᛶࡶ኱ࡁ࡞ὀ┠ࢆ㞟ࡵ࡚࠸ࡿࠋ
ࡲࡓࢺ࣏ࣟࢪ࢝ࣝ㉸ఏᑟయࡶࠊ㉸ఏᑟࢠࣕࢵࣉ࡛Ᏺࡽࢀࡓ㟁Ꮚࡢ༨᭷࢚ࢿࣝࢠ࣮≧ែࡀ┿✵࡜␗࡞ࡿ
ࢺ࣏ࣟࢪ࣮ࢆᣢࡘ㉸ఏᑟయ࡛࠶ࡾࠊࡑࡢ⾲㠃࡟≉Ṧ࡞ࢠࣕࢵࣉࣞࢫ≧ែࡀ⌧ࢀࡿࠋࢺ࣏ࣟࢪ࢝ࣝ㉸ఏᑟ
య࡟࠾ࡅࡿ⾲㠃≧ែࡢ୰ࡢ‽⢏Ꮚࡣࡋࡤࡋࡤࠊ⢏Ꮚ࡜཯⢏Ꮚࡀྠ୍࡛࠶ࡿ࡜࠸࠺୙ᛮ㆟࡞ᛶ㉁ࢆࡶࡘ
ࠕ࣐ࣚࣛࢼ⢏Ꮚࠖ࡜ࡋ࡚᣺⯙࠺ࠋࡇࡢ࣐ࣚࣛࢼ⢏Ꮚࡣࠊᨐ஘࡟ᙉ࠸ࢺ࣏ࣟࢪ࢝ࣝ㔞Ꮚࢥࣥࣆ࣮ࣗࢱࢆᐇ
⌧ࡍࡿࡓࡵࡢ㘽ࢆᥱࡿ࡜⪃࠼ࡽࢀ࡚࠾ࡾࠊᅛయ୰ࡢ‽⢏Ꮚ࡜ࡋ࡚ࡢ࣐ࣚࣛࢼ⢏ᏊࡢⓎぢࡣࠊᇶ♏≀⌮Ꮫ
ୖ⯆࿡῝࠸ࡔࡅ࡛࡞ࡃࠊᛂ⏝ୖࡶ㔜せ࡞ព࿡ࢆᣢࡘ࡜ᮇᚅࡉࢀ࡚࠸ࡿࠋ
㸯 ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࢹࣂ࢖ࢫࡢヨస◊✲
ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࢆ⏝࠸ࡓࢹࣂ࢖ࢫࡢ㛤Ⓨ࡟࠾࠸࡚
ࡣࠊࡲࡎࣂࣝࢡ⤯⦕ᛶࡢ㧗࠸ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࡢ㧗ရ
㉁ⷧ⭷ࢆస〇ࡋࠊࡉࡽ࡟ࡑࡢୖ࡟ᙧᡂࡍࡿࢺࢵࣉࢤ࣮ࢺ
࡟㟁ᅽࢆຍ࠼࡚⾲㠃≧ែࡢࣇ࢙࣑ࣝ‽఩ࢆไᚚࡍࡿࡇ࡜
ࡀᇶᮏ࡜࡞ࡿࠋࡋ࠿ࡋࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య⾲㠃≧ែࡢ≉
ᛶࡣ⇕࡞࡝࡟ࡼࡗ࡚ࡍࡄ࡟ຎ໬ࡍࡿࡓࡵࠊࡇࢀࡲ࡛⾲㠃
≧ែࡢ㟁Ꮚ⛣ືᗘࢆ㧗ࡃಖࡗࡓࡲࡲ࡛ࢺࢵࣉࢤ࣮ࢺࢆᙧ
― 49 ―
ᅗ 2䠖 MBE ἲ䛷ᡂ⭷䛧䛯䝞䝹䜽⤯⦕ᛶ䛾㧗䛔䝖䝫䝻䝆䜹
䝹⤯⦕య(Bi2-xSbx)2Te3 ⷧ⭷䛾ୖ䛻 SiNx ㄏ㟁య䜢ప 䛷
ᙧᡂ䛩䜛䛣䛸䛻䜘䜚స〇䛧䛯䝖䝑䝥䝀䞊䝖䝕䝞䜲䝇䛾෗┿䚹
ᡂࡍࡿࡇ࡜ࡣᅔ㞴ࡔࡗࡓࠋᡃࠎࡣࠊ⏘◊ࡢᯇᮏ◊✲ᐊࡀ᭷ࡍࡿ
Cat-CVD ࡟ࡼࡿప ࡛ࡢ SiNx ㄏ㟁యᙧᡂᢏ⾡ࢆ฼⏝ࡋ࡚ࠊMBE
ἲ࡛ᡂ⭷ࡋࡓࣂࣝࢡ⤯⦕ᛶࡢ㧗࠸ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య
(Bi2-xSbx)2Te3 ⷧ⭷ࡢୖ࡟ 80Υ௨ୗࡢప ࡛ SiNx ㄏ㟁యࢆᙧᡂࡍ
ࡿࡇ࡜࡟ࡼࡾࠊ⾲㠃≧ែࡢ㟁Ꮚ⛣ືᗘࢆຎ໬ࡉࡏࡎ࡟ไᚚᛶࡢ㧗
࠸ࢺࢵࣉࢤ࣮ࢺࢆస〇ࡍࡿࡇ࡜࡟ᡂຌࡋࡓ㸦ᅗ 2㸧
ࠋࡉࡽ࡟ヨసࡋ
ࡓࢹࣂ࢖ࢫࡢ ᐃ࡟ࡼࡗ࡚ࢺ࣏ࣟࢪ࢝ࣝ⾲㠃≧ែ୰ࡢࢹ࢕ࣛࢵࢡ
⢏Ꮚࢆ㟁Ꮚ࡜ṇᏍࡢ࡝ࡕࡽ࡟ࡶไᚚ࡛ࡁࡿࡇ࡜ࢆᐇドࡋࡓ㸦ᅗ 3㸧
ࠋ
㸰㸬ࢺ࣏ࣟࢪ࢝ࣝ㉸ఏᑟయࡢ᥈⣴
௒ᖺᗘᡃࠎࡣࠊࢺ࣏ࣟࢪ࢝ࣝ㉸ఏᑟయ Bi2Se3 ࡜ᬑ㏻ࡢ⤯⦕య ᅗ 3䠖 స〇䛧䛯(Bi2-xSbx)2Te3 ࢺࢵࣉࢤ࣮ࢺࢹ
PbSe ࡀ✚ᒙࡉࢀࡓᙧࡢ࣊ࢸࣟᵓ㐀ࡀࣂࣝࢡ༢⤖ᬗ୰࡛⮬↛࡟ᙧ ࣂ࢖ࢫࡢ 1.8 K ࡟࠾ࡅࡿ࣮࣍ࣝಀᩘ RH㸦ୖ㸧
࡜㠃᢬ᢠ R‫ڧ‬㸦ୗ㸧ࡢࢤ࣮ࢺ㟁ᅽ౫Ꮡᛶࠋࢺ
ᡂࡉࢀ࡚࠸ࡿ(PbSe)5(Bi2Se3)6 ࡜࠸࠺≀㉁࡟ Cu ࢆ࢖ࣥࢱ࣮࣮࢝ࣞ ࣏ࣟࢪ࢝ࣝ⤯⦕యⷧ⭷ࡢୖ㒊⾲㠃࡟Ꮡᅾࡍ
ࢺࡍࡿ࡜ࠊ㌿⛣ ᗘ 2.8 K ࡢ㉸ఏᑟࡀⓎ⌧ࡍࡿࡇ࡜ࢆⓎぢࡋࡓ㸦ᅗ ࡿࢺ࣏ࣟࢪ࢝ࣝ⾲㠃≧ែ୰ࡢࢹ࢕ࣛࢵࢡ㗹
ศᩓࡢ㟁Ⲵ୰ᛶⅬࢆࣇ࢙࣑ࣝ‽఩ࡀ㏻㐣ࡍ
4㸧ࠋࡇࡢ㉸ఏᑟయࡢẕ≀㉁(PbSe)5(Bi2Se3)6 ࡟࠾ࡅࡿ㟁Ꮚᵓ㐀ࡣ᪤ ࡿࡇ࡜࡟ࡼࡾࠊRH ࡟࠾ࡅࡿ㗦࠸㈇ࡢࣆ࣮ࢡ
࡟ゅᗘศゎග㟁Ꮚศග࡟ࡼࡗ࡚ ᐃࡉࢀ࡚࠾ࡾࠊࢺ࣏ࣟࢪ࢝ࣝ࡞ ࡜ R‫ࡢڧ‬㢧ⴭ࡞ᴟ኱ࡀほ ࡉࢀ࡚࠸ࡿࠋ
㉳※ࢆᣢࡘᨃ 2 ḟඖⓗࣂࣥࢻࡀࣂࣝࢡ࡟Ꮡᅾࡍࡿࡇ࡜ࡀࢃ࠿ࡗ࡚
࠸ࡿࠋᚑࡗ࡚ࠊࡑࡇ࡛Ⓨ⌧ࡍࡿ㉸ఏᑟࡶࠊᨃ 2 ḟඖᛶࢆᣢࡘࡇ࡜ࡀᮇᚅࡉࢀࡿࠋࡇࡢ≀㉁࡛ࡣ㉸ఏᑟయ
✚ศ⋡ࡀ࡯ࡰ 100%࡟㐩ࡍࡿヨᩱࢆస〇ࡍࡿࡇ࡜ࡀྍ⬟࡛࠶ࡿࡓࡵࠊࣂࣝࢡࡢ㉸ఏᑟ≀ᛶࢆㄪ࡭ࡿࡢ࡟
኱ኚ㒔ྜࡀⰋ࠸ࠋࡑࡇ࡛㉸ఏᑟ≧ែ࡟࠾ࡅࡿ㟁Ꮚẚ⇕ Cel ࢆ 0.3 K ࡢᴟప ࡲ࡛ ᐃࡋࡓ࡜ࡇࢁࠊCel/T
ࡢ ᗘ౫Ꮡᛶࡣᚑ᮶ᆺࡢ㉸ఏᑟయ࡟ᮇᚅࡉࢀࡿ BCS ⌮ㄽࡢ᣺⯙࠸࡜ࡣ␗࡞ࡾࠊࢠࣕࢵࣉࣀ࣮ࢻࡢᏑᅾࢆ
ᙉࡃ♧၀ࡍࡿ᣺⯙࠸ࢆ♧ࡍࡇ࡜ࡀࢃ࠿ࡗࡓ㸦ᅗ 5㸧
ࠋࢠࣕࢵࣉࣀ࣮ࢻࡢᏑᅾࡣࠊ㉸ఏᑟࢠࣕࢵࣉࡀ p Ἴࡸ
d Ἴࡢࡼ࠺࡞➢ྕ཯㌿ࢆక࠺㠀㉸ఏᑟᆺ࡛࠶ࡿࡇ࡜ࢆព࿡ࡍࡿࠋࡑࡢࡼ࠺࡞➢ྕ཯㌿ࢆక࠺㠀㉸ఏᑟࢠ
ࣕࢵࣉࢆᣢࡘ㉸ఏᑟయࡢ⾲㠃࡟ࡣᚲࡎ࢔ࣥࢻ࣮࢚ࣞࣇ᮰⦡≧ែࡀฟ⌧ࡍࡿࡇ࡜ࡀ▱ࡽࢀ࡚࠾ࡾࠊࡋ࠿ࡶ
ࡇࡢ Cux(PbSe)5(Bi2Se3)6 ㉸ఏᑟయ࡟࠾࠸࡚ࡣࢫࣆࣥ㌶㐨┦஫స⏝ࡀᙉ࠸ࡢ࡛ࠊ⾲㠃࢔ࣥࢻ࣮࢚ࣞࣇ᮰⦡
≧ែࡣࢫࣆࣥศ⿣ࡍࡿࡇ࡜ࡀᮇᚅࡉࢀࡿࠋࢫࣆࣥ⦰㏥ࡢ࡞࠸⾲㠃࢔ࣥࢻ࣮࢚ࣞࣇ᮰⦡≧ែࡣࡍ࡞ࢃࡕ࣐
ࣚࣛࢼ⢏Ꮚ࡛࠶ࡿࡢ࡛ࠊ௒ᅇⓎぢࡉࢀࡓ㉸ఏᑟయ Cux(PbSe)5(Bi2Se3)6 ࡣ⾲㠃࡟࣐ࣚࣛࢼ⢏Ꮚࢆక࠺ࢺ࣏
ࣟࢪ࢝ࣝ㉸ఏᑟయ࡛࠶ࡿྍ⬟ᛶࡀ㠀ᖖ࡟㧗࠸ࠋ
ᅗ 4䠖 ᪂ࡓ࡟Ⓨぢࡉࢀࡓࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య࣋
࣮ࢫࡢ㉸ఏᑟయ Cux(PbSe)5(Bi2Se3)6 ࡢ(a)⤖ᬗᵓ
㐀࡜(b)᢬ᢠ⋡ࡀ♧ࡍ㉸ఏᑟ㌿⛣ࠋ
ᅗ 5䠖 Cux(PbSe)5(Bi2Se3)6 䛾㧗ရ㉁༢⤖ᬗ
ヨᩱ䛻䛚䛔䛶ほ 䛥䜜䛯(a)䜋䜌 100%䛾㉸ఏ
ᑟయ✚ศ⋡䛸(b)㟁Ꮚẚ⇕䛾 ᗘ౫Ꮡᛶ䚹
― 50 ―
༙ᑟయᮦᩱ࣭ࣉࣟࢭࢫ◊✲ศ㔝
ᩍᤵ
ᑠᯘ ග
෸ᩍᤵ
ᯇᮏ ೺ಇ
ຓᩍ
௒ᮧ ೺ኴ㑻
≉௵ᩍᤵ
బ㈡ 㐩⏨ࠊᑎᕝ ⃈㞝ࠊ୰ᡞ ⩏⚰
≉௵◊✲ဨ
ᑠᯘ ᝆ㍤ࠊ㧗᳃ ᫭
≉௵ᢏ⾡⫋ဨ
㯮ᓮ ༓㤶
኱Ꮫ㝔Ꮫ⏕
๓⏣ ㆡ❶ࠊ㉥஭ ᬛ႐ࠊධ㮵 ኱ᆅࠊ႐ᮧ ຾▮ࠊ୰ᓥ ᐶグࠊ㔝୰ ၨ❶ࠊ
ᯇ⏣ ┿㍜ࠊᕷᕝ ㎮ဢ
Ꮫ㒊Ꮫ⏕
⸨Ụ ಇኴ
஦ົ⿵బဨ
࿴⏣ ᚸࠊఫྜྷ ㈷Ꮚ
a) ᴫせ
༙ᑟయᢏ⾡ࡣࠊᛴ㏿࡟㐍Ṍࡍࡿ⌧௦♫఍ࢆᨭ࠼࡚࠸ࡿ࡜࠸ࡗ࡚ࡶ㐣ゝ࡛ࡣ࡞࠸ࠋᙜ◊✲ศ㔝࡛ࡣࠊ᪂
つࡢ༙ᑟయ໬Ꮫࣉࣟࢭࢫࢆ㛤Ⓨࡍࡿࡇ࡜࡟ࡼࡗ࡚ࠊ✀ࠎࡢ༙ᑟయࢹࣂ࢖ࢫࡢ㧗ᛶ⬟໬࡜పࢥࢫࢺ໬ࢆ┠
ᣦࡍ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋ༙ᑟయࢹࣂ࢖ࢫ࣭ᮦᩱ࡜ࡋ࡚ࡣࠊ(1)࢚ࢿࣝࢠ࣮ၥ㢟࡜⎔ቃၥ㢟ࡢゎỴࢆ┠ᣦࡋ
ࡓኴ㝧㟁ụࠊ(2)ࢩࣜࢥࣥษ⢊࠿ࡽᙧᡂࡍࡿࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡࣝࡢⓎගᮦᩱࡸ㟁ụᮦᩱ࡬ࡢᛂ⏝࠾
ࡼࡧ(3)㧗ຠ⋡࣮ࣞࢨ࣮↷᫂࡟㛵ࡍࡿ◊✲࣭㛤Ⓨࢆ⾜ࡗ࡚࠸ࡿࠋࡲࡓࠊୖグࢹࣂ࢖ࢫࡢ≉ᛶࢆ኱ࡁࡃᙳ㡪
ࡍࡿ༙ᑟయ⏺㠃ࡢ㧗ឤᗘほ ࡟㛵ࡍࡿ◊✲ࡶ⾜ࡗ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭◪㓟㓟໬ἲࢆ⏝࠸ࡓ⾲㠃ࣃࢵࢩ࣮࣋ࢩࣙࣥຠᯝ࡟ࡼࡿ⤖ᬗᆺࢩࣜࢥࣥኴ㝧㟁ụࡢ≉ᛶྥୖ >ㄽᩥ@
◪㓟㓟໬ἲࢆ⏝࠸ࡿ࡜ᴟⷧ SiO2 ⭷ࡀ༢⤖ᬗࢩࣜࢥࣥኴ㝧㟁ụ࡟୚࠼ࡿᙳ㡪࡜ࠊ◪㓟㓟໬⭷ᙧᡂᚋࡢ
ࣉࣛࢬ࣐࢔ࣥࣔࢽ࢔ฎ⌮ࡢ⾲㠃ࡢ⤌ᡂศᕸ࡟ࡘ࠸࡚᫂ࡽ࠿࡟ࡋ
ࡓࠋp ᆺࢩࣜࢥࣥኴ㝧㟁ụ࡟࠾࠸࡚ࠊࢩࣜࢥࣥᇶᯈ࡜ࢩࣜࢥࣥ❅
໬⭷ࡢ⏺㠃࡟◪㓟㓟໬⭷ࢆᙧᡂࡋ࡞࠸ሙྜࠊኴ㝧㟁ụࡢ࢚ࢿࣝࢠ
࣮ኚ᥮ຠ⋡ࡣ 16.6%࡛࠶ࡗࡓࡀࠊ⏺㠃࡟◪㓟㓟໬⭷ࢆᙧᡂࡋࡓሙ
ྜࠊ
ኴ㝧㟁ụࡢ࢚ࢿࣝࢠ࣮ኚ᥮ຠ⋡ࡣ 17.5%ࡲ࡛ቑຍࡋࡓ
㸦ᅗ㸯㸧
ࠋ
ࡲࡓࠊ㛤ᨺ㟁ᅽࡣࠊp-ᆺࢩࣜࢥࣥᇶᯈ⾲㠃࡜ࢩࣜࢥࣥ❅໬⭷ࡢ⏺
㠃࡟◪㓟㓟໬⭷ࢆᤄධࡍࡿࡇ࡜࡟ࡼࡾࠊ620 mV ࠿ࡽ 630 mV ࡟
኱ࡁࡃቑຍࡋࡓࠋࡇࡢ࢚ࢿࣝࢠ࣮ኚ᥮ຠ⋡ࡸ㛤ᨺ㟁ᅽࡢቑຍࡣࠊ
ᅛᐃ㟁Ⲵ࡟ࡼࡿࡶࡢ࡛ࡣ࡞ࡃࠊ⏺㠃‽఩ᐦᗘࡢపῶ࡟ࡼࡿࡶࡢ࡜
⪃࠼ࡽࢀࡿࠋࡇࢀࡣࠊAl/SiN/Si MIS ࢲ࢖࣮࢜ࢻᵓ㐀ࡢ㟁Ẽᐜ㔞
̿㟁ᅽ᭤⥺࡟࠾࠸࡚ࠊࢩࣜࢥࣥᇶᯈ࡜ࢩࣜࢥࣥ❅໬⭷ࡢ⏺㠃࡟◪
㓟㓟໬⭷ࢆᤄධࡋࡓ࡟ࡶ࠿࠿ࢃࡽࡎࠊࣇࣛࢵࢺࣂࣥࢻࡀࢩࣇࢺࡏ
ࡎࠊ◪㓟㓟໬ࡢ᭷↓࡟ࡼࡾࠊᅛᐃ㟁Ⲵᐦᗘࡀኚ໬ࡋ࡞࠿ࡗࡓ࠿ࡽ
࡛࠶ࡿࠋࡲࡓࠊㄽᩥ㸲࡛ࡣࠊ◪㓟㓟໬⭷࡟ࡼࡾࢩࣜࢥࣥ⏺㠃ࢆࣃ
ࢵࢩ࣮࣋ࢩࣙࣥࡍࡿࡇ࡜࡟ࡼࡾࠊn ᆺኴ㝧㟁ụࡢ≉ᛶࢆྥୖࡉࡏ
ࡿࡇ࡜࡟ࡶᡂຌࡋ࡚࠸ࡿࠋࡇࡢ⤖ᯝࡶࠊࢩࣜࢥࣥ⏺㠃࡟ᙧᡂࡋࡓ
◪㓟㓟໬⭷ࡣࠊᅛᐃ㟁Ⲵ࡟ࡼࡿ㟁⏺ຠᯝᆺࣃࢵࢩ࣮࣋ࢩ࡛ࣙࣥࡣ
ᅗ㸯 $J6L1Q6LS6L$Oᵓ㐀ࢆᣢࡘS
࡞ࡃࠊ⏺㠃‽఩ᾘ⁛ᆺࣃࢵࢩ࣮࣋ࢩ࡛ࣙࣥ࠶ࡿࡇ࡜ࢆ♧ࡍࠋࡲࡓࠊ ᆺࢩࣜࢥࣥኴ㝧㟁ụࡢ㟁ὶ̿㟁ᅽ᭤⥺ࠋ
ࡇࡢ⤖ᯝࡣࠊp ᆺཬࡧ n ᆺࡢ୧ኴ㝧㟁ụ࡟◪㓟㓟໬ἲࢆ㐺⏝ࡍࡿ
6L16L⏺㠃࡟D◪㓟㓟໬⭷࡞ࡋࠊE◪㓟
ࡇ࡜ࡀ࡛ࡁࠊ㔞⏘⿦⨨ࡢపࢥࢫࢺ໬ࡶྍ⬟࡛࠶ࡿࡇ࡜ࢆ♧၀ࡍࡿࠋ 㓟໬⭷࠶ࡾࠋ
p-ᆺࢩࣜࢥࣥᇶᯈ⾲㠃࡟◪㓟㓟໬⭷ࢆᙧᡂᚋࠊ㓟⣲㞺ᅖẼୗ࡛ຍ
― 51 ―
⇕ࡋࠊ⏺㠃≉ᛶࢆࡉࡽ࡟ྥୖࡉࡏࡿᐇ㦂ࡶ⾜ࡗࡓࠋప ᙧᡂࡋࡓ◪㓟㓟໬⭷ࢆ 600ÝC ࡲࡓࡣ 800ÝC ࡛
ຍ⇕ࡍࡿ࡜ࠊᑡᩘ࢟ࣕࣜ࢔ࣛ࢖ࣇࢱ࢖࣒ࡣࠊࡑࢀࡒࢀࠊ12 Ǎs ࠿ࡽ 35 Ǎs ࠾ࡼࡧ 45Ǎs ࡟ྥୖࡋࡓࠋࡇࢀ
ࡣࠊ◪㓟㓟໬⭷࡜㓟⣲୰࡛ࡢຍ⇕ࡢ⤌ྜࡏ࡟ࡼࡾࠊࡉࡽ࡟ኴ㝧㟁ụࡢ࢚ࢿࣝࢠ࣮ኚ᥮ຠ⋡ࢆྥୖ࡛ࡁࡿ
ྍ⬟ᛶࡀ࠶ࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓࠋࡲࡓࠊ◪㓟㓟໬⭷ࢆࢩࣜࢥࣥᇶᯈ⾲㠃࡟ᙧᡂࡋ࡞࠿ࡗࡓሙྜ࡟ࡣࠊ
࢔ࣥࣔࢽ࢔ࣉࣛࢬ࣐ฎ⌮ࢆࡍࡿ࡜ࠊ0.3 nm ࡢࢩࣜࢥࣥ❅໬⭷ࡀࢩࣜࢥࣥᇶᯈ⾲㠃࡟⏕ᡂࡋࡓࠋࡇࢀ࡟
ᑐࡋࠊ◪㓟㓟໬⭷ࢆࢩࣜࢥࣥᇶᯈ⾲㠃࡟ᙧᡂࡋࡓሙྜ࡟ࡣࠊ0.1 ML ࡢࢩࣜࢥࣥ❅໬ⷧ⭷ࡀ᭱⾲㠃࡟ᙧ
ᡂࡉࢀࡿࡀࠊࢩࣜࢥࣥ⏺㠃࡟ࡣ SiON ⷧ⭷ࡀࢃࡎ࠿࡟ᙧᡂࡉࢀࡓࡔࡅ࡛࠶ࡗࡓࠋࡇࢀࡽࡢ⤖ᯝࡣࠊ◪㓟
㓟໬⭷ࡀࠊࢩࣜࢥࣥᇶᯈࡢ┤᥋❅໬཯ᛂࢆᢚไࡋࠊࢩࣜࢥࣥᇶᯈ࡬ࡢࣉࣛࢬ࣐ࢲ࣓࣮ࢪࢆ㜵ࡄࡇ࡜࡟ࡼ
ࡗ࡚ࠊࢩࣜࢥࣥ⏺㠃ࡢ⏺㠃‽఩ᐦᗘࢆపῶࡉࡏࡿຠᯝࢆᣢࡕࠊ◪㓟㓟໬⭷ࢆ⏝࠸ࡓኴ㝧㟁ụࡢ࢚ࢿࣝࢠ
࣮ኚ᥮ຠ⋡ࡸ㛤ᨺ㟁ᅽࢆቑຍࡉࡏࡓ࡜⪃࠼ࡽࢀࡿࠋ
࣭◪㓟㓟໬ἲ࡟ࡼࡿᑡᩘ࢟ࣕࣜ࢔ࣛ࢖ࣇࢱ࢖࣒࡜ࢩࣜࢥࣥኴ㝧㟁ụ≉ᛶࡢྥୖ >ㄽᩥ@
◪㓟㓟໬ἲࢆ⏝࠸࡚ࢩࣜࢥࣥᇶᯈ⾲㠃࡟ᴟⷧࡢ◪㓟㓟໬⭷ࢆ
ᙧᡂࡍࡿࡇ࡜࡟ࡼࡾࠊ༢⤖ᬗࢩࣜࢥࣥᇶᯈࡢᑡᩘ࢟ࣕࣜ࢔ࣛ࢖
ࣇࢱ࢖࣒ࡀቑຍࡋࡓࠋ68wt%࠾ࡼࡧ 98wt%ࡢ◪㓟Ỉ⁐ᾮ୰࡛◪
㓟㓟໬ࢆ࠾ࡇ࡞ࡗࡓሙྜ࡟ࡣࠊᑡᩘ࢟ࣕࣜ࢔ࣛ࢖ࣇࢱ࢖࣒ࡀ኱
ࡁࡃྥୖࡋࡓࡀࠊ40wt%ࡢ◪㓟Ỉ⁐ᾮ୰࡛◪㓟㓟໬ࢆ࠾ࡇ࡞ࡗ
ࡓሙྜ࡟ࡣࠊᑡᩘ࢟ࣕࣜ࢔ࣛ࢖ࣇࢱ࢖࣒ࡣ㏫࡟పୗࡋࡓࠋࣇࢵ
໬Ỉ⣲㓟࡛ࢩࣜࢥࣥᇶᯈ⾲㠃ࢆỈ⣲⤊➃ࡋࡓሙྜ࡟ࡣࠊ᭱ึࡣ
ᑡᩘ࢟ࣕࣜ࢔ࣛ࢖ࣇࢱ࢖࣒ࡀ㧗࠿ࡗࡓࡀࠊ኱Ẽ୰࡟ 5 ᪥㛫ᨺ⨨
ࡋࡓᚋࡣࠊࣇࢵ໬Ỉ⣲㓟ฎ⌮ࢆࡍࡿ๓ࡢᑡᩘ࢟ࣕࣜ࢔ࣛ࢖ࣇࢱ
࢖࣒ࡲ࡛ῶᑡࡋࡓࠋࡋ࠿ࡋࠊ◪㓟㓟໬ฎ⌮ࢆ⾜ࡗࡓሙྜ࡟ࡣࠊ
኱Ẽ୰࡟ᨺ⨨ࡋ࡚ࡶࠊ◪㓟㓟໬ฎ⌮࡟ࡼࡾቑຍࡋࡓᑡᩘ࢟ࣕࣜ
࢔ࣛ࢖ࣇࢱ࢖࣒ࡣࠊῶᑡࡋ࡞࠿ࡗࡓࠋࡇࡢᑡᩘ࢟ࣕࣜ࢔ࣛ࢖ࣇ
ࢱ࢖࣒ࡢᏳᐃᛶࡣࠊ◪㓟㓟໬⭷ࡢཎᏊᐦᗘࡀ㧗ࡃࠊ㓟໬✀ࡢࢩ
ࣜࢥࣥ⏺㠃࡬ࡢᣑᩓࢆ㜵Ṇࡋ࡚࠸ࡿࡓࡵ࡛࠶ࡿࠋ◪㓟㓟໬⭷ࡢ
ཎᏊᐦᗘࡣࠊฎ⌮࡟౑⏝ࡋࡓ◪㓟ࡢ⃰ᗘࡀ㧗ࡃ࡞ࡿ࡟ᚑࡗ࡚ቑ
ຍࡋࠊࡇࢀ࡟ࡼࡾ Si/SiO2 ⏺㠃࡟࠾ࡅࡿ౯㟁Ꮚᖏ୙㐃⥆࢚ࢿࣝࢠ
࣮ࡀቑຍࡍࡿࠋࡲࡓࠊ◪㓟㓟໬⭷࡛ࢩࣜࢥࣥ⏺㠃ࢆࣃࢵࢩ࣮࣋
ᅗ 㸰 $J$O6L1S6LQ6LQ6L$O ᵓ 㐀
ࢩࣙࣥࡋࡓኴ㝧㟁ụࢆస〇ࡋࠊࡑࡢ≉ᛶࢆホ౯ࡋࡓࠋ◪㓟㓟໬
ࢆᣢࡘQᆺࢩࣜࢥࣥኴ㝧㟁ụࡢ㟁ὶ̿㟁ᅽ᭤
⭷ࢆࢩࣜࢥࣥᇶᯈ࡜ࢩࣜࢥࣥ❅໬⭷ࡢ⏺㠃࡟ᙧᡂࡍࡿࡇ࡜࡟ࡼ
⥺ࠋ6L16L⏺㠃࡟D◪㓟㓟໬⭷࡞ࡋࠊE◪
ࡾࠊn ᆺࢩࣜࢥࣥኴ㝧㟁ụࡢ࢚ࢿࣝࢠ࣮ኚ᥮ຠ⋡ࡣࠊ17.2%࠿ࡽ
㓟㓟໬⭷࠶ࡾࠋ
18.9%࡟ቑຍࡋࡓ㸦ᅗ㸰㸧
ࠋࡲࡓࠊ㛤ᨺ㟁ᅽࡶ 630.0 mV ࠿ࡽ 633.4
mV ࡟ࠊ
▷㟁ὶᐦᗘࡶ 34.3 mA/cm2 ࠿ࡽ 38.2 mA/cm2 ࠿ࡽ࡟ࠊ
኱ࡁࡃቑຍࡋࡓࠋ
ෆ㒊㔞Ꮚຠ⋡ࡣࠊ300-600
nm ࡢ▷Ἴ㛗ഃ࡛ࡣࠊ◪㓟㓟໬⭷ࢆࢩࣜࢥࣥᇶᯈ࡜ࢩࣜࢥࣥ❅໬⭷ࡢ⏺㠃࡟ᙧᡂࡍࡿࡇ࡜࡟ࡼࡾࠊ኱ࡁ
ࡃྥୖࡋࡓࠋࡇࢀࡽࡢ⤖ᯝࡣࠊ◪㓟㓟໬⭷ࡀࢩࣜࢥࣥᇶᯈ⾲㠃ࢆຠᯝⓗ࡟ࣃࢵࢩ࣮࣋ࢩࣙࣥࡋࡓࡓࡵ࡜
⪃࠼ࡽࢀࡿࠋ
࣭ࢩࣜࢥࣥษ⢊࠿ࡽస〇ࡋࡓࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡࣝࡢኴ㝧㟁ụ࡬ࡢᛂ⏝ >ㄽᩥ@
ษ⢊ࢆࣅ࣮ࢬ࣑ࣝἲ࡟ࡼࡾ⢊○ࡍࡿࡇ࡜࡟ࡼࡾࠊ┤ᚄ 1㹼20 nm ࡢࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡࣝࢆస〇
ࡋࡓࠋᕼࣇࢵ໬Ỉ⣲㓟࡛ࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡ⾲㠃ࡢ㓟໬⭷ࢆ㝖ཤࡋࠊ኱Ẽ୰࡛ 1 㐌㛫ᨺ⨨ࡋ࡚ࡶࠊ
㓟໬⭷ཌࡣ 1.2 nm ࡲ࡛ࡋ࠿ᡂ㛗ࡋ࡞࠿ࡗࡓࠋn ᆺ༢⤖ᬗࢩࣜࢥࣥᇶᯈୖ࡟ p ᆺࡢࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ
࢕ࢡࣝࢆሬᕸࡋࡓ⾲㠃࡛ࡣࠊ㟁ὶ̿㟁ᅽ᭤⥺࡛ࡣࠊᩚὶᛶࢆ♧ࡋ࡚࠾ࡾࠊpn ᥋ྜࡀᙧᡂࡉࢀ࡚࠸ࡿࡇ
࡜ࢆ♧ࡋ࡚࠸ࡿࠋࡲࡓࠊ◪㓟㓟໬ᚋ࡟ 900ÝC ࡛ຍ⇕ࡍࡿࡇ࡜࡟ࡼࡾࠊ┤ิ᢬ᢠࡀῶᑡࡋࡓࠋࡇࢀࡣࠊ◪
㓟㓟໬ἲ࡟ࡼࡾᙧᡂࡉࢀࡓᴟⷧ⭷ࡀ⼥ゎࡋ࡚ࠊ࿘ᅖࡢࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡࣝ࡜⤖ྜࢆᙧᡂࡋ࡚࠸ࡿ
ࡶࡢ࡜⪃࠼ࡽࢀࡿࠋp ᆺࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡࣝࢆ n ᆺࢩࣜࢥࣥᇶᯈ࡟ሬᕸࡍࡿ࡜ࠊᩚὶᛶ࠾ࡼࡧග
㟁ຠᯝࡀぢࡽࢀࡓࠋࡲࡓࠊࡇࢀࡣࠊࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡࣝࡀኴ㝧㟁ụ࡟ᛂ⏝ࡋ࠼ࡿࡇ࡜ࢆ♧ࡋ࡚࠸
ࡿࠋ
― 52 ―
ඛ➃ࣁ࣮ࢻᮦᩱ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
≉௵◊✲ဨ
኱Ꮫ㝔Ꮫ⏕
◊✲⏕
஦ົ⿵బဨ
㛵㔝 ᚭ
ከ᰿ ṇ࿴
ᚋ⸨ ▱௦㸦ᖹᡂ 27 ᖺ 2 ᭶ 16 ᪥᥇⏝㸧
す⏣ ᑦᩗ㸦ᖹᡂ 26 ᖺ 6 ᭶ 1 ᪥᥇⏝㸧
㕥ᮌ ⩧ᝅࠊ⸨஭ ㈼భࠊ▮Ᏺ ᆂభ
ጧ ፣㟷
ℊྡ ኤె㸦ᖹᡂ 26 ᖺ 7 ᭶ 16 ᪥᥇⏝㸧
a) ᴫせ
♫఍ᇶ┙࡜ࡋ࡚ࡢᮦᩱࡢ㔜せᛶࡣ㏆ᖺࡲࡍࡲࡍ㧗ࡲࡗ࡚࠸ࡿࠋᮏ◊✲ศ㔝࡛ࡣࠊᮦᩱᕤᏛࡸ≀⌮Ꮫࠊ
໬Ꮫ࡞࡝ከᵝ࡞Ꮫၥ࡟ᇶ࡙ࡁࠊࢭ࣑ࣛࢵࢡࢫࡸ㔠ᒓᮦᩱ࡞࡝ࢆ୰ᚰ࡜ࡋ࡚ศ㔝࠾ࡼࡧᮦᩱᶓ᩿ⓗ࡞ほⅬ
࡟❧⬮ࡋࡓḟୡ௦ᆺᮦᩱ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋࡑࡢᑐ㇟ࡣ⤖ᬗᵓ㐀ࣞ࣋ࣝ࡟ጞࡲࡾࠊࢼࣀ࠿ࡽ࣐ࢡࣟࢫࢣ
࣮ࣝࡲ࡛ࡢከࡃࡢ㝵ᒙ࡟ཬࡪᵓ㐀タィࡸࣉࣟࢭࢫไᚚ࠾ࡼࡧ⼥ྜ໬ᡭἲࢆ࣮࢟ࢸࢡࣀࣟࢪ࣮࡜ࡋ࡚ࠊከ
ᵝ࡞ᶵ⬟ࢆ⋓ᚓࡋࡓᶵ⬟ඹ⏕ᆺࡢࣁ࣮ࢻᮦᩱࡸࢼࣀᮦᩱࡢ๰〇ࠊᵓ㐀ࡸᇶ♏≀ᛶࠊ≉ᛶࡢホ౯࠾ࡼࡧᶵ
⬟Ⓨ⌧࣭ᶵᵓゎ᫂࡟㛵ࡍࡿ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋࡇ࠺ࡋࡓ᪂つ࡞ᵓ㐀≉ᛶࡸᶵ⬟≉ᛶࢆ᭷ࡍࡿඛ➃ᶵ⬟ᛶ
ᵓ㐀ᮦᩱࡢ◊✲㛤Ⓨࢆ⾜࠺ࡇ࡜࡛ࠊከᵝ࡞ศ㔝࡬ࡢᛂ⏝ࢆᑐ㇟࡜ࡋࡓᵓ㐀㒊ᮦ࡜ࡋ࡚ࡢ㧗ᙉᗘ㧗㠎ᛶᮦ
ᩱࡸከᶵ⬟ㄪ࿴ᆺࣂࣝࢡᮦᩱࠊ⏕య㐺ྜᛶᮦᩱࠊ᭦࡟ࡣ⎔ቃ࣭࢚ࢿࣝࢠ࣮ᮦᩱ࡞࡝ࠊ௒᪥ࡢ♫఍ࡀᢪ࠼
ࡿ㔜せ࡞ㄢ㢟ࡢゎỴ࡟㈨ࡍࡿࡇ࡜ࡢ࡛ࡁࡿḟୡ௦ᆺᇶ┙ᮦᩱ๰ฟ࡜ࡑࡢᛂ⏝ࢆᣦྥࡋ࡚࠸ࡿࠋලయⓗ࡟
ࡣࠊຊᏛⓗᶵ⬟࡜㟁Ẽⓗᶵ⬟ࡀඹ⏕ࡋࡓࢭ࣑ࣛࢵࢡࢫ」ྜᮦᩱࠊ᪂つ࡞ᙎᛶ⋡ィ ࣭ゎᯒᡭἲࡢ☜❧࡜
≉ᛶᨭ㓄ᅉᏊࡢゎ࣭᫂ไᚚ࠾ࡼࡧᮦᩱタィࠊపḟඖ␗᪉ᵓ㐀ࢆᣢࡘ㓟໬≀ࢼࣀᮦᩱࡢᵓ㐀ไᚚ࡜ගゐ
፹࣭≀⌮ග໬Ꮫከᶵ⬟ᛶࡢ῝໬࠾ࡼࡧ⏕యᮦᩱ࡬ࡢᒎ㛤࡟㛵ࡍࡿ◊✲࡞࡝࡟࠾࠸࡚ࠊࡑࡢᇶ♏Ꮫ⾡ⓗ◊
✲࠾ࡼࡧᛂ⏝ᒎ㛤ࢆᣦྥࡋࡓ◊✲ࢆ㐍ࡵ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭㓟໬≀༙ᑟయ࣊ࢸࣟ」ྜᵓ㐀࣭⏺㠃ࡢ⮬ᕫ⤌⧊໬ᙧᡂ࡜ࡑࡢ㟁Ẽⓗᶵ⬟
ࣂࣝࢡ୰࡟ࢼࣀࣞ࣋ࣝࡢ࣊ࢸࣟ⏺㠃㸦㸰ḟඖ㸧
ࢆ⮬ᕫ⤌⧊໬ⓗ࡟ᙧᡂࡉࡏࡿ࡜ඹ࡟ࠊྠ᫬࡟୧┦
ࢆ␗࡞ࡿ༙ᑟయⓗᛶ㉁࡬࡜ไᚚࡍࡿࡇ࡜ࢆ┠ⓗ࡟ࠊ
ࢫࣆࣀ࣮ࢲࣝ┦ศ㞳⣔࡜ࡋ࡚᪤▱ࡢ㓟໬ࢫࢬ
㸦SnO2㸧-㓟໬ࢳࢱࣥ㸦TiO2㸧஧ඖ⣔ࢭ࣑ࣛࢵࢡࢫ
㸦➼ࣔࣝ㸧ࢆᑐ㇟࡜ࡋࠊFe2O3 ࢆ 1ࠥ5mol%ῧຍࡋࠊ
኱Ẽ୰ 1300Υ㹼1550Υ࡛ྛ᫬㛫↝ᡂࡋࡓࠋࡑࡢ⤖
ᯝࠊFe ࢆᚤ㔞ῧຍࡍࡿࡇ࡜࡛ SnO2- TiO2 ⣔࡟࠾࠸
࡚┦ศ㞳ᵓ㐀ࡀ୍ẁ㝵ࡢ཯ᛂ↝⤖࡟ࡼࡾ⏕ࡌࠊࣛ
࣓ࣛ⤌⧊ࢆక࠺ࢫࣆࣀ࣮ࢲࣝ┦ศ㞳ᵓ㐀ࡀᙧᡂࡉ
ࢀࡿࡇ࡜ࢆぢ࠸ࡔࡋ㸦ᅗ 1㸧ࠊ↝⤖ ᗘ࣭᫬㛫࠾ࡼ
ࡧ Fe ῧຍ㔞࡟౫Ꮡࡋ࡚ᵓ㐀ࡀไᚚ࡛ࡁࡿࡇ࡜ࢆ᫂
ࡽ࠿࡜ࡋࡓࠋ࣓ࣛࣛ⤌⧊Ⓨ㐩ึᮇ࡛ࡣ Sn ࡀ TiO2
ᅗ 1 ࢫࣆࣀ࣮ࢲࣝ┦ศ㞳࡟ࡼࡾᙧᡂࡋࡓ 5mol%Fe2O3 ᅛ⁐
┦࡬㑅ᢥⓗ࡟ᣑᩓࡍࡿࡇ࡜࡛ࠊ⢏Ꮚෆ࡟ TiO2/SnO2
SnO2-TiO2 ஧ඖ⣔ࢭ࣑ࣛࢵࢡࢫ࡟࠾ࡅࡿ」ྜᵓ㐀㸸1450Υ-24h ↝
ࣜࢵࢳ࡞࣓ࣛࣛ┦ࡀࢼࣀ࡛ࣞ࣋ࣝⓎ㐩ࡋࠊ ᗘᡈ
⤖య(a)࠾ࡼࡧ TEM ෗┿(b)ࠊ1360Υ࡟࠾ࡅࡿ࣓ࣛࣛᙧᡂ㐣⛬(c)ࠊ
࠸ࡣ᫬㛫⤒㐣࡟ࡼࡾ SnࠊTi ୧ඖ⣲ࡀ┦஫ᣑᩓࡋ࡚
1450Υ-10 ศ↝⤖᫬ࡢᵓ㐀ࠋ
ᆒ୍࡞ኚㄪᵓ㐀࡬࡜Ⓨ㐩ࡋࡓࠋ᭦࡟┦ศ㞳ᵓ㐀ࡢ
Ⓨ㐩࡟౫Ꮡࡋ࡚」ྜᵓ㐀యࡢ㟁Ẽఏᑟ⋡ࡀୖ᪼ࡋࠊFe ῧຍ➃ᡂศ↝⤖య࡛ࡣຓ๣㔞ཬࡧ↝ᡂ㞺ᅖẼไᚚ
࡟ࡼࡾᑟ㟁ᛶࢆไᚚ࡛ࡁࡿྍ⬟ᛶࡀ♧၀ࡉࢀࠊᮏἲ࡟ࡼࡾ┦ศ㞳ᵓ㐀࠾ࡼࡧ༙ᑟయⓗᛶ㉁ࢆྠ᫬࡟ไᚚ
― 53 ―
ࡋࡓࢭ࣑ࣛࢵࢡࢫ๰〇ࡢᇶ♏ⓗᣦ㔪ࢆᚓࡓࠋ
࣭ᵓ㐀ಟ㣭࡟ࡼࡿ㓟໬≀ࢼࣀࢳ࣮ࣗࣈ࡬ࡢ㧗ḟ≀⌮໬Ꮫᶵ⬟ࡢ௜୚
ప ࡛ࡢỈ⁐ᾮ໬Ꮫ཯ᛂ࡟ࡼࡾከᵝ࡞㔠ᒓ࢖
࢜ࣥࢆᅛ⁐ಟ㣭ࡋࡓࢳࢱࢽ࢔ࢼࣀࢳ࣮ࣗࣈ
㸦TiO2 Nanotube, TNT㸧ࢆྜᡂࡋࠊࡑࡢࢼࣀᵓ㐀ࠊ
≀⌮ⓗ≉ᛶࠊ໬Ꮫⓗᛶ㉁ࡸගゐ፹≉ᛶ࡟ࡘ࠸࡚
ㄪᰝࡋࡓࠋࡑࡢ⤖ᯝࠊᅛ⁐ඖ⣲࡜ࡋ࡚ Cr ࡸ Vࠊ
Nb ࡞࡝ࢆῧຍࡋࡓ TNT ࡀྜᡂ࡛ࡁࠊ࠸ࡎࢀࡶ
඾ᆺⓗ࡞ࢼࣀࢳ࣮ࣗࣈᵓ㐀ࢆ♧ࡋࡓࠋࡇࢀࡽᅛ
⁐ᆺ TNT ᮦᩱࡢගᏛ྾཰ࢫ࣌ࢡࢺࣝ ᐃ࠿ࡽࠊ
ᅛ⁐ඖ⣲ࡀᙧᡂࡍࡿ୙⣧≀‽఩ࡢᙧᡂࡀㄆࡵࡽ
ࢀࡓࠋᴟࡵ࡚㧗࠸᭷ᶵศᏊ㸦Methylene blue, MB㸧
྾╔⬟ࢆ♧ࡍ࡜ඹ࡟ࠊඃࢀࡓගゐ፹≉ᛶࢆ♧ࡋ
ࡓࠋ≉࡟ Nb ࡸ Cr ᡈ࠸ࡣ 2 ✀㢮ࡢඖ⣲ࢆඹࢻ࣮ ᅗ 2 Cr ࠾ࡼࡧ V ᅛ⁐ࢳࢱࢽ࢔ࢼࣀࢳ࣮ࣗࣈ㸦TNT㸧ࡢ㏱㐣ᆺ㟁Ꮚ㢧ᚤ
ࣉࡋࡓሙྜࠊ⣸እග࡟ຍ࠼࡚ྍどග↷ᑕ࡛ࡶඃ 㙾ീ㸦ᕥ㸧࡜ྛ✀ᅛ⁐ᆺ TNT ࡢྍどග↷ᑕ㸦>400nm㸧࡟ࡼࡿ࣓ࢳࣞ
ࣥࣈ࣮ࣝⰍ⣲ศゎගゐ፹≉ᛶ㸦ྑ㸧
ࢀࡓගゐ፹≉ᛶࢆ♧ࡋࡓ㸦ᅗ 2㸧
ࠋ௨ୖࡢ⤖ᯝ࠿
ࡽࠊ᱁Ꮚᵓ㐀㸦ᅛ⁐㸧ไᚚࡋࡓᮏࢼࣀࢳ࣮ࣗࣈᮦᩱࡣࠊඃࢀࡓᶵ⬟ࡀඹ⏕ࡋࡓḟୡ௦ᆺ⎔ቃί໬ᶵ⬟ᛶ
ࢼࣀ࣐ࢸࣜ࢔ࣝ࡜ࡋ࡚ᮇᚅࡉࢀࡓࠋ
Nominal stress, V(MPa)
୍࣭᪉ྥ࣏࣮ࣛࢫ࣐ࢢࢿࢩ࣒࢘ࡢረᛶኚᙧᣲືࡢゎ᫂
୍᪉ྥ࡟ఙ㛗ࡋࡓከᩘࡢ෇ᰕ≧ࡢẼᏍࢆ
᭷ࡍࡿ୍᪉ྥ࣏࣮ࣛࢫ㔠ᒓࡣࠊ⏕య་⒪⏝
200
Porous Mg
ᮦᩱࠊࣄ࣮ࢺࢩࣥࢡ࠾ࡼࡧ㍍㔞ᵓ㐀ᮦᩱ࡜
Comp. // Pore
ࡋ࡚ࡢᛂ⏝ࡀᮇᚅࡉࢀ࡚࠾ࡾࠊᙎᛶ⋡➼ࡢ
Comp. A Pore
ຊᏛ≉ᛶࡸ⇕ఏᑟ≉ᛶ➼ࡢྛ✀≉ᛶࡢ◊✲
150
ࡀ┒ࢇ࡟⾜ࢃࢀ࡚࠸ࡿࠋ
ᮏ◊✲࡛ࡣࠊ୍᪉ྥ࣏࣮ࣛࢫ㔠ᒓࡢ୰࡛
ࡶ⏬ᮇⓗ࡞㍍㔞ᛶࢆ᭷ࡍࡿ୍᪉ྥ࣏࣮ࣛࢫ
100
࣐ࢢࢿࢩ࣒࢘࡟╔┠ࡋࠊࡑࡢረᛶኚᙧ≉ᛶ
ࢆㄪ࡭ࡓࠋ
ᅗ 3 ࡟Ỉ⣲㞺ᅖẼୗ࡛ࡢ୍᪉ྥจᅛ࡟ࡼ
50
ࡗ࡚స〇ࡉࢀࡓẼᏍ⋡ 37.5㸣ࡢ࣏࣮ࣛࢫ࣐
ࢢࢿࢩ࣒࢘ࡢẼᏍࡢ㛗ᡭ᪉ྥ࡟ᖹ⾜(//)࠾
ࡼࡧᆶ┤(ԋ)࡞᪉ྥࡢ‽㟼ⓗ㏿ᗘ(పࡦࡎࡳ
0
㏿ᗘ)࡛ࡢᅽ⦰ᛂຊ̺ࡦࡎࡳ᭤⥺ࢆ♧ࡍࠋẼ
0
10
20
30
40
50
60
Ꮝ࡟ᆶ┤࡞᪉ྥࡢᅽ⦰ኚᙧ࡟࠾࠸࡚ࡣࠊࡦ
Nominal strain, H(%)
ࡎࡳࡢቑຍ࡟క࠸ᛂຊ್ࡀ༢ㄪ࡟ቑຍࡍࡿࠋ
ᅗ 3 ୍᪉ྥ࣏࣮ࣛࢫ࣐ࢢࢿࢩ࣒࢘ࡢẼᏍࡢ㛗ᡭ᪉ྥ࡟ᖹ⾜࠾ࡼࡧᆶ┤
୍᪉ࠊẼᏍ࡟ᖹ⾜࡞᪉ྥࡢᅽ⦰࡟࠾࠸࡚ࡣࠊ
࡞᪉ྥࡢᛂຊ̺ࡦࡎࡳ᭤⥺(‽㟼ⓗ㏿ᗘ)ࠋ
ࡦࡎࡳ⣙ 20㹼25㸣⛬ᗘ࡛ᛂຊ್ࡀࣆ࣮ࢡ
ࢆ♧ࡍ≉␗࡞ኚᙧᣲືࡀ⌧ࢀࡿࡇ࡜ࡀ᫂ࡽ
࠿࡜࡞ࡗࡓࠋࡇࡢࡼ࠺࡞ᛂຊ್ࡢࣆ࣮ࢡࡣࠊ
ࡦࡎࡳ㏿ᗘ 1.9™103 s-1 ࡢ㧗ࡦࡎࡳ㏿ᗘ࡛ࡶ⌧ࢀࠊࡑࡢ⤖ᯝࠊ⣙ 30 kJ/kg ࡜࠸࠺ඃࢀࡓ⾪ᧁ࢚ࢿࣝࢠ࣮྾
཰≉ᛶࡀᚓࡽࢀࡿࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡗࡓࠋ
⤖ᬗረᛶ᭷㝈せ⣲ἲ࠾ࡼࡧ X ⥺ᴟⅬᅗࢆ⏝࠸ࡓኚᙧ࣓࢝ࢽࢬ࣒ࡢゎᯒ࡟ࡼࡾࠊẼᏍ࡟ᖹ⾜࡞᪉ྥࡢᅽ
⦰ኚᙧ࡟࠾࠸࡚ฟ⌧ࡍࡿᛂຊ್ࡢࣆ࣮ࢡࡣࠊ୍᪉ྥจᅛ࡟ࡼࡗ࡚ᙧᡂࡉࢀࡿ {1013} ࡢἲ⥺ࡀẼᏍࡢ㛗ᡭ
᪉ྥ(จᅛ᪉ྥ)࡟ඃඛⓗ࡟㓄ྥࡋࡓ≉␗࡞㞟ྜ⤌⧊࡜୍᪉ྥẼᏍࡢ┦஫స⏝࡟ࡼࡗ࡚ᘬࡁ㉳ࡇࡉࢀࡿࡇ
࡜ࡀ᫂ࡽ࠿࡟࡞ࡗࡓࠋ
― 54 ―
ඛ➃ᐇ⿦ᮦᩱ◊✲ศ㔝
ᩍᤵ
Ⳣ἟ ඞ᫛
≉௵ᩍᤵ ᮧᯇ ဴ㑻
≉௵෸ᩍᤵ
㛗ᑿ ⮳ᡂ
ຓᩍ
Ⳣཎ ᚭ
≉௵ຓᩍ
㓇 㔠፱
≉௵ᢏ⾡⫋ဨ ᶓ஭ ⤮⨾
༤ኈ◊✲ဨ
Manjeet shingh, Hui-Wang Cui, ᮔ ⪷※
ᢏ⾡⿵బဨ ⏿ᮧ ┿⌮Ꮚࠊຍ㈡⨾ ᐀ᏊࠊἨ Ὀⴥࠊ㧗ᶫ ྖࠊᘅ℩ ⏤⣖Ꮚࠊ
኱Ꮫ㝔Ꮫ⏕
ᅜ᐀ ဴᖹࠊⲨᮌ ᚭᖹࠊ㔠 Ọ㘏ࠊ࿋
ࢳ࣑ࣙࣝࣥࠊᮔ ࢭ࣑ࣥࠊ஝ ဴ἞ࠊୖ℧ 㡿஧ࠊእᮧ ⱥႹࠊᯇᑿ ⌶ᮁࠊྀ ᶞ
ோࠊ⋤ ྩࠊ๽ ೺᫓ ᙇ ᪿࠊᑠ㈡ ಇ㍜ࠊⰰᕝ 㡴ࠊ
஦ົ⿵బဨ
㕥ᮌ ᩗᏊࠊ⸨஭ ࡳ࡝ࡾ
a) ᴫせ
ᙜ◊✲ᐊ࡛ࡣࠊࢼࣀࢸࢡࣀࣟࢪ࣮࡜࢚ࣞࢡࢺࣟࢽࢡࢫࡢ᥋Ⅼࡣᐇ⿦࡟࠶ࡿ࡜ᥦ᱌ࡋࠊ᪂ࡓ࡞ᢏ⾡ศ㔝
ࡢ㛤ᣅࢆୡ⏺࡟ඛ㥑ࡅ࡚㐍ࡵ࡚ࡁࡓࠋ᪂ࡓ࡞ᐇ⿦ᢏ⾡ࢆ㛤Ⓨࡍࡿࡓࡵ࡟ࠊ༳ๅᢏ⾡ࢆ⏝࠸ࡓࢹࣂ࢖ࢫ⏝
ᑟ㟁ᛶ㓄⥺ࡢ㛤Ⓨࡸḟୡ௦᥋ྜᮦᩱࡢ㛤Ⓨࠊ≉࡟࣡࢖ࢻࣂࣥࢻࢠࣕࢵࣉ༙ᑟయࢆ⏝࠸ࡓ㧗 ືసࣃ࣮࣡
ࢹࣂ࢖ࢫྥࡅࡓᐇ⿦ᮦᩱࡢ㛤Ⓨ࡜ಙ㢗ᛶホ౯➼ࢆ⢭ຊⓗ࡟㐍ࡵ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭࢞ࢫࢭࣥࢧ࣮ࡢࡓࡵࡢ࣡ࣥࢫࢸࢵࣉ࣭ࢯࣝࢤࣝἲ࡟ࡼࡿ 0R2 ࢼࣀࣟࢵࢻࡢྜᡂ
༳ๅ࡟ࡼࡿ࢞ࢫࢭࣥࢧ࣮⣲Ꮚࡢ㛤Ⓨ࡟ྥࡅ࡚ࠊ࣡ࣥࢫࢸࢵࣉ࣭ࢯࣝࢤࣝἲࢆ⏝࠸࡚┤᥋Ș┦㓟໬ࣔ
ࣜࣈࢹࣥ0R2ࡢࢼࣀࣟࢵࢻࢆࢩࣜ࢝࢞ࣛࢫᇶᯈୖ࡟ྜᡂ࣭ᡂ㛗ࡉࡏࡿ஦࡟ᡂຌࡋࡓࠋᇶᯈୖ࡛ࣛࣥࢲ
࣒࡞ྥࡁ࡟࡟ᡂ㛗ࡋࡓࠊ༢┦༢⤖ᬗࢼࣀࣟࢵࢻࡢᖹᆒᚄ࡜㛗ࡉࡣࡑࢀࡒࢀQP࡜QP࡛࠶ࡗࡓࠋ
.࡛ศࡢ↝⤖࡟ࡼࡾࠊ᭱኱㛗 QP ࢼࣀࣟࢵࢻࢆᚓࡓࠋࢼࣀࣟࢵࢻࡢᡂ㛗㏿ᗘࡣࠊࣉ࣮ࣜ࢝
ࢧ࣮୰࡛0R࡜ࢡ࢚ࣥ㓟ࡢసࡿ㘒యࡢศゎࢫࢸࢵࣉ࡟኱ࡁࡃ㛵ಀࡋ࡚࠸ࡿࡇ࡜ࡀࢃ࠿ࡗࡓࠋ
― 55 ―
࣭㔠ᒓࢼࣀ࣡࢖ࣖࡢ㏱᫂ᑟ㟁⭷ཬࡧᛂ⏝
㔠ᒓࢼࣀ࣡࢖ࣖࠊ㖟ࢼࣀ࣡࢖࣮ࣖ㸦$J1:V㸧࡜㖡ࢼࣀ࣡࢖࣮ࣖ㸦&X1:V㸧ࡣࠊ‵ᘧ໬Ꮫἲ࡛኱つᶍ࠿ࡘ
㧗཰⋡࡛ྜᡂࡍࡿࡇ࡜ࡀ࡛ࡁࡿࠋࡇࢀࡽࡢࢼࣀ࣡࢖ࣖࡣᛌ㏿࡛⡆༢࡟༳ๅᢏ⾡࡟ࡼࡗ࡚✀ࠎࡢᇶᮦୖ࡟
ࢥ࣮ࢸ࢕ࣥࢢࡋ࡚ࠊ㏱᫂ᑟ㟁⭷ࢆసࡿࡇ࡜ࡀ࡛
ࡁࠊࡑࡢᚋࠊᑟ㟁⋡ཬࡧ㏱㐣⋡ࢆᨵၿࡍࡿࡓࡵࠊ
ᵝࠎ࡞ᚋฎ⌮ࢆ⏝࠸࡚ࠊ㧗ᛶ⬟㏱᫂ᑟ㟁⭷ࢆస
〇ࡍࡿࡇ࡜ࡀ࡛ࡁࡓࠋ3(7 ᇶᯈୖ 㸣ࡢ㏱㐣⋡
ࡢ $J1:V ㏱ ᫂ 㟁 ᴟ ࡢ ࢩ ࣮ ࢺ ᢬ ᢠ ࡣ ࢃ ࡎ ࠿
Ȑ‫࡟ڧ‬ᐇ⌧ࡋࠊྠࡌࡼ࠺࡟ࡼࡾᏳ౯࡞ &X1:V
ࡣ 㸣ࡢ㏱㐣⋡࡜ Ȑ‫ࢺ࣮ࢩࡢڧ‬᢬ᢠࡶไᚚ
ࡋࡓࠋ༙㏱᫂ $J1:V ⭷ࢆ⏝࠸࡚ࠊࢧࣥࢻ࢖ࢵࢳ
ᵓ㐀ࡢࢭࣥࢧ࣮ࢹࣂ࢖ࢫࢆస〇ࡋࠊே㛫ࡢ⾑ᾮ
ࣃࣝࢫࠊࣁ࣮ࢺࣅ࣮ࢺࠊ࿧྾࡞࡝ࡢືࡁࢆ᳨ฟ
ࡍࡿࡇ࡜ࡀ࡛ࡁࡓࠋ
࣭SiC ᚤᑠ⢏Ꮚῧຍ࡟ࡼࡿ㖟࣮࣌ࢫࢺ᥋ྜࡢ㧗 ⪏ᛶࢲ࢖࢔ࢱࢵࢳࡢᨵၿ
ືస ᗘ 200 ᗘ௨ୖࢆ┠ᣦࡍḟୡ௦ SiC ࣃ࣮༙࣡ᑟయࡢᐇ⿦ᢏ⾡࡛ࡣࠊ㧗⪏⇕ࢲ࢖࢔ࢱࢵࢳᢏ⾡ࡀ㘽
࡜࡞ࡿࠋࡇࢀࡣࠊ୺࡟༙ᑟయࢲ࢖࡜࣮ࣜࢻࣇ࣮࣒ࣞࡢ⇕⭾ᙇಀᩘ(CTE)ࡢ኱ࡁ࡞㐪࠸࡟ࡼࡿ⇕ᛂຊࡀၥ
㢟࡟࡞ࡿ࠿ࡽ࡛࠶ࡿࠋ㖟࣮࣌ࢫࢺ᥋ྜࡣ↝⤖⤌⧊ࡀከᏍ㉁ࢿࢵࢺ࣮࣡ࢡࢆసࡿࡢ࡛ࠊࢲ࢖࡜ᇶᯈ㛫ࡢ⇕
ᛂຊࢆ⦆࿴ࡍࡿࡇ࡜ࡀᮇᚅࡉࢀ࡚࠸ࡿࠋࡋ࠿ࡋ࡞ࡀࡽࠊ↝⤖ ᗘ࡛࠶ࡿ 250 ᗘ௨ୖ࡛ࡣࠊ㖟࣮࣌ࢫࢺࡢ
᭦࡞ࡿ↝⤖ࡀ㐍ࡴ஦ࡀᠱᛕࡉࢀ࡚࠾ࡾࠊ㖟ࡢᚤ⣽ᵓ㐀ࡢ㧗 Ᏻᐃᛶࡀ☜❧ࡋ࡚࠸࡜ࡣゝ࠼࡞࠸ࠋᡃࠎࡣࠊ
㸿㹥࣮࣌ࢫࢺ࡟ SiC ᚤ⢏Ꮚࢆῧຍࡍ
ࡿࡇ࡜࡛ࠊ㧗 ࡟࠾ࡅࡿᚤ⣽⤌⧊ࡢ
⢒኱໬ࢆ㜵Ṇࡍࡿࡇ࡜࡟ᡂຌࡋࡓࠋ
ᅗ࡟ 250 ᗘ࡟࠾ࡅࡿ㸿㹥↝⤖⤌⧊ࡢ
ኚ໬ࢆ♧ࡍࠋSiC ࢭ࣑ࣛࢵࢡ⢏Ꮚࡀ
ぢ஦࡟㐣๫࡞↝⤖ࢆ㜵ࡂࠊᚤ⣽࡞㖟
ࢿࢵࢺ࣮࣡ࢡᵓ㐀ࢆ⥔ᣢࡋ࡚࠾ࡾࠊ
᭦࡞ࡿ㧗 ⪏ᛶࠊᏳᐃᛶࡀᮇᚅ࡛ࡁ
ࡿࠋ
࣭ᛂຊ࣐࢖ࢢ࣮ࣞࢩࣙࣥ࡜ࣄࣟࢵࢡᙧᡂ࡟ࡼࡿ㖟⭷┤᥋᥋ྜ
ᡃࠎࡣ㧗⪏⇕᥋ྜᢏ⾡࡜ࡋ࡚ᛂຊ࣐࢖ࢢ࣮ࣞࢩࣙࣥ
ࢆ⏝࠸ࡓ㖟⭷┤᥋᥋ྜᢏ⾡ࢆᥦ᱌ࡋ࡚ࡁࡓࠋࡇࢀࡣࠊ
኱Ẽ㞺ᅖẼ࡟࠾࠸࡚ప ࡜↓ᅽຊ࡛᥋ྜྍ⬟࡛࠶ࡿ
࡜࠸࠺኱ࡁ࡞฼Ⅼࢆᣢࡘࠋࡇࡢ᥋ྜࣉࣟࢭࢫࡢ࣓࢝ࢽ
ࢬ࣒ࢆ᫂ࡽ࠿࡟ࡍࡿࡓࡵ࡟ࠊࣄࣟࢵࢡᡂ㛗ࡢࣉࣟࢭࢫ
ࢆゎ᫂ࡍࡿࡓࡵ࡟㹒㹃㹋ほᐹ࡟ࡼࡿ᥋ྜ⏺㠃ࡢほᐹ
ࢆ⾜ࡗࡓࠋ⤖ᬗ⢏௨ୖᡂ㛗ࢆ♧ࡍࣄࣟࢵࢡࡢ࿘ࡾ࡟ࡣ
㖟ࢼࣀ⢏Ꮚࡀ෌⤖ᬗࡍࡿᵝᏊࡀぢࡽࢀࡿࠋ㖟ࡢ㓟໬㑏
ඖࣉࣟࢭࢫ࡜෌⤖ᬗࡢ⤌ࡳྜࢃࡏࡀ㖟⭷┤᥋᥋ྜࢆ
ྍ⬟࡟ࡋ࡚࠸ࡿࡇ࡜ࡀุࡗࡓࠋ
― 56 ―
ບ㉳≀ᛶ⛉Ꮫ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
෸ᩍᤵ
ຓᩍ
༤ኈ◊✲ဨ
஦ົ⿵బဨ
㇂ᮧ ඞᕫ
⏣୰ ៅ୍㑻
㔠ᓮ 㡰୍
ᡂ℩ ᘏᗣ㸦ᖹᡂ 27 ᖺ 2 ᭶ 28 ᪥ࡲ࡛㸧
Giret Yvelin
ΎỈ ᐇబᏊ
a) ᴫせ
ᮏ◊✲ศ㔝࡛ࡣࠊᅛయࡢ㟁Ꮚ⣔ࡀບ㉳ࡉࢀࡓ㝿࡟Ⓨ⏕ࡍࡿ✀ࠎࡢཎᏊ㐣⛬㸦㟁Ꮚບ㉳ㄏ㉳ཎᏊ㐣⛬㸧
ࡢᶵᵓࢆゎ᫂ࡋࠊཎᏊ㐣⛬ࢆไᚚ࣭⤌⧊໬ࡋ࡚᪂つࡢ㧗ḟᶵ⬟ᵓ㐀ࢆ๰〇ࡍࡿ஦ࠊࢆ┠ⓗ࡜ࡋ࡚࠸ࡿࠋ
ᚑ᮶ࡢᡭἲࡀ᭷ࡋ࡚࠸ࡓ⇕ຊᏛⓗᖹ⾮᮲௳ࡢไ⣙ࢆ኱ࡁࡃᡴ◚ࡋࠊᮦᩱ⛉Ꮫ࣭≀㉁⛉Ꮫࡢ᪂ࡓ࡞ᒎ㛤᪉
ྥࢆ㛤ᣅࡍࡿࠋࡇࡢ┠ⓗࡢⅭࠊᅛయෆ㒊ཬࡧ⾲㠃࡟࠾ࡅࡿ㟁Ꮚ࣭ṇᏍ࣭᱁Ꮚ⣔ࡢ㠀ᖹ⾮ບ㉳≧ែ࡟㛵ࡍ
ࡿヲ⣽࡞▱ぢࢆᚓࡿ࡜ඹ࡟ࠊࡑࡢᚋࡢ⦆࿴ࢲ࢖ࢼ࣑ࢡࢫࢆゎ᫂ࡍࡿࠋᅛయࡢບ㉳ᡭἲ࡜ࡋ࡚ࠊࣃࣝࢫࣞ
࣮ࢨ࣮ගࠊࢩࣥࢡࣟࢺࣟࣥᨺᑕගࠊ㟁Ꮚ⥺ࠊࣉ࣮ࣟࣈ㢧ᚤ㙾࡟ࡼࡿ࢟ࣕࣜ࢔ὀධ➼ࠊከᙬ࡞ບ㉳※ࢆ⏝
࠸࡚㟁Ꮚບ㉳≧ែࢆไᚚࡋ࡚Ⓨ⏕ࡉࡏࠊ⏕ᡂࡉࢀࡿ㟁Ꮚບ㉳≧ែࡢᛶ㉁࡜ࡑࡢືⓗᣲືࢆࠊゅᗘ࣭᫬㛫
ศゎග㟁Ꮚศගἲࢆ୺࡜ࡍࡿศගᡭἲࢆ⏝࠸࡚ࠊ࢚ࢿࣝࢠ࣮࣭㐠ື㔞✵㛫࡜࠸ࡗࡓከḟඖ✵㛫࡟࠾࠸࡚
ࣇ࢙࣒ࢺ⛊ࡢ᫬㛫㡿ᇦ࡛ᐇ᫬㛫㏣㊧ࡍࡿ࡜ඹ࡟ࠊㄏ㉳ࡉࢀࡿᵓ㐀ኚ໬ࡸ᪂ወᵓ㐀┦ࢆ㉮ᰝᆺࢺࣥࢿࣝ㢧
ᚤ㙾/ࢺࣥࢿࣝศගἲ࡟ࡼࡾཎᏊ࡛ࣞ࣋ࣝ┤᥋ほᐹࡍࡿࠋ
b) ᡂᯝ
࣭㹇 ༙ᑟయෆ㒊ཬࡧ⾲㠃࡟࠾ࡅࡿບ㉳㟁Ꮚ⣔ࡢ㉸㧗㏿ືຊᏛ
ບ㉳㟁Ꮚ⣔ࡢ⦆࿴ືຊᏛࡣࠊᅛయෆ㒊ࡔࡅ࡛࡞ࡃࠊ⾲㠃࣭⏺㠃࡟࠾ࡅࡿᵝࠎ࡞ບ㉳ㄏ㉳⌧㇟࡟㛵୚ࡋ
࡚࠸ࡿࠋᚑࡗ࡚ࠊᅛయෆ㒊࡜⾲㠃ࡢບ㉳㟁Ꮚ⣔࡟ࡘ࠸࡚ࠊ࢚ࢿࣝࢠ࣮࣭㐠ື㔞✵㛫࡟࠾ࡅࡿᐦᗘศᕸኚ
໬ࢆᐇ᫬㛫㏣㊧ࡍࡿ஦ࡣࠊບ㉳ㄏ㉳⌧㇟ࢆゎ᫂ࡍࡿୖ࡛ᮏ㉁ⓗ࡟㔜せ࡛࠶ࡿࠋ ࣇ࢙࣒ࢺ⛊㸦IV㸧⛬
ᗘࡢ᫬㛫ᖜࢆᣢࡘ࣏ࣥࣉࣃࣝࢫ࡟ࡼࡾఏᑟᖏ࡟ගὀධࡉࢀࡓບ㉳㟁Ꮚࢆࠊບ㉳࠿ࡽࡢ㐜ᘏ᫬㛫ࢆไᚚࡋ
ࡓࣉ࣮ࣟࣈࣃࣝࢫ࡟ࡼࡾග㟁Ꮚ࡜ࡋ࡚ᨺฟࡉࡏࡿࣇ࢙࣒ࢺ⛊㸰ගᏊග㟁Ꮚศගἲࡣࠊ࢚ࢿࣝࢠ࣮࣭㐠ື
㔞✵㛫࡟࠾ࡅࡿບ㉳㟁Ꮚᐦᗘศᕸࡢ᫬㛫Ⓨᒎ࡟㛵ࡍࡿ┤᥋ⓗ▱ぢࢆ୚࠼ࡿࠋᮏศ㔝࡛ࡣࠊᨺฟ㟁Ꮚࡢ࢚
ࢿࣝࢠ࣮࡜ᨺฟゅ㸦㐠ື㔞㸧ࢆྠ᫬㸰ḟඖ᳨ฟ࡛ࡁࡿ㟼㟁ᆺศᯒჾ࡟ࡼࡾࠊ⤖ᬗෆ㒊ཬࡧ⾲㠃࡟࠾ࡅࡿ
ບ㉳㟁Ꮚ⣔ࡢ⦆࿴㐣⛬ࢆ࢚ࢿࣝࢠ࣮࣭㐠ື㔞㸦㸰ḟඖ㸧
࣭᫬㛫ࡢ㸲ḟඖศග࡜ࡋ࡚㐙⾜ࡋࡓࠋ
༙ᑟయෆ㒊ཬࡧ⾲㠃࡟࠾ࡅࡿບ㉳㟁Ꮚ⣔ࡢ⦆࿴㐣⛬࡟㛵ࡍࡿ▱ぢࢆᚓࡿⅭࠊࢺࣥࢿࣝ㢧ᚤ㙾࡟ࡼࡾཎ
ᅗ1 . Ge(111)-c(2x8) ⾲㠃㏆ഐ࡛ࡢບ㉳㟁ᏊືຊᏛࠋ࢚ࢿࣝࢠ࣮ࠊ㐠ື㔞㸦ゅᗘ㸧✵㛫࡟࠾ࡅࡿග㟁Ꮚᙉᗘ࢖࣓࣮ࢪࡢ᫬㛫Ⓨᒎࠋ
― 57 ―
Ꮚࢫࢣ࣮࡛ࣝ⾲㠃ᵓ㐀ࢆ☜ㄆࡋࡓ༙ᑟయΎί⾲㠃ࢆ⏝࠸ࡓࠋGe(111)-c(2x8)ࢆヨᩱ࡜ࡋ࡚⏝࠸ࠊࣂࣝࢡ
ఏᑟᖏ࡟ගὀධࡉࢀࡓບ㉳㟁Ꮚ⣔࡟ࡘ࠸࡚ᐦᗘศᕸࡢ᫬㛫Ⓨᒎࢆ ᐃࡋࡓ⤖ᯝࢆᅗ㸯࡟♧ࡍࠋ࣏ࣥࣉග
(s ೫ග)ບ㉳ࡼࡗ࡚Ⓨ⏕ࡋࡓࣂࣝࢡఏᑟᖏ㟁Ꮚࡣࠊ౯㟁Ꮚᖏ heavy hole (HH)ࣂࣥࢻࠊlight hole (LH)ࣂࣥ
ࢻ࠾ࡼࡧ split-off (SO)ࣂࣥࢻ࠿ࡽࡢ㑄⛣࡟ᑐᛂࡋ࡚ࠊ࢚ࢿࣝࢠ࣮ཬࡧ㐠ື㔞ࢆಖᏑࡋࡓ -valley ෆࡢఏᑟ
ᖏ఩⨨࡟ὀධࡉࢀࡿࠋග㟁Ꮚᨺฟ㐣⛬࡛ࡢ㑅ᢥ๎ࡢࡓࡵ࡟ࠊⓎ⏕ࡋࡓ -valley ບ㉳㟁Ꮚࡣ⾲㠃ᆶ┤᪉ྥ
࡟ᙉࡃほ ࡉࢀࡿࠋບ㉳ᚋࡢ᫬㛫⤒㐣࡜ඹ࡟ࠊ -valley ෆ࡟⏕ᡂࡉࢀࡓࣂࣝࢡບ㉳㟁Ꮚࡣࠊ60fsec ࡢ᫬
ᐃᩘ࡛ L-valley ෆ㸦ᅗ୰Ⅼ⥺㸧࡟ intervalley ᩓ஘ࡉࢀࡿ஦ࠊࡑࡢᚋ 1psec ⛬ᗘࡢ᫬㛫ࢫࢣ࣮࡛ࣝఏᑟ
ᖏୗ➃(CBM)࡟ྥࡅ࡚ L-valley ෆࢆ࢚ࢿࣝࢠ࣮⦆࿴ࡍࡿ஦ࠊࡀ᫂☜࡟☜ㄆ࡛ࡁࡿࠋࡉࡽ࡟ࠊL-valley
ෆࡢࣂࣝࢡບ㉳㟁Ꮚࡢ୍㒊ࡣࠊࣂࣝࢡࣂࣥࢻࢠࣕࢵࣉ୰࡟Ꮡᅾࡍࡿูࡢࣂࣥࢻ(SB)࡟㑄⛣ࡋࠊࡇࡢࣂࣥ
ࢻෆࢆࡉࡽ࡟࢚ࢿࣝࢠ࣮⦆࿴ࡍࡿࠋᮏ ᐃ࡟ࡼࡾほ ࡉࢀࡓ SB ࣂࣥࢻࡣ Ge(111)-c(2x8)ࡢ㠀༨᭷⾲㠃
ࣂࣥࢻ࡛࠶ࡾࠊ Ⅼ㏆ഐ࡟࠾ࡅࡿศᩓ≉ᛶࡣᐇ㦂ⓗ࡟௒ᅇึࡵ࡚ほ ࡉࢀࡓࡶࡢ࡛࠶ࡿࠋᮏ◊✲ࡢ⤖ᯝ
ࡣࠊ༙ᑟయ⾲㠃ࡢ㠀༨᭷ࣂࣥࢻᵓ㐀ࡢỴᐃࡔࡅ࡛࡞ࡃࠊගㄏ㉳⾲㠃⌧㇟ࡢ⌮ゎ࡟࠾࠸࡚ᴟࡵ࡚㔜せ࡞▱
ぢࢆ୚࠼ࡿࡶࡢ࡜ᮇᚅ࡛ࡁࡿࠋ
࣭II ༢⤖ᬗࢢࣛࣇ࢓࢖ࢺ࡟࠾ࡅࡿ㟁Ꮚ᱁Ꮚ┦஫స⏝ࡢ┤᥋ほᐹ
㟁Ꮚ࣭᱁Ꮚ┦஫స⏝㸦ᩓ஘㸧ࡣᅛయ≀ᛶ࡟࠾࠸࡚᭱ࡶᇶᮏⓗ࡞⣲ບ㉳ࡢ୍ࡘ࡛࠶ࡾࠊ㛗ᖺࡢ◊✲ᑐ㇟
࡜࡞ࡗ࡚࠸ࡿࠋᡃࠎࡣ᭱㏆ࠊ㛫᥋㑄⛣ࠊࡍ࡞ࢃࡕࣇ࢛ࣀࣥ࡟ࡼࡗ࡚ᩓ஘ࡉࢀࡓ㟁Ꮚࢆ┤᥋ゅᗘศゎග㟁
Ꮚศග(ARPES)࡟ࡼࡗ࡚ ᐃࡍࡿ᪂ࡋ࠸ᐇ㦂ᡭἲࢆ㛤Ⓨࡋ[S. Tanaka et al., Sci.Rep. 3 (2013) 3031]ࠊ
ࡉࡽ࡟◊✲ࢆ㐍ࡵ࡚࠸ࡿࠋᅗ 2 ࡣࠊᗈᓥ኱Ꮫࡢᨺᑕග᪋タ HiSOR㸦BL9A㸧࡟࠾࠸࡚ 7.1eV ࠾ࡼࡧ 11.1eV
ࡢບ㉳ගࢆ⏝࠸ࠊ༢⤖ᬗࢢࣛࣇ࢓࢖ࢺ࡛ ᐃࡋࡓ㧗ศゎ⬟ ARPES ࡛࠶ࡿࠋࡇࢀࡽࡢບ㉳࢚ࢿࣝࢠ࣮ࡣࠊ
ࡑࢀࡒࢀࢢࣛࣇ࢓࢖ࢺࡢ㠃㛫᣺ື࠾ࡼࡧ㠃ෆ᣺ືࣇ࢛ࣀࣥ࡟ࡼࡿᩓ஘ࢆྵࡴ㛫᥋㑄⛣࡜ඹ㬆ࡋ࡚࠸ࡿࠋ
ᅗࡢⰍᙉᗘࡣࠊග㟁Ꮚᙉᗘࢆ࢚ࢿࣝࢠ࣮࡟ࡼࡗ࡚ᚤศࡋࠊࢫࢸࢵࣉᙧ≧ࢆࣆ࣮ࢡ࡟ኚ᥮ࡋࡓࡶࡢ࡛࠶ࡿࠋ
࢚ࢿࣝࢠ࣮ಖᏑ๎࡟ࡼࡗ࡚ࠊ㟁Ꮚࣇ࢛ࣀࣥᩓ஘࡟క࠸ࣇ࢙࣑࢚ࣝࢵࢪࡀࣇ࢛ࣀࣥࡢ࢚ࢿࣝࢠ࣮ศࡔࡅࢩ
ࣇࢺࡋ࡚ほ ࡉࢀࡿࡢ࡛ࠊࡇࢀ࡟ࡼࡗ࡚ࣇ࢛ࣀࣥࡢศᩓࢆࣉࣟࢵࢺ࡛ࡁࡿࠋࣇ࢛ࣀࣥ࡟ࡼࡿᩓ஘ࡢጞ≧
ែࡣࢢࣛࣇ࢓࢖ࢺ࡟࠾࠸࡚ࡣ㹉࠾ࡼࡧ㹉̓Ⅼ࡟࠶ࡾࠊࡇࡇ࡛ࡣ㟁Ꮚࡢศᩓࢆǻ̿㹉᪉ྥ࡛ ᐃࡋ࡚࠸ࡿ
ࡢ࡛ࠊ㐠ື㔞ಖᏑ๎࡟ࡼࡾࣇ࢛ࣀࣥࡢ㐠ື㔞࡜ࡋ࡚ࡣ㹉̓㸫ǻ࠾ࡼࡧ㹉㸫㹋ࢆほ ࡋ࡚࠸ࡿࡇ࡜࡟࡞ࡿࠋ
ᅗ୰ࡢᐇ⥺࠾ࡼࡧⅬ⥺ࡣࡑࢀࡒࢀࡢ᪉ྥ࡛ࡢ⌮ㄽィ⟬ࡢ⤖ᯝ࡛࠶ࡾࠊᴫࡡᐇ㦂⤖ᯝ࡜୍⮴ࡋ࡚࠸ࡿࡇ࡜
ࡀศ࠿ࡿࠋࡇࡇ࡛ほᐹࡋ࡚࠸ࡿ㛫᥋㑄⛣ࡣࠊጞ≧ែ࣭୰㛫≧ែ࣭⤊≧ែ࣭ග㟁ሙ࣋ࢡࢺ࣭ࣝࣇ࢛ࣀࣥࡀ
඲࡚㛵୚ࡋࡓ࣐ࢺࣜࢵࢡࢫ࢚࣓ࣞࣥࢺ࡟ࡘ࠸࡚ࡢ┤᥋ⓗ࡞▱ぢࢆ୚࠼࡚ࡃࢀࡿࠋࡇࡢᡭἲࡣࠊᅛయ࡟࠾
ࡅࡿ㟁Ꮚ᱁Ꮚᩓ஘ࢆ࢚ࢿࣝࢠ࣮࣭㐠ື㔞ࡲ࡛ศゎࡋ࡚ ᐃ࡛ࡁࡿึࡵ࡚ࡢᡭἲ࡛࠶ࡿࠋࡉࡽ࡟ࢢࣛࣇ࢙
ࣥࡸࢢࣛࣇ࢓࢖ࢺ┦㛵໬ྜ≀࡞࡝ࠊᵝࠎ࡞≀㉁࡟࠾࠸࡚◊✲ࢆ㐍ࡵࠊ㟁Ꮚ᱁Ꮚ┦஫స⏝ࡢᮏ㉁࡟ࡘ࠸࡚
⤫୍ⓗ࡞⌮ゎࢆᚓࡿ࡭ࡃ◊✲ࡀ㐍ࢇ࡛࠸ࡿࠋ
TO mode
ZO,ZA mode
ᅗ 2 ARPES ࡟ࡼࡗ࡚ồࡵࡓ㟁Ꮚࡢᩓ஘࡟ᐤ୚ࡋࡓ༢⤖ᬗࢢࣛࣇ࢓࢖ࢺࡢࣇ࢛ࣀࣥࡢศᩓ㸸hȞ=7.1eVᕥ11.1eVྑࠋ
― 58 ―
㔞Ꮚࣅ࣮࣒Ⓨ⏕⛉Ꮫ◊✲ศ㔝
ᩍᤵ ෸ᩍᤵ ຓᩍ ≉௵ᩍᤵ
኱Ꮫ㝔Ꮫ⏕
☾ᒣ
ຍ⸨
ᕝ℩
ධ⃝
Ⳣ ⸨ᮏ
ᝅᮁ
㱟ዲ
ၨᝅ
᫂඾
⁠ṇ
ᑘ㍤ࠊ▮ཱྀ 㞞㈗ࠊ⯪㉺ ኊுࠊሐ ுኴ
a) ᴫせ
⢏Ꮚຍ㏿ჾࡣᇶ♏⛉Ꮫ࠿ࡽ⏘ᴗࡲ࡛ᗈࡃ฼⏝ࡉࢀ࡚࠸ࡿࠋᙜ◊✲ศ㔝ࡣࠊ㧗㍤ᗘ㟁Ꮚࣅ࣮࣒ࡸග࡞࡝
㔞Ꮚࣅ࣮࣒ࡢⓎ⏕࡜࠸࠺ほⅬ࠿ࡽຍ㏿ჾࢆ࡜ࡽ࠼◊✲ࡋ࡚࠸ࡿࠋຍ㏿ჾࡣேᕤ≀࡛࠶ࡿࡀࠊᴟ㝈ᛶ⬟ࢆ
㏣ồࡍࡿ࡜㠀⥺ᙧᛶࡸ㞟ᅋ㐠ື࡞࡝ࡢ⯆࿡᭷ࡿ≀⌮ࡢᇶᮏၥ㢟ࡀ⌧ࢀࡿࠋ᪂ࡋ࠸㔞Ꮚࣅ࣮࣒ࡣேࡀぢࡿ
஦ࡢฟ᮶ࡿୡ⏺ࢆᗈࡆࡿࡢ࡛ᇶ♏◊✲࠿ࡽᛂ⏝ࡲ࡛ᗈ࠸⠊ᅖࡢ฼⏝ࡀᮇᚅ࡛ࡁࡿࠋලయⓗ࡟ࡣࠊ㟁Ꮚ⥺
ᙧຍ㏿ჾࡢ㧗ᛶ⬟໬࣭㧗Ᏻᐃ໬࡟㛵ࡍࡿ◊✲ࡸ㟁Ꮚࣅ࣮࣒ຍ㏿࡟క࠺ࣅ࣮࣒ࢲ࢖ࢼ࣑ࢡࢫࡢ◊✲ࠊ⥺ᙧ
ຍ㏿ჾ࡛Ⓨ⏕ࡋࡓ㟁Ꮚࣅ࣮࣒ࢆ⏝࠸࡚㉥እ㸦ࢸࣛ࣊ࣝࢶ㸧㡿ᇦ࡛ࡢ⮬⏤㟁Ꮚ࣮ࣞࢨ࣮㸦FEL㸧ࡢᐇ⏝໬
࡬ྥࡅ࡚ࡢ㛤Ⓨ◊✲࡜ࠊⓎ⏕ࡋࡓࢥࣄ࣮ࣞࣥࢺගࢆ⏝࠸ࡓ≀ᛶ≀⌮Ꮫࡸ㛵㐃ศ㔝ࡢ฼⏝◊✲ࢆ⾜ࡗ࡚࠸
ࡿࠋ
b) ᡂᯝ
࣭/ ࣂࣥࢻ㟁Ꮚࣛ࢖ࢼࢵࢡࢆ⏝࠸ࡓࢸࣛ࣊ࣝࢶ )(/ ࡢ㧗ᛶ⬟໬
ᡃࠎࡀ㛤Ⓨ◊✲ࢆ㐍ࡵ࡚࠸ࡿ㐲㉥እ࣭ࢸࣛ࣊ࣝࢶ㡿ᇦࡢ)(/ࡣࠊἼ㛗ࡀ25࠿ࡽ150 ȝm㸦࿘Ἴᩘ࡛࠿ࡽ
12 THz㸧ࡢ⠊ᅖ࡛ฟຊ㣬࿴࡟㐩ࡍࡿ㧗ฟຊືసࢆᐇ⌧ࡋ࡚࠸ࡿࠋ27 MHz࣮ࣔࢻ࡜ྡ௜ࡅࡓFELࡢ㧗ฟຊ
㐠㌿ࢆ᫖ᖺᗘ㛤Ⓨࡋࡓࡀࠊ௒ᖺᗘࡣFELࡢ᭦࡞ࡿฟຊ㧗ᙉᗘ໬ࢆ┠ᣦࡋ࡚㟁Ꮚࣛ࢖ࢼࢵࢡ࡜ࣅ࣮࣒㍺㏦
㊰ࡢ᭱㐺໬ࢆヨࡳࡓࠋ108 MHz࣮ࣔࢻ࡜ྡ௜ࡅࡓᚑ᮶ࡢ㐠㌿࣮ࣔࢻ࡛ࡣࠊ㟁Ꮚ㖠࠿ࡽ㛗ࡉ8 —sࡢࣃࣝࢫ㟁
Ꮚࣅ࣮࣒ࢆྲྀࡾฟࡋࠊࢧࣈࣁ࣮ࣔࢽࢵࢡࣂࣥࢳ࣮ࣕࢆ⏝࠸࡚㟁Ꮚࣂࣥࢳ⧞㏉ࡋࡀ108 MHzࡢ㟁Ꮚࣅ࣮࣒
ࢆ⏕ᡂࡍࡿࠋࡇࡢ㐠㌿࣮ࣔࢻ࡛ࡢ᭱㐺࡞ධᑕࣅ࣮
࣒㟁ὶࡣ0.6 A࡛ࠊFEL࡬ධᑕࡍࡿ㟁Ꮚࣅ࣮࣒ࡢࣂ
ࣥࢳ㟁Ⲵࡣ1 nC⛬ᗘ࡛࠶ࡿࠋࡑࡇ࡛ࠊ27 MHzࣃ
ࣝࢫ࡛㟁Ꮚ㖠ࢆ㥑ືࡍࡿࢢࣜࢵࢻࣃࣝࢧ࣮ࡢ㛤
Ⓨ┠ᶆ࡜ࡋ࡚ࠊ㟁Ꮚ㖠ࣆ࣮ࢡฟຊ㟁ὶࢆ108 MHz
࣮ࣔࢻࡢ㸲ಸ࡛࠶ࡿ2.4 A࡜ࡋࡓࠋ㛤Ⓨࡋࡓࢢࣜ
ࢵࢻࣃࣝࢧ࣮ࡣ┠ᶆ್ࢆ㉸࠼ࡿฟຊ㟁ὶࢆⓎ⏕
࡛ࡁࡿࡀࠊࣅ࣮࣒ㄪᩚࡢ⤖ᯝࠊධᑕࣆ࣮ࢡ㟁ὶࡣ
1.6 A⛬ᗘࡀ᭱㐺࡛࠶ࡗࡓࠋࡇࢀࢆ㉸࠼ࡿ㟁ὶࢆ
ධᑕࡍࡿ࡜ࠊࢧࣈࣁ࣮ࣔࢽࢵࢡࣂࣥࢳ࣮ࣕࡢRF
ࡀ኱ࡁࡃ஘ࢀࠊ㧗ရ㉁ࡢࣅ࣮࣒ࡀ⏕ᡂ࡛ࡁ࡞࠸ࠋ
ࡇࡢཎᅉ࡟ࡘ࠸࡚ࡣࠊ௒ᚋㄪᰝࡍࡿணᐃ࡛࠶ࡿࠋ
㟁Ꮚ㖠ࡢࣆ࣮ࢡฟຊ㟁ὶࡀ1.6 A࡛ຍ㏿ჾࣃࣛ
ᅗ㸯0+] ࢢࣜࢵࢻࣃࣝࢧ࣮ࢆ⏝࠸ࡓ )(/ Ⓨ᣺࡟ࡼࡾᚓࡽࢀࡓ
࣓࣮ࢱࢆㄪᩚࡋࡓ⤖ᯝࠊFEL࡬ධᑕࡍࡿࣅ࣮࣒ࡢ
࣐ࢡࣟࣃࣝࢫ࠶ࡓࡾࡢฟຊ࢚ࢿࣝࢠ࣮ࡢἼ㛗౫Ꮡᛶࠋ᭱኱ᙉᗘࡣ
ࣂࣥࢳ㟁Ⲵࡣ4 nC࡛࠶ࡾࠊධᑕ㟁ὶࡀప࠸࡟ࡶ࠿
⌧ᅾࡢࢢࣜࢵࢻࣃࣝࢧ࣮ࢆ⏝࠸ࡓ 0+] ⧞ࡾ㏉ࡋࡢሙྜ࡜ẚ࡭
࠿ࢃࡽࡎ┠ᶆ್࡛࠶ࡿᚑ᮶ࡢ108 MHz࣮ࣔࢻࡢ4
࡚⣙ ಸࠊ)(/ Ⓨ⏕ㄪᩚࡍࡿ๓ᖺᗘ࡟ẚ࡭࡚ࡶ㸯㸬㸳ಸ௨ୖ㧗࠸
ಸࢆ㐩ᡂࡋࡓࠋࡇࡢ㟁Ꮚࣅ࣮࣒ࢆ⏝࠸࡚FELࡢⓎ
ᙉᗘ࡟㐩ࡋ࡚࠸ࡿࠋ
⏕ࢆㄪᩚࡋࡓ⤖ᯝࠊᅗ㸯࡟♧ࡍࡼ࠺࡟ᚑ᮶ࡢ27
MHz࣮ࣔࢻࡼࡾࡶࡉࡽ࡟㸯㸬㸳ಸ௨ୖ㧗࠸ᙉᗘࡢ
― 59 ―
FELⓎ⏕ࢆ㐩ᡂࡋࡓࠋ᭱ࡶ㧗࠸FELࡢࣃࣝࢫ࢚ࢿࣝࢠ࣮ࡣἼ㛗67 ȝm࡛ᚓࡽࢀࠊ࣐ࢡࣟࣃࣝࢫ࢚ࢿࣝࢠ࣮
ࡣ26 mJࠊ࣑ࢡࣟࣃࣝࢫ࢚ࢿࣝࢠ࣮࡛ࡣ200 ȝJ௨ୖ࡜࡞ࡾࠊ20 psࡢࣃࣝࢫᖜࢆ௬ᐃࡍࡿ࡜ࣆ࣮ࢡࣃ࣮࣡ࡣ
10 MW௨ୖ࡜࡞ࡿࠋࡲࡓࠊࣅ࣮࣒ㄪᩚࡢ⤖ᯝࠊᚑ᮶ࡢ108 MHz࣮ࣔࢻ࡛ࡶ࣐ࢡࣟࣃࣝࢫ࢚ࢿࣝࢠ࣮ࡀ10 mJ
ࢆ㉺࠼ࡿ࡟⮳ࡗࡓࠋගඹ᣺ჾෆ࡛Ⓨ⏕ࡍࡿFELࣃࣝࢫࡣ108 MHz࣮ࣔࢻ࡛㸲ಶࡔࡀࠊ27 MHz࣮ࣔࢻ࡛ࡣ
㸯ಶ࡛࠶ࡿࠋ27 MHz࣮ࣔࢻ࡛ࡣ࣑ࢡࣟࣃࣝࢫࡢᩘࡀ4ศࡢ㸯࡟ῶᑡࡍࡿࡇ࡜ࢆ⪃៖ࡍࡿ࡜ࠊ࣑ࢡࣟࣃࣝ
ࢫ࢚ࢿࣝࢠ࣮ࡣ108 MHzࡢ8ಸ࡟ቑຍࡍࡿࠋࡇࢀࡣࠊFELࡀᚑ᮶ࡢ⌮ㄽ࡛ࡣㄝ࡛᫂ࡁ࡞࠸඲ࡃ᪂ࡋ࠸㧗ฟ
ຊືస㡿ᇦ࡟ධࡗࡓࡇ࡜ࢆ♧၀ࡋࠊ௒ᚋࠊගᙉᗘࡀቑ኱ࡍࡿᶵᵓࢆゎ᫂ࡍࡿࡇ࡜ࡀㄢ㢟࡜࡞ࡿࠋ
࣭㧗ᙉᗘࣃࣝࢫ 7+] ගࡢ฼⏝◊✲
ᡃࠎࡣ FEL ࡛Ⓨ⏕ࡋࡓ㧗ᙉᗘ THz ගࡢ฼⏝◊✲ࢆ㐍ࡵ࡚࠸ࡿࠋࡇࢀࡲ࡛ࠊFEL ࡢ༢Ⰽࠊ㧗ᙉᗘᛶࢆ
ά࠿ࡋࡓ㧗㏿ศග࢖࣓࣮ࢪࣥࢢࡸᚤ㔞ᡂศࡢࡑࡢሙศᯒ࡟ᡂຌࡋࡓࠋTHz ගࡣඹ᣺ჾ࣑࣮ࣛ࠿ࡽฟࡓᚋࠊ
ගᏛ⣔࡟ࡼࡗ࡚᭱⤊ⓗ࡟ᖹ⾜ග࡜ࡋ࡚ᐇ㦂ࢫࢸ࣮ࢩࣙࣥୖ࡟ྲྀࡾฟࡍࠋᐇ㦂ࡣ㞟ගୗ࡛⾜࠺ࡀࠊගᏛ⣔
ࢆ᭦࡟ᨵⰋࡋ࡚᭷ຠᚄ 1/2 ࢖ࣥࢳࠊ↔Ⅼ㊥㞳 1/2 ࢖ࣥࢳࡢ㍈እࡋᨺ≀㠃㙾ࢆ⏝࠸ࡿࡇ࡜࡟ࡼࡾࠊᅇᢡ㝈
⏺࡟㏆࠸ࢧ࢖ࢬ࡟ࡲ࡛㞟ගࡍࡿࡇ࡜࡟ᡂຌࡋࡓࠋᅗ 2㸦a㸧࡟ࢼ࢖ࣇ࢚ࢵࢪ࡟ࡼࡗ࡚ ᐃࡋࡓ㞟ග᮲௳ୗ
࡛ࡢගᙉᗘࡢ✵㛫ศᕸࢆ♧ࡍࠋග㍈᪉ྥࢆ z ࡜ࡋࠊග㍈࡟ᆶ┤࡞㠃ࢆ xy ࡜ࡍࡿ࡜ࠊz ㍈(300ȝm ࢫࢸࢵ
ࣉ)ࢆኚ໬ࡉࡏࡿ࡟ࡋࡓࡀࡗ࡚ xy ᖹ㠃࡛ࡣ࡯ࡰ෇ᙧࡢࡲࡲࠊ↔Ⅼ㸦7 ࢫࢸࢵࣉ㸧࡟ྥࡅ࡚㞟᮰ࡍࡿࠋࡲ
ࡓࠊࣅ࣮࣒ᚄࡀ 200ȝm
௨ୗࢆಖࡘ㡿ᇦࡀ z ㍈᪉
ྥ࡛ 5mm ⛬ᗘ࠶ࡾࠊᅗ
㸰㸦b㸧࡟♧ࡍࣅ࣮࣒ࢧ
࢖ࢬࡀ᭱ᑠⅬ࡛ࡢᙉᗘ
ศᕸࡢ್༙඲ᖜࡣࠊἼ㛗
100ȝm ࡛ ࡢ ᅇ ᢡ 㝈 ⏺
127ȝm ࡟㏕ࡿ 167ȝm ࡛
࠶ࡿࠋ᭱኱㟁ሙᙉᗘࡀ 10
MV/cm ࢆ㉺࠼ࡿࡇࡢ᮲
ᅗ㸰 ࢼ࢖ࣇ࢚ࢵࢪ࡟ࡼࡿࣅ࣮࣒ࡢ
௳ୗ࡛ࠊTHz ග࡟ᑐࡍࡿ
ࣉࣟࣇ࢓࢖ࣝ ᐃࡢ⤖ᯝ㸦a㸧࡜᭱ᑠ
≀㉁ࡢ㠀⥺ᙧᛂ⟅ࡢᐇ
ࣅ࣮࣒఩⨨࡛ࡢᙉᗘศᕸ㸦b㸧
ࠋᅇᢡ
㦂ࢆヨࡳ࡚࠸ࡿࠋᅗ 3 ࡟
㝈⏺ࡀ 127ȝm ࡜࡞ࡿ᮲௳࡛ࡢ㸦Ἴ㛗
♧ࡍࡼ࠺࡟ࠊ㧗㟁ሙ࡟ࡼ
100ȝm㸧್༙඲ᖜࡣ 167ȝm ࡛࠶ࡗࡓࠋ
ࡿᅛయࡢᨺ㟁⌧㇟ࡸ≀
㉁ࡢ⼥ゎࠊ⵨ᩓ࡞࡝ࡀぢ
ࡽࢀࠊ኱Ẽࡀࣉࣛࢬ࣐໬
ࡍࡿ⌧㇟ࡶほ ࡉࢀࡓࠋ
▷Ἴ㛗࣮ࣞࢨ࣮ࡢ㠀⥺
ᙧຠᯝ࡟ࡼࡿ㧗࢚ࢿࣝࢠ࣮ບ㉳࡜ࡣ␗࡞ࡿࢸࣛ࣊ࣝࢶ㡿ᇦ≉᭷ࡢ㠀⥺ᙧບ㉳⌧㇟ࢆぢฟࡍࡇ࡜ࡀᮇᚅ
ࡉࢀࡿࠋ
ᅗ㸱 㞟ගࡋࡓࢸࣛ࣊ࣝࢶ
FEL ࡟ࡼࡿᨺ㟁ࠊࣉࣛࢬ࣐
໬⌧㇟ࠋ᭱኱㟁ሙᙉᗘࡣ 10
MV/cm ࢆ㉺࠼ࡿ࡜ホ౯ࡉ
ࢀࡿࠋ
― 60 ―
㔞Ꮚࣅ࣮࣒≀㉁⛉Ꮫ◊✲ศ㔝
ᩍᤵ ྂ⃝ Ꮥᘯ
෸ᩍᤵ
ᐊᒇ ⿱బ
ຓᩍ
ᑠᯘ ୍㞝
ຓᩍ
ᒣᮏ ὒ᥹
኱Ꮫ㝔Ꮫ⏕
⸨ᕝ 㯞⏤ࠊᑠᐊ ჆ᓫࠊ㬀ᮏ ኱♸ࠊගᏳ ᑘ㥽ࠊ㄃⏣ ᫂ᏹࠊྜྷ⏣ ဴ㑻
஦ົ⿵బဨ Ώ㑔 ⤱Ꮚ
a) ᴫせ
༙ᑟయ〇㐀࡟࠾ࡅࡿᴟ➃⣸እගࣜࢯࢢࣛࣇ࢕ࠊ⢏Ꮚ⥺࢞ࣥ἞⒪➼ࠊ௒ᚋ㟁㞳ᨺᑕ⥺㡿ᇦ࡟࠶ࡿ㔞Ꮚࣅ
࣮࣒ࡢ฼⏝ࡀ኱ࡁࡃᒎ㛤ࡋ࡚⾜ࡃࡇ࡜ࡀண᝿ࡉࢀࡿࠋ㔞Ꮚࣅ࣮࣒≀㉁⛉Ꮫ◊✲ศ㔝࡛ࡣ᭱ඛ➃ࡢ㔞Ꮚࣅ
࣮࣒㸦㟁Ꮚ⥺ࠊᴟ➃⣸እගࠊ࣮ࣞࢨ࣮ࠊᨺᑕගࠊX ⥺ࠊ࣐࢞ࣥ⥺ࠊ࢖࢜ࣥࣅ࣮࣒㸧ࢆ฼⏝ࡋ࡚ࠊ㔞Ꮚࣅ
࣮࣒ࡀ≀㉁࡟ᘬࡁ㉳ࡇࡍ໬Ꮫ཯ᛂ࡜཯ᛂሙࡢ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋ㔞Ꮚࣅ࣮࣒࡟ࡼࡿ≀㉁࡬ࡢ࢚ࢿࣝࢠ࣮
௜୚࠿ࡽࠊ໬Ꮫ཯ᛂࢆ⤒࡚ࠊᶵ⬟Ⓨ⌧࡟⮳ࡿࡲ࡛ࡢ໬Ꮫ཯ᛂࢩࢫࢸ࣒ࡢゎ᫂ࠊᚓࡽࢀࡓ▱ぢ࠿ࡽ᪂つ໬
Ꮫ཯ᛂࢩࢫࢸ࣒ࡢᵓ⠏ࢆ⾜ࡗ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭㧗 㧗ᅽỈࡢᨺᑕ⥺ㄏ㉳཯ᛂึᮇ㐣⛬ࡢゎ᫂
Ỉࡢᨺᑕ⥺ศゎ཯ᛂ࡟ࡼࡾ▷᫬㛫࡟⏕ᡂࡍࡿ୰㛫άᛶ
✀ࡣࠊᵝࠎ࡞㓟໬㑏ඖ཯ᛂࢆᘬࡁ㉳ࡇࡍࡓࡵࠊࡑࡢᣲືࢆ
ᢕᥱࡍࡿࡇ࡜ࡣཎᏊຊᕤᏛࡸᨺᑕ⥺་Ꮫ࣭⏕≀Ꮫ➼ࠊᨺᑕ
⥺ຠᯝࢆ⪃࠼ࡿୖ࡛୙ྍḞ࡛࠶ࡿࠋᐊ ୗࡢᨺᑕ⥺໬Ꮫ཯
ᛂࡣ㛗ᖺ࡟ࢃࡓࡾ▱ぢࡀ⵳✚ࡉࢀ࡚ࡁࡓࡀࠊ㧗 㧗ᅽ≧ែ
࡟ࡘ࠸࡚ࡣ༑ศ࡛ࡣ࡞࠸ࠋ㧗 㧗ᅽୗ࡛ࡣ໬Ꮫ✀ࡢ཯ᛂᛶ
ࡀቑ኱ࡋ▷ᑑ࿨໬ࡍࡿࡓࡵࠊ㐣Ώⓗ࡞᫬㛫ᣲືࢆ ᐃࡍࡿ
ࡓࡵ࡟ࡣࣆࢥ⛊ศゎ⬟ࡢィ ࢩࢫࢸ࣒ࡀᚲせ࡜࡞ࡿࡀࠊࡇ
ࢀࡲ࡛ᵓ⠏ࡋࡓࣃࣝࢫࣉ࣮ࣟࣈࢩࢫࢸ࣒࡛ࡣከ኱࡞ ᐃ
᫬㛫ࢆせࡍࡿ࡞࡝ᐇ⏝ᛶ࡟ㄢ㢟ࡀ࠶ࡗࡓࠋࡑࡇ࡛㟁Ꮚ࣭ࣞ
ᅗ 1. ᐊ ᮲௳ୗ࡟࠾ࡅࡿỈ࿴㟁Ꮚࡢࣆࢥ⛊㹼ࢼࣀ⛊
஧ḟඖ㐣Ώ྾཰ࢫ࣌ࢡࢺࣝ
࣮ࢨྠᮇࢩࢫࢸ࣒ࡸศග ᐃ⣔ࢆ୍᪂ࡋࠊ᪂ࡓ࡞ࣃࣝࢫࣉ
㹼ࢼࣀ⛊㡿ᇦ࡟࠾ࡅࡿ㐣Ώ྾཰ ᐃࢆ⾜ࡗࡓ㸦ᅗ㸧ࠋࢫ࣌
ࢡࢺࣝ㍈࠾ࡼࡧ᫬㛫㍈ࡢ஧ḟඖ྾ගᗘࡀྲྀᚓྍ⬟࡜࡞ࡗ
ࡓࠋ྾ගᗘࣀ࢖ࢬࡣ0.004 Abs.ࠊ ᐃ᫬㛫ࡣศ࡛ᚓࡽࢀࠊ
ᚑ᮶ࡼࡾࡶᴟࡵ࡚ᐇ⏝ᛶࡢ㧗࠸ࢩࢫࢸ࣒ࡀᵓ⠏࡛ࡁࡓࠋ㧗
㧗ᅽୗࡢỈ࿴㟁Ꮚࡢ᫬㛫ᣲືࢆᅗ࡟♧ࡍࠋ㧗 㧗ᅽୗ
࡟࠾࠸࡚ࡶᚑ᮶ࡼࡾࡶ㧗⢭ᗘୟࡘ㎿㏿࡞ ᐃࡀ⾜࠼ࡿࡇ
࡜ࡀศ࠿ࡗࡓࠋ௒ᚋ⢭ຊⓗ࡞ ᐃࢆᐇ᪋ࡋࠊᩘ್ィ⟬࡟ࡼ
ࡿ཯ᛂࣔࢹࣜࣥࢢ࡜ྜࢃࡏ࡚㧗 㧗ᅽỈࡢ㧗㏿࡞ᨺᑕ⥺
໬Ꮫ཯ᛂᶵᵓࢆ᫂ࡽ࠿࡟࡛ࡁࡿ࡜ᮇᚅࡉࢀࡿࠋ
― 61 ―
H2O
1
Normalized absorbance
࣮ࣟࣈయ⣔ࢆᵓ⠏ࡋࡓࠋᐊ ୗ࡟࠾ࡅࡿỈ࿴㟁Ꮚࡢࣆࢥ⛊
0.8
0.6
Normalized to 1
0.4
21C/25MPa/700nm
200C/25MPa/900nm
380C/30MPa/950nm
400C/40MPa/950nm
420C/40MPa/1000nm
0.2
0
0
500
1000
1500
2000
Time /ps
ᅗ 2. 㧗 㧗ᅽ᮲௳ୗ࡟࠾ࡅࡿỈ࿴㟁Ꮚࡢࣆࢥ⛊㹼ࢼ
ࣀ⛊᫬㛫ᣲື
࣭㌿෗ᅉᏊ 6R[5 ࡢࢫ࣮ࣃ࣮࢜࢟ࢧ࢖ࢻ࢔ࢽ࢜ࣥࡢ཯ᛂᛶࢆᨭ㓄ࡍࡿᅉᏊ
ࣂࢡࢸࣜ࢔ෆ࡟ࡣࠊࢭࣥࢧ࣮㒊఩࡟[2Fe-2S] ࢡࣛࢫࢱ࣮ࢆᣢࡕࠊࡑࡢྍ㏫ⓗ࡞㓟໬㑏ඖ࡟ࡼࡗ࡚ไ
ᚚࡉࢀࡿ㌿෗ᅉᏊ SoxR ࡀᏑᅾࡍࡿࠋSoxR ࡣ✀ࠎࡢࢢ࣒ࣛ㝜ᛶ⳦࡟Ꮡᅾࡍࡿࡀࠊࡑࡢ⏕⌮ⓗᙺ๭ࡣ⳦
✀࡟ࡼࡗ࡚኱ࡁࡃ␗࡞ࡿࠋE. coli ࡛ࡣ㓟໬ࢫࢺࣞࢫ࡟ᛂ⟅ࡋ࡚㌿෗άᛶࢆᣢࡕࠊࢫ࣮ࣃ࣮࢜࢟ࢧ࢖ࢻࢹ
࢕ࢫ࣒ࢱ࣮ࢮ➼ࡢ㓟໬ࢫࢺࣞࢫ㜵ᚚࢱࣥࣃࢡ㉁ࡢⓎ⌧ࢆ
ไᚚࡋ࡚࠸ࡿࠋࡑࢀ࡟ᑐࡋ࡚⥳⮋⳦(P. aeruginosa)࡟࠾࠸
࡚ࣆ࢜ࢩ࢔ࢽࣥ࡟ᛂ⟅ࡋࠊᢠ⏕≀㉁㍺㏦ࢱࣥࣃࢡ㉁ࡸศゎ
㓝⣲ࡢⓎ⌧࡟㛵ࢃࡿ࡜ሗ࿌ࡉࢀ࡚࠸ࡿࠋ୧⪅ࡣ࢔࣑ࣀ㓟㓄
ิࡀ 62% identity ࡜ࡼࡃಖᏑࡉࢀ࡚࠸ࡿࡀࠊ⏕యෆ࡛ࡢ
ᙺ๭ࡣࡇࡢࡼ࠺࡟኱ࡁࡃ␗࡞ࡿࠋᡃࠎࡣࠊࣃࣝࢫࣛࢪ࢜ࣜ
ࢩࢫἲ࡟࡚ࠊO2-࡜ࢭࣥࢧ࣮㒊఩࡛࠶ࡿ[2Fe-2S]ࡢ཯ᛂࡀࠊ
E. coli ࡢ㌿෗ࢫ࢖ࢵࢳ࢜ࣥࡢࢺ࣮ࣜ࢞࡜࡞ࡿࡇ࡜ࢆሗ࿌
ࡋࡓࠋࡑࢀ࡟ᑐࡋ࡚ࠊP.aerugisa SoxR ࡣ E. coli ࡜ẚ㍑ࡋ
୍࡚᱆௨ୖᑠࡉ࠸ࡇ࡜ࡀศ࠿ࡗࡓࠋࡉࡽ࡟ࡇࡢ㐪࠸ࢆ᳨ウ
ࡍࡿࡓࡵ࡟ࠊE. coli ࡜ P.aerugisa ࡜࡛␗࡞ࡿ࢔࣑ࣀ㓟ࢆࡑ
ᅗ 3. E. coli SoxR ࡢ㕲࢖࢜࢘ࢡࣛࢫࢱ࣮㏆ഐࡢᵓ㐀
ࢀࡒࢀᑐᛂࡍࡿ࢔࣑ࣀ㓟࡟⨨᥮ࡋࡓኚ␗యࢆస〇ࡋࠊO2࡜ࡢ཯ᛂ㏿ᗘࢆ᳨ウࡋࡓࠋ[2Fe-2S] ㏆ഐ࡟࠾࠸࡚ E. coli
࡜ P.aerugisa ࡢ୧⪅࡛␗࡞ࡿ࢔࣑ࣀ㓟ṧᇶ࡛࠶ࡿ 89 ␒┠࠾ࡼࡧ 92 ␒┠ࡢࣜࢪࣥṧᇶ࡜࢔ࣝࢠࢽࣥ/
ࢭࣜࣥ/࢔ࢫࣃࣛࢠࣥ㓟(RSD)࣮ࣝࣉࡀ୧⪅࡛␗࡞ࡿ(ᅗ 3)ࠋࡑࡢኚ␗యࢆ⏝࠸ࡓᐇ㦂ࡼࡾࠊ92 ␒┠ࡢࣜ
ࢪࣥṧᇶࡀ O2-ࢆ㓟໬ࡍࡿ㝿ࡢࣉࣟࢺࣥ donar ࡜ࡋ࡚ാ࠸࡚࠸ࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓ㸦ୗᘧ㸧ࠋ
ࢫ࣮࣒࢟ SoxR ࡜ O2-ࡢ཯ᛂ㐣⛬
࣭⮬ᕫ⤌⧊໬ࢸࣥࣉ࣮ࣞࢺ࡟ࡼࡿ㔠ᒓࢼࣀ⢏Ꮚࡢ఩⨨ไᚚ
⌧ᅾࠊࣜࢯࢢࣛࣇ࢕ᢏ⾡ࡣ 30 nm ௨ୗࡢ༙ᑟయ⏘ᴗࢆᨭ࠼ࡿᚤ⣽ຍᕤᢏ⾡࡛౑⏝ࡉࢀ࡚࠸ࡿࠋࡋ࠿ࡋ
࡞ࡀࡽࠊࡇࡢᢏ⾡࡟ࡼࡗ࡚㔞⏘࡛ࣞ࣋ࣝ 10nm ௨ୗࡢࣃࢱ࣮ࣥࢆᙧᡂࡍࡿࡇ࡜ࡣᅔ㞴࡛࠶ࡿࠋࡑࢀࡺ࠼ࠊ
㠉᪂ⓗ࡞ᚤ⣽ຍᕤᢏ⾡ࡢ㛤Ⓨࡀᚲせ୙ྍḞ࡛࠶ࡿࠋ࣏ࣜࢫࢳ࣮࣏࣓ࣥࣜࢱࢡ࣮ࣜࣞࢺࣈࣟࢵࢡඹ㔜ྜయ
㸦PS-co-PMMA)ࡢ┦ศ㞳ࢆ㉳ࡇࡍࡇ࡜ࡀ▱ࡽࢀ࡚࠸ࡿࠋࣈࣟࢵࢡඹ㔜ྜయࡢ⮬ᕫ⤌⧊໬ࢆ฼⏝ࡋ࡚ᚤ⣽
ࣃࢱ࣮ࣥࢆᙧᡂࡋࡓࠋ
AFM ⏬ീࡣ PS-co-PMMA ࡢ⮬ᕫ⤌⧊໬࡟ࡼࡗ࡚ᙧᡂࡉࢀࡓᚤ⣽ࣃࢱ࣮࡛ࣥ࠶ࡿࠋ
ࡑࡢࣃࢱ࣮ࣥࢆࢸࣥࣉ࣮ࣞࢺ࡜ࡋ࡚౑ࡗ࡚ࠊࣜࣇࢺ࢜ࣇἲ࡟ࡼࡗ࡚㔠ࡢᚤ⣽ࣃࢱ࣮ࣥࢆస〇ࡋࡓࠋࡑࡢ
ᚋ ࠊ ࢪ ࢳ ࢜ ࣮ ࣝ ༢ ศ Ꮚ ⭷ 㸦 Self-assembly
monolayer :SAM㸧ࢆᚤ⣽ࣃࢱ࣮ࣥୖ࡟ᙧᡂࡋࠊ
ྜᡂࡋࡓ㔠ࢼࣀ⢏Ꮚࢆ໬Ꮫ⤖ྜࡉࡏࡓࠋSEM
ീࡣࢪࢳ࣮࢜ࣝ SAM ⭷ࡢᚤ⣽ࣃࢱ࣮ࣥୖ࡟㔠
ࢼࣀ⢏Ꮚࢆ୪࡭ࡓࡶࡢ࡛࠶ࡿࠋࡇࡢࡼ࠺࡟ࠊ⮬
ᕫ⤌⧊໬ࢸࣥࣉ࣮ࣞࢺࢆ౑ࡗ࡚㔠ᒓࢼࣀ⢏Ꮚ
ࡢ఩⨨ไᚚ࡟ᡂຌࡋࡓࠋࡇࡢᡭἲ࡛㓄ิไᚚࡉ
ࢀࡓ㔠ᒓࢼࣀ⢏Ꮚࡣࣉࣟࢬࣔࢽࢡࢫࢆࡣࡌࡵࠊ
400 nm
㠉᪂ⓗ࡞ࢹࣂ࢖ࢫ࡬ࡢᛂ⏝ࡀᮇᚅࡉࢀࡿࠋ
― 62 ―
➨ 3 ◊✲㒊㛛㸦⏕య࣭ศᏊ⛉Ꮫ⣔㸧
ᴫせ
ᮏ◊✲㒊㛛ࡣࠊᨵ⤌๓ࡢ⏕యᛂ⟅⛉Ꮫ◊✲㒊㛛࡜ᶵ⬟ศᏊ⛉Ꮫ◊✲㒊㛛ࢆẕయ࡜ࡋࡓ⏕య⛉Ꮫ⣔◊✲
ศ㔝࠾ࡼࡧศᏊ⛉Ꮫ⣔◊✲ศ㔝࠿ࡽ࡞ࡿ◊✲㒊㛛࡛ࠊບ㉳ศᏊ໬Ꮫࠊᶵ⬟≀㉁໬Ꮫࠊ⢭ᐦไᚚ໬Ꮫࠊ་
⸆ရ໬Ꮫࠊ⏕యศᏊ཯ᛂ⛉Ꮫࠊ⏕యศᏊไᚚ⛉Ꮫࠊ⏕యศᏊᶵ⬟⛉Ꮫࡢ㸵◊✲ศ㔝࡛ᵓᡂࡉࢀ࡚࠸ࡿࠋ
⏕య⛉Ꮫ⣔࡟࠾࠸࡚ࡣࠊࡇࢀࡲ࡛ࠊ⺯ග࠾ࡼࡧ໬ᏛⓎගࢱࣥࣃࢡ㉁ࢆ⏝࠸ࡓࣂ࢖࢜ࢭࣥࢧ࣮㛤Ⓨࡸ⏕
యෆࣆ࣏ࣥ࢖ࣥࢺ⸆≀㏦㐩ࢩࢫࢸ࣒ࡢ㛤Ⓨࠊከ๣⪏ᛶᶵᵓࡢゎ᫂࡜᪂つ἞⒪⸆㛤Ⓨ࡞࡝⏕≀࡟࡜ࡗ࡚᭱
ࡶᇶᮏⓗ࡞཯ᛂࡢศᏊᶵᵓࡢゎ᫂࡞ࡽࡧ࡟ࡑࡢ▱ぢࢆά࠿ࡋࡓ⏘ᴗᛂ⏝◊✲ࢆ㐍ࡵ࡚ࡁࡓࠋ୍᪉ࠊศᏊ
⛉Ꮫ⣔࡟࠾࠸࡚ࡣࠊศᏊ໬Ꮫࡢᇶ♏࠿ࡽᛂ⏝࡟ཬࡪከᵝ࡞◊✲ࢆᇶ┙࡜ࡋ࡚ࠊ᭷ᶵ໬Ꮫࠊ≀⌮໬Ꮫࠊゐ
፹໬Ꮫࠊ⾲㠃໬Ꮫࠊࣅ࣮࣒໬Ꮫࠊᮦᩱ໬Ꮫࠊࡉࡽ࡟ࡣ⏕యᶵ⬟ࡢศᏊ໬Ꮫⓗゎ᫂࡞࡝࡟ࡶ◊✲ࢆᒎ㛤ࡋ
࡚ࡁࡓࠋᮏ◊✲㒊㛛࡛ࡣࠊྛ◊✲ศ㔝ࡢ⊂⮬ࡢ◊✲ࢆࡉࡽ࡟῝໬ࡉࡏࡿࡇ࡜ࢆᇶᮏ࡜ࡋࡘࡘࠊ⏕య⛉Ꮫ
࡜ศᏊ⛉Ꮫࡢ᪂ࡓ࡞⼥ྜ◊✲ࡢ๰ᡂࡶ┠ᣦࡋ࡚࠸ࡿࠋ
ᩍ⫱㠃࡛ࡣࠊ⌮Ꮫ◊✲⛉㸦໬Ꮫᑓᨷࠊ⏕≀⛉Ꮫᑓᨷ㸧
ࠊᕤᏛ◊✲⛉㸦ᛂ⏝໬Ꮫᑓᨷࠊᛂ⏝⏕≀ᕤᏛᑓ
ᨷ㸧
ࠊ⸆Ꮫ◊✲⛉㸦ศᏊ⸆⛉Ꮫᑓᨷ㸧
ࠊ࠾ࡼࡧ⏕࿨ᶵ⬟◊✲⛉࠿ࡽ኱Ꮫ㝔Ꮫ⏕ࢆཷࡅධࢀ࡚࠾ࡾࠊᗈ࠸ど
㔝ࢆᣢࡘ◊✲⪅ࡢ⫱ᡂࢆ┠ᣦࡋ࡚࠸ࡿࠋ
― 63 ―
ບ㉳ศᏊ໬Ꮫ◊✲ศ㔝
ᩍᤵ
┿ᔱ ဴᮁ
෸ᩍᤵ
⸨ሯ Ᏺࠊᕝ஭ Ύᙪ
ຓᩍ
ᑠ㜰⏣ ὈᏊ㸦ᖹᡂ 26 ᖺ 5 ᭶ 1 ᪥㹼㸧
≉௵ᩍᤵ ᮡᮏ ᫭
≉௵ຓᩍ ᓲ ṇ໕㸦㹼ᖹᡂ 26 ᖺ 8 ᭶ 31 ᪥㸧
Ꮫ᣺እᅜே≉ู◊✲ဨ
㒯 ᫛⛉
኱Ꮫ㝔Ꮫ⏕
㔠 Ỉ⦕ࠊᙇ 㭉ࠊᯘ ኈຼࠊ㩃 ㉸ࠊ⏣୰ ᩔᚿࠊ2VVDPD(OEDQQDࠊ
㜿㔝 㥴௓ࠊ୰ᑿ ๢ኈࠊ㯮⏣ ⤢㤶ࠊ㔝ᮧ බኴ
◊✲⏕ ࿘ ᶘ
஦ົ⿵బဨ
ᐩỌ ᪩ⱑ
a) ᴫせ
ᮏศ㔝ࡣࠊග࠾ࡼࡧᨺᑕ⥺࡟ࡼࡾㄏ㉳ࡉࢀࡿບ㉳ศᏊ໬Ꮫ࡜ᶵ⬟ศᏊ໬Ꮫࢆᇶ┙࡜ࡋ࡚ࠊࣅ࣮࣒ไᚚ
໬ᏛࡸศᏊ࣭཯ᛂሙไᚚ໬Ꮫࡢᡭἲࢆ⏝࠸ࡓ᪂ࡋ࠸ࠕࣅ࣮࣒ᶵ⬟໬Ꮫࠖࡢ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋࣅ࣮࣒ไ
ᚚ໬Ꮫ࡜ࡣ✵㛫ⓗ࣭᫬㛫ⓗ࡟ไᚚࡋࡓከ✀ከᵝ࡞ࣅ࣮࣒ࡢ」ྜ↷ᑕ࡟ࡼࡗ࡚ࠊồࡵࡿ཯ᛂάᛶ✀࣭୰㛫
యࢆ㏲ḟⓗࠊᒁᡤⓗࠊ㑅ᢥⓗ࡟Ⓨ⏕ࡉࡏࠊ࠿ࡘࡑࢀࡽࡢ࢚ࢿࣝࢠ࣮ࢆไᚚࡍࡿࡇ࡜࡟ࡼࡗ࡚ࠊ཯ᛂࢆไ
ᚚࡍࡿࡇ࡜࡛࠶ࡿࠋࡲࡓࠊ࣐ࣝࢳࣅ࣮࣒ࡢ฼⏝࡟ࡼࡗ࡚ࠊ᪂ࡋ࠸཯ᛂάᛶ✀ࡢⓎ⏕࡜ࠊࡑࢀ࡟ࡼࡿ᪂ࡋ
࠸཯ᛂ࣭ࣉࣟࢭࢫࡸ」ྜ཯ᛂ࡬ࡢᒎ㛤ࡀྍ⬟࡛࠶ࡿࠋศᏊ࣭཯ᛂሙไᚚ໬Ꮫ࡜ࡣࠊศᏊタィࡉࢀࡓ཯ᛂ
ᇶ㉁㸦DNAࠊࢱࣥࣃࢡ㸧
ࠊ㉸ศᏊࠊ࣓ࢰࢫࢥࣆࢵࢡศᏊ࡞࡝ࡢศᏊሙࡸࠊẼయ࣭ᾮయ࣭ᅛయࠊ⾲㠃ࠊⷧ
⭷ࠊᾮᬗ࡞࡝࠿ࡽ࡞ࡿ」ྜ⣔ࠊከᡂศ⣔ࠊᾮయᕼ࢞ࢫࠊᴟప ࡞࡝ࡢ཯ᛂሙࡢ❧యⓗ࣭㟁Ꮚⓗ࣭ᵓ㐀ⓗ࣭
໬Ꮫⓗᛶ㉁ࢆ฼⏝ࡍࡿࡇ࡜࡟ࡼࡗ࡚ࠊ཯ᛂࢆไᚚࡍࡿࡇ࡜࡛࠶ࡿࠋ
ࠕࣅ࣮࣒ᶵ⬟໬Ꮫࠖࡢ┠ᣦࡍ᪉ྥࡣࠊ
㧗ḟඖ཯ᛂไᚚࠊ᪂ྜᡂ໬Ꮫࠊ᪂ᶵ⬟ᛶศᏊ࣭㧗ᶵ⬟ᛶᮦᩱ࡬ࡢᒎ㛤࡛࠶ࡿࠋ
b) ᡂᯝ
࣭࣐ࣝࢳࣅ࣮࣒໬Ꮫ
ᏳᐃศᏊ࡬ࡢ➨㸯ࡢࣅ࣮࣒㸦࣮ࣞࢨ࣮ࣃࣝࢫࡲࡓࡣ㟁Ꮚ⥺ࣃࣝࢫ㸧↷ᑕ࡟ࡼࡗ࡚⏕ᡂࡉࡏࡓ▷ᑑ࿨ά
ᛶ✀ࢆฟⓎศᏊ࡜ࡋࠊࡇࢀࡢ྾཰࡟ྜࢃࡏࡓἼ㛗ࡢ➨㸰ࡢ࣮ࣞࢨ࣮ࣃࣝࢫࢆ↷ᑕࡍࡿࡇ࡜࡟ࡼࡿ࣐ࣝࢳ
ࣅ࣮࣒໬Ꮫࢆᒎ㛤ࡍࡿࡇ࡜࡛ࠊࢃࢀࢃࢀࡣ✀ࠎࡢ཯ᛂ୰㛫య࣭▷ᑑ࿨άᛶ✀ࢆཎᩱ࡜ࡍࡿග໬Ꮫࠊ▷ᑑ
࿨άᛶ✀ࡢගບ㉳≧ែࡸ㧗ບ㉳≧ែࡢືⓗᣲືࡢゎ᫂ࢆ⾜ࡗ࡚ࡁࡓࠋ௒ᖺᗘࡣࠊ໬Ꮫ㑏ඖ࡟ࡼࡾ⏕ࡌࡓ
࢖࣑ࢻ㢮ࡢࣛࢪ࢝ࣝ࢔ࢽ࢜ࣥࢆࣇ࢙࣒ࢺ⛊ࣃࣝࢫ࣮ࣞࢨ࣮ບ㉳ࡍࡿࡇ࡜࡛ࠊບ㉳ࣛࢪ࢝ࣝ࢔ࢽ࢜ࣥ࠿ࡽ
ࡢ㟁Ꮚ⛣ື㐣⛬ࢆ᫂ࡽ࠿࡟ࡋࡓࠋ࡜ࡃ࡟ࢼࣇࢱࣝࢪ࢖࣑ࢻࡢບ㉳ࣛࢪ࢝ࣝ࢔ࢽ࢜ࣥ࡟ࡘ࠸࡚ヲ⣽࡟᳨ウ
ࡍࡿࡇ࡜࡛㟁Ꮚ⛣ືࡢ㊥㞳౫Ꮡᛶ࠾ࡼࡧ⮬⏤࢚ࢿࣝࢠ࣮౫Ꮡᛶࢆ᫂ࡽ࠿࡟ࡍࡿࡇ࡜࡟ᡂຌࡋࡓࠋࢃࢀࢃ
ࢀࡢࢢ࣮ࣝࣉ࡛ࡣࠊࣃࣝࢫࣛࢪ࢜ࣜࢩࢫ࡛⏕ࡌࡓࣛࢪ࢝ࣝ࢖࢜ࣥ✀࡟ࣃࣝࢫ࣮ࣞࢨ࣮↷ᑕࡍࡿࡇ࡜࡛᫬
㛫ศゎඹ㬆࣐ࣛࣥ ᐃࢆᐇ⌧ࡋ࡚࠸ࡿࡀࠊᮏᖺᗘࡣᮏᡭἲࢆࢫࢳࣝ࣋ࣥㄏᑟయࡢࣛࢪ࢝ࣝ࢖࢜ࣥ࡟㐺⏝
ࡍࡿࡇ࡜࡛ࠊࣛࢪ࢝ࣝ࢖࢜ࣥ✀ᙧᡂ࡟క࠺ᵓ㐀ኚ໬ࢆ᫂ࡽ࠿࡟ࡋࡓࠋ≉࡟ࣛࢪ࢝ࣝ࢖࢜ࣥ✀⏕ᡂ᫬ࡢ࢚
ࢳࣞࣥ⤖ྜࡢ⤖ྜḟᩘࡢኚ໬ࡢ⨨᥮ᇶ౫Ꮡᛶࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
࣭⺯ගศᏊࡢ⁐፹᥋ゐ⾲㠃✚࡟ᇶ࡙ࡃ WULSOHWEOLQNLQJ
⺯ගศᏊບ㉳୕㔜㡯≧ែ࡜㓟⣲ࡢ཯ᛂ㏿ᗘࡀࠊ⺯ගศᏊࡢ⁐፹᥋ゐ⾲㠃✚࡟ᛂࡌ࡚ኚ໬ࡍࡿࡇ࡜࡟╔
┠ࡋࠊ⺯ගศᏊࡢ⁐፹᥋ゐ⾲㠃✚ࡢኚ໬ࢆࠊບ㉳୕㔜㡯ࡢ⏕ᡂῶ⾶࡟⏤᮶ࡍࡿ blinking ࡟ࡼࡾほ ࡍࡿ
ࡇ࡜ࢆ᳨ウࡋࡓࠋ࢔࣑ࣀ࣮ࣜࣥ࢝ࢆ௓ࡋ࡚⺯ගศᏊࢆ DNA ࡟ᑟධࡍࡿࡇ࡜࡟ࡼࡾࠊ⺯ගศᏊࡀ஧ᮏ㙐
ᵓ㐀୰࡛ࡣ DNA ෆ࡟࢖ࣥࢱ࣮࣮࢝ࣞࢺࡋ⁐፹࠿ࡽ㐽ⶸࡉࢀࡿࡢ࡟ᑐࡋࠊ࣊࢔ࣆࣥ㒊఩࡛ࡣ⁐፹࡟㟢ฟ
ࡉࢀࡿࡼ࠺タィࡋࡓࠋ⺯ගศᏊ࡜ࡋ࡚ Rhodamine 6G㸦R6G㸧ࢆಟ㣭ࡋࡓ DNA ࢆྜᡂࡋࠊ୍ศᏊࣞ࣋ࣝ
― 64 ―
⺯ගほ ࡜ࡋ࡚⺯ග┦㛵ศගἲ㸦FCS㸧ࢆ⏝࠸࡚ࠊບ㉳୕㔜㡯ࡢ⏕ᡂ࣭ῶ⾶࡟⏤᮶ࡍࡿ blinking ࢆほ ࡋࡓࠋ⺯ගࡀᾘ࠼࡚࠸ࡿ᫬㛫㸦off time: IJoff㸧࠿ࡽບ㉳୕㔜㡯ࡢᑑ࿨ࢆ ᐃࡋࡓ࡜ࡇࢁࠊ࣊࢔ࣆࣥ㒊఩࡟
R6G ࢆᑟධࡋࡓሙྜ࡜ẚ㍑ࡋ࡚ࠊ஧ᮏ㙐ᵓ㐀୰࡛ࡣࠊ⁐፹᥋ゐ⾲㠃✚ࡢపୗ࡟క࠸ IJoff ࡀ㛗ࡃ࡞ࡿࡇ࡜
ࡀ♧ࡉࢀࡓࠋࡇࢀ࡟ࡼࡾࠊບ㉳୕㔜㡯ࡢ⏕ᡂ࣭ῶ⾶࡟⏤᮶ࡍࡿ blinking ࡢほ ࡟ࡼࡾࠊ⺯ගศᏊ࿘㎶ࡢ
⁐፹᥋ゐ⾲㠃✚ࡢኚ໬ࢆㄞࡳฟࡏࡿࡇ࡜ࡀ♧ࡉࢀࡓࠋ
࣭ග࡜≀㉁ࡢ┦஫స⏝࡟ࡼࡿᮦᩱ࣭⏕≀ศ㔝࡬ࡢᛂ⏝
ගᶵ⬟ᛶศᏊࡸᮦᩱࡣࠊᕤᏛࡸ⏕≀Ꮫศ㔝࡞࡝࡛ᵝࠎ࡞ᛂ⏝ࡀᮇᚅࡉࢀ࡚࠸࡚ࠊග໬Ꮫ཯ᛂࡀᇶ┙࡜
࡞ࡗ࡚࠸ࡿࠋ౛࠼ࡤࠊගㄏ㉳㟁Ꮚ⛣ື཯ᛂࡸບ㉳࢚ࢿࣝࢠ࣮⛣ື཯ᛂ࡞࡝ࢆ⏝࠸ࠊᚲせ࡞ᶵ⬟ࢆ᭷ࡍࡿ
ศᏊࡸࢼࣀᮦᩱࡢタィ࣭ྜᡂࢆ⾜࠸ࠊᮦᩱ๰ᡂࠊ⏕≀࢖࣓࣮ࢪࣥࢢࡸᶵ⬟ไᚚ࡞࡝ᵝࠎ࡞ศ㔝࡟฼⏝࡛
ࡁࡿࠋࡑࡇ࡛ࠊග໬Ꮫ཯ᛂ࡟ࡼࡾ᪂つගᶵ⬟ᛶᮦᩱࢆタィ࣭ྜᡂࡋࠊࡑࢀࢆ฼⏝ࡋࡓ⏕≀࢖࣓࣮ࢪࣥࢢ
ᡭἲࡸග᧯సἲࠊ᪂ࡋ࠸࢚ࢿࣝࢠ࣮ኚ᥮ᮦᩱࠊ⚄⤒ᶵ⬟ࢆྍど໬࣭ไᚚ࡛ࡁࡿᡭἲ࡞࡝ࡢ㛤Ⓨࢆ⾜ࡗ࡚
࠸ࡿࠋ
࣭ග⥺ຊᏛⓗ⒪ἲ3'7࡟࠾࠸࡚⣽⬊ෆ࡟Ⓨ⏕ࡍࡿ୍㔜㡯㓟⣲ࡢ⺯ගࣉ࣮ࣟࣈ
3'7 ࡟࠾࠸࡚ࠊග↷ᑕ࡟ࡼࡾ 2 ࡀⓎ⏕ࡋࠊࡑࡢ཯ᛂ࡟ࡼࡾ⣽⬊ẘᛶࡀⓎ⌧ࡍࡿ࡜⪃࠼ࡽࢀ࡚࠸ࡿࠋᐇ
㝿ࡢ་⒪⌧ሙ࡛ࡶࠊ2 ࡢⓎ⏕࡜ኚ໬ࢆᐇ᫬㛫ほᐹࡍࡿࡇ࡜ࡣ㠀ᖖ࡟㔜せ࡛࠶ࡿࠋࡇࢀࡲ࡛ 2 ࢆ㧗ឤᗘ
࡟᳨ฟࡍࡿ⡆౽࡞᪉ἲࡀ࡞ࡃࠊ⣽⬊ෆ࡟ᐜ᫆࡟ᑟධࡉࢀࠊ⣽⬊ෆ 2 ࢆຠ⋡ࡼࡃ᳨ฟࡍࡿ᪂ࡓ࡞⺯ගࣉ
࣮ࣟࣈ㛤Ⓨࡀᚲせ୙ྍḞ࡛࠶ࡗࡓࠋࡑࡇ࡛ᡃࠎࡣࠊࡇࡢࡼ࠺࡞᮲௳ࢆഛ࠼ࠊගቑឤ๣࠿ࡽⓎ⏕ࡍࡿ 2
ࢆሙᡤ㑅ᢥⓗ࡟᳨ฟྍ⬟࡞㉥Ⰽ⺯ගࣉ࣮ࣟࣈ Si-DMA㸦ࢣ࢖⣲ࢆྵࡴ Rhodamine ࡜࢔ࣥࢺࣛࢭࣥᇶࡀ㐃
⤖ࡋࡓศᏊ㸧ࡢ㛤Ⓨ࡟ᡂຌࡋࡓࠋࡇࡢࡼ࠺࡞ࠊ⣽⬊ෆ 2 ࢆ᳨ฟ࡛ࡁࠊ⣽⬊ෆ࡛ගቑឤ๣࡜ࡢ㧗࠸ሙᡤ
㑅ᢥᛶࢆᣢࡗ࡚࠸ࡿ⺯ගࣉ࣮ࣟࣈࡣࠊୡ⏺᭱ึࡢ౛࡛࠶ࡿࠋ
― 65 ―
ᶵ⬟≀㉁໬Ꮫ◊✲ศ㔝
ᩍᤵ
≉௵ᩍᤵ
෸ᩍᤵ
ຓᩍ
༤ኈ◊✲ဨ
኱Ꮫ㝔Ꮫ⏕
◊✲⏕
ᢏ⾡⿵బဨ
஦ົ⿵బဨ
➲஭ ᏹ᫂
໭ Ὀ⾜
⃝ ᚸ
ᕷཎ ₶Ꮚࠊ➉୰ ࿴ᾈ
Mohanta Suman ChandraࠊPriyabrata Das㸦㹼ᖹᡂ 26 ᖺ 12 ᭶ 31 ᪥㸧
ࠊᖹ⏣ ಟ୍ࠊ
Lulu Fan㸦㹼ᖹᡂ 26 ᖺ 5 ᭶ 30 ᪥㸧ࠊ㧗㇂ ಟᖹ㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥㹼㸧
Tue Minh-Nhat Nguyen㸦㹼ᖹᡂ 26 ᖺ 9 ᭶ 30 ᪥㸧
ࠊᯘ ㈼௒ࠊIsmiyartoࠊ
Arteaga Arteaga Fernando㸦㹼ᖹᡂ 26 ᖺ 9 ᭶ 30 ᪥㸧
ࠊྜྷ⏣ Ὀᚿࠊ⬥⏣ ࿴ᙪࠊ
Mohamed Ahmed Abozeidࠊబྂ ┿ࠊ㔜ಙ ໷ᚿࠊᮾ ༓ᑜࠊᓊ 㕲㤿ࠊṊෆ ⰾᶞࠊ
ᆏ஭ ᬛᘯࠊ⃝⏣ ࿴ᘺࠊ⸨⏣ ࿴ஓࠊDaniel Hack㸦㹼ᖹᡂ 27 ᖺ 5 ᭶ 11 ᪥㸧ࠊ
Steffen Madar㸦ᖹᡂ 27 ᖺ 3 ᭶ 5 ᪥㹼㸧
Benqiang Cui㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥㹼㸧ࠊBijan Mohon Chaki㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥㹼㸧
ࠊ
Moaz Mohamed Mohamed Abdou㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥㹼㸧ࠊ
Taslima Aktar㸦ᖹᡂ 26 ᖺ 11 ᭶ 1 ᪥㹼㸧
ᅵ஭ ㈗⿱
ᮏከ ⥤㤶
a) ᴫせ
୙ᩧゐ፹ࡣࠊᴟᚤ㔞ࡢ౑⏝࡟ࡼࡾ་⸆ရཎᩱ࡞࡝ࡢ᭷⏝࡞ගᏛάᛶ໬ྜ≀ࢆ኱㔞࡟౪⤥࡛ࡁࡿࠋ㝈ࡾ
࠶ࡿ㈨※ࢆ᭷ຠ࠿ࡘ᭱኱㝈࡟ά࠿ࡋࠊ⎔ቃởᰁ≀㉁ࡢ᤼ฟࢆᢚไࡍࡿࡓࡵ࡟ࡣࠊᐇ⏝ⓗ࡞㧗άᛶ୙ᩧゐ
፹ࡢ㛤Ⓨࡀ᭱㔜せㄢ㢟ࡢ 1 ࡘ࡜࡞ࡗ࡚࠸ࡿࠋᙜ◊✲ศ㔝࡛ࡣࠊ᪂ࡋ࠸ゐ፹ⓗ୙ᩧྜᡂἲࡢ㛤Ⓨ࡜ࡑࡢ཯
ᛂ࣓࢝ࢽࢬ࣒ࡢゎ᫂࡟✚ᴟⓗ࡟ྲྀࡾ⤌ࡳࠊ㓝⣲ⓗ࡞స⏝ᶵᗎ࡛ാࡃከᶵ⬟࡞୙ᩧゐ፹ࡢ㛤Ⓨ࡟ᡂຌࡋ࡚
࠸ࡿࠋ᪤Ꮡゐ፹ࡢ༢⣧࡞୙ᩧ໬࡜ࡣ␗࡞ࡿ᪂ࡋ࠸άᛶ໬ᶵᵓࢆᇶ┙࡜ࡍࡿ᪂つ཯ᛂࡢ㛤ᣅⓗ◊✲࡛࠶ࡿࠋ
⌧ᅾࠊࡇࢀࡽከᶵ⬟୙ᩧゐ፹ࡢᅛᐃ໬ࠊᙉᅛ࡞㦵᱁࡟ᇶ࡙ࡃຠᯝⓗ୙ᩧ⎔ቃࢆ᭷ࡍࡿ᪂つගᏛάᛶ㓄఩
Ꮚ࡞ࡽࡧ࡟᭷ᶵศᏊゐ፹ࡢタィ࣭๰ฟࢆ㔜Ⅼⓗ࡟᥎㐍ࡋ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭ࣃࣛࢪ࣒࢘ゐ፹ࢆ⏝࠸ࡿࢫࣆࣟ[4.4]ࣀࢼࣀࣥ㢮ࡢ࢚ࢼࣥࢳ࢜㑅ᢥⓗྜᡂ࡜᭷ᶵศᏊゐ፹࡬ࡢᒎ㛤
ᙜ◊✲ᐊ࡛ࡣ࢟ࣛࣝ࡞ࢫࣆࣟ㦵᱁ࢆ᭷ࡍࡿ㑄⛣㔠ᒓ㓄఩Ꮚࠊ᭷ᶵศᏊゐ፹ࠊ࢖࢜ࣥᛶᾮయࢆ㛤Ⓨࡋࠊ
୙ᩧ཯ᛂ࡬ࡢᛂ⏝ࢆᒎ㛤ࡋ࡚࠸ࡿࠋࡋ࠿ࡋ࡞ࡀࡽࠊගᏛⓗ࡟⣧⢋࡞ࢫࣆࣟ໬ྜ≀ࢆᚓࡿࡓࡵ࡟ࡣࠊከࡃ
ࡢሙྜ࡟࠾࠸࡚↹ࢃࡋ࠸ගᏛศ๭సᴗࡀᚲせ࡛࠶ࡗࡓࠋᮏၥ㢟ࢆඞ᭹ࡍࡿࡓࡵࠊ௒ᅇࠊ⎔≧ࢣࢺࣥ 1 ࡢ
࢚ࢼࣥࢳ࢜㑅ᢥⓗศᏊෆȘ఩࢔࣮ࣜࣝ໬཯ᛂ࡟ࡼࡿࢫࣆࣟ[4.4]ࣀࢼࣀࣥ㢮 2 ࡢຠ⋡ྜᡂࢆヨࡳࡓ㸦ᅗ 1㸧ࠋ
᳨ウࡢ⤖ᯝࠊ5 mol %ࡢ㓑㓟ࣃࣛࢪ࣒࢘࡜ 7.5 mol %ࡢ(S,Rp)-Josiphos 㓄఩Ꮚࢆ⏝࠸ࡿ࡜ࠊᐃ㔞ⓗ࠿ࡘ 83%
ee ࡛┠ⓗࢫࣆࣟ໬ྜ≀ 2 ࡀᚓࡽࢀࡿࡇ࡜ࢆぢฟࡋࡓࠋ⏕ᡂ≀ࡢ⤯ᑐ㓄⨨ࡣࠊ༢⤖ᬗ X ⥺ᵓ㐀ゎᯒ࡟ࡼࡾ
S య࡛࠶ࡿࡇ࡜ࢆ☜ㄆࡋࡓࠋࡉࡽ࡟ࠊᚓࡽࢀࡓࢫࣆࣟ[4.4]ࣀࢼࣀࣥ 2a㸦R = Me㸧ࢆ㓟㸫ሷᇶᆺ᭷ᶵศᏊ
ゐ፹ 3 ࡬࡜ኚ᥮ࡋࠊ࣓ࢳࣝࣅࢽࣝࢣࢺࣥ࡜࢔ࣝࢪ࣑ࣥ࡜ࡢ࢚ࢼࣥࢳ࢜㑅ᢥⓗ aza-᳃⏣–Baylis–Hillman ཯
ᛂ࡛ࡢάᛶ
ホ౯ࢆ㏻ࡋ
࡚ࠊᮏ᪂つ࢟
ࣛࣝࢫࣆࣟ
㦵᱁ࡢ᭷⏝
ᛶࢆ᫂ࡽ࠿
࡟ࡋࡓࠋ
ᅗ 1 ࣃࣛࢪ࣒࢘ゐ፹ࢆ⏝࠸ࡿࢫࣆࣟ[4.4]ࣀࢼࣀࣥ㢮ࡢ࢚ࢼࣥࢳ࢜㑅ᢥⓗྜᡂ࡜ᛂ⏝
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࣭ࣃࣛࢪ࣒࢚࢘ࣀ࣮ࣛࢺ✀ࡢᴟᛶ㌿᥮ࢆά⏝ࡍࡿከᐁ⬟ᛶ໬ྜ≀ࡢຠ⋡ྜᡂ
࢚ࣀ࣮ࣝࡢඹᙺሷᇶ࡛࠶ࡿ࢚ࣀ࣮ࣛࢺࡣࠊ᭷⏝࡞ồ᰾๣࡜ࡋ࡚᭷ᶵྜᡂ໬Ꮫ࡟࠾࠸࡚ᗈࡃ฼⏝ࡉࢀ࡚
࠸ࡿࠋࡑࡢᑐ࢝ࢳ࢜ࣥ࡟㑄⛣㔠ᒓ࡛࠶ࡿࣃࣛࢪ࣒࢘ࢆᣢࡘࡶࡢࡣࣃࣛࢪ࣒࢚࢘ࣀ࣮ࣛࢺ㸦Pd ࢚ࣀ࣮ࣛࢺ㸧
࡜࿧ࡤࢀࠊ඾ᆺඖ⣲ࢆ᭷ࡍࡿ࢚ࣀ࣮ࣛࢺ࡛ࡣᐇ⌧ᅔ㞴࡞ኚ᥮ࢆྍ⬟࡟ࡍࡿࠋࡋ࠿ࡋ࡞ࡀࡽࠊ௒ࡲ࡛ሗ࿌
ࡉࢀࡓ࡝ࡢ཯ᛂ࡟࠾࠸࡚ࡶࠊPd ࢚ࣀ࣮ࣛࢺࡣ௚ࡢ࢚ࣀ࣮ࣛࢺ✀࡜ྠᵝ࡟࢔ࣝࢹࣄࢻࡸ࢚ࣀࣥࡢࡼ࠺࡞ồ
㟁Ꮚ๣࡜ࡋ࠿཯ᛂࡋ࡚࠸࡞࠸ࠋࡑࡢࡓࡵࠊ࢚ࣀ࣮ࣛࢺ࡟ᑐࡋ࡚ồ᰾๣ࢆ཯ᛂࡉࡏࡽࢀࢀࡤࠊ࢝ࣝ࣎ࢽࣝ
໬ྜ≀ࡢྜᡂ࡟ከᵝ໬ࢆࡶࡓࡽࡍ࡜ᮇᚅࡉࢀ࡚࠸ࡿࠋ
ᙜ◊✲ᐊ࡛ࡣࠊ᭱㏆ࠊࢫࣆࣟࣅࢫ࢖ࢯ࢜࢟ࢧࢰࣜࣥ㓄఩Ꮚ SPRIX ࡢ≉ᚩⓗ࡞཯ᛂಁ㐍ຠᯝࢆά࠿ࡋࠊ
⣔୰࡛⏕ࡌࡓ Pd ࢚ࣀ࣮ࣛࢺ࡬ồ᰾✀࡛࠶ࡿ࢔ࢭࢸ࣮ࢺࢆ཯ᛂࡉࡏࡿࠕᴟᛶ㌿᥮཯ᛂࠖࢆୡ⏺࡟ඛ㥑ࡅ
࡚㐩ᡂࡋࡓࠋᮏᖺᗘࡣࠊࡇࡢ Pd ࢚ࣀ࣮ࣛࢺࡢᴟᛶ㌿᥮཯ᛂࡢⓎᒎࢆᅗࡗࡓ⤖ᯝࠊ୍ẁ㝵࡛஧ࡘࡢ␗࡞
ࡿồ᰾✀ࢆ⏕ᡂ≀࡟ᑟධ࡛ࡁࡿ᪂つゐ፹ⓗ⎔໬཯ᛂࡢ㛤Ⓨ࡟ᡂຌࡋࡓࠋࡍ࡞ࢃࡕࠊPd–i-Pr-SPRIX ゐ፹
࡜࢔ࣝ࢟ࢽࣝࢩࢡࣟ࣊࢟ࢧࢪ࢚ࣀࣥᇶ㉁ 4 ࢆࠊሷ໬ࣜࢳ࣒࢘ࡸ⮯໬࣒࢝ࣜ࢘࡞࡝ࡢࣁࣟࢤࣥ໬≀ሷ࡜ඹ
࡟㓟⣲㞺ᅖẼୗ࡟࡚㓑㓟࡜ࢺ࢚ࣝࣥࡢ 3:7 ΰྜ⁐፹୰ 60 °C ࡛᧠ᢾࡋࡓ࡜ࡇࢁࠊࣅࢽࣝ఩࡟ࣁࣟࢤࣀᇶ
ࢆࠊ࢝ࣝ࣎ࢽࣝ Į ఩࡟࢔ࢭࢺ࢟ࢩᇶࢆࡑࢀࡒࢀ᭷ࡍࡿ஧⎔ᘧ⏕ᡂ≀ 5 ࡀ㧗཰⋡࡛ᚓࡽࢀࡿࡇ࡜ࢆぢฟࡋ
ࡓ㸦ᅗ 2㸧
ࠋගᏛⓗ࡟⣧⢋࡞ SPRIX ࢆ
⏝࠸ࡿ࡜࢚ࢼࣥࢳ࢜㑅ᢥᛶࡣ୰⛬ᗘ
࡞ࡀࡽ୙ᩧྜᡂࡶྍ⬟࡛࠶ࡾࠊ⏕ᡂ≀
5 ࡀ᭱㧗 57% ee ࡛ᚓࡽࢀࡓࠋ
ᮏ཯ᛂࡣࠊᇶ㉁ 4 ࡟࠶ࡿ࢔ࣝ࢟ࣥ㒊
఩࡬ࡢࣁࣟࣃࣛࢹ࣮ࢩࣙࣥࢆዎᶵ࡜
ࡋ࡚㐍⾜ࡋࠊࣅࢽࣝ Pd ୰㛫య A ࡢศ
Ꮚෆ࢜ࣞࣇ࢕ࣥᤄධ࡟ࡼࡾ⏕ࡌࡓ Pd
࢚ࣀ࣮ࣛࢺ୰㛫య B ࡟ᑐࡋ࡚࢔ࢭࢸ
࣮ࢺ࢔ࢽ࢜ࣥࡀồ᰾ᨷᧁࡋከᐁ⬟ᛶ
໬ྜ≀ 5 ࢆ୚࠼࡚࠸ࡿ࡜⪃࠼ࡽࢀࡿࠋ
ࡇࡢ㐣⛬࡛㉳ࡁ࡚࠸ࡿ໬Ꮫ㑅ᢥⓗ࡞
ồ᰾ᨷᧁࠊࡘࡲࡾࠊࣁࣟࢤࣥ໬≀࢔ࢽ
࢜ࣥࡢ࢔ࣝ࢟ࣥ࡟ᑐࡍࡿ཯ᛂ࡜࢔ࢭ
ࢸ࣮ࢺ࢔ࢽ࢜ࣥࡢ Pd ࢚ࣀ࣮ࣛࢺ࡟ᑐ
ࡍࡿ཯ᛂ࡟㛵ࡋ࡚ᶵᵓࢆ᫂ࡽ࠿࡟࡛
ࡁࢀࡤࠊPd ࢚ࣀ࣮ࣛࢺࡢᴟᛶ㌿᥮ࡢ
ᅗ 2 Pd ࢚ࣀ࣮ࣛࢺࡢᴟᛶ㌿᥮ࢆά⏝ࡍࡿከᐁ⬟ᛶ໬ྜ≀ࡢຠ⋡ྜᡂ
୍⯡໬࡟⧅ࡀࡿ࡜᥎ᐹࡉࢀࡿࠋ
࣭࢔ࣃࢱ࢖ࢺࢆ⏝࠸ࡓ⎔ቃ࡟ࡸࡉࡋ࠸⢊య㓟໬཯ᛂࢩࢫࢸ࣒
㛤Ⓨࡋࡓ͆⢊య⣔㓟໬཯ᛂ㸦ࣀࣥࣁࣛ࢖ࢺ®㸧
͇ࡣࠊ⎔ቃ࡟ప㈇Ⲵ࡞࢔ࣃࢱ࢖ࢺ⢊య࡟ࠊཎᩱ࢔ࣝࢣࣥ
࡜㐣㓟໬Ỉ⣲ࢆⁱࡳ㎸ࡲࡏࠊ᭷ᶵ⁐፹ࣇ࣮ࣜࡢ⢊య≧ែ࡛཯ᛂࡉࡏ࡚ࠊ࢚࣏࢟ࢩ໬ྜ≀ࢆྜᡂࡍࡿ࡜࠸
࠺㠉᪂ⓗ࡞ྜᡂἲ࡛࠶ࡿࠋ㟁Ꮚᮦᩱ⏝࢚࣏࢟ࢩᶞ⬡ࡢ◊✲㛤Ⓨ࡟ࡣ㧗⣧ᗘࡢࣁࣟࢤࣥࣇ࣮࢚࣏ࣜ࢟ࢩ໬
ྜ≀㸦ከࡃࡣࢢࣜࢩࢪ࢚࣮ࣝࢸࣝᆺ㸧ࡀ௒ᚋᚲせ࡜࡞ࡿࠋࢢࣜࢩࢪ࢚࣮ࣝࢸࣝᆺࡣࠊ㐣㓟໬Ỉ⣲ࢆ⏝࠸
ࡓᾮ┦⣔཯ᛂ࡛ࡣ࢚࣏࢟ࢩ⎔ࡀ
ຍỈศゎࡋࡸࡍࡃࡇࢀࡲ࡛ྜᡂ
ࡀ㞴ࡋ࠿ࡗࡓࡀࠊ⢊య⾲㠃ࡢ≉
Ṧ࡞཯ᛂሙࢆ฼⏝ࡍࡿࣀࣥࣁ
ࣛ࢖ࢺἲࢆ⏝࠸࡚ྜᡂࡍࡿࡇ
࡜ࡀ࡛ࡁࡓ㸦ᅗ 3㸧ࠋ⢊య཯ᛂ
⿦⨨ࢆ㛤Ⓨࡋ࡚ࠊ ࣂࢵࢳ J
ᅗ 3 ࣀࣥࣁࣛ࢖ࢺ®࡟ࡼࡿ࢚࣏࢟ࢩ໬཯ᛂ
ࡢ〇㐀ࡀྍ⬟࡟࡞ࡗࡓࠋ
― 67 ―
⢭ᐦไᚚ໬Ꮫ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
≉௵ຓᩍ
≉௵◊✲ဨ
኱Ꮫ㝔Ꮫ⏕
◊✲⿵ຓဨ
஦ົ⿵బဨ
୰㇂ ࿴ᙪ
ᇽ㔝 ୺⛯
Ṋ஭ ྐᜨࠊᮧ⏣ ளἋᏊ
┦ᕝ ᫓ኵ
ࣦ࢙࣐ࣝ ࣛࢪࣈࠊࢧࣥࢪࣗࢡࢱ ࣒ࢣࣝࢪ࣮ࠊᒣ⏣๛ྐ㸦ᖹᡂ 26 ᖺ 8 ᭶᥇⏝㸧
ᑠ⏣㒊 ᑲᗈࠊ┿႐ᚿ ⤀࿃ࠊὠ⏣ ဴဢࠊᮤ 㔠ᫍࠊᯇᮏ ဏ
ࣀࣝࣁࣖࢸ࢕ ࢧࣂࢽࠊኟཎ ᮃࠊᒸ⏣ Ὀᖾࠊᯇᮏ ᝡ
㐨ᕝ ⁞Ꮚࠊ᳃ ཭⣖ࠊᒣཱྀ 㣁ேࠊ㜰⏣ ᙯ⿱ࠊఀ⸨ ὒᚿ
ᮌᮧ ┿㈗ࠊཎ⏣ ᜤᯞࠊ㡲㈅ ள▮Ꮚ
᳜⏣ ⨾▱㸦ᖹᡂ 26 ᖺ 10 ᭶␗ື㸧
ࠊ▮ཱྀ ⓒྜᏊ㸦ᖹᡂ 26 ᖺ 10 ᭶᥇⏝㸧
a) ᴫせ
ᙜศ㔝࡛ࡣࠊ᭷ᶵྜᡂ໬Ꮫࢆᇶ┙࡜ࡋ࡚ࠊࢣ࣑࢝ࣝࣂ࢖࢜ࣟࢪ࣮࡜ࢼࣀࢸࢡࣀࣟࢪ࣮ࢆᣦྥࡋࡓ◊✲
ࢆ㐍ࡵ࡚࠸ࡿࠋࢣ࣑࢝ࣝࣂ࢖࢜ࣟࢪ࣮࡟㛵ࡋ࡚ࡣࠊ᰾㓟≉␗ᵓ㐀ࡢㄆ㆑࡜㑇ఏᏊⓎ⌧ไᚚ࡟↔Ⅼࢆ⤠ࡾࠊ
1㸧࣑ࢫ࣐ࢵࢳሷᇶᑐ≉␗ⓗ࡞పศᏊ᭷ᶵࣜ࢞ࣥࢻࡢศᏊタィ࡜ࠊ2㸧ศᏊ⏕≀Ꮫⓗᡭἲࢆ⏝࠸ࡓ RNA
࢔ࣉࢱ࣐࣮๰ฟࡢᑐᴟⓗ࡞஧ࡘࡢ᪉ྥ࠿ࡽ࢔ࣉ࣮ࣟࢳࡋ࡚࠸ࡿࠋ୍᪉ࠊCࠊHࠊOࠊNࠊP ࡢྛඖ⣲࠿ࡽ
࡞ࡿ DNA ࡣࠊ㑇ఏᏊ࡜ࡋ࡚㔜せ࡛࠶ࡿࡤ࠿ࡾ࡛࡞ࡃࠊࡽࡏࢇᵓ㐀ࢆ⮬Ⓨⓗ࡟ᙧᡂࡍࡿᴟࡵ࡚≉ᚩⓗ࡞
᭷ᶵ໬ྜ≀࡜ᤊ࠼ࡿࡇ࡜ࡀฟ᮶ࡿࠋࢼࣀࢸࢡࣀࣟࢪ࣮࡟࠾ࡅࡿ⢭ᐦᮦᩱ࡜ࡋ࡚ࡢ㧗ᗘ฼⏝ࢆ㐍ࡵࡿࡓࡵ
࡟ࠊ᰾㓟ࡢ཯ᛂᛶࡸ≀ᛶࡢゎ᫂ࠊ໬Ꮫಟ㣭࡟ࡼࡿ᪂つ≀ᛶࡢ⋓ᚓࢆ┠ᣦࡋ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭࣐࢖ࢡࣟ 51$ ๓㥑య࡟⤖ྜࡍࡿࣜ࢞ࣥࢻࡢࢫࢡ࣮ࣜࢽࣥࢢ
㏆ᖺࠊ࣐࢖ࢡࣟ RNA㸦miRNA㸧ࡣⓎ⏕ࡸศ໬ࠊ
ࡀࢇ࡞࡝ࠊከࡃࡢ⏕࿨⌧㇟࡟㛵ࢃࡗ࡚࠸ࡿࡇ࡜ࡀ
᫂ࡽ࠿࡞ࡾࠊmiRNA ࢆᶆⓗ࡜ࡋࡓ๰⸆ࡢྍ⬟ᛶࡀ
ᮇᚅࡉࢀ࡚࠸ࡿࠋ≉ᐃࡢ miRNA ⏕ᡂ⤒㊰ࢆࢥࣥ
ࢺ࣮ࣟࣝࡍࡿᑠศᏊࡣࠊ⸆ࡢ࣮ࣜࢻ໬ྜ≀ࡸࢶ࣮
ࣝ࡟࡞ࡾ࠺ࡿࠋᡃࠎࡣࠊᙜ◊✲ᐊ࡛㛤Ⓨࡋࡓ⺯ග
ࢹ࢕ࢫࣉࣞ࢖ࢫ࣓ࣥࢺ࢔ࢵࢭ࢖ࢆ኱つᶍ໬ྜ≀ࣛ
࢖ࣈ࣮ࣛࣜࡢࢫࢡ࣮ࣜࢽࣥࢢ࡟ᛂ⏝ࡋ㸪ࢳ࢜࢟ࢧ
ࣥࢺࣥㄏᑟయࢆ⺯ගᣦ♧⸆࡜ࡋ࡚ pre-miRNA ࡟⤖
ྜࡍࡿࣜ࢞ࣥࢻࡢ᥈⣴ࢆ⾜ࡗࡓࠋࡲࡓࠊᚓࡽࢀࡓ
ࣄࢵࢺ໬ྜ≀࡟ᑐࡋ࡚㸰ḟࢫࢡ࣮ࣜࢽࣥࢢ࡜ࡋ࡚
⾲㠃ࣉࣛࢬࣔࣥඹ㬆ࢆ฼⏝ࡋࡓ࢔ࢵࢭ࢖ࢆ⾜ࡗࡓࠋ
ᮏ࢔ࢵࢭ࢖⣔ࢆ☜❧ࡍࡿࡇ࡜࡛ miRNA ࢆᶆⓗ࡜
ࡋࡓ๰⸆࣮ࣜࢻ࡜࡞ࡿ໬ྜ≀ࡢࡼࡾຠ⋡ⓗ࡞᥈⣴
ࡀྍ⬟࡟࡞ࡿ࡜ᮇᚅ࡛ࡁࡿࠋࢫࢡ࣮ࣜࢽࣥࢢ࡟㛵
ࡋ࡚᭱㏆ࠊ8 ఩⨨᥮࢔ࢹࢽࣥㄏᑟయ࠿ࡽ࡞ࡿ࣑ࢽ
ࣛ࢖ࣈ࣮ࣛࣜࡢᵓ⠏࡜ࢫࢡ࣮ࣜࢽࣥࢢࢆ⾜࠸ࠊᢡࢀ᭤ࡀࡾᵓ㐀ࢆ᭷ࡍࡿ 5’-࢔࣑ࣀ࢔ࢹࣀࢩࣥㄏᑟయࡀ
᭱ࡶ㑅ᢥⓗ࡟ pre-miRNA (pre-miR-29a)ࡢᵓ㐀ࢆㄆ㆑ࡍࡿࡇ࡜ࢆ♧ࡋࡓ[ㄽ
ㄽᩥ㸱]ࠋࢫࢡ࣮ࣜࢽࣥࢢࡣࠊRNA
ࡢண ᵓ㐀ࢆᇶ࡟ࡍࡿศᏊࢹࢨ࢖ࣥ࡜ࡣ␗࡞ࡿ࢔ࣉ࣮ࣟࢳ࡛ RNAíᑠศᏊࡢ⤌ࡳྜࢃࡏࢆ᥈⣴ࡍࡿࡶࡢ
࡛࠶ࡿࠋ
― 68 ―
࣭51$ ⤖ྜᛶࣜ࢞ࣥࢻࢆ⏝࠸ࡓ 51$ 㧗ḟᵓ㐀࣭ᶵ⬟ࡢไᚚ
ᡃࠎࡣࡇࢀࡲ࡛࡟ࠊDNA ࡢ≉␗ᵓ㐀ࢆㄆ㆑ࡋ࡚⤖ྜࡍࡿࣜ࢞ࣥࢻࡢ㛤Ⓨࢆ⾜ࡗ࡚ࡁࡓࠋ⌧ᅾࠊDNAࣜ࢞ࣥࢻࡢ┦஫స⏝࡟ࡘ࠸࡚ࡢ▱ぢࢆࡶ࡜࡟ࠊRNA ࡢ≉␗ᵓ㐀࡟⤖ྜࡍࡿࣜ࢞ࣥࢻࡢタィ࣭ྜᡂࢆ⾜ࡗ
࡚࠸ࡿࠋ࡞࠿࡛ࡶ㸪4 ࡘࡢࢼࣇࢳࣜࢪࣥࣘࢽࢵࢺࢆ࣓ࢳ࣮࡛ࣞࣥࣜࣥ࢝ࡘ࡞࠸ࡔ NCTn (Naphthyridine
Carbamate Tetramer)ࡀࠊRNA ୰࡟Ꮡᅾࡍࡿ CGG/CGG 㓄ิࢆ≉␗ⓗ࡟ㄆ㆑ࡋࠊRNA ࡟㧗ḟᵓ㐀ࢆㄏ㉳࡛
ࡁࡿࡇ࡜ࡀศ࠿ࡗࡓࠋ
NCTn ㄏᑟయࡢࡦ࡜ࡘ࡛࠶ࡿ NCT6 ࡣࠊ࣊࢔ࣆࣥ RNA ࡢ࣮ࣝࣉ㒊ศ࡟⤌ࡳ㎸ࡲࢀࡓ(CGG)3 㓄ิ࡟⤖
ྜࡋࠊ㸰ࡘࡢ࣊࢔ࣆࣥ RNA ࢆ㐃⤖ࡉࡏࡿࡇ࡜ࡀศ࠿ࡗࡓ[ㄽ
ㄽᩥ㸯]ࠋ⺯ගᶆ㆑ࡋࡓ㸰✀㢮ࡢ࣊࢔ࣆࣥ RNA
ࢆ⏝࠸࡚ NCT6 ࡢ㠀Ꮡᅾୗ㸭Ꮡᅾୗ࡛ FRET ࢆほ ࡋࡓ࡜ࡇࢁࠊNCT6 ࡢ⃰ᗘ౫Ꮡⓗ࡟ FRET ຠ⋡ࡀኚ
໬ࡋࡓࠊࡍ࡞ࢃࡕࠊ2 ศᏊࡢ RNA ࡢ㏆᥋ࡀ☜ㄆࡉࢀࡓࠋ࣮ࣝࣉ㛫┦஫స⏝ࡣࠊከࡃࡢ」㞧࡞ RNA㸱ḟ
ᵓ㐀࡟ぢࡽࢀࠊRNA ᵓ㐀ࢆᵓ⠏ࡍࡿୖ࡛㔜せ࡞┦஫స⏝࡛࠶ࡿࠋ࣮ࣝࣉ㛫┦஫స⏝ࢆㄏ㉳ࡍࡿࡼ࠺࡞ᑠ
ศᏊ໬ྜ≀ࡣࠊRNA ࡢᵓ㐀࡜ᶵ⬟ࢆไᚚࡍࡿࢶ࣮ࣝ࡟࡞ࡾ࠺ࡿࠋ
࣭୧ぶ፹ᛶ '1$ ࡜⬡㉁஧㔜⭷ࡢ⤖ྜไᚚ
DNA ࡣ㑇ఏࢆࡘ࠿ࡉ࡝ࡿ⏕య㧗ศᏊ࡛࠶ࡾࠊࡲࡓ㧗࠸ศᏊㄆ㆑⬟ࢆࡶࡘ㧗ᶵ⬟ᛶศᏊ࡛࠶ࡿࠋᡃࠎ
ࡣ DNA ࢆ⏝࠸ࡓ⬡㉁஧㔜⭷ࡢಟ㣭ࡸᨵኚࢆᣦྥࡋ࡚ࠊ⬡㉁⭷ୖ࡛ DNA ࡢ≉ᛶࢆⓎ᥹ࡍࡿࡇ࡜ࡢ࡛ࡁࡿ
୧ぶ፹ᛶ DNA ࡢ㛤Ⓨࢆ⾜ࡗ࡚ࡁࡓࠋ㈇㟁ⲴࢆࡶࡕぶỈᛶࡢ㧗࠸ࣜࣥ㓟ࢪ࢚ࢫࢸࣝࢆ␯Ỉᛶࡢ㧗࠸ࢻࢹ
ࢩࣝࣜࣥ㓟ࢺ࢚ࣜࢫࢸࣝ࡟⨨ࡁ᥮࠼ࡓ୧ぶ፹ᛶ DNA㸦dod-DNA㸧ࡣࠊ⬡㉁஧㔜⭷࡟ぶ࿴ᛶࢆ♧ࡍࠋ␯
Ỉᛶಟ㣭ࡢᑟධᩘ࡜఩⨨ࡢ␗࡞ࡿ✀ࠎࡢ dod-DNA ࢆྜᡂࡋࠊ⬡㉁஧㔜⭷࡜ࡢ⤖ྜࢆ SPR ゎᯒ࡟ࡼࡾホ
౯ࢆ⾜ࡗࡓࠋ
dod-DNA ࡜⬡㉁஧㔜⭷ࡢ⤖ྜࡣࠊdod-DNA 㙐ෆ࡟ᑟධࡋࡓ␯Ỉᛶಟ㣭ࡢᩘࠊ఩⨨࡟ᙉࡃ౫Ꮡࡍࡿࠋ
࡞࠿࡛ࡶࠊDNA 㙐ࡢ୧ᮎ➃࡟」ᩘࡢ␯Ỉᛶಟ㣭ࢆᑟධࡋࡓ dod-DNA ࡣࠊ⬡㉁஧㔜⭷࡟ᑐࡍࡿ㠀ᖖ࡟㐜
࠸ゎ㞳㏿ᗘࢆ♧ࡋࠊ⬡㉁஧㔜⭷࡜ᙉᅛ࡟⤖ྜࡍࡿࡇ࡜ࡀ᫂ࡽ࠿࡟࡞ࡗࡓࠋ⬡㉁஧㔜⭷࡟ᙉࡃ⤖ྜࡋࡓ
dod-DNA ࡣࠊ┦⿵㙐࡜ࡢ஧ᮏ㙐ᙧᡂࢆ௓ࡋ࡚ࠊᵝࠎ࡞ᶵ⬟ᛶศᏊࡢ⬡㉁஧㔜⭷ୖ࡬ࡢ㓄⨨ࡸࠊDNA ࢼ
ࣀᵓ㐀ᵓ⠏ࡢ㊊ሙ࡜ࡋ࡚ᶵ⬟ࡋࠊ⬡㉁஧㔜⭷ࢆ DNA ࢆ⏝࠸࡚ಟ㣭ࡍࡿศᏊࢶ࣮ࣝ࡜ࡋ࡚㠀ᖖ࡟᭷⏝࡛
࠶ࡿ[ㄽᩥ㸰]ࠋ
― 69 ―
་⸆ရ໬Ꮫ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
≉௵෸ᩍᤵ
኱Ꮫ㝔Ꮫ⏕
≉ู◊✲Ꮫ⏕
◊✲⏕
ᢏ⾡⿵బဨ
஦ົ⿵బဨ
ຍ⸨ ಟ㞝
࿴⏣ ὒ
᪂⏣ Ꮧࠊᒣཱྀ ಇ㑻ࠊᵽཱྀ 㞝௓
㛤ⓐ 㑥ᏹ
⡿ᒣ ᚭࠊ஭ୖ 㞝ኴࠊ㧗ᮌ ㈼ྖࠊ⚟ᒸ Ᏹ⣫
Yesil, Fatma㸦ࠥᖹᡂ 26 ᖺ 8 ᭶ 31 ᪥㸧
㡑 ⋹㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥ࠥ㸧ࠊ⋤ ซ㸦ᖹᡂ 26 ᖺ 11 ᭶ 1 ᪥ࠥ㸧
ྂ⃝ ⚽᫂ࠊ➉୰ ⥤ࠊኴ⏣ ᮍኸࠊᒣᒸ ࣐࢟㸦ᖹᡂ 26 ᖺ 8 ᭶ 16 ᪥㹼㸧
ࠊ
ఀ⸨ ୙஧㞝㸦㹼ᖹᡂ 26 ᖺ 6 ᭶ 30 ᪥㸧
୹㔝 ⨾㕥
a) ᴫせ
ᙜ◊✲ศ㔝ࡣࠊ་⸆ရࡢࢩ࣮ࢻ࣭࣮ࣜࢻ໬ྜ≀ࡢ๰〇࠾ࡼࡧ⸆≀࡜⸆≀ཷᐜయ࡜ࡢ┦஫స⏝࡞࡝་⸆
ရࡢస⏝ᶵᵓゎ᫂ࢆ◊✲┠ⓗ࡜ࡋ࡚࠸ࡿࠋࢪࢸࣝ࣌ࣥ㓄⢾యࢆᇶ┙࡜ࡋࡓ⣽⬊ෆಙྕఏ㐩⣔ࡢไᚚ໬ྜ
≀ࡸࣂࢡࢸࣜ࢔ࡢከ๣⪏ᛶ໬࡟ಀࡿከ๣᤼ฟࡓࢇࡥࡃ㉁㜼ᐖ๣࡞࡝ࡢ๰⸆◊✲ࠊ࣌ࣉࢳࢻ᰾㓟࡟ࡼࡿ࢖
ࣥࣇ࢚ࣝࣥࢨࢆጞࡵ࡜ࡍࡿ࢘࢖ࣝࢫࢤࣀ࣒ࡢ㎿㏿┠どデ᩿ᢏ⾡ࡢ㛤Ⓨ◊✲ࠊ⑌⑓⑓⌮ࡢᇶ┙࡜࡞ࡿࢩࢢ
ࢼࣝఏ㐩ࡀᵓᡂⓗ࡟␗ᖖ࡜࡞ࡿ㑇ఏᏊᨵኚື≀ࡢసฟ࡟ྲྀ⤌ࢇ࡛࠸ࡿࠋ
b) ᡂᯝ
࣭3,12 ఩↓⨨᥮ᆺࣇࢩࢥࢡࢩࣥㄏᑟయࡢ anoikis ㄏᑟάᛶ
ࡇࢀࡲ࡛ࠊࢪࢸࣝ࣌ࣥ㓄⢾య࡛࠶ࡿࣇࢩࢥࢡࢩࣥ㸦FC㸸࢔ࢢࣜࢥࣥ㒊 12
఩࡟ࣄࢻࣟ࢟ࢩᇶ㸧࠾ࡼࡧࢥࢳࣞࢽࣥ㸦CN㸸3 ఩࡟ࣄࢻࣟ࢟ࢩᇶ㸧ࡢศ໬
ㄏᑟάᛶࡸ⭘⒆ቑṪᢚไάᛶࢆሗ࿌ࡋ࡚᮶ࡓࠋ௒ᅇࠊ3,12 ఩↓⨨᥮ᆺ FC
ㄏᑟయ 1 ࡀኳ↛ᆺ FC/CN ࡜ࡣ␗࡞ࡿ⏕⌮άᛶࢆ᭷ࡍࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
1 ࡣ CN ࡜ྠᵝ࡟ HL-60㸦ࣄࢺ㦵㧊ᛶⓑ⾑⑓⣽⬊㸧࡟ᑐࡍࡿศ໬ㄏᑟάᛶ
ࢆᣢࡘ࡜ྠ᫬࡟ࠊCN ࡟ࡣぢࡽࢀ࡞࠸≉ᚩⓗ࡞⣽⬊ẘᛶࢆ♧ࡋࡓࠋࡍ࡞ࢃ
ࡕࠊA549㸦ࣄࢺ⫵⬊ᇶᗏୖ⓶⭢⒴⣽⬊㸧ࡣࡀࢇ⣽⬊࡟≉ᚩⓗ࡞㊊ሙ㠀౫Ꮡ
ⓗቑṪ⬟㸦anoikis ⪏ᛶ㸧ࢆ᭷ࡍࡿࡀࠊ1 ࡣᾋ㐟≧ែ࡟࠶ࡿ A549 ⣽⬊ࢆ
apoptosis ࡟ᑟࡃࠋࡍ࡞ࢃࡕࠊ1 ࡣ anoikis㸦㊊ሙ౫Ꮡᆺ apoptosis㸧ㄏᑟάᛶ ᅗ㸯
3,12 ఩↓⨨᥮ᆺ FC ㄏᑟయ 1
ࢆᣢࡘࠋࡋࡓࡀࡗ࡚ࠊ1 ࡟ࡣࠊࡀࢇ㌿⛣
ᢚไ๣࡜ࡋ࡚ࡢྍ⬟ᛶࡀᮇᚅ࡛ࡁࡿࠋ
ࡉࡽ࡟ࠊ1 ࡣࠊA549 ࡟ᑐࡋ࡚㐟㉮㜼ᐖ
άᛶࡶ♧ࡋࡓࠋࡑࡢ㝿ࠊ࢔ࢡࢳࣥࢫࢺ
ࣞࢫࣇ࢓࢖ࣂ࣮ࡢ㢧ⴭ࡞ῶ㏥ࡀほ ࡉ
ࢀࡿࡇ࡜࠿ࡽࠊࡑࢀࡀ㐟㉮㜼ᐖࢆࡶࡓ
ࡽࡍࡇ࡜ࡀᙉࡃ♧၀ࡉࢀࡿࠋࡲࡓࠊ3,12
ᅗ㸰 A549 cells were incubated in the presence of compound 1 (middle), CN
఩↓⨨᥮ᆺㄏᑟయࡣࠊஙࡀࢇ⣽⬊
(right) or absence of compounds (left) and stained with Acti-stain 488. Yellow
㸦MCF-7㸧࡟ᑐࡍࡿ↓Ỉளࣄ㓟ࡢቑṪ
arrows indicate stress fibers, which diminished by treatment with compound 1.
ᢚไຠᯝࢆ㢧ⴭ࡟ቑᙉࡍࡿࡇ࡜ࡶ᫂ࡽ
࠿࡟ࡋࡓࠋ⌧ᅾࡇࢀࡽࡢάᛶࡢస⏝ᶵᗎゎ᫂ࢆ⥅⥆୰࡛࠶ࡿࠋ
࣭⥳⮋⳦ከ๣᤼ฟࢺࣛࣥࢫ࣏࣮ࢱ࣮㜼ᐖ๣ࡢ㛤Ⓨ
RND ᆺࡢከ๣᤼ฟࢺࣛࣥࢫ࣏࣮ࢱ࣮ࡣከ๣⪏ᛶ⥳⮋⳦㸦MDRP㸧࡞࡝ࡢࢢ࣒ࣛ㝜ᛶ⳦ࡢከ๣⪏ᛶ໬࡟
― 70 ―
኱ࡁࡃ㛵୚ࡋ࡚࠾ࡾࠊ⮫ᗋศ㞳ࡉࢀࡓ MDRP ࡛ࡣ᤼ฟࢺࣛࣥࢫ࣏࣮ࢱ࣮MexBࠊMexY ࡀ㐣๫Ⓨ⌧ࡋ࡚
࠸ࡿࠋࡋࡓࡀࡗ࡚ࠊMexBࠊMexY ࡢ㜼ᐖ๣ࡣ MDRP ࡢ἞⒪⸆࡜ࡋ࡚ᮇᚅ࡛ࡁࡿ࡜ࡢほⅬ࠿ࡽࠊ⏕య㜵
ᚚᏛ◊✲ศ㔝㸦ᒣཱྀ◊㸧࡜ࡢඹྠ◊✲࡜ࡋ࡚㜼ᐖ๣㛤Ⓨ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋࡑࡢ⤖ᯝࠊ᪤▱ࡢ MexB 㜼
ᐖ๣࡛࠶ࡿࣆࣜࢻࣆ࣑ࣜࣥࢪࣥㄏᑟయ
㸦PP㸧
ࡼࡾᵓ㐀ࡀ⡆␎໬ࡉࢀࡓ MexB 㑅ᢥⓗ㜼ᐖ๣ 2 ࢆぢฟࡋࡓࠋ
2 ࡣࠊMexB ࢆ㐣๫Ⓨ⌧ࡉࡏࡿࡇ࡜࡛ erythromycin㸦EM㸧⪏ᛶࢆ㈿୚ࡋࡓ኱⭠⳦ࡢቑṪࢆ㢧ⴭ࡟ᢚไࡍ
ࡿࠋࡍ࡞ࢃࡕࠊከ๣᤼ฟ
ࢺࣛࣥࢩ࣏࣮ࢱ࣮ࢆ㜼ᐖ
ࡍࡿࡇ࡜࡛ࠊEM ឤཷᛶࢆ
ᅇ᚟࡛ࡁࡓࠋࡉࡽ࡞ࡿᵓ
㐀ᒎ㛤࡟ࡼࡗ࡚ࠊMexB ࠾
ࡼࡧ MexY ࢆྠ᫬࡟㜼ᐖ
ࡍࡿࣘࢽࣂ࣮ࢧࣝ㜼ᐖ๣
ᅗ㸱 ᪤▱㸦PP㸧࠾ࡼࡧ᪂つ㸦2㸧MexB 㜼ᐖ๣
ࡢ㛤Ⓨࢆ᳨ウࡋ࡚࠸ࡿࠋ
࣭ࢺࣛࣥಟ㣭࣌ࣉࢳࢻ᰾㓟ࢆ⏝࠸ࡓ୍ሷᇶ࣑ࢫ࣐ࢵࢳ㆑ู
㑇ఏᏊୖࡢ୍ሷᇶከᆺࢆ㆑ูࡍࡿࡇ࡜ࡣࠊ⑌ᝈࡸ⸆๣࡟ᑐࡍࡿ
๪స⏝ࣜࢫࢡࢆぢᴟࡵࡿୖ࡛ࡣ኱ኚ㔜せ࡛࠶ࡿࠋ࣌ࣉࢳࢻ᰾㓟
(PNA)ࡣᶆⓗ㓄ิ୰ࡢ୍ሷᇶኚ␗ࢆࡼࡾ㑅ᢥⓗ࡟㆑ูࡍࡿࡇ࡜ࡀ
▱ࡽࢀ࡚࠸ࡿࠋࡋ࠿ࡋࠊࡑࡢ㑅ᢥᛶࡣ࣑ࢫ࣐ࢵࢳሷᇶᑐࡀ┦⿵㙐
ࡢᮎ➃㏆ഐ࡟࠶ࡿሙྜ࡟పୗࡋ࡚ࡋࡲ࠺ࠋᡃࠎࡣ PNA ࡢ㓄ิ㑅ᢥ
ᛶࢆྥୖࡉࡏࡿࡓࡵࠊ✀ࠎ࢖ࣥࢱ࣮࣮࢝ࣞࢱ࣮ศᏊࢆ PNA ࡢ N
ᅗ㸲 Tolane 3 ࡢ໬Ꮫᵓ㐀.
ᮎ➃࡟࢔࣑ࢻ⤖ྜ࡟ࡼࡾᑟධࡋࡓࠋࡑࡢ⤖ᯝࠊPNA ࡟᪂つࢺࣛࣥ
ㄏᑟయ㸦Tolane 3, ᅗ㸲㸧ࢆᑟධࡍࡿ࡜ࠊ┦⿵㙐࡟ᑐࡍࡿᏳᐃᛶࢆ
5.7oC ྥୖࡉࡏࡓ㸦⾲㸯㸧
ࠋPNA-tolane ࢥࣥࢪࣗࢤ࣮ࢺࡣ㏆ഐࡢ஧㔜㙐ᵓ㐀ࢆ㆑ูࡋ࡚ሷᇶᑐᙧᡂࢆᏳᐃ
໬ࡉࡏࡿྍ⬟ᛶࡀぢ࠸ࡔࡉࢀࡓࠋ
⾲ 1. UV ⼥ゎ᭤⥺ࢆ⏝࠸ࡓ PNA/DNA ஧㔜㙐఍ྜ≉ᛶホ౯
Tm( oC)
Entry
PNA sequence (N-C )
PNA-Control
PNA-Tolane 3
H2N-TTCCCTCCTCTA-Lys
Tolane 3-TTCCCTCCTCTA-Lys
1)
DNA
Match1)
56.6㼼0.9
62.9㼼0.3
DNA
Mismatch2)
49.4㼼0.9
50.0㼼0.6
'Tm
7.2
12.9
5’-ATGTCCTAGAGGAGGGAATAA-3’, 2) 5’-ATGTCCTAGAGGAGGGCATAA-3’.
࣭⣽⬊ෆࢩࢢࢼࣝఏ㐩ࡢไᚚᶵᵓ࡜ࡋ࡚ࡢ࣑ࢡ࣮ࣟࣟࢺࣇ࢓ࢪ࣮
࢚ࣥࢻࢧ࢖ࢺ࣮ࢩࢫࡣ⣽⬊እࢩࢢࢼࣝࡢཷᐜࠊᰤ㣴౪⤥ࢆ㏻ࡌ࡚ࠊᵝࠎ࡞⏕⌮ᶵ⬟ࡢไᚚ࡟ᚲ㡲࡞ᙺ
๭ࢆᯝࡓࡍࠋึᮇⓎ⏕࡛ࡣࢩࢢࢼࣝఏ㐩άᛶࡸ⤌⧊ᵓ㐀ࡀࢲ࢖ࢼ࣑ࢵࢡ࡟ኚ໬ࡋࠊࡑࡢไᚚ࡟࢚ࣥࢻࢧ
࢖ࢺ࣮ࢩࢫࡀ㛵୚ࡍࡿ࡜⪃࠼ࡽࢀࡿࠋ࣐࢘ࢫึᮇ⬇࡛ࡣࠕ࣑ࢡ࣮ࣟ࢜ࢺࣇ࢓ࢪ࣮ࠖ࡜ࡼࡤࢀࡿᴟࡵ࡚ࣘ
ࢽ࣮ࢡ࡞࣓࢝ࢽࢬ࣒࡛࢚ࣥࢻࢧ࢖ࢺ࣮ࢩࢫࡀ㐍⾜ࡍࡿࠋ࣑ࢡ࣮ࣟ࢜ࢺࣇ࢓ࢪ࣮࡟ࡣపศᏊ㔞 GTP ⤖ྜࢱ
ࣥࣃࢡ㉁ rab7 ࡀᚲ㡲࡛࠶ࡿࠋrab7 ࢆḞኻࡍࡿ࣐࢘ࢫ⬇ࡣࠊึᮇⓎ⏕ࠊཎ⭠㝗ධ㏵୰࡛Ⓨ⏕ࡀ೵Ṇࡍࡿࠋ
ึᮇⓎ⏕ࢆᨭ㓄ࡍࡿࢩࢢࢼࣝఏ㐩࡟╔┠ࡋࠊNodal/Tgf-beta ࢩࢢࢼࣝࠊBmp ࢩࢢࢼࣝࠊFgf ࢩࢢࢼࣝࠊࡉ
ࡽ࡟ canonical Wnt ࢩࢢࢼࣝࢆ᳨ウࡋࡓࠋTGF-beta, BMP ⤒㊰ࡣᢠࣜࣥ㓟໬ Smad ᢠయࢆ⏝࠸࡚ whole
mount ⬇⺯ගᢠయᰁⰍࢆ⾜ࡗࡓ࡜ࡇࢁࠊ
ኚ␗⬇࡛ࡶ㢧ⴭ࡞␗ᖖࡀぢࡽࢀ࡞࠸ࠋ
ࡲࡓࠊFgf ⤒㊰ࡢᣦᶆ p42/44
ࡢࣜࣥ㓟໬ࣃࢱ࣮ࣥࡶ㔝⏕ᆺ࡜ኚ␗⬇࡛ᕪ㐪ࡀほᐹࡉࢀ࡞࠸ࠋ୍᪉ࠊBrachyury ࡢⓎ⌧పୗࠊAxin2 ࡢⓎ
⌧ࡢḞᦆ࡞࡝ࠊcanonical Wnt ⤒㊰࡟ᨭ㓄ࡉࢀࡿ㑇ఏᏊⓎ⌧ࡣࠊኚ␗⬇࡛࠶ࡁࡽ࠿࡟␗࡞ࡿࣃࢱ࣮ࣥࢆ♧
ࡋࠊrab7 ࡢᶵ⬟ࡀ Wnt ⤒㊰ࡢไᚚ࡟ᚲ㡲࡛࠶ࡿࡇ࡜ࡀࢃ࠿ࡗࡓࠋࡍ࡞ࢃࡕࠊrab7 ࢆḞᦆࡍࡿ࣐࢘ࢫ⬇ࡀ
♧ࡍ⾲⌧ᆺࢆ⬇࡛ࣞ࣋ࣝゎᯒࡋࠊ࣑ࢡ࣮ࣟ࢜ࢺࣇ࢓ࢪ࣮ࢆక࠺࢚ࣥࢻࢧ࢖ࢺ࣮ࢩࢫࡀ⤌⧊ᵓ⠏ࠊึᮇ⬇
ࣃࢱ࣮ࣥᙧᡂࢆᨭ㓄ࡍࡿཎ⌮ࡢ୍➃ࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
― 71 ―
⏕యศᏊ཯ᛂ⛉Ꮫ◊✲ศ㔝
෸ᩍᤵ
ຓᩍ
ᒸᓥ ಇⱥ
❧ᯇ ೺ྖࠊ୰஭ ᛅᚿ
a) ᴫせ
ᙜ◊✲ศ㔝࡛ࡣࠊᗈࡃ⏕໬ᏛࠊศᏊ⏕≀Ꮫࠊ⣽⬊⏕≀Ꮫ࡞࡝ࡢ❧ሙ࠿ࡽࠊ⏕࿨⌧㇟ࢆᢸ࠺✀ࠎࡢ⏕య
ᶵ⬟ศᏊࡢᵓ㐀࡜ᶵ⬟ࡢ┦㛵ࢆศᏊ࡛ࣞ࣋ࣝゎ᫂ࡍࡿࡇ࡜ࢆ┠ᣦࡋ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋ≀㉁௦ㅰࡸ࢚ࢿ
ࣝࢠ࣮௦ㅰࢆᢸ࠺⏕యゐ፹“㓝⣲”ࢆᑐ㇟࡜ࡋ࡚ࠊ඲యᵓ㐀ࠊ࠾ࡼࡧάᛶ㒊఩ᵓ㐀ࠊࡑࢀࡽ࡟ᇶ࡙࠸࡚ゐ
፹཯ᛂᶵᵓࢆ᫂ࡽ࠿࡟ࡍࡿ࡭ࡃ◊✲ࢆᒎ㛤ࡋ࡚࠸ࡿࠋ≉࡟ࠊ㖡࢔࣑ࣥ㓟໬㓝⣲ࡢࢺࣃ࢟ࣀࣥ⿵㓝⣲ࢆࡣ
ࡌࡵ࡜ࡋ࡚ࠊ᭱㏆┦ḟ࠸࡛Ⓨぢࡉࢀ࡚࠸ࡿ࢔࣑ࣀ㓟ṧᇶ⏤᮶ࡢ᪂つ࡞ඹ᭷⤖ྜᆺ⿵㓝⣲㸦࠸ࢃࡺࡿ࣌ࣉ
ࢳࢻ࣭ࣅࣝࢺ࢖ࣥᆺ⿵㓝⣲㸧ࡢᵓ㐀࡜ゐ፹ᶵ⬟ࠊࢱࣥࣃࢡ㉁⩻ヂᚋಟ㣭࡟ࡼࡿ⏕ྜᡂᶵᵓࡢゎ᫂࡟ຊࢆ
ὀ࠸࡛࠸ࡿࠋࡲࡓࠊ᪂つᢠ⳦๣ࡢ㛤Ⓨࢆ┠ᣦࡋ࡚⣽⳦ࡢ᝟ሗఏ㐩⣔࡟㛵ࢃࡿࢱࣥࣃࢡ㉁ࡢᵓ㐀⏕≀Ꮫⓗ
◊✲ࡶ⾜ࡗ࡚࠸ࡿࠋ୍᪉ࠊᛂ⏝ⓗ◊✲࡜ࡋ࡚ࠊ௵ពࡢ⤌⧊࣭⣽⬊࡟ᶆⓗ≉␗ᛶࢆ᭷ࡍࡿࣂ࢖࢜ࢼࣀ࢝ࣉ
ࢭࣝࢆ⏝࠸ࡓ㑇ఏᏊᑟධἲࡸࢻࣛࢵࢢࢹࣜࣂ࣮ࣜἲࢆ㛤Ⓨࡋ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭ࣛࢪ࢝ࣝࢆ฼⏝ࡍࡿ࣌ࣉࢳࢻᯫᶫᙧᡂ㓝
⣲ࡢ཯ᛂᶵᵓゎᯒ
࢟ࣀ࣒࣊ࣉࣟࢸ࢖࣭ࣥ࢔࣑ࣥ⬺Ỉ⣲㓝⣲
(QHNDH)ࡣ Paracoccus denitrificans ࡞࡝ࡢ
ከࡃࡢࢢ࣒ࣛ㝜ᛶ⣽⳦࡜ࡈࡃ୍㒊ࡢࢢ࣒ࣛ
㝧ᛶ⣽⳦࡟Ꮡᅾࡍࡿ㓝⣲࡛࠶ࡾࠊ୍⣭࢔࣑
ࣥ㢮ࢆ㈨໬ࡍࡿᙺ๭ࢆࡶࡘࠋQHNDH ࡣ ĮȕȖ
࣊ࢸࣟ 3 㔞యᵓ㐀ࢆ᭷ࡍࡿศἪ㓝⣲࡛࠶ࡿࠋ
᭱ᑠࡢ Ȗ ࢧࣈࣘࢽࢵࢺࡣࠊCys ࡜ Trp ṧᇶ
࠿ࡽᙧᡂࡉࢀࡓ⿵㓝⣲ࢩࢫࢸ࢖ࣥࢺࣜࣉࢺ
ࣇ࢕ࣝ࢟ࣀࣥ(CTQ)࠾ࡼࡧ Cys ṧᇶ࡜㏆ഐ
ࡢ Asp/Glu ṧᇶ㛫࡟ᙧᡂࡉࢀࡓ 3 ࣧᡤࡢศ
ᅗ㸯 4KS' ᯫᶫᙧᡂࡢ཯ᛂᶵᵓ
Ꮚෆࢳ࢚࣮࢜ࢸࣝᯫᶫᵓ㐀ࢆྵࢇ࡛࠾ࡾࠊ
ከẁ㝵ࡢ⩻ヂಟ㣭ᶵᵓ࡟ࡼࡗ࡚⏕ྜᡂࡉࢀ࡚࠸ࡿ࡜⪃࠼ࡽࢀ࡚࠸ࡿࠋࡇࢀࡲ࡛࡟ࠊᵓ㐀㑇ఏᏊ qhpABC
ࡣࠊ㏆᥋ࡍࡿ㑇ఏᏊ࡜ࡶ࡟࢜࣌ࣟࣥ qhpADCBEF ࢆᵓᡂࡋ࡚࠾ࡾࠊqhpDE ࡀȚࢧࣈࣘࢽࢵࢺࡢ⩻ヂᚋಟ
㣭࡟㛵ࢃࡗ࡚࠸ࡿࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡗ࡚࠸ࡿࠋࡇࡢ࠺ࡕ qhpD ࡣࠊȖ ࢧࣈࣘࢽࢵࢺෆࡢࢳ࢚࣮࢜ࢸࣝᯫ
ᶫࢆᙧᡂࡍࡿࣛࢪ࢝ࣝ SAM 㓝⣲ QhpD ࢆࢥ࣮ࢻࡋ࡚࠸ࡿࠋᮏ◊✲࡛ࡣࠊ࣌ࣉࢳࢻศᏊෆᯫᶫᙧᡂ࡜࠸
࠺ QHNDH ࡢ⏕ྜᡂ㐣⛬࡟࠾ࡅࡿ㞴⏕໬Ꮫ཯ᛂࡢ཯ᛂᶵᵓࢆ᫂ࡽ࠿࡟ࡍࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚ࠊQhpD ࢱ
ࣥࣃࢡ㉁ࢆ኱⭠⳦ෆ࡛Ⓨ⌧ࡉࡏࠊࡑࢀࢆ⏝࠸࡚ Ȗ ࢧࣈࣘࢽࢵࢺෆᯫᶫᙧᡂ཯ᛂࢆゎᯒࡋࡓ㹙ㄽᩥ 8㹛ࠋ
㔝⏕ᆺ࠾ࡼࡧኚ␗ᆺ QhpD ࡢ㕲࠾ࡼࡧ◲㯤ྵ㔞ࡢᐃ㔞ࡸศගᏛⓗゎᯒࡢ⤖ᯝࠊ㸱ࡘࡢ[4Fe-4S]㕲◲㯤
ࢡࣛࢫࢱ࣮ࡀྵࡲࢀ࡚࠸ࡿࡇ࡜ࡀࢃ࠿ࡗࡓࠋࡇࡢ࠺ࡕࠊN ᮎ➃ഃ࡟Ꮡᅾࡍࡿ㕲◲㯤ࢡࣛࢫࢱ࣮ࡀࠊS-࢔
ࢹࣀࢩ࣓ࣝࢳ࢜ࢽࣥࡢ㑏ඖⓗศゎ࡟㛵୚ࡋ࡚࠸ࡓࠋࡲࡓࠊᇶ㉁࡜࡞ࡿ Ȗ ࢧࣈࣘࢽࢵࢺࡢᯫᶫᙧᡂ㒊఩࡟
Ꮡᅾࡍࡿ Asp/Glu ṧᇶࢆࠊ㈇㟁Ⲵࢆᣢࡓ࡞࠸ Asn/Gln ṧᇶ࡟ᨵኚࡍࡿ࡜ࠊᯫᶫᙧᡂࡀ㉳ࡇࡽ࡞࠿ࡗࡓࠋ
QhpD/Ȗ ࢧࣈࣘࢽࢵࢺ」ྜయࡢࣔࢹࣝᵓ㐀ࢆᵓ⠏ࡍࡿ࡜ࠊಖᏑࡉࢀࡓ Arg373 ࡀ Asp/Glu ṧᇶࡢㄆ㆑࡟ᶵ
⬟ࡋ࡚࠸ࡿ࡜᥎ ࡉࢀࠊArg373 ࢆ Ala ࡟ኚ᥮ࡍࡿ࡜ࠊᯫᶫᙧᡂࡀ㉳ࡇࡽ࡞࠸ࡇ࡜࡜ࡶྜ⮴ࡋࡓࠋ⯆࿡῝
࠸ࡇ࡜࡟ࠊȖ ࢧࣈࣘࢽࢵࢺࡢ㸱ࡘࡢᯫᶫᙧᡂ㒊఩࡬ࡢኚ␗ᑟධᐇ㦂ࡢ⤖ᯝࠊȖ ࢧࣈࣘࢽࢵࢺࡢ N ᮎ➃࠿
ࡽ C ᮎ➃࡬ࠊ㐃⥆ⓗ࠿ࡘ㡰୙ྠ࡟ᯫᶫᙧᡂࡉࢀ࡚࠸ࡿࡇ࡜ࡀࢃ࠿ࡗࡓࠋ௨ୖࡢ⤖ᯝ࡟ᇶ࡙࠸࡚⏕ᡂࡋࡓ
࢔ࢹࣀࢩࣝࣛࢪ࢝ࣝࡀᯫᶫᙧᡂ࡟㛵ࢃࡿ཯ᛂᶵᵓࢆ᝿ᐃࡍࡿࡇ࡜ࡀ࡛ࡁࡓ(ᅗ 1)ࠋ
― 72 ―
࣭ࢽࢥࢳࣥᛶ࢔ࢭࢳࣝࢥࣜࣥཷᐜయࡢࢿ࢜ࢽࢥࢳࣀ࢖ࢻㄆ㆑ᶵᵓ
࢖࣑ࢲࢡࣟࣉࣜࢻ࡟௦⾲ࡉࢀࡿẅ⹸๣ࢿ࢜ࢽࢥࢳࣀ࢖ࢻࡣࠊ᪻⹸ࡢࢽࢥࢳ
ࣥᛶ࢔ࢭࢳࣝࢥࣜࣥཷᐜయ(nAChR)ࢆศᏊᶆⓗ࡜ࡍࡿẅ⹸๣࡛࠶ࡿࠋࡑࡢᶆ
ⓗ࡜࡞ࡿ nAChR ࡣ Cys-loop ࢫ࣮ࣃ࣮ࣇ࢓࣑࣮ࣜ࡟ᒓࡍࡿࣜ࢞ࣥࢻ㛤ཱྀ࢖࢜
ࣥࢳࣕࢿ࡛ࣝ࠶ࡾࠊ⬨᳝ື≀࣭↓⬨᳝ື≀ࡢ࠸ࡎࢀ࡟࠾࠸࡚ࡶ࢔ࢭࢳࣝࢥࣜ
ࣥ࡟ࡼࡿ⚄⤒ఏ㐩ࢆ⾜࠺㔜せ࡞⭷ཷᐜయ࡛࠶ࡿࠋࣄࢺࢆྵࡴ⬨᳝ື≀ࡢ
nAChR ࡟ࡣ⤖ྜࡏࡎࠊ᪻⹸ࡢ nAChR ࡜㑅ᢥⓗ࡟┦஫స⏝ࡍࡿࡇ࡜ࡀࠊࢿ࢜
ࢽࢥࢳࣀ࢖ࢻࡢᏳ඲ᛶ࡟ᐤ୚ࡋ࡚࠸ࡿࡀࠊ᪻⹸ nAChR 㑅ᢥⓗ࡞ࢿ࢜ࢽࢥࢳ
ࣀ࢖ࢻࡢ┦஫స⏝ࡀࠊ࡝ࡢࡼ࠺࡞ศᏊᶵᵓ࡟ࡼࡗ࡚⏕ࡌ࡚࠸ࡿࡢ࠿ࡣ౫↛ᮍ
ゎ᫂࡞Ⅼࡀከ࠸ࠋᐇ㝿ࠊࢿ࢜ࢽࢥࢳࣀ࢖ࢻࡣࠊẅ⹸๣࡜ࡋ࡚ୡ⏺ᕷሙࡢ⣙
20%ࢆ༨ࡵࡿ୍᪉࡛ࠊ᭱㏆ࠊ⻏⩌ᔂቯ⑕ೃ⩌㸦CCD㸧ࡢ୺࡞ཎᅉ࡛࠶ࡿ࡜␲
ࢃࢀࠊࡑࡢ⎔ቃ࡬ࡢᙳ㡪ࡶᠱᛕࡉࢀ࡚࠸ࡿࠋࡑࡇ࡛ࠊᮏ◊✲࡛ࡣࠊnAChR
ࡢ࢔ࢭࢳࣝࢥࣜࣥ⤖ྜࢻ࣓࢖ࣥ࡟ᑐᛂࡍࡿྍ⁐ᛶࢱࣥࣃࢡ㉁ࠊࣔࣀ࢔ࣛ࢞࢖
⏤᮶࢔ࢭࢳࣝࢥࣜࣥ⤖ྜࢱࣥࣃࢡ㉁(AChBP)ࢆࣔࢹࣝ࡜ࡋ࡚ࠊࢿ࢜ࢽࢥࢳࣀ
࢖ࢻࡀ᪻⹸ࡢ nAChR ࡟ᑐࡋ࡚㑅ᢥⓗ࡟⤖ྜࡍࡿศᏊᶵᵓ࡟ࡘ࠸࡚ヲ⣽࡟
ゎᯒࡋࡓ㹙ㄽᩥ 7㹛ࠋ
AChBP ࡣྜᡂ㑇ఏᏊࢆ Pichia pastoris Ⓨ⌧⣔ࢆ⏝࠸࡚⳦యእ࡬ศἪⓎ⌧ࡋࠊ ᅗ㸰 $&K%3 ࢿ࢜ࢽࢥࢳࣀ࢖ࢻ
」ྜయࡢᵓ㐀
ᇵ㣴ୖΎࡢ⃰⦰ᾮࡼࡾ࢖࢜ࣥ஺᥮࠾ࡼࡧࢤࣝࢁ㐣ࢡ࣐ࣟࢺ
ࢢࣛࣇ࢕࣮࡟ࡼࡗ࡚⢭〇ࡋࡓࠋࡇࢀࡲ࡛ࡢ◊✲ࡢ⤖ᯝࠊ᪻⹸
nAChR ࡟࠾࠸࡚ࢿ࢜ࢽࢥࢳࣀ࢖ࢻ࡜ࡢ┦஫స⏝࡟㔜せ࡜⪃
࠼ࡽࢀࡓ㒊఩㸦AChBP ࡢ 55 ఩࡟┦ᙜ㸧ࡀࠊ᪻⹸ nAChR ࡛
ࡣ Arg ṧᇶࡢ࡜ࡇࢁࠊAChBP ࡛ࡣ Gln ࡟ኚ໬ࡋ࡚࠸ࡓࡢ࡛ࠊ
᪻⹸ nAChR ࡟㏆࡙ࡅࡿࡓࡵ Q55R ኚ␗ᆺ AChBP ࡶࠊ㔝⏕ᆺ
࡟ຍ࠼ࠊྜࢃࡏ࡚ㄪ〇ࡋࡓࠋࡲࡎࠊ⵨Ẽᣑᩓἲࢆ⏝࠸࡚ࢿ࢜
ࢽࢥࢳࣀ࢖ࢻ࠾ࡼࡧ㛵㐃໬ྜ≀࡜㔝⏕ᆺ࣭Q55R ኚ␗ᆺ
AChBP ࡢඹ⤖ᬗࢆసᡂࡋࠊX ⥺⤖ᬗᵓ㐀ゎᯒࢆ⾜ࡗࡓࠋࡑ
ࡢ⤖ᯝࠊࡇࢀࡽ AChBP 」ྜయ⤖ᬗᵓ㐀ࡣศゎ⬟ 2.09-2.68Å
࡛ゎᯒࡍࡿࡇ࡜ࡀ࡛ࡁࠊ㔝⏕ᆺ࡜ྠࡌ⎔≧ࡢ࣌ࣥࢱ࣐࣮ᵓ㐀
ࢆ᭷ࡋ࡚࠸ࡿࡇ࡜ࡀࢃ࠿ࡗࡓ(ᅗ㸰)ࠋࡲࡓࠊ࠸ࡎࢀࡢ」ྜయ
ᅗ㸱 ࢿ࢜ࢽࢥࢳࣀ࢖ࢻㄏᑟయࡢ⤖ྜ㒊఩
࡟࠾࠸࡚ࡶࠊࢧࣈࣘࢽࢵࢺቃ⏺࡟Ꮡᅾࡍࡿ࢔ࢭࢳࣝࢥࣜࣥ⤖
ྜ㒊఩࡟ࢿ࢜ࢽࢥࢳࣀ࢖ࢻ࠶ࡿ࠸ࡣ㛵㐃໬ྜ≀ࡀ⤖ྜࡋ࡚
࠸ࡓࠋࣜ࢞ࣥࢻ⤖ྜ㒊఩ࢆヲ⣽࡟᳨ドࡍࡿ࡜ࠊQ55R ኚ␗ᑟධ࡟ࡼࡗ࡚ࠊ඲࡚ࡢࢿ࢜ࢽࢥࢳࣀ࢖ࢻࡢࢩ
࢔ࣀᇶࡸࢽࢺࣟᇶࡀኚ␗ᑟධࡋࡓ Arg55 ࡜┦஫స⏝ࡋ࡚࠾ࡾࠊ➼ ⁲ᐃᆺ⇕㔞ศᯒ࡟࠾࠸࡚ࡶ⤖ྜࡢ⇕
ຊᏛⓗࣃ࣓࣮ࣛࢱ࣮ࡀ኱ࡁࡃኚ໬ࡋࡓࠋ⯆࿡῝࠸ࡇ࡜࡟ࠊ࠸ࡃࡘ࠿ࡢ໬ྜ≀ࡣ Gln55(Arg55)ࡔࡅ࡛ࡣ࡞
ࡃ᪻⹸࡟ಖᏑࡉࢀࡓሷᇶᛶṧᇶ Lys34 ࡜ࡶ┦஫స⏝ࡋ࡚࠸ࡓ(ᅗ㸱)ࠋLys34 ࡣࠊGln55 ࡀᏑᅾࡍࡿ ȕ2 ࢫ
ࢺࣛࣥࢻ࡜㏫ᖹ⾜ ȕ ࢩ࣮ࢺᵓ㐀ᙧᡂࡍࡿ ȕ1 ࢫࢺࣛࣥࢻୖ࡟Ꮡᅾࡋ࡚࠸ࡿࡀࠊ❧యᵓ㐀ୖࠊࢿ࢜ࢽࢥࢳ
ࣀ࢖ࢻ࡜ࡶ㏆᥋ࡋ࡚࠸ࡓࠋࡍ࡞ࢃࡕࠊ᪻⹸ nAChR ࡢᑐᛂࡍࡿ࢔࣑ࣀ㓟ṧᇶࡀࢿ࢜ࢽࢥࢳࣀ࢖ࢻ࡜ࡢ┦
஫స⏝࡟㛵୚ࡋ࡚࠸ࡿྍ⬟ᛶࡀ♧၀ࡉࢀࡓࠋࡑࡇ࡛ࠊAChBP ࡜㧗࠸┦ྠᛶࡢ࢔ࢦࢽࢫࢺ⤖ྜ㡿ᇦࢆࡶ
ࡘࢽ࣡ࢺࣜ Į7 nAChR ࡟┦ྠࡢ᪻⹸ᆺṧᇶ㸦Q79R, S58K㸧ࢆᑟධࡋࠊ࢔ࣇࣜ࢝ࢶ࣓࢚࢞ࣝ༸ẕ⣽⬊Ⓨ⌧
⣔࡟࠾࠸࡚ࢿ࢜ࢽࢥࢳࣀ࢖ࢻࡢάᛶࢆ஧㟁ᴟ⭷㟁఩ᅛᐃἲ࡟ࡼࡗ࡚ホ౯ࡋࡓࠋࡑࡢ⤖ᯝࠊĮ7 nAChR ࡟
ᑐࡋ࡚ࠊࢿ࢜ࢽࢥࢳࣀ࢖ࢻࡣ㢧ⴭ࡞࢔ࢦࢽࢫࢺάᛶࢆ♧ࡋࠊ᪻⹸ nAChR ࡢ Lys34 ࡟┦ᙜࡍࡿሷᇶᛶ࢔
࣑ࣀ㓟ṧᇶࡀࢿ࢜ࢽࢥࢳࣀ࢖ࢻࡢ⤖ྜ࡟㛵୚ࡍࡿࡇ࡜ࢆᨭᣢࡋࡓࠋ௨ୖࡢ⤖ᯝࡣࠊ㑅ᢥᛶࢆᨵၿࡋࠊ⎔
ቃ࡟ࡸࡉࡋ࠸ࢿ࢜ࢽࢥࢳࣀ࢖ࢻࡢ㛤Ⓨ࡟ᐤ୚ࡍࡿࡶࡢ࡜ᮇᚅࡉࢀࡿࠋ
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⏕యศᏊไᚚ⛉Ꮫ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
≉௵◊✲ဨ
኱Ꮫ㝔Ꮫ⏕
Ꮫ㒊Ꮫ⏕
≉ู◊✲Ꮫ⏕
஦ົ⿵బဨ
す㔝 㑥ᙪ㸦ᖹᡂ 27 ᖺ 2 ᭶ 16 ᪥᥇⏝㸧
す Ẏ
す ᬗᏊ
ᒣᓮ ⪷ྖࠊᯘ ඞᙪ
Ἑᔱ ၨኴ
Allison NEUGEBAUER㸦ᖹᡂ 27 ᖺ 10 ᭶㸯᪥ࡼࡾ㸧
ᯇᒸ ⃈ᜨ
a) ᴫせ
⣽⬊ࡣእ⏺࡜⣽⬊⭷࡟ࡼࡗ࡚༊ูࡉࢀ࡚࠸ࡿࠋ⣽⬊⭷ࢆᵓᡂࡍࡿ⬡㉁ 2 㔜⭷ࡣࡑࡢ≀⌮໬Ꮫⓗᛶ㉁࠿
ࡽぶỈᛶࡢ≀㉁ࢆ㏻㐣ࡉࡏࡿࡇ࡜ࡀ࡛ࡁࡎࠊࢺࣛࣥࢫ࣏࣮ࢱ࣮ࡸࢳࣕࢿࣝ࡜࠸ࡗࡓ⺮ⓑ㉁࡟ࡼࡗ࡚㍺㏦
ࡉࢀࡿࠋࢺࣛࣥࢫ࣏࣮ࢱ࣮ࡢ୰࡟ࡣࠊ␗≀᤼ฟࢺࣛࣥࢫ࣏࣮ࢱ࣮࡜ࡼࡤࢀࡿ୍⩌ࡢ⭷㍺㏦యࡀᗈࡃศᕸ
ࡋ࡚࠸࡚ࠊ⣽⬊ࣞ࣋ࣝ࡟࠾ࡅࡿࡶࡗ࡜ࡶᇶᮏⓗ࡞⏕య㜵ᚚᶵᵓ࡜࡞ࡗ࡚࠸ࡿࠋᮏ◊✲ศ㔝࡛ࡣࠊ⣽⳦࠿
ࡽື≀⣽⬊ࡲ࡛ࠊ⏕య␗≀᤼ฟࢺࣛࣥࢫ࣏࣮ࢱ࣮ࡢᵓ㐀࡜ᶵ⬟ࠊⓎ⌧ไᚚࠊ⏕⌮ⓗᙺ๭ࡢゎᯒ࠿ࡽࠊ᪂
つ᤼ฟࢱࣥࣃࢡ㑇ఏᏊࡢ᳨⣴ࡲ࡛ᖜᗈࡃ◊✲ࢆᒎ㛤ࡋ࡚࠸ࡿࠋࡇࢀࡲ࡛࡟ࠊ⣽⳦ࡢ௦⾲ⓗ␗≀᤼ฟ㍺㏦
య AcrB ࡢ⤖ᬗᵓ㐀ࢆୡ⏺࡟ඛ㥑ࡅ࡚Ỵᐃࡋࠊከ๣ㄆ㆑ཬࡧ᤼ฟࡢศᏊᶵᵓࢆゎ᫂ࡋ࡚ࡁࡓࠋࡲࡓື≀
⣽⬊࡟࠾࠸࡚ࡶ␗≀᤼ฟ㍺㏦య࣍ࣔࣟࢢࡢ⏕⌮ⓗᙺ๭ࡢゎᯒࢆ㐍ࡵࠊ⣽⬊⭷ࡢᵓᡂᡂศ࠿ࡽసࡽࢀࡿ⬡
⁐ᛶࡢ⣽⬊㛫᝟ሗఏ㐩≀㉁ࠊ⬡㉁࣓ࢹ࢕࢚࣮ࢱ࣮ࡢࢺࣛࣥࢫ࣏࣮ࢱ࣮ࢆྠᐃࡋࠊࡇࢀࡲ࡛ࡢぶỈᛶࡢศ
Ꮚ࡜ࡣ␗࡞ࡿ㍺㏦ᶵᵓࡢゎ᫂ࢆ㐍ࡵ࡚࠸ࡿࠋᮏᖺᗘ࡟࠾࠸࡚ࡣ௨ୗࡢࡼ࠺࡞㐍ᒎࡀ࠶ࡗࡓࠋ
b) ᡂᯝ
࣭ࢫࣇ࢕ࣥࢦࢩࣥ 1 ࣜࣥ㓟㍺㏦యࡢ့ஙື≀࡟࠾ࡅࡿ⏕⌮ⓗᙺ๭ࡢゎ᫂
ࢫࣇ࢕ࣥࢦࢩࣥ 1 ࣜࣥ㓟㸦S1P㸧ࡣ⣽⬊㛫᝟ሗఏ㐩≀㉁࡜ࡋ࡚ാࡃ⬡⁐ᛶศᏊ࡛ࠊ့ஙື≀࡟࠾࠸࡚
ࢭ࣑ࣛࢻࡢ௦ㅰ≀࡛࠶ࡿࢫࣇ࢕ࣥࢦࢩࣥࡀ⣽⬊ෆ࡛ࡢࣜࣥ㓟໬ࡉࢀࡿࡇ࡜࡛⏕ᡂࡉࢀࡿࠋ⾑₢୰࡟ࡣ㧗
⃰ᗘࡢ S1P ࡀ HDL ࡞࡝࡟⤖ྜࡋࡓ≧ែ࡛Ꮡᅾࡋ࡚࠾ࡾ㸦ࠥ1ȝM㸧ࠊS1P ⃰ᗘࡢప࠸ 2 ḟࣜࣥࣃ⤌⧊࡜ࡢ
㛫ࡢ⃰ᗘ໙㓄ࢆㄆ㆑ࡋࠊࣜࣥࣃ⌫
ࡀ⾑ᾮ୰࡬⛣⾜ࡍࡿ࡜⪃࠼ࡽࢀ
࡚࠸ࡿ(ᅗ㸯)ࠋ⚾ࡓࡕࡣࢮࣈࣛࣇ
࢕ࢵࢩࣗ࡟࠾࠸࡚⏕⌮ⓗ࡟ᶵ⬟
ࡍࡿ S1P ㍺㏦య࡜ࡋ࡚ぢ࠸ࡔࡋ
ࡓ spinster-like protein 2㸦SPNS2㸧
ࡣ့ங㢮࡛ࡶ࢜ࣝࢯࣟࢢࡀᏑᅾ
ࡋࠊᇵ㣴⣽⬊࡬ࡢᙉไⓎ⌧⣔ࢆ⏝
࠸ࡓ࢔ࢵࢭ࢖⣔࡛ S1P ㍺㏦య࡜
ࡋ࡚ാࡃࡇ࡜ࢆ᫂࠿࡟ࡋ࡚ࡁࡓࠋ
S1P ㍺ ㏦ య ࡜ ࡋ ࡚ ᶵ ⬟ ࡍ ࡿ
SPNS2 ࡢ㑇ఏᏊḞᦆ࣐࢘ࢫ࡛ࡣ
⾑₢୰ࡢ S1P ⃰ᗘࡀ༙ศ⛬ᗘ࡟
ࡲ࡛ῶᑡࡋ࡚࠸ࡓࠋࡇࢀࡲ࡛࡟
S1P ྜᡂ㓝⣲ࡢ 1 ࡘ࡛࠶ࡿࢫࣇ࢕
ᅗ㸯 ⾑₢୰ S1P ࡢ౪⤥ᶵᵓ࡜ච␿⣽⬊ࡢ⾑୰⛣⾜ᶵᵓࡢᶍᘧᅗ
ࣥࢦࢩࣥ࢟ࢼ࣮ࢮ㸯㸦SphK㸯㸧ࡢ
ᶵ⬟Ḟᦆ࣐࢘ࢫ࡟࠾࠸࡚ࠊ⾑₢୰ࡢ S1P ⃰ᗘࡀ༙ศ⛬ᗘ࡟ῶᑡࡍࡿࡇ࡜ࡀሗ࿌ࡉࢀ࡚࠸ࡓࡀࠊSphK㸯㑇
ఏᏊḞᦆ࣐࢘ࢫ࡛ࡣ⾑୰ࡢࣜࣥࣃ⌫ᩘ࡞࡝࡟␗ᖖࡣሗ࿌ࡉࢀ࡚࠸࡞࠿ࡗࡓࠋࡋ࠿ࡋࠊSPNS2 㑇ఏᏊḞᦆ
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࣐࢘ࢫࡣ⾑୰࡬ࡢࣜࣥࣃ⌫ࡢ⛣⾜ࡀ᏶඲࡟㜼ᐖࡉࢀ࡚࠾ࡾࠊࣜࣥࣃ⌫ῶᑡ⑕࡜࡞ࡗ࡚࠸ࡓࠋ≉࡟ T ࣜࣥ
ࣃ⌫ࡢ⾑୰ᩘࡀ኱ࡁࡃῶᑡࡋࠊࣜࣥࣃ⌫ࡢ S1P ㄆ㆑ࡢ⬟ࡣṇᖖ࡛࠶ࡿ࡟ࡶ࠿࠿ࢃࡽࡎࠊ⬚⭢࠿ࡽࡢ T ࣜ
ࣥࣃ⌫ࡢ⾑୰࡬ࡢ⛣⾜ࡀ㜼ᐖࡉࢀ࡚࠸ࡓࠋS1P ࡢ㍺㏦య࡛࠶ࡿ SPNS2 ࡢᶵ⬟ࡀࣜࣥࣃ⌫ࡢ㐟㉮࡟㛵ࢃࡿ
S1P ࡢ౪⤥࡟࠶ࡿࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡗࡓࠋࡇࡢࡇ࡜ࡣࡇࢀࡲ࡛⾑ᾮ୰ࡢ S1P ࡢ୺せ࡞౪⤥※࡛࠶ࡿ࡜⪃
࠼ࡽࢀ࡚࠸ࡓ㉥⾑⌫࡟ࡼࡿ⾑ᾮ඲యࡢ S1P ⃰ᗘ࡛ࡣ࡞ࡃࠊࣜࣥࣃ⌫࡞࡝ࡀ⾑⟶ෆ࡟ฟ࡚ࡇࡼ࠺࡜ࡍࡿ㒊
఩࡟Ꮡᅾࡍࡿ⾑⟶ෆ⓶⣽⬊ࡢᒁᡤⓗ࡞ S1P ౪⤥ࡀࣜࣥࣃ⌫ࡢ⾑ᾮ୰࡬ࡢ⛣⾜ࢆㄪ⠇ࡋ࡚࠸ࡿࡇ࡜ࢆ♧ࡋ
࡚࠾ࡾࠊࡇࡢ㍺㏦యࢆᶆⓗ࡜ࡋࡓ๪స⏝ࡢᑡ࡞࠸ච␿ᢚไ๣ࢆ㛤Ⓨ࡛ࡁࡿྍ⬟ᛶࢆ♧၀ࡋ࡚࠸ࡿࠋ
ࡲࡓᮏᖺᗘࡣࠊSPNS2 ࡟ࡣࡑࡢ N ᮎ➃ࡀḞᦆࡋࡓ࢔࢖ࢯࣇ࢛࣮࣒㸦SPNS2-S1㸧ࡀᏑᅾࡍࡿࡇ࡜ࢆぢ
࠸ࡔࡋࡓࠋࡇࡢ࢔࢖ࢯࣇ࢛࣮࣒ࡣᑠ⭠࡞࡝࡟ከࡃⓎ⌧ࡋ࡚࠸ࡿࡀࠊ⣽⬊⭷࡛ࡣ࡞ࡃ⣽⬊ෆࡢᑠ⬊࡟ᒁᅾ
ࡍࡿࡇ࡜࡛ࠊ⣽⬊እ࡬ࡢ S1P ࡢᨺฟ࡟ࡣ㛵୚ࡋ࡚࠸࡞࠸ࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
࣭ࢫࣇ࢕ࣥࢦࢩࣥ 1 ࣜࣥ㓟㍺㏦య㜼ᐖ๣ࢫࢡ࣮ࣜࢽࣥࢢ⣔ࡢᵓ⠏
SPNS2 ㍺㏦యࡢᶵ⬟ࢆ㜼ᐖࡍࡿࡇ࡜࡛๪స⏝ࡢᑡ࡞࠸᪂ࡋ࠸ච␿ᢚไ๣ࡢ᥈⣴ࢆ┠ᣦࡋࠊ㜼ᐖ๣ࡢ
ࢫࢡ࣮ࣜࢽࣥࢢ⣔ࡢᵓ⠏ࢆ㐍ࡵࡓࠋࡇࢀࡲ࡛࡟ᵓ⠏ࡋࡓ S1P ㍺㏦యࡢάᛶ ᐃ⣔ࡣ[3H]S1P ࡞࡝ࡢᨺᑕ
ᛶྠ఩ඖ⣲ᶆ㆑యࡸ᭷ᶵᢳฟࡢᚋ࡟⺯ගᶆ㆑ࡋ HPLC ࡛ศᯒࡍࡿ᪉ἲࡸ㉁㔞ศᯒᶵࢆ⏝࠸ࡿ᪉ἲ࡛࠶ࡾࠊ
ከ᳨యࢆ▷᫬㛫࡛ ᐃࡍࡿࡢ࡟ࡣࢥࢫࢺࡸᡭ㛫ࡢⅬ࠿ࡽ㐺ࡋ࡚࠸࡞࠸ࠋࡑࡇ࡛࠶ࡽ࠿ࡌࡵ⺯ගᶆ㆑ࡋࡓ
ᇶ㉁ࢆྲྀࡾ㎸ࡲࡏᇵᆅ୰࡟ᨺฟࡉࢀࡓ⺯ගᶆ㆑యࢆ┤᥋ ᐃࡍࡿ⣔ࡢ☜❧ࢆ┠ᣦࡋࡓࠋ᫖ᖺᗘࡲ࡛࡟⺯
ගᶆ㆑ S1P ࡣᇵ㣴⣽⬊㸦CHO ࡸ 293 ⣽⬊㸧࡛ࡣඖࠎᏑᅾࡋ࡚࠸ࡓከ๣᤼ฟ㍺㏦యࡢᇶ㉁࡜࡞ࡗ࡚ S1P
㍺㏦య࡜ࡣ㛵ಀ࡞ࡃᨺฟࡉࢀࡿࡀࠊ⾑୰࡛ࡢ S1P ࡢᜏᖖᛶ⥔ᣢ࡟ാࡃ㉥⾑⌫࠿ࡽࡢ⺯ගᶆ㆑ S1P ࡢᨺฟ
ࡀࠊS1P ᨺฟࢆ㜼ᐖࡍࡿ glyburide ࡟ࡼࡗ࡚㜼ᐖࡉࢀࡿࡇ࡜ࢆぢ࠸ࡔࡋࡓࠋᮏᖺᗘࡣ㉥⾑⌫࡟࠾࠸࡚ࡣ
S1P ࡜⺯ගᶆ㆑ S1P ࡀྠࡌ㍺㏦యࢆ⏝࠸࡚᤼ฟࡉࢀࡿࡇ࡜ࢆ➇ྜᐇ㦂࡞࡝࡟ࡼࡾ᫂ࡽ࠿࡟ࡋࡓࠋࡉࡽ࡟ࠊ
㜼ᐖ๣ࢫࢡ࣮ࣜࢽࣥࢢࡢࡓࡵ࡟ࠊࡇࡢᨺฟάᛶࡢ㸷㸴✰࣐࢖ࢡࣟࣉ࣮ࣞࢺࢆ⏝࠸ࡓ᳨ฟࢆྍ⬟࡟ࡋࡓࠋ
ࡲࡓࠊᇵ㣴⣽⬊ࢆ⏝࠸ࡓ SPNS2 ౫Ꮡⓗ࡞ S1P ᨺฟࡢ᳨౽࡞᳨ฟࡢࡓࡵ࡟ࠊ
᪂ࡋ࠸ࣉ࣮ࣟࣈ࡜ࡋ࡚ Alkynࢫࣇ࢕ࣥࢦࢩࣥࡢྜᡂࢆ㜰኱⏘◊ࡢຍ⸨ᩍᤵࡢࢢ࣮ࣝࣉ࡜㐍ࡵࠊỈ⁐ᾮ୰࡛࠶ࢀࡤ⺯ගࢆ⏝࠸࡚ȣM ⛬
ᗘࡢ᳨ฟឤᗘ᳨࡛ฟ࡛ࡁࡿࡇ࡜ࢆぢ࠸ࡔࡋࡓࠋ௒ᚋࡣࠊࡇࢀࡽࡢ⣔ࢆᐇ㝿ࡢ S1P ㍺㏦㜼ᐖ๣ࡢ᥈⣴࡟⏝
࠸ࡽࢀࡿࡼ࠺࡟ᨵⰋࢆ㐍ࡵࡿ࡜࡜ࡶ࡟ࠊ㜼ᐖ๣ࡢࢫࢡ࣮ࣜࢽࣥࢢ࡟ࡼࡿ᪂ࡋ࠸⸆ࡢ㛤Ⓨࢆ┠ᣦࡍࠋ
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⏕యศᏊᶵ⬟⛉Ꮫ◊✲ศ㔝
ᩍᤵ
Ọ஭ ೺἞
෸ᩍᤵ
ᯇ⏣ ▱ᕫ
ຓᩍ
᪂஭ ⏤அࠊ୰㔝 㞞⿱
≉௵෸ᩍᤵ
࿴ἑ 㕲୍
≉௵ຓᩍ
ᒾ㔝 ᝴
≉௵◊✲ဨ
Perez Koldenkova Vadimࠊྜྷ⏣ 㑥ேࠊⓑ ㈗⵷
JSPS እᅜே≉ู◊✲ဨ
Tiwari Dhermendra Kumar
JST ࡉࡁࡀࡅ◊✲ဨ
ᥭጔ ṇ࿴
኱Ꮫ㝔Ꮫ⏕
㕥ᮌ ࿴ᚿࠊ⚟⏣ ᠇㝯ࠊ✄ᇉ ᡂ▴ࠊᕝୖ ⚈ྖࠊ㟷ᰗ ὒᖹࠊ⠛⏣ ⫕ࠊ
㧗ෆ ኱㈗ࠊJenny Rose Cruz TrinidadࠊThitikorn Phanuprayoon
Ꮫ㒊Ꮫ⏕
ⰱ㇂ ⯙ࠊୡᡞ ⰋᏊ
◊✲⏕
Nadim MD. Hossain
ᢏ⾡⿵బဨ
ஂᐩ ᩥ㸦ᖹᡂ 26 ᖺ 9 ᭶ 1 ᪥᥇⏝㸧
஦ົ⿵బဨ
㓇஭ ࿴௦
a) ᴫせ
⏕࿨⌧㇟ࡢᮏ㉁ࡢ୍ࡘ࡜ࡋ࡚ࠊᣦᢡࡾᩘ࠼ࡿࡇ࡜ࡀฟ᮶ࡿ⛬ᗘࡢᑡᩘࡢせ⣲ศᏊ࠿ࡽᵓᡂࡉࢀࡿࢼࣀ
ࢩࢫࢸ࣒ࡀ͆༠ྠⓗ͇࡟ᶵ⬟࣭ືసࡍࡿࡇ࡜ࡀᣲࡆࡽࢀࡿࠋࡇࢀࡲ࡛͆࢔࣎࢞ࢻࣟᩘ͇⛬ᗘࡢࢱࣥࣃࢡ
㉁ࡢ཯ᛂࡸ͆༢ศᏊ͇ࡢ⣲㐣⛬ࢆほᐹࡍࡿ 1 ศᏊ࢖࣓࣮ࢪࣥࢢ࡟ࡼࡿ཯ᛂゎᯒࡀᩘከࡃሗ࿌ࡉࢀ࡚ࡁࡓ
ࡀࠊ
͆ᑡᩘศᏊ͇ࡢᶵ⬟ືែࢆࠊ⏕ࡁࡓ⣽⬊ෆ࡟࠾࠸࡚ゎᯒࡋࡓ౛ࡣ࡯࡜ࢇ࡝↓࠸ࠋ⏕యศᏊᶵ⬟⛉Ꮫ
◊✲ศ㔝࡛ࡣࠊ㉸ゎീศᏊィᩘ໬ࠊศᏊᶵ⬟ࡢྍど໬࣭᧯సࢆྍ⬟࡜ࡍࡿᢏ⾡ࢆ๰ฟࡋࠊᑡᩘせ⣲ศᏊ
ࡀዴఱ࡟ࡋ࡚ࠊ⣽⬊ᶵ⬟ࡢ㡹೺ᛶࡸ㐺ᛂᛶࢆ๰Ⓨࡍࡿࡢ࠿࡟࢔ࣉ࣮ࣟࢳࡍࡿࠋ
b) ᡂᯝ
࣭㟷⥳㸦ࢩ࢔ࣥ㸧Ⰽ࠾ࡼࡧ࢜ࣞࣥࢪⰍࡢ㉸㧗ගᗘⓎගࢱࣥࣃࢡ㉁ࡢ㛤Ⓨ
2012 ᖺ࡟㛤Ⓨࡋࡓ㯤⥳Ⰽࡢ㉸㧗
ගᗘⓎගࢱࣥࣃࢡ㉁ Nano-lantern
㸦ࢼࣀ࣭ࣛࣥࢱࣥ㸧ࢆᨵⰋࡋ࡚ࠊ
ࡉࡽ࡟᫂ࡿࡃගࡿ㟷⥳(ࢩ࢔ࣥ)Ⰽ
࠾ࡼࡧ࢜ࣞࣥࢪⰍࡢ㉸㧗ගᗘⓎග
ࢱࣥࣃࢡ㉁ࡢ㛤Ⓨ࡟ᡂຌࡋࡓࠋ࠸
ࡎࢀࡶᚑ᮶ࡢⓎගࢱࣥࣃࢡ㉁ࡢ 20
ಸ⛬ᗘ᫂ࡿࡃගࡿࡓࡵࠊ≉Ṧ࡞㉸
㧗ឤᗘ࣓࢝ࣛࢆ౑ࢃ࡞ࡃ࡜ࡶࠊ⫗
║ࡸࢫ࣐࣮ࢺࣇ࢛ࣥࡢ࣓࡛࢝ࣛࡑ
ࡢ Ⓨගࢆ ほᐹࡍ ࡿࡇ ࡜ࡀ ฟ᮶ ࡿ
ᅗ 13 Ⰽࡢ㉸㧗㍤ᗘⓎගࢱࣥࣃࢡ㉁ࢼࣀ࣭ࣛࣥࢱࣥ
㸦ᅗ 1㸧
ࠋ3 ⰍࡢⰍ㐪࠸ࡢࢼࣀ࣭ࣛ
A⢭〇ࡋࡓ 3 Ⰽࡢࢼࣀ࣭ࣛࣥࢱࣥࠋᐙᗞ⏝ࡢ㏻ᖖࡢࢹࢪࢱࣝ㺃࣓࡛࢝ࣛ᧜ᙳࠋ
ࣥࢱࣥࡀ᏶ᡂࡋࡓࡇ࡜࡟ࡼࡾࠊ⣽
B3 Ⰽࡢࢼࣀ࣭ࣛࣥࢱࣥ࠾ࡼࡧᚑ᮶ࡢࣝࢩࣇ࢙࣮ࣛࢮࡢⓎගࢫ࣌ࢡࢺࣝࡢẚ㍑
⬊ෆࡢᚤ⣽࡞ᵓ㐀ࡢືែࡸ㑇ఏᏊ
ࡢⓎ⌧ࢆ」ᩘྠ᫬࡟ィ ࡍࡿࡇ࡜
ࡀึࡵ࡚ྍ⬟࡜࡞ࡾࠊ୓⬟⣽⬊(ES ⣽⬊)ࡢ୓⬟ᛶ⥔ᣢ࡟㔜せ࡞ 3 ࡘࡢ㑇ఏᏊࡢⓎ⌧ࡢᵝᏊࢆྠ᫬࡟ほᐹ
ࡍࡿࡇ࡜࡟ୡ⏺࡛ึࡵ࡚ᡂຌࡋࡓ㸦ᅗ 2㸧
ࠋ୓⬟⣽⬊ࡢ◊✲࡛ࡣࠊ⺯ගࢱࣥࣃࢡ㉁ࢆ⏝࠸ࡿ㝿ࡢ⮬ᐙ⺯ග
ࡸගẘᛶࡢᙳ㡪ࡀၥ㢟࡜࡞ࡗ࡚࠸ࡓࠋࢼࣀ࣭ࣛࣥࢱࣥࡣࠊእ㒊࠿ࡽࡢບ㉳ගࢆᚲせ࡜ࡋ࡞࠸ࡓࡵࠊ⮬ᐙ
― 76 ―
⺯ගࡸගẘᛶࡢᙳ㡪ࢆ඲ࡃཷࡅ࡞࠸ࠋᚑࡗ࡚ࠊ෌⏕་⒪ࡢ◊✲࡟࠾࠸࡚኱ࡁ࡞㈉⊩ࡀᮇᚅࡉࢀࡿࠋࡉࡽ
࡟ࠊࢼࣀ࣭ࣛࣥࢱࣥࢆᨵኚࡋ࡚⣽⬊ෆ࢝ࣝࢩ࣒࢘࢖࢜ࣥࢆ᳨ฟ࡛ࡁࡿࢩ࢔ࣥ࠾ࡼࡧ࢜ࣞࣥࢪⰍࡢⓎගᣦ
♧⸆ࡢ㛤Ⓨ࡟ᡂຌࡋࡓ㸦ᅗ 3㸧
ࠋࡇࢀࡽࡢⓎගᣦ♧⸆ࡣࠊእ㒊࠿ࡽࡢ↷᫂ගࢆᚲせ࡜ࡏࡎ⮬ࡽⓎගࡍࡿࡓ
ࡵࠊග࡛⣽⬊ࡢάືࡸࢱࣥࣃࢡ㉁ࡢᶵ⬟ࢆไᚚࡍࡿග㑇ఏᏛⓗᢏ⾡࡜ࡢ⤌ࡳྜࢃࡏࡀᐜ࡛᫆࠶ࡿࠋ⚄⤒
άືࡢ᧯స࡜ィ ࢆྠ᫬࡟⾜࠺ࡇ࡜ࡀྍ⬟࡜࡞ࡾࠊ⬻ࡢ࣓࢝ࢽࢬ࣒ࡢ◊✲࡬ࡢᛂ⏝ࡀᮇᚅࡉࢀࡿࠋ⺯ග
ࢱࣥࣃࢡ㉁ࡣࠊ᭱ึࡢ⥳Ⰽ࠿ࡽࠊ㟷⥳Ⰽࠊ⥆࠸࡚࢜ࣞࣥࢪ㹼㉥Ⰽ࡜ 3 Ⰽᥞ࠺ࡇ࡜࡛ᛴ㏿࡟ᛂ⏝ࡀᣑ኱ࡋ
ࡓࠋ⺯ගࢱࣥࣃࢡ㉁࡟ẚ⫪ࡋ࠺ࡿ᫂ࡿࡉ࡛ගࡿ㉸㧗ගᗘⓎගࢱࣥࣃࢡ㉁ࢼࣀ࣭ࣛࣥࢱࣥࡀ㟷⥳Ⰽࠊ㯤⥳
Ⰽࠊ࢜ࣞࣥࢪⰍ࡜ 3 Ⰽᥞࡗࡓࡇ࡜࡛ࠊྠᵝ࡟฼ά⏝ࡀ㐍ᒎࡍࡿࡶࡢ࡜ᮇᚅࡉࢀࡿࠋ
ᅗ 3 2 Ⰽࡢࢼࣀ࣭ࣛࣥࢱࣥࢆ⏝࠸ࡓ⣽⬊ෆ࢝ࣝࢩ࣒࢘࢖࢜ࣥືែィ A: ⣽⬊ෆ࢝ࣝࢩ࣒࢘࢖࢜ࣥࢆ ᐃ࡛ࡁࡿࢩ࢔ࣥⰍ࡜࢜ࣞࣥࢪⰍࡢࢼࣀ࣭ࣛࣥ
ᅗ 2 ࢼࣀ࣭ࣛࣥࢱࣥࢆ⏝࠸ࡓⓎග࢖࣓࣮ࢪࣥࢢ
ࢱࣥࢆࡑࢀࡒࢀ࣑ࢺࢥࣥࢻࣜ࢔࡜᰾࡟Ⓨ⌧ࡉࡏࡓ HeLa ⣽⬊
࡟ࡼࡿ㑇ఏᏊⓎ⌧ゎᯒ
B: ࣑ࢺࢥࣥࢻࣜ࢔㸦A ࡢ㡿ᇦ 1㸧࡜᰾㸦A ࡢ㡿ᇦ 2㸧࡛ࡢⓎගᙉᗘࡢ᫬㛫ኚ໬
࣭⺯ගࢱࣥࣃࢡ㉁ࢆ⏝࠸ࡓ⣽⬊ෆ㓟໬㑏ඖ≧ែࢆྍど໬ࡍࡿ᪂つࣉ࣮ࣟࣈࡢ㛤Ⓨ
⣽⬊ෆࡢ㓟໬㑏ඖ≧ែࡣࠊάᛶ㓟⣲
✀ࡢ⏘⏕࡞࡝ࡢᵝࠎ࡞௦ㅰ㓝⣲ࡢάᛶ
ࢆㄪ⠇ࡍࡿ⣽⬊ᶵ⬟࡟㔜せ࡞せᅉ࡛ࡍࠋ
ࡇࢀࡲ࡛⏕ࡁࡓ⣽⬊ࡢ㓟໬㑏ඖ≧ែࢆ
ྍど໬ࡍࡿࡓࡵ࡟ roGFP ࡸ Redoxfluor
࡞࡝ࡢ㑇ఏⓗ࡟ࢥ࣮ࢻࡉࢀࡓ⺯ගᛶࣞ
ࢻࢵࢡࢫࢭࣥࢧ࣮ࡀ㛤Ⓨࡉࢀ࡚ࡁࡓࠋ
ࡋ࠿ࡋࠊࡇࢀࡽࡢࢭࣥࢧ࣮ࡣ⥳Ⰽࡢ⺯
ගࢆⓎࡍࡿࡓࡵࠊᚑ᮶᭱ࡶከࡃ㛤Ⓨࡉ
ࢀ࡚࠸ࡿ௚ࡢ⥳ࡢ⺯ගࢆⓎࡍࡿࢭࣥࢧ
࣮ࡸ CFP/YFP ࡢ FRET ࢭࣥࢧ࣮࡞࡝࡜
ే⏝ࡍࡿࡇ࡜ࡣ㞴ࡋ࠸ࠋࡑࡇ࡛ᡃࠎࡣࠊ
௚ࡢⰍࡢࣞࢻࢵࢡࢫࢭࣥࢧ࣮ࢱࣥࣃࢡ
㉁ ࡛ ࠶ ࡿ ࠊ Oba-Q (oxidation balance
sensed quenching) ࢱࣥࣃࢡ㉁࡜࿧ࡤࢀ
ࡿ⣽⬊ࡢ㓟໬≧ែࢆྍど໬ࡍࡿ⺯ගࢱ
ᅗ 4 Oba-Q ࢱࣥࣃࢡ㉁ࡢ⣽⬊ෆ࡛ࡢ཯ᛂ
ࣥࣃࢡ㉁ࢆ㛤Ⓨࡋࡓࠋ ࡇࡢ CFP ཬࡧ
A: Oba-Q ࢱࣥࣃࢡ㉁ࢆⓎ⌧ࡋࡓ HeLa ⣽⬊ෆࡢ㓟໬㑏ඖ≧ែࢆኚ໬ࡉࡏࡓ࡜
Sirius ⏤᮶ࡢࢭࣥࢧ࣮ࢱࣥࣃࢡ㉁ࡣࠊ⣽
ࡁࡢ⺯ග⏬ീ
⬊ෆࡀ㓟໬≧ែ࡟࡞ࡿ࡜⺯ගᙉᗘࡀῶ
B: A ࡢ⏬ീࡢ⺯ගᙉᗘࡢ᫬⣔ิኚ໬㸦㯮▮༳࡛㓟໬๣ H2O2ࠊⓑᢤࡁ▮༳࡛㑏
ᑡࡍࡿࠋࡇࢀࡽࡢ Oba-Q ࢱࣥࣃࢡ㉁ࡣ
⩌㟷ཬࡧࢩ࢔ࣥⰍࡢ⺯ගࢆⓎࡍࡿࡓࡵࠊ ඖ๣ DTT ࢆࡑࢀࡒࢀ⣽⬊࡟ῧຍࡋࡓ㸧
ᚑ᮶ࡢ௚ࡢⰍࡢࢭࣥࢧ࣮ࢱࣥࣃࢡ㉁࡜
ే⏝࡛ࡁࠊᵝࠎ࡞ᅉᏊ࡜୍⥴࡟⣽⬊ࡢ㓟໬㑏ඖ≧ែࢆࣔࢽࢱ࣮࡛ࡁࡿࡼ࠺࡟࡞ࡗࡓࠋ
― 77 ―
᪂⏘ᴗ๰ᡂ◊✲㒊㛛
ᴫせ
ᮏ◊✲㒊㛛ࡣࠊᖹᡂ 18 ᖺᗘ 10 ᭶࡟タ⨨ࡉࢀࠊ᪂⏘ᴗண ◊✲ศ㔝࣭᪂⏘ᴗ๰㐀ࢩࢫࢸ࣒◊✲ศ㔝࣭
▱ⓗ㈈⏘◊✲ศ㔝ࡢ 3 ࡘࡢ◊✲ศ㔝࡛ᵓᡂࡉࢀ࡚࠸ࡿࠋᮏ㒊㛛ࡣࠊ⏘◊ࡢᣢࡘ⏘ᴗ⏺࡜ࡢᐦ᥋࡞㐃ᦠࡢ
ఏ⤫ࢆ⏕࠿ࡋࠊ21 ୡ⣖ࡢ⛉Ꮫᢏ⾡࣭⏘ᴗᢏ⾡ࡢⓎᒎࢆඛᑟࡍࡿඛ➃ⓗᛂ⏝◊✲࡟ྲྀࡾ⤌ࡳࠊᡂᯝࡢ♫఍
࡬ࡢ㑏ඖ࡟㛵ࡍࡿ┠ᶆࢆ㐩ᡂࡍࡿࡓࡵࡢලయⓗ᪉⟇࡜ࡋ࡚ࠕ◊✲ᡂᯝࢆ᪂⏘ᴗࡢ๰ᡂ࡟⤖ࡧࡘࡅࡿ◊
✲ࠖࢆ⾜ࡗ࡚࠸ࡃ◊✲㒊㛛࡛ࠊ3 ࡘࡢ◊✲ศ㔝ࡢ◊✲ෆᐜࡣ௨ୗࡢ㏻ࡾ࡛࠶ࡿࠋ
࣭᪂⏘ᴗண ◊✲ศ㔝㸸௒ᚋ㐍ࡵࡿ࡭ࡁ◊✲᪉ྥ࡟ᐦ᥋࡟㛵㐃ࡍࡿᮍ᮶♫఍ࡢ⏘ᴗண ࡟㛵ࡍࡿ◊✲ࢆ
⾜࠺ࠋ
࣭᪂⏘ᴗ๰㐀ࢩࢫࢸ࣒◊✲ศ㔝㸸኱Ꮫࡢᇶ♏◊✲ࢆຠ⋡ࡼࡃ㎿㏿࠿ࡘ☜ᐇ࡟᪂⏘ᴗ࡟⤖ࡧࡘࡅࡿᇶᮏⓗ
ࢩࢫࢸ࣒ࡢᵓ⠏࡟㛵ࡍࡿ◊✲ࢆ⾜࠺ࠋ
࣭▱ⓗ㈈⏘◊✲ศ㔝㸸኱Ꮫࡢ⊂๰ⓗ࡞ᇶ♏◊✲࠿ࡽຠ⋡ࡼࡃ▱ⓗ㈈⏘ࢆ๰ฟࡋࠊ᪂ࡋ࠸₯ᅾࢽ࣮ࢬ࡟⧅
ࡀࡿά⏝࡟ྥࡅࡓ▱㈈ᡓ␎࡟㛵ࡍࡿ◊✲ࢆ⾜࠺ࠋ
᪂⏘ᴗ๰ᡂ◊✲㒊㛛࡛ࡣࠊ኱Ꮫࡢ◊✲ᡂᯝࡢ♫఍㑏ඖࡢ㐍ᒎࠊ㎿㏿࡞௻ᴗ໬ࠊ〇ရ໬࡟ࡼࡾᣢ⥆ⓗ࡞
⤒῭ⓎᒎࡸᅜẸ⏕άࡢྥୖࡀᮇᚅ࡛ࡁࡿ◊✲ࡢ᭦࡞ࡿᒎ㛤ࢆᅗࡿ◊✲ࢆ⾜ࡗ࡚࠸ࡃணᐃ࡛࠶ࡿࠋ
― 78 ―
᪂⏘ᴗ๰㐀ࢩࢫࢸ࣒◊✲ศ㔝
≉௵ᩍᤵ
ᑠ಴ ᇶḟ
a) ᴫせ
኱㜰኱Ꮫ⏘ᴗ⛉Ꮫ◊✲ᡤ㸦ᡤ㛗 ඵᮌᗣྐᩍᤵ㸧ࡣࠊH24 ᖺᗘ࡟᥇ᢥࡉࢀࡓ JSPS 㢌⬻ᚠ⎔(Brain
Circulation)ࣉࣟࢢ࣒ࣛࠊཬࡧ JSPS ᣐⅬᙧᡂ஦ᴗ(Core to core)ࣉࣟࢢ࣒ࣛࢆᐇ⾜ࡋࡓࠋ
7 ᭶࡟ࡣᣐⅬᙧᡂ஦ᴗࡢḢᕞᣐⅬࡢ୍ࡘ࡛࠶ࡿ࢜ࢵࢡࢫࣇ࢛࣮ࢻ኱࡟࡚ࢭ࣑ࢼ࣮ࢆ㛤ദࠊ12 ᭶࡟ࡣࠊ
኱㜰ࢢࣛࣥࣇࣟࣥࢺ࡟࡚ࠊ➨ 2 ᅇᣐⅬᙧᡂ஦ᴗࣉࣟࢢ࣒ࣛ఍㆟ࠊཬࡧ௒ᖺᗘ࡛⤊஢࡜࡞ࡿ➨ 3 ᅇ㢌⬻ᚠ
⎔ࣉࣟࢢ࣒ࣛ఍㆟(/➨ 3 ᅇ imec Handai symposium)ࢆ㛤ദࡋࠊ඲యࡢ㐍ᤖ≧ἣࢆඹ᭷ࡋࡓࠋ
ే⾜ࡋ࡚ࠊ኱㜰኱Ꮫ COI ࡣࠊ23 ♫ࠊ9 ◊✲ᶵ㛵࡜ඹྠ◊✲ዎ⣙ࢆ⥾⤖ࡋࠊࠕே㛫ຊάᛶ໬࡟ࡼࡿࢫ࣮
ࣃ࣮᪥ᮏேࡢ⫱ᡂࠖᣐⅬ࡜ࡋ࡚ࠊunder one roof ࡢୗࠊඹྠ◊✲ࢆ㛤ጞࠊ7 ᭶࡟࢟ࢵࢡ࢜ࣇ఍㆟(බ㛤)ࠊ
11 ᭶࡟ࡣ➨ 2 ᅇ㜰኱ COI ࣮࣡ࢡࢩࣙࢵࣉ(බ㛤)ࠊ3 ᭶࡟ࡣ H26 ᖺᗘᡂᯝሗ࿌఍ࢆ㛤ദࡋࠊᙜึࡢ┠ᶆ௨
ୖࡢᡂᯝࢆᚓࡓࠋ
b) ᡂᯝ
࣭-636 ᣐⅬᙧᡂ஦ᴗ&RUHWRFRUHࣉࣟࢢ࣒ࣛࡢ 2[IRUG ኱Ꮫࢭ࣑ࢼ࣮ࢆ㛤ദ
Oxford Workshop ࡀࠊprofs. Sonia Contera, and Sonia Trigueros ࡢ local committee ࡢୗࠊ7 ᭶ 24 ᪥ࠊ25 ᪥ࠊ
Martin School, The University of Oxford ࡛㛤ദࡉࢀࡓࠋࡇࡢ࣮࣡ࢡࢩࣙࢵࣉ࡛ࡣྜィ 15 ௳ࡢⓎ⾲ࡀ࠶ࡾࠊ
ඹྠ◊✲ศ㔝ࡣ imec Healthcare devices, CNT drug safety screening, Biosensing nontoxicity, Graphene FETs,
biosensors, flexible and stretchable technologies(UTCP, OTC), organic semiconductor devices ࡜ከᒱ࡟Ώࡗࡓࠋ
࡜ࡾࢃࡅ⯆࿡῝࠸ᡂᯝࡣ prof. Yulin Chen, Univ. Oxford ࡟ࡼࡿ Bi2Te3 , Bi2Se3 topological quantum
insulators ࡛⇕࡛ఏᑟᛶࢆᣢࡘࡇ࡜࡟࡞ࡿࠋ ⏘◊⬟ᮌඛ⏕࠿ࡽࡣ 15-50nm diameter transparent nanofiber
paper ≉ᛶホ౯ࡀᚓࡽࢀࡓࠋࢺ࣮ࢱࣝཧຍ⪅ࡣࡑࢀࡒࢀ 27 ྡ(7/24), 21 ྡ(7/25)࡛࠶ࡗࡓࠋ
Sonia Kontera ࡟ࡼࡿ࢚࣒࣮࢘ࣝ࢝࣡ࢻ Oxford workshop ࢫࢼࢵࣉ Oxford Martin School ࡛ࡢ㞟ྜ෗┿
࣭➨ 2 ᅇᣐⅬᙧᡂ஦ᴗࣉࣟࢢ࣒ࣛ఍㆟ࠊཬࡧ௒ᖺᗘ࡛⤊஢࡜࡞ࡿ➨ 3 ᅇ㢌⬻ᚠ⎔ࣉࣟࢢ࣒ࣛ఍㆟(/➨ 3
ᅇ imec Handai symposium)ࢆ㛤ദ
12/12(㔠)ࠊ኱㜰ࢢࣛࣥࣇࣟࣥࢺෆᅜ㝿఍㆟ሙ࡟࡚ࠊ➨ 2 ᅇᙧᡂ஦ᴗࣉࣟࢢ࣒ࣛ఍㆟ࠊཬࡧ➨ 3 ᅇ㢌⬻
ᚠ⎔ࣉࣟࢢ࣒ࣛ(➨ 3 ᅇ imec Handai symposium)ࡀࠊJo De Boeck imec CTO&senior vice president, Chris Van
Hoof imec fellow, Max Planck Mainz lab.ࡢ Paul Blom professor & director, Oxford univ. Sonia Contera
professor ௚ࡀཧຍࡋ࡚ࠊ㛤ദࡉࢀࡓࠋࡑࢀࡒࢀࡢཧຍ⪅ࡣእᅜᅜ⡠ 22 ྡࢆྵࢇ࡛ࠊࢺ࣮ࢱࣝ 38 ྡࠊ41
ྡ࡛࠶ࡗࡓࠋෆᐜⓗ࡟ࡣᣐⅬᙧᡂࣉࣟࢢ࣒࡛ࣛࡣࠊbio electronics, organic electronics ࡀ୰ᚰ࡛ 8 ௳ࠊ㢌⬻
ᚠ⎔ࣉࣟࢢ࣒ࣛ఍㆟࡛ࡣࠊflexible, organic, bioe-electronics/life science ศ㔝࡛ 6 ௳ࡢⓎ⾲ࡀ࠶ࡗࡓࠋ⏘◊
ࡢᙉຊ࡞ඹྠ◊✲ࣃ࣮ࢺࢼ࣮࡛࠶ࡿ imec ࡢከᩘࡢཧ⏬ᐤ୚ࡀ኱ࡁࡃࠊࡲࡓ୧ࣉࣟࢢ࣒࡛ࣛ imec 㥔ᅾ⤒
― 79 ―
㦂ࡢ࠶ࡿᏛ⏕ࠊຓᩍࡀཧ⏬ࡋࠊάⓎ࡞㆟ㄽࢆࡋ࡚࠸ࡓࡢࡀ༳㇟ⓗ࡛࠶ࡗࡓࠋImec ࡜ࡢ bilateral program
࡛࠶ࡿ㢌⬻ᚠ⎔ࣉࣟࢢ࣒ࣛࡣ H26 ᖺᗘ࡛⤊஢ࡔࡀࠊimec ࡜ࡢໟᣓඹྠ◊✲ዎ⣙(collaboration framework
agrrement)࡟ᇶ࡙ࡁࠊᘬࡁ⥆࠸࡚ᵝࠎ࡞ࢸ࣮࣐࡛ඹྠ◊✲ࢆ⥅⥆ࡍࡿࠋ
Jo De Boeck imec CTO& senior vice president ࡟ࡼࡿ welcome word, ఍㆟㢼ᬒ
ᾏእ࠿ࡽࡢᣍᚅㅮ₇⪅ࢆᅖࢇ࡛ࡢពぢ஺᥮఍
㞟ྜ෗┿
― 80 ―
▱ⓗ㈈⏘◊✲ศ㔝
≉௵ᩍᤵ㸦ව௵㸧
ᣍ࡬࠸ᩍᤵ
≉௵෸ᩍᤵ
≉௵ຓᩍ
ΎỈ
ᑠᯘ
ᕝୖ
ᮌᮧ
⿱୍
᫛㞝
ⱱᶞ
Ὀ⿱
a) ᴫせ
ᮦᩱ࣭᝟ሗ࣭⏕యศ㔝ࢆ⼥ྜࡋࡓ᪂ࡋ࠸⛉Ꮫᢏ⾡ศ㔝࡟࠾ࡅࡿ኱Ꮫࡢ⊂๰ⓗ࡞ᇶ♏◊✲࠿ࡽ⏕ࡲࢀࡿ
ከᒱ࡟ரࡿ▱ぢ࠿ࡽࠊຠ⋡ࡼࡃ▱ⓗ㈈⏘ࢆ๰ฟࡋά⏝ࡍࡿࡇ࡜ࡀồࡵࡽࢀ࡚࠸ࡿࠋᮏ◊✲ศ㔝࡛ࡣࠊ◊
✲㛤Ⓨ࡟࠾ࡅࡿ▱ⓗ㈈⏘ࡢ๰ฟࠊ▱ⓗ㈈⏘ࡢศᯒ࣭ホ౯ࠊά⏝ࢆຠ⋡ⓗ࡟⾜࠺᪉ἲࡸࣉࣟࢭࢫ➼࡟ࡘ࠸
࡚ࠊୡ⏺࡟ඛ㥑ࡅ࡚᪂ࡋ࠸₯ᅾࢽ࣮ࢬ࡟⧅ࡀࡿ▱㈈ᡓ␎ࡢ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋ
ࡲࡓࠊ5 ௳ࡢ᪂つእ㒊㈨㔠㸦ձ᪥ᮏᮭ௰◊✲఍࣭➨ 10 ᅇ◊✲ຓᡂࠊղ᪥ᮏᏛ⾡᣺⯆఍᳜≀ࣂ࢖࢜➨
160 ጤဨ఍࣭ᖹᡂ 26 ᖺᗘ⏘Ꮫ㐃ᦠάືᙉ໬ࣉࣟࢢ࣒ࣛࠊճᖹᡂ 25 ᖺᗘබເụ⏣Ἠᕞ㖟⾜ࠕࢥࣥࢯ࣮ࢩ
࢔࣒◊✲㛤Ⓨຓᡂ㔠ࠖࠊᖹᡂ 24 ᖺᗘ⿵ṇࠕࡶࡢ࡙ࡃࡾ୰ᑠ௻ᴗ࣭ᑠつᶍ஦ᴗ⪅ヨస㛤Ⓨ➼ᨭ᥼⿵ຓ㔠ࠖ
[մᰴᘧ఍♫ࢧ࣮ࣥ࣡ࢻၟ఍ࠊյ᪥᪂ᢏ◊ᰴᘧ఍♫]㸧࡜ࠊ2 ௳ࡢ⥅⥆እ㒊㈨㔠㸦᪥ᮏᮭ௰◊✲఍࣭➨ 8
ᅇ◊✲ຓᡂࠊཷク◊✲࣭⎔ቃ⏘ᴗ๰ฟ࡟㈨ࡍࡿ⣲ᮦ㛤Ⓨ࡜ࡑࡢά⏝࡟㛵ࡍࡿ◊✲㸧࡟ࡼࡾࠊᐇド◊✲ࢆ
ᐇ᪋ࡋࡓࠋ
b) ᡂᯝ
࣭≉チㄪᰝ࡟ࡼࡿ⏘Ꮫ㐃ᦠࣃ࣮ࢺࢼ࣮ࡢ᥈⣴ᡭἲࡢ◊✲
኱Ꮫࡢಖ᭷ࡍࡿ▱ⓗ㈈⏘ࡢά⏝ࢆಁ㐍ࡍࡿࡓࡵࠊ⏘ᴗ⏺࡜ࡢ࢔ࣛ࢖࢔ࣥࢫࡸඹྠ◊✲ࡢ┦ᡭࢆ≉チㄪ
ᰝ࡟ࡼࡗ࡚᥈⣴ࡍࡿᡭἲࡢ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋ≉チ᳨⣴ࢆ⏝࠸࡚ᑓ㛛࣭ᑓᴗᛶࡢ㧗࠸௻ᴗࢆ᥈⣴ࡍࡿᡭ
ἲࢆᐇ㝿ࡢලయⓗ◊✲஦౛࡟㐺⏝ࡋࠊࡇࡢ᪉ἲࡀᛂ⏝ᒎ㛤ࡢྍ⬟ᛶࡢ㧗࠸௻ᴗࢆぢฟࡍୖ࡛ࠊ᭷ຠ࡛࠶
ࡿࡇ࡜ࢆᐇドࡍࡿ◊✲ࢆ㐍ࡵࡓࠋ
࣭⏘Ꮫ㐃ᦠ࡟ࡼࡿ᪂つ◊✲ศ㔝ࡢᨭ᥼
௨ୗࡢ᪂つ஦ᴗศ㔝ࢸ࣮࣐࡟㛵ࡍࡿ⏘Ꮫ㐃ᦠ࡟ࡼࡿ◊✲㛤Ⓨ࠾ࡼࡧࡑࡢᨭ᥼ࢆ⾜ࡗࡓࠋ
ࠕኳ↛⣲ᮦࡢ௜ຍ౯್௜ࡅࢆྍ⬟࡜ࡍࡿ᪂せ⣲ᢏ⾡ࠖ㸦ඹྠ◊✲㸧
ࠕ⸆๣ࡢప௜╔ᛶࢆᐇ⌧ࡍࡿᡴ㘄㔠ᆺ〇㐀ᢏ⾡ࡢ◊✲㛤Ⓨࠖ㸦⿵㛫◊✲㸧
ࠕ࣮ࣞࢨ↷᫂ᢏ⾡ࡢ㛤Ⓨࠖ㸦NEDO ᡓ␎ⓗ┬࢚ࢿࣝࢠ࣮ᢏ⾡㠉᪂ࣉࣟࢢ࣒ࣛ㸧
࣭㒔ᕷᮍ฼⏝✵㛫ά⏝࡛͆ࡳ࡝ࡾࡢ㢼͇ࢆឤࡌࡿ኱㜰ࡘࡃࡾࢩ࣏ࣥࢪ࣒࢘ࡢ㛤ദ
ᖹᡂ 26 ᖺ 11 ᭶ 19 ᪥㸦Ỉ㸧࡟኱㜰኱Ꮫ୰அᓥࢭࣥࢱ࣮࡛ࠊ㒔
ᕷ⥳໬࡟㛵ࡍࡿࢩ࣏ࣥࢪ࣒࢘ࢆ㛤ദࡋࡓ㸦ඹദ㸸୍⯡㈈ᅋἲே኱
㜰኱Ꮫ⏘ᴗ⛉Ꮫ◊✲༠఍ࠊ୍⯡♫ᅋἲேࢸࣛࣉࣟࢪ࢙ࢡࢺࠊᆅ᪉
⊂❧⾜ᨻἲே኱㜰ᗓ❧⎔ቃ㎰ᯘỈ⏘⥲ྜ◊✲ᡤ㸧ࠋᕷẸࡀవᬤ᫬
㛫ࢆ౑࠸ࠊ㒔ᕷࡢవ๫✵㛫ࢆά⏝ࡋ㒔ᕷ⥳໬ࠊ㒔ᕷ㎰ᴗ࡜࠸࠺᪂
ࡋ࠸⏘ᴗࢆ๰ฟࡍࡿ㊃᪨࡛ࠊ኱ᡭ௻ᴗ 10 ♫࡟ࡼࡿ㎰ᴗ࣭⎔ቃࣅ
ࢪࢿࢫࡢ⌧ἣሗ࿌ࠊዪᛶࡢཧ୚࡟ࡼࡿࢯ࣮ࢩࣕࣝࢿࢵࢺ࣮࣡ࢡ࣭
ࣅࢪࢿࢫࢆά⏝ࡋࡓ㎰ᴗᒎ㛤࡟ࡘ࠸࡚ࡢάⓎ࡞㆟ㄽࡀ࠶ࡾࠊవᬤ
ᆺ㎰ᴗࡢྍ⬟ᛶࡀᙉࡃ♧၀ࡉࢀࡓࠋᐃဨ 200 ྡࡢ࡜ࡇࢁ❧ࡕぢࢆ
㒔ᕷ⥳໬䛻㛵䛩䜛䝅䞁䝫䝆䜴䝮㛤ദ㻌
ྵࡵ࡚ 250 ྡࢆ㉸࠼ࡿཧຍ⪅ࡀ࠶ࡾࠊ♫఍ࢆኚ㠉ࡉࡏࡿ㒔ᕷ⥳໬
᥎㐍࡟ࡣࠊᐁබᗇ࠿ࡽࢺࢵࣉࢲ࢘ࣥᆺࡢⓎಙ࡟ຍ࠼ࠊ௻ᴗࡸᕷẸࡀせᮃࢆᙧ࡟ࡋ࡞ࡀࡽࢿࢵࢺ࣮࣡ࢡࢆ
ᗈࡆ࡚⾜ࡃ࣎ࢺ࣒࢔ࢵࣉᆺࡢ᝟ሗⓎಙࡢᚲせᛶࡀ☜ㄆࡉࢀࡓࠋ
― 81 ―
࣭ኳ↛⣲ᮦࡢ௜ຍ౯್௜ࡅࢆྍ⬟࡜ࡍࡿ᪂せ⣲ᢏ⾡
㣗ရ㛤Ⓨ◊✲࡜ࡋ࡚ࠊ኱㜰ྡ≀ࡢ⢖࠾ࡇࡋ㸦࠸ࢃ࠾ࡇࡋ㸧ࡢ௜ຍ౯್ࢆ㧗ࡵࡿࡓࡵ࡟ࠊᆅᇦࡢࢿࢵࢺ
࣮࣡ࢡࢆ᭱኱㝈࡟ά⏝ࡋࡓࢥࣥࢯ࣮ࢩ࢔࣒◊✲ࢆࢫࢱ࣮ࢺࡉࡏࡓࠋ኱㜰ࡢᆅඖ௻ᴗ࡜⾜ᨻࠊ࠾ࡼࡧ኱㜰
኱Ꮫ࡜኱㜰ᗓ❧◊✲ᶵ㛵ࡢ࠸ࢃࡺࡿ⏘ᐁᏛࡀ㐃ᦠࡋࠊ≉࡟⅏ᐖ᫬ࡢಖᏑ㣗࡟ồࡵࡽࢀࡿ✀ࠎࡢせ⣲ࠊࡘ
ࡲࡾ㛗ᮇಖᏑᛶ࣭㧗࣮࣭࢝ࣟࣜ㣗࡭ࡸࡍࡉࢆేࡏᣢࡘ᪂ࡋ࠸ᙧࡢࠕ⢖࠾ࡇࡋࠖࡢ㛤Ⓨࢆࡍࡍࡵࡿ௙⤌ࡳ
࡙ࡃࡾ࡜ၟရ㛤Ⓨࢆ᳨ウࡋࡓࠋ
ࡲࡓࠊ₎᪉⸆ࡸ೺ᗣ㣗ရࠊࢦ࣒➼ࡢཎᮦᩱ࡞࡝ከᒱ࡟ά⏝ࡉࢀࡿࢺࢳࣗ࢘࡟ࡘ࠸࡚ࠊ᪂ࡓ࡞▱㈈๰ฟ
ࡢࢩࢫࢸ࣒ᵓ⠏࡟ࡘ࠸࡚ࡢ᳨ドࠊ᭷⏝ᛶࢆ㧗ࡵࡿᢏ⾡㛤Ⓨ◊✲ࢆᘬࡁ⥆ࡁ⾜࡞ࡗࡓࠋ
ࡉࡽ࡟ࠊ㒔ᕷ⥳໬࡟㈨ࡍࡿỈ⪔᱂ᇵᢏ⾡ࡢ㛤Ⓨ࣭ᐇᆅヨ㦂࡜ࠊ୰ᑠ௻ᴗᨭ᥼ࡢຓᡂ㔠 2 ௳࡟ࡼࡿ⏘Ꮫ
㐃ᦠ࡟ࡼࡿࡶࡢ࡙ࡃࡾࡢヨస㛤Ⓨᨭ᥼ࢆ⾜ࡗࡓࠋ
࣭ࠕࠥᮍ᮶ࢆᣅࡃ᳜≀ࣂ࢖࢜ࡢࢳ࢝ࣛࠥ 㑇ఏᏊ⤌᥮࠼᳜≀ࡢ⌧≧࡜ᒎᮃࠖࢩ࣏ࣥࢪ࣒࢘ࡢ㛤ദ
ᖹᡂ 27 ᖺ 3 ᭶ 28 ᪥(ᅵ)ࠊ኱㜰ᱵ⏣࡟࠾࠸࡚ࠊ᪥ᮏᏛ⾡᣺⯆఍᳜≀ࣂ࢖࢜➨ 160 ጤဨ఍ ♫఍᝟ሗⓎ
ಙ஦ᴗ୺ദ࡛ࠊ㑇ఏᏊ⤌᥮࠼᳜≀࡟㛵ࡍࡿࢩ࣏ࣥࢪ࣒࢘ࢆ㛤ദࡋࡓ㸦ඹദ㸸୍⯡㈈ᅋἲே኱㜰኱Ꮫ⏘ᴗ
⛉Ꮫ◊✲༠఍ࠊ୍⯡♫ᅋἲேࢸࣛࣉࣟࢪ࢙ࢡࢺ㸧ࠋ
ㅮ₇࡜⛉Ꮫᐇ㦂࣭ᐇ⩦ࢆ⾜࠺≉ูࣉࣟࢢ࣒࡛ࣛࠊ᳜≀ࡢ㠃ⓑࡉࡸ㑇ఏᏊ⤌᥮࠼᳜≀࡟ࡘ࠸࡚ࡢ㸲ࡘࡢ
ㅮ₇࡟ཧຍ⪅ࡣ⇕ᚰ࡟⪥ࢆഴࡅ࡚࠸ࡓࠋᐇ⩦ࡢ㒊࡛ࡣࠊ㑇ఏᏊ⤌᥮࠼ࣃࣃ࢖࢔ࡢゎㄝ࡜ヨ㣗ࡢ࠶࡜ࠊክ
ࡢගࡿ᳜≀ࢆ᝿ᐃࡋࡓ໬ᏛⓎගࡢᐇ㦂ࠊ
᳜≀࠿ࡽ㤶ࡾࡸⰍࢆྲྀࡾฟࡍᐇ㦂ࡀᐇ
₇ࡉࢀࠊ୰Ꮫᰯ࡞࡝࡛ྠᵝࡢᐇ㦂ࢆ⾜࠺
㝿ࡢ࣏࢖ࣥࢺࡶㄝ᫂ࡉࢀࡓࠋཧຍ⪅ࡢ୰
Ꮫᰯᩍㅍ࠿ࡽࡣࠊ
ࠕᏛ⩦࡛ࡁ࡚ࡼ࠿ࡗࡓࠋ
༢࡟୙Ᏻࡀࡽࡎ࡟Ꮫ⩦ࡋ⥆ࡅࡓ࠸ࠋࠖ࡜
ࡢពぢࡀ࠶ࡾࠊṇ☜࡞▱㆑ࢆ᝟ሗⓎಙࡍ
㻌
㻌
ࡿࡇ࡜ࡢ㔜せᛶࡀ☜ㄆࡉࢀࡓࠋ
ㅮ₇䠄ᕥ㻧㻌 ₇⪅䛿⏘ᴗ⛉Ꮫ◊✲ᡤ㻌 Ọ஭ᩍᤵ䜙䠅䛸⛉Ꮫᐇ㦂䠄ྑ䠅䛾ᵝᏊ㻌
― 82 ―
ឤᰁไᚚᏛ◊✲ศ㔝㸦➨㸰ࣉࣟࢪ࢙ࢡࢺ◊✲ศ㔝㸧
෸ᩍᤵ
す㔝 㑥ᙪ
≉௵ຓᩍ
す㔝 ⨾㒔Ꮚ
≉௵◊✲ဨ ᯇᮏ ెᕭ㸦ᐈဨᩍᤵ㸧
኱Ꮫ㝔Ꮫ⏕
ᯘ ඞᙪࠊᒣᓮ ⪷ྖ
(ୖグ኱Ꮫ㝔⏕ࡣ㐃ᦠ◊✲ᐊࡢ⏕యศᏊไᚚ⛉Ꮫ◊✲ศ㔝ࡼࡾཷධ)
ὴ㐵⫋ဨ
⚟ᓥ ឡᏊࠊ஬༑ᔒ ⥤
a) ᴫせ
⣽⳦ࡢ⣽⬊⭷࡟ࡣ≀㉁㍺㏦ࡢᙺ๭ࢆᢸ࠺⭷ࢱࣥࣃࢡ㉁ࡀᩘከࡃᏑᅾࡋ࡚࠸ࡿࠋ㏆ᖺࠊ⸆࡛἞⒪ࡍࡿࡇ
࡜ࡢ࡛ࡁ࡞࠸⸆๣⪏ᛶ⳦࡟ࡼࡿឤᰁ⑕ࡀฟ⌧ࡋࠊୡ⏺ඹ㏻ࡢ῝้࡞ၥ㢟࡜࡞ࡗ࡚࠸ࡿࡀࠊ⸆๣⪏ᛶᶵᵓ
ࡢ୍ࡘ࡜ࡋ࡚⭷ࢱࣥࣃࢡ㉁࡟ࡼࡿ⸆๣ࡢ᤼ฟࡀ࠶ࡆࡽࢀࡿࠋᮏ◊✲ศ㔝࡛ࡣࠊឤᰁ⑕ࡢ᣺⯆ࢆᮍ↛࡟㜵
ࡄࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚ࠊ⣽⳦ࡢ⭷ࢱࣥࣃࢡ㉁࠾ࡼࡧࡑࡢไᚚᶵᵓ࡟㛵ࡍࡿ◊✲࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿࠋ⑓ཎ⳦
ࡢ㐺ᛂຊ࡜㐍໬ࡢ௙⤌ࡳࢆ᫂ࡽ࠿࡟ࡋࡓୖ࡛ࠊ⣽⳦ࡢ⸆๣⪏ᛶ࡜⑓ཎᛶࢆྠ᫬࡟㍍ῶࡍࡿࡇ࡜ࡢ࡛ࡁࡿ
᪂つ἞⒪ἲ☜❧ࢆ┠ᣦࡋ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭࣓ࢳࣝࢢࣜ࢜࢟ࢧ࣮ࣝࡀከ๣⪏ᛶ⥳⮋⳦࡟࠾ࡼࡰࡍᙳ
㡪
⻏⻤࡟ࡣᵝࠎ࡞໬ྜ≀ࡀྵࡲࢀ࡚࠾ࡾࠊᗈ⠊ᅖࡢ⣽⳦
✀࡟ᑐࡋ࡚ࠊᢠ⳦άᛶࢆಖ᭷ࡋ࡚࠸ࡿࡇ࡜ࡀ▱ࡽࢀ࡚࠸
ࡿࠋࡑࡢάᛶࡣࠊ᥇ࡿⰼࡸẼ㇟ࠊ⻏⻤཰✭ࡢ≧ἣ࡟ࡼࡗ
࡚␗࡞ࡿࡇ࡜ࡀ▱ࡽࢀ࡚࠸ࡿࠋ࣓ࢳࣝࢢࣜ࢜࢟ࢧ࣮ࣝࡣࠊ
⻏⻤࡟ྵࡲࢀࡿᢠ⳦ᛶ≀㉁࡜ࡋ࡚ྠᐃࡉࢀࠊ≉࡟࣐ࢾ࢝
ࣁࢽ࣮࡟࠾࠸࡚ࡣࠊ௚ࡢ⻏⻤࡟ẚ࡭࡚࣓ࢳࣝࢢࣜ࢜࢟ࢧ
࣮ࣝࡢྵ᭷㔞ࡀከࡃࠊࡑࡢ⃰ᗘ࡟ᛂࡌ࡚ࠊၟရ౯᱁ࡶศ
㢮ࡉࢀ࡚࠸ࡿࠋ࣓ࢳࣝࢢࣜ࢜࢟ࢧ࣮ࣝࡀᣢࡘࠊ࣓ࢳࢩࣜ
ࣥ⪏ᛶ㯤Ⰽࣈࢻ࢘⌫⳦ࡸࣂࣥࢥ࣐࢖ࢩࣥ⪏ᛶ⭠⌫⳦➼ࡢ
ࢢ࣒ࣛ㝧ᛶ⳦࡟ᑐࡍࡿᢠ⳦άᛶ࡟ࡘ࠸࡚ࡣࠊࡇࢀࡲ࡛ࡶ
ሗ࿌ࡀ࠶ࡗࡓࡀࠊ୍᪉ࠊࢢ࣒ࣛ㝜ᛶ⳦࡟ᑐࡋ࡚࡝ࡢࡼ࠺
࡞άᛶࢆಖ᭷ࡋ࡚࠸ࡿࡢ࠿ࡣศ࠿ࡗ࡚࠸࡞࠿ࡗࡓࠋᮏ◊
✲࡛ࡣࠊ⮫ᗋ࠿ࡽศ㞳ࡉࢀࡓከ๣⪏ᛶ⥳⮋⳦㸦MDRP㸧
㸳㸱ᰴ࡟ᑐࡍࡿ࣓ࢳࣝࢢࣜ࢜࢟ࢧ࣮ࣝࡢᢠ⳦άᛶ࡟ࡘ࠸
࡚ㄪᰝࢆ⾜ࡗࡓ㸦⾲㸯㸧ࠋࡲࡓࠊ㸳ࡘࡢ⸆๣᤼ฟࢩࢫࢸ࣒
ࢆḞᦆࡉࡏࡓ⥳⮋⳦ࡸࠊ኱⭠⳦ࠊࢧࣝࣔࢿࣛࡢ⸆๣᤼ฟ
ࢩࢫࢸ࣒Ḟᦆᰴ࡟ᑐࡍࡿ࣓ࢳࣝࢢࣜ࢜࢟ࢧ࣮ࣝࡢᢠ⳦ά
ᛶ࡟ࡘ࠸᳨࡚ドࡋࡓ㸦ᅗ㸯㸧ࠋࡑࡢ⤖ᯝࠊ࣓ࢳࣝࢢࣜ࢜࢟
ࢧ࣮ࣝࡣࠊ㧗⃰ᗘῧຍࡍࡿࡇ࡜࡟ࡼࡾ MDRP ࡢቑṪࢆ㜼
Ṇࡍࡿࡇ࡜ࠊࡲࡓࠊࡇࡢ໬ྜ≀ࡣ⸆๣᤼ฟࢩࢫࢸ࣒࡟ࡼ
ࡗ࡚ㄆ㆑ࡉࢀ࡞࠸ࡇ࡜ࡀศ࠿ࡗࡓ(Front Microbiol. 2014
Apr 17;5:180)ࠋ
࣓ࢳࣝࢢࣜ࢜࢟ࢧ࣮ࣝࡣࠊMDRP ࡟ᑐࡋ࡚࢖࣑࣌ࢿ࣒ࠊ
࢔࣑࢝ࢩࣥࠊࢩࣉࣟࣇࣟ࢟ࢧࢩࣥ࡜ྠ➼ࡢ MIC ್ࢆ♧ࡋ
࡚࠾ࡾࠊ἞⒪࡟⏝࠸ࡿࡇ࡜ࡣᅔ㞴࡜ุ᩿ࡉࢀࡿࠋ
― 83 ―
⾲㸯. ᢠ⳦ᛶ≀㉁࡟ᑐࡍࡿከ๣⪏ᛶ⥳⮋⳦㸦MDRP㸧ࡢ
ឤཷᛶ. (Front Microbiol. 2014 Apr 17;5:180)
ᅗ 1. ࣓ࢳࣝࢢࣜ࢜࢟ࢧ࣮ࣝࡀ኱⭠⳦ࠊࢧࣝࣔࢿࣛࠊ⥳
⮋⳦ࡢቑṪ࡟࠾ࡼࡰࡍᙳ㡪.
(Front Microbiol. 2014 Apr 17;5:180)
࣭$FU%$FU' ࡜ 0GW$%& ከ๣᤼ฟࢩࢫࢸ࣒ࡣ኱⭠⳦࢚ࣥࢸࣟࣂࢡࢳࣥࡢ㍺㏦࡟㛵୚ࡋ࡚࠸ࡿ
⸆๣᤼ฟࢩࢫࢸ࣒ࡣࡶ࡜ࡶ࡜⸆๣
⪏ᛶᅉᏊ࡜ࡋ࡚ྠᐃࡉࢀࡓ⤒⦋࠿ࡽ
ࡑࡢྡ๓ࡀ௜ࡅࡽࢀ࡚࠸ࡿࡀࠊ⚾㐩ࡢ
◊✲࠿ࡽࠊ⸆๣⪏ᛶࡔࡅ࡛ࡣ࡞ࡃࠊ௦
ㅰ⏘≀ࡢ㍺㏦ࡸ⣽⳦⑓ཎᛶⓎ⌧࡟ࡶ
㛵୚ࡋ࡚࠸ࡿࡇ࡜ࡀ᫂ࡽ࠿࡟࡞ࡗ࡚
ࡁࡓࠋᮏ◊✲࡛ࡣࠊ㕲Ḟஈ᫬࡟࠾ࡅࡿ
⸆๣᤼ฟࢩࢫࢸ࣒ࡢᙺ๭ࢆ᫂ࡽ࠿࡟
ࡍࡿࡓࡵࠊࡑࡢ⏕⌮ᶵ⬟࡟ࡘ࠸࡚ゎᯒ
ࢆ⾜ࡗࡓࠋ
⸆๣᤼ฟ䝅䝇䝔䝮䛷䛒䜛 AcrB, AcrD
䛸 MdtABC 䛿䚸䃑-䝷䜽䝍䝮๣䜢䛿䛨䜑䛸
ᅗ 2. AcrB, AcrD ࡜ MdtABC ⸆๣᤼ฟࢩࢫࢸ࣒ࡣ࢚ࣥࢸࣟࣂࢡࢳࣥ㍺㏦࡟ᚲ
䛩䜛ᢠ⳦⸆䜢᤼ฟ䛧䚸⣽⳦䜢ከ๣⪏ᛶ
せ࡛࠶ࡿ. ࢚ࣥࢸࣟࣂࢡࢳࣥࡢ⳦యእ࡬ࡢ㍺㏦ࢆ RP HPLC ࢆ⏝࠸࡚ゎᯒࡋࡓ.
໬䛥䛫䜛䚹䛔䛪䜜䛾᤼ฟ䝅䝇䝔䝮䜒䚸እ
(PLoS One. 2014 Sep 26;9:e108642)
⭷䝍䞁䝟䜽㉁䛷䛒䜛 TolC 䛸ඹᙺ䛧䛶⸆๣
䜢⣽⬊እ䜈᤼ฟ䛩䜛䛣䛸䛜ศ䛛䛳䛶䛔䛯䚹
୍᪉䛷䚸䛣䛾 3 䛴䛾⸆๣᤼ฟ䝅䝇䝔䝮䛜
⸆๣䛾᤼ฟ௨እ䛻䛹䛾䜘䛖䛺⏕⌮ᶵ⬟䜢ᢸ䛳䛶䛔䜛䛾䛛䛻䛴䛔䛶䛿䜘䛟ศ䛛䛳䛶䛔䛺䛛䛳䛯䚹AcrB 䛿㏻ᖖ䛾ᇵ
㣴᮲௳䛷ᜏᖖⓗ䛻Ⓨ⌧䛧䛶䛔䜛⸆๣᤼ฟ䝅䝇䝔䝮䛷䛒䜛䛜䚸AcrD 䛸 MdtABC 䛿㏻ᖖ䜋䛸䜣䛹Ⓨ⌧䛧䛶䛔䛺䛔䚹
䛣䜜䜎䛷䛾ᐇ㦂䛛䜙䚸AcrD 䛸 MdtABC ⸆๣᤼ฟ䝅䝇䝔䝮䛜䚸㕲Ḟஈ᮲௳ୗ䛻䛚䛔䛶ㄏᑟ䛥䜜䚸䛣䛾Ⓨ⌧ㄏᑟ䛿䚸
Fur 䛸䛔䛖㕲௦ㅰ䛻㛵䜟䜛ㄪ⠇ᅉᏊ䛻䜘䛳䛶ไᚚ䛥䜜䛶䛔䜛䛣䛸䛜ศ䛛䛳䛶䛝䛯䚹䜎䛯䚸㕲Ḟஈ᮲௳ୗ䛻䛚䛔䛶䚸
䛣䜜䜙᤼ฟ䝫䞁䝥䛜⳦䛾⏕⫱䛻ᚲせ䛷䛒䜛䛣䛸䛜ศ䛛䛳䛯䚹㕲䛿⑓ཎᛶ⣽⳦䛻䛸䛳䛶ᚲ㡲䛾ᚤ㔞㔠ᒓ䛷䛒䜚䚸
⣽⳦䛿ຠ⋡ⓗ䛺㕲ྲྀ䜚㎸䜏ᵝᘧ䜢䜒䛳䛶䛔䜛䚹⣽⳦䛿䝅䝕䝻䝣䜷䜰䛸䜘䜀䜜䜛 Fe3+䛸≉␗ⓗ䛻⤖ྜ䛩䜛ศᏊ䠄䜻
䝺䞊䝍䞊䠅䜢ศἪ䛧䚸䝅䝕䝻䝣
䜷䜰-Fe3+ 」ྜయ䜢ྲྀ䜚㎸䜐䛣
䛸䛻䜘䜚㕲䜢྾཰䛩䜛䚹䛭䛣䛷䚸
኱⭠⳦䛜⏘⏕䛩䜛䝅䝕䝻䝣䜷
䜰䛷䛒䜛䜶䞁䝔䝻䝞䜽䝏䞁䛾⳦
య䛛䜙䛾ศἪ䛸䚸䛣䜜䜙 AcrB,
AcrD 䛸 MdtABC ⸆๣᤼ฟ䝅
䝇䝔䝮䛾㛵ಀ䛻䛴䛔䛶ㄪ䜉䛯
䠄ᅗ 2䠅䚹ゎᯒ䛾⤖ᯝ䚸AcrB,
AcrD 䛚䜘䜃 MdtABC 䛿䚸䜶䞁
䝔䝻䝞䜽䝏䞁䜢᤼ฟ䛧䚸⳦䛾㕲
⋓ᚓ䛻㛵୚䛧䛶䛔䜛䛣䛸䜢Ⓨ
ぢ䛧䛯䠄ᅗ 3䠅䚹㕲䛿⣽⳦⑓ཎ
ᛶⓎ⌧䛻ᚲせ䛺ᅉᏊ䛷䛒䜛䛣
䛸䛛䜙䚸⸆๣᤼ฟ䝅䝇䝔䝮䛻䜘
䜛䝅䝕䝻䝣䜷䜰᤼ฟ䛜ྛ✀⣽
⳦䛾⑓ཎᛶⓎ⌧䛻䜒㛵୚䛧䛶
䛔䜛䛣䛸䛜ᙉ䛟♧၀䛥䜜䜛
(PLoS
One.
2014
Sep
26;9:e108642)䚹
ᅗ 3. ኱⭠⳦࢚ࣥࢸࣟࣂࢡࢳࣥ㍺㏦ࡢᶵᵓ. ࢚ࣥࢸࣟࣂࢡࢳࣥࡣ⣽⬊㉁ෆ࡛ྜᡂࡉࢀࡓᚋࠊ
࣌ࣜࣉࣛࢬ࣒㛫㝽ࡲ࡛ EntS ࡟ࡼࡗ࡚㍺㏦ࡉࢀࡿࠋࡑࡢᚋࠊAcrB, AcrD ࡜ MdtABC ࡀ࣌ࣜ
ࣉࣛࢬ࣒㛫㝽࠿ࡽ⣽⬊እ࡟ TolC ࢆ௓ࡋ࡚ᨺฟࡍࡿ. (PLoS One. 2014 Sep 26;9:e108642)
― 84 ―
ᴟᚤᮦᩱࣉࣟࢭࢫ◊✲ศ㔝㸦➨㸰ࣉࣟࢪ࢙ࢡࢺ◊✲ศ㔝㸧
෸ᩍᤵ
≉௵ຓᩍ
≉௵◊✲ဨ
஦ົ⿵బဨ
ᰗ⏣ ๛ 㸦ᖹᡂ 27 ᖺ 1 ᭶ 1 ᪥ࡼࡾᣍ⪸ᩍᤵ㸧
㛗ᓥ ୍ᶞ
Fuwei ZhugeࠊYong HeࠊGang Meng
⸨ཎ ⥤Ꮚࠊሯ⏣ ᜨᏊ
a) ᴫせ
ᙜศ㔝࡛ࡣࠊཎᏊ࣭ศᏊࡀ⮬↛ࡢᦤ⌮࡟❧⬮ࡋ࡚ᕦࡳ࡟⤌ࡳୖࡀࡾ㧗ḟࢼࣀᵓ㐀యࢆᙧᡂࡍࡿᴟᚤᮦ
ᩱࣉࣟࢭࢫࢆᇶ㍈࡜ࡋ࡚ࠊࠕᴟᚤᮦᩱᙧᡂ࣓࢝ࢽࢬ࣒ࡢゎ࣭᫂ไᚚ࣭࣐ࢸࣜ࢔ࣝࢹࢨ࢖ࣥࠖࠊࠕไ㝈✵㛫
࡟࠾ࡅࡿࢼࣀ≀ᛶホ౯ࠖ
ࠊ
ࠕ⎔ቃㄪ࿴ࢹࣂ࢖ࢫ࣭⏕యศᏊศᯒࢹࣂ࢖ࢫࡢ๰ᡂࠖ࡞࡝ࠊᴟᚤᮦᩱࡢࡶࡢ࡙
ࡃࡾ࡟ጞࡲࡾࡑࡢ≀ᛶホ౯࣭ࢹࣂ࢖ࢫᛂ⏝࡟⮳ࡿࡲ୍࡛㐃ࡢ◊✲ࢆᒎ㛤ࡍࡿࠋᙜศ㔝ࡢ┠ᣦࡍࡶࡢࡣࠊ
ᮦᩱ⛉Ꮫࠊ≀⌮ࠊ໬Ꮫࡢቃ⏺㡿ᇦ࡟఩⨨ࡍࡿᴟᚤᮦᩱᙧᡂࣉࣟࢭࢫࢆ᰿ᮏ࠿ࡽ⌮ゎ࣭ไᚚࡋࠊᮏࣉࣟࢭ
ࢫࢆ௓ࡋ࡚ᚓࡽࢀࡿᴟࡵ࡚Ⰻ㉁࡞ࢼࣀࢫࢣ࣮ࣝᵓ㐀యࢆ௓ࡋ࡚ᚑ᮶ᅔ㞴࡛࠶ࡗࡓ㧗ḟᵓ㐀యࡸᶵ⬟ࢆ
᥈⣴ࡍࡿࡇ࡜࡟ࡼࡾࠊ᪤Ꮡᢏ⾡ࢆ㠉᪂ࡍࡿ͆┬࣭๰࢚ࢿࣝࢠ࣮ࢹࣂ࢖ࢫ͇ࠊ
͆⏕యศᏊศᯒࢹࣂ࢖ࢫ͇ࢆ
๰ฟࡍࡿࡇ࡜࡛࠶ࡿࠋ
୺࡞◊✲ㄢ㢟࡜ࡋ࡚ࠊձᴟᚤᮦᩱᙧᡂࣉࣟࢭࢫࡢ࣓࢝ࢽࢬ࣒ゎ᫂࡜ᶵ⬟ᛶ㸯ḟඖࢼࣀ࣡࢖ࣖᵓ㐀యࡢ
๰ᡂࠊղ༢୍ࢼࣀ࣡࢖ࣖ⣲Ꮚࢆ௓ࡋࡓไ㝈✵㛫ࢼࣀ≀ᛶࡢ᥈⣴ࠊճࢢ࣮࢚ࣜࣥࣞࢡࢺࣟࢽࢡࢫࢹࣂ࢖ࢫ
㸦పᾘ㈝㟁ຊ୙᥹Ⓨᛶ࣓ࣔࣜࠊ࢚ࢿࣝࢠ࣮ኚ᥮➼㸧ཬࡧ⏕యศᏊศᯒࢹࣂ࢖ࢫ࡬ࡢᒎ㛤ࢆᥖࡆ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭Ẽᾮᅛ཯ᛂἲࢆ௓ࡋࡓ༢⤖ᬗ㓟໬≀ࢼࣀ࣡࢖ࣖᡂ㛗࡟࠾ࡅࡿ᪂つ⤖ᬗ┦ࡢᐇ⌧
⮬ᕫ⤌⧊໬ࢼࣀ࣡࢖ࣖᡂ㛗ࡣࣂࣝࢡࡸⷧ⭷࡟࠾ࡅࡿ⤖ᬗᡂ㛗࡜ࡣ඲ࡃ␗࡞ࡿᡂ㛗ᶵᵓࢆ᭷ࡍࡿࡓࡵࠊ
ᚑ᮶స〇ࡀᅔ㞴࡛࠶ࡗࡓ໬Ꮫ⤌ᡂࡸ⤖ᬗ┦ࢆᐇ⌧࡛ࡁࡿྍ⬟ᛶࡀᮇᚅࡉࢀ࡚࠸ࡿࡀࠊࢼࣀ࣡࢖ࣖᡂ㛗࣓
࢝ࢽࢬ࣒࡟࠾ࡅࡿ⌮ゎࡀ୙༑ศ࡛࠶ࡾࠊࡇࢀࡲ࡛࡟໬Ꮫ⤌ᡂࡸ⤖ᬗ┦ࡢไᚚࡣ୙ྍ⬟࡛࠶ࡗࡓࠋᡃࠎࡣࠊ
Ẽᾮᅛ཯ᛂἲ㸦VLS ἲ㸧࡟ᇶ࡙ࡃ༢⤖ᬗ㓟໬≀ࢼࣀ࣡࢖ࣖᡂ㛗㸦In-Sn 㓟໬≀⣔㸧࡟࠾࠸࡚ࠊࢼࣀ࣡࢖
ࣖᡂ㛗㏿ᗘࡀᾮᅛ⏺㠃࡟࠾ࡅࡿ⤖ᬗ᰾⏕ᡂ㢖ᗘ࡟ࡼࡗ࡚ᨭ㓄ࡉࢀ࡚࠾ࡾࠊࡲࡓྛᮦᩱ࡟ᅛ᭷ࡢ⤖ᬗ᰾⏕
ᡂ㢖ᗘࡀᏑᅾࡍࡿࡇ࡜ࢆぢฟࡋࡓࠋᮏ࣓࢝ࢽࢬ࣒࡟ᇶ࡙࠸࡚ᮦᩱ౪⤥㏿ᗘࢆタィࡍࡿࡇ࡜࡟ࡼࡾࠊ㓟໬
≀ࢼࣀ࣡࢖ࣖࡢ໬Ꮫ⤌ᡂཬࡧ⤖ᬗ┦ࢆ௵ព࡟ኚㄪྍ⬟࡛࠶ࡿࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡗࡓࠋ᭦࡟ᮏ◊✲࡛ࡣࠊ
ᚑ᮶ࣂࣝࢡࡸⷧ⭷࡛ࡣస〇ࡀᅔ㞴࡛࠶ࡗࡓ‽Ᏻᐃ⤖ᬗ┦࡛࠶ࡿ InxSnyO3.5 ࡢࢼࣀ࣡࢖ࣖ๰ᡂ࡟ᡂຌࡋࡓࠋ
ࡇࢀࡽ୍㐃ࡢ⤖ᯝࡣࠊከᙬ࡞≀ᛶࢆ᭷ࡍࡿ㔠ᒓ㓟໬≀ᮦᩱࢆࢼࣀ࣡࢖ࣖᵓ㐀໬ࡋࠊ᪤Ꮡᮦᩱࡢ㝈⏺ࢆ෽
㥙ࡋࡓ໬Ꮫ⤌ᡂタィཬࡧ᪂ᶵ⬟ࡢᐇ⌧ࢆ┠ᣦࡍୖ࡛ᴟࡵ࡚㔜せ࡞▱ぢ࡛࠶ࡿࠋ
In-Sn 㓟໬≀ࢼࣀ࣡࢖ࣖࡢ໬Ꮫ⤌ᡂ࣭⤖ᬗᵓ㐀࡟࠾ࡅࡿ
ྛᮦᩱ⣔ࡢࢼࣀ࣡࢖ࣖᡂ㛗㏿ᗘ࡟࠾ࡅࡿ
ᮦᩱ౪⤥㏿ᗘ౫Ꮡᛶ
ᮦᩱ౪⤥㏿ᗘ౫Ꮡᛶ
― 85 ―
࣭࣐࢖ࢡࣟࢫࢣ࣮ࣝἜỈ⏺㠃ࢆ฼⏝ࡋࡓࢼࣀ࣡࢖ࣖ㓄ิἲࡢ㛤Ⓨ
௵ពࡢ✵㛫఩⨨࡟ಶู࡟ࢼࣀ࣡࢖ࣖᵓ㐀యࢆ㓄⨨ࡍࡿࢼࣀ࣡࢖ࣖ㓄ิἲࡣࠊࢼࣀ࣡࢖ࣖࡢᶵ⬟≀ᛶホ
౯࠾ࡼࡧࢹࣂ࢖ࢫᒎ㛤࡬ྥࡅ࡚୙ྍḞ࡞ᇶ┙ᢏ⾡࡛࠶ࡿࠋ≉࡟㧗 ⎔ቃ࡛ᙧᡂࡋࡓ༢⤖ᬗࢼࣀ࣡࢖ࣖࢆ
௵ពࡢᇶᯈୖ࡟ᐊ ࣉࣟࢭࢫ࡛ไᚚ㓄ิࡉࡏࡿࡇ࡜ࡀྍ⬟࡜࡞ࢀࡤࠊ᪤Ꮡࡢᢏ⾡࡛ࡣᐇ⌧ࡋᚓ࡞࠸㧗ᶵ
⬟࣭᪂ᶵ⬟ࢆ᭷ࡍࡿ᪂ወࢼࣀࢹࣂ࢖ࢫ⩌ࡢ๰ฟࡀᮇᚅ࡛ࡁࡿࠋᮏ◊✲࡛ࡣᇶᯈୖ࡟ࣃࢱ࣮ࣥᙧᡂࡉࢀࡓ
ἜỈ⏺㠃ࢆ฼⏝ࡋ࡚ࢼࣀ࣡࢖ࣖࢆᡤᮃࡢ✵㛫఩⨨࡟ไᚚ㓄ิࡉࡏࡿࢼࣀ࣡࢖ࣖ㓄ิἲࡢ㛤Ⓨ࡟ྲྀࡾ⤌
ࢇࡔࠋ࣐࢖ࢡࣟࢫࢣ࣮ࣝࡢぶỈࣃࢱ࣮ࣥୖ࡟ᙧᡂࡉࢀࡿࢼࣀࢫࢣ࣮ࣝࡢỈᒙࡢ㧗ࡉࢆ฼⏝ࡍࡿࡇ࡜࡛ࠊ
㓄ิࡍࡿࢼࣀ࣡࢖ࣖ࡟ࢧ࢖ࢬ㑅ᢥᛶࢆ௜୚ࡉࡏࡿࡇ࡜࡟ᡂຌࡋࡓࠋ᭦࡟ࠊᮏࢧ࢖ࢬ㑅ᢥᛶࢆ฼⏝ࡋ࡚ࠊ
␗✀ࢼࣀ࣡࢖ࣖᵓ㐀యࢆྠ୍ᇶᯈୖࡢᡤᮃࡢ఩⨨࡟㓄ิࡍࡿࡇ࡜࡟ᡂຌࡋࡓࠋᮏ㛤Ⓨᡭἲ࡟ࡼࡾ〇㐀ࣉ
ࣟࢭࢫࡢ➇ྜ࡟ࡼࡾࡇࢀࡲ࡛ไ㝈ࡉࢀ࡚ࡁࡓᶵ⬟ᮦᩱࡢ㞟✚໬ࢆ㸯ࢳࢵࣉୖ࡛ᐇ⌧ࡍࡿࡇ࡜ࡀᮏ㉁ⓗ
࡟ྍ⬟࡜࡞ࡾࠊከᶵ⬟ࡀ⼥ྜࡋࡓ᪂ወࢹࣂ࢖ࢫ⩌๰ฟ࡬ࡢᒎ㛤ࡀᮇᚅࡉࢀࡿࠋ
ἜỈ⏺㠃ࢆ฼⏝ࡋࡓࢼࣀ࣡࢖ࣖ㓄ิἲࡢᴫᛕᅗ
ࢧ࢖ࢬ㑅ᢥᛶࢆ฼⏝ࡋࡓ␗✀ࢼࣀ࣡࢖ࣖ㓄ิ
࣭% ࢻ࣮ࣉ 6L ࢼࣀ࣡࢖ࣖࡢ⇕㟁ಀᩘ࡟࠾ࡅࡿ୙⣧≀ศᕸ౫Ꮡᛶ
᤼⇕࠿ࡽ㟁Ẽ࢚ࢿࣝࢠ࣮ࢆྲྀࡾฟࡍ⇕㟁ኚ᥮⣲Ꮚࡣࠊ࢚ࢿࣝࢠ࣮ၥ㢟࡟㈨ࡍࡿ๰࢚ࢿࣝࢠ࣮ࢹࣂ࢖ࢫ
ࡢ๰〇ࡢࡳ࡞ࡽࡎࠊ㟁Ꮚࢹࣂ࢖ࢫࡢ┬㟁ຊ໬ࡸⓎ⇕࡟ࡼࡿᛶ⬟పୗࢆ㜵ࡄୖ࡛㔜せ࡞ᢏ⾡࡜࡞ࡿࠋ⇕㟁
ኚ᥮ᛶ⬟ࡣࠊ⇕㉳㟁ຊ㸦ࢮ࣮࣋ࢵࢡಀᩘ㸧࠾ࡼࡧ㟁Ẽఏᑟ⋡࡟ẚ౛ࡋࠊ⇕ఏᑟ⋡ࡢ㏫ᩘ࡟ẚ౛ࡍࡿࡇ࡜
ࡀ▱ࡽࢀ࡚࠸ࡿࡀࠊ㏆ᖺࢼࣀ࣡࢖ࣖᵓ㐀య࡟࠾࠸࡚ࠊ⾲㠃ࣇ࢛ࣀࣥᩓ஘ຠᯝ࡟ࡼࡾ⇕ఏᑟ⋡ࡀ๻ⓗ࡟ῶ
ᑡࡍࡿࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡾࠊࢼࣀ࣡࢖ࣖࢆ⏝࠸ࡓ⇕㟁ኚ᥮⣲Ꮚ࡬ࡢ㛵ᚰࡀ㧗ࡲࡗ࡚࠸ࡿࠋᮏ◊✲࡛ࡣࠊ
ࢼࣀ࣡࢖ࣖ⇕㟁ኚ᥮⣲Ꮚࡢ᭦࡞ࡿ⇕㟁ᛶ⬟ྥୖࢆ┠ᣦࡋ࡚ࠊB ࢻ࣮ࣉ Si ࢼࣀ࣡࢖ࣖ࡟࠾ࡅࡿ⇕㉳㟁ຊཬ
ࡧ㟁Ẽఏᑟ⋡࡜୙⣧≀ศᕸ࡜ࡢ㛵ಀᛶࢆ᳨ウࡋࡓࠋࡑࡢ⤖ᯝࠊᆒ୍࡞୙⣧≀ศᕸࢆ᭷ࡍࡿ⣔࡜ẚ㍑ࡋ࡚
୙ᆒ୍࡞୙⣧≀ศᕸࢆ᭷ࡍࡿ Si ࢼࣀ࣡࢖ࣖࡣ㧗࠸⇕㉳㟁ຊࢆ♧ࡍࡇ࡜ࢆぢฟࡋࡓ㸦ྠ୍㟁Ẽఏᑟ⋡࡟࠾
ࡅࡿẚ㍑㸧ࠋ✀ࠎࡢ᳨ド࡟ࡼࡾࠊᮏຠᯝࡀ㧗୙⣧≀⃰ᗘᒙ࠿ࡽప୙⣧≀⃰ᗘᒙ࡬ࡢ࢟ࣕࣜ࢔ᣑᩓ࡟ࡼࡿ
㟁Ẽఏᑟ⋡ࡢྥୖ࡟㉳ᅉࡍࡿࡶࡢ࡛࠶ࡿࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡗࡓࠋ᭦࡟ࠊᮏ◊✲࡛᫂ࡽ࠿࡟ࡋࡓ࢟ࣕࣜ࢔
ᣑᩓ࣓࢝ࢽࢬ࣒࡟ᇶ࡙ࡁᛴᓧ࡞୙⣧≀⃰ᗘ໙㓄ࢆタィࡍࡿࡇ࡜࡛ࠊᚑ᮶ࡢᆒ୍୙⣧≀ศᕸ⣔࡜ẚ㍑ࡋ࡚
⣙஧ಸࡢ⇕㉳㟁ຊࢆᚓࡿࡇ࡜࡟ᡂຌࡋࡓࠋᮏ⤖ᯝࡣࠊSi ⇕㟁ኚ᥮⣲Ꮚ࡟࠾ࡅࡿ⇕㟁ᛶ⬟ࡢᚑ᮶㝈⏺ࢆᡴ
◚ࡋ㧗ຠ⋡⇕㟁ኚ᥮⣲Ꮚࢆ๰〇ࡍࡿୖ࡛㔜せ࡞▱ぢ࡛࠶ࡿࠋ
Seebeck coefficient S (—V/K)
2000
1600
G-doped nanowire
VLS nanowire
1200
800
Homogeneous
400
Theory
0
10-4 10-3 10-2 10-1 100 101 102 103
Resistivity U (:cm)
༢୍ࢼࣀ࣡࢖ࣖ⇕㉳㟁ຊ ᐃホ౯⏝⣲Ꮚ
B ࢻ࣮ࣉ Si ࢼࣀ࣡࢖ࣖࡢ⇕㉳㟁ຊ࡟ᑐࡍࡿ
୙⣧≀ศᕸ౫Ꮡᛶ
― 86 ―
ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ᮦᩱ◊✲ศ㔝㸦➨㸰ࣉࣟࢪ࢙ࢡࢺ◊✲ศ㔝㸧
෸ᩍᤵ
≉௵ຓᩍ
ᢏ⾡⿵బဨ
⬟ᮌ 㞞ஓ
ྂ㈡ ኱ᑦ
ㅰ ᫂ྩࠊᰗ⏕ ▖ࠊᇼỤ ᬛ⤮ࠊ㞴Ἴ ┤Ꮚ
a) ᴫせ
ࢭ࣮ࣝࣟࢫࡣࠊᆅ⌫ୖ࡟᭱ࡶ㇏ᐩ࡟Ꮡᅾࡍࡿ෌⏕⏘ྍ⬟࡞ࣂ࢖࣐࢜ࢫ㈨※࡛࠶ࡾࠊ඲࡚ࡢ᳜≀ࡣࠊᖜ
4-15 nm ࡢࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮࠿ࡽ࡛ࡁ࡚࠸ࡲࡍࠋᙜ◊✲ᐊ࡛ࡣࠊࡇࡢ᳜≀ࢼࣀࣇ࢓࢖ࣂ࣮ࢆ౑
ࡗ࡚ࠕ㏱᫂࡞⣬㸦ࢼࣀ࣮࣌ࣃ࣮㸧ࠖࢆ㛤Ⓨࡍࡿࡇ࡜࡟ᡂຌࡋࡲࡋࡓࠋ⌧ᅾࡣࠊࢼࣀ࣮࣌ࣃ࣮ᇶᯈୖ࡟㟁
Ꮚࢹࣂ࢖ࢫࢆᦚ㍕ࡍࡿࠕࢼࣀ࣮࣌ࣃ࣮࢚ࣞࢡࢺࣟࢽࢡࢫࠖࢆࡣࡌࡵࠊ⣬࡞ࡽ࡛ࡣࡢᢒ⣬ࣉࣟࢭࢫࡸ⎔ቃ
ㄪ࿴ᛶ࣭ᰂ㌾ᛶ࣭ᵓ㐀≉ᛶ࡟╔┠ࡋࡓ᪂つᶵ⬟ᮦᩱࡢ๰ฟ࡟ྲྀࡾ⤌ࢇ࡛࠸ࡲࡍࠋ
b) ᡂᯝ
࣭ࢹࢪࢱࣝ᝟ሗࢆグ᠈ࡍࡿ⣬
ᴟᚤᮦᩱࣉࣟࢭࢫศ㔝ࡢᰗ⏣๛෸ᩍᤵࠊ㛗ᓥ୍ᶞ≉௵ຓᩍࠊ஑ᕞ኱Ꮫ
ࡢ໭ᒸ༟ஓᩍᤵ࡜ඹྠ࡛ࠊ㖟ࢼࣀ⢏Ꮚᢸᣢࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮࡛
సࡗࡓࢼࣀ࣮࣌ࣃ࣮ࢆ⏝࠸࡚ࠊࢹࢪࢱࣝ᝟ሗࢆグ᠈ࡍࡿ୙᥹Ⓨᛶ࣮࣌ࣃ
࣮࣓ࣔࣜࢆ㛤Ⓨࡍࡿࡇ࡜࡟ᡂຌࡋࡲࡋࡓ㸦ᅗ 1㸧ࠋࡇࡢࠕࢹࢪࢱࣝ᝟ሗࢆ
グ᠈ࡍࡿ⣬ࠖࡣࠊ᭤⋡༙ᚄ 0.35 mm ࡛ᢡࡾ᭤ࡆ࡚ࡶ࣓ࣔࣜᶵ⬟ࢆಖᣢࡍ
ࡿ㧗࠸ࣇࣞ࢟ࢩࣈࣝᛶ࡟ຍ࠼ࠊ0.5 V ௨ୗࡢప㟁ᅽ㥑ືᛶࡸ㟁ὶ ON/OFF
ẚ 106 ௨ୖ➼ࡢඃࢀࡓ୙᥹Ⓨᛶ࣓ࣔࣜᛶ⬟ࡶ㐩ᡂࡋࡲࡋࡓࠋḟୡ௦ࡢࣇ
ࣞ࢟ࢩࣈ࣭࢚ࣝ࢘࢔ࣛࣈࣝ㟁Ꮚࢹࣂ࢖ࢫ࡟㈨ࡍࡿ᪂つ࡞ࣇࣞ࢟ࢩࣈࣝ୙
᥹Ⓨᛶ࣓ࣔࣜ࡜ࡋ࡚᭷⏝࡛ࡍࠋࡲࡓࠊࡇࡢᡂᯝ࡟ࡼࡾࠊ
ࠕᩥᏐ࡛グ㘓ࡍࡿ
⣬ࠖ࠿ࡽࠕ㟁Ẽ࡛グ㘓ࡍࡿ⣬ࠖ࡬ࡢࣃࣛࢲ࢖࣒ࢩࣇࢺࡀ㉳ࡇࡾࠊࢹࢪࢱ
ࣝ᝟ሗ♫఍࡟࠾ࡅࡿࠕ⣬ࠖ࡟᪂ࡋ࠸౯್ࡀ⏕ࡲࢀࡿࡇ࡜ࡀᮇᚅࡉࢀࡲࡍࠋ
ᅗ ࢹࢪࢱࣝ᝟ሗࢆグ᠈ࡍࡿ⣬
࣭㧗ㄏ㟁⋡ࢼࣀ࣮࣌ࣃ࣮ࢆ⏝࠸ࡓᑠᆺࣇࣞ࢟ࢩࣈࣝ࢔ࣥࢸࢼ
㏆࠸ᑗ᮶ࠊேࡸ≀ࡸᶵჾࠊ࠶ࡽࡺࡿࣔࣀ࡟㏻ಙᶵ⬟ࢆᣢࡓࡏ࡚࢖ࣥࢱ࣮ࢿࢵࢺ࡟⧅ࡂࠊ⮬ືㄆ㆑ࡸ⮬
ືไᚚࠊ㐲㝸ィ ࡞࡝ࢆ⾜࠺ IoT(Internet of Things)♫఍ࡀ฿᮶ࡍࡿ࡜ண ࡉࢀ࡚࠸ࡲࡍࠋࡇࡢࢺࣞࣥࢻ
ࡢ୰࡛ࠊⷧࡃ࡚㍍㔞࣭ᑠࡉࡃᰂ㌾࡛㐪࿴ឤ࡞ࡃ⿦╔࡛ࡁࡿ࣡࢖ࣖࣞࢫ᝟ሗ㏻ಙ࢔ࣥࢸࢼࢹࣂ࢖ࢫࡢ㛤Ⓨ
ࡀᕼồࡉࢀ࡚࠸ࡲࡍࠋࡑࡢࡓࡵ࡟ࡣࠊ࢔ࣥࢸࢼᇶᯈᮦᩱࡢ㍍㔞࣭ࣇࣞ࢟ࢩࣈࣝ໬࣭㧗ㄏ㟁⋡໬ࡀᚲせ୙
ྍḞ࡛ࡍࠋᡃࠎࡣࠊࢼࣀ࣮࣌ࣃ࣮ෆ㒊࡟ᑡ㔞ࡢ㖟ࢼࣀ࣡࢖ࣖࢆᆒ୍ศᩓࡉࡏࡿࡇ࡜࡛ࠊࣇࣞ࢟ࢩࣈࣝ࡞
㧗ㄏ㟁⋡ᇶᯈ㸦[email protected] GHz㸧ࢆ㛤Ⓨࡍࡿࡇ࡜࡟ᡂຌࡋࡲࡋࡓࠋ㧗ㄏ㟁⋡ࡢ㖟ࢼࣀ࣡࢖ࣖ」ྜࢼࣀ
࣮࣌ࣃ࣮ࢆᇶᯈ࡟⏝࠸࡚࢔ࣥࢸࢼࢹࣂ࢖ࢫࢆస〇ࡍࡿ࡜ࠊඖࡢࢼࣀ࣮࣌ࣃ࣮ᇶᯈࡸỗ⏝ࣉࣛࢫࢳࢵࢡᇶ
ᯈ࡜ẚ࡭࡚ࠊࢱ࣮ࢤࢵࢺࡢ㟁Ἴ࿘Ἴᩘ࡜Ⰻዲ࡞ឤᗘࢆಖࡗࡓࡲࡲࠊࢹࣂ࢖ࢫࢆ⣙༙ศ࡟ᑠᆺ࠿ࡘ㍍㔞໬
ࡍࡿࡇ࡜࡟ᡂຌࡋࡲࡋ
ࡓࠋࡲࡓࠊ1000 ᅇࡢ⧞ࡾ
㏉ࡋᢡࡾ᭤ࡆヨ㦂ᚋࡶ
࢔ࣥࢸࢼᛶ⬟ࢆ⥔ᣢࡍ
ࡿඃࢀࡓࣇࣞ࢟ࢩࣈࣝ
ᛶࡶ♧ࡋࡲࡋࡓࠋIoT ♫
఍࡟㈨ࡍࡿᑠᆺ࠿ࡘࣇ
ࣞ࢟ࢩࣈࣝ࡞࣮࣌ࣃ࣮
࢔ࣥࢸࢼࢹࣂ࢖ࢫ࡜ࡋ
࡚ᮇᚅࡀᣢࡓࢀࡲࡍࠋ
ᅗ 㧗ㄏ㟁ࢼࣀ࣮࣌ࣃ࣮ᇶᯈ㸦ᕥ㸧ࢆ⏝࠸࡚స〇ࡋࡓᑠᆺࣇࣞ࢟ࢩࣈࣝ࢔ࣥࢸࢼ㸦ྑ㸧
― 87 ―
⏕య㜵ᚚᏛ◊✲ศ㔝㸦➨㸱ࣉࣟࢪ࢙ࢡࢺ◊✲ศ㔝㸧
≉௵ᩍᤵ
≉௵෸ᩍᤵ
≉௵ຓᩍ
஦ົ⿵బဨ
ὴ㐵⫋ဨ
ᒣཱྀ
୰ᓥ
Ḉ஭
ᯇᒸ
໭ᕝ
᫂ே
Ⰻ௓
ၨ௓
⃈ᜨ
බᜨࠊ㡑 ⌋⌇
a) ᴫせ
⏕≀⏺࡟ࡣࠊ␗≀᤼ฟࢺࣛࣥࢫ࣏࣮ࢱ࣮࡜ࡼࡤࢀࡿ୍⩌ࡢ⭷㍺㏦యࡀᗈࡃศᕸࡋ࡚࠸࡚ࠊ⣽⬊ࣞ࣋ࣝ
࡟࠾ࡅࡿࡶࡗ࡜ࡶᇶᮏⓗ࡞⏕య㜵ᚚᶵᵓ࡜࡞ࡗ࡚࠸ࡿࠋᮏ◊✲ศ㔝࡛ࡣࠊ⣽⳦࠿ࡽື≀⣽⬊ࡲ࡛ࠊ⏕య
␗≀᤼ฟࢺࣛࣥࢫ࣏࣮ࢱ࣮ࡢᵓ㐀࡜ᶵ⬟ࠊⓎ⌧ไᚚࠊ⏕⌮ⓗᙺ๭ࡢゎᯒ࠿ࡽࠊ᪂つ᤼ฟࢱࣥࣃࢡ㑇ఏᏊ
ࡢ᳨⣴ࡲ࡛ᖜᗈࡃ◊✲ࢆᒎ㛤ࡋ࡚࠸ࡿࠋ⚾ࡓࡕࡢ◊✲ᐊ࡛ࡣࠊ⣽⳦ࡢ௦⾲ⓗ␗≀᤼ฟ㍺㏦య AcrB ࡢ⤖
ᬗᵓ㐀ࢆୡ⏺࡟ඛ㥑ࡅ࡚Ỵᐃࡋࠊ⣽⬊⭷ࣂ࣮࣒࢟ࣗࢡ࣮ࣜࢼ࣮࡛࠶ࡿ஦ࠊ࣐ࣝࢳࢧ࢖ࢺ⤖ྜࡀከ๣ㄆ㆑
ࡢᇶ♏࡛࠶ࡿ஦ࠊࠕfunctionally rotatingࠖཬࡧࠕperistaltic pumpࠖ࡜࠸࠺᤼ฟࡢศᏊᶵᵓࢆゎ᫂ࡋ࡚
ࡁࡓࠋࡉࡽ࡟ࠊ᭱ึࡢ㜼ᐖ๣⤖ྜᆺ AcrB ཬࡧ MexB ࡢ⤖ᬗᵓ㐀ゎᯒ࡟ࡶᡂຌࡋࡓࠋ2014 ᖺᗘࡣ
AcrAB-TolC ࡜࠸࠺ࢩࢫࢸ࣒ࡢ඲యീࢆゎ᫂ࡍࡿ㊊ࡀ࠿ࡾ࡜ࡋ࡚ AcrB-AcrA ⼥ྜࢱࣥࣃࢡࢆᵓ⠏ࡋࡓࠋ
b) ᡂᯝ
࣭$FU%$FU$ ⼥ྜࢱࣥࣃࢡ
ࣔࣝẚ 1㸸1 ࡢ⼥ྜࢱࣥࣃࢡࡣ㔝⏕ᆺ࡜ྠ➼ࡢ᤼ฟάᛶࢆ᭷ࡍࡿࡇ࡜ࢆ☜ㄆࡋࠊ⤖ᬗ໬࡟ྥࡅࡓ኱㔞
Ⓨ⌧࡟ࡶᡂຌࡋࡓࠋᙜึ୍
ᐃ๭ྜ࡛ AcrA 㒊ศࢆḞᦆ
ࡋࡓࢱࣥࣃࢡࡀྵࡲࢀࡓ
ࡀࠊ࣮ࣜࣥ࢝ࡢ⭷㈏㏻㒊ศ
ࢆ AcrA ࢩࢢࢼࣝ࣌ࣉࢳࢻ
࠿ࡽ AcrB ࡢ⭷㈏㏻࡬ࣜࢵ
ࢡࢫ TM7 ࡬ࡢኚ᭦ࡍࡿࡇ
࡜࡟ࡼࡾ␗≀᤼ฟάᛶࢆ
⥔ᣢࡋࡘࡘ኱ᖜ࡞ᨵၿࢆ
㐩ᡂࡋࡓࠋࡲࡓᅗ୰㯤Ⰽ࡛
♧ࡋࡓ࣮ࣜࣥ࢝ࡢ⣽⬊㉁
ᅗ 1. AcrB-AcrA ⼥ྜࢱࣥࣃࢡࡢࢹࢨ࢖ࣥ࡜Ⓨ⌧☜ㄆ
㒊ศࢆ᭱ᑠ໬ࡋࠊࡼࡾ⤖ᬗ
a. AcrB-linker-AcrA ࡢᶍᘧᅗ, b. ⼥ྜࢱࣥࣃࢡࡢタィ, c. western blot
໬䛻㐺䛧䛯⼥ྜ䝍䞁䝟䜽䛾
ྲྀᚓ䛻䜒ᡂຌ䛧䛯䚹㻌
࣭$FU$$FU%7RO&㸱⪅」ྜయࡢㄪ〇
᭱⤊┠ⓗ࡛࠶ࡿ AcrA-AcrB-TolC㸱⪅」ྜయࡢᵓ㐀ゎᯒ࡟ྥࡅ
࡚ C ᮎ࡟ FLAG ࢱࢢࢆ௜ຍࡋࡓእ⭷ࢳࣕࢿࣝ TolC ࡢ኱㔞Ⓨ⌧ࠊ
⢭〇ἲࢆ☜❧ࡋࡓࠋᏳᐃ㸱⪅」ྜయసᡂ࡬ࡢ࢔ࣉ࣮ࣟࢳ࡜ࡋ࡚
AcrB-TolC ⤖ྜ㠃࡬ࡢࢩࢫࢸ࢖ࣥᑟධ࡟ࡼࡿࢪࢫࣝࣇ࢕ࢻ⤖ྜ
ᙧᡂࢆ฼⏝ࡍࡿࡇ࡜࡜ࡋࡓࠋࢩࢫࢸ࢖ࣥᑟධኚ␗యࢆ⏝࠸ࡓ in
vivo ᐇ㦂࡟࠾࠸࡚ࠊAcrB-AcrA -TolC 㸱⪅」ྜయࡢᙧᡂࢆ☜ㄆ
ࡋࡓ(ᅗ 2)ࠋ௒ᚋࡣࢩࢫࢸ࢖ࣥᯫᶫ࡛Ᏻᐃ໬ࡋࡓ AcrB-TolC 」ྜ
య࡜ AcrA ࡢඹ⤖ᬗ໬ࠊࡶࡋࡃࡣ AcrB-AcrA ⼥ྜࢱࣥࣃࢡ-TolC
」ྜయࡢ⤖ᬗ໬ࢆ⾜࠸ࠊ㸱⪅」ྜయᵓ㐀ゎᯒࢆ┠ᣦࡍࠋ
― 88 ―
ᅗ 2. Ᏻᐃ㸱⪅」ྜయࡢㄪᩚ
⑌ᝈ⢾㙐ࢆ୰ᚰ࡜ࡋࡓࢣ࣑࢝ࣝࣂ࢖࢜ࣟࢪ࣮ศ㔝㸦⌮◊Ѹ⏘◊࢔ࣛ࢖࢔ࣥࢫࣛ࣎㸧
ᣍ࡬࠸ᩍᤵ
ᣍ࡬࠸ᩍᤵ
ᣍ࡬࠸ᩍဨ
࢔ࣛ࢖࢔ࣥࢫ㐃ᦠ᥎㐍ဨ
㇂ཱྀ ┤அ
኱ᆤ ࿴᫂
㧗 ྀ➗ࠊ᫝㔠 ᏹ᫛
㣤ᓥ㡰ᏊࠊEmmanuel Siota PALACPACࠊ⏣୰ඃᏊ
a) ᴫせ
⢾㙐ࡣ᰾㓟ࠊࢱࣥࣃࢡ㉁࡜࠸ࡗࡓ⏕࿨άືࢆᢸ࠺㙐≧⏕య㧗ศᏊ࡟ࡘࡄࠊ➨㸱ࡢ⏕࿨㙐࡜ゝࢃࢀ࡚࠸
ࡿࠋ㧗➼⏕࿨యࡣ⢾ࢆ༢࡞ࡿ࢚ࢿࣝࢠ࣮ࢆᚓࡿᡭẁ࡜ࡋ࡚ࡔࡅ࡛࡞ࡃࠊ⢾ࢆ㙐≧࡟ࡘ࡞ࡄ஦࡛⭾኱࡞⏕
࿨᝟ሗࢆఏ࠼ࡿ᝟ሗศᏊࠕ⢾㙐ࠖ࡜ࡋ࡚ࡶ฼⏝ࡋ࡚࠸ࡿࡢ࡛࠶ࡿࠋᡃࠎࡢಶయࡣ⣙㸴㸮඙ಶࡢ⣽⬊ࡢ㞟
ྜయ࡛࠶ࡿ࡜࡜ࡶ࡟ࠊࡑࢀࡽࡀ࠾஫࠸࡟㧗ḟⓗ࡞ㄪ࿴ࡢ࡜ࢀࡓୡ⏺࡜ࡶ࠸࠼ࡿࠋ⣽⬊ࡢ⾲㠃࡟ࡣ࢔ࣥࢸ
ࢼࡢࡼ࠺࡟✀ࠎࡢ⢾㙐ࡀᙇࡾᕠࡽࡉࢀ࡚࠾ࡾࠊ⢾㙐ࢆ௓ࡋࡓ᝟ሗఏ㐩ࢆᢸࡗ࡚࠸ࡿࠋ㏆ᖺࡢ⢾㙐⏕≀Ꮫ
ࡢⓎᒎ࡟ࡼࡾ⢾㙐ࡀࢥ࣮ࢻࡍࡿ᝟ሗࡀᚎࠎ࡟ゎㄞࡉࢀࠊ⢾㙐ࡀ⏕࿨ᶵ⬟ࡢ⥔ᣢ࡟୙ྍḞ࡛࠶ࡿ஦ࡀ᫂ࡽ
࠿࡟࡞ࡗ࡚ࡁࡓࠋ஦ᐇࠊ✀ࠎࡢ⢾㙐ྜᡂ㞀ᐖࡀ࢞ࣥࠊ⮬ᕫච␿⑌ᝈࠊච␿୙඲ࠊ⅖⑕ᛶ⑌ᝈ࡞࡝ᵝࠎ࡞
㞴἞⑌ᝈࡸ⢾ᒀ⑓ࠊ៏ᛶ㛢ሰᛶ⫵⑌ᝈ࡜࠸ࡗࡓ⏕ά⩦័⑓ࢆᘬࡁ㉳ࡇࡍࡇ࡜ࡀ᫂ࡽ࠿࡟࡞ࡾࡘࡘ࠶ࡿࠋ
ᮏ◊✲㒊㛛࡛ࡣ⏕໬Ꮫⓗ࣭ศᏊ㑇ఏᏛⓗ◊✲ᡭἲ࡟ࡼࡾ⢾㙐␗ᖖ࡟ࡼࡾᘬࡁ㉳ࡇࡉࢀࡿ⑌ᝈࡢ࣓࢝ࢽ
ࢬ࣒ࡢゎ᫂ࠊ⢾㙐ࢆࢱ࣮ࢤࢵࢺ࡜ࡋࡓ⑌ᝈデ᩿࣐࣮࣮࢝ࡢ㛤Ⓨࠊࡉࡽ࡟⢾㙐ࢆ⏝࠸ࡓ᪂つ἞⒪ἲࡢ㛤Ⓨ
ࢆ┠ᣦࡋࡓ◊✲ࢆ㐍ࡵ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭៏ᛶ㛢ሰᛶ⫵⑌ᝈࡢ⑓ែ࡟࠾ࡅࡿ⢾㙐ࡢᙺ๭
COPD ࡣࠊ㓟⣲࡜஧㓟໬Ⅳ⣲ࢆ஺᥮ࡍࡿ⫵⬊ࡀ◚
ቯࡉࢀࡿ⫵Ẽ⭘࡜៏ᛶẼ⟶ᨭ⅖ࡢ⥲⛠࡛ࠊẼ㐨㛢ሰ
࡟ࡼࡿ࿧྾ᅔ㞴ࢆᘬࡁ㉳ࡇࡍࠋ࢘࢖ࣝࢫࡸ⣽⳦࡟ឤ
ᰁࡍࡿ࡜ᛴ⃭࡟⑕≧ࡀᝏ໬ࡋࠊṚஸ⋡ࡀ㠀ᖖ࡟㧗ࡃ
࡞ࡿࠋࢃࡀᅜࢆྵࡵୡ⏺ⓗ࡟ᝈ⪅ᩘࡀከࡃࠊࡑࡢ἞
⒪ἲࡢ㛤Ⓨࡀႚ⥭ࡢㄢ㢟࡜࡞ࡗ࡚࠸ࡿࠋCOPD Ⓨ⑕
࡟ࡣႚ↮࡞࡝ࡢእⓗせᅉ࡜ࡉࡲࡊࡲ࡞㑇ఏⓗせᅉࡀ
㛵ಀࡋ࡚࠸ࡿ࡜⪃࠼ࡽࢀ࡚࠸ࡿࠋࡑࡢ୰ࠊ⢾㌿⛣㓝
⣲ alpha 1,6 fucosyltransferase (Fut8)㑇ఏᏊኚ␗࣐࢘ࢫ
࡟࠾ࡅࡿႚ↮ㄏⓎᛶ⫵Ẽ⭘ࡢⓎ⑕࡟ࡘ࠸࡚ྲྀࡾ⤌ࢇ
࡛࠸ࡿࠋFut8 Ḟᦆ࣐࢘ࢫࡣ TGF-ȕ ཷᐜయ࡟ᑐࡍࡿࢥ
࢔ࣇࢥ࣮ࢫ௜ຍࡀ࡞ࡉࢀ࡞࠸ࡓࡵ TGF-ȕ ཷᐜయࢆ௓
ࡋࡓࢩࢢࢼࣝࡀῶᙅࡉࢀࠊMMP ࡢάᛶ໬ࡀ㉳ࡇࡉࢀ
ࡿࠋࡇࢀࡀᘬࡁ㔠࡜࡞ࡾ⫵⬊ࡀ◚ቯࡉࢀ⫵Ẽ⭘ᵝ⑓
ኚࢆ♧ࡍࠋ
᭦࡟ࠊႚ↮᭚㟢ᐇ㦂ゎᯒ࠿ࡽࠊ࣊ࢸ࣐ࣟ࢘ࢫࡣࡁࢃࡵ࡚▷᫬㛫࡛⫵Ẽ⭘ࢆⓎ⑕ࡋࠊࡑࡢ᪩ᮇⓎ⑕ࡢ⫼
ᬒ࡟ࡣ≉␗ⓗ࡞᫬ᮇ࡟ MMP ࡢⓎ⌧ཬࡧάᛶࡢୖ᪼ࡀ࠶ࡗࡓࠋFUT8 ࡢάᛶపୗࡣ⏕య࡟ႚ↮ࡸ✵Ẽở
ᰁ࡞࡝ࡢእくᛶᅉᏊ࡬ࡢ㧗ឤཷᛶࢆࡶࡓࡽࡋࠊࡉࡽ࡟⫵㛫㉁ࡢྜᡂ࡜◚ቯࡢࣂࣛࣥࢫࢆᔂࡋࠊ⫵Ẽ⭘ࡢ
Ⓨ⑕࡟ࡘ࡞ࡀࡿ࡜⪃࠼ࡽࢀࡿࠋࡲࡓࠊࣄࢺ COPD ᝈ⪅࡟࠾ࡅࡿ⾑୰ FUT8 άᛶࡀ COPD ࡢ㐍⾜㸦⬚㒊
CT ࡟࠾ࡅࡿ⫵Ẽ⭘ࡢ⛬ᗘ㸧࡜㈇࡟┦㛵ࡍࡿ࡜࠸࠺▱ぢࢆ㐃ᦠ◊✲࡟ࡼࡗ࡚ᚓ࡚࠸ࡿࠋࡇࢀࡽࡢ◊✲࡟
ࡼࡗ࡚ࠊFut8 ࡀࣄࢺ COPD ࡢ host factor ࡜ࡋ࡚ࡢ఩⨨࡙ࡅࡀࡉࡽ࡟㩭᫂࡟࡞ࡗࡓࠋ
― 89 ―
࣭⢾ᒀ⑓Ⓨ⑕࣓࢝ࢽࢬ࣒࡟࠾ࡅࡿ⢾㙐ᶵ⬟ࡢ◊✲
ᡃࠎࡣࠊ⮅⮚ ȕ ⣽⬊ࡢࢢࣝࢥ࣮ࢫࢭࣥࢧ࣮ࢱࣥࣃࢡ㉁࡛
࠶ࡿࢢࣝࢥ࣮ࢫࢺࣛࣥࢫ࣏࣮ࢱ࣮㸰ࡀ⢾㌿⛣㓝⣲ GnT-IVa
࡟ࡼࡾ N-ᆺ⢾㙐ಟ㣭ࢆཷࡅࡿࡇ࡜࡛⣽⬊⾲㠃࡟␃ࡲࡿࡇ࡜
ࡀ࡛ࡁࠊ⤖ᯝࠊ⾑⢾ࣞ࣋ࣝ࡟ᛂࡌࡓ࢖ࣥࢫࣜࣥศἪࡀ࡛ࡁ
ࡿࡇ࡜ࢆⓎぢࡋࡓࠋࡲࡓࠊGnT-IVa ࡢḞᦆࡸ㧗⬡⫫㣗ᦤྲྀ
࡟ࡼࡿ GnT-IVa Ⓨ⌧పୗࡀࡇࡢ࣓࢝ࢽࢬ࣒ࢆ◚⥢ࡉࡏࠊ⤖
ᯝࠊ࢖ࣥࢫࣜࣥศἪ୙඲ࢆ࡜ࡶ࡞࠺㸰ᆺ⢾ᒀ⑓ࢆⓎ⑕ࡍࡿ
ࡇ࡜ࢆゎ᫂ࡋࡓࠋୖ㏙ࡢ⑌ᝈᶵᗎࡣᐇ㝿ࡢࣄࢺ㸰ᆺ⢾ᒀ⑓
Ⓨ⑕ࡢせᅉ࡜࡞ࡗ࡚࠸ࡿࡇ࡜ࢆゎ᫂ࡋࡓࠋࡇࡢ▱ぢࢆࡶ࡜
࡟ࠊGnT-IVa ᑟධ࡟ࡼࡿ⢾ᒀ⑓἞⒪ࡢྍ⬟ᛶࢆ᳨ウࡋ࡚࠸
ࡿࠋ
࣭㧗ឤᗘ࣭㧗≉␗ᛶ࢞ࣥデ᩿࣐࣮࣮࢝ࡢ㛤Ⓨ
⢾ࢱࣥࣃࢡ㉁⢾㙐ࡢ⒴ᛶኚ໬ࢆᢠయ࡜ࣞࢡࢳࣥ(⢾⤖ྜࢱ
ࣥࣃࢡ㉁ࡢ⥲⛠)ࢆ⏝࠸࡚≉␗ⓗ࡟ ᐃ࡛ࡁࢀࡤࠊ⒴ࡢ᪩ᮇデ
᩿࡟ά⏝࡛ࡁࡿࠋࡲࡓࠊ㧗㢠࡞ᶵჾࢆᚲせ࡜ࡏࡎ ELISA ࡢࢩ
ࢫࢸ࣒ࢆ⏝࠸࡚ ᐃྍ⬟࡞ࡇ࡜࠿ࡽ᭷⏝࡞᪂つᢏ⾡࡜࡞ࡾᚓ
ࡿࠋᡃࠎࡣ⫢⣽⬊⒴࣐࣮࣮࢝࡜ࡋ࡚▱ࡽࢀࡿࣇࢥࢩࣝ໬Ș
ࣇ࢙ࢺࣉࣟࢸ࢖ࣥAFPࢆࣔࢹࣝ࡜ࡋ࡚ࠊࣇࢥࢩࣝ໬ࢱࣥࣃ
ࢡ㉁࣐࣮࣮࢝ࡢ㧗ឤᗘ ᐃἲࡢ㛤Ⓨ࡟ྲྀࡾ⤌ࡳࠊ⾑ΎᏑᅾୗ
࡛ 1.25-80ng/mlࡢࣇࢥࢩࣝ໬ AFP ࢆᐃ㔞 ᐃྍ⬟࡞ᢠయ
ࣞࢡࢳࣥ EIA ἲࡢ㛤Ⓨ࡟ᡂຌࡋࡓࠋ⌧ᅾࠊᮏ ᐃἲࡢᐇ⏝໬
࢟ࢵࢺ໬࡟ྥࡅࡓ᮲௳᳨ウࢆ⾜ࡗ࡚࠸ࡿࠋ
࣭᪂つࡢ⢾㙐ಟ㣭ไᚚᅉᏊ (133 ࡢྠᐃ࡜ᶵ⬟ゎ᫂
⚾㐩ࡣ⬻≉␗ⓗ࡟Ⓨ⌧ࡍࡿศᒱᆺ O-Man ⢾㙐ࡀ⚄⤒⣽⬊
࡟࠾ࡅࡿ෌࣑࢚ࣜࣥ໬ࡢ㐣⛬࡟῝ࡃ㛵㐃ࡍࡿࡇ࡜ࢆゎ᫂ࡋ
ࡘࡘ࠶ࡿࠋᮏ⢾㙐ᵓ㐀ࡣ⬻≉␗ⓗ࡟Ⓨ⌧ࡍࡿ⢾㌿⛣㓝⣲ࡢ
୍ࡘ࡛࠶ࡿ GnT-IX ࡟ࡼࡗ࡚⏕ྜᡂࡉࢀࡿࠋ⚾㐩ࡣᮏ㓝⣲
࡟ᑐࡍࡿෆᅾᛶࡢ㜼ᐖάᛶࢆ Neuro2a(N2a)⚄⤒ⱆ⭘⣽⬊୰
࡟ぢฟࡋࡓࠋࡉࡽ࡟㜼ᐖάᛶࡢ༢㞳⢭〇࡜㉁㔞ศᯒ࡟ࡼࡗ
࡚ࠊࡑࡢᐇయࡀ࢚ࢡࢺࢾࢡࣞ࢜ࢳࢻ ࣆࣟ࣍ࢫࣇ࢓ࢱ࣮ࢮ/
࣍ࢫ࣍ࢪ࢚ࢫࢸ࣮ࣛࢮ 3(ENPP3)࡜࿧ࡤࢀࡿࢾࢡࣞ࢜ࢳࢻ
ࡢຍỈศゎ㓝⣲࡛࠶ࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓࠋࡉࡽ࡟⚾㐩ࡣ
ENPP3 ࡟ࡼࡿ GnT-IX 㜼ᐖࡢᶵᗎゎ᫂࡟╔ᡭࡋࠊ⢭〇⤌᥮
࠼యࢆ⏝࠸ࡓヨ㦂⟶ෆ࡟࠾ࡅࡿ✀ࠎ㓝⣲Ꮫⓗゎᯒ࡟ࡼࡾࠊ
1) ENPP3 ࡀ GnT-IX ཯ᛂ࡟ᚲ㡲ࡢ⢾ࢾࢡࣞ࢜ࢳࢻᇶ㉁
UDP-GlcNAc ࢆ UMP ࡜ GlcNAc-1 ࣜࣥ㓟࡟ຍỈศゎࡍࡿࡇ
࡜ࠊࡲࡓ 2) ENPP3 ཯ᛂ⏘≀࡛࠶ࡿ UMP ࡀ GnT-IX ࡟ᑐࡋ
࡚ᙉຊ࡞㜼ᐖຠᯝࢆⓎ᥹ࡍࡿࡇ࡜࡞࡝ࢆ᫂ࡽ࠿࡟ࡋࡓࠋḟ
࡟⚾㐩ࡣ ENPP3 ࡟ࡼࡿ⢾㌿⛣㓝⣲㜼ᐖࡀ⏕⣽⬊ࣞ࣋ࣝ࡟
࠾࠸࡚ࡶᶵ⬟ࡋᚓࡿࡢ࠿࡝࠺࠿࡟ࡘ࠸࡚ࠊENPP3 Ⓨ⌧ࢆᢚ
ไࡋࡓ⚄⤒ⱆ⭘⣽⬊ࢆ⏝࠸᳨࡚ウࡋࠊ1) ENPP3 ࡀ✀ࠎࡢ⣽
⬊ෆ⢾ࢾࢡࣞ࢜ࢳࢻࢆ⏕⌮ⓗᇶ㉁࡜ࡋ࡚ຍỈศゎࡍࡿࡇ࡜ࠊ
ࡲࡓ 2) ENPP3 Ⓨ⌧ࡢᢚไ࡟ࡼࡾᐇ㝿࡟⣽⬊࡛ࣞ࣋ࣝ⢾㙐ಟ㣭ࣃࢱ࣮ࣥࡢኚືࡀច㉳ࡉࢀࡿࡇ࡜࡞࡝ࢆ
ᐇドࡋࡓࠋࡇࢀࡣࠕ⢾ࢾࢡࣞ࢜ࢳࢻ௦ㅰࢆ௓ࡋࡓ⣽⬊ᶵ⬟ไᚚࠖ࡜࠸࠺᪂ࡋ࠸ไᚚᴫᛕ๰ฟ࡟⧅ࡀࡿⓎ
ぢ࡜࡞ࡾᚓࡿࠋ
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［ 附 2 ］ 各附属研究施設等の組織と活動
⏘ᴗ⛉Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮
ࢭࣥࢱ࣮㛗㸦ව௵㸧ᩍᤵ ྜྷ⏣ 㝧୍
஦ົ⿵బဨ
ᱵᮏ ⏤㤶
ᴫせ
⏘ᴗ⛉Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮ࡣࠊཎᏊ࣭ศᏊࢆ✚ࡳୖࡆ࡚ᮦᩱࢆ๰〇ࡍࡿ࣎ࢺ࣒࢔ࢵࣉࢼࣀࢸ
ࢡࣀࣟࢪ࣮ࠊᮦᩱࢆᴟ㝈ࡲ࡛๐ࡗ࡚ࢼࣀࢹࣂ࢖ࢫࢆస〇ࡍࡿࢺࢵࣉࢲ࢘ࣥࢼࣀࢸࢡࣀࣟࢪ࣮ࠊࡉࡽ࡟ࡑ
ࢀࡽࡢ⼥ྜ࡟ࡼࡿ⏘ᴗᛂ⏝ࢆ┠ᣦࡋ࡚⥲ྜⓗ࡟ࢼࣀࢧ࢖࢚ࣥࢫ࣭ࢼࣀࢸࢡࣀࣟࢪ࣮ࢆ᥎㐍ࡍࡿࡇ࡜ࢆ┠
ⓗ࡜ࡋ࡚ࠊ2002 ᖺ࡟⏘ᴗ⛉Ꮫ◊✲ᡤ࡟タ⨨ࡉࢀࡓ඲ᅜึࡢࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮࡛࠶ࡿࠋ
タ❧ᙜึࡣࠊᑓ௵ 3ࠊᡤෆව௵ 7ࠊᏛෆව௵ 3ࠊᅜෆ࣭እᅜேᐈဨ 3 ࡢ 16 ◊✲ศ㔝࠿ࡽ࡞ࡿ 3 ◊✲㒊
㛛ไ࡛Ⓨ㊊ࡋࡓࠋ2003 ᖺ࡟ࡣࢼࣀࢸࢡࣀࣟࢪ࣮⥲ྜ◊✲Ჷࡀ᏶ᡂࡋࠊ඲Ꮫࡢࢼࣀࢸࢡࣀࣟࢪ࣮◊✲ࢆ᥎
㐍ࡍࡿࡓࡵࡢ࣮࢜ࣉࣥࣛ࣎ࣛࢺ࣮ࣜࡢ㐠⏝ࡶ㛤ጞࡉࢀࡓࠋࡲࡓࠊ⏘ᏛᐁࡢᏛእࢼࣀࢸࢡࣀࣟࢪ࣮◊✲⪅
ࡢࡓࡵࡢඹྠ᪋タ࡜ࡋ࡚ࢼࣀࢸࢡࣀࣟࢪ࣮ࣉࣟࢭࢫࣇ࢓ࣥࢻ࣮ࣜࡀタ⨨ࡉࢀᨭ᥼άືࢆ㛤ጞࡋࡓࠋ2004
ᖺ࡟ࡣ 20 ◊✲ศ㔝࠿ࡽ࡞ࡿ 4 ◊✲㒊㛛࡟ᣑ඘ࡉࢀࡓࠋࡉࡽ࡟ࠊ2006 ᖺ࡟ࢼࣀຍᕤᐊࡀタ⨨ࡉࢀࠊ2007
ᖺ࡟ࢼࣀࢸࢡࣀࣟࢪ࣮ࣉࣟࢭࢫࣇ࢓ࣥࢻ࣮ࣜ࡟௦ࢃࡗ࡚㜰኱」ྜᶵ⬟ࢼࣀࣇ࢓࢘ࣥࢲࣜࡀࢫࢱ࣮ࢺࡋ
ࡓࠋࡑࡋ࡚ࠊ2009 ᖺ࡟⏘◊ࡢ኱ᖜ࡞ᨵ⤌࡟క࠸ࠊ᪂ࡋ࠸⤌⧊࡟඘ᐇᙉ໬ࡉࢀࡓࠋ
᪂ࡋ࠸⏘ᴗ⛉Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮ࡣࠊᑓ௵ 6 ◊✲ศ㔝ࢆ୰ᚰ࡜ࡋ࡚ࠊᡤෆව௵ 3ࠊᏛෆව௵
6ࠊᅜෆ࣭እᅜேᐈဨ 3 ࡢ 18 ◊✲ศ㔝࠿ࡽ࡞ࡾࠊࡉࡽ࡟ࠊ᪂ࡓ࡟ࢼࣀࢸࢡࣀࣟࢪ࣮࡟≉໬ࡋࡓ౪⏝᭱ඛ
➃ᶵჾࢆタ⨨ࡍࡿࢼࣀࢸࢡඛ➃ᶵჾᐊࡀタࡅࡽࢀࡓࠋᙜึ௜ࡉࢀ࡚࠸ࡓ᫬㝈ࢆ᧔ᗫࡋ࡚ࠊࣁ࣮ࢻࠊࢯࣇ
ࢺࠊ⏕యᮦᩱࡢᖜᗈ࠸ศ㔝࡟࠾࠸࡚ࢺࢵࣉࢲ࢘ࣥ࡜࣎ࢺ࣒࢔ࢵࣉࡢࢼࣀࣉࣟࢭࢫࡢ⼥ྜ࡟ࡼࡿࢼࣀࢩࢫ
ࢸ࣒ࢆ๰ᡂࡋࠊࡉࡽ࡟ࠊ⌮ㄽ࠾ࡼࡧホ౯࡜ࡢ◊✲⼥ྜ࡟ࡼࡾ᪂ࡓ࡞ᒎ㛤ࢆᅗࡿࡇ࡜࡛ࢼࣀࢸࢡࣀࣟࢪ࣮
◊✲ࢆᏛ㝿⼥ྜᇶ┙⛉Ꮫᢏ⾡࡬࡜Ⓨᒎࡉࡏࡿࡇ࡜ࢆ┠ᣦࡋ࡚࠸ࡿࠋࡲࡓࠊᏛෆ࣭ᅜෆ࣭ᅜእࡢከᙬ࡞ࢿ
ࢵࢺ࣮࣡ࢡࢆᵓ⠏ࡋ࡚ࠊࢼࣀࢸࢡࣀࣟࢪ࣮◊✲ࡢᣐⅬ࡜࡞ࡿࡇ࡜ࢆ┠ᶆ࡜ࡋ࡚࠸ࡿࠋ
― 93 ―
ࢼࣀᶵ⬟ᮦᩱࢹࣂ࢖ࢫ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
እᅜேᣍ࡬࠸◊✲ဨ
኱Ꮫ㝔Ꮫ⏕
Ꮫ㒊Ꮫ⏕
◊✲⏕
ᢏ⾡⿵బဨ
஦ົ⿵బဨ
⏣୰ ⚽࿴
⚄ྜྷ ㍤ኵ
᭹㒊 ᱻࠊ⸨ཎ ᏹᖹ
Alexis Borowiak㸦ᖹᡂ 26 ᖺ 7 ᭶ 15 ᪥㹼ᖹᡂ 27 ᖺ 7 ᭶ 14 ᪥㸧
㧗ぢ ⱥྐࠊNguyen Thi Van AnhࠊWei Tingtingࠊᒣᓮ ⩧ኴࠊᇼ ❳ஓࠊ
బࠎᮌ ⩼ࠊᕥᾏ ᗣኴ㑻ࠊ୰ᮧ ᣅ㑻ࠊ኱Ụ ᗣᏊ
ᆤ⏣ ᬛྖࠊ୰⃝ ᐦ
ᮤ ᫂Ᏹ
ᒾᇛ ᩥ
ዟᮏ ᭸Ꮚ
a) ᴫせ
ᵝࠎ࡞እሙ(ගࠊ☢ሙࠊ㟁ሙࠊ ᗘ)࡟ᑐࡋᕧ኱࡟ᛂ⟅ࡋከᙬ࡞≀ᛶࢆ♧ࡍ㑄⛣㔠ᒓ㓟໬≀ᮦᩱ⩌ࢆᑐ
㇟࡜ࡋࠊࢺࢵࣉࢲ࢘ࣥࢼࣀࢸࢡࣀࣟࢪ࣮(㉸ᚤ⣽ࢼࣀຍᕤᢏ⾡)࡜࣎ࢺ࣒࢔ࢵࣉࢼࣀࢸࢡࣀࣟࢪ࣮(㉸ⷧ
⭷࣭࣊ࢸࣟ᥋ྜ࣭ேᕤ᱁Ꮚ⤖ᬗᡂ㛗)ࢆ⼥ྜࡍࡿࡇ࡜࡟ࡼࡗ࡚ࠊᮃࡳࡢ఩⨨࡟ࠊᮃࡳࡢ≀㉁࣭㟁Ꮚ≧ែࡢ
✵㛫ⓗ㓄⨨࡜ḟඖᛶࢆࢼࣀࢫࢣ࣮࡛ࣝ௵ព࡟ไᚚࡍࡿᢏ⾡᪉ἲㄽࢆ☜❧ࡋࠊࡑࢀ࡟ࡼࡗ࡚ᚓࡽࢀࡿ㓟໬
≀ࢼࣀᵓ㐀ࡀ♧ࡍᇶ♏≀ᛶࡢ⌮ゎࢆ㏻ࡋ࡚ࠊ㧗ᶵ⬟࠿ࡘ┬࢚ࢿࣝࢠ࣮㥑ືࡢ᪂ཎ⌮ࢹࣂ࢖ࢫᵓ⠏࡟ྲྀࡾ
⤌ࢇ࡛࠸ࡿࠋ௒ᖺᗘࡢ୺࡞ᡂᯝࢆ௨ୗ࡟ヲ㏙ࡍࡿࠋ
b) ᡂᯝ
࣭஧㓟໬ࣂࢼࢪ࣒࢘(VO2)ࡢ㟁Ꮚ┦ࢻ࣓࢖ࣥࡢࢧ࢖ࢬไᚚ࡜┦㌿⛣ࡢ࣓࢝ࢽࢬ࣒ゎ᫂
VO2 ࡣࠊ㟁ሙࠊගࠊ⇕࡞࡝ࡢእሙ࡟ࡼࡾ㔠ᒓ̿⤯⦕య㟁Ꮚ┦
㌿⛣(MIT)ࢆᘬࡁ㉳ࡇࡋࠊᩘ᱆࡟ࡶཬࡪᕧ኱࡞᢬ᢠ⋡ኚ໬ࢆ♧ࡍ
ࡓࡵᑗ᮶ࡢ㟁Ꮚࢹࣂ࢖ࢫ࡟࡜ࡗ࡚㨩ຊⓗ࡞ᮦᩱ࡛࠶ࡿࠋ┦㌿⛣
Ⅼ㏆ഐ࡛ࡣࠊࢼࣀ㹼࣐࢖ࢡࣟࢫࢣ࣮ࣝࡢ⤯⦕యࠊ㔠ᒓ㟁Ꮚ㞟ᅋ
ࡀධࡾΰࡌࡗࡓ┦ΰྜ≧ែ࡜࡞ࡗ࡚࠾ࡾࠊ✵㛫ⓗ࡟ࣛࣥࢲ࣒࡟
ฟ⌧ࡍࡿ㔠ᒓ㟁Ꮚ┦ࢻ࣓࢖ࣥ࡟ᑐࡋ࡚ࠊಶࠎ࡟┦㌿⛣ไᚚࡀྍ
⬟࡟࡞ࢀࡤࠊࢻ࣓࢖ࣥࢆࣅࢵࢺ࡜ࡍࡿ᝟ሗグ᠈ࠊ㟁Ꮚ┦㓄ิࢆ
ไᚚࡋࡓ㟁Ꮚ┦ࢧ࣮࢟ࢵࢺ➼ࠊ᪂つ࢚ࣞࢡࢺࣟࢽࢡࢫ࡬ࡢᒎ㛤
ࡀᮇᚅ࡛ࡁࡿࠋࡇࢀࡲ࡛ࠊᡃࠎࡣ TiO2(001)ᇶᯈୖࡢ VO2 ⷧ⭷࡟
࠾࠸࡚ࠊ㟁ሙࡸ⇕࡟ࡼࡾ࣐࢖ࢡ࣓࣮ࣟࢺࣝࢧ࢖ࢬࡢಶࠎࡢ㔠ᒓ
̿⤯⦕యࢻ࣓࢖ࣥࡢ┦㌿⛣ไᚚࢆヨࡳࠊࢻ࣓࢖ࣥ㓄⨨ࡀࠊ㌿⛣
ᗘࡸ᢬ᢠኚ໬⋡࡞࡝ࡢ㟁Ẽఏᑟ≉ᛶࢆ኱ࡁࡃኚㄪ࡛ࡁࡿࡇ࡜
ࢆሗ࿌ࡋ࡚ࡁࡓࠋᮏᖺᗘࡣࠊVO2 ⷧ⭷ࡢ⭷ཌࢆኚ໬ࡉࡏࡿࡇ࡜
࡟ࡼࡾࠊ㔠ᒓ-⤯⦕యࢻ࣓࢖ࣥࡢࢧ࢖ࢬࢆࢧࣈ ȝm ࠿ࡽᩘ༑ ȝm
ࡢ㛫࡛ไᚚ࡛ࡁࡿࡇ࡜ࢆぢฟࡋࡓࠋࢻ࣓࢖ࣥቃ⏺࡟ࡣล≧㌿఩
ࡀᏑᅾࡋࠊ㌿఩ᐦᗘࡣ⭷ཌࡀཌ࠸࡯࡝ቑ࠼ࠊࢻ࣓࢖ࣥࢧ࢖ࢬࡀ
ᑠࡉࡃ࡞ࡗ࡚࠸ࡃഴྥࡀぢࡽࢀࡓ(ᅗ㸯)ࡲࡓࠊ10nm ௨ୗ࡛ࡣⷧ
⭷඲యࡀᆒ㉁࡟࡞ࡾᛴᓧ࡞┦㌿⛣ࡀぢࡽࢀࡓࠋล≧㌿఩ࡣṍ࢚
ࢿࣝࢠ࣮ࢆ⦆࿴ࡍࡿࡓࡵ࡟Ⓨ⏕ࡋࠊ⭷ཌ࡜ࢻ࣓࢖ࣥࢧ࢖ࢬࡢ㛵
ಀࡣ⌮ㄽ࡜Ⰻ࠸୍⮴ࢆ♧ࡋࡓ[ㄽᩥ 4]ࠋࢻ࣓࢖ࣥࡢࢧ࢖ࢬไᚚࡣࠊ ᅗ 1 (a)̽(d) ྛ⭷ཌ࡟ᑐࡍࡿ┦㌿⛣Ⅼ㏆ഐ
ࡢගᏛ㢧ᚤ㙾ീࠊཬࡧ(e)ࢻ࣓࢖ࣥࢧ࢖ࢬ࡜
ࢻ࣓࢖ࣥ㓄⨨ไᚚ࡜ྠᵝ࡟௒ᚋࡢ㓟໬≀ࢹࣂ࢖ࢫࢆᒎ㛤ࡋ࡚࠸
⭷ཌࡢ㛵ಀ㻌
ࡃ࠺࠼࡛㔜せ࡞せ⣲࡛࠶ࡿࠋ
― 94 ―
-1
X(T)
-1
Vdc(T) (: .m )
࣭᪂ወගࣉ࣮ࣟࣈ࡟ࡼࡿࢼࣀ┦ศ㞳࣐ࣥ࢞ࣥ㓟໬≀ࡢఏᑟࢲ࢖ࢼ࣑ࢡࢫゎ᫂
ᙉ┦㛵㟁Ꮚ⣔㓟໬≀࡛ࡣࠊࢼࣀ┦ศ㞳ࡋࡓࢻ࣓࢖ࣥ≧ែࡀᕧ኱ᛂ⟅ࡢᮏ㉁ࢆᢸࡗ࡚࠾ࡾࠊᕧ኱☢Ẽ᢬
ᢠຠᯝࢆⓎ⌧ࡍࡿ(La,Pr,Ca)MnO3 (LPCMO)࡛ࡣࠊᙉ┦㛵㡿ᇦ࡛ᩘ༑࠿ࡽᩘⓒ nm ࢧ࢖ࢬࡢᙉ☢ᛶ㔠ᒓ
┦࣭㟁Ⲵ⛛ᗎ⤯⦕య┦ࡢ㟁Ꮚ┦ࡀඹᏑࡍࡿࡇ࡜ࡀሗ࿌ࡉࢀ࡚࠸ࡿࠋ༢୍
ࢼࣀࢻ࣓࢖ࣥࡢ㔠ᒓ̿⤯⦕య㌿⛣(MIT)≉ᛶࡸࡑࡢືⓗ≉ᛶࡢゎ᫂ࡣࠊ
ᇶ♏⛉Ꮫࡢࡳ࡞ࡽࡎࢻ࣓࢖ࣥࢼࣀ࢚ࣥࢪࢽ࢔ࣜࣥࢢ࡟ᇶ࡙ࡃ᪂ወᙉ┦
㛵ࢼࣀࢹࣂ࢖ࢫࡢ๰〇࡜࠸ࡗࡓᛂ⏝࡟ࡶࡘ࡞ࡀࡿࠋ┦ศ㞳≧ែ࡛ࡢఏᑟ
ᗘࡣ㔠ᒓ┦࡜⤯⦕య┦ࡢศᕸ࡛Ỵࡲࡿఏᑟ⤒㊰࡟ࡼࡿࡀࠊ㏻ᖖࡢఏᑟ ᐃ࡛ࡣఏᑟᗘ࡜⤌ᡂศᕸࢆྠ᫬࡟ᑟฟࡍࡿࡇ࡜ࡣ࡛ࡁ࡞࠸ࠋࡑࡇ࡛ᡃࠎ
ࡣࠊග࡜㟁Ἴࡢ୰㛫ࡢ࿘Ἴᩘࢆࡶࡘࢸࣛ࣊ࣝࢶ(THz)Ἴࢆ⏝࠸ࡓ THz ᫬
㛫㡿ᇦศග(THz̽TDS)ィ ࡟ࡼࡾࠊMIT 㐣⛬ࡢఏᑟࢲ࢖ࢼ࣑ࢡࢫゎ᫂࡟
ᅗ 2 ᪼ 㐣⛬࡛ࡢ LPCMO ࡢ
ྲྀࡾ⤌ࡳࠊᐃ㔞ⓗ࡞ఏᑟᗘኚ໬࡜┦≧ែࡢ๭ྜኚ໬ࡢᑟฟἲࡢ☜❧࡟ᡂ
THz ࿘Ἴᩘ㡿ᇦ࡛ࡢఏᑟᗘࠋ
ຌࡋࡓࠋ10̽250K ࡢ ᗘ㡿ᇦ࡛ THz-TDS ᐃ(0.5-3.5 THz)࠿ࡽࠊᅗ 2 ࡢ
ᵝ࡟ LPCMO ࡢ THz ఏᑟᗘࢆᚓࡓࠋ ᗘࡢୖ᪼࡟క࠸ఏᑟᗘࡀపୗࡋ࡚࠾ࡾࠊ⣔ࡢ㔠ᒓ࠿ࡽ⤯⦕య࡬࡜
㌿⛣ࡋࡓࡇ࡜࡟ᑐᛂࡋ࡚࠸ࡿࠋ㔠ᒓࠊ⤯⦕య୧┦ࡢఏᑟᗘ࡬ࡢ㈉⊩ᗘ(⤌ᡂẚ)ࢆᐃ㔞ᑟฟࡍࡿࡓࡵ࡟ࠊ
㔠ᒓ̿⤯⦕యྜᡂࣔࢹࣝࢆᥦ᱌ࡋࠊࣇ࢕ࢸ࢕ࣥࢢ࡟ࡼࡾ㔠ᒓ┦࡜⤯⦕య┦ࡢ dc ఏᑟᗘ(ı0M, ı0I)ࠊཬࡧ㔠
ᒓ┦ࡢయ✚๭ྜ X(T)ࡢᑟฟࢆ⾜ࡗࡓ(ᅗ 3)ࠋᮏᡭἲ࡟ࡼࡾࠊ㔠ᒓ̿⤯⦕య㌿⛣㐣⛬ࡢᐃ㔞ⓗ࡞ఏᑟᗘኚ
໬࡜┦≧ែࡢ๭ྜኚ໬ࡢྠ᫬ᑟฟࡀᐇ⌧
(a)㻌
(b)㻌
ࡋࡓࠋࡇࡢᡭἲࡣࠊ࣐ࣥ࢞ࣥ㓟໬≀࡟㝈
1.0
㻌
5
10
㻌
ࡽࡎ௚ࡢ≀㉁⣔࡟ࡶ㐺ᛂ࡛ࡁࡿࡔࡅ࡛࡞
0.8
4
Metal㻌
10
ࡃࠊ㠀᥋ゐᡭἲ࡛࠶ࡿࡓࡵࠊ㟁ᴟࡢస〇
0.6
3
10
࡟ᅔ㞴ࡀక࠺ࢼࣀᵓ㐀ヨᩱ࡟ࡶ㐺ᛂࡀྍ
0.4
2
Coexistence㻌
10
cooling
⬟࡛࠶ࡿࠋLPCMO ࢼࣀ⣽⥺ᵓ㐀యヨᩱ࡟
0.2
heating
1
Insulator㻌
10
࠾࠸࡚ࡶఏᑟᗘ࡜┦≧ែࡢ๭ྜࡢኚ໬ࡢ
0.0
0
50
100
150
200
250
0
50 100 150 200 250
ᐃ㔞ᑟฟࡀྍ⬟࡜࡞ࡗ࡚࠾ࡾࠊࢼࣀᵓ㐀
Temperature (K)
Temperature (K)
࡟㉳ᅉࡍࡿ๻ⓗ࡞᪂⌧㇟࣭ᕧ኱≀ᛶࡢ᥈
ᅗ 3 ᑟฟࡋࡓ(a)dc ఏᑟᗘVdc(T)࡜(b)㔠ᒓ┦య✚๭ྜࡢ ᗘ౫Ꮡᛶࠋ㻌
⣴࡬࡜ᒎ㛤ࡋ࡚࠸ࡃࠋ
࣭ᒙ≧㕲㓟໬≀ࡢ㟁Ⲵ⛛ᗎ≧ែࡢ㟁⏺ไᚚ࡜ࢹࣂ࢖ࢫᛂ⏝
ᐊ 㟁Ⲵ⛛ᗎ≧ែࡢ㟁⏺┦ไᚚ(㟁Ⲵ⛛ᗎ⤯⦕≧ែ-↓⛛ᗎ㔠ᒓ≧┦ែࡢኚ໬)ࢆᇶ♏࡜ࡋࡓࢹࣂ࢖ࢫ㛤
Ⓨࢆ┠ᣦࡋ REFe2O4 ࢚ࣆࢱ࢟ࢩࣕࣝⷧ⭷(ᕼᅵ㢮ඖ⣲)ࡢྜᡂἲࢆ☜❧ࡋࠊ㟁⏺ࢫࢺࣞࢫ࡟ࡼࡾ㟁Ⲵ⛛ᗎ
≧ែࡢࢫ࢖ࢵࢳࣥࢢࢆヨࡳࡓࠋ᭦࡟ࠊ㟁⏺ຠᯝࢺࣛࣥࢪࢫࢱᵓ㐀ࢆ⏝࠸ࡓ㟼㟁࢟ࣕࣜ࢔ࢻ࣮ࣆࣥࢢ࡟ࡼ
ࡿ┦ไᚚ࡟ヨࡳࡓࠋᏳᐃ໬ࢪࣝࢥࢽ࢔ YSZ(111)ᇶᯈୖ࡟ࠊࣃࣝࢫ࣮ࣞࢨ࣮ሁ✚ἲࢆ⏝࠸࡚ REFe2O4 ⷧ⭷
ࢆస〇ࡋࡓࠋ࢚ࣆࢱ࢟ࢩࣕࣝ YbFe2O4 ࡢ⏕ᡂࢆ☜ㄆࡋࠊ㠃┤࠾ࡼࡧ㠃ෆ᪉఩ࡢ㛵ಀ ࡀࡑࢀࡒࢀ
YbFe2O4[001] // YSZ[111] ࠊ YbFe2O4[100] //
8
(a)
(b)
YSZ[1-10]࡛࠶ࡿࡇ࡜ࢆ☜ㄆࡋࡓ YbFe2O4 ⷧ⭷࡟
0.1
0.05
Ig (nA)
7
0
-0.05
6
-0.1
-0.15
5
0.5
0
100*(Gmax-G0)/G0 (%)
MMIM-MeSO4
MMIM-TFSI
EMIM-BF4
EMIM-TFSI
HMIM-TFSI
DEME-BF4
3
Vg (V)
1
f = 100 mHz
300 K
4
DEME-TFSI
㟁ᴟࢆྲྀࡾ௜ࡅࠊ㠃ෆ࡬ࡢ㟁ᅽ༳ຍ࡟ࡼࡾ㟁Ⲵ
⛛ᗎ≧ែࡢࢫ࢖ࢵࢳࣥࢢࢆヨࡳࡓ࡜ࡇࢁࠊᐊ ࡟࠾࠸࡚᫂░࡞ࢫ࢖ࢵࢳࣥࢢࡢほ ࡟ᡂຌࡋࡓࠋ
ࡉࡽ࡟㟁⏺ຠᯝ࡟ࡼࡾఏᑟᗘࡢኚㄪࢆヨࡳࡓ
( ᅗ 4) ࠋ ࢤ ࣮ ࢺ ⤯ ⦕ య ࡜ ࡋ ࡚ ࢖ ࢜ ࣥ ᾮ య
Ethyl-3-methylimidazolium
methanesulfonate
(EMIM-MeSO4)ࢆ⏝࠸ࡿࡇ࡜࡟ࡼࡾ⣙ 2㸣ࡢఏ
ᑟᗘࡢኚㄪ࡟ᡂຌࡋࡓࠋ㓟໬≀ࢹࣂ࢖ࢫᮦᩱ࡜
ࡋ࡚ᮍ㛤ᣅ࡛࠶ࡗࡓ REFe2O4 ࡢⷧ⭷໬࠾ࡼࡧ㟁
⏺ຠᯝࢺࣛࣥࢪࢫࢱᵓ㐀ࡢస〇࡟ࡼࡾࠊᮏᮦᩱ
ࡢࢹࣂ࢖ࢫᛂ⏝ࡢྍ⬟ᛶࢆ♧ࡋࡓࠋ
Capacitance (PF/cm2)
0.15
2
1
0
-1
-2
0
T = 300 K
VD = 0.25 V
30
l = 5 Pm
w = 120 Pm
t = 7.5 nm
60
90 120
Time (min.)
150
ᅗ 4 (a)ྛ✀࢖࢜ࣥᾮయࡢ㟼㟁ᐜ㔞 (b)EMIM-MeSO4 ࢆࢤ࣮ࢺᒙ
࡟⏝࠸ࡓ YbFe2O4 㟁⏺ຠᯝࢺࣛࣥࢪࢫࢱࡢࢳࣕࢿࣝࢥࣥࢲࢡࢱ
ࣥࢫ㟁⏺ኚㄪ
― 95 ―
180
ࢼࣀᴟ㝈ࣇ࢓ࣈࣜࢣ࣮ࢩࣙࣥ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
≉௵◊✲ဨ
ᐈဨᩍᤵ
ᐈဨ෸ᩍᤵ
኱Ꮫ㝔Ꮫ⏕
Ꮫ㒊Ꮫ⏕
஦ົ⿵బဨ
ྜྷ⏣ 㝧୍
᳿ 㔠ᓠ
㏆⸨ ᏕᩥࠊⳢ ᫭୍
⚄ᡞ ṇ㞝
ᑠ᪉ ཌࠊᑠᯘ ோ
ᰘ⏣ ⿱ᐇ
ᵽᕝ ᬛὒࠊబࠎᮌ Ὀࠊ஭Ἑཎ ኱ᶞࠊ㔝⃝ ୍ኴࠊᮤ ுࠊす஭ ⪽ᚿࠊᒣᒽ ඃ
ᮏ୰㔝 ๢ᚿ
୰㔝 ஂ⨾Ꮚࠊ༓௦ Ᏻዉ
a) ᴫせ
ᴟ㝈ࢼࣀࣇ࢓ࣈࣜࢣ࣮ࢩࣙࣥࢆᐇ⌧ࡍࡿࡓࡵ࡟ࠊ᫬㛫࣭✵㛫཯ᛂゎᯒᡭἲࢆ⏝࠸࡚㔞Ꮚࣅ࣮࣒ᴟ㝈ࢼ
ࣀࣇ࢓ࣈࣜࢣ࣮ࢩࣙࣥࡢᇶ♏㐣⛬ࢆゎ᫂ࡋࠊ㔞Ꮚࣅ࣮࣒ㄏ㉳཯ᛂࡢไᚚ᪉ἲࡢ㛤Ⓨࢆ┠ᣦࡋ࡚࠸ࡿࠋࡑ
ࢀࡽࢆᨭ࠼ࡿࡓࡵ࡟ୡ⏺᭱㧗᫬㛫ศゎ⬟ࢆ᭷ࡍࡿࣇ࢙࣒ࢺ⛊࣭࢔ࢺ⛊ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫࢩࢫࢸ࣒࠾ࡼ
ࡧࣇ࢙࣒ࢺ⛊᫬㛫ศゎ㟁Ꮚ㢧ᚤ㙾࡟ࡼࡿࠊࢼࣀ✵㛫ෆࡢ㔞Ꮚࣅ࣮࣒ㄏ㉳㧗㏿⌧㇟ࡢゎ᫂࡟㛵ࡍࡿ◊✲ࢆ
⾜ࡗ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭฼⏝ᣑ኱ࢆ┠ᣦࡋࡓ RF 㟁Ꮚ㖠ࣛ࢖ࢼࢵࢡࡢ࢔ࢵࣉࢢ࣮ࣞࢻ
2014 ᖺ 1 ᭶࡟⌧ᅾࡢ RF 㟁Ꮚ㖠ࣛ࢖ࢼࢵࢡ࡜᫬㛫ศゎ㟁Ꮚ㢧ᚤ㙾ࢆࢩࣕࢵࢺࢲ࢘ࣥࡋࠊ⊂❧ࡋࡓᐇ㦂
ᐊ࡟⛣タࡍࡿ࡜ඹ࡟࢔ࢵࣉࢢ࣮ࣞࢻࢆ⾜ࡗࡓࠋࣛ࢖ࢼࢵࢡ࡛ࡣࠊ᪂ࡓ࡟ࢩࣥࢢࣝࢩࣙࢵࢺࣃࣝࢫࣛࢪ࢜
ࣜࢩࢫ ᐃ⏝ࡢ Achromatic ࣅ࣮࣒ࣛ࢖ࣥࢆቑタࡋࠊ3 ࡘࡢࣅ࣮࣒฼⏝࣏࣮ࢺࢆᩚഛࡋࠊࣇ࢙࣒ࢺ⛊࣭࢔
ࢺ⛊ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫࡢᵓ⠏࣭࠾ࡼࡧ㔞Ꮚࣅ࣮࣒ㄏ㉳㉸㧗㏿཯ᛂゎᯒࢆ⾜ࡗ࡚࠸ࡿࠋ᫬㛫ศゎ㟁Ꮚ㢧
ᚤ㙾࡛ࡣࠊ࢚ࢿࣝࢠ࣮ࡢ࢔ࢵࣉࢢ࣮ࣞࢻ㸦5 MeV㸧ࢆ⾜࠺࡜ྠ᫬࡟ࠊ10 nm ࡢศゎ⬟ࢆ᭷ࡍࡿࣇ࢙࣒ࢺ
⛊᫬㛫ศゎ㟁Ꮚ㢧ᚤ㙾ࡢ㛤Ⓨࢆ⾜ࡗ࡚࠸ࡿࠋࡲࡓࠊ㧗⧞㏉ࡋ㸦1kHz㸧ࡢᖖఏᑟࣇ࢛ࢺ࢝ࢯ࣮ࢻ RF 㟁Ꮚ
㖠ࡢ㛤Ⓨࢆࢫࢱ࣮ࢺࡋࠊ᫬㛫ศゎ㟁Ꮚᅇᢡࡸࡑࡢ௚ࡢ࣏ࣥࣉ࣭ࣉ࣮ࣟࣈ࡞࡝ࡢᛂ⏝ᐇ㦂࡟฼⏝ࢆணᐃࡋ
࡚࠸ࡿࠋ
࣭ᖸ΅ィ࡟࠾ࡅࡿឤᗘࣔࢹࣝࢆ⏝࠸ࡓ㉸▷ࣃࣝࢫ㟁Ꮚࣅ࣮࣒ィ ᴟ㝈᫬㛫ศゎ⬟ࢆ᭷ࡍࡿ࢔ࢺ⛊ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫᐇ⌧࡟ྥࡅࡓࠊ10 ࣇ࢙࣒ࢺ⛊௨ୗ㉸▷ࣃࣝࢫ㟁Ꮚ
ࣅ࣮࣒ࡢⓎ⏕࣭ィ ἲࡢ☜❧ࢆ⾜ࡗࡓࠋ㟁Ꮚࣅ࣮࣒ィ ࡛⏝࠸ࡿᖸ΅ィࡢ࿘Ἴᩘ≉ᛶࢆ㉥እග※࡟ࡼࡾ
ホ౯ࢆ⾜࠸ࠊ㟁Ꮚࣅ࣮࣒ィ ࡟㐺⏝ࡋࡓࠋ࣓࣮࣎ࣟࢱ࠾ࡼࡧ MCT㸦HgCdTe㸧᳨ฟჾࢆ⏝࠸࡚ࠊ㟁Ꮚࣅ
࣮࣒ࡀᨺᑕࡍࡿࢥࣄ࣮ࣞࣥࢺ㑄⛣ᨺᑕࡢィ ࢆ⾜ࡗࡓࠋ㟁Ꮚࣅ࣮࣒ィ ࡛ᚓࡽࢀࡓ࿘Ἴᩘࢫ࣌ࢡࢺࣝࡣࠊ
ឤᗘࣔࢹࣝ࡟ࡼࡾᚓࡽࢀࡿ࿘Ἴᩘࢫ࣌ࢡࢺࣝ࠿ࡽண ࡛ࡁࡿࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡾࠊ8.9 ࣇ࢙࣒ࢺ⛊ࡢ㟁
Ꮚࣅ࣮࣒ࡢⓎ⏕࣭ィ ࡟ᡂຌࡋࡓࠋ௒ᚋࠊ㟁Ꮚࣅ࣮࣒ࡢࢥࣄ࣮ࣞࣥࢺᨺᑕ࡟ᑐࡋ࡚ࠊᗈᖏᇦ࡞ィ ࢆ⾜
࠸ࠊ࢔ࢺ⛊㟁Ꮚࣅ࣮࣒Ⓨ⏕࣭ィ ࡟㐺⏝ࡍࡿࠋ
࣭ࢻࢹ࢝ࣥࡢᨺᑕ⥺໬Ꮫึᮇ㐣⛬࡜ศゎ㐣⛬ࡢゎ᫂
ࣇ࢙࣒ࢺ⛊ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫࡢ ᐃἼ㛗ᣑᙇ࡜Ᏻᐃ໬࡟ࡼࡿ S/N ࡢᨵၿ࡟ࡼࡾࠊග㊰㛗 1 mm ࡢࢻ
ࢹ࢝ࣥ୰ࡢ࢔ࣝ࢟ࣝࣛࢪ࢝ࣝࡢ⏕ᡂ㐣⛬ࢆ 240 nm ࡛ほ ࡍࡿࡇ࡜࡟ᡂຌࡋࠊ3 ps ࡛⏕ᡂࡍࡿࡇ࡜ࢆぢ
ฟࡋࡓࠋ࢔ࣝ࢟ࣝࣛࢪ࢝ࣝࡢ⏕ᡂᣲືࡀࢻࢹ࢝ࣥࣛࢪ࢝ࣝ࢝ࢳ࢜ࣥࡢ 800 nm ࡛ࡢ⏕ᡂᣲື࡜Ⰻࡃ୍⮴
ࡍࡿࡇ࡜ࢆぢฟࡋࡓࠋບ㉳ࣛࢪ࢝ࣝ࢝ࢳ࢜ࣥ࠿ࡽ࢔ࣝ࢟ࣝࣛࢪ࢝ࣝ࡬ࡢ┤᥋ศゎࢆ♧၀ࡋࡓࠋᨺᑕ⥺໬
Ꮫึᮇ㐣⛬࠿ࡽࠊ⏕ᡂ≀࡟⮳ࡿࢻࢹ࢝ࣥ୰ࡢᨺᑕ⥺໬Ꮫ཯ᛂࡢ඲యࡢᴫほࢆᚓࡿࡇ࡜ࡀ࡛ࡁࡓࠋ᰾⇞ᩱ
― 96 ―
෌ฎ⌮࡟࠾ࡅࡿᢳฟ๣⁐፹ࡢศゎᶵᵓࡢ⌮ゎࡢࡳ࡞ࡽࡎࠊ⪏ᨺᑕ⥺㧗ศᏊᮦᩱ㛤Ⓨࠊḟୡ௦༙ᑟయࢼࣀ
ࣇ࢓ࣈࣜࢣ࣮ࢩࣙࣥࡢࡓࡵࡢࣞࢪࢫࢺᮦᩱ㛤Ⓨ࡟ࡶタィᣦ㔪ࢆ୚࠼ࡿ࡜⪃࠼ࡽࢀࡿࡢ࡛ࠊࡇࡢ▱ぢࡣ㠀
ᖖ࡟㔜せ࡛࠶ࡿࠋ
࣭ග྾཰ ᐃࡢ㧗ᗘ໬࠾ࡼࡧࣇ࢙࣒ࢺ⛊㟁Ꮚ⥺࣭࣮ࣞࢨ࣮」ྜ↷ᑕࣃࣝࢫࣛࢪ࢜ࣜࢩࢫࡢ‽ഛ
ࢻࢹ࢝ࣥࡢศゎ㐣⛬࡟࠾࠸࡚ࠊບ㉳ࣛࢪ࢝ࣝ࢝ࢳ࢜ࣥࡀศゎࡢ㉳Ⅼ࡜࡞ࡗ࡚࠸ࡿࡇ࡜ࡀ♧၀ࡉࢀࡓࡀࠊ
ບ㉳ࣛࢪ࢝ࣝ࢝ࢳ࢜ࣥࡣࠊ㏆㉥እ࠿ࡽྍど㡿ᇦ࡟࠿ࡅ࡚᥈⣴ࡋࡓ࡟ࡶ࠿࠿ࢃࡽࡎࠊᮍࡔ┤᥋ほ ࡉࢀ࡚
࠸࡞࠸ࠋࢻࢹ࢝ࣥࡢᨺᑕ⥺ศゎ࡟࠾ࡅࡿບ㉳ࣛࢪ࢝ࣝ࢝ࢳ࢜ࣥࡢᙺ๭ࢆ᫂☜࡟ࡍࡿࡓࡵ࡟ࠊࣇ࢙࣒ࢺ⛊
㟁Ꮚ⥺↷ᑕ࡟ࡼࡾࣛࢪ࢝ࣝ࢝ࢳ࢜ࣥࢆ⏕ᡂࡋࠊࣇ࢙࣒ࢺ⛊ගࣃࣝࢫ࡛ࣛࢪ࢝ࣝ࢝ࢳ࢜ࣥࢆ෌ບ㉳ࡋ࡚ບ
㉳ࣛࢪ࢝ࣝ࢝ࢳ࢜ࣥࢆ⏕ᡂࡋࠊࣇ࢙࣒ࢺ⛊ศᯒග࡛࢔ࣝ࢟ࣝࣛࢪ࢝ࣝࢆࣔࢽࢱ࣮ࡍࡿࠋࡑࡢࡓࡵࡢ㟁Ꮚ
⥺-࣮ࣞࢨ࣮」ྜ↷ᑕࣃࣝࢫࣛࢪ࢜ࣜࢩࢫ ᐃ⣔ࢆᵓ⠏ࡋࡓࠋ2015 ᖺᗘ࡟ࡇࢀࢆ⏝࠸ࡓᐇ㦂ࢆ⾜࠺ࠋ
࣭ࣇ࢙࣒ࢺ⛊ࣃࣝࢫ㟁Ꮚ㢧ᚤ㙾ࡢ㛤Ⓨ
ࢼࣀ✵㛫ෆ࡛ࡢᙧែᵓ㐀ኚ໬ࢆ┤᥋ᐇീほ ࡍࡿࡓࡵ࡟ࠊࣇ࢛ࢺ࢝ࢯ࣮ࢻ RF 㟁Ꮚ㖠ࢆ⏝࠸ࡓࣇ࢙࣒
ࢺ⛊ࣃࣝࢫ㟁Ꮚ㢧ᚤ㙾ࢆ㛤Ⓨࡋ࡚࠸ࡿࠋ௒ᖺᗘࡣࠊࢧࣥࣉࣝࡢᵓ㐀ኚ໬➼ࢆㄏ㉳ࡍࡿࡓࡵࡢእ㒊ࢺࣜ࢞
࣮࡜ࡋ࡚ග↷ᑕ⏝ࡢධᑕࣃࢫࢆᨵⰋ࣭ᑟධࡋࡓࠋ㟁Ꮚ㢧ᚤ㙾࡟⏝࠸ࡿ࡟ࡣࠊప࢚ࢿࣝࢠ࣮ศᩓࠊప࢚࣑
ࢵࢱࣥࢫࡢ㟁Ꮚ⥺ࣃࣝࢫⓎ⏕ࡀ㔜せ࡛࠶ࡾࠊࣇ࢛ࢺ࢝ࢯ࣮ࢻ RF 㟁Ꮚ㖠ࡸ࢚࣑ࢵࢱࣥࢫ⿵ൾ⏝ࡢࢯࣞࣀ
࢖ࢻ࡞࡝ࡢྛ✀㟁ᏊගᏛ⣔ࢆ᭱㐺໬ࡍࡿᚲせࡀ࠶ࡿࠋࡇࢀࡲ࡛ຍᕤ⢭ᗘ࡛Ỵࡲࡗ࡚࠸ࡓࡀࠊࡇࢀ࡟ㄪᩚ
ᶵᵓࢆྲྀࡾ௜ࡅࡿ࡭ࡃタィኚ᭦ࢆ⾜ࡗࡓࠋ
࣭᪂つ㧗⧞ࡾ㏉ࡋࣇ࢛ࢺ࢝ࢯ࣮ࢻ RF 㟁Ꮚ㖠࡜ࣇ࢙࣒ࢺ⛊ࣃࣝࢫ㟁Ꮚ⥺ᅇᢡ⿦⨨ࡢ㛤Ⓨ
ࣇ࢙࣒ࢺ⛊ࣃࣝࢫ㟁Ꮚ㢧ᚤ㙾࡛ࡣࠊࣇ࢙࣒ࢺ⛊ࡢࣃࣝࢫᖜࡢ㟁Ꮚ⥺ࢆⓎ⏕ࡉࡏࡿࡓࡵ࡟ࠊ㟁Ⲵ㔞ࢆᢚ
࠼࡚࠸ࡿࠋࡇࡢࡓࡵ࡟ࠊ༑ศ࡞ࢥࣥࢺࣛࢫࢺീࢆᚓࡿࡓࡵ࡟ࡣࠊ✚⟬ࡍࡿᚲせࡀ࠶ࡿࠋࡇࡢࡓࡵ࡟ࠊ⌧
ᅾࡢ 10 Hz ࠿ࡽ 100 ಸࡢ 1 kHz ࡢ㟁Ꮚ㖠ࡢ㛤Ⓨࢆ┠ᣦࡋ࡚࠸ࡿࡀࠊ㧗ฟຊࡢ㧗⧞ࡾ㏉ࡋ㧗࿘Ἴ※ࡀ↓࠸
ၥ㢟ࠊ⇕㔞ࡀ 100 ಸ࡟࡞ࡿ➼ࡢၥ㢟ࡀ࠶ࡿࠋᑗ᮶ࡢ㧗⧞ࡾ㏉ࡋࣇ࢛ࢺ࢝ࢯ࣮ࢻ RF 㟁Ꮚ㖠ࡢ㛤Ⓨࢆ┠ᣦ
ࡋ࡚ࠊ⇕ࡢၥ㢟ࢆゎỴࡋࠊ࠿ࡘప࢚࣑ࢵࢱࣥࢫࡢ㟁Ꮚࣅ࣮࣒ࢆⓎ⏕ࡉࡏࡿࡓࡵ࡟ࠊ෭༷Ỉ㊰ࢆቑᙉࡋࠊ
✵Ὕෆ㟁ሙࡀపࡃ࡞ࡿࡼ࠺࡞ࠊ᪂ࡋ࠸ࣇ࢛ࢺ࢝ࢯ࣮ࢻ RF 㟁Ꮚ㖠ࢆタィࡋࠊKEK ࡜ࡢඹྠ◊✲࡟ࡼࡾస
ᡂࡋࡓࠋࡇࡢ㟁Ꮚ㖠ࢆ⏝࠸࡚ࣇ࢙࣒ࢺ⛊㟁Ꮚ⥺ᅇᢡ⿦⨨ࢆ᪂ࡓ࡟タィ࣭㛤Ⓨࡋࡓࠋ㧗ရ㉁ࡢ㟁Ꮚࣅ࣮࣒
Ⓨ⏕࡟ᡂຌࡋࠊ㔠༢⤖ᬗࢱ࣮ࢤࢵࢺࡢᅇᢡീࢆࢩࣥࢢࣝࢩࣙࢵࢺ࡛ᚓࡿࡇ࡜࡟ᡂຌࡋࡓࠋ
࣭ࢩࣥࢢࣝࢩࣙࢵࢺࣃࣝࢫࣛࢪ࢜ࣜࢩࢫࡢ㛤Ⓨ
㟁Ꮚ⥺ࣃࣝࢫ࡜ศᯒගࣃࣝࢫࡢࢧࣥࣉࣝ୰࡛ࡢ㏿ᗘᕪ࡟ࡼࡿ᫬㛫ศゎ⬟ຎ໬ࡢၥ㢟ࢆゎỴࡍࡿࡓࡵ
࡟ࠊ➼౯㏿ᗘศගἲࡢ㛤Ⓨࢆ⾜ࡗ࡚࠸ࡿࠋࡇࢀࢆᛂ⏝ࡋ࡚ࠊ㟁Ꮚ⥺ࣃࣝࢫ࡜ศᯒගࣃࣝࢫࡢゅᗘࢆṇ☜
࡟ไᚚࡍࡿࡇ࡜࡟ࡼࡾࠊศᯒගࣃࣝࢫෆ࡟᫬㛫᝟ሗࢆ⧊ࡾ㎸ࢇࡔࢩࣥࢢࣝࢩࣙࢵࢺࣃࣝࢫࣛࢪ࢜ࣜࢩࢫ
ࢆ㛤Ⓨࡋ࡚࠸ࡿࠋ㟁Ꮚ⥺↷ᑕ࡟ࡼࡾศゎࡋࡸࡍ࠸ࢧࣥࣉࣝࡸάᛶ✀ᑑ࿨ࡢ㠀ᖖ࡟㛗࠸ࢧࣥࣉ࡛ࣝ↷ᑕຠ
ᯝ⵳✚ࢆᢚ࠼ࡿࡓࡵ࡟ࠊࢩࣥࢢࣝࢩࣙࢵࢺࣃࣝࢫࣛࢪ࢜ࣜࢩࢫࡢ㛤Ⓨࡀせㄳࡉࢀ࡚࠸ࡿࠋ
― 97 ―
ࢼࣀᵓ㐀࣭ᶵ⬟ホ౯◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
≉௵◊✲ဨ
኱Ꮫ㝔Ꮫ⏕
஦ົ⿵బဨ
➉⏣ ⢭἞
ྜྷ⏣ ⚽ே
⚄ෆ ┤ேࠊ㯞⏕ ுኴ㑻
Ꮮ ⛉ᣲ
ෆᒣ ᚭஓࠊ┦㤿 ೺ኴ㑻ࠊᑠᕝ ὒᖹࠊ⋢ᒸ ṊὈࠊ⛅ᒣ ᬸ♸ࠊᐩ⏣ 㞝ே
㧗℩ ⣖Ꮚ
a) ᴫせ
㟁Ꮚ㢧ᚤ㙾࡟ࡼࡿࢼࣀᵓ㐀ࡢゎᯒࡸᶵ⬟ࡢホ౯ࡣࠊᶵ⬟ᛶᮦᩱࢆᨵⰋࡲࡓࡣ᪂つ㛤Ⓨࡍࡿୖ࡛ᚲせ୙
ྍḞ࡛࠶ࡿࠋ≉࡟ࠊ㏱㐣㟁Ꮚ㢧ᚤ㙾(TEM)ࢆ⏝࠸ࡓࢼࣀᵓ㐀࣭ࢼࣀࢹࣂ࢖ࢫࡢ⏕ᡂࣉࣟࢭࢫࡢホ౯ࠊཬ
ࡧᶵ⬟Ⓨ⌧୰ࡢࡑࢀࡽࡢホ౯ࡣࠊ௒ᚋ┈ࠎ㔜せ࡟࡞ࡿ࡜⪃࠼ࡽࢀࡿࠋᙜ◊✲ศ㔝࡛ࡣࡇࢀࡲ࡛࡟ࠊẼయ
୰ࡢࢼࣀᵓ㐀ࡸࢼࣀࢹࣂ࢖ࢫࢆཎᏊࢫࢣ࣮࡛ࣝほᐹྍ⬟࡞⎔ቃไᚚᆺ㏱㐣㟁Ꮚ㢧ᚤ㙾(ETEM)ࢆ㛤Ⓨࡋ
࡚ࡁࡓࠋࡇࡢ ETEM ࢆά⏝ࡋࠊᵝࠎ࡞Ẽయ࡜ᅛయࡢ⏺㠃࡛㉳ࡇࡿືⓗ࡞⌧㇟ࢆゎᯒࡍࡿࡇ࡜࡛ࠊࢼࣀᵓ
㐀࣭ࢼࣀࢹࣂ࢖ࢫࡢ⏕ᡂ㐣⛬ࡢゎ᫂ࡸࠊ᪂つᶵ⬟ᛶᮦᩱࡢ㛤Ⓨ࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿࠋලయⓗ࡟ࡣࠊ୍㓟໬
Ⅳ⣲(CO)㓟໬཯ᛂ⎔ቃୗ࡛ࡢ㔠ࢼࣀ⢏Ꮚゐ፹ࡸⓑ㔠ࢼࣀ⢏Ꮚゐ፹࡞࡝ࡢཎᏊᵓ㐀ࡢኚ໬ࡸࠊ࣮࢝࣎ࣥࢼ
ࣀࢳ࣮ࣗࣈ(CNTs)࡟௦⾲ࡉࢀࡿࢼࣀᵓ㐀ࡢ⏕ᡂ㐣⛬ࢆཎᏊࢫࢣ࣮࡛ࣝࡑࡢሙほᐹࡋࠊࡑࢀࡽࡢ⏺㠃⌧㇟
ࡢ⫼ᚋ࡟₯ࡴ≀⌮ࢆ◊✲ࡋ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭ࢭࣜ࢔ᢸᣢⓑ㔠ࢼࣀ⢏Ꮚゐ፹ࡢ㓟໬࣭㑏ඖ㐣⛬
ࡢゎ᫂
㓟໬ࢭ࣒ࣜ࢘࡟ᢸᣢࡉࢀࡓⓑ㔠ࢼࣀ⢏Ꮚゐ፹
(Pt/CeO2)ࡣࠊCO ࡢ㓟໬཯ᛂ࡟ᑐࡋ࡚ᐊ ࡛㧗࠸ゐ
፹άᛶࢆ♧ࡍࠋⓑ㔠ࢼࣀ⢏Ꮚࡢᙧ≧ࡸ㓄ྥࡣࠊゐ
፹άᛶ࡜ᙉ࠸┦㛵ࢆᣢࡘࡇ࡜ࡀ▱ࡽࢀ࡚࠸ࡿࡓࡵࠊ
ゐ፹཯ᛂࡢᇶᮏ࡛࠶ࡿ㓟໬࣭㑏ඖ㐣⛬࡟࠾ࡅࡿⓑ
㔠⾲㠃ࡢࢼࣀᵓ㐀ࡢኚ໬ࢆཎᏊࢫࢣ࣮࡛ࣝࡑࡢሙ
ほᐹࡍࡿࡇ࡜ࡀ㔜せ࡜࡞ࡿࠋᮏ◊✲࡛ࡣࠊ཰ᕪ⿵
ṇ ETEM ࢆ⏝࠸࡚ࠊ㓟໬ࢭ࣒ࣜ࢘࡟ᢸᣢࡉࢀࡓⓑ
㔠ࢼࣀ⢏Ꮚ⾲㠃ࡢ㓟໬࣭㑏ඖ㐣⛬ࢆࡑࡢሙほᐹࡋ
ࡓࠋ
Pt/CeO2 ゐ፹ࡣᯒฟỿẊἲ࡛ㄪ〇ࡋࡓࠋᅗ 1 ࡟ࠊ
Pt/CeO2 ゐ፹ࡢ ETEM ほᐹ⤖ᯝࢆ♧ࡍࠋᕥୖ࡟♧
ࡍ┿✵୰࡛ࡣⓑ㔠ࢼࣀ⢏Ꮚࡣ⤖ᬗ㠃࡛ᅖࡲࢀࡓᙧ
≧ࢆࡋ࡚࠸ࡿࡀࠊ㓟⣲୰࡛ࡣⓑ㔠ࢼࣀ⢏Ꮚࡢ⾲㠃
ࡀ㓟໬ࡉࢀ࡚ⓑ㔠ࡢ㓟໬ᒙࡀᙧᡂࡉࢀࡓࠋཎᏊศ
ゎ⬟ ETEM ീ࡜ࡑࡢሙ EELS ᐃ࡟ࡼࡾࠊࡇࡢ⾲
㠃ᒙࡣ Į-PtO2 ࢆྵࡴᵝࠎ࡞ⓑ㔠㓟໬≀࡛࠶ࡿࡇ࡜
ࡀࢃ࠿ࡗࡓࠋࡲࡓࠊ㓟⣲ 100 Pa ࡟ CO ࡜ H2O ࢞ࢫ
ࢆᑡ㔞ຍ࠼ࡿ࡜ࠊⓑ㔠ࢼࣀ⢏Ꮚ⾲㠃ࢆそࡗ࡚࠸ࡓ
ⓑ㔠ࡢ㓟໬ᒙࡀ㑏ඖࡉࢀ࡚ᾘኻࡋࠊⓑ㔠ࡢ⤖ᬗ㠃
ࡀ⌧ࢀࡓࠋ
ᅗ 2 ࡣࠊPt/CeO2 ゐ፹࡟࠾ࡅࡿⓑ㔠ࢼࣀ⢏Ꮚࡢ⾲
― 98 ―
ᅗ 1 ⓑ㔠ࢼࣀ⢏Ꮚ⾲㠃ࡢ㓟໬࣭㑏ඖ㐣⛬
㠃ᵓ㐀ࡢ࢞ࢫศᅽ౫Ꮡᛶࢆࡲ࡜ࡵࡓࡶࡢ࡛࠶ࡿࠋ
㓟⣲ࡢ࢞ࢫศᅽࢆ኱ࡁࡃࡋ࡚࠸ࡃ࡜ࠊ⾲㠃ࡢ୍㒊
ࡢ㠃࠿ࡽⓑ㔠㓟໬ᒙࡀᙧᡂࡉࢀጞࡵࠊ᭱⤊ⓗ࡟ࡣ
ࢼࣀ⢏Ꮚ඲యࢆⓑ㔠㓟໬ᒙࡀそࡗࡓᙧ≧࡜࡞ࡿࠋ
㓟⣲ 100 Pa ࡟ᑐࡋ࡚ CO ࢆ 4 ™ 10Ѹ3 Paࠊࡲࡓࡣ
H2O ࢆ 10 Pa ΰࡐࡿࡇ࡜࡛ࠊࢼࣀ⢏Ꮚ⾲㠃ࡀ㑏ඖ
ࡉࢀⓑ㔠㓟໬ᒙࡀᾘኻࡍࡿࠋࡲࡓࠊⓑ㔠㓟໬ᒙࡀ
ᙧᡂࡉࢀࡓ≧ែ࡛┿✵࡟ࡍࡿࡇ࡜࡛ࡶ⾲㠃ࡢ㓟
໬ᒙࡀ㑏ඖࡉࢀࡿࠋࡇࢀࡽ୍㐃ࡢ཯ᛂࡣࠊධᑕ㟁
Ꮚ⥺ࡀẼయࢆάᛶ໬ࡍࡿࡇ࡜࡛ㄏ㉳ࡉࢀࡿࡓࡵࠊ
ᐊ ࡛ࡶ཯ᛂࡀ㐍ࡴࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡗࡓࠋ
ᮏ◊✲࡛᫂ࡽ࠿࡟ࡉࢀࡓ㓟໬࣭㑏ඖ཯ᛂ୰࡟࠾
ࡅࡿⓑ㔠ࢼࣀ⢏Ꮚࡢ⾲㠃ཎᏊᵓ㐀ࡢኚ໬ࡣࠊ
Pt/CeO2 ゐ፹ࡢ CO 㓟໬཯ᛂ࣓࢝ࢽࢬ࣒ࢆゎ᫂ࡍ
ࡿୖ࡛ᴟࡵ࡚㔜せ࡛࠶ࡿࠋ
࣭࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈᡂ㛗୰ࡢࢼࣀ⢏Ꮚゐ፹ࡢᵓ
㐀ゎᯒ
࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈ(CNTs)ࡣࠊࢼࣀ⢏Ꮚゐ፹ࢆ
⏝࠸ࡓ໬Ꮫ⵨╔(CVD)ἲ࡟ࡼࡾᡂ㛗ࡍࡿࡇ࡜ࡀ▱ࡽ
ࢀ࡚࠾ࡾࠊࢼࣀ⢏Ꮚゐ፹࡟ࡣ Co, Ni, Fe ࡞࡝ᵝࠎ࡞
㔠ᒓࡀ⏝࠸ࡽࢀࡿࠋCNTs ᡂ㛗୰ࡢࢼࣀ⢏Ꮚゐ፹ࡢ
ᵓ㐀ࡀ CNTs ࡢᙧ≧࡟ᙳ㡪ࡍࡿࡓࡵࠊCNTs ᡂ㛗୰ࡢ
ࢼࣀ⢏Ꮚゐ፹ࡢᵓ㐀ࢆヲ⣽࡟ゎᯒࡍࡿࡇ࡜ࡀᚲせ࡜
࡞ࡿࠋᮏ◊✲࡛ࡣࠊCo ࢼࣀ⢏Ꮚゐ፹ࢆ⏝࠸ࡓ CNTs
ࡢᡂ㛗㐣⛬ࢆ ETEM ࡟ࡼࡗ࡚ࡑࡢሙほᐹࡋࠊCo ࢼ
ࣀ⢏Ꮚゐ፹ࡢᵓ㐀࣭⤌ᡂኚ໬ࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
SiO2 ࡢ⾲㠃ᒙࢆᣢࡘ Si ᇶᯈ࡟ Co ࢆ┿✵⵨╔ࡋࡓ
ࡢࡕࠊ┿✵ୗ 550°C ࡛ຍ⇕ࡋ Co ࢼࣀ⢏Ꮚゐ፹ࢆస〇
ࡋࡓࠋࡇࢀ࡟ࠊཎᩱ࡜࡞ࡿ࢔ࢭࢳࣞࣥ࢞ࢫࢆ 3 Pa/h
ࡢ㏿ࡉ࡛ᑟධࡍࡿࡇ࡜࡛ CNTs ࡢᡂ㛗㐣⛬ࢆ ETEM
࡛ࡑࡢሙほᐹࡋࡓࠋᅗ 3 ࡟ࠊCNTs ᡂ㛗୰ࡢࢼࣀ⢏
Ꮚゐ፹ࡢ ETEM ほᐹ⤖ᯝࢆ♧ࡍࠋ㧗ศゎ⬟ ETEM ほ
ᐹ࡟ࡼࡾࠊࢼࣀ⢏Ꮚゐ፹୰࡟᱁Ꮚ⦤ࡀほᐹࡉࢀࠊ᱁
Ꮚ㛫㝸ࡼࡾࢼࣀ⢏Ꮚゐ፹ࡣ hcp Co ࡲࡓࡣ Co3C ࡛࠶
ࡿࡇ࡜ࡀࢃ࠿ࡗࡓࠋ
ᅗ 4 ࡟ࠊCNTs ᡂ㛗୰ࡢࢼࣀ⢏Ꮚゐ፹ᵓ㐀ࣔࢹࣝ
ࢆ♧ࡍࠋᅗ 4b ࡢࡼ࠺࡟ࠊࢼࣀ⢏Ꮚࡢᗏࢆ Co3C ࡀ༨
ࡵࡿ࡜ࠊཎᩱࡢ࣮࢝࣎ࣥࡀቑ࠼ࡿࡓࡵ CNTs ࡢᡂ㛗
ࡀಁ㐍ࡉࢀࡿࠋࡲࡓࠊCo3C ࡀࢼࣀ⢏Ꮚࡢ࿘ᅖࢆྲྀࡾ
ᅖࡴᵓ㐀࡛ࡣࠊCNTs ࡢᡂ㛗ࡀ㐜ࡃ࡞ࡿࠋᐇ㝿࡟ࠊᅗ
4b ࡢࣔࢹࣝ࡟ᑐᛂࡍࡿᅗ 3b ࡢᵓ㐀࡛ࡣࠊ0.6 nm/s ࡢ
ᡂ㛗⋡࡛࠶ࡾࠊᅗ 4c ࡢࣔࢹࣝ࡟ᑐᛂࡍࡿᅗ 3a ࡢᵓ
㐀࡛ࡣ 0.1 nm/s ࡜㐜ࡃ࡞ࡿࠋ
CNTs ࡢᵓ㐀ࢆไᚚࡍࡿࡓࡵ࡟ࡣࠊCNTs ᡂ㛗୰ࡢ
ࢼࣀ⢏Ꮚゐ፹ࡢ୙ᆒ୍ᵓ㐀ࡢ᫬㛫ኚ໬࡟㛵ࡋ࡚ࠊࡉ
ࡽ࡞ࡿᐇ㦂ⓗ࣭⌮ㄽⓗ◊✲ࡀᚲせ࡜࡞ࡿࠋ
ᅗ 2 ⓑ㔠ࢼࣀ⢏Ꮚ⾲㠃཯ᛂࡢ࢞ࢫศᅽ౫Ꮡᛶ
ᅗ 3 CNTs ᡂ㛗୰ࡢࢼࣀ⢏Ꮚゐ፹ࡢᵓ㐀ኚ໬
ᅗ 4 CNTs ᡂ㛗୰ࡢࢼࣀ⢏Ꮚゐ፹ࡢᵓ㐀ࣔࢹࣝ
― 99 ―
ࢼࣀᶵ⬟ண ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
ᣍ࡬࠸ᩍᤵ
≉௵◊✲ဨ
እᅜேᐈဨᩍᤵ
኱Ꮫ㝔Ꮫ⏕
Ꮫ㒊Ꮫ⏕
஦ົ⿵బဨ
ᑠཱྀ ከ⨾ኵ
ⓑ஭ ග㞼
ᒣෆ 㑥ᙪࠊ⢄⏣ ᾈ⩏
ᮏἙ ග༤ࠊᇛ ೺⏨
㇏⏣ 㞞அ
Bog Gi. Kim 㸦ᖹᡂ 27 ᖺ 3 ᭶ 8 ᪥~ᖹᡂ 27 ᖺ 5 ᭶ 9 ᪥㸧
☾ᒣ ె⏠ࠊୖᮧ ┤ᶞࠊ⸨ᮧ ༟ຌࠊᑠ᳃ ᑦᖹࠊすᲄ Ὀ⤂ࠊᖹ㔝 ⿱⌮
῝⏣ ༟ぢ
ᇉෆ ⨾ዉᏊ㸦ࠥᖹᡂ 27 ᖺ 3 ᭶ 31 ᪥㸧ᰩᯘ ༓ᙲ
a) ᴫせ
➨୍ཎ⌮ィ⟬࡟ᇶ࡙ࡁࠊ✀ࠎࡢᅛయ⣔࣭⾲㠃⣔࡛Ⓨ⌧ࡍࡿ≀ᛶ࣭ᶵ⬟ࢆ⌮ㄽⓗ࡟ண ࡍࡿ◊✲ࢆ⾜ࡗ
࡚࠸ࡿࠋⓎ⌧ᶵᵓࢆ㟁Ꮚ≧ែࡢ≉␗ᛶ࠿ࡽ᫂ࡽ࠿࡟ࡍࡿࡇ࡜࡟ࡼࡗ࡚ࠊ᪂ࡓ࡞≀㉁ࢆタィࡍࡿ◊✲࡟ࡶ
ᒎ㛤ࡋ࡚࠸ࡿࠋࡲࡓࠊ➨୍ཎ⌮ィ⟬࡟ᚲせ࡜࡞ࡿᇶ♏⌮ㄽࡸィ⟬ᡭἲࡢ㛤Ⓨ࡟ࡶྲྀࡾ⤌ࢇ࡛࠸ࡿࠋ
b) ᡂᯝ
࣭ࢫࣆࣥ㌶㐨┦஫స⏝࡟㉳ᅉࡍࡿ᪂ወ≀ᛶⓎ⌧
ࢫࣆࣥ㌶㐨┦஫స⏝࡟㉳ᅉࡍࡿ᪂ወ࡞≀㉁┦ࡸ≀
ᛶࡣࡑࡢᚤどⓗⓎ⌧ᶵᵓ࡟࠾ࡅࡿ⯆࿡࡜ྠ᫬࡟ࠊḟୡ
௦ࢹࣂ࢖ࢫ࡬ࡢᛂ⏝㠃࡛ὀ┠ࢆ㞟ࡵ࡚࠸ࡿࠋBi ࡣࣂ
ࣝࢡ࡜ࡋ࡚ࡣ༙㔠ᒓ࡛࠶ࡿࡀࠊⷧ⭷⣔࡟ᑐࡋ࡚ࡣ⭷ᅽ
࡟౫Ꮡࡋࡓ㔞Ꮚ஭ᡞ≧ែ࡜ࢫࣆࣥศ⿣ࢆ♧ࡍ⾲㠃≧
ែࡀ᭱㏆ࡢゅᗘศゎග㟁Ꮚศග㸦ARPES㸧ᐇ㦂࡜➨୍
ཎ⌮ィ⟬࡟ࡼࡾ┒ࢇ࡟◊✲ࡉࢀ࡚ࡁࡓࠋࡈࡃ᭱㏆ࠊBi
ⷧ⭷⾲㠃࡟㠀ᖖ࡟ᚤᙅ࡞ Rashba ᆺࡢศᩓࢆࡶࡘࣂࣥ
ࢻᵓ㐀ࡀ ARPES ᐇ㦂࡟ࡼࡾⓎぢࡉࢀࠊ✀ࠎࡢ⾲㠃ࣔ
ࢹࣝ࡟ᑐࡍࡿ➨୍ཎ⌮ィ⟬࠿ࡽࠊ୕ゅᙧ≧࡟ᡂ㛗ࡋࡓ
ᅗ 1 Bi ⾲㠃࡛ほ ࡉࢀࡓ୍ḟඖ࢚ࢵࢪ≧ែࡢ ARPES ᙉᗘ
ࣂ࢖ࣞ࢖࣮ࣖᓥᵓ㐀ࡢ࢚ࢵࢪ≧ែ࡟ࡼࡿ୍ḟඖⓗ࡞
࡜➨୍ཎ⌮ィ⟬ࡼࡾᚓࡽࢀࡓࣂࣥࢻᵓ㐀㸦ᐇ⥺㸧
ࣂࣥࢻ࡛࠶ࡿࡇ࡜ࡀุ᫂ࡋࡓࠋࡑࡢ୍ḟඖࣂࣥࢻࡣࢫ
ࣆࣥ㌶㐨┦஫స⏝࡟ࡼࡾ Rashba ศ⿣ࢆ㉳ࡇࡋࠊࡑࡢ
ࢫࣆࣥศᴟࡣ࢚ࢵࢪ᪉ྥ࡟ᆶ┤࡞⾲㠃ෆཬࡧ⾲㠃ᆶ┤ᡂศࢆྠ⛬ᗘ࡟᭷ࡍࡿࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡗࡓࠋ
࣭ཎᏊࢲ࢖ࢼ࣑ࢵࢡࢫࢆ฼⏝ࡋࡓ࣐ࢸࣜ࢔ࣝࢹࢨ࢖ࣥ
≀㉁ࡢᇶᗏ≧ែࢆグ㏙ࡍࡿ➨୍ཎ⌮㟁Ꮚ≧ែィ⟬࡜⇕ຊᏛⓗ⪃ᐹࢆ⤌ࡳྜࢃࡏࡿࡇ࡜࡟ࡼࡾࠊ᭷㝈 ᗘ࡟࠾ࡅࡿ≀㉁ྜᡂண ࢆ⾜ࡗ࡚࠸ࡿࠋ┦ᅗண ࡣࡑࡢ୰ᚰⓗ࡞ㄢ㢟࡛ࠊᙜࢢ࣮ࣝࣉ࡛ࡣ㧗࠸ Tc ࡢ㉸ఏ
ᑟ≀㉁࡜ࡋ࡚ᮇᚅࡉࢀࡿᅛయ࣍࢘⣲ࡢ┦ᅗண ࡟ຊࢆධࢀ࡚࠸ࡿࠋ௒ᖺᗘࡣ௨ୗࡢᡂᯝࢆᣲࡆࡓࠋⅣ໬
࣍࢘⣲⤖ᬗࡣ㧗࠸ Tc ࡢ㉸ఏᑟᮦᩱ࡜ࡋ࡚⌮ㄽண ࡉࢀ࡚࠸ࡿࡀࠊᐇ㦂࡛ࡣ㔠ᒓⓗ࡞᣺ࡿ⯙࠸ࡉ࠼ほ ࡉ
ࢀࡎࠊ༙ᑟయ࡛࠶ࡿࠋࡇࡢ⌮ㄽ࡜ᐇ㦂࡜ࡢ┦㐪ࡣࠊ㛗࠸㛫ᮍゎỴࡢ㞴ၥ࡛࠶ࡗࡓࠋᙜࢢ࣮ࣝࣉࡣ࣍࢘⣲
㛵ಀࡢ┦ᅗసᡂࢆ⾜࠸࡞ࡀࡽᏳᐃ࡞⤖ᬗᵓ㐀ࢆ᥈⣴ࡋࠊࡇࡢၥ㢟ࢆゎỴࡋࡓࠋࡇࢀࡲ࡛ࡢ┦㐪ࡢཎᅉ
ࡣ໬Ꮫ㔞ㄽⓗ⤌ᡂẚ࠿ࡽࡢࡎࢀ࡟࠶ࡗࡓࠋ໬Ꮫ㔞ㄽⓗ⤌ᡂẚࡢ⤖ᬗ࡛࠶ࢀࡤ㔠ᒓ࡟࡞ࡗࡓࡣࡎࡔࡀࠊࡑ
ࡢሙྜඹ᭷ᛶ⤖ྜࡢ᮲௳ࡀ‶ࡓࡉࢀࡎ⤖ᬗࡣ୙Ᏻᐃ࡟࡞ࡿࠋࡇࡢ୙Ᏻᐃᛶࢆ࿴ࡽࡆࡿࡼ࠺࡞໬Ꮫ㔞ㄽⓗ
⤌ᡂẚ࠿ࡽࡢࡎࢀࡀ࢚ࢿࣝࢠ࣮ⓗ࡟チࡉࢀࢀࡤ⤖ᬗࡣ⤯⦕య࡜࡞ࡿࠋࡑࡢࡼ࠺࡞᮲௳ࢆ‶ࡓࡍࡼ࠺࡞᱁
ᏊḞ㝗ࡀぢࡘ࠿ࡗࡓࠋࡑࢀࡣ㸲ࡘࡢ B ཎᏊ࠿ࡽᡂࡿࣜࣥࢢୖࡢḞ㝗࡛ࠊࡇࡢᵓ㐀ࣔࢹࣝ࡟ࡼࡾࡇࢀࡲ࡛
― 100 ―
ᮍゎỴ࡛࠶ࡗࡓᵝࠎ࡞⌧㇟ࡀㄝ࡛᫂ࡁࡿࡼ࠺࡟࡞ࡗࡓࠋ
࣭ᙉㄏ㟁㓟໬≀࡟࠾ࡅࡿ⇕㟁≉ᛶࡢ⌮ㄽண ᙉㄏ㟁ᛶ≀㉁ࡣ⤖ᬗࡢ✵㛫཯㌿ᛶࢆ◚ࡿࡇ࡜࡟ࡼࡗ࡚⯆࿡῝࠸⌧㇟ࢆ♧ࡍࡇ࡜ࡀ࠶ࡿࠋࢳࢱࣥ㓟ࣂࣜ
࣒࢘ࡣᐊ ࡛ᙉㄏ㟁ᛶࢆ♧ࡋ኱ࡁ࡞㟁Ẽศᴟࢆࡶࡘࡇ࡜ࡀ▱ࡽࢀ࡚࠸ࡿࡀࠊࡑࡢᴟᛶᵓ㐀ṍࡳࡀ⇕㟁≉
ᛶࢆ኱ࡁࡃ㧗ࡵࡿࡇ࡜ࢆ⌮ㄽண ࡋࡓࠋᡃࠎࡢ㟁Ꮚ≧ែィ⟬ࡢ⤖ᯝࠊ㟁Ꮚࢻ࣮ࣉࡋࡓࢳࢱࣥ㓟ࣂ࣒ࣜ࢘
ࡢࣇ࢙࣑ࣝ㠃ࡣ኱ࡁ࡞␗᪉ᛶࢆࡶࡗ࡚࠾ࡾࠊᐇ✵㛫࡛ࡣศᴟ᪉ྥࡢࢮ࣮࣋ࢵࢡಀᩘࢆ㧗ࡵࡿࡇ࡜ࡀ᫂ࡽ
࠿࡟࡞ࡗࡓࠋ௒ᚋࠊᙉㄏ㟁ṍࡳࢆไᚚࡍࡿࡇ࡜࡟ࡼࡾ⇕㟁≉ᛶࡀኚ໬ࡋ࠺ࡿ᪂ࡋ࠸ࢹࣂ࢖ࢫ࡬ࡢᛂ⏝ࡀ
ᮇᚅ࡛ࡁࡿࠋ
࣭ᅛయᆺࢼࢺ࣒ࣜ࢘◲㯤஧ḟ㟁ụࡢ඘ᨺ㟁ᶵᵓ
S ࡸ Na ከ◲໬≀⤖ᬗࡢ㟁Ꮚᵓ㐀࠾ࡼࡧ┦Ᏻᐃᛶࢆ
㔞Ꮚㄽ࡟ᇶ࡙ࡃ➨୍ཎ⌮ィ⟬࠿ࡽヲ⣽࡟ㄪ࡭ࠊᅛయ
Na/S 㟁ụࡢ඘ᨺ㟁ᶵᵓ࠾ࡼࡧ㟁ᅽ≉ᛶண ࢆ⾜ࡗࡓࠋ
S ⤖ᬗࡣࠊ8 ಶࡢ S ࡀ⎔≧࡟⧅ࡀࡗࡓ S8 ᵓ㐀ࣘࢽࢵࢺ
࡛ᵓᡂࡉࢀ࡚࠾ࡾࠊS8 ᵓ㐀ࣘࢽࢵࢺ㛫ࡢᙅ࠸ࣇ࢓ࣥࢹ
࣮ࣝ࣡ࣝࢫຊ࡟ࡼࡾᅛయ࡜ࡋ࡚จ㞟ࡋ࡚࠸ࡿࡇ࡜ࡀ᫂
ࡽ࠿࡜࡞ࡗࡓࠋNa/S ᨺ㟁཯ᛂ࡟ࡼࡗ࡚ᅛయ S ṇᴟ୰ࡢ
Na 㔞ࡀቑຍࡍࡿ࡜ࠊNa ࡜ S ࡢ⤌ᡂẚ࡟౫Ꮡࡋࡓ Na
ከ◲໬≀㸦Na2Sx㸧ࡀ⏕ᡂࡉࢀࡿࡇ࡜ࡀ࢚ࢿࣝࢠ࣮ゎᯒ
࠿ࡽ♧ࡉࢀࡓࠋᅛయ≧ែ࡟࠶ࡿ SࠊNaࠊ࠾ࡼࡧ Na ከ
◲໬≀㉁ࡢ┦Ᏻᐃᛶ࡟㛵ࡍࡿィ⟬⤖ᯝ࡟ᇶ࡙࠸࡚ࠊᅛ
య Na/S 㟁ụࡢᨺ㟁཯ᛂᘧ࡜㟁ᅽѸᐜ㔞᭤⥺ࢆ⌮ㄽⓗ࡟
ᅗ 2 ᅛయ Na/S 㟁ụࡢ㟁ᅽ-ᐜ㔞≉ᛶࡢ⌮ㄽィ⟬್
ண ࡋࡓࠋィ⟬ࡉࢀࡓ㟁ᅽ್ࡣࠊᨺ㟁᫬࡟ṇᴟഃ࡛⏕
ᡂࡉࢀࡿ Na2Sx ᅛయ┦ࡢ㐪࠸࡟㉳ᅉࡋ࡚ࠊ୺࡟ 3 ࡘࡢ
ࣉࣛࢺ࣮㡿ᇦࡀᏑᅾࡍࡿࡇ࡜ࢆ♧ࡋ࡚࠸ࡿࠋࡇࡢ⤖ᯝࡣ㧗 Na/S 㟁ụࡸࡈࡃ᭱㏆ࡢᅛయ Na/S ᐊ ືస
≉ᛶࡢᐇ㦂ሗ࿌࡜ࡶ▩┪ࡋ࡞࠸ࠋ
࣭A ࢧ࢖ࢺ⛛ᗎᆺ࣌ࣟࣇࢫ࢝࢖ࢺ㓟໬≀ࡢ☢ᛶ
A ࢧ࢖ࢺ⛛ᗎᆺ࣌ࣟࣇࢫ࢝࢖ࢺ㓟໬≀ AA’3B4O12 ࡣ༢⣧࡞࣌ࣟࣇࢫ࢝࢖ࢺᆺ㓟໬≀ ABO3 ࡢ A ࢧ࢖ࢺ
ࢆ஧✀㢮ࡢ㝧࢖࢜ࣥ A ࡜ A’࡛༨᭷ࡉࡏࡓ㓟໬≀⣔࡛ࠊ☢ᛶࢆࡣࡌࡵከᵝ࡞㟁Ꮚ≀ᛶࢆ♧ࡍࠋᡃࠎࡣ㸿̓
ࢧ࢖ࢺ࡟ Mn ࢆྵࡴ YMn3Al4O12 ࡜ LaMn3V4O12 ࡀ␗࡞ࡿ཯ᙉ☢ᛶⓗࢫࣆࣥ⛛ᗎࢆ♧ࡍࡇ࡜࡟╔┠ࡋ࡚㟁
Ꮚ≧ែ࡜☢Ẽ┦஫స⏝ࢆィ⟬ࡋࡓࠋࡑࡢ⤖ᯝ㸪 Mn ࡢ౯ᩘࡢᕪࡀ㉸஺᥮┦஫స⏝ࢆኚ໬ࡉࡏࠊ␗࡞ࡿࢫ
ࣆࣥ⛛ᗎࢆᏳᐃ໬ࡉࡏ࡚࠸ࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
― 101 ―
ࢯࣇࢺࢼࣀ࣐ࢸࣜ࢔ࣝ◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
኱Ꮫ㝔Ꮫ⏕
≉௵◊✲ဨ
Ꮫ᣺༤ኈ◊✲ဨ
஦ົ⿵బဨ
ᢏ⾡⿵బဨ
Ᏻ⸽ ⰾ㞝
ᐙ ⿱㝯
㎞ᕝ ㄔࠊ஧㇂ ┿ྖ
㝕ෆ 㟷ⴌࠊ➲⏣ ⩧ᖹࠊ⏣௦ ᙬࠊෆ⏣ ⤢⳯ࠊᒸᮏ ♸἞
Shreyam Chattergee
୹Ἴ ಇ㍜
ᒣᓮ ៞Ꮚ
㐂 ፍፍ㸦ᖹᡂ 26 ᖺ 4 ᭶ 1 ᪥㹼ᖹᡂ 26 ᖺ 10 ᭶ 31 ᪥㸧ࠊ
ᗈ℩ ⏤⨾㸦ᖹᡂ 26 ᖺ 7 ᭶ 1 ᪥㹼㸧
a) ᴫせ
᭷ᶵ≀㉁ࡢᶵ⬟ࢆศᏊࡢ࡛ࣞ࣋ࣝゎ᫂ࡋไᚚࡍࡿࡇ࡜ࢆᇶ┙࡜ࡋ࡚ࠊඃࢀࡓ㟁Ꮚ࣭ගᶵ⬟ࢆ᭷ࡍࡿ᭷
ᶵศᏊࡢ㛤Ⓨ࡜ᵓ㐀≀ᛶ┦㛵ࠊ࠾ࡼࡧࠊᶵ⬟ホ౯࡜᭷ᶵ࢚ࣞࢡࢺࣟࢽࢡࢫᛂ⏝ࡢ୍㈏ࡋࡓ◊✲ࢆ⾜ࡗ࡚
࠸ࡿࠋ᭷ᶵ࢚ࣞࢡࢺࣟࢽࢡࢫ࡟㐺ࡋࡓ᭷ᶵᶵ⬟ศᏊࡢ㛤Ⓨࠊ࠾ࡼࡧࠊศᏊࢫࢣ࣮࢚ࣝࣞࢡࢺࣟࢽࢡࢫࢆ
ᚿྥࡋࡓࢼࣀࢫࢣ࣮ࣝȧඹᙺศᏊᮦᩱࡢศᏊタィ࡜≀㉁ྜᡂࠊࡑࢀࡽࡢ≀ᛶ᭷ᶵ໬Ꮫ࡜ᶵ⬟᭷ᶵ໬Ꮫࡢ
◊✲ࢆ୰ᚰ࡟ࠊ1) ȧ㟁Ꮚඹᙺ⣔ࡢ໬Ꮫಟ㣭࡟ࡼࡿ㧗࠸㟁Ꮚ⛣ືᗘࢆ♧ࡍ᭷ᶵ༙ᑟయᮦᩱࡢ㛤Ⓨ 2) ศᏊ
࢚ࣞࢡࢺࣟࢽࢡࢫ⣲Ꮚ࡟㐺ࡋࡓࢼࣀࢫࢣ࣮ࣝศᏊᮦᩱࡢ㛤Ⓨࢆ┠ⓗ࡜ࡋ࡚ࠊᶵ⬟໬ศᏊ࣡࢖ࣖ࠾ࡼࡧ㔠
ᒓ㟁ᴟ᥋ྜࣘࢽࢵࢺࡢ㛤Ⓨ࡜ホ౯ࢆ㐍ࡵ࡚࠸ࡿࠋ
b) ᡂᯝ
᭷ᶵ࢚ࣞࢡࢺࣟࢽࢡࢫᮦᩱ࡜ࡋ࡚ࠊn ᆺࡢ᭷ᶵࢺࣛࣥࢪࢫࢱᮦᩱࡢ㛤Ⓨࢆ⾜ࡗࡓࠋṇᏍࢆ㍺㏦ࡍࡿ p
ᆺ༙ᑟయᮦᩱࡣᩘከࡃぢฟࡉࢀ࡚࠸ࡿ୍᪉ࠊ㟁Ꮚ㍺㏦⬟ࢆ᭷ࡍࡿ n ᆺ༙ᑟయᮦᩱࡢ㛤Ⓨࡣ౫↛࡜ࡋ࡚
㝈ࡽࢀ࡚࠸ࡿࠋȧ㟁Ꮚඹᙺ⣔࡟㟁Ꮚồᘬᛶᇶࢆᑟධࡍࡿࡇ࡜࡛ n ᆺ≉ᛶࡀⓎ⌧ࡍࡿ஦ࡀ▱ࡽࢀ࡚࠸ࡿࠋ
ᙜ◊✲ᐊ࡛ࡣࠊᙉ࠸㟁Ꮚồᘬᛶࡢຠᯝ࡜࢜ࣜࢦ࣐࣮࡟࠾ࡅࡿඹᙺᖹ㠃ᛶಖᣢࡢほⅬ࠿ࡽࠊ࢝ࣝ࣎ࢽࣝᇶ
ࢆ」ᩘᑟධࡋࡓȧ㟁Ꮚᣑᙇࣅࢳ࢔ࢰ࣮ࣝࣘࢽࢵࢺ 1 ࢆタィࡋࠊࡑࡢྜᡂἲࢆ☜❧ࡋ࡚࠸ࡿࠋ௒ᖺᗘࡣࠊ
㟁Ꮚཷᐜᛶࡢྥୖ࠾ࡼࡧࠊ኱Ẽୗ࡛ࡢᏳᐃࡋࡓ⣲Ꮚ㥑ືࢆᣦྥࡋ࡚ࠊ1 ࢆྵࡴ᪂つ࡞㟁Ꮚཷᐜᛶȧ㟁Ꮚ
⣔໬ྜ≀ 2̽6 ࡢྜᡂࢆ⾜࠸ࠊᇶ♏≀ᛶࢆ᫂ࡽ࠿࡜ࡋࡓࠋࡉࡽ࡟ࠊࡇࢀࡽࢆ༙ᑟయάᛶᒙ࡜ࡋࡓ FET ⣲Ꮚ
ࢆస〇ࡋ n ᆺ≉ᛶࡢホ౯ࢆ⾜ࡗࡓࠋ኱Ẽᭀ㟢ୗ࡛ࡢ ᐃ࡟࠾࠸࡚ࠊ࢔ࢩࣝᇶࢆᑟධࡋࡓ 2, 3 ࡛㟁Ꮚ⛣
ືᗘࡀ┿✵ୗ࡟ẚ࡭࡚ 2 ᱆పୗࡋࡓࡢ࡟ᑐࡋ࡚ࠊࣃ࣮ࣇࣝ࢜ࣟ࢔ࢩࣝᇶࢆ⏝࠸ࡓ 4, 5 ࡣ኱Ẽᭀ㟢ୗ࡛ࡶ
Ⰻዲ࡞㟁Ꮚ⛣ືᗘࢆ♧ࡋࡓࠋ
୍᪉ࠊ5 ⷧ⭷ࡢ X ⥺ᅇᢡ ᐃࢆ⾜ࡗࡓ࡜ࡇࢁࠊᙅ࠸ᅇ
ᢡࣆ࣮ࢡࡀほ ࡉࢀࡿࡢࡳ
࡛࠶ࡾࠊ⤖ᬗᛶࡢప࠸ⷧ⭷
࡛࠶ࡿࡇ࡜ࡀ♧၀ࡉࢀࡓࠋ
ࡇࢀࡽࡢ⤖ᯝ࠿ࡽࠊ5 ࡟࠾
ࡅࡿ኱Ẽୗ࡛ࡢᏳᐃࡋࡓ㟁
Ꮚ㍺㏦⬟ࡢⓎ⌧ࡣࠊࣃ࣮ࣇ
ࣝ࢜ࣟ࢔ࢩࣝᇶࡢ┤᥋ᑟධ
࡟ࡼࡿ᭱ప✵㌶㐨 (LUMO)
‽఩ࡢపୗ࡟㉳ᅉࡋࡓ㑏ඖ
✀ࡢ⇕ຊᏛⓗᏳᐃ໬࡟⏤᮶
ࡍࡿࡶࡢ࡛࠶ࡿ࡜♧၀ࡉࢀ
ᅗ 1 ࢝ࣝ࣎ࢽࣝᯫᶫࣘࢽࢵࢺࢆྵࡴ㟁Ꮚཷᐜᆺȧ㟁Ꮚ⣔໬ྜ≀
― 102 ―
㻌
Current Density / mA·cm–2
ࡓࠋ[ㄽᩥ 4](ᅗ 1)ࠋ
᭷ᶵⷧ⭷ኴ㝧㟁ụ㸦OPV㸧࡬ࡢᛂ⏝ࢆ┠ᣦࡋࡓ p ᆺ༙ᑟయᮦᩱ࡟㛵ࡋ࡚ࡣࠊࢻࢼ࣮㒊఩(D)࡜࢔ࢡࢭࣉ
ࢱ࣮㒊఩(A)ࢆ㐃⤖ࡉࡏࡓ D–A ᆺ஺஫࣏࣐࣮ࣜࡀ᭷ຠ࡛࠶ࡿࡇ࡜ࡀሗ࿌ࡉࢀ࡚࠸ࡿࠋࡇࢀࡲ࡛࡟ᡃࠎࡀ
㛤Ⓨࡋࡓࢪ࢜࢟ࢯࢩࢡࣟ࢔ࣝࢣࣥ⦰⎔ࢳ࢜ࣇ࢙ࣥ(C6)ࢆ࢔ࢡࢭࣉࢱ࣮㒊఩࡟⏝࠸ࡓ D–A ᆺࢥ࣏࣐࣮ࣜ
DTS-C6 ࡜ࣇ࣮ࣛࣞࣥㄏᑟయ(PC71BM)࡜ࢆ⤌ࡳྜࢃࡏࡓ⣲Ꮚ࡟࠾࠸࡚ 4.87%ࡢග㟁ኚ᥮ຠ⋡(PCE)ࢆ♧ࡍ
㻌
ࡇ࡜ࡀぢฟࡉࢀ࡚࠸ࡿࠋග㟁ኚ
᥮ຠ⋡ࢆࡉࡽ࡟ྥୖࡉࡏࡿほ
Ⅼ࠿ࡽࠊศᏊ㔞ไᚚࠊࣈࣞࣥࢻ
⭷ࡢࣔࣝࣇ࢛ࣟࢪ࣮ࡢไᚚࡢ
᳨ウࢆ⾜࡞ࡗࡓ⤖ᯝࠊPCE ࢆ
7.85%ࡲ࡛ྥୖࡉࡏࡿࡇ࡜࡟ᡂ
ຌࡋࡓ[ㄽᩥ 5](ᅗ 2)ࠋ
PC61BM ࡸ PC71BM ࡣ OPV
࡟࠾ࡅࡿ඾ᆺⓗ࡞ n ᆺ༙ᑟయ
㻌
ᮦᩱ࡜ࡋ࡚⏝࠸ࡽࢀ࡚࠸ࡿࠋࡋ
ᅗ 2 ᭷ᶵⷧ⭷ᆺኴ㝧㟁ụᮦᩱ࡟ྥࡅࡓ D-A ᆺ࣏࣐࣮ࣜ
࠿ࡋࠊ㏆ᖺࠊࣇ࣮ࣛࣞࣥㄏᑟయ
ࡣ p ᆺ㍺㏦⬟ࡶేࡏᣢࡘࡇ࡜
ࡀሗ࿌ࡉࢀ࡚࠸ࡿࠋᡃࠎࡣࡇࢀ
OMe
OMe
ࡲ࡛࡟ࠊࡇࢀࡽࣇ࣮ࣛࣞࣥㄏᑟ
O
O
యࡼࡾప࠸ LUMO ࣞ࣋ࣝࢆᣢ
p-type
ࡕࠊ࠿ࡘࠊⰋዲ࡞㟁Ꮚ㍺㏦≉ᛶ
ࢆ♧ࡍ BCN-HH-BCN ࡢ㛤Ⓨ
PC61BM PC71BM
࡟ᡂຌࡋ࡚࠸ࡓࠋࡑࡇ࡛ࠊ௒ᖺ
NC
CN
ᗘࡣࣂࣝࢡ࣊ࢸࣟ᥋ྜ OPV ࡟
C H
F
NC
CN
S
࠾ࡅࡿࣇ࣮ࣛࣞࣥㄏᑟయࡢ p
S
F
F
S
S
n-type NC
ᆺ≉ᛶࢆ᫂ࡽ࠿࡜ࡍࡿࡓࡵࠊ
CN
F
H C
NC
CN
BCN-HH-BCN ࡜ PC61BM ࡸ
BCN-HH-BCN
PC71BM ࢆ⤌ࡳྜࢃࡏࡓ OPV
࡛ホ౯ࢆ⾜࡞ࡗࡓࠋࡑࡢ⤖ᯝࠊ ᅗ 3 ࣇ࣮ࣛࣞࣥㄏᑟయࢆ p ᆺᮦᩱ࡟⏝࠸ࡓ OPV
࠸ࡎࢀࡢ⣲Ꮚࡶ඾ᆺⓗ࡞ග㟁
ኚ᥮≉ᛶࢆ♧ࡋࡓࠋࡉࡽ࡟ࠊ㐣Ώ྾཰ ᐃ࠿ࡽࣇ࣮ࣛࣞࣥㄏᑟయࡢࣛࢪ࢝ࣝ࢝ࢳ࢜ࣥ࡜ BCN-HH-BCN
ࡢࣛࢪ࢝ࣝ࢔ࢽ࢜ࣥ✀ࡀほ ࡉࢀࡓࠋࡇࢀࡽࡢ⤖ᯝ࠿ࡽࠊࡇࡢ⣔࡟࠾࠸࡚ࣇ࣮ࣛࣞࣥㄏᑟయࡣࢻࢼ࣮ᮦ
ᩱ࡜ࡋ࡚ᶵ⬟ࡍࡿࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡗࡓ[ㄽᩥ 1](ᅗ 3)ࠋ
ࡲࡓࠊ᭷ᶵⷧ⭷ᆺኴ㝧㟁ụ࡟࠾ࡅࡿ n ᆺ༙ᑟయᮦᩱ࡜ࡋ࡚ࡢᛂ⏝ࢆ┠ⓗ࡜ࡋ࡚ࠊ᪂つࣇ࣮ࣛࣞࣥㄏᑟ
యࡢ㛤Ⓨࢆ௻ᴗ࡜ඹྠ◊✲࡟ࡼࡾ⾜ࡗ࡚࠸ࡿࠋᡃࠎࡣࣇࣞࣟࣆࣟࣜࢪࣥㄏᑟయࢆᇶᮏ࡟ࠊ⨨᥮ᇶ࡜≀ᛶ
┦㛵ࡢぢᆅ࠿ࡽ᳨ウࢆ㔜ࡡ࡚ࡁࡓࠋࡇࢀࡲ࡛࡟ PCBM ࡟௦ࢃࡿኴ㝧㟁ụᮦᩱࣇ࣮ࣛࣞࣥㄏᑟయࢆぢฟࡋ
࡚࠸ࡿ[ㄽᩥ 8]ࠋࡇࢀࢆᇶ┙࡟ OPV ⣲Ꮚࡢ㧗㟁ᅽ໬࡟ᐤ୚ࡍࡿ᪂つᮦᩱ㛤Ⓨ࡜ࢹࣂ࢖ࢫ ᐃ⤖ᯝ࡟ࡘ࠸
࡚᭦࡞ࡿ᳨ウࢆ⾜ࡗࡓࠋࡑࡢ⤖ᯝࠊࣇ࣮ࣛࣞࣥㄏᑟయ࡬ᑟධࡋࡓ⨨᥮ᇶ࡟ࡼࡗ࡚㛤ᨺ➃㟁ᅽࢆ㐃⥆ⓗ࡟
ኚ໬ࡉࡏࡿࡇ࡜ࡀ࡛ࡁࡿࡇ࡜ࡀศ࠿ࡗࡓ(ᅗ 4,5)ࠋ
6 13
13 6
㻌
㻌
10
N
R4
1: R1, R2
R3 , R4
= F and H,
=H
2: R1, R2 = F, R3, R4 = H
3: R1, R2 = H, R3, R4 = F and H
4: R1, R2 = H, R3, R4 = F
5: R1, R2 , R3 , R4 = F
6: R1, R2 = F and H, R3 , R4 = OMe and H
7: R1, R2 = F, R3, R4 = OMe and H
8: R1, R2 = F, R3, R4 = OMe
ᅗ 4 ᪂つࣇ࣮ࣛࣞࣥㄏᑟయࡢ໬Ꮫᵓ㐀
15
10
2
R2R 3
5
6
7
8
5
0
-5
-10
-15
-1.0
-0.5
Current density (mA/cm )
R1
1
2
3
4
㻌
2
Current density (mA/cm )
20
0.0
0.5
Voltage (V)
1.0
5
0
-5
-10
0.5
0.6
0.7
0.8
0.9
Voltage (V)
ᅗ 5 ᪂つࣇ࣮ࣛࣞࣥࡢ OPV ⣲Ꮚ࡟࠾ࡅࡿ㛤ᨺ➃㟁ᅽኚ໬
― 103 ―
1.0
ࣂ࢖࢜ࢼࣀࢸࢡࣀࣟࢪ࣮◊✲ศ㔝
ᩍᤵ
෸ᩍᤵ
ຓᩍ
≉௵ᩍᤵ
≉௵ຓᩍ
≉௵◊✲ဨ
༤ኈ◊✲ဨ
኱Ꮫ㝔Ꮫ⏕
Ꮫ㒊Ꮫ⏕
஦ົ⿵బဨ
㇂ཱྀ ṇ㍤
⟄஭ ┿ᴋ
⏣୰ ⿱⾜ࠊᶓ⏣ ୍㐨
ᕝྜ ▱஧
኱ᇛ ᩗேࠊỤᓮ ⿱Ꮚ㸦ᖹᡂ 27 ᖺ 1 ᭶ 16 ᪥᥇⏝㸧
ᮧᒣ ࡉ࡞࠼ࠊ㔠஭ ┿ᶞࠊYuhui He㸦ᖹᡂ 26 ᖺ 8 ᭶ 31 ᪥ࡲ࡛㸧ࠊ
ᑠ࿴⏣ ᘯᯞ㸦ᖹᡂ 26 ᖺ 4 ᭶ࡢࡳ㸧
ࠊಖᡭ὾ ༓⤮㸦ᖹᡂ 26 ᖺ 4 ᭶ࡢࡳ㸧ࠊ
ᒣ⏣ 㔛⤮㸦ᖹᡂ 26 ᖺ 4 ᭶ࡢࡳ㸧
Yuhui He㸦ᖹᡂ 26 ᖺ 9 ᭶ 1 ᪥᥇⏝㸧
᭷㤿 ᙲ⚽ࠊ᳃ᕝ 㧗඾
㇂ᮏ ᖾᯞ
⸨ᯘ ஀⌮Ꮚ
a) ᴫせ
⚾㐩ࡢࢢ࣮ࣝࣉ࡛ࡣࠊ་⒪デ᩿ᢏ⾡ࡢ㧗ᗘ໬࣭㧗ᛶ⬟໬࡟ྥࡅ࡚ࠊ⏕యෆࡢᵓ㐀ࡸᶵ⬟ࢆᶍೌࡋࡓ༙
ᑟయࢼࣀࢹࣂ࢖ࢫࡸ 1 ศᏊ᳨ฟཎ⌮ࡢ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋ㟁Ꮚ⥺ᥥ⏬ἲ࡞࡝ࡢඛ➃ࣞ࣋ࣝࡢࢼࣀຍᕤᢏ
⾡ࢆ㥑౑ࡋࡓࠊᩘࢼࣀ࣓࣮ࢺࣝࢧ࢖ࢬࡢ㟁ᴟࢠࣕࢵࣉࢆసࡿࡓࡵࡢ᪂ࡓ࡞ᢏ⾡ࢆ๰〇ࡋࠊࡇࢀࢆᛂ⏝ࡋ
࡚ࠊ㟁ᴟ㛫࡟㓄⥺ࡉࢀ࡚࠸ࡿศᏊࡢᩘࡸ✀㢮ࠊ1 ศᏊࡀ㟁ᴟ࡟ࡘ࡞ࡀࡗ࡚࠸ࡿᙉᗘࡸ᫬㛫ࠊ㟁ᴟ࡟᥋⥆
ࡉࢀ࡚࠸ࡿ 1 ศᏊࡢ㏻㟁᫬࡟࠾ࡅࡿᒁᡤ ᗘࠊ1 ศᏊࡢࢲ࢖ࢼ࣑ࢡࢫࡸ໬Ꮫ཯ᛂࢆ㟁Ẽⓗ࡟ㄪ࡭ࡿ᪉ἲ
ࢆᵓ⠏ࡋ࡚࠸ࡿࠋࡲࡓࠊ㉮ᰝࣉ࣮ࣟࣈ㢧ᚤ㙾࡟ࡼࡾࠊ⾲㠃ୖ࡟࠶ࡿ DNA ࡞࡝ࡢ 1 ศᏊほᐹ࠾ࡼࡧศග
࡜ศᏊ࣐ࢽࣆ࣮ࣗࣞࢩࣙࣥࢆ⾜ࡗ࡚࠸ࡿࠋࡑࡋ࡚ࠊࡇࢀࡽࡢᇶ♏◊✲ࢆ㏻ࡌ࡚ࠊ1 ศᏊࡢᛶ㉁ࢆㄪ࡭ࡿ
1 ศᏊ⛉Ꮫࢆ㛤ᣅࡋࠊྠ᫬࡟ࡇࡢ 1 ศᏊ⛉Ꮫࢆᇶᮏཎ⌮࡜ࡍࡿ᪂ࡋ࠸ࣂ࢖࢜ศᏊࢹࣂ࢖ࢫࡸࣂ࢖࢜ࢭࣥ
ࢧ࣮ࢆ㛤Ⓨࡍࡿ࡜ඹ࡟ࠊSM-TAS(Single-Molecule Total Analysis System)ࡢᐇ⌧࡟㈨ࡍࡿ 1 ศᏊᢏ⾡ࡢ๰ฟ
࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿࠋ
୺࡞◊✲ㄢ㢟࡜ࡋ࡚ࡣࠊSPM ࡟ࡼࡿ DNA ➼ࡢࣂ࢖࢜ศᏊࡢࢼࣀࢧ࢖࢚ࣥࢫ࣭ࢼࣀࢸࢡࣀࣟࢪ࣮ࠊࢼ
ࣀ㟁ᴟ࡜ࢼࣀὶ㊰ࢆ⼥ྜࡉࡏࡓ 1 ศᏊࣂ࢖࢜ࢭࣥࢧ࣮ࡢ㛤Ⓨࠊᅛయࢼࣀ࣏࢔ࢹࣂ࢖ࢫࢆ⏝࠸ࡓࢼࣀ࣏࢔
ࢩ࣮ࢡ࢚ࣥࢩࣥࢢἲࡢ㛤Ⓨࠊ┬㈨※࣭┬࢚ࢿࣝࢠ࣮࡟㈨ࡍࡿ༢୍ศᏊࢹࣂ࢖ࢫࡢ㛤Ⓨࠊࡀᣲࡆࡽࢀࡿࠋ
b) ᡂᯝ
࣭༢ศᏊ᥋ྜࡢ⇕㟁ᛶ⬟ホ౯
༢ศᏊ᥋ྜ࡟≉᭷ࡢ㟁Ꮚ≧ែࢆ฼⏝ࡍࡿࡇ࡜࡛ࠊ㧗࠸ᛶ⬟ࢆ᭷ࡍࡿ⇕㟁⣲Ꮚࢆ๰〇ࡍࡿࡇ࡜ࡀ⌮ㄽୖ
ྍ⬟࡛࠶ࡿࡇ࡜ࡀᣦ᦬ࡉࢀ࡚௨᮶ࠊ༢ศᏊ᥋ྜࡢ
⇕㟁≉ᛶ࡟㛵ࡍࡿ◊✲ࡀ⢭ຊⓗ࡟⾜ࢃࢀ࡚ࡁ࡚
࠸ࡿࠋࡋ࠿ࡋࡇࢀࡲ࡛ࡢ㉮ᰝࢺࣥࢿࣝ㢧ᚤ㙾ࢆ⏝
࠸ࡓ㸯ศᏊ⇕㉳㟁ຊィ ἲ࡛ࡣࠊ⇕ࢻࣜࣇࢺ➼ࡢ
ၥ㢟ࡀ࠶ࡾࠊ㟁ᴟ̿༢ศᏊ̿᥋ྜࢆᙧᡂ࡛ࡁ࡚ࡶࠊ
ࡑࡢ≧ែࢆࠊ⇕㉳㟁ຊ ᐃࢆᐇ⾜ࡍࡿୖ࡛༑ศ࡟
㛗࠸᫬㛫ಖᣢࡍࡿࡇ࡜ࡀᅔ㞴࡛࠶ࡗࡓࠋࡑࡇ࡛ࠊ
༢ศᏊ᥋ྜࡢᏳᐃಖᣢ࡟㐺ࡋࡓࢼࣀຍᕤ MCBJ
(mechanically-controllable break junction㸧ࢆᨵⰋࡋࠊ
ࢼࣀ᥋ྜࡢ㏆ഐ࡟㏻㟁ᆺࡢࣄ࣮ࢱ࡜ࡋ࡚⏝࠸ࡿ
ࡇ࡜ࡀ࡛ࡁࡿࣉࣛࢳࢼ⣽⥺ࢆసࡾࡇࢇࡔ࣐࢖ࢡ
ࣟࣄ࣮ࢱ⤌㎸ࡳᆺ MCBJ㸦ᅗ 1㸧ࢆ㛤Ⓨࡋࠊࡇࢀ
ᅗ 1 ࣐࢖ࢡࣟࣄ࣮ࢱ⤌㎸ࡳᆺ MCBJ ⣲ᏊࡢගᏛ㢧ᚤ㙾ീ.
― 104 ―
ࢆ⏝࠸࡚㔠㸫1,4-࣋ࣥࢮࣥࢪࢳ࣮࢜ࣝ㸫㔠᥋ྜࡢ㟁Ẽఏᑟᗘ࡜⇕㉳㟁ຊࡢྠ᫬ィ ࢆᐇ᪋ࡋࡓࠋ
ᚓࡽࢀࡓ⇕㉳㟁ຊࡣ᥋ྜᙧ≧࡟ࡼࡗ࡚኱ࡁࡃࣂࣛࡘࡃഴྥࡀぢࡽࢀࡓࠋࡇࢀࡣࠊ㟁ᴟ㛫ࢆᯫᶫࡍࡿศ
Ꮚࡢ㓄ྥࡸࠊ㟁ᴟ㸫ศᏊࢥࣥࢱࢡࢺ㒊ศࡢཎᏊᵓ㐀ࡢ㐪࠸࡟ࡼࡗ࡚ࠊ༢ศᏊ᥋ྜࡢ㟁Ꮚ≧ែࡀ኱ࡁࡃኚ
໬ࡍࡿࡓࡵࡔ࡜⪃࠼ࡽࢀࡿࠋ
୍᪉ࠊ⇕㉳㟁ຊࡢᖹᆒ್ࡣ༢ศᏊ᥋ྜ㟁Ẽఏᑟᗘ࡟ࡼࡽࡎᴫࡡ୍ᐃ್ࢆ♧ࡋࡓࠋࡇࢀࡣࣂࣝࢡᮦᩱ࡟
࠾ࡅࡿࣔࢵࢺࡢ⌮ㄽ࡜ࡣ␗࡞ࡿഴྥ࡛ࠊศᏊ᥋ྜ≉᭷ࡢ≉ᛶ࡛࠶ࡾࠊ㔠㸫1,4-࣋ࣥࢮࣥࢪࢳ࣮࢜ࣝ㸫㔠
᥋ྜࡢࡼ࠺࡟ࠊࣇࣟࣥࢸ࢕࢔ศᏊ㌶㐨ࣞ࣋ࣝࡀ㟁ᴟࣇ࢙࣑ࣝࣞ࣋ࣝࡼࡾ 1eV ⛬ᗘ㞳ࢀࡓ఩⨨࡟Ꮡᅾࡍࡿ
ࢺࣥࢿࣝ᥋ྜ⣔࡟࠾࠸࡚⌮ㄽⓗ࡟ண ࡉࢀ࡚࠸ࡓ⌧㇟࡛࠶ࡿࠋ
ࡲࡓࠊᚓࡽࢀࡓ㟁Ẽఏᑟᗘ࡜⇕㉳㟁ຊ࠿ࡽ↓ḟඖᛶ⬟ᣦᩘ ZT ࢆィ⟬ࡋࡓ࡜ࡇࢁࠊ᭱㐺࡞᥋ྜᵓ㐀᮲
௳ୗ࡟࠾࠸࡚ 1 ௨ୖࡢ㧗࠸್ࡀᚓࡽࢀࡓࠋᮏ⤖ᯝࡣࠊ㧗ᛶ⬟࡞ 1 ศᏊ⇕㟁⣲Ꮚࢆ㛤Ⓨࡍࡿ࠺࠼࡛ࠊศᏊ
ᵓ㐀࡟ຍ࠼࡚㟁ᴟ㸫ศᏊ᥋ྜᵓ㐀ࢆタィ࡟ྲྀࡾධࢀࡿࡇ࡜ࢆ♧၀ࡋ࡚࠸ࡿࠋ
࣭኱Ẽ୰ᾋ㐟ᚤ⢏Ꮚࡢᤕ㞟⏝ࢹࣂ࢖ࢫࡢ㛤Ⓨ
ᅛయ࣓ࣥࣈࣞࣥ୰ࡢࢼࣀࢧ࢖ࢬࡢ⣽
Ꮝ࡛ᵓᡂࡉࢀࡿࢼࣀ࣏࢔ࢭࣥࢧ࣮ࡣࠊ
ᚤ⢏Ꮚࡸ⣽⳦࣭࢘࢖ࣝࢫ➼ࢆ㧗ឤᗘ࡛
᳨ฟࡍࡿࣂ࢖࢜ࢭࣥࢧ࣮࡜ࡋ࡚ࠊࡑࡢ
ᐇ⏝໬࡟ྥࡅࡓ◊✲㛤Ⓨࡀᗈࡃᒎ㛤ࡉ
ࢀ࡚ࡁ࡚࠸ࡿࠋ
ࡇࡢᢏ⾡ࡢᐇ⏝໬࡟ࡣࠊከᩘࡢዃ㞧
≀ࡀΰࡌࡿࢧࣥࣉࣝ㸦኱Ẽởᰁ≀㉁ࡸ
⏕యᢳฟ≀㸧࠿ࡽ᳨ฟᑐ㇟࡜࡞ࡿ≀㉁
ࢆຠ⋡ⓗ࡟ࢼࣀ࣏࢔ࢭࣥࢧ࣮㒊࡟㍺㏦
ࡍࡿࡇ࡜ࡀᚲせ࡛࠶ࡾࠊࢼࣀ࣏࢔ࢹࣂ
࢖ࢫࡢ㛗ᑑ࿨໬࡟ࡣ᳨ฟᑐ㇟௨እࡢዃ
㞧≀ࢆ᤼㝖ࡍࡿࡇ࡜ࡀᮃࡲࡋ࠸ࠋ
ࡑࡇ࡛࣐࢖ࢡࣟὶ㊰ୖ࡟ከᩘࡢ࣐࢖ ᅗ 2 ኱Ẽ୰ᾋ㐟ᚤ⢏Ꮚࡢᤕ㞟⏝ࢹࣂ࢖ࢫࠋ࣐࢖ࢡࣟὶ㊰࡟ࡣࣂࢵࣇ࢓⁐ᾮࡀ඘ሸ
ࢡ࣏ࣟ࢔ࢆస〇ࡋࠊࡑࡢ㟁ゎ㉁⁐ᾮ࣓ ࡉࢀࠊᚤ⢏Ꮚࡣᤕ㞟⏝࣐࢖ࢡ࣏ࣟ࢔ࡢ࣓ࢽࢫ࢝ࢫ࠿ࡽᤕ㞟ࡉࢀࡿࠋᚤ⢏Ꮚࡣ㟁Ẽ
ࢽࢫ࢝ࢫ࠿ࡽ᳨య⢏Ꮚࢆᤕ㞟ࡍࡿ࡜࡜ Ὃື࡟ࡼࡗ࡚ศ㞳⏝࣐࢖ࢡࣟࢫࣜࢵࢺ࡟ㄏᑟࡉࢀࡓᚋࠊࢼࣀ࣏࢔᳨࡛ฟࡉࢀࡿࠋ
ࡶ࡟ࠊ㟁ẼὋື࡟ࡼࡗ࡚ศ㞳⏝࣐࢖ࢡࣟࢫࣟࢵࢺ࡟ㄏᑟࡋࢧ࢖ࢬศ㞳ࢆ⾜࠺ᶵᵓࢆࠊࢼࣀ࣏࢔ࢹࣂ࢖ࢫ
ࡢࢳࢵࣉࢹୖ࡟㞟✚໬ࡋࡓ㸦ᅗ 2㸧
ࠋ⺯ග㢧ᚤ㙾ほᐹ࡟ࡼࡾࠊᯤⲡ⳦ࡀ࣐࢖ࢡ࣏ࣟ࢔࠿ࡽᤕ㞟ࡉࢀࠊ㟁Ẽ
Ὃື㟁ᅽࡢ༳ຍ࡟ࡼࡗ࡚ᯤⲡ⳦ࡢ㍺㏦ไᚚࡀྍ⬟࡛࠶ࡿࡇ࡜ࢆ☜ㄆࡋࡓࠋࡲࡓᖜ 2ȝm ࡢ࣐࢖ࢡࣟࢫࣜࢵ
ࢺ࠿ࡽࠊ┠ⓗࢧ࢖ࢬࡢ᳨యࢆ㑅ᢥⓗ࡟ᢳฟ࡛ࡁࡿࡇ࡜ࢆᐇドࡋࡓࠋ
࣭ࢢࣛࣇ࢙ࣥᡂ⭷⏝ࡢཎᏊ࡛ࣞ࣋ࣝᖹᆠ࡞ Pt(111)ᇶᯈࡢసᡂ
DNA ࡢሷᇶศᏊ࡞࡝ࢆ㆑ูࡍࡿ㟁ᴟࡸᇶᯈ࡜ࡋ
࡚ࢢࣛࣇ࢙ࣥࡀὀ┠ࡉࢀ࡚࠸ࡿࠋ㔠ᒓᇶᯈ࡟ᨭᣢࡉ
ࢀࡓࢢࣛࣇ࢙ࣥࢆ⏝࠸ࡿሙྜࠊୗᆅᨭᣢᇶᯈࡢ㔠ᒓ
✀࡟ࡼࡗ࡚ࡣࢢࣛࣇ࢙ࣥ≉᭷ࡢ㟁Ꮚ≧ែࡀᦆ࡞ࢃ
ࢀࡿࡇ࡜ࡀ▱ࡽࢀ࡚࠸ࡿࡀࠊⓑ㔠࡛ࡣࣇ࣮ࣜࢫࢱࣥ
ࢹ࢕ࣥࢢ࡟㏆ࡃࠊ ᐃࡍࡿ࡭ࡁ྾╔ศᏊࡢ㟁Ꮚ≧ែ
࡬ࡢࠊୗᆅ㔠ᒓᇶᯈ࠿ࡽࡢᙳ㡪ࡶᑡ࡞࠸ࠋṧᛕ࡞ࡀ
ࡽ Pt(111)ࡢཎᏊⓗ࡟ᖹᆠ࡛Ύί࡞⾲㠃ࢆᚓࡿࡇ࡜
ࡣᅔ㞴࡞ࡇ࡜ࡀከ࠸ࠋࡑࡇ࡛ࠊ㧗౯࡞ Pt(111)༢⤖ ᅗ 3 YSZ(111)ཬࡧ Al2O3(0001)ୖ࡟ᡂ⭷ࡉࢀࡓ Pt(111)ⷧ⭷
ᬗࡢΎί໬࠿ࡽ࡛ࡣ࡞ࡃࠊࡼࡾᏳ౯࡞ᅛయᇶᯈ࡟ⓑ㔠ࢆ⵨╔ࡍࡿࡇ࡜࡟ࡼࡾཎᏊⓗ࡟ᖹᆠ࡞⾲㠃ࢆᚓࡿ
ࡇ࡜ࢆ᳨ウࡋࡓࠋࡑࡢ⤖ᯝࠊYSZ(111)ࡸ Al2O3(0001)ᇶᯈୖࡢⓑ㔠ࡢᡂ⭷࡟ࡼࡾࠊᅗ 3 ࡟♧ࡍᵝ࡞ࠊPt(111)
⾲㠃ࡢ༢ཎᏊࢫࢸࢵࣉࡀ᫂░࡟☜ㄆ࡛ࡁࡿ࡯࡝ཎᏊⓗ࡟ᖹᆠ࡞⾲㠃ࢆసᡂࡍࡿࡇ࡜࡟ᡂຌࡋࡓࠋࡉࡽ࡟
⾲㠃ࢆΎί໬ࡋࠊࢢࣛࣇ࢙ࣥࡢᡂ⭷ࡀ࡛ࡁࡿࡇ࡜ࡶ᫂ࡽ࠿࡟ࡋࡓࠋ
― 105 ―
⎔ቃ࣭࢚ࢿࣝࢠ࣮ࢼࣀᛂ⏝ศ㔝
ᩍᤵ㸦ව௵㸧
Ᏻ⸨ 㝧୍
a) ᴫせ
ᮏ◊✲ศ㔝࡛ࡣࠊ⏘ᴗ⛉Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮ࡀ᭷ࡍࡿ࣐࢖ࢡ࣭ࣟࢼࣀຍᕤࡢࡓࡵࡢタഛ࡜ᢏ
⾡ࢆ฼⏝ࡋ࡚ࠊ⎔ቃ࣭࢚ࢿࣝࢠ࣮ၥ㢟ࡢゎỴ࡟ᙺ❧ࡘ㉸ఏᑟᮦᩱ࣭ࢫࣆࣥࢺࣟࢽࢡࢫᮦᩱ࣭㧗ຠ⋡⇕㟁
ኚ᥮ᮦᩱ࡞࡝ࡢ≀ᛶ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋᮏᖺᗘࡣ≉࡟ࠊࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࡢ୰࡛ࡶࣂࣝࢡ⤯⦕ᛶࡀ㣕
㌍ⓗ࡟ྥୖࡋࡓ Bi2-xSbxTe3-ySey ࡟ὀ┠ࡋ࡚◊✲ࡋࡓࠋ
b) ᡂᯝ
࣭ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࡢᇶ♏≀ᛶゎ᫂
㟁Ꮚࡢᣢࡘࢫࣆࣥࡢྥࡁࡢ⮬⏤ᗘࢆ฼⏝ࡍࡿࢫࣆࣥࢺࣟࢽࢡࢫ࡟࠾࠸࡚ࡣࠊ࠸࠿࡟ࢫࣆࣥࢆไᚚࡍࡿ
࠿ࡀᢏ⾡ࡢ୰ᚰ࡛࠶ࡿࠋ2007 ᖺ࡟ࠊ≀㉁୰ࡢ౯㟁Ꮚᖏࡢᣢࡘ఩┦ᗄఱᏛⓗ࡞ᛶ㉁࡟ࡼࡗ࡚ࠊࣂࣝࢡ࡟ࡣ
⤯⦕యࡔࡀ⾲㠃࡟↓ᩓ㐓ࡢࢫࣆࣥὶࡀᏑᅾࡍࡿࡼ࠺࡞≀㉁ࡀ࠶ࡿࡢ࡛ࡣ࡞࠸࠿࡜⌮ㄽⓗ࡟ண ࡉࢀࠊࡑ
ࡢࡼ࠺࡞≀㉁ࡣࠕࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࠖ࡜ྡ௜ࡅࡽࢀࡓࠋᛂ⏝ࡢほⅬ࠿ࡽࡣࠊࡑࡢ↓ᩓ㐓ࡢࢫࣆࣥὶࢆ
ࢹࣂ࢖ࢫ࡟ᛂ⏝࡛ࡁࢀࡤࠊ㉸┬࢚ࢿࣝࢠ࣮ᆺࡢࢫࣆࣥࢺࣟࢽࢡࢫࡀᐇ⌧࡛ࡁࡿྍ⬟ᛶࡀ࠶ࡿࠋ
ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య◊✲ࡢึᮇ࡟࠾࠸࡚ࠊᐇ㝿࡟ Bi1-xSbxࠊBi2Se3ࠊBi2Te3 ࡀࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య࡛࠶
ࡿࡇ࡜ࡀ᫂ࡽ࠿࡟࡞ࡗࡓࡀࠊࣂࣝࢡ⤯⦕ᛶࡀప࠸ࡇ࡜ࡀၥ㢟࡛࠶ࡗࡓࠋࡑࡢࡓࡵࡼࡾ㧗࠸ࣂࣝࢡ⤯⦕ᛶ
ࢆᣢࡘࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࡢ᥈⣴ࡀ⥆ࡅࡽࢀ࡚࠸ࡿࠋࡑࡢ୰࡛ᡃࠎࡣࠊ2010 ᖺ࡟ึࡵ࡚ࡢࣂࣝࢡ⤯⦕ᛶ
ࢆ♧ࡍࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య≀㉁ Bi2Te2Se ࢆⓎぢࡋࠊ2011 ᖺ࡟ࡣࡑࡢᨵⰋ∧ Bi2-xSbxTe3-ySey ࢆ㛤Ⓨࡍࡿ࡞
࡝ࠊࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࡢᇶ♏◊✲࡟࠾࠸࡚㔜せ࡞ᡂᯝࢆᣲࡆ࡚࠸ࡿࠋ
࣭ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య࡟࠾ࡅࡿࣇ࢙࣑ࣝ‽఩ࡢ㟁⏺ไᚚ
ୖグࡢ≀ᛶゎ᫂◊✲࡜୪⾜ࡋ࡚ࠊࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య࡟ࡼࡿࢫࣆࣥࢺࣟࢽࢡࢫ⣲Ꮚ㛤Ⓨࡢࡓࡵࡢᇶ♏
◊✲ࡶ⾜ࡗ࡚࠾ࡾࠊ⌧ᅾࠊࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య⾲㠃࡟࠾ࡅࡿࢫࣆࣥὶࡢ┤᥋᳨ฟࢆ┠ᣦࡋ࡚࠸ࡿࠋ
ࡑࡢࡓࡵࡢせ⣲ᢏ⾡࡜ࡋ࡚ࠊSiO2 ⤯⦕ᒙࢆᙧᡂࡋࡓࢩࣜࢥࣥᇶᯈୖ࡟ࠊࢢࣛࣇ࢙ࣥ࡜ྠᵝࡢࢫࢥࢵࢳ
ࢸ࣮ࣉࢆ⏝࠸ࡓ๼㛤ἲ࡟ࡼࡗ࡚ Bi2-xSbxTe3-ySey ࡢᚤᑠ༢⤖ᬗⷧ∦ࢆᐃ╔ࡉࡏࠊࡑࡢୖ࡟㟁Ꮚࣅ࣮࣒ࣜࢯ
ࢢࣛࣇ࢕࣮࡟ࡼࡗ࡚㟁ᴟࢆᙧᡂࡋࡓ㸦ᅗ 1㸧ࠋࡇࡢࢹࣂ࢖ࢫ࡛ࡣࠊࣂࢵࢡࢤ࣮ࢺ࠿ࡽ༳ຍࡍࡿ㟁⏺࡟ࡼࡗ
࡚ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య୰ࡢࣇ࢙࣑ࣝ‽఩ࢆไᚚࡋࠊ࢟ࣕࣜ࢔ࡢᴟᛶࢆ n ᆺ࠿ࡽ p ᆺࡲ࡛ኚ໬ࡉࡏࡿࡇ࡜
ࡀ࡛ࡁࡿࠋࡇࡢࡼ࠺࡞ࢹࣂ࢖ࢫࢆ ᐃ࣭ホ౯ࡋࠊࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࢫࣆࣥࢺࣟࢽࢡࢫ⣲Ꮚࢆస〇ࡍࡿ
ࡓࡵ࡟ᚲせ࡟࡞ࡿせ⣲ᢏ⾡ࢆ㛤Ⓨࡋࡓࠋ
ᅗ 1 ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యୖ࡟ᚤ⣽㟁ᴟࢆᙧᡂࡋࡓࣂࢵࢡࢤ࣮ࢺᆺ㟁⏺ຠᯝࢹࣂ࢖ࢫࠋࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య Bi2-xSbxTe3-ySey ༢⤖ᬗ࠿ࡽ๤
㞳ࡋ SiO2 ⤯⦕ᒙࢆᣢࡘ Si ᇶᯈ࡟ᐃ╔ࡉࢀࡓⷧ∦ୖ࡟ࠊ㟁Ꮚࣅ࣮࣒ࣜࢯࢢࣛࣇ࢕࣮࡟ࡼࡗ࡚ Pd ࡢᚤ⣽㟁ᴟࡀᙧᡂࡉࢀ࡚࠸ࡿࠋ
― 106 ―
ࢼࣀ▱⬟ࢩࢫࢸ࣒◊✲ศ㔝
ᩍᤵ㸦ව௵㸧
㮖ᑿ 㝯
a) ᴫせ
ᐇ㦂࡜ィ ᢏ⾡ࡢ㐍Ṍ࡟కࡗ࡚ࠊࢼࣀࢸࢡࣀࣟࢪ࣮◊✲ศ㔝࡟࠾࠸࡚኱㔞ࡢᐇ㦂ࢹ࣮ࢱࡀ⵳✚ࡉࢀࡘ
ࡘ࠶ࡿࠋࡋ࠿ࡋ࡞ࡀࡽࠊ◊✲⪅ࢆྵࡴே㛫ࡢ᝟ሗฎ⌮⬟ຊࡢ㝈⏺࡟ࡼࡾࠊࡑࡢࡼ࠺࡞኱㔞ࢹ࣮ࢱ࠿ࡽ⛉
ᏛⓗࠊᕤᏛⓗ࡟ព⩏῝࠸▱㆑ࢆᡭື࡛ຠ⋡ⓗ࡟ᢳฟࡍࡿࡇ࡜ࡣ㞴ࡋ࠸ࠋࡇࡢၥ㢟ࢆゎỴ࡞࠸ࡋ㍍ῶࡍࡿ
ࡓࡵ࡟ࠊᮏ◊✲㒊㛛࡛ࡣᵝࠎ࡞᥎ㄽࡸ᥈⣴࢔ࣝࢦࣜࢬ࣒ࢆ㥑౑ࡋ࡚኱㔞ࢹ࣮ࢱ࠿ࡽே㛫࡟࡜ࡗ࡚ព࿡ࡢ
኱ࡁ࡞▱㆑ࢆᢳฟ࡞࠸ࡋ᥎ᐃࡍࡿᡭἲࡢ㛤Ⓨࢆ⾜ࡗ࡚࠸ࡿࠋᮏᖺᗘࡣ᫖ᖺᗘ࡟ᘬࡁ⥆ࡁࠊ㔞Ꮚ᝟ሗࣇ࢛
ࢺࢽࢡࢫ◊✲ศ㔝㜰኱⏘◊࣭໭኱㟁Ꮚ◊࢔ࣛ࢖࢔ࣥࢫࣛ࣎ࡢ◊✲ࢳ࣮࣒࡜ࠊ㔞Ꮚ᝟ሗฎ⌮ᐇ㦂࡟࠾ࡅ
ࡿᐇ㦂᮲௳ࡢ␗ᖖኚື᳨▱ᡭἲࡢ㛤Ⓨ࡟ྲྀࡾ⤌ࢇࡔࠋ㛗᫬㛫࡟ரࡿ㔞Ꮚ᝟ሗฎ⌮ᐇ㦂࡟࠾࠸࡚ࡣࠊ✀ࠎ
ࡢእ஘ࡸ⿦⨨タᐃࡢຎ໬࡞࡝࡟ࡼࡗ࡚ᐇ㦂᮲௳ࡀ୙ព࡟ኚືࡋࠊࡑࢀࡀᐇ㦂⤖ᯝࡢಙ㢗ᛶࢆపୗࡉࡏࡿ
ྍ⬟ᛶࡀ࠶ࡿࠋࡑࡇ࡛ࠊᮏ◊✲࡛ࡣ≧ែᐦᗘ⾜ิࢆᐃᖖ㸦㠀ືⓗ㸧ᡂศ࡜␗ᖖኚືࢆ⾲ࡍ㠀ᐃᖖ㸦ືⓗ㸧
ᡂศ࡟ศゎࡋ⢭ᗘࡢ㧗࠸᥎ᐃ⤖ᯝࢆᚓࡿ᪂ࡓ࡞ᩘᏛⓗつ⠊ࢆ⪃᱌ࡋࠊࡑࢀࢆゎᯒᡭἲ࡜ࡋ࡚ලయ໬ࡍࡿ
◊✲ࢆ㐍ࡵࡓࠋᮏᖺᗘࡣࠊ≉࡟ࡶࡘࢀ㔞Ꮚࡢ఩┦ኚ໬ࢆక࠺␗ᖖኚືࢆ㧗ឤᗘ࡟᳨▱ࡍࡿᡭἲࡢ㛤Ⓨ࡟
ྲྀࡾ⤌ࢇࡔࠋ
b) ᡂᯝ
㔞Ꮚ≧ែࡢ␗ᖖኚ໬᳨▱ࢆᐇ⌧ࡍࡿࡓࡵ࡟ࠊ๓ᖺᗘ࡟ࡣ㔞Ꮚࡢほ ≧ែᐦᗘ⾜ิ Û k ࢆṇᖖᡂศ T ࡜␗
ᖖኚ໬ᡂศ Z k ࡟ศ㞳᥎ᐃࡍࡿᇶ‽࡜ࡋ࡚ࠊ௨ୗࡢホ౯ᘧࢆ⏝࠸ࡓࠋ
1
¦ Uˆ k T Z k
1,..., K ) k 1 2
min
T ,Zk ( k
K
2
F
K
J¦
k 1
d
2
ij
¦s Z
2
k ,ij
i, j 1
ࡋ࠿ࡋ࡞ࡀࡽࠊࡇࡢᘧ࡛ࡣ≧ែᐦᗘ⾜ิࡢྛせ⣲ࡢ⤯ᑐ್ᡂศࡢኚ໬ࡋ࠿ホ౯ᑐ㇟࡜ࡋ࡚࠾ࡽࡎࠊྛせ
⣲ࡢ」⣲ᩘᡂศ࡟ࡣ཯ᫎࡉࢀࡿࡀ⤯ᑐ್ᡂศ࡟ࡣ཯ᫎࡉࢀ࡞࠸఩┦ኚ໬ࢆឤ▱ࡍࡿࡇ࡜ࡣ࡛ࡁ࡞࠸ࠋࡑ
ࡇ࡛ࠊ௒ᖺᗘࡣࡇࡢホ౯ᘧ࡟」⣲ᡂศࢆ཯ᫎࡍࡿࡼ࠺࡟ᣑᙇࢆ⾜࠺᳨ウࢆ㐍ࡵࡓࠋ⌧ᅾࠊࡑࡢ⤖ᯝ࡟ᇶ
࡙ࡃᩘ್ᐇ㦂ࠊᐇ ᐃᐇ㦂ࢆᐇ᪋୰࡛࠶ࡿࠋ
― 107 ―
ࢼࣀ་⒪ᛂ⏝ࢹࣂ࢖ࢫศ㔝
ᩍᤵ㸦ව௵㸧
୰㇂ ࿴ᙪ
a) ᴫせ
ᙜศ㔝࡛ࡣࠊ㎿㏿ࠊ⡆౽ࠊᏳ౯࡞㑇ఏᏊデ᩿ἲࡢ㛤Ⓨࢆ┠ᣦࡋ࡚ࠊ᳨ฟ࡟ᚲせ࡞ᇶᮏᢏ⾡ᴫᛕࡢᥦ᱌
࡜᳨ドࢆ⾜࠺࡜࡜ࡶ࡟ࠊࢼࣀᚤ⣽ຍᕤ࡜⤌ࡳྜࢃࡏࡓࢹࣂ࢖ࢫࡸࠊ་⒪デ᩿ᶵჾࡢ㛤Ⓨ࡬ࡶᒎ㛤ࡍࡿࠋ
b) ᡂᯝ
࣭ࢩࢺࢩࣥࣂࣝࢪ࡬࢔ࣆࣥࣉࣛ࢖࣐࣮ࢆ⏝࠸ࡓ⡆౽࡞㑇ఏᏊኚ␗᳨ฟἲ
㑇ఏᏊࡢࢃࡎ࠿࡞㐪࠸ࢆ㎿㏿࡟᳨ฟࡍࡿ
ᡭἲࡀࠊࢸ࣮࣓࣮ࣛࢻ་⒪ࢆᨭ࠼ࡿ᰿ᖿᢏ
⾡࡜ࡋ࡚ᮇᚅࡉࢀ࡚࠸ࡿࠋᙜ◊✲ศ㔝࡛ࡣࠊ
࣑ࢫ࣐ࢵࢳࡸࣂࣝࢪᵓ㐀ࢆࡶࡘ DNA ࡟≉
␗ⓗ࡟⤖ྜࡍࡿᑠศᏊࢆ⏝࠸ࡓ㑇ఏᏊኚ␗
᳨ᰝᢏ⾡ࢆᥦ᱌ࡋ࡚ࡁࡓࠋᡃࠎࡢ᪉ἲࡢ≉
ᚩࡣࠊᶆⓗ DNA ࡀᑡ㔞࡛ࡶ PCR ࢆ౑࠺ࡇ
࡜᳨࡛ฟࡀྍ⬟࡛࠶ࡿࡇ࡜ࠊ඲࡚ࢆΰྜࡋ
࡚ PCR ࡀ࠿ࡅࡽࢀࡿ࡜࠸࠺ࡁࢃࡵ࡚⡆౽
࡞ᡭἲ࡛㑇ఏᏊኚ␗ࡀุᐃ࡛ࡁࡿⅬ࡟࠶ࡿࠋ
ࢸࣥࣉ࣮ࣞࢺࢆ⏝࠸࡚ PCR ࢆ⾜࡞ࡗࡓ⤖
ᯝࠊ3’ᮎ➃ࡢ୍ሷᇶࡢ㐪࠸࡛⺯ගࡢኚ໬࡟
኱ࡁ࡞ᕪࡀほ ࡉࢀࠊ୍ሷᇶࡢ㐪࠸ࢆㄆ㆑
ࡍࡿࡇ࡜࡟ᡂຌࡋࡓࠋࡉࡽ࡟ࡇࡢᡭἲࢆ⏝
࠸࡚ࠊ⌧ᅾ࢘࢖ࣝࢫࡢ㧗ឤᗘ᳨ฟࢆ௻ᴗࠊ
ࢩ࣏࣮ࣥ࢞ࣝ኱Ꮫ࡜ඹྠ࡛⾜ࡗ࡚࠸ࡿࠋ
RNA ࢘࢖ࣝࢫ࡟≉␗ⓗ࡞ࣉࣛ࢖࣐࣮࡟࣊
࢔ࣆࣥࢆࢱࢢ࡜ࡋ࡚௜୚ࡋࠊ㏫㌿෗̾PCR(RT-PCR)ࢆ⾜࠺࡜ࠊ୍ᮏࡢࢳ࣮ࣗࣈෆ࡛ PCR ࡀ㐍⾜ࡋࠊ࢘࢖
ࣝࢫࡢ᳨ฟࡀྍ⬟࡛࠶ࡿࡇ࡜ࡀ♧၀ࡉࢀࡓࠋࡲࡓࠊDNA ࢘࢖ࣝࢫ࡛ࡶྠᵝ࡟࢘࢖ࣝࢫࡢ᳨ฟࡀྍ⬟࡛
࠶ࡾࠊ࢘࢖ࣝࢫࡢ⡆౽࡞᳨ฟἲ࡜ࡋ࡚ࡢᛂ⏝ᒎ㛤ࡀᮇᚅࡉࢀࡿࠋ
ᑦࠊᮏ◊✲ࡣ⢭ᐦไᚚ໬Ꮫ◊✲ศ㔝ࡢṊ஭ྐᜨຓᩍ࡜ࡢඹྠ◊✲࡛࠶ࡿࠋ
― 108 ―
ࢼࣀࢩࢫࢸ࣒タィศ㔝
ᐈဨᩍᤵ
ቑ⏣ ⱱ 㸦ᖹᡂ 26 ᖺ 5 ᭶ 1 ᪥㹼ᖹᡂ 27 ᖺ 3 ᭶ 31 ᪥㸧
a) ᴫせ
᭷ᶵⷧ⭷ኴ㝧㟁ụ࡞࡝᭷ᶵ༙ᑟయࢆ฼⏝ࡋࡓࢹࣂ࢖ࢫ㛤ᣅࡀ┒ࢇ࡟⾜ࢃࢀ࡚࠸ࡿࠋࡇࢀࡽࡢࢹࣂ࢖ࢫ
࡛ࡣ㸪᭷ᶵ༙ᑟయ⮬㌟ࡢ≉ᛶ㸦⤖ᬗᛶࡸ࢟ࣕࣜ࢔⛣ືᗘ࡞࡝㸧ࡢࡳ࡞ࡽࡎࠊ㟁ᴟ㔠ᒓ/᭷ᶵ⏺㠃ࡸ⤯⦕య
/᭷ᶵ⏺㠃࡛ࡢ≉ᛶ㸦࢟ࣕࣜ࢔ὀධࡸ࢟ࣕࣜ࢔㍺㏦㸧ࡀỴᐃⓗ࡞ᙺ๭ࢆᯝࡓࡍࠋᮏ◊✲࡛ࡣࠊࢩࣜࢥࣥᇶ
ᯈୖ࡟㔠ᒓ/᭷ᶵ༙ᑟయ/㔠ᒓᵓ㐀ࢆᙧᡂࡋࠊ㔠ᒓ㟁ᴟ㛫࡟㟁ᅽ༳ຍࡋࡓ≧ែ࡛㟁Ꮚ≧ែィ ࢆ⾜࠺ࠋィ
࡟ࡣࠊ࣌ࢽࣥࢢ࢖࢜ࣥ໬㟁Ꮚศග(PIES)ࠊ⣸እග㟁Ꮚศග(UPS)ࠊග㟁Ꮚ㢧ᚤ㙾(PEEM)࡞࡝ࢆ⏝࠸ࡿࠋ
㟁ᅽ༳ຍ࡟ࡼࡗ࡚᭷ᶵ༙ᑟయࡢࣇ࢙࣑ࣝ‽఩ࡀࢩࣇࢺࡋࠊ㟁Ꮚࡢ༨᭷≧ែࡶኚ໬ࡍࡿ࡜⪃࠼ࡽࢀࡿࠋࣂ
ࣥࢻ࣋ࣥࢹ࢕ࣥࢢࡢ࢚ࢿࣝࢠ࣮࡟㛵ࡍࡿ᝟ሗࡣධᑕࣅ࣮࣒ࢆ⤠ࡗࡓ PIES ࡜ UPS ࡛ࠊ✵㛫ศᕸ࡟㛵ࡍࡿ
᝟ሗࡣ PEEM ࡟ࡼࡾᚓࡿࠋࡇࡢࡼ࠺࡞┦⿵ⓗ࡞ᐇ㦂ࡣᅜ㝿ⓗ࡟ࡶึࡵ࡚ࡢヨࡳ࡛࠶ࡿࠋኴ㝧㟁ụ࡞࡝࡛
ඃࢀࡓᴗ⦼ࢆᣲࡆ࡚ࡁࡓ⏘◊ࡢᑠᯘࢢ࣮ࣝࣉ࡜ඹྠ◊✲ࢆ⾜࠸ࠊ㟁ሙୗ࡟࠾ࡅࡿ᭷ᶵ/㔠ᒓ⏺㠃ࡢ㟁Ꮚ≀
ᛶࡢᇶ♏ࢆ☜❧ࡍࡿࡇ࡜ࢆ┠ᣦࡍࠋ
b) ᡂᯝ
᭷ᶵศᏊ࡟ࡣࠊࢪ࣋ࣥࢰ࣌ࣥࢱࢭࣥ㸦DBP㸧ࢆ⏝࠸ࡓࠋࡲࡎࡣࠊDBP ࢆ Au(111)༢⤖ᬗ࡞࡝ࡢ㔠ᒓ⾲
㠃࡟〇⭷ࡋࠊPIES ཬࡧ UPS ࢆ⏝࠸࡚㟁Ꮚ≧ែࢆィ ࡋࡓࠋDBP ⷧ⭷࡛ࡣࠊ8bg(HOMO)ࠊ7bg+7auࠊ6auࠊ
6bg ࡢ ʌ ㌶㐨ࡸ ı ㌶㐨࡟ᖐᒓࡉࢀࡿࣆ࣮ࢡࡀ UPS ཬࡧ PIES ࢫ࣌ࢡࢺ࡛ࣝほᐹࡉࢀࡓࠋࡑࡇ࡛ࠊࢩࣜࢥ
ࣥᇶᯈୖ࡟㔠ᒓ/᭷ᶵ༙ᑟయ/㔠ᒓᵓ㐀ࢆᑠᯘ◊✲ᐊ࡛సᡂࡋࠊ㔠ᒓ㟁ᴟ㛫࡟㟁ᅽ༳ຍࡋࡓ≧ែ࡛ࡢ㟁Ꮚ
≧ែィ ࡛ࡁࡿࢧࣥࣉࣝᵓ㐀ࡢ᭱㐺໬ࢆ㐍ࡵ࡚࠸ࡿࠋࡲࡓࠊࡇࢀ࡜୪⾜ࡋ࡚ࠊධᑕࣅ࣮࣒ࢆ⤠ࡗࡓ PIES
࡜ UPS ᐃࡸ PEEM ᐃࢆ⾜ࡗࡓࠋ
― 109 ―
ࢼࣀࢩࢫࢸ࣒タィศ㔝
ᐈဨ෸ᩍᤵ
୰ᕝཎ ಟ 㸦ᖹᡂ 26 ᖺ 6 ᭶ 16 ᪥㹼ᖹᡂ 27 ᖺ 3 ᭶ 31 ᪥㸧
a) ᴫせ
㓟໬≀୕ḟඖࢼࣀ࣊ࢸࣟᵓ㐀ᙧᡂ࡜ᛂ⏝࡟㛵ࡍࡿ◊✲
b) ᡂᯝ
㓟໬≀ᮦᩱࢆ⏝࠸࡚ࢼࣀ㡿ᇦ࡬ࡢ࢚ࣆࢱ࢟ࢩࣕࣝⷧ⭷⤖ᬗᡂ㛗ࢆ฼⏝ࡋࡓ୕ḟඖࢼࣀ࣊ࢸࣟᵓ㐀ⷧ⭷
ࢆస〇ࡋࠊ୕ḟඖࢼࣀ࣊ࢸࣟ⏺㠃ࡢ๰〇࡜᪂つ≀ᛶⓎ⌧ࠊࡉࡽ࡟ࡑࡢ≉ᛶࢆᛂ⏝ࡋࡓࢹࣂ࢖ࢫࢆ๰〇
ࡍࡿࠋලయⓗ࡟ࡣࠊ⮬ᕫ⤌⧊໬ࢼࣀ┦ศ㞳⌧㇟࡜ࣃࣝࢫ࣮ࣞࢨ࣮࢚ࣆࢱ࢟ࢩࣕࣝⷧ⭷⵨╔ἲࢆ⼥ྜࡍ
ࡿࡇ࡜࡟ࡼࡾࠊᴟᚤ⣽࠿ࡘ㉸㧗㞟✚ࡢ㏱᫂㓟໬≀ࢼࣀࣆ࣮ࣛᵓ㐀ࢆస〇ࡍࡿᢏ⾡ࢆ☜❧ࡋࡓࠋ ― 110 ―
ࢼࣀࢹࣂ࢖ࢫホ౯࣭デ᩿ศ㔝
ᐈဨᩍᤵ ఱ 㭉 㸦ᖹᡂ 26 ᖺ 4 ᭶ 1 ᪥㹼ᖹᡂ 26 ᖺ 6 ᭶ 30 ᪥㸧
a) ᴫせ
㏆ᖺࠊࣇࣞ࢟ࢩࣈࣝࡸ࢙࢘࢔ࣛࣈࣝࢹࣂ࢖ࢫ࡟ᑐᛂࡋࡓ㏱᫂ᑟ㟁⭷ࡀᙉࡃồࡵࡽࢀ࡚࠾ࡾࠊ࣮࢝࣎ࣥ
ࢼࣀࢳ࣮ࣗࣈࠊࢢࣛࣇ࢙ࣥࠊ㔠ᒓ࣓ࢵࢩࣗࠊ㔠ᒓࢼࣀ࣡࢖ࣖ࡞࡝ᵝࠎ࡞㏱᫂ᑟ㟁⭷ᮦᩱࡀ᳨ウࡉࢀ࡚࠸
ࡿࠋ୰࡛ࡶ㖟ࢼࣀ࣡࢖ࣖ㏱᫂ᑟ㟁⭷ࡣ ITO ࢆୖᅇࡿᑟ㟁ᛶࠊ㏱᫂ᛶࡀሗ࿌ࡉࢀ࡚࠾ࡾࠊࡋ࠿ࡶప౯࡛⡆
༢࡞༳ๅࣉࣟࢭࢫ࡛స〇ࡉࢀ࡚࠸ࡿࠋࡋ࠿ࡋࠊⰋዲ࡞≉ᛶࢆᚓࡿ࡟ࡣ 200Υ௨ୖࡢຍ⇕ࡸග↷ᑕࡸຍᅽ
࡞࡝ࡢᚋฎ⌮ࡀᚲせ࡛࠶ࡿࠋ200Υ࡜࠸࠺ ᗘࡣከࡃࡢࣇࣞ࢟ࢩࣈࣝࢹࣂ࢖ࢫࡢᵓᡂᮦᩱ࡟࡜ࡗ࡚㧗ࡍ
ࡂࡿ ᗘ࡛࠶ࡾࠊຍᅽฎ⌮࡟ࡼࡾࢹࣂ࢖ࢫᛶ⬟࡟ࢲ࣓࣮ࢪࢆ୚࠼ࡿࠋࡋࡓࡀࡗ࡚ࠊప ࠾ࡼࡧᚋฎ⌮࡞
ࡋࡢࣉࣟࢭࢫࡀᮇᚅࡉࢀ࡚࠸ࡿࠋᮏ◊✲࡛ࡣࠊ㖟ࢼࣀ࣡࢖ࣖࡢྜᡂࣉࣟࢭࢫ࡟ὀ┠ࡋࠊ⡆༢࡞Ὑί᪉ἲ
ࢆ⏝࠸࡚ࠊ㧗ᑟ㟁ᛶ࡜㏱᫂ᛶࢆ᭷ࡍࡿ㖟ࢼࣀ࣡࢖ࣖ⭷ࢆᐊ ࡛స〇ࡍࡿᢏ⾡ࢆ☜❧ࡋࡓࠋ
b)ᡂᯝ
ᚑ᮶ࠊ㖟ࢼࣀ࣡࢖ࣖࡢྜᡂ࡟ࡣࠊ࣏࣮ࣜ࢜ࣝἲࢆ⏝࠸࡚࢚ࢳࣞࣥࢢࣜࢥ࣮ࣝࢆ⁐፹࡜㑏ඖ๣࡜ࡋ࡚ࠊ
࣏ࣜࣅࢽࣝࣆࣟࣜࢻࣥ(PVP)ࢆ⾲㠃ಖㆤ๣࡜ࡋ࡚ࠊ◪㓟㖟ࢆ㑏ඖ๣࡜ࡋ࡚㖟ࢼࣀ࣡࢖ࣖࢆྜᡂࡋ࡚࠸ࡓࠋ
ࡇࡢ᪉ἲࡣࠊ⡆༢࡛㧗཰⋡ࡢ㖟ࢼࣀ࣡࢖ࣖࡀᚓࡿࡇ࡜ࡀฟ᮶ࡿࡀࠊ⾲㠃ಖㆤ๣ࡢ PVP ࡀ㖟ࢼࣀ࣡࢖ࣖ⾲
㠃ࢆそ࠺ࡇ࡜࡟ࡼࡾࠊࢼࣀ࣡࢖ࣖ㛫ࡢ᥋ゐ᢬ᢠ࡟኱ࡁࡃᙳ㡪ࢆ୚࠼࡚࠸ࡿࠋࡲࡓࠊ㧗 ฎ⌮ࡸග↷ᑕࡢ
ᚋฎ⌮᪉ἲ࡟ࡼࡾ PVP ᒙࡢᰂ㌾ᛶࡢྥୖࠊ⇕ศゎࡍࡿ᪉ἲࡣ⾜ࢃࢀ࡚ࡁࡓࡀࠊPVP ᒙࢆὙίࡋ࡚ྲྀࡾ
㝖ࡃ◊✲ࡣ࡯࡜ࢇ࡝ሗ࿌ࡉࢀ࡚࠸࡞࠸ࠋᮏ◊✲࡛ࡣྜᡂࡋࡓ㖟ࢼࣀ࣡࢖ࣖ࡟ࡘ࠸࡚ࠊὙίᅇᩘࠊὙί࡟
౑࠺⁐፹ࠊὙί ᗘࢆࣃ࣓࣮ࣛࢱ࣮࡜ࡋ࡚ࠊ㖟ࢼࣀ࣡࢖ࣖ⾲㠃࡟ṧࡗࡓ PVP ᒙࢆศᯒࡋࠊ㖟ࢼࣀ࣡࢖ࣖ
⭷ࡢ᢬ᢠኚ໬ࢆ᳨ウࡋࡓࠋྜᡂࡋࡓ㖟ࢼࣀ࣡࢖ࣖࢆ࢚ࢱࣀ࣮࡛ࣝὙίࡋࠊὙίᅇᩘࢆቑࡍࡈ࡜࡟ࠊPVP
ᒙࡢཌࡉࡀపୗࡋࠊ㖟ࢼࣀ࣡࢖ࣖ⭷ࡢᑟ㟁ᛶࡀୖࡀࡗࡓࠋࡲࡓࠊὙί ᗘࢆୖࡆࡿ࡟ࡘࢀࠊPVP ᒙࢆ᪩
ࡃ㝖ཤ࡛ࡁࡿࡇ࡜ࡀศ࠿ࡗࡓࠋ୍᪉ࠊὙί⁐፹࡜ࡋ࡚ࠊN,N-ࢪ࣓ࢳ࣒ࣝ࣍ࣝ࢔࣑ࢻὙί⁐፹ࢆ౑⏝ࡍࡿ
ࡇ࡜࡟ࡼࡾࠊ㧗㏱᫂ᛶ࠿ࡘ㧗ᑟ㟁ᛶࢆ᭷ࡍࡿ㖟ࢼࣀ࣡࢖ࣖ⭷ࢆᚓࡿࡇ࡜ࡀ࡛ࡁࡓࠋࡇࢀࡽࡢ୍㐃ࡢ⤖ᯝ
࠿ࡽࠊὙίࣉࣟࢭࢫࢆ᭱㐺໬ࡍࡿࡇ࡜࡟ࡼࡾᐊ ⎔ቃ࡛㧗ᛶ⬟㖟ࢼࣀ࣡࢖ࣖ⭷ࢆᚓࡿࡇ࡜ࢆド᫂ࡋࡓࠋ
௒ᚋࠊᐊ స〇ࡋࡓ㖟ࢼࣀ࣡࢖ࣖ㏱᫂ᑟ㟁⭷ࢆᵝࠎ࡞ࢹࣂ࢖ࢫ࡟ᛂ⏝ࡋ࡚㧗ᛶ⬟ࢹࣂ࢖ࢫࢆ┠ᣦࡍணᐃ
࡛࠶ࡿࠋ
ࡲࡓࠊఱᩍᤵࡣࠊ◊✲ᐊࡢᏛ⏕ࡸ⫋ဨ࡟ྥࡅࠊࣁࣝࣅࣥ኱Ꮫࡢ◊✲άືࡸᏛ⏕⏕άࡸ኱Ꮫ␃Ꮫᨻ⟇࡞
࡝ࢆ⤂௓ࡋࠊࣁࣝࣅࣥ኱Ꮫࡢᐇ⿦ᢏ⾡Ⓨᒎཬࡧ◊✲㐍ࡵ᪉ྥࢆヲ⣽࡟ㅮ⩏ゎㄝࡋࡓࠋ௒ᚋ୧኱Ꮫࡢඹྠ
◊✲࡟኱࠸࡟㈨ࡍࡿࡶࡢ࡜ゝ࠼ࡿࠋ
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ࢼࣀࢹࣂ࢖ࢫホ౯࣭デ᩿ศ㔝
Peerapon Vateekul㸦ᖹᡂ 26 ᖺ 7 ᭶ 1 ᪥ ࠥ 8 ᭶ 18 ᪥㸧
a) ᴫせ
㏆ᖺࠊィ⟬ᶵ࡟ࡼࡿឤ᝟᥎ᐃࡣ≉࡟㡢ᴦ᥎⸀࡟࠾࠸࡚኱ࡁ࡞ὀ┠ࢆ㞟ࡵ࡚࠸ࡿࠋᮏ◊✲࡛ࡣࠊ㡢ᴦ่
⃭࡟ᑐࡋ࡚ࠊ⬻Ἴ㸦Electroencephalograph : EEG㸧࠿ࡽឤ᝟ࢆ᥎ᐃࡍࡿࡇ࡜ࢆ┠ⓗ࡜ࡍࡿࠋࡑࡇ࡛ࠊ࢔࢖
ࢸ࣒࣮࣋ࢫࡢᏛ⩦࢔ࣉ࣮ࣟࢳ࡟ࡼࡿศ㢮࢔ࣝࢦࣜࢬ࣒ࢆ᪂ࡓ࡟ᥦ᱌ࡋࠊឤ᝟᥎ᐃ⢭ᗘࡢྥୖࢆ☜ㄆࡋࡓࠋ
b) ᡂᯝ
࣭㡢ᴦ่⃭࡟ᑐࡍࡿ EEG ࡟ᇶ࡙ࡃឤ᝟᥎ᐃ
ឤ᝟᥎ᐃ࡜ࡣࠊ႐ᛣယᴦ࡞࡝ேࡢឤ᝟ࢆィ⟬ᶵ࡟ࡼࡿ᥎ᐃࡍࡿࡇ࡜࡛࠶ࡿࠋ㏆ᖺࠊឤ᝟࡜⬻άື㸦EEG㸧
࡜ࡢ㛫࡟ᙉ࠸㛵ಀᛶࡀ࠶ࡿࡇ࡜ࡀ☜ㄆࡉࢀ࡚࠾ࡾࠊᮏ◊✲࡛ࡣ஧✀㢮ࡢࢹ࣮ࢱࢭࢵࢺࢆ⏝࠸࡚ࡇࡢ㛵ಀ
ᛶࢆ᫂ࡽ࠿࡟ࡋࡓࠋࡦ࡜ࡘ┠ࡣࠊᶆ‽ⓗ࡞࣋ࣥࢳ࣐࣮ࢡࢹ࣮ࢱࢭࢵࢺ DEAP ࡛࠶ࡾࠊࡩࡓࡘ┠ࡣ▱⬟࢔
࣮࢟ࢸࢡࢳࣕ◊✲ศ㔝㸦἟ᑿ◊㸧࡟࡚཰㞟ࡋࡓࢹ࣮ࢱࢭࢵࢺ࡛࠶ࡿࠋ▱⬟࢔࣮࢟ࢸࢡࢳࣕ◊✲ศ㔝࡟࠾
ࡅࡿ⿕㦂⪅ᐇ㦂࡛ࡣࠊWaveguard™ EEG ィࠊPolymate AP1532 ࢔ࣥࣉࠊ࠾ࡼࡧ APMonitor ⬻Ἴグ㘓ࢯࣇ
ࢺ࢙࢘࢔ࢆ⏝࠸࡚ࠊ15 ྡࡢ⿕㦂⪅࠿ࡽ㡢ᴦ่⃭࡟ᑐࡍࡿ⬻Ἴࢆ཰㞟ࡋࡓࠋᮏ◊✲ࡢ⤖ᯝ࠿ࡽࠊ㡢ᴦ่⃭
࡟ᑐࡋ࡚ࡶឤ᝟࡜⬻Ἴ࡜ࡢ㛫࡟ᙉ࠸㛵ಀᛶࡀ☜ㄆࡉࢀࠊEEG ࠿ࡽேࡢឤ᝟ࡀ࠶ࡿ⛬ᗘ᥎ᐃྍ⬟࡛࠶ࡿࡇ
࡜ࢆ♧ࡋࡓࠋ
࣭࢔࢖ࢸ࣒࣮࣋ࢫࡢᏛ⩦࢔ࣉ࣮ࣟࢳ
EEG ࡟ᇶ࡙ࡃឤ᝟᥎ᐃࡢඛ⾜◊✲ࡣࡲࡔᑡ࡞࠸ࠋᮏ◊✲࡛ࡣࠊឤ᝟᥎ᐃ⢭ᗘྥୖ࡟ྥࡅ࡚ࠊ࢔࢖ࢸ࣒
࣮࣋ࢫࡢ༠ㄪࣇ࢕ࣝࢱࣜࣥࢢ㸦Collaborative Filtering: CF㸧࡟ᇶ࡙ࡃ᪂つศ㢮࢔ࣝࢦࣜࢬ࣒ EEG-CF ࢆᥦ
᱌ࡋࡓࠋᮏᡭἲ࡟ࡣḟࡢ୕ࡘࡢ㈉⊩ࡀ࠶ࡿࠋ(i) EEG ࢹ࣮ࢱ࡟ᑐࡍࡿ CF 㢮ఝᗘࢫࢥ࢔ィ⟬ࠊ(ii) ᮍホ౯
࢔࢖ࢸ࣒㸦ᴦ᭤㸧࡟ᑐฎࡍࡿ࣓࢝ࢽࢬ࣒ࠊ(iii) EEG ࡟ᇶ࡙ࡃ㊥㞳࡟ࡼࡿእࢀ್㝖ཤࠊ࡛࠶ࡿࠋᐇ㦂࡛ࡣࠊ
ホ౯ࡀᐦ࡞ DEAP ࡜␯࡞▱⬟࢔࣮࢟ࢸࢡࢳࣕ◊✲ศ㔝࡛཰㞟ࡋࡓ஧✀㢮ࡢࢹ࣮ࢱࢭࢵࢺ࡟ᑐࡋ࡚ឤ᝟᥎
ᐃࢆ⾜ࡗࡓ⤖ᯝࠊᮏᡭἲࡣᚑ᮶ἲ࡟ẚ࡭࡚ඃࢀࡓ᥎ᐃ⢭ᗘࡀᚓࡽࢀࡓࠋ
ᅗ 1. ᥦ᱌ἲ(EEG-CF, ୍␒ྑࡢᲬࢢࣛࣇ)࡜ᚑ᮶ἲ࡜ࡢẚ㍑㸬
ᕥࡢࢢࣛࣇࡣ valence㸪ྑࡢࢢࣛࣇࡣ arousal
࡟࠾ࡅࡿ᥎ᐃ⤖ᯝ(F1)ࢆ♧ࡋ࡚࠸ࡿ㸬
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ࢼࣀࢹࣂ࢖ࢫホ౯࣭デ᩿ศ㔝
ᐈဨ෸ᩍᤵ
Stanislav JURECKA 㸦ᖹᡂ 26 ᖺ 9 ᭶ 1 ᪥㹼ᖹᡂ 26 ᖺ 10 ᭶ 3 ᪥㸧
a) ᴫせ
ᑠᯘ◊✲ᐊ࡛ࢩࣜࢥࣥ⾲㠃࡟ࢩࣜࢥࣥࢼࣀࢡࣜࢫࢱࣝᒙࢆᙧᡂࡋࠊࢩࣜࢥࣥ⾲㠃ࢆᴟప཯ᑕ⋡໬ࡍࡿ
໬Ꮫⓗ㌿෗ἲࢆ㛤Ⓨࡋࡓࠋࡋ࠿ࡋࠊࢩࣜࢥࣥࢼࣀࢡࣜࢫࢱࣝᒙࡢᵓ㐀࡜཯ᑕ⋡ࡢ㛵ಀࡣ᫂ࡽ࠿࡛࡞࠸ࡢ
࡛ࠊࡑࡢࢩࣜࢥࣥࢼࣀࢡࣜࢫࢱࣝᒙࡢᵓ㐀ࢆࠊ㢧ᚤ㙾ἲ➼ࢆ⏝࠸࡚ゎᯒࡍࡿࡇ࡜ࡀ㔜せ࡛࠶ࡿࠋࡉࡽ࡟ࠊ
ࢩࣜࢥࣥࢼࣀࢡࣜࢫࢱࣝᒙࡢࣃࢵࢩ࣮࣋ࢩࣙࣥἲ࡜ࡋ࡚ࠊ◪㓟㓟໬ἲࠊࢩ࢔ࣥ໬ἲࠊỈ⣲ฎ⌮ἲࠊ⇕㓟
໬ἲཬࡧࡇࢀࡽࡢ⤌ࡳྜࢃࡏࢆ᳨ウࡋࠊࡑࡢ⾲㠃ᵓ㐀࣭⾲㠃≧ែ࡜ᑡᩘ࢟ࣕࣜ࢔࣮ࣛ࢖ࣇࢱ࢖࣒ࡢ㛵ಀ
ࢆぢฟࡍࠋࢩࣜࢥࣥࢼࣀࢡࣜࢫࢱࣝᒙࡢ⾲㠃ᵓ㐀ࢆไᚚࡍࡿࡇ࡜ࡼࡗ࡚ࠊᴟప཯ᑕ⋡ࢆ㐩ᡂࡋ࡚ࢩࣜࢥ
ࣥኴ㝧㟁ụࡢග㟁ὶᐦᗘࢆ᭱኱㝈࡟ቑຍࡉࡏࡿࠋࡲࡓࠊ⾲㠃Ḟ㝗ไᚚ࡟ࡼࡗ࡚ࠊࢩࣜࢥࣥኴ㝧㟁ụࡢග
㉳㟁ຊࢆቑຍࡉࡏࡿࠋ
b) ᡂᯝ
໬Ꮫⓗ㌿෗ἲࢆ⏝࠸࡚ࠊࢩࣜࢥࣥ⾲㠃࡟ࢩࣜࢥࣥࢼࣀࢡࣜࢫࢱࣝᒙࢆᙧᡂࡋ࡚ࠊᴟప཯ᑕ⾲㠃ࢆస〇
ࡋࡓࠋࡲࡓࠊ໬Ꮫⓗ㌿෗ฎ⌮᫬㛫ࢆኚ໬ࡉࡏࠊࡑࡢ⾲㠃≧ែࢆ㉮ᰝᆺ㟁Ꮚ㢧ᚤ㙾ࡸཎᏊ㛫ຊ㢧ᚤ㙾࡟ࡼ
ࡾほᐹࡋࡓࠋࡲࡓࠊࣇࣛࢡࢱࣝゎᯒ࡟ࡼࡾࠊࢩࣜࢥࣥࢼࣀࢡࣜࢫࢱࣝᒙࡢᵓ㐀࡜཯ᑕ⋡ࡢ㛵ಀࢆゎᯒ୰
࡛࠶ࡿࠋࡉࡽ࡟ࠊ◪㓟㓟໬ἲࠊࢩ࢔ࣥ໬ἲࠊỈ⣲ฎ⌮ἲࠊ⇕㓟໬ἲཬࡧࡇࢀࡽࡢ⤌ࡳྜࢃࡏ࡟ࡼࡾࠊࢩ
ࣜࢥࣥࢼࣀࢡࣜࢫࢱࣝᒙࡢࣃࢵࢩ࣮࣋ࢩࣙࣥἲࢆ⏝࠸ࡓࢩࣜࢥࣥᇶᯈࡢᑡᩘ࢟ࣕࣜ࢔࣮ࣛ࢖ࣇࢱ࢖࣒
ࢆ ᐃࡋࠊࡲࡓࠊࡇࡢᇶᯈࢆ⏝࠸࡚ࢩࣜࢥࣥኴ㝧㟁ụࡶస〇ࡋࡓࠋࡇࢀࡽࡢ≉ᛶࡢẚ㍑ࢆ⾜࠸ࠊ᭱㐺࡞
ࣃࢵࢩ࣮࣋ࢩࣙࣥ᮲௳ࢆ᥈⣴ࡋ࡚࠸ࡿࠋ
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ࢼࣀࢹࣂ࢖ࢫホ౯࣭デ᩿ศ㔝
ᐈဨᩍᤵ
Harald Gröger㸦ᖹᡂ 26 ᖺ 10 ᭶ 7 ᪥㹼ᖹᡂ 26 ᖺ 11 ᭶ 27 ᪥㸧
a) ᴫせ
࣊ࣜࢭࣥࡣ」ᩘࡢⰾ㤶⎔ࡀ࢜ࣝࢺ఩࡛⦰⎔ࡋࡓ㠀ᖹ㠃ᛶࡽࡏࢇ≧໬ྜ≀࡛࠶ࡾࠊྑᕳࡁ(P)࡜ᕥᕳࡁ
(M)ࡢ࣊ࣜࢩࢸ࢕࣮࡟㉳ᅉࡍࡿ㙾ീ␗ᛶయࡀᏑᅾࡍࡿࠋගᏛάᛶ࡞࣊ࣜࢭࣥࡣࠊຠᯝⓗ࡞୙ᩧ※࡜ࡋ࡚
୙ᩧ㓄఩Ꮚࡸ᭷ᶵศᏊゐ፹࡞࡝࡬ࡢᛂ⏝ࡸࠊࡑࡢ⊂≉࡞ගᏛⓗࠊ㟁Ꮚⓗᛶ㉁࠿ࡽᶵ⬟ᛶ໬ྜ≀࡬ࡢ฼⏝
ࡀᮇᚅࡉࢀ࡚࠸ࡿࠋࡇࢀࡲ࡛࡟࢟ࣛࣝ࡞㑄⛣㔠ᒓゐ፹ࢆ⏝࠸ࡿ⎔໬௜ຍ཯ᛂ࡟ࡼࡿࠊ࣊ࣜࢭࣥᆺศᏊࡢ
ゐ፹ⓗ୙ᩧྜᡂࡀᩘ౛ሗ࿌ࡉࢀ࡚࠸ࡿࡶࡢࡢࠊࡑࡢྜᡂ࡟ࡣ㧗ᕼ㔘᮲௳ࡀᚲせ࡛࠶ࡾࠊ཯ᛂᇶ㉁ࡢྜᡂ
ࡀከẁ㝵࡛࠶ࡿ➼ࡢၥ㢟ࡀ࠶ࡿࠋⰾ㤶᪘」⣲⎔ࢆྵࡴ࣊ࣜࢭࣥᆺศᏊࡢྜᡂࡣ≉࡟ᅔ㞴࡛࠶ࡾࠊ࣊ࣜࢭ
ࣥ㦵᱁ෆ࡟ࣇࣛࣥ⎔ࢆ᭷ࡍࡿ࢜࢟ࢧ࡬ࣜࢭࣥࡢゐ፹ⓗ୙ᩧྜᡂࡣᮍ㛤ᣅ࡞㡿ᇦ࡜࡞ࡗ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭ࣂࢼࢪ࣒࢘ゐ፹ࢆ⏝࠸ࡿ࢚ࢼࣥࢳ࢜㑅ᢥⓗࢻ࣑ࣀ཯ᛂ࡟ࡼࡿ࢜࢟ࢧ>@࣊ࣜࢭࣥࡢྜᡂ
௒ᅇࠊ༢᰾ࡢ࢟ࣛࣝࣂࢼࢪ࣒࢘ゐ፹(Ra,S)-3 ࢆከ⎔ᘧࣇ࢙ࣀ࣮࡛ࣝ࠶ࡿ 2-ࣄࢻࣟ࢟ࢩ࣋ࣥࢰ[c]ࣇ࢙ࢼ
ࣥࢺࣞࣥㄏᑟయ 1 ࡟⏝࠸ࡿ࡜ࠊࣂࢼࢪ࣒࢘㘒యࡢࣞࢻࢵࢡࢫ/㓟ゐ፹స⏝࡟ࡼࡾ㓟໬ⓗ࢝ࢵࣉࣜࣥࢢ࡜ศ
Ꮚෆ⬺Ỉ⎔໬ࡢ㐃⥆཯ᛂࡀ㐍⾜ࡋ࡚ࠊ࢜࢟ࢧ[9]࣊ࣜࢭࣥ㢮 2 ࡀ㧗཰⋡࠿ࡘ㧗࢚ࢼࣥࢳ࢜㑅ᢥⓗ࡟ྜᡂ࡛
ࡁࡿ࡜ࡇ࡜ࢆぢฟࡋࡓࠋᮏゐ፹཯ᛂ࡛ᚓࡽࢀࡿගᏛάᛶ࣊ࣜࢭࣥ(2a: R = H)ࡣ୍ᗘࡢ෌⤖ᬗ᧯స࡟ࡼࡾ
ගᏛⓗ࡟⣧⢋࡞࣊ࣜࢭࣥ 2a ࡬࡜ᑟࡃࡇ࡜ࡀ࡛ࡁࡓࠋ2a ࡢ X ⥺༢⤖ᬗᵓ㐀ゎᯒ࡟ࡼࡾࠊᮏ཯ᛂࡣᕥᕳࡁ
(M)ࡢ࣊ࣜࢭࣥࢆ㑅ᢥⓗ࡟୚࠼ࡿࡇ࡜ࡀุ᫂ࡋࡓࠋ
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ࢼࣀࢹࣂ࢖ࢫホ౯࣭デ᩿ศ㔝
ᐈဨᩍᤵ
Emil PINCIK 㸦ᖹᡂ 26 ᖺ 12 ᭶ 1 ᪥㹼ᖹᡂ 27 ᖺ 1 ᭶ 30 ᪥㸧
a) ᴫせ
ᑠᯘ◊✲ᐊ࡛ࢩࣜࢥࣥኴ㝧㟁ụࡢ㧗ຠ⋡໬ࡢ᪂つᡭἲ࡜ࡋ࡚ࠊձ໬Ꮫⓗ㌿෗ἲࠊղ◪㓟㓟໬ἲࠊճḞ
㝗ᾘ⁛ᆺ༙ᑟయὙίἲࢆ⏝࠸࡚ࢩࣜࢥࣥࡢ⾲㠃࣭⏺㠃ࢆไᚚࡍࡿ᪉ἲࢆ㛤Ⓨࡋ࡚ࡁࡓࠋࡑࡢ≀ᛶࢆ᳨ウ
ࡍࡿࡓࡵ࡟ࠊศගᏛⓗᡭἲཬࡧ㟁Ẽⓗᡭἲࢆ⏝࠸࡚ ᐃࡍࡿࠋ≉࡟ࠊ໬Ꮫⓗ㌿෗ἲࢆ⏝࠸࡚ᙧᡂࡍࡿᴟ
ప཯ᑕ⋡ࢩࣜࢥࣥ⾲㠃ࡢᚤどⓗ࡞≀ᛶ࡜ኴ㝧㟁ụ≉ᛶ࡜ࡢ㛵ಀࢆゎ᫂ࡍࡿࠋ໬Ꮫⓗ㌿෗ἲ࡛ᙧᡂࡉࢀࡿ
ࢩࣜࢥࣥࢼࣀࢡࣜࢫࢱࣝᒙࡢ≀ᛶࢆゎ᫂ࡋࠊᴟప཯ᑕ⋡ࡢᶵᵓࢆぢฟࡍࡇ࡜ࡶ㔜せ࡞ㄢ㢟࡛࠶ࡿࠋ㧗࠸
ᑡᩘ࢟ࣕࣜ࢔࣮ࣛ࢖ࣇࢱ࢖࣒࡜ඹ࡟ࠊࡇࡢᵓ㐀ࢆኴ㝧㟁ụ࡟฼⏝ࡋࡓሙྜ࡟㧗࠸ග㉳㟁ຊࢆᚓࡿࢩࣜࢥ
ࣥࢼࣀࢡࣜࢫࢱࣝᒙࡢࣃࢵࢩ࣮࣋ࢩࣙࣥἲࢆぢฟࡍࠋࣃࢵࢩ࣮࣋ࢩࣙࣥἲ࡜ࡋ࡚ࠊ◪㓟㓟໬ἲࠊḞ㝗ᾘ
⁛ᆺ༙ᑟయὙίἲࠊ⇕㓟໬ἲࠊỈ⣲ฎ⌮ࢆ᳨ウࡍࡿࠋࣃࢵࢩ࣮࣋ࢩࣙࣥฎ⌮ᚋࡢ⾲㠃࣭⏺㠃≀ᛶࢆ✀ࠎ
ࡢศගἲࢆ⏝࠸࡚ゎᯒࡍࡿࠋ
b) ᡂᯝ
໬Ꮫⓗ㌿෗ἲࢆ⏝࠸࡚ᙧᡂࡍࡿᴟప཯ᑕ⋡ࢩࣜࢥࣥ⾲㠃ࡢᚤどⓗ࡞཯ᑕ⋡ࢆ ᐃࡋࠊᴟప཯ᑕ⋡ࡢᶵ
ᵓࡸኴ㝧㟁ụ≉ᛶ࡜ࡢ㛵ಀࢆゎᯒ୰࡛࠶ࡿࠋࢩࣜࢥࣥࢼࣀࢡࣜࢫࢱࣝᒙࡢࣃࢵࢩ࣮࣋ࢩࣙࣥἲ࡜ࡋ࡚ࠊ
◪㓟㓟໬ἲࠊḞ㝗ᾘ⁛ᆺ༙ᑟయὙίἲࠊ⇕㓟໬ἲཬࡧỈ⣲ฎ⌮ࢆࠊฎ⌮᫬㛫ࡸ⤌ྜࡏࢆኚ࠼࡚⾜࠸ࠊࡇ
ࢀࡽࡢᇶᯈࢆ⏝࠸࡚ᑡᩘ࢟ࣕࣜ࢔࣮ࣛ࢖ࣇࢱ࢖࣒ࠊኴ㝧㟁ụ≉ᛶࢆホ౯ࡋࡓࠋࡲࡓࠊࣃࢵࢩ࣮࣋ࢩࣙࣥ
ฎ⌮ᚋࡢ⾲㠃࣭⏺㠃≀ᛶࢆ✀ࠎࡢ㉥እ྾཰ศගἲࢆ⏝࠸࡚ゎᯒࡋࠊࡉࡽ࡟ࠊ῝࠸‽఩㐣Ώศග࡟ࡼࡿホ
౯ࢆ⥅⥆୰࡛࠶ࡿࠋࡇࢀࡽࡢ⤖ᯝࢆᇶ࡟ࠊࢩࣜࢥࣥࢼࣀࢡࣜࢫࢱࣝᒙࡢࣃࢵࢩ࣮࣋ࢩࣙࣥἲࡢ࣓࢝ࢽࢬ
࣒ゎ᫂ࢆ㐍ࡵ࡚࠸ࡿࠋ
― 115 ―
ࢼࣀࢹࣂ࢖ࢫホ౯࣭デ᩿ศ㔝
እᅜே◊✲ဨ ᓲ ṇ໕ (ᖹᡂ 27 ᖺ 2 ᭶ 2 ᪥㹼ᖹᡂ 27 ᖺ 3 ᭶ 2 ᪥)
a) ᴫせ
᭱㏆ࠊ㔞Ꮚࣅ࣮࣒⛉Ꮫ◊✲᪋タ࡛ࡣࠊࣃࣝࢫࣛࢪ࢜ࣜࢩࢫ࡜⤌ࡳྜࢃࡏࡓ᫬㛫ศゎ࣐ࣛࣥศගἲࡀ᪂
ࡓ࡟㛤Ⓨࡉࢀࡓࠋࡑࡇ࡛ᮏ◊✲࡛ࡣࠊࡇࡢ⿦⨨ࢆ౑⏝ࡋ࡚ࠊࣃࣛ⨨᥮ࣅࣇ࢙ࢽࣝ(Bp-X; X = -OH, -OCH 3 ,
-CH 3 , -H, -CONH 2 , -COOH, ࠾ࡼࡧ-CN)࠾ࡼࡧ ࡑࢀࡽࡢࣛࢪ࢝ࣝ࢔ࢽ࢜ࣥ(Bp-Xx-)ࡢᵓ㐀࡟ࡘ࠸᳨࡚ウ
ࡋࡓࠋBp-X ࡢ⎔ෆ C1-C1cఙ⦰᣺ືࣔʊࢻ(Q 6 )ࡣ~1285 cm-1࡟ほ ࡉࢀࠊ୍᪉ࠊBp-Xx-ࡢQ 6 ࡣࣃࣛ఩ࡢ⨨
Bp-Xx᥮ᇶ X ࡢ㟁Ꮚ౪୚ᛶࠊ
㟁Ꮚཷᐜᛶ࡟౫Ꮡࡋ࡚㧗Ἴᩘഃ࡟⛣ືࡋࡓࠋ
Bp-X ࡜ Bp-Xx-ࡢQ 6 ࡢᕪ␗࠿ࡽࠊ
ࡢᵓ㐀ࡣ X ࡢ㟁Ꮚぶ࿴ຊ࡟౫ᏑࡋࠊHammett ࡢ⨨᥮ᇶᐃᩘV p ࡜ࡼ࠸㛵ಀࢆ♧ࡍࡇ࡜ࡀࢃ࠿ࡗࡓࠋ
b) ᡂᯝ
Bp-X ࡛ࡣ 2 ࡘࡢ࣋ࣥࢮࣥ⎔ࡢ࢜ࣝࢺ఩ࡢỈ⣲ࡢ❧య཯Ⓨࡢࡓࡵ࡟㸰ࡘࡢ࣋ࣥࢮࣥ⎔ࡀ᏶඲࡟ᖹ㠃࡛
ࡣ࡞ࡃࠊࡸࡸࡡࡌࢀࡓᵓ㐀ࢆྲྀࡿࡇ࡜ࡀ▱ࡽࢀ࡚࠸ࡿࠋྠᵝ࡟ࠊBp-Xx- ࡢᵓ㐀࡟ࡘ࠸࡚ࡶᵝࠎ࡞◊✲ࡀ
⾜ࢃࢀ࡚ࡁࡓࠋᮏ◊✲࡛ࡣࠊBp-X ࡜ Bp-Xx-ࡢᵓ㐀ࢆࠊࡑࢀࡒࢀࠊ㏻ᖖࡢ࣐ࣛࣥศගἲ࠾ࡼࡧࣃࣝࢫࣛ
ࢪ࢜ࣜࢩࢫ࡜⤌ࡳྜࢃࡏࡓ᫬㛫ศゎ࣐ࣛࣥศගἲ࡟ࡼࡗ᳨࡚ウࡋࡓࠋ≉࡟ࠊࣃࣛ఩ࡢ⨨᥮ᇶ X ࡢ㟁Ꮚ౪
୚ᛶࠊ
㟁Ꮚཷᐜᛶࡢᵓ㐀࡟ཬࡰࡍຠᯝࢆ᫂ࡽ࠿࡟ࡋࡓࠋᐇ㦂⤖ᯝࡣࠊ
⌮ㄽィ⟬࡟ᇶ࡙࠸ࡓ Bp-X ࡜ Bp-Xxxࡢᵓ㐀࡜ࡼ࠸┦㛵ࢆ♧ࡋࡓࠋBp-X ࡢᵓ㐀ࡣ X ࡢ㟁Ꮚぶ࿴ຊ࡟౫Ꮡࡋࠊ୍᪉ࠊBp-X ࡣࡡࡌࢀᵓ㐀ࢆ᭷
ࡋ X ࡟౫Ꮡࡋ࡞࠸ࠋBp-X ࠾ࡼࡧ Bp-Xx-ࡢ⎔ෆ C1-C1cఙ⦰᣺ືࣔʊࢻ(Q 6 )ࡢᕪ␗ࡣ Hammett ࡢ⨨᥮ᇶᐃ
ᩘV p ࡜┦㛵ࢆ♧ࡋࠊ㟁Ꮚ౪୚ᛶ࠾ࡼࡧ㟁Ꮚཷᐜᛶࡢ࡝ࡕࡽ࡟࠾࠸࡚ࡶࠊ2 ࡘࡢ࣋ࣥࢮࣥ⎔ࡀࡡࡌࢀᵓ㐀
࡜࡞ࡿࡇ࡜ࡀ♧၀ࡉࢀࡓࠋ୍᪉ࠊBp-Hx- ࡢ㸰ࡘࡢ࣋ࣥࢮࣥ⎔ࡣᖹ㠃ᵓ㐀࡛࠶ࡿࠋBp-Xx- ࡢࡡࡌࢀᵓ㐀ࡣ
୙ᑐ㟁Ꮚ࠾ࡼࡧ㈇㟁Ⲵࡀ∦᪉ࡢ࣋ࣥࢮࣥ⎔࡟ᒁᅾ໬ࡋ࡚࠸ࡿࡓࡵ࡛࠶ࡿࠋࡉࡽ࡟ࠊX ࡀ㟁Ꮚ౪୚ᛶࡢ
Bp-Xx-ࡢሙྜࠊ୙ᑐ㟁Ꮚ࠾ࡼࡧ㈇㟁Ⲵࡣ X ࡀ⨨᥮ࡋ࡚࠸࡞࠸ഃࡢ࣋ࣥࢮࣥ⎔࡟ᒁᅾ໬ࡋࠊ㏫࡟ࠊX ࡀ㟁
Ꮚཷᐜᛶࡢ Bp-Xx-ࡢሙྜࠊ୙ᑐ㟁Ꮚ࠾ࡼࡧ㈇㟁Ⲵࡣ X ࡀ⨨᥮ࡋࡓഃࡢ࣋ࣥࢮࣥ⎔࡟ᒁᅾ໬ࡍࡿࡇ࡜ࡀ♧
၀ࡉࢀࡓࠋ
― 116 ―
ࢼࣀࢸࢡࣀࣟࢪ࣮⏘ᴗᛂ⏝◊✲ศ㔝
ᐈဨᩍᤵ
Ralescu Anca Luminita㸦ᖹᡂ 26 ᖺ 2 ᭶ 3 ᪥㹼ᖹᡂ 26 ᖺ 4 ᭶ 30 ᪥㸧
a) ᴫせ
㏆ᖺࠊேᕤ▱⬟ࠊᶵᲔᏛ⩦ࠊ⤫ィ⌮ㄽ (AI/ML/S ᢏ⾡) ࢆࢼࣀࢸࢡࣀࣟࢪ࣮⏘ᴗศ㔝࡟㐺⏝ࡍࡿືࡁ
ࡀ࠶ࡿࠋࢩ࣮ࣗࣞࢹ࢕࣮ࣥ࢞᪉⛬ᘧࢆ㠀⥺ᙧᅇᖐၥ㢟࡟ኚ᥮ࡋ࡚ゎࡃᡭἲࡶࡑࡢ୍౛࡛࠶ࡿࠋࡋ࠿ࡋࠊ
ࡇࢀࡽࡢ࡝ࡢᢏ⾡ࡀࢼࣀࢸࢡࣀࣟࢪ࣮ࡢ࡝ࡢၥ㢟ゎỴ࡟᭷ຠ࠿ࡢලయⓗ࡞ᣦ㔪ࡣࡲࡔ࡞࠸ࠋࡑࡢ⌮⏤ࡣ
⏕≀ࠊ໬Ꮫࠊ≀⌮ศ㔝࡛㛤Ⓨࡉࢀ࡚᮶ࡓࣔࢹࣝࡢከࡃࡣỗ⏝ⓗ࡟⤫ྜࡋ࡚ᢅ࠺ࡇ࡜ࡀ㞴ࡋ࠸ࡇ࡜࡟㉳ᅉ
ࡋ࡚࠸ࡿࠋࡑࡢࡓࡵࠊ⌧᫬Ⅼ࡛ࡣ AI/ML/S ᢏ⾡ࡢ㐺⏝ࡢ௙᪉ࡣ࢔ࢻ࣍ࢵࢡ࡛࠶ࡿ࡜ゝࢃࡊࡿࢆᚓ࡞࠸ࠋ
ᮏ◊✲࡛ࡣࠊࡲࡎࠊ᭱ඛ➃ AI/ML/S ᢏ⾡ࡢࢼࣀࢸࢡࣀࣟࢪ࣮ᛂ⏝≧ἣࢆㄪᰝศᯒࡋࠊศᏊタィ࡞࡝ࡢࢼ
ࣀࢸࢡࣀࣟࢪ࣮⏘ᴗᛂ⏝࡟㐺⏝ࡍࡿ࡟㝿ࡋࠊ࡝ࡢࡼ࠺࡞ AI/ML/S ᢏ⾡ࢆ౑࠼ࡤຠᯝⓗ࠿ࢆ᳨ウࡋࡓࠋ
b) ᡂᯝ
✀ࠎࡢㄪᰝࡢ⤖ᯝࠊࢼࣀࢸࢡࣀࣟࢪ࣮ࢆ౑⏝ࡋ࡚᪂ࡋ࠸ࢭࣥࢩࣥࢢࢹࣂ࢖ࢫࢆ㛤Ⓨࡍࡿືࡁࡀ࠶ࡿࡇ
࡜ࡀศ࠿ࡗࡓࠋࡓ࡜࠼ࡤࠊᙜࢼࣀࢸࢡࣀࣟࢪ࣮◊✲ࢭࣥࢱ࣮࡛ࡣࠊࢼࣀ࣭࣏࢔ࢆ⏝࠸࡚ 1 ศᏊィ ࡸศ
Ꮚ DNA࣭RNA ࢩ࣮ࢡ࢚ࣥࢩࣥࢢ◊✲ࠊࢼࣀࣉࣟࢭࢫ࡟ࡼࡿ㟁Ꮚࢹࣂ࢖ࢫ◊✲ࠊ㔞Ꮚࣅ࣮࣒࡟ࡼࡿ㟁Ꮚ
㢧ᚤ㙾◊✲ࠊࢼࣀࢫࢣ࣮ࣝ⣲Ꮚ࡟ࡼࡿ࢚ࢿࣝࢠ࣮ኚ᥮◊✲࡞࡝ࡀ⾜ࢃࢀ࡚࠸ࡿࠋ᳨ウࡢ⤖ᯝࠊࡇࢀࡽࡢ
◊✲࠿ࡽᑗ᮶๰ฟࡉࢀࡿ࡛࠶ࢁ࠺᪂ࡋ࠸ࢭࣥࢧ࣮ࡢฟຊಙྕࡣࠊࢼࣀࢫࢣ࣮ࣝࡢࢭࣥࢩࣥࢢ㐣⛬࡛࠶ࡿ
ࡀᨾ࡟ከࡃࡢࣀ࢖ࢬࢆྵࡴ࡛࠶ࢁ࠺ࡇ࡜ࡀ᫂ࡽ࠿࡜࡞ࡗࡓࠋࡑࡢࡼ࠺࡞ฟຊಙྕࢆ㐺ษ࡟ฎ⌮ࡋ࡚㧗⢭
ᗘࡢࢭࣥࢩࣥࢢ⤖ᯝࢆᚓࡿࡓࡵ࡟ࡣࠊ⤫ィⓗࣔࢹࣝ࡟ᇶ࡙ࡃᶵᲔᏛ⩦ᡭἲࡢ㐺⏝ࡀ᭷ຠ࡛࠶ࡿࡇ࡜ࢆ☜
ㄆࡋࡓࠋ
― 117 ―
ࢼࣀࢸࢡࣀࣟࢪ࣮⏘ᴗᛂ⏝ศ㔝
ᐈဨᩍᤵ
Daniel Arenas (ᖹᡂ 26 ᖺ 5 ᭶ 1 ᪥㹼ᖹᡂ 26 ᖺ 7 ᭶ 1 ᪥)
a) ᴫせ
㔠ᒓ࢝ࢳ࢜ࣥࢆ୰ᚰ࡜ࡋࡓ㓟⣲ඵ㠃య࠿ࡽᵓᡂࡉࢀࡿࢩࣞࢼ࢖ࢺ㸦Bi12SiO20ࠊBi12GeO20㸧ࡣࠊᩘከࡃ
ࡢ㠀⥺ᙧගᏛ≉ᛶࢆᣢࡘࡓࡵ◊✲ࡀ㐍ࡵࡽࢀ࡚ࡁ࡚࠸ࡿࠋ᭱㏆ࠊBi25FeO39ࠊBi25InO39 ࡜࠸ࡗࡓ᪂ࡋ࠸ࢩ
ࣞࢼ࢖ࢺࡀගゐ፹≉ᛶࢆᣢࡘࡓࡵὀ┠ࢆ㞟ࡵ࡚࠸ࡿࠋࡋ࠿ࡋ࡞ࡀࡽࠊᵓ㐀ࡸ⤌ᡂࡀᮍゎ᫂࡞ࡓࡵ≀ᛶࡢ
ཎᅉࢆ✺ࡁṆࡵࡿࡇ࡜ࡀᅔ㞴࡛࠶ࡗࡓࠋ࣐ࣛࣥ ᐃࢆ⏝࠸ࡓ◊✲࠿ࡽࠊ4 ౯ࡢ Bi12Si+4O20 ࡸ Bi12Ge+4O20
࡜ẚ࡭࡚ࠊ3 ౯ࡢ Bi25Fe+3O39 ࡜ Bi25In+3O39 ࡣࠊBi-O 㦵᱁࡟ከࡃࡢ୙ᆒ୍࡞ disorder ࢆᣢࡘࡇ࡜ࡀሗ࿌ࡉ
ࢀ࡚࠾ࡾࠊᐇ㝿࡟㟁Ꮚ⥺ᅇᢡ ᐃ࡟࠾࠸࡚ disorder ࢆ♧ࡍࢫࢺ࣮ࣜࢡࡀほ ࡉࢀ࡚࠸ࡿࠋᮏ◊✲࡛ࡣࠊ
࣐ࣝࢳࢫࣛ࢖ࢫἲࢆ⏝࠸࡚㟁Ꮚ⥺ᅇᢡീࢆィ⟬ࡋࠊࡉࡽ࡟㏣ຍࢹ࣮ࢱࢆྲྀᚓࡍࡿࡇ࡜࡛ disorder ⏤᮶ࡢ
ࢫࢺ࣮ࣜࢡࢆゎᯒࡋࡓࠋ
b) ᡂᯝ
୕ࡘࡢࢩࣞࢼ࢖ࢺࡢ㟁Ꮚ⥺ᅇᢡࣃࢱ࣮ࣥࢆྲྀᚓࡋࡓ࡜ࡇࢁࠊBi25FeO39 ࡜ Bi25InO39 ࡛ࡣᖹᆒᵓ㐀࠿ࡽ
ࡢ೫ᕪ⏤᮶ࡢࢫࢺ࣮ࣜࢡࡀほ ࡉࢀࡓࡀࠊBi12SiO20 ࡛ࡣほ ࡉࢀ࡞࠿ࡗࡓࠋ࣐ࣝࢳࢫࣛ࢖ࢫィ⟬
㸦MacTempas software㸧࡟ࡼࡿ࡜ࠊࡇࡢࢫࢺ࣮ࣜࢡࡣ㓟⣲Ḟᦆࡢ▷㊥㞳⛛ᗎ໬࡟ࡼࡿࡶࡢ࡜᥎ᐃࡉࢀࡓࠋ
㓟⣲Ḟᦆࡣゐ፹㐣⛬࡟࠾࠸࡚㔜せ࡞ᙺ๭ࢆᢸ࠺ࡓࡵࠊࡇࡢ⤖ᯝࡣ㠀ᖖ࡟㔜せ࡛࠶ࡿࠋᚑ᮶ࡢ࣐ࣛࣥ ᐃ
࡟ࡼࡿ◊✲࡜ేࡏ࡚⪃࠼ࡿࡇ࡜࡛ࠊྜᡂࡸ≉ᛶホ౯࡟࠾࠸࡚㔜せ࡞▱ぢࡀᚓࡽࢀࡿࠋ
ᮏ◊✲ࡢᡂᯝࡣࠊAIP Advances ㄅ࡟ࠕElectron diffraction study of the sillenites Bi12SiO20, Bi25FeO39 and
Bi25InO39: Evidence of short-range ordering of oxygen-vacancies in the trivalent sillenitesࠖ࡜࠸࠺ࢱ࢖ࢺ࡛ࣝⓎ
⾲ࡋࡓࠋᮏㄽᩥ࡛ࡣࠊᐈဨᩍᤵࢆ㈐௵ⴭ⪅࡜ࡋ࡚࠾ࡾࠊ➉⏣ᩍᤵࡽࢆඹⴭ⪅࡜ࡋ࡚࠸ࡿࠋࡲࡓࠊᮏࢧ࣏
࣮ࢺ࡟ࡼࡾࠊ㛵㐃ࡍࡿ◊✲ࢆ Physical Review B ㄅ࡟ࠕFirst-principles study of the phonon modes in bismuth
sillenitesࠖⓎ⾲࡛ࡁࡓࡇ࡜࡟ឤㅰ⏦ࡋୖࡆࡿࠋ
ᅾᏛࡋ࡚࠸ࡓ 8 㐌㛫ࡢ㛫ࠊ㐌࡟୍ᅇࠊ➉⏣◊✲ᐊࡢ኱Ꮫ㝔⏕࡟ᑐࡋ࡚ࠊಶேࡢ◊✲࡟ࡘ࠸࡚ࡢⱥㄒ࡛
ࡢ 10 ศ㛫ࡢࣉࣞࢮࣥࢸ࣮ࢩࣙࣥࡢᣦᑟࢆ⾜ࡗࡓࠋ᭱⤊㐌࡟ࡣ◊✲ᐊෆ࡛ⱥㄒⓎ⾲ࢆ⾜࠸ࠊ⣲ᬕࡽࡋ࠸
ⱥㄒࣉࣞࢮࣥࢸ࣮ࢩࣙࣥᢏ⾡ࢆ㌟࡟ࡘࡅࡉࡏࡿࡇ࡜ࡀ࡛ࡁࡓࠋ௒ᚋࡶ➉⏣ᩍᤵ࡞ࡽࡧ࡟ྜྷ⏣෸ᩍᤵ࡜ඹ
ྠ◊✲ࢆ㐍ࡵ࡚࠸ࡁࡓ࠸࡜⪃࠼࡚࠸ࡿࠋ
― 118 ―
ࢼࣀຍᕤᐊ
ᐊ㛗㸦ව௵㸧ᩍᤵ
ᢏ⾡⫋ဨ
⏣୰ ⚽࿴
ᴬཎ ୍᪼ࠊ㇂⏿ බ᫛
a) ᴫせ
ࢼࣀຍᕤᐊࡣࠊ⏘◊ࡢ᭷ࡍࡿྛ✀ࢼࣀຍᕤ⿦⨨࠾ࡼࡧࢼࣀຍᕤᢏ⾡ࢆ┦஫࡟᭷ຠά⏝ࡋࠊྛศ㔝ࡢ◊
✲ࡢ᥎㐍ࢆᅗࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚࠸ࡿࠋᚤ⣽ຍᕤࡢᢏ⾡௦⾜ࡢ࡯࠿ࠊᚤ⣽ຍᕤࡢᛂ⏝࡟㛵ᚰࢆᣢࡘ◊✲
⪅࡟ࢹࣂ࢖ࢫࡢ㛤Ⓨ࣭ᥦ౪ࢆ⾜ࡗ࡚࠸ࡿࠋ
b) ᡂᯝ
౫㢗௳ᩘ
౫㢗ඛ
౫㢗௳ᩘ
࣭ຍᕤ౫㢗
ࢼࣀຍᕤᐊࡀ⾜࠺ຍᕤᴗົࡣࠊ᪂つࢹࣂ࢖ࢫࡢ㛤Ⓨ
ࢆึࡵ࠿ࡽ⾜࠺ࡇ࡜ࡶ࠶ࢀࡤࠊ࢚ࢵࢳࣥࢢࡸᡂ⭷࡜࠸
ࡗࡓࠊࢹࣂ࢖ࢫຍᕤࣉࣟࢭࢫࡢ୍㒊ࢆᢸᙜࡍࡿࡇ࡜ࡶ
࠶ࡿࠋ2014 ᖺᗘࡣ 9 ◊✲ᐊ࠿ࡽ 80 ௳ࡢຍᕤ౫㢗ࡀ࠶ࡗ
ࡓࠋᅗ 1 ࡟ࡣ 2005 ᖺᗘࡢⓎ㊊௨᮶ࡢ౫㢗ඛ࡜౫㢗௳ᩘ
ࡢ᥎⛣ࢆ♧ࡋࡓࠋ฼⏝◊✲ᐊࡢቑຍ࣭ῶᑡ࡟క࠺ᛴ⃭
࡞ኚ໬ࡀぢࡽࢀࡿࡀࠊ┠ᶆ࡜ࡋ࡚ 10 ౫㢗ඛ࠿ࡽ 100 ౫
㢗௳ᩘࢆ┠ᣦࡋ࡚ࡺࡁࡓ࠸ࠋ
2014 ᖺᗘࡣ᪂つ࡞ຍᕤ౫㢗ࡣ࡞࠿ࡗࡓࡀࠊࡇࢀࡲ࡛
స〇ࡋ࡚࠸ࡓࢩࣜࢥࣥⷧ⭷ࢆࠊࡉࡽ࡟ⷧ⭷໬ࡉࡏࡿຍ
ᕤࢆ⾜ࡗࡓࠋᅗ 2 ࡣࢩࣜࢥࣥⷧ⭷ࡢගᏛ㢧ᚤ㙾ീ࡛ࠊ
࣮࣋ࢪࣗⰍ࡟ぢ࠼ࡿ㒊ศࡀ 30nm ࡢཌࡉ࡟࡞ࡗ࡚࠸ࡿࠋ
౫㢗ඛ
ᖺᗘ
ᅗ㸯 2005 ᖺⓎ㊊௨᮶ࡢάືᒚṔ
࣭ᅜ㝿ࢼࣀࢸࢡࣀࣟࢪ࣮⥲ྜᒎࡢཧຍ
2015 ᖺ 1 ᭶ 28 ᪥ 㹼 30 ᪥ ࡟ ᮾ ி ࡛ ⾜ ࢃ ࢀ ࡓ
nanotech2015 ࡟⏘◊ࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮ࡢ୍ဨ
࡜ࡋ࡚ཧຍࡋࡓࠋάືෆᐜࢆࡲ࡜ࡵࡓࣃࢿࣝ࡜ࠊࢧࣥ
ࣉࣝࡢᒎ♧ࢆ⾜ࡗ࡚ࡁࡓࠋ
ᅗ㸰 ࢩࣜࢥࣥⷧ⭷ࠋ࣮࣋ࢪࣗⰍࡢ㒊ศࡀ┤ᚄ ȣPࠊ
ཌࡉ QP ࡢࢩࣜࢥࣥⷧ⭷㒊ศ࡟࡞ࡗ࡚࠸ࡿࠋ
― 119 ―
ࢼࣀࢸࢡඛ➃ᶵჾᐊ
ᐊ㛗㸦ව௵㸧ᩍᤵ
≉௵ᢏ⾡⫋ဨ
⏣୰ ⚽࿴
బஂ㛫 ⨾ᬛᏊ
a) ᴫせ
ࢼࣀࢸࢡඛ➃ᶵჾᐊࡣࠊࢼࣀࢸࢡࣀࣟࢪ࣮࡟≉໬ࡋࡓ᭱ඛ➃ᶵჾࢆタ⨨ࡋࠊࢼࣀࢸࢡࣀࣟࢪ࣮◊✲ࢆ
ᡓ␎ⓗ࡟Ⓨᒎࡉࡏࡿࡓࡵ࡟ࠊࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮ࡢᨵ⤌ᣑ඘࡟క࠸ 2009 ᖺᗘ࡟Ⓨ㊊ࡋࡓࠋᴟᚤ
⣽࡞ࢼࣀࢹࣂ࢖ࢫᵓ㐀ࢆᙧᡂ࡛ࡁࡿ㟁Ꮚ⥺㟢ග⿦⨨ࢆ⏝࠸ࡓ㉸ᚤ⣽ຍᕤࢩࢫࢸ࣒ཬࡧࢼࣀࢹࣂ࢖ࢫຍ
ᕤ⿦⨨⩌ࠊࢼࣀࢹࣂ࢖ࢫᵓ㐀ホ౯⿦⨨⩌ࠊࢼࣀࢹࣂ࢖ࢫᶵ⬟ホ౯⿦⨨⩌࠿ࡽ࡞ࡿࢼࣀࢹࣂ࢖ࢫ㉸⢭ᐦຍ
ᕤ࣭≀ᛶホ౯ࢩࢫࢸ࣒ࡀタ⨨ࡉࢀ࡚࠾ࡾࠊ↓ᶵ≀ࠊ㔠ᒓ㓟໬≀ࠊ᭷ᶵ≀ࠊ⏕య㛵㐃≀㉁➼ࡢከᵝ࡞ᮦᩱ
ࡢࢼࣀᵓ㐀ᙧᡂ࠾ࡼࡧᵓ㐀࣭ᶵ⬟࣭㟁Ꮚ≉ᛶ➼ࡢ㧗⢭ᗘゎᯒ࠾ࡼࡧホ౯ࡀྍ⬟࡜࡞ࡿࠋࡇࢀࡽඛ➃⿦⨨
⩌࡟ࡼࡾ㐃ᦠࡋࡓࢼࣀࢸࢡࣀࣟࢪ࣮◊✲ࡢⓎᒎⓗ᥎㐍ࢆྍ⬟࡜ࡋࠊࡉࡽ࡟ࡑࡢᡂᯝࢆᬑཬࡉࡏࡿࡇ࡜ࢆ
┠ᣦࡋ࡚࠸ࡿࠋ
b) ᡂᯝ
ඛ➃ᶵჾᐊࡢ⿦⨨ูࡢ฼⏝≧ἣࢆྑࡢࢢࣛࣇ࡟
♧ࡍࠋ฼⏝⥲ᩘࡣ 994 ௳࡛๓ᖺᗘ࡜ẚ㍑ࡋ࡚ 84 ௳
ῶᑡࠋ
LED ᥥ⏬⿦⨨ࡸ㞟᮰࢖࢜ࣥࣅ࣮࣒⿦⨨࡞࡝ࡢຍᕤ
⿦⨨ࡸⷧ⭷ࢼࣀᵓ㐀ゎᯒ⿦⨨ࡢ฼⏝ࡀከ࠿ࡗࡓࠋ
ᅗ㸯
ᅗ㸯 ࣟࢦ࣐࣮ࢡ㸦㹋㹑᫂ᮅ
ᅗ㸯
ࣟࢦ࣐࣮ࢡ㸦㹋㹑᫂ᮅ
ࣟࢦ
᫂ᮅ SW㸧
᫂ᮅ
SW㸧
― 120 ―
ࢼࣀࢸࢡࣀࣟࢪ࣮タഛ౪⏝ᣐⅬ
ᣐⅬ㛗㸦ව௵㸧ᩍᤵ
ᩍᤵ㸦ව௵㸧
≉௵ᩍᤵ㸦ව௵㸧
ຓᩍ㸦ව௵㸧
≉௵ຓᩍ
≉௵◊✲ဨ
஦ົ⿵బဨ
ὴ㐵⫋ဨ
ྜྷ⏣ 㝧୍
ಖ⏣ ⱥὒ
⏣୰ ⚽࿴
㇂ཱྀ ṇ㍤
᳃ ༤ኴ㑻
ᑠᯘ ៞ኴ
໭ᓥ ᙲ
ἲ⃝ බᐶ
᯽಴ ⨾⣖
ᵽཱྀ ᏹ஧
㇂ཱྀ 㝯
Dinh Cong Que
㏆⏣ ࿴⨾
ୗ‶ ᜤᏊ
ᅭぢ ᜨᏊ
๓ᕝ ⰾ⨾
ୖ㇂ ᬛⱥᏊ
㸦㹼ᖹᡂ 26 ᖺ 7 ᭶ 1 ᪥㸧
㸦ᖹᡂ 26 ᖺ 7 ᭶ 2 ᪥㹼㸧
㸦㹼ᖹᡂ 27 ᖺ 3 ᭶ 31 ᪥㸧
㸦㹼ᖹᡂ 26 ᖺ 6 ᭶ 30 ᪥㸧
㸦ᖹᡂ 26 ᖺ 4 ᭶ 1 ᪥㹼㸧
㸦ᖹᡂ 26 ᖺ 4 ᭶ 8 ᪥㹼ᖹᡂ 27 ᖺ 3 ᭶ 31 ᪥㸧
㸦ᖹᡂ 26 ᖺ 8 ᭶ 4 ᪥㹼㸧
a) ᴫせ
ᩥ㒊⛉Ꮫ┬ጤク஦ᴗࠕࢼࣀࢸࢡࣀࣟࢪ࣮ࣉࣛࢵࢺࣇ࢛࣮࣒஦ᴗ㸦௨ᚋ“ᮏ஦ᴗ”࡜␎ࡍ㸧
ࠖࡣࠊ኱ࡁ࡞ᮇ
ᚅࡀ࠿࠿ࡿ┿࡟᪂ࡋ࠸ࢼࣀᮦᩱࡸࢼࣀࢹࣂ࢖ࢫ➼ࡢ๰ฟ࡟㈉⊩ࡋࠊࡲࡓࠊᆅᇦࡢ௻ᴗࡸ◊✲ᶵ㛵࡜ࡢ᭷
ᶵⓗ࡞㐃ᦠ➼ࢆ῝ࡵࡿࡇ࡜ࢆ┠ⓗ࡜ࡍࡿࠋᮏ஦ᴗ࡟ཧ⏬ࡍࡿ኱㜰኱Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮タഛ౪⏝ᣐⅬ
㸦௨ᚋ“ᙜᣐⅬ”࡜␎ࡍ㸧ࡣࠊᙜᣐⅬࡀಖ᭷ࡍࡿձᚤ⣽ᵓ㐀ゎᯒࠊղᚤ⣽ຍᕤࠊճศᏊ࣭≀㉁ྜᡂࡢ 3 ࡘ
ࡢࣉࣛࢵࢺࣇ࢛࣮࣒࡟ᒓࡋ࡚ᙜᣐⅬࡢ᪋タ࣭⿦⨨࣭ᢏ⾡➼ࡢ≉ᚩࢆ⏕࠿ࡋ࡚ࠊࢼࣀࣉࣟࢭࢫࡸࢼࣀᵓ㐀࣭
ᶵ⬟ࡢゎᯒ࡟ᚲせ࡞⥲ྜⓗ࡞◊✲ᨭ᥼ࢆ⾜࠺࡜࡜ࡶ࡟ࠊ༢࡞ࡿඛ➃⿦⨨࣭᪋タ࡜ࡋ࡚ࡢᶵ⬟ࡔࡅ࡛࡞ࡃࠊ
ேᮦ⫱ᡂࡸ࢖ࣀ࣮࣋ࢩࣙࣥ๰ฟࡢ᰾࡜࡞ࡿ◊✲ᢏ⾡ࢭࣥࢱ࣮ⓗᶵ⬟ࢆᯝࡓࡋ࡚࠸ࡿࠋ
ձ ᚤ⣽ᵓ㐀ゎᯒࣉࣛࢵࢺࣇ࢛࣮࣒
nm ࢫࢣ࣮ࣝࡢศゎ⬟࡛ ȝm ࢫࢣ࣮ࣝࡢཌࡉࡢヨᩱෆ㒊ࢆᵓ㐀ศᯒ࣭ゎᯒࠊྛ✀ᮦᩱࡸ⏕యヨᩱ➼
ࡢㄪ〇࡜ຠ⋡ⓗ࡞ศᯒ࣭ゎᯒ➼ࡢᨭ᥼
ղ ᚤ⣽ຍᕤࣉࣛࢵࢺࣇ࢛࣮࣒
ࣜࢯࢢࣛࣇ࢕࣮ᢏ⾡ࠊࣅ࣮࣒ࢸࢡࣀࣟࢪ࣮ࢆ฼⏝ࡋࡓⷧ⭷ヨᩱࡢᚤ⣽ຍᕤ࡜ࢹࣂ࢖ࢫ໬ࠊ࠾ࡼࡧࡑ
ࡢࢹࣂ࢖ࢫࡢホ౯➼ࡢᨭ᥼
ճ ศᏊ࣭≀㉁ྜᡂࣉࣛࢵࢺࣇ࢛࣮࣒
᭷ᶵ≀࣭↓ᶵ≀࣭㔠ᒓ➼ࡀᣢࡘᶵ⬟ࢆ᭱኱㝈࡟฼⏝ࡋࠊ✵㛫ⓗ࣭࢚ࢿࣝࢠ࣮ⓗ࡟᭱㐺࡞㓄ิࡸ⤌ྜ
ࡏࢆ⪃៖ࡋࡓཎᏊ࣭ศᏊ㓄ิࢆ᭷ࡍࡿᮦᩱࡢ๰〇ࠊࡲࡓⷧ⭷ࡸேᕤ᱁Ꮚࡢᙧᡂ࣭≀ᛶ ᐃ➼ࡢᨭ᥼
b) ᡂᯝ
ᮏ஦ᴗ࡟ࡼࡿᅜෆእ࣭Ꮫෆእࡢࢼࣀࢸࢡࣀࣟࢪ࣮◊✲ࢆࢧ࣏࣮ࢺࡍࡿඛ➃ඹ⏝᪋タ࡜ࡋ࡚ࠊ⏘ᴗ⛉Ꮫ
◊✲ᡤࡀಖ᭷ࡍࡿᚤ⣽ຍᕤ࡜ศᏊ࣭≀㉁ྜᡂ㸦ⷧ⭷ྜᡂ㸧ࠊࡑࡋ࡚㉸㧗ᅽ㟁Ꮚ㢧ᚤ㙾ࢭࣥࢱ࣮ࡀಖ᭷ࡍ
ࡿᚤ⣽ᵓ㐀ゎᯒࡢ 3 ࡘࡢࣉࣛࢵࢺࣇ࢛࣮࣒ࢆ⼥ྜ࣭」ྜ໬ࡋࠊࢼࣀࢫࢣ࣮ࣝࣉࣟࢭࢫࡸࢼࣀᵓ㐀࣭ᶵ⬟
ࡢゎᯒ࡟ᚲせ࡞᪋タ࣭⿦⨨࣭ᢏ⾡➼ࡢᥦ౪࡟ࡼࡿ⥲ྜⓗ࡞◊✲ᨭ᥼ࢆ⾜ࡗࡓࠋࡲࡓᮏᖺᗘࡣᮏ஦ᴗࡢ 3
― 121 ―
ᖺᗘ┠࡛࠶ࡾࠊᙜᣐⅬ࡛ࡣ 3 ࣉࣛࢵࢺࣇ࢛࣮࣒ྜィ࡛ᘏ࡭ 157 ௳ࡢᨭ᥼ࢆ⾜ࡗࡓࠋᖹᡂ 26 ᖺᗘࡢᡂᯝ
බ㛤஦ᴗ࡟࠾ࡅࡿᨭ᥼௳ᩘࡢ㡯┠ูෆヂࢆ⾲㸫1 ࡟♧ࡍࠋ
⾲㸫1㸸ᖹᡂ 26 ᖺᗘࡢᨭ᥼ㄢ㢟௳ᩘ㸦ᡂᯝබ㛤஦ᴗ㸦ᡂᯝබ㛤⊰ணࢆྵࡴ㸧
㸧
ᚤ⣽ᵓ㐀ゎᯒ
ᚤ⣽ຍᕤ
ศᏊ࣭≀㉁ྜᡂ
ྜィ
Ꮫ
⊂
⏘
ィ
Ꮫ
⊂
⏘
ィ
Ꮫ
⊂
⏘
ィ
Ꮫ
⊂
⏘
ィ
ᶵჾ฼⏝
9
0
3
12
39
2
6
47
25
2
7
34
73
4
16
93
ඹྠ◊✲
26
5
9
40
4
0
2
6
3
0
2
5
33
5
13
51
ᢏ⾡௦⾜
0
1
1
2
6
1
1
8
1
0
0
1
7
2
2
11
ᢏ⾡⿵ຓ
0
0
0
0
0
0
0
0
2
0
0
2
2
0
0
2
ᢏ⾡┦ㄯ
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ྜ ィ
35
6
13
54
49
3
9
61
31
2
9
42
115
11
31
157
஦ᴗ࠾ࡼࡧᣐⅬάື⤂௓ࡢࡓࡵࠊᏛእ࠿ࡽࡢゼၥ⪅࡟ࡼࡿ᪋タぢᏛࢆཷࡅධࢀࡓࠋᖹᡂ 25 ᖺᗘ࡟ཷ
ࡅධࢀࡓ᪋タぢᏛࢆ⾲㸫2 ࡟♧ࡍࠋ
⾲㸫2㸸᪋タぢᏛ㸦⏘ᴗ⛉Ꮫ◊✲ᡤഃ᪋タࠊ᪋タ฼⏝ࡢᡴྜࡏ࡟ࡼࡿぢᏛࢆ㝖ࡃ㸧
᪥௜
ゼၥ⪅㸦ᅋయ㸧
ᑐ㇟
ᖹᡂ 26 ᖺ 7 ᭶ 15 ᪥ ᛂ⏝≀⌮Ꮫ఍
௚኱Ꮫ࣭⊂ἲ
኱ศࢫ࣮ࣃ࣮ࢧ࢖࢚ࣥࢫࢥࣥࢯ࣮
ᖹᡂ 26 ᖺ 7 ᭶ 30 ᪥
㧗ᰯ⏕
ࢩ࢔࣒㸦኱ศ┴❧ୖ㔝ୣ㧗➼Ꮫᰯ㸧
ࢫ࣮ࣃ࣮ࢧ࢖ࢭࣥࢫࣁ࢖ࢫࢡ࣮ࣝ
ᖹᡂ 26 ᖺ 8 ᭶ 27 ᪥
㧗ᰯ⏕
ᅄ᮲␝㧗ᰯ
⏘ᴗ⛉Ꮫ◊✲ᡤ๰❧ 75 ࿘ᖺグᛕ஦
ᖹᡂ 26 ᖺ 11 ᭶ 29 ᪥
୍⯡
ᴗ◊✲ᡤබ㛤
ᖹᡂ 26 ᖺ 12 ᭶ 18 ᪥ ኱㜰ᅜ㝿኱࿴⏣㧗ᰯ
㧗ᰯ⏕
ேᩘ
50
20
10
102
20
ᣐⅬάື⤂௓࠾ࡼࡧᢏ⾡◊㛑ࡢሙࡢᥦ౪ࡢࡓࡵࠊᒎ♧఍ሙ࡛ࡢ฼⏝άື⤂௓ࡸࢼࣀࢸࢡࣀࣟࢪ࣮ࣉࣛ
ࢵࢺࣇ࢛࣮࣒ᢏ⾡ᨭ᥼⪅஺ὶࣉࣟࢢ࣒࡛ࣛࡢᢏ⾡ᨭ᥼⪅ཷࡅධࢀࢆ⾜ࡗࡓࠋᖹᡂ 26 ᖺᗘ㛤ദศࢆ⾲㸫3
࡟♧ࡍࠋ
⾲㸫3㸸ᣐⅬάື⤂௓࣭ࢭ࣑ࢼ࣮࣭ࢫࢡ࣮ࣝ➼
᪥௜
㛤ദྡ
ᖹᡂ 26 ᖺ 7 ᭶ 28 ᪥
-31 ᪥
ࢼࣀࢸࢡࣀࣟࢪ࣮ࣉࣛࢵࢺࣇ࢛࣮
࣒Ꮫ⏕◊ಟࣉࣟࢢ࣒ࣛ
㟁Ꮚࢹࣂ࢖ࢫࣇ࢛࣮࣒ࣛி㒔
㸦ி㒔኱Ꮫ࣭ዉⰋඛ➃⛉Ꮫᢏ⾡኱Ꮫ
㝔኱Ꮫ࡜ࡢඹྠฟᒎ࠾ࡼࡧ฼⏝┦
ㄯ఍࣭ࢭ࣑ࢼ࣮㛤ദ㸧
Nanotech2015㸦኱㜰኱Ꮫ⏘ᴗ⛉Ꮫ◊
✲ᡤ ⏘ᴗ⛉Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮
ࢭࣥࢱ࣮࡜ࡋ࡚ඹྠฟᒎ㸧
ࢼࣀࢸࢡࣀࣟࢪ࣮ࣉࣛࢵࢺࣇ࢛࣮
࣒ᢏ⾡ᨭ᥼⪅஺ὶࣉࣟࢢ࣒ࣛ
ᖹᡂ 26 ᖺ 10 ᭶ 30 ᪥
-31 ᪥
ᖹᡂ 27 ᖺ 1 ᭶ 28 ᪥
-30 ᪥
ᖹᡂ 27 ᖺ 1 ᭶ 19 ᪥
-22 ᪥
― 122 ―
ᑐ㇟
㝔⏕࣭Ꮫ㒊⏕
ேᩘ
1
௻ᴗࠊ኱Ꮫࠊබⓗᶵ㛵࡞࡝
⣙
150
௻ᴗࠊ኱Ꮫࠊබⓗᶵ㛵࡞࡝
⣙
200
ࢼࣀࢸࢡࣀࣟࢪ࣮ࣉࣛࢵࢺ
ࣇ࢛࣮࣒ᢏ⾡ᨭ᥼⪅
㸯
⥲ྜゎᯒࢭࣥࢱ࣮ ࢭࣥࢱ࣮㛗㸦ව௵㸧ᩍᤵ
෸ᩍᤵ
ຓᩍ ≉௵ຓᩍව௵
ᢏ⾡⫋ဨ㸦ව௵㸧
ᢏ⾡⿵బဨ
஦ົ⿵బဨ
ຍ⸨ ಟ㞝
㕥ᮌ ೺அ
࿘ ኱ᥭࠊᮅ㔝 ⰾ⧊
す㔝 ⨾㒔Ꮚ
⏣୰ 㧗⣖ࠊᯇᓮ ๛ࠊ⩚Ꮚᒸ ோᚿࠊᮧୖ ὒ㍜
▼ᶫ Ṋࠊᔞཎ ⥘ྜྷ
㇂ ᝋᏊ
a) ᴫせ
⥲ྜゎᯒࢭࣥࢱ࣮ࡣࠊᮦᩱゎᯒࡢࡓࡵࡢྛ✀ࡢศᯒ࠾ࡼࡧ ᐃࢆ⾜࠸ࠊ࠿ࡘࠊࡑࡢ࿘㎶ᢏ⾡࡟㛵ࡍࡿ
◊✲ࢆ⾜࠺ࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚࠸ࡿࠋ
⏘ᴗ⛉Ꮫ◊✲ᡤෆ◊✲㒊㛛ࡢࣉࣟࢪ࢙ࢡࢺ◊✲ࠊᇶ┙◊✲ࠊ࠾ࡼࡧ୍⯡ᇶ♏◊✲࡞࡝ࡢ㐙⾜࡟ᙜࡓࡾࠊ
ᙜࢭࣥࢱ࣮ᡤᒓࡢศගศᯒᶵჾࠊ⤌ᡂศᯒᶵჾࠊ≧ែศᯒᶵჾ㢮ࢆ⏝࠸ࡿྛ✀ᮦᩱࢫ࣌ࢡࢺࣝ ᐃࠊゎ
ᯒࠊホ౯࡞࡝ࢆ㏻ࡌ࡚ᙉຊ࡞◊✲ᨭ᥼άືࢆ⾜ࡗ࡚࠸ࡿࠋ
୍᪉ࠊࡇࢀࡽศᯒ⿦⨨㢮ࢆ㥑౑ࡋ࡚᪂ࡋ࠸ᮦᩱྜᡂἲࡢ㛤Ⓨ࡜ᛂ⏝࡟㛵ࡍࡿ◊✲ࠊ᪂つᶵ⬟ᛶ≀㉁ࡢ
ᵓ㐀ゎᯒ࡞࡝ࡢ◊✲άືࢆ⾜ࡗ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭࢖ࣜࢪ࣒࢘ゐ፹ࢆ⏝࠸ࡿ㓟໬཯ᛂࡢ㛤Ⓨ࡜ᛂ⏝
ࢡ࣮ࣜࣥ࡞㓟໬๣ࢆ⏝࠸ࡿゐ፹཯ᛂࡢ㛤Ⓨࡣ᭱㔜せㄢ㢟ࡢ୍ࡘ࡛࠶ࡿࠋࡲࡓᑐ⛠ࢪ࣮࢜ࣝࡢ㠀ᑐ⛠໬
ࡣ࢟ࣛࣝࣅࣝࢹ࢕ࣥࢢࣈࣟࢵࢡࢆྜᡂࡍࡿୖ࡛᭷ຠ࡞ᡭẁ࡛࠶ࡿࠋ࣓ࢯࢪ࣮࢜ࣝࡢ㓟໬ⓗ㠀ᑐ⛠໬཯ᛂ
ࢆ㘽཯ᛂ࡜ࡍࡿ࣏࣡ࣥࢵࢺᆺࡢ୙ᩧゐ፹཯ᛂࢆ⏝࠸ࠊࣀ࢘ࢮࣥ࢝ࢶࣛ⛉ࡢ࢟ࢧࢧࢤ࠿ࡽ༢㞳ࡉࢀࡿ
catalponolࡢྜᡂ࡟ᛂ⏝ࡋࡓࠋ
୙ᩧ࢖ࣜࢪ࣒࢘ゐ፹཯ᛂ࡟ࡼࡿ࢝ࢱ࣏ࣝࣀ࣮ࣝࡢྜᡂ
― 123 ―
㔞Ꮚࣅ࣮࣒⛉Ꮫ◊✲᪋タ
᪋タ㛗㸦ව௵㸧ᩍᤵ
ᩍᤵ㸦ව௵㸧
෸ᩍᤵ
෸ᩍᤵ㸦ව௵㸧
ຓᩍ
ຓᩍ㸦ව௵㸧
┿ᔱ ဴᮁ
☾ᒣ ᝅᮁࠊྜྷ⏣ 㝧୍ࠊྂ⃝ Ꮥᘯ
㄃⏣ ⩏ⱥ
ຍ⸨ 㱟ዲࠊ⸨ሯ Ᏺࠊᕝ஭ Ύᙪࠊ᳿ 㔠ᓠࠊᐊᒇ ⿱బ
⸨஌ ᖾᏊ
ᑠᯘ ୍㞝ࠊ㏆⸨ Ꮥᩥࠊᕝ℩ ၨᝅࠊධ⃝ ᫂඾ࠊᒣᮏ ὒ᥹ࠊ
Ⳣ ᫭୍ࠊᑠ㜰⏣ὈᏊ㸦H26 ᖺ 4 ᭶㹼㸧
≉௵ຓᩍ㸦ව௵㸧
ᢏ⾡⫋ဨ
ᢏ⾡⿵బဨ
ᓲ ṇ໕㹼H26 ᖺ 8 ᭶)
ྂᕝ ࿴ᘺ
ᒣᮏ ಖࠊᚨᆅ ᫂ࠊஂಖ
ஂ⨾Ꮚ
a) ᴫせ
㔞Ꮚࣅ࣮࣒⛉Ꮫ◊✲᪋タ࡟ࡣ 40 MeV ࡢ L ࣂࣥࢻ㟁Ꮚࣛ࢖ࢼࢵࢡࠊ150 MeV ࡢ㹑ࣂࣥࢻࣛ࢖ࢼࢵࢡࠊ
࣮ࣞࢨ࣮ࣇ࢛ࢺ࢝ࢯ࣮ࢻ RF 㟁Ꮚ㖠ࢆ⿦ഛࡋࡓ 40 MeV ࡢ㹑ࣂࣥࢻ㟁Ꮚࣛ࢖ࢼࢵࢡࠊࡑࡋ࡚ࢥࣂࣝࢺ 60
࣐࢞ࣥ⥺↷ᑕ⿦⨨࡞࡝ࡀ࠶ࡾࠊࡇࢀࡽࡢ⿦⨨࣭タഛࡣ኱㜰኱Ꮫෆࡢඹྠ฼⏝࡟౪ࡉࢀ࡚࠸ࡿࠋᮏ᪋タࡣ
᪋タ㛗ࡢ࡯࠿ 2 ྡࡢᑓ௵ᩍဨࠊ1 ྡࡢᢏ⾡⫋ဨ࡜㸯ྡࡢᢏ⾡⿵బဨࠊ㸯ྡࡢ≉௵◊✲ဨ࠾ࡼࡧව௵ᩍဨ
࡛ᵓᡂࡉࢀࠊ㔞Ꮚࣅ࣮࣒ㄏ㉳໬Ꮫ཯ᛂ㐣⛬࡟㛵ࡍࡿ◊✲ࠊ㔞Ꮚࣅ࣮࣒⛉Ꮫ࡟ᇶ࡙ࡃ⎔ቃᕤᏛ㛵㐃ศ㔝ࠊ
ඛ➃ࣅ࣮࣒⛉Ꮫࠊ᪂࢚ࢿࣝࢠ࣮㈨※࡜ඛ㐍་⒪ᢏ⾡㛤Ⓨ➼࡟ྲྀࡾ⤌ࢇ࡛࠸ࡿࠋࡲࡓࠊᨺᑕ⥺⟶⌮ࡸ᪋タ
ࡢ⥔ᣢ⟶⌮ࢆྵࡴࡍ࡭࡚ࡢタഛࡢ㐠Ⴀࡣࠊඹྠ฼⏝㛵ಀ⪅ࡢ༠ຊࡢࡶ࡜⾜ࡗ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭ඹྠ฼⏝
ඹྠ฼⏝᥇ᢥࢸ࣮࣐ᩘࡣࠊ⏘◊࠿ࡽࡀ 20 ௳ࠊᏛෆ࠿ࡽ
ࡀ 7 ௳ࠊᏛእࡢ◊✲⪅ࢆྵࡴࡶࡢࡀ 10 ௳ࠊᣐⅬ࠿ࡽࡀ 10
21%
⏘◊
௳ࡢྜィ 47 ௳࡛࠶ࡗࡓࠋ
㸦ᅗ 1㸧
㔞Ꮚࣅ࣮࣒⛉Ꮫ◊✲᪋タ◊✲఍ࢆ 4 ᅇ㛤ദࡋ㸦ᖹᡂ 25
௚㒊ᒁ
43%
計４7 件
ᖺ 9 ᭶ 1 ᪥ࠊᖹᡂ 25 ᖺ 9 ᭶ 3 ᪥ࠊᖹᡂ 25 ᖺ 12 ᭶ 9 ᪥ࠊ
ᣐⅬ
ᖹᡂ 25 ᖺ 12 ᭶ 11 ᪥㹼12 ᪥㸧ࠊᖹᡂ 26 ᖺᗘᡂᯝሗ࿌఍ࢆ
21%
௚ᶵ㛵
ᖹᡂ 26 ᖺ 2 ᭶ 27 ᪥࡟㛤ദࡋࡓࠋࡑࡢ࡯࠿ࠊ㡑ᅜཎᏊຊ⛉
15%
Ꮫ◊✲ᡤඛ➃ᨺᑕ⥺ᢏ⾡◊✲ᡤ࡜ࡢ㐃ᦠࣛ࣎ࢆ 2 ᅇ㸦ᖹᡂ
26 ᖺ 1 ᭶ 26 ᪥ࠊᖹᡂ 26 ᖺ 2 ᭶ 25 ᪥㸧࠾ࡇ࡞ࡗࡓࠋࡲࡓ
ᅗ 1 ᖹᡂ 26 ᖺᗘ᥇ᢥࢸ࣮࣐ෆヂ
215 ྡ௨ୖࡢ᪋タぢᏛࡀ࠶ࡗࡓࠋ
ձ 㟁Ꮚ⥺ᙧຍ㏿ჾ㸦L ࣂࣥࢻࣛ࢖ࢼࢵࢡࠊRF 㟁Ꮚ㖠 S ࣂࣥࢻࣛ࢖ࢼࢵࢡ㸧
඲࡚ࡢ㟁Ꮚ⥺ᙧຍ㏿ჾ㸦ࣛ࢖ࢼࢵࢡ㸧ࡢᖹᡂ 26 ᖺᗘࡢ⥲㐠㌿≧ἣࡣ⥲฼⏝᫬㛫 3,414 ᫬㛫ࠊ⥲฼⏝᪥
ᩘ 236 ᪥ࠊ⥲ㄢ㢟௳ᩘ 37 ௳࡛࠶ࡗࡓࠋ㸦ᅗ 2㸧
㹊ࣂࣥࢻ㟁Ꮚࣛ࢖ࢼࢵࢡ࡟ࡘ࠸࡚ࠊ㐠㌿᪥ᩘࡣ 236 ᪥ࠊ㏻⟬㐠㌿᫬㛫ࡣ⣙ 3,414 ᫬㛫࡛࠶ࡗࡓࠋࢡࣛ
࢖ࢫࢺࣟࣥ㛵ಀ࡛ࡣ 11 ᭶ࡢᚋ༙࡟ࢡࣛ࢖ࢫࢺࣟࣥ࠿ࡽࡢ෭༷Ỉ₃ࢀࡀ㉳ࡇࡗࡓࡓࡵࠊணഛရ࡟஺᥮ࡋ
ࡓࠋ௒ᅇࡢࢡࣛ࢖ࢫࢺࣟࣥ஺᥮࡟ࡼࡾࠊ30 MW ࢡࣛ࢖ࢫࢺࣟࣥࡢணഛࡣ࡞ࡃ࡞ࡗࡓࡓࡵࠊ㛗ᮇ࡟ࢃࡓ
ࡿᏳᐃ࡞࣐ࢩࣥࢱ࢖࣒ࡢ౪⤥ࡢほⅬ࠿ࡽ᪩ᛴ࡞ᡭ㓄ࡀᚲせ࡛࠶ࡿࠋࣔࢪ࣮ࣗࣞࢱ࡟ࡘ࠸࡚ࡣࢧ࢖ࣛࢺࣟ
ࣥࢆ༙ᑟయࢫ࢖ࢵࢳ࡟ኚ᭦ࡋࠊヨ㦂㐠㌿ࢆ⾜ࡗ࡚ࡁ࡚࠸ࡿࡀࠊࡲࡔࣀ࢖ࢬᑐ⟇ࡸᨺ⇕ᑐ⟇ࡀ༑ศ࡛ࡣ࡞
ࡃࠊᘬࡁ⥆ࡁᨵⰋࢆຍ࠼࡞ࡀࡽ㐠㌿ࢆ⾜ࡗ࡚࠸ࡿ࡜ࡇࢁ࡛࠶ࡿࠋ㟁Ꮚ㖠㛵ಀ࡛ࡣࠊ1 ᖺ 4 ࣨ᭶࡯࡝౑⏝
ࡋࡓ࢝ࢯ࣮ࢻࢆ 12 ᭶࡟࢝ࢯ࣮ࢻ஺᥮ࡋࡓࡀࠊ஺᥮࠿ࡽ⣙ 1 ࠿᭶ᚋ࡟୙ලྜࡀ⏕ࡌࡓࡓࡵࠊ෌ࡧ࢝ࢯ࣮
ࢻ஺᥮ࢆ⾜ࡗࡓࠋ෭༷Ỉ⿦⨨㛵ಀ࡛ࡣࠊ᫖ᖺᗘᮎ࡟ぢࡘ࠿ࡗࡓ୺ຍ㏿⟶ࡢ⢭ᐦ ㄪ⣔㓄⟶ࡢ₃Ỉࡢཎᅉ
― 124 ―
ࡀࠊ෭༷Ỉὶ㔞ㄪᩚ⏝࣮࣎ࣝࣂࣝࣈࡢࣆ࣮࡛ࣥ࣍ࣝ࠶ࡗࡓࡇ࡜࠿
ࡽࠊ௒ᅇࡣᙉᗘࢆ⪃࠼࡚ࢫࢸࣥࣞࢫ〇ࡢ࣮࣎ࣝࣂࣝࣈ࡟஺᥮ࡋࡓࠋ
ࡇࡢసᴗ࡟ྜࢃࡏ࡚ࠊ᫖ᖺᮎࡢసᴗ࡛஺᥮࡛ࡁ࡞࠿ࡗࡓࣇ࣮ࣟࢫ
࢖ࢵࢳ࡜ᮎ➃ࡢྂ࠸෭༷Ỉࣂࣝࣈࡢ஺᥮ࡶ⾜ࡗࡓࠋࡇࢀ௨እ࡟ࡣࠊ
8 ᭶࡟ࢡࣛ࢖ࢫࢺࣟࣥᐊ࡟タ⨨ࡉࢀ࡚࠸ࡿ෭༷⿦⨨ࡢ⇕஺᥮ჾ஺
᥮ᕤ஦ࢆࠊ9 ᭶࡟ CT3 ⣔ࡢࣇ࢕ࣝࢱ࣮஺᥮ࢆ⾜ࡗࡓࠋࡑࡢ௚ࡢᶵ
ჾ࡟ࡘ࠸࡚ࡣࠊ11 ᭶࡟Ⓨ⏕⿦⨨ᐊࡢ࢚࢔ࢥࣥࡢࣇ࢓ࣥ࣋ࣝࢺࢆ
஺᥮ࡋࡓࠋᖺ᫂ࡅ࡟ࡣࠊRF ⣔ࡢప㟁ຊ⛣┦ჾ࡟୙ලྜࡀ⏕ࡌࡓࠋ
⌧ᅾ࢚ࣥࢥ࣮ࢲࡢ௚࣓࣮࣮࢝࡬ࡢ஺᥮ࡸࠊ⛣┦ჾࡑࡢࡶࡢࡢ⨨ࡁ
᥮࠼ࢆ᳨ウࡋ࡚࠸ࡿࠋ୍᪉ࠊࢧࣈࣁ࣮ࣔࢽࢵࢡࣂࣥࢳ࣮ࣕࢩࢫࢸ
࣒ࢆ⏝࠸ࡓ༢ࣂࣥࢳ㟁Ꮚࣅ࣮࣒ࠊ࣐ࣝࢳࣂࣥࢳ㟁Ꮚࣅ࣮࣒ࡢᏳᐃ
໬ࡢࡓࡵ࡟ࠊᖹᡂ 22 ᖺᗘ࠿ࡽᖹᡂ 24 ᖺᗘ࡟࠿ࡅ࡚ 3 ྎࡢ༙ᑟయ
ࣃࣝࢫቑᖜჾࡀᑟධࡉࢀࡓࡀࠊᑟධᙜึ࠿ࡽ⥆ࡃᵝࠎ࡞୙ලྜ࡟
ᅗ 2 L ࣂࣥࢻࣛ࢖ࢼࢵࢡ฼⏝ᐇ⦼
ࡼࡾࠊᏳᐃ࡞ᐃᖖ㐠㌿࡟ࡣ⮳ࡗ࡚࠸࡞࠿ࡗࡓࠋ࠸ࢁ࠸ࢁࢺࣛࣈࣝ
ࢩ࣮ࣗࢸ࢕ࣥࢢࢆ⾜ࡗࡓ⤖ᯝࠊFET ࣘࢽࢵࢺࡢ ᗘ⿵ൾᅇ㊰࡟ၥ
㢟ࡀ࠶ࡿࡇ࡜ࡀࢃ࠿ࡾࠊᨵⰋࢆ⾜ࡗࡓࠋ௒ᚋᏳᐃ࡞ࢩࣥࢢ࣮ࣝࣔ
ࢻࠊ࣐ࣝࢳ࣮ࣔࢻ࡛ࡢ㐠㌿ࡀᮇᚅ࡛ࡁࡿࠋ㹐㹄㟁Ꮚ㖠㹑ࣂࣥࢻࣛ
࢖ࢼࢵࢡ࡟ࡘ࠸࡚ࡣࠊඹྠ฼⏝ເ㞟ࡣ⾜ࡗࡓࡀࠊᐇ㝿࡟ࡣ⛣タ‽
ഛࡢࡓࡵ㐠㌿ࡣ⾜ࢃࢀ࡞࠿ࡗࡓࠋ
ղ ࢥࣂࣝࢺ 60 ࣐࢞ࣥ⥺↷ᑕ⿦⨨
ࢥࣂࣝࢺ 60 ↷ᑕ᪋タࡢ฼⏝ㄢ㢟ᩘࡣ 21 ௳ࠊ฼⏝᪥ᩘࡣ 76 ᪥ࠊ
⥲฼⏝᫬㛫ࡣ 1,144 ᫬㛫࡛࠶ࡗࡓࠋ㸦ᅗ 3㸧
ճ ᨺᑕ⥺Ᏻ඲⟶⌮
⏘ᴗ⛉Ꮫ◊✲ᡤᨺᑕ⥺᪋タ࡟࠾ࡅࡿᨺᑕ⥺ᴗົᚑ஦⪅ᩘࡣ 133
ྡ࡛࠶ࡗࡓࠋࡇࡢෆࡢ 43 ྡ࡟ᑐࡋࠊ5 ᭶ 15 ᪥࡟ᩍ⫱カ⦎ࢆ⏘◊ㅮ
ᇽ࡛ᐇ᪋ࡋࡓࠋᖺ 2 ᅇࡢἲ௧࡛ᐃࡵࡿ᪋タ⮬୺Ⅼ᳨ࢆ⾜࠸ࠊᚲせ
࡞ฎ⨨ࢆ⾜ࡗࡓࠋ
࣭Ỉ⁐ᾮ୰ࡢ㓟໬άᛶ✀ࡢࣃࣝࢫࣛࢪ࢜ࣜࢩࢫ㐣Ώ࣐ࣛࣥศග
ᅗ 3 ࢥࣂࣝࢺ 60 ฼⏝ᐇ⦼
࣐ࣛࣥศගἲࡣศᏊᵓ㐀ࢆ᣺ື࡛ࣞ࣋ࣝほᐹࡍࡿࡇ࡜ࡀ࡛ࡁࡿࠋ▷
ᑑ࿨άᛶ✀ࢆᨺᑕ⥺໬Ꮫⓗ࡟㧗ᐦᗘ⏕ᡂࡉࡏࠊ୙ᆒ୍⣔࡞࡝」㞧࡞⣽⬊ෆ཯ᛂࡸᮦᩱ⏺㠃࡟࠾ࡅࡿ㐣Ώ
ศᏊ✀ࡢ᣺ືᵓ㐀ゎ᫂࡬ࡢⓎᒎࢆ┠ᣦࡋ࡚ࠊ࣏ࣥࣉග࡜ࡋ࡚㜰኱⏘◊ L ࣂࣥࢻࣛ࢖ࢼࢵࢡ࠿ࡽࡢ 8ns
㟁Ꮚ⥺ࣃࣝࢫࢆ⏝࠸ࡓࣃࣝࢫࣛࢪ࢜ࣜࢩࢫ᫬㛫ศゎ࣐ࣛࣥศග ᐃࢩࢫࢸ࣒ࢆᵓ⠏ࡋࡓࠋỈ⁐ᾮ୰⏕ᡂ
ࡍࡿ㓟໬άᛶ✀ࡢ⤖ྜ≧ែࢆඹ㬆࣐ࣛࣥศග࡟ࡼࡾ㑅ᢥⓗ࡟᳨ฟࡍࡿࡇ࡜࡟ᡂຌࡋࡓࠋ
࣭㝧㟁Ꮚ࡟ࡼࡿᮦᩱ◊✲ᅵተ࡟㝆ࡾὀ࠸ࡔᨺᑕᛶࢭࢩ࣒࢘ࡣ≉࡟⢓ᅵ㖔≀ࠊ≉࡟ࣂ࣮࣑࢟ࣗࣛ࢖ࢺෆ࡟
⵳✚ࡉࢀࡿࡇ࡜ࡀࢃ࠿ࡗ࡚ࡁ࡚࠸ࡿࠋఱᨾࣂ࣮࣑࢟ࣗࣛ࢖ࢺ࡞ࡢ࠿ࡣࠊෆໟࡍࡿࣇࣞ࢖ࢻ࢚ࢵࢪࢧ࢖ࢺ
࡜࿧ࡤࢀࡿḞ㝗࡟ᤕᤊࡉࢀࡿࡓࡵࡔ࡜⪃࠼ࡽࢀ࡚࠸ࡿࡀࠊࡲࡔࡣࡗࡁࡾ࡜ࡣࢃ࠿ࡗ࡚࠸࡞࠸ࠋࡇࡢࡼ࠺
࡞㖔≀࡟࠾ࡅࡿḞ㝗ࡢ㐪࠸ࢆㄪ࡭ࡿࡓࡵ㝧㟁Ꮚᾘ⁛ἲࢆ⏝࠸࡚ㄪ࡭ࡓ⤖ᯝࠊ㏻ᖖḞ㝗ࡢ኱ࡁࡉࢆㄪ࡭ࡿ
┠Ᏻ࡜ࡍࡿ࢜ࣝࢯ࣏ࢪࢺࣟࢽ࣒࢘ࡢ⏕ᡂ㔞ࡢᑡ࡞ࡃࠊ≉࡟ྠ✀ࡢ㖔≀㛫㸦2:1㖔≀㸧࡛ࡣࡑࡢᑑ࿨࡟኱ࡁ
࡞ᕪࡣぢࡽࢀ࡞࠿ࡗࡓࠋࡋ࠿ࡋࠊᾘ⁛Ț⥺㸰ගᏊྠ᫬ ᐃ࡛ࡣ㖔≀㛫ࡢᕪࡀぢࡽࢀࡓࠋࡲࡓࠊ࣏ࣜࢸࢺ
ࣛࣇ࢚ࣝ࢜ࣟࢳࣞࣥ㸦PTFE㸧ࡢ⁐⼥᫬࡟࠾ࡅࡿᵓ㐀ኚ໬ࢆ㝧㟁Ꮚᾘ⁛ἲ࡛ㄪ࡭ࡓ⤖ᯝࠊ㝧㟁Ꮚᾘ⁛ἲ࡛
ࡣ ᗘኚ໬࡟క࠺࢔ࣔࣝࣇ࢓ࢫ㒊ศࡢᵓ㐀ኚ໬࡜ᬗ㉁㒊⾲㠃ࡢᵓ㐀ኚ໬ࡢᵝᏊࢆㄪ࡭ࡿࡇ࡜ࡀྍ⬟࡛࠶
ࡿࡇ࡜ࡀࢃ࠿ࡗࡓࠋ
― 125 ―
⏘ᴗ⛉Ꮫ㐃ᦠᩍ⫱᥎㐍ࢭࣥࢱ࣮
ࢭࣥࢱ࣮㛗㸦ව௵㸧ᩍᤵ
ᩍ⫱㐃ᦠ᥎㐍ᐊ㛗㸦ව௵㸧ᩍᤵ
ᐊဨ㸦ව௵㸧ᩍᤵ
ᐊဨ㸦ව௵㸧෸ᩍᤵ
ᐊဨ㸦ව௵㸧෸ᩍᤵ
⏘Ꮫ࣭ᅜ㝿㐃ᦠ᥎㐍ᐊ㛗㸦ව௵㸧ᩍᤵ
ᐊဨ㸦ව௵㸧ᩍᤵ
ᐊဨ㸦ව௵㸧෸ᩍᤵ
ᐊဨ㸦ව௵㸧ຓᩍ
ྜྷ⏣
➉⏣
㮖ᑿ
℩ᕝ
⃝
Ᏻ⸨
┿ᔱ
⚄ྜྷ
᳃ᒣ
㝧୍
⢭἞
㝯
⪔ྖ
ᚸ
㝧୍
ဴ㑻
㍤ኵ
⏥୍
ᴫせ
⏘◊ࡣࠊ㐃ᦠࡍࡿ 6 ࡘࡢ◊✲⛉࠿ࡽᏛ⏕ࢆཷࡅධࢀࡿ࡜࠸࠺ࣘࢽ࣮ࢡ࡞≉ᚩࡀ࠶ࡾࠊ⏘◊࡜ࡋ࡚ࡢඹ
㏻ࡢᏛ㝿ᩍ⫱ࢆ᪋ࡍࡇ࡜ࡀࠊ⏘◊࡟࠾ࡅࡿᏛ㝿⼥ྜᆺ◊✲ࢆ᥎ࡋ㐍ࡵࡿࡓࡵ࡟ࡶᚲせ࡛࠶ࡿࠋ
ࡑࡇ࡛ࠊ⏘◊࡟ᡤᒓࡍࡿᏛ⏕඲యࢆᑐ㇟࡜ࡋࡓᏛ㝿ᩍ⫱ࡢ௻⏬❧᱌࣭ᐇ᪋ࢆ୺ࡓࡿ┠ⓗ࡜ࡍࡿ㐃ᦠᩍ
⫱᥎㐍ࢭࣥࢱ࣮ࢆᖹᡂ 21 ᖺ 4 ᭶࡟タ⨨ࡋࡓࠋ
㐃ᦠᩍ⫱᥎㐍ࢭࣥࢱ࣮࡛ࡣࠊ᪂ே࢚࢜ࣜࣥࢸ࣮ࢩࣙࣥࠊᢏ⾡⩦ᚓࢫࢡ࣮ࣜࣥࢢࠊ௻ᴗ࢖ࣥࢱ࣮ࣥࢩࢵ
ࣉࠊᏛ⏕ᾏእὴ㐵࣭ཷධࣉࣟࢢ࣒ࣛ࡞࡝ࠊከᙬ࡞ᩍ⫱άືࢆ௻⏬࣭ᐇ⾜ࡍࡿ࡜࡜ࡶ࡟ࠊ඲Ꮫ࡟᪂タࡉࢀ
ࡓࢼࣀࢧ࢖࢚ࣥࢫ࣭ࢹࢨ࢖ࣥᩍ⫱◊✲ࢭࣥࢱ࣮࡜ᐦ᥋࡟㐃ᦠࡋࠊࢼࣀࢧ࢖࢚ࣥࢫ๪ࣉࣟࢢ࣒ࣛᩍ⫱➼ࡢ
ᩍ⫱άືࢆ❧᱌࣭ᐇ⾜ࡋ࡚࠸ࡿࠋ
― 126 ―
ᅜ㝿ඹྠ◊✲ࢭࣥࢱ࣮
ᴫせ
ᅜ㝿ඹྠ◊✲ࢭࣥࢱ࣮ࡣࠊᅜ㝿஺ὶ࡟࠾ࡅࡿᣢ⥆ⓗ࡞ேᮦ஺ὶ࡜ᅜ㝿ඹྠ◊✲ࢆ᥎㐍ࡍࡿࡓࡵ࡟ࠊ
2009 ᖺ 4 ᭶࡟⏘◊ෆ࡟タ⨨ࡉࢀࡓࠋᮏࢭࣥࢱ࣮ࡣࠊᅜ㝿஺ὶࢆ⾜࠺኱Ꮫ࣭◊✲ᶵ㛵➼࡜ࡢ㛫࡟タ❧ࡋࡓ
」ᩘࡢ㐃ᦠ◊✲ࣛ࣎⩌࠿ࡽᵓᡂࡉࢀࡿࠋྛࣛ࣎࡟ࡣව௵ᩍᤵࠊව௵ᩍဨⱝᖸྡࢆ㓄⨨ࡋࠊࡉࡽ࡟┦ᡭ
ഃ࠿ࡽࡢ◊✲⪅ࢆᐈဨ◊✲ဨ࡜ࡋ࡚ཷࡅධࢀࡿࡇ࡜ࡀ࡛ࡁࡿࠋ
⌧ᅾࠊ8 ࡘࡢ㐃ᦠ◊✲ࣛ࣎ࡀタ⨨ࡉࢀ࡚࠸ࡿࠋ୰ᅜ࣭໭ி኱Ꮫ᝟ሗ⛉ᏛᏛ㝔࡜ࡢ㛫ࡢ᝟ሗࢥ࣑ࣗࢽࢣ
࣮ࢩࣙࣥᢏ⾡㸦ICT㸧㐃ᦠ◊✲ࣛ࣎ࡣࠊ2009 ᖺ࡟᝟ሗ࡜ࢥ࣑ࣗࢽࢣ࣮ࢩࣙࣥᢏ⾡࡟㛵ࡍࡿ㐃ᦠ◊✲ࢆ⾜
࠺┠ⓗ࡛ࠊඵᮌᩍᤵࢆࣛ࣎㛗࡜ࡋ࡚タ⨨ࡉࢀࡓࠋICT 㐃ᦠ࡛ࣛ࣎ࡣࠊࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ࡜࣓ࢹ࢕࢔
ฎ⌮࡟㛵ࡍࡿᇶ♏◊✲࠿ࡽᛂ⏝◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋ㡑ᅜ࣭㧗㯇኱Ꮫᰯ⛉Ꮫᢏ⾡኱Ꮫ࠾ࡼࡧ㡑ᅜ࣭ᾆ㡯
ᕤ⛉኱Ꮫᰯ⎔ቃᕤᏛ㒊࡜ࡢ㛫ࡢඛ➃ᮦᩱ◊✲㸦AMR㸧࠾ࡼࡧගᛂ⟅≀㉁⛉Ꮫ◊✲(PMR)㐃ᦠ◊✲ࣛ࣎ࡣࠊ
┿ᔱᩍᤵࢆࣛ࣎㛗࡜ࡋࠊඛ➃ᮦᩱ⛉Ꮫ◊✲࠾ࡼࡧගᛂ⟅≀㉁⛉Ꮫ◊✲࡟㛵㐃ࡍࡿ㐃ᦠ◊✲ࣛ࣎ࢆྛࠎ
ࡢᶵ㛵ෆ࡟タ⨨ࡋࠊάⓎ࡞┦஫ゼၥࠊᅾ⡠࡟ࡼࡗ࡚㐃ᦠ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋⱥᅜ࣭University College
London ᩘ⌮⛉Ꮫ㒊࡜ࡢ㛫ࡢບ㉳⾲㠃⛉Ꮫ㸦ESS㸧㐃ᦠ◊✲ࣛ࣎ࡣࠊ㇂ᮧᩍᤵࢆࣛ࣎㛗࡜ࡋࠊᅛయ⾲㠃࡟
࠾ࡅࡿගㄏ㉳ᵓ㐀ኚ໬࡜᪂≀㉁┦๰〇࡟㛵ࡋ⌮ㄽ࡜ᐇ㦂ࡢ཮᪉࠿ࡽࡢඹྠ◊✲ࢆ᥎㐍ࡋ࡚࠸ࡿࠋ࣐ࢽ
࣭ࣛࢹ࣭࣭ࣛࢧ࣮ࣝ኱Ꮫ࡜ࡢ㛫ࡢ᝟ሗࢥ࣑ࣗࢽࢣ࣮ࢩࣙࣥᢏ⾡(ICT)㐃ᦠ◊✲ࣛ࣎ࡣࠊ἟ᑿᩍᤵࢆࣛ࣎
㛗࡜ࡋࠊ࢔ࢪ࢔ࡢᅜࠎ࡛ࡢᕷሙ㛤ᣅ࡜ᩍ⫱࡟㈨ࡍࡿࢭࣥࢩࣥࢢᢏ⾡࡜ࡋ࡚ࠊேࡢඹឤ࡟ࡘ࠸࡚ࡢᶵᲔ
Ꮫ⩦ࢆ◊✲ࡋ࡚࠸ࡿࠋ⏕యࢭࣥࢧ➼ࢆ㥑౑ࡋࡓඹྠ◊✲ࢆ᥎㐍୰࡛࠶ࡿࠋࢻ࢖ࢶ࣭࢔࣮࣊ࣥᕤ⛉኱Ꮫ࠾
ࡼࡧࢻ࢖ࢶ࣭ࣅ࣮ࣞࣇ࢙ࣝࢺ኱Ꮫ࡜ࡢ㛫ࡢ᭷ᶵྜᡂ໬Ꮫ㸦SOC㸧㐃ᦠ◊✲ࣛ࣎ࡣࠊ࠸ࡎࢀࡶ 2012 ᖺ࡟
➲஭ᩍᤵࢆࣛ࣎㛗࡜ࡋ࡚タ⨨ࡉࢀࡓࠋ⎔ቃㄪ࿴ᆺඛ㐍ศᏊኚ᥮ᢏ⾡ࡢ㛤Ⓨ࡜ᛂ⏝ࢆᒎ㛤୰࡛࠶ࡿࠋ㡑
ᅜ࣭㡑ᅜཎᏊຊ◊✲ᡤඛ➃ᨺᑕ⥺ᢏ⾡◊✲ᡤ࡜ࡢ㛫ࡢ㔞Ꮚࣅ࣮࣒⛉Ꮫ㸦QBS㸧㐃ᦠ◊✲ࣛ࣎ࡣࠊ㔞Ꮚࣅ
࣮࣒ࡢⓎ⏕࡜฼⏝࡟㛵ࡍࡿඛ➃◊✲ࢆ⾜࡞࠺ࡓࡵ 2014 ᖺ࡟☾ᒣᩍᤵࢆࣛ࣎㛗࡜ࡋ࡚タ❧ࡉࢀࡓࠋ⏘◊
ࡢ௒ᚋࡢᅜ㝿ඹྠ◊✲ࡢ㐍ᒎ࡟ᚑ࠸ࠊᅜ㝿ඹྠ◊✲ࢭࣥࢱ࣮ࡢ㐃ᦠ◊✲ࣛ࣎ᩘࢆቑࡸࡍࡇ࡜ࢆணᐃࡋ
࡚࠸ࡿࠋ
໭ி኱Ꮫ-ICT ࣛ࣎
1. 㸱ḟඖ᚟ඖ࡜㊥㞳ィ 2. ⏬ീࡢࢭࢢ࣓ࣥࢸ࣮ࢩࣙࣥ࡜≀య᳨ฟ
3. ே㐠ືゎᯒ࡜ே≀ㄆ㆑
㧗㯇኱Ꮫ-AMR ࣛ࣎
1. ගᛂ⟅ᛶ≀㉁ࡢ㧗㏿࢚ࢿࣝࢠ࣮࣭㟁Ꮚ⛣ື
2. ⨨᥮࢝ࣝ࣎ࣛࣥࡢ㓟໬㑏ඖ཯ᛂ
3. ኴ㝧ග࢚ࢿࣝࢠ࣮ኚ᥮≀㉁
ᾆ㡯ᕤ⛉኱Ꮫᰯ-PMR ࣛ࣎
1. 㓟໬ࢳࢱࣥගゐ፹
2. ྍどගᛂ⟅ᆺගゐ፹
3. ගゐ፹࡟ࡼࡿேᕤගྜᡂ
UCL-ESS ࣛ࣎
1. ࢢࣛࣇ࢓࢖ࢺ࠾ࡼࡧ㔠༢⤖ᬗ࡟࠾ࡅࡿ࣮ࣞࢨ࣮ㄏ㉳ᵓ㐀┦㌿⛣
2. ࢩࣜࢥࣥ⾲㠃㟁Ꮚ≧ែࡢ➨୍ཎ⌮ィ⟬࡟ࡼࡿ◊✲
3. ບ㉳≧ែ➨୍ཎ⌮ศᏊືຊᏛⓗᡭἲࡢ㛤Ⓨ◊✲
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ࢹ࣭࣭ࣛࢧ࣮ࣝ኱Ꮫ-ICT ࣛ࣎
1. ඹឤィ⟬(Empathic Computing)
2. ⏕యィ ࡸ Kinnect ➼ࡢྛ✀ࢭࣥࢧࢆ⏝࠸ࡓ࣮ࣘࢨࡢࣔࢹࣝ໬
3. 㐺ᛂ࢖ࣥࢱࣇ࢙࣮ࢫ࡜ᶵᲔᏛ⩦
࢔࣮࣊ࣥᕤ⛉኱Ꮫ-SOC ࣛ࣎
1. ࢚ࢼࣥࢳ࢜㑅ᢥⓗ᭷ᶵศᏊゐ፹
2. 㑄⛣㔠ᒓゐ፹཯ᛂ
3. ࢻ࣑ࣀࣉࣟࢭࢫࡢ㛤Ⓨ
ࣅ࣮ࣞࣇ࢙ࣝࢺ኱Ꮫ-SOC ࣛ࣎
1. ⏕యゐ፹࡜ศᏊゐ፹ࡢࣁ࢖ࣈࣜࢵࢻ໬
2. ࢚ࢼࣥࢳ࢜㑅ᢥⓗゐ፹ࡢᅛᐃ໬
3. ᪂つⅣ⣲ʊⅣ⣲⤖ྜ⏕ᡂ཯ᛂࡢ㛤ᣅ
㡑ᅜཎᏊຊ◊✲ᡤQBS ࣛ࣎
1. ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫἲ࡟ࡼࡿᨺᑕ⥺໬Ꮫࡢ◊✲
2. ຍ㏿ჾࢆ⏝࠸ࡓඛ➃㔞Ꮚࣅ࣮࣒ࡢⓎ⏕࡜฼⏝◊✲
3. 㔞Ꮚࣅ࣮࣒ࢆ⏝࠸ࡓ≀㉁࣭ᮦᩱ⛉Ꮫ
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㝃⨨◊✲ᡤ㛫࢔ࣛ࢖࢔ࣥࢫ࡟ࡼࡿࢼࣀ࡜࣐ࢡࣟࢆࡘ࡞ࡄ≀㉁࣭ࢹࣂ࢖ࢫ࣭ࢩ
ࢫࢸ࣒๰〇ᡓ␎ࣉࣟࢪ࢙ࢡࢺ
ᴫせ
ᮏ࢔ࣛ࢖࢔ࣥࢫࡢ┠ⓗࡣࠊḟୡ௦࢚ࣞࢡࢺࣟࢽࢡࢫࠊ࢚ࢿࣝࢠ࣮ࠊ་⒪ࠊ⎔ቃㄪ࿴ᮦᩱࡢࠕ≀㉁࣭ࢹ
ࣂ࢖ࢫ࣭ࢩࢫࢸ࣒๰〇ᇶ┙ᢏ⾡ࠖࢆࠕࢼࣀ࡜࣐ࢡࣟࡢ⼥ྜࠖ࡟ࡼࡾ◊✲࣭㛤Ⓨࡍࡿࡇ࡜࡛࠶ࡿࠋ≀㉁࣭
ࢹࣂ࢖ࢫ࣭ࢩࢫࢸ࣒ᇶ┙ᢏ⾡ࡣࠊᏳ඲Ᏻᚰ࡛㉁ࡢ㧗࠸⏕άࡢ࡛ࡁࡿ♫఍ࡢᐇ⌧࡟ᚲ㡲࡛࠶ࡾࠊ≀㉁㺃ࢹ
ࣂ࢖ࢫ◊✲࡟࠾࠸࡚㇏ᐩ࡞ᐇ⦼ࢆ᭷ࡍࡿ㸳㝃⨨◊✲ᡤࡀࠊᚓពࡢศ㔝࡛ᡓ␎ⓗ࡟㐃ᦠࢆ⤌ࡳࠊࢿࢵࢺ࣡
࣮ࢡᆺඹྠ◊✲ࢆ᥎㐍ࡍࡿ஦࡟ࡼࡾ≀㉁࣭ࢹࣂ࢖ࢫ࣭ࢩࢫࢸ࣒๰〇◊✲ࡢ᱁ẁࡢ㐍ᒎࢆᅗࡿࡶࡢ࡛࠶ࡿࠋ
ᮏ࢔ࣛ࢖࢔ࣥࢫ࡛ࡣࠊ໭ᾏ㐨኱Ꮫ㟁Ꮚ⛉Ꮫ◊✲ᡤ㸦㟁Ꮚ◊㸧ࠊᮾ໭኱Ꮫከඖ≀㉁⛉Ꮫ◊✲ᡤ㸦ከඖ◊㸧ࠊ
ᮾிᕤᴗ኱Ꮫ㈨※໬Ꮫ◊✲ᡤ㸦㈨※◊㸧ࠊ኱㜰኱Ꮫ⏘ᴗ⛉Ꮫ◊✲ᡤ㸦⏘◊㸧ࠊ஑ᕞ኱Ꮫඛᑟ≀㉁໬Ꮫ◊✲
ᡤ㸦ඛᑟ◊㸧ࡢ㸳㝃⨨◊✲ᡤᶓ᩿࡛ࠊ
㸦㹅㸯㸧ḟୡ௦࢚ࣞࢡࢺࣟࢽࢡࢫࠊ
㸦㹅㸰㸧᪂࢚ࢿࣝࢠ࣮ᮦᩱ࣭ࢹ
ࣂ࢖ࢫࠊ
㸦㹅㸱㸧་⒪ᮦᩱ࣭ࢹࣂ࢖ࢫ࣭ࢩࢫࢸ࣒ࠊ
㸦㹅㸲㸧⎔ቃㄪ࿴ᮦᩱ࣭ࢹࣂ࢖ࢫ࡟㛵ࡍࡿ◊✲ࢢ࣮ࣝ
ࣉࢆ⤌⧊ࡋࠊᡓ␎ⓗࣉࣟࢪ࢙ࢡࢺ◊✲ࢆ᥎㐍ࡋ࡚࠸ࡿࠋྛ◊✲ᡤ࡟࠾ࡅࡿ㛗ᮇᅾ◊✲ࠊேᮦࡢ஺ὶ࣭
ࢩ࢙࢔ࣜࣥࢢࠊ⿦⨨࣭ሙᡤࡢࢩ࢙࢔ࣜࣥࢢ࡟ࡼࡾࠊຠ⋡ⓗ࡟ࣉࣟࢪ࢙ࢡࢺ◊✲ࡢ᥎㐍ࢆ⾜ࡗ࡚࠸ࡿࠋࡲ
ࡓࠊ࢔ࣛ࢖࢔ࣥࢫ㐃ᦠ◊✲ࡢᡂᯝࡢ♫఍㑏ඖࡢࡓࡵ࡟ࠊ⏘◊࢖࣮ࣥ࢟ࣗ࣋ࢩࣙࣥᲷࢆ✚ᴟⓗ࡟฼⏝ࡋࠊ
≀㉁࣭ࢹࣂ࢖ࢫ࣭ࢩࢫࢸ࣒๰〇ᇶ┙ᢏ⾡ࢆ᱁ẁ࡟㐍ᒎࡉࡏࠊᐇ⏝໬ࢆ┠ᣦࡋࡓ⏘ᴗᛂ⏝࡟⧅ࡆࡿࡇ࡜ࢆ
┠ᣦࡍࠋࡇࢀ࡟ࡼࡾᏳ඲Ᏻᚰ࡛㉁ࡢ㧗࠸⏕άࡢ࡛ࡁࡿ♫఍ᐇ⌧࡬ࡢ኱ࡁ࡞ᐤ୚࡜࡜ࡶ࡟ࠊࢼࣀ࡜࣐ࢡࣟ
⼥ྜࡢ᪂Ꮫ⾡ศ㔝ࡢ๰ᡂࢆᐇ⌧ࡍࡿࠋ
ᮏ࢔ࣛ࢖࢔ࣥࢫࡣࠊ㸳㝃⨨◊✲ᡤ࠿ࡽ࡞ࡿ㐠Ⴀጤဨ఍࡟ࡼࡾ㐠Ⴀࡉࢀ࡚࠾ࡾࠊ⏘◊࠿ࡽࡢᖹᡂ 26 ᖺ
ᗘ㐠Ⴀጤဨࡣࠊ⏣୰⚽࿴ᩍᤵ㸦๪㐠Ⴀጤဨ㛗㸧ࠊඵᮌᗣྐᩍᤵࠊᑠཱྀከ⨾ኵᩍᤵ࡛࠶ࡿࠋࡲࡓࠊྛ◊✲
ࢢ࣮ࣝࣉࡢ࣓ࣥࣂ࣮㸦H26.4 ᫬Ⅼ㸧ࡣḟࡢ㏻ࡾ࡛࠶ࡿࠋ
㸦㹅㸯㸧ࠕḟୡ௦࢚ࣞࢡࢺࣟࢽࢡࢫࠖ◊✲ࢢ࣮ࣝࣉ㸦㸷ྡ㸧
ᯇᮏ࿴ᙪ ᩍᤵ㸦ࢢ࣮ࣝࣉ㛗㸧ࠊᏳ⸽ⰾ㞝 ᩍᤵࠊᏳ⸨㝧୍ ᩍᤵࠊᑠཱྀከ⨾ኵ ᩍᤵࠊ
⏣୰⚽࿴ ᩍᤵࠊ㮖ᑿ 㝯 ᩍᤵࠊ኱ᒾ㢧 ᩍᤵࠊ㛵㇂Ẏ ᩍᤵࠊᰗ⏣ ๛ ෸ᩍᤵ
㸦㹅㸰㸧ࠕ᪂࢚ࢿࣝࢠ࣮ᮦᩱ࣭ࢹࣂ࢖ࢫࠖ◊✲ࢢ࣮ࣝࣉ㸦㸵ྡ㸧
ᑠᯘග ᩍᤵ㸦ࢢ࣮ࣝࣉ㛗㸧ࠊⳢ἟ඞ᫛ ᩍᤵࠊ➉⏣⢭἞ ᩍᤵࠊ㇂ᮧඞᕫ ᩍᤵࠊ
἟ᑿṇ⾜ ᩍᤵࠊ㄃⏣⩏ⱥ ෸ᩍᤵࠊ㕥ᮌ೺அ ෸ᩍᤵ
㸦㹅㸱㸧ࠕ་⒪ᮦᩱ࣭ࢹࣂ࢖ࢫ࣭ࢩࢫࢸ࣒ࠖ◊✲ࢢ࣮ࣝࣉ㸦㸯㸮ྡ㸧
୰㇂࿴ᙪ ᩍᤵ㸦ࢢ࣮ࣝࣉ㛗㸧ࠊຍ⸨ಟ㞝 ᩍᤵࠊᒣཱྀ᫂ே ≉௵ᩍᤵࠊඵᮌᗣྐ ᩍᤵࠊ
㇂ཱྀṇ㍤ ᩍᤵࠊỌ஭೺἞ ᩍᤵࠊ㥖㇂࿴⠊ ᩍᤵࠊᒸᓥಇⱥ ෸ᩍᤵࠊす Ẏ ෸ᩍᤵࠊ
す㔝㑥ᙪ ෸ᩍᤵ
㸦㹅㸲㸧ࠕ⎔ቃㄪ࿴ᮦᩱ࣭ࢹࣂ࢖ࢫࠖ◊✲ࢢ࣮ࣝࣉ㸦㸴ྡ㸧
ྜྷ⏣㝧୍ ᩍᤵ㸦ࢢ࣮ࣝࣉ㛗㸧ࠊ┿ᔱဴᮁ ᩍᤵࠊ➲஭ᏹ᫂ ᩍᤵࠊ☾ᒣᝅᮁ ᩍᤵࠊ
ྂ⃝Ꮥᘯ ᩍᤵࠊ㛵㔝ᚭ ᩍᤵ
― 129 ―
ࠕḟୡ௦࢚ࣞࢡࢺࣟࢽࢡࢫࠖ◊✲ࢢ࣮ࣝࣉ
ᩍᤵ㸦ව௵㸧
෸ᩍᤵ㸦ව௵㸧
ᯇᮏ ࿴ᙪ㸦ࢢ࣮ࣝࣉ㛗㸧ࠊ⏣୰ ⚽࿴ࠊ➉㇂ ⣧୍ࠊ㮖ᑿ 㝯ࠊ
Ᏻ⸨ 㝧୍ࠊᏳ⸽ ⰾ㞝ࠊᑠཱྀ ከ⨾ኵࠊ኱ᒾ 㢧ࠊ㛵㇂ Ẏ
ᰗ⏣ ๛
a) ᴫせ
᪂ᶵ⬟ࢼࣀ࢚ࣞࢡࢺࣟࢽࢡࢫࢢ࣮ࣝࣉ࡛ࡣࠊୗグ࡟♧ࡍࡼ࠺࡟༙ᑟయࢆ୺࡞⣲ᮦ࡜ࡋࠊࡑࡢᮦᩱホ౯ࠊ
≀ᛶホ౯ࠊࢹࣂ࢖ࢫ≉ᛶホ౯ࡢ◊✲ࢆ୰ᚰ࡟⾜ࡗࡓࠋ
❅໬≀༙ᑟయࢆ࣮࣋ࢫ࡜ࡋࡓᐊ ㏱᫂Ⓨගᙉ☢ᛶ༙ᑟయࢆ๰〇࣭㛤Ⓨࡋࠊ᪂つ༙ᑟయࢼࣀࢫࣆࣥࢺࣟ
ࢽࢡࢫࢹࣂ࢖ࢫࡢ๰〇ࢆ┠ᣦࡋࡓ◊✲ࢆ⾜ࡗࡓࠋ㸦ᮅ᪥㸧
࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈࡢᚤ⣽࡞≉㛗ࢆ฼⏝ࡋࡓࢼࣀࢹࣂ࢖ࢫࠊ㔞Ꮚࢹࣂ࢖ࢫࡢ◊✲㛤Ⓨ࡜࡜ࡶ࡟ࠊᐇ
⏝໬ࢆ┠ᣦࡋࡓࢼࣀࢳ࣮ࣗࣈࣂ࢖࢜ࢭࣥࢧ࣮ࡢ㛤Ⓨࢆ⾜ࡗ࡚࠸ࡿࠋࡉࡽ࡟ࢢࣛࣇ࢙ࣥࡢ㧗㟁Ꮚ⛣ືᗘࢆ
฼⏝ࡋ࡚㑅ᢥⓗࣂ࢖࢜ࢭࣥࢧ࣮ࢆ㛤Ⓨࡋࡓࠋ㸦ᯇᮏ㸧
ศᏊࢼࣀ࢚ࣞࢡࢺࣟࢽࢡࢫ࡟ྥࡅࠊ༢ศᏊ࡟ග࣭㟁Ꮚ࣭☢Ẽ࡞࡝ࡢ」ྜᶵ⬟㞟✚ࢆᅗࡗࡓࢼࣀඹᙺศ
Ꮚࡢ㛤Ⓨ࡜༢ศᏊࢹࣂ࢖ࢫࡢ๰〇ࢆ⾜ࡗ࡚࠸ࡿࠋ㸦Ᏻ⸽㸧
㠀ᖖ࡟㧗 ࡛ᕧ኱≀ᛶࢆⓎ⌧ࡍࡿᶵ⬟ᛶ㓟໬≀࡟࠾࠸࡚ࠊ␗࡞ࡿᶵ⬟ࢆᣢࡘ≀㉁ࢆ⤌ࡳྜࢃࡏࡿࠕ࣊
ࢸࣟᵓ㐀ࠖࠊ᱁ẁ࡟ᑠࡉ࡞ࠕࢼࣀ࣊ࢸࣟᵓ㐀ࠖ࡟ࡼࡾࠊ≀ᛶⓎ⌧ࡢ※࡛࠶ࡿ㟁Ꮚ┦㛵ไᚚࢆ㏻ࡌᕧ኱≀
ᛶࢆไᚚࡍࡿ㓟໬≀ࢼࣀ࢚ࣞࢡࢺࣟࢽࢡࢫࡢᵓ⠏ࢆ⾜ࡗ࡚࠸ࡿࠋ㸦⏣୰㸧
ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࡸࢺ࣏ࣟࢪ࢝ࣝ㉸ఏᑟయࢆᑐ㇟࡟ࠊ㧗ရ㉁༢⤖ᬗస〇࠿ࡽ≀ᛶゎ᫂ࡲ࡛ࢆ୍㈏ࡋ
࡚⾜࠸ࠊ㠉᪂ⓗ࡞㔞Ꮚᶵ⬟ࢹࣂ࢖ࢫࡢືసཎ⌮ࡢ㛤ᣅࢆ⾜ࡗ࡚࠸ࡿࠋᮏᖺᗘࡣࠊࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య࣭
㉸ఏᑟయࡢ≀ᛶゎ᫂࡜ࠊඃࢀࡓ≉ᛶࢆ♧ࡍ᪂≀㉁ࡢ㛤Ⓨ࡟ὀຊࡋࡓࠋ
㸦Ᏻ⸨㸧
ሬᕸ࣭༳ๅἲ࡟ࡼࡗ࡚ࠊከᩘࡢ᭷ᶵ༙ᑟయࡢ༢⤖ᬗⷧ⭷ࢆ୍ᗘ࡟స〇ࡍࡿ᪉ἲࢆ㛤Ⓨࡋࠊᚑ᮶ࡢᛶ⬟
ࢆ㸯ࢣࢱୖᅇࡿ࢔ࢡࢸ࢕ࣈ࣐ࢺࣜࢵࢡࢫࣃࢿࣝࡢ〇సཬࡧᾮᬗࢹ࢕ࢫࣉࣞ࢖ࡢ㥑ື࡟ᡂຌࡋࡓࠋ
㸦➉㇂㸧
➨୍ཎ⌮ィ⟬࡟ᇶ࡙ࡁ≀ᛶࡢⓎ⌧ᶵᵓࡢゎ᫂࡟㛵ࡍࡿ◊✲ࢆ㐍ࡵ࡚࠸ࡿࠋ㑄⛣㔠ᒓከᒙ⭷࡟ᑐࡍࡿ⤖
ᬗ☢Ẽ␗᪉ᛶࠊ࣐ࣝࢳࣇ࢙ࣟ࢖ࢵࢡ≀㉁࡟࠾ࡅࡿ㟁Ẽ☢Ẽຠᯝ࡟ࡘ࠸࡚◊✲ࢆ㐍ࡵࡓࠋ㸦ᑠཱྀ㸧
㔞Ꮚ᝟ሗᐇ㦂࡟࠾ࡅࡿ᮲௳ኚ໬࡟ᑐࡋ࡚ࠊ㔞Ꮚ≧ែࢆ୙ኚ࡞㒊ศ࡜ኚ໬ࡍࡿ㒊ศ࡟ศ㞳᥎ᐃࡍࡿᡭἲ
࡟ࡘ࠸୍࡚ᒙࡢ㧗⢭ᗘ໬ࢆ⾜࠺◊✲ࢆ㐍ࡵࡓࠋ
㸦㮖ᑿ㸧
b) ᡂᯝ
࣭ᐊ Ⓨගᙉ☢ᛶ❅໬≀༙ᑟయࡢ๰〇࣭≉ᛶྥୖ࡜ࢼࣀᵓ㐀ࡢస〇
GaDyN/AlGaN MQW ᵓ㐀ࢆᡂ㛗ࡋࠊᐊ ᙉ☢ᛶࠊPL Ⓨගࢆほ ࡋࠊGaDyN ༢ᒙࡼࡾᙉ࠸㣬࿴☢໬ࢆ
♧ࡋࡓࠋGaGdN ࢼࣀࣟࢵࢻᵓ㐀࡟࠾࠸࡚ᙧ≧☢Ẽ␗᪉ᛶ࡟ࡼࡿ㠃ᆶ┤᪉ྥ☢໬ࡢቑ኱ࢆᐇ⌧ࡋࡓࠋ
InGaGdN/GaN ከ㔜㔞Ꮚࢹ࢕ࢫࢡᵓ㐀ࡢᡂ㛗࡟ᡂຌࡋࡓࠋࢺࣥࢿࣝ☢Ẽ᢬ᢠຠᯝ⣲Ꮚ⏝ GaDyN/GaN ஧㔜
㞀ቨᵓ㐀ࢆᡂ㛗ࡋࠊྛᒙࡢཌࡉ࡜☢ᛶࡢ㛫࡟┦㛵ࡢ࠶ࡿࡇ࡜ࢆศ࠿ࡗࡓࠋ
࣭࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈࢆ⏝࠸ࡓ㔞Ꮚࢼࣀ࣓ࣔࣜ
࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈࡢᚤ⣽┤ᚄࢆ฼⏝ࡍࡿ࡜ࠊ㟁⏺㞟୰ࡀ⏕ࡌࡿࡇ࡜ࢆ฼⏝ࡋࠊࢼࣀࢳ࣮ࣗࣈࡢ࿘
㎶࡟❅໬ࢩࣜࢥࣥ㸭㓟໬ࢩࣜࢥࣥࡢ㸰ᒙㄏ㟁య⭷ࢆᙧᡂࡋࠊࢤ࣮ࢺ㟁ᴟࢆᙧᡂࡍࡿ஦࡟ࡼࡾࠊᚑ᮶ࡢᖹ
㠃ᵓ㐀ࡢ 1/10 ࡢ 2V ࡢ᭩ࡁ㎸ࡳ㸭ㄞࡳฟࡋ㟁ᅽࢆᐇ⌧ࡋࡓࠋࡲࡓཎᏊᒙሁ✚ἲࢆ⏝࠸࡚ 10nm ࡢࢤ࣮ࢺ
㛗ࢆᐇ⌧ࡋࠊ༢୍ࡢ㟁Ⲵࡢ࣓ࣔࣜຠᯝࢆᐊ ᳨࡛ฟࡋࡓࠋ
࣭ࢢࣛࣇ࢙ࣥࢆ⏝࠸ࡓࣂ࢖࢜ࢭࣥࢧ࣮
ࢢࣛࣇ࢙ࣥࢆࢳࣕࢿࣝ࡜ࡍࡿ㟁⏺ຠᯝࢺࣛࣥࢪࢫࢱࢆసᡂࡋࠊ㟁ゎ⁐ᾮ୰࡛ືసࢆࡍࡿ஦ࢆ☜ㄆࡋࡓࠋ
ࡲࡓࢢࣛࣇ࢙ࣥ⾲㠃ࢆࣇࣛࢢ࣓ࣥࢺᢠయ࡛ಟ㣭ࡋࠊᢠཎ㸭ᢠయ཯ᛂࡀ㟁Ẽⓗ࡟᳨ฟ࡛ࡁࡿ஦ࢆึࡵ࡚♧
ࡋࡓࠋ
― 130 ―
࣭ศᏊ࢚ࣞࢡࢺࣟࢽࢡࢫᮦᩱࡢ㛤Ⓨ
ࣆࣜࢪࣝᇶࢆ୕⬮ᆺ࡟㓄⨨ࡋࡓ㟁ᴟ࢔࣮ࣥ࢝ࢆ㛤Ⓨࡋࠊࡇࢀࢆ୧➃࡟᭷ࡍࡿศᏊ࣡࢖ࣖࡢ༢ศᏊ㟁Ẽ
ఏᑟホ౯࡜⌮ㄽィ⟬࠿ࡽࠊʌ ㌶㐨ࡀ㛵୚ࡍࡿ㔠㟁ᴟ᥋ྜ࡜ LUMO ㌶㐨ࢆ௓ࡋࡓ㟁Ꮚఏᑟࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
ࡇࡢ⤖ᯝࡣࠊ࢔࣮ࣥ࢝ࡢ✀㢮࡟ࡼࡗ࡚࢟ࣕࣜ࢔✀ࢆ㑅ᢥ࡛ࡁࡿ㐨ࢆᣅࡃ࡜ᮇᚅࡉࢀࡿࠋࡲࡓࠊ୧ᮎ➃࡟
ࢳ࣮࢜ࣝ࢔࣮ࣥ࢝ࢆ᭷ࡋࠊࡍ࡭࡚ࡢࢳ࢜ࣇ࢙ࣥ࡟࢔ࣝ࢟ࣝࣇࣝ࢜ࣞࣥࢆࢫࣆࣟᆺ࡟⨨᥮ࡉࢀࡓࠊ㙐㛗ࡢ
␗࡞ࡿ⤯⦕⿕そᆺ࢜ࣜࢦࢳ࢜ࣇ࢙ࣥศᏊ࣡࢖ࣖࡢྜᡂ㐩ᡂࡋࠊ≀ᛶ ᐃ࠿ࡽ⿕そࡢຠᯝࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
ࡉࡽ࡟ STM ࣈ࣮ࣞࢡࢪࣕࣥࢡࢩࣙࣥἲ࡛༢ศᏊࡢ㟁Ẽఏᑟホ౯ࢆ㐩ᡂࡋࠊᖹ㠃ᛶࡀ㧗ࡃࢡࣟࢫࢺ࣮ࢡ
ࢆ㜼ᐖࡋࡓ࢜ࣜࢦࢳ࢜ࣇ࢙ࣥࡢᮏ㉁ⓗ࡞㟁Ẽఏᑟῶ⾶ᅉᏊࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
㺃ᙉ┦㛵㓟໬≀ࢼࣀ࢚ࣞࢡࢺࣟࢽࢡࢫࡢᵓ⠏ࡢ◊✲
ᐊ ࡛ᕧ኱㔠ᒓʊ⤯⦕య┦㌿⛣ࢆ♧ࡋࠊᕧ኱ On/Off ẚຠᯝࡀᮇᚅ࡛ࡁࡿ஧㓟໬ࣂࢼࢪ࣒࢘(VO2)ⷧ⭷
࡟࠾࠸࡚Pm ࢧ࢖ࢬࡢᕧ኱㟁Ꮚ┦ࢆぢ࠸ࡔࡋࡓࠋࡲࡓ VO2 ࢆ⏝࠸ࡓࣇ࣮ࣜࢫࢱࣥࢹ࢕ࣥࢢᵓ㐀యࢆస〇
ࡋࠊᚑ᮶ࡢ VO2 ⷧ⭷⣲Ꮚ࡟ẚ࡭࡚ 1/100 ࡢ㟁ຊ࡛᭩ࡁ㎸ࡳࡀ࡛ࡁࡿከ್࣓ࣔࣜຠᯝࢆᐇドࡋࡓࠋᮾ໭኱
ከඖ◊࡜ࡢඹྠ◊✲࡟࠾࠸࡚ᙉ☢ᛶ㓟໬≀ࢼࣀ⣽⥺ࡢ☢Ẽ࣍ࣟࣈࣛࣇ࢕࣮ほᐹ࡟ྲྀࡾ⤌ࢇࡔࠋ
࣭ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య࣭㉸ఏᑟయࡢᇶ♏◊✲
᫖ᖺᗘ୰࡟ᡃࠎࡣ Bi2Te2Se ࡜࠸࠺≀㉁ࡀ᱁ẁ࡟㧗࠸ࣂࣝࢡ⤯⦕ᛶࢆᣢࡘࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య᪂≀㉁࡛
࠶ࡿࡇ࡜ࢆⓎぢࡋࡓࡀࠊࡇࡢ㛵㐃≀㉁࡛࠶ࡿ Bi2-xSbxTe3-xSex ࡟࠾࠸࡚ࠊBi2Te2Se ࡼࡾࡶࡉࡽ࡟ඃࢀࡓࣂ
ࣝࢡ⤯⦕ᛶࢆ♧ࡍ୍㐃ࡢ⤌ᡂࢆⓎぢࡋࡓࠋࡉࡽ࡟ࡇࡢ Bi2-xSbxTe3-xSex ࡢ᭱㐺໬࡟ࡼࡾࠊ⾲㠃ఏᑟ⋡ࡀࣂ
ࣝࢡఏᑟ⋡ࢆୖᅇࡿ༢⤖ᬗヨᩱࢆୡ⏺࡛ึࡵ࡚ᐇ⌧ࡋࡓࠋࡲࡓࠊࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య࡟㟁Ꮚࢆὀධࡋࡓ
㉸ఏᑟయ࡛࠶ࡿ CuxBi2Se3 ࡀࠊ⾲㠃࡟࣐ࣚࣛࢼ⢏Ꮚࡢฟ⌧ࢆక࠺ࢺ࣏ࣟࢪ࢝ࣝ㉸ఏᑟయ࡜ࡋ࡚᭱ึࡢල
య౛࡛࠶ࡿࡇ࡜ࢆⓎぢࡋࡓࠋ
࣭༳ๅἲ࡟ࡼࡿ㧗⛣ືᗘ᭷ᶵࢺࣛࣥࢪࢫࢱࡢ࢔ࢡࢸ࢕ࣈ࣐ࢺࣜࢵࢡࢫ㛤Ⓨ
⁐ᾮࢆሬᕸࡋࡓᚋ࡟୍᪉ྥ࡟஝⇱ࡉࡏࡿᡭἲ࡟ࡼࡗ࡚ࠊ㧗㏿࡟᭷ᶵ༢⤖ᬗⷧ⭷ࢆᙧᡂࡍࡿᡭἲࢆⓎᒎ
ࡉࡏࠊ1000 ಶࡢࢺࣛࣥࢪࢫࢱ࢔ࣞ࢖ࢆྠ᫬࡟〇సࡍࡿࣉࣟࢭࢫࢆᐇ⌧ࡋࡓࠋࡲࡓࠊᚑ᮶ࡼࡾ 1 ᱆㧗ᛶ
⬟ࡢ᭷ᶵࢺࣛࣥࢪࢫࢱ࡟ࡼࡗ࡚࢔ࢡࢸ࢕ࣈ࣐ࢺࣜࢵࢡࢫࣃࢿࣝࢆᵓᡂࡋࠊᾮᬗࢹ࢕ࢫࣉࣞ࢖ࡢ㥑ື࡟ࡶ
ᡂຌࡋࡓࠋᮏᡂᯝࡣࠊᑗ᮶ࡢࣉࣜࣥࢸࢵࢻ࢚ࣞࢡࢺࣟࢽࢡࢫ⏘ᴗ࡟ᐤ୚ࡍࡿᢏ⾡࡜ࡋ࡚ὀ┠ࡉࢀࠊ
nanotech2012 ኱㈹ࣉࣟࢪ࢙ࢡࢺ㈹ࢆཷ㈹ࡍࡿ࡞࡝ࠊ⏘ᴗ⏺࡛ࡶ㧗ࡃホ౯ࡉࢀ࡚࠸ࡿࠋ
࣭➨୍ཎ⌮ィ⟬࡟ࡼࡿ≀ᛶࡢᶵᵓゎ᫂
☢Ẽ␗᪉ᛶࡢ࠺ࡕࢫࣆࣥ㌶㐨┦஫స⏝࡟㉳ᅉࡍࡿ⤖ᬗ☢Ẽ␗᪉ᛶ࡟㛵ࡋ࡚FePtࡸCoPt࡛ࡢᵓ㐀ࡢ㐪࠸
࡟ࡼࡿ☢Ẽ␗᪉ᛶࡢኚ໬࡟㛵ࡋ࡚㟁Ꮚ≧ែ࡟ᇶ࡙ࡃ㆟ㄽࢆ㐍ࡵ࡚࠸ࡿࠋࡲࡓࠊᙧ≧☢Ẽ␗᪉ᛶࡢ㉳※࡟
㛵ࡋ࡚ࡶ㆟ㄽࢆ⾜ࡗࡓࠋ࣐ࣝࢳࣇ࢙ࣟ࢖ࢵࢡ≀㉁࡟ࡘ࠸࡚ࡣBa2CoGe2O7࡟࠾࠸࡚ࠊࢫࣆࣥ㌶㐨┦஫స⏝
࡟ࡼࡾ⏕ࡎࡿᙉㄏ㟁ศᴟࡢⓎ⌧ᶵᵓࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
࣭㔞Ꮚ᝟ሗᐇ㦂࡟࠾ࡅࡿ㔞Ꮚ≧ែ᥎ᐃᡭἲࡢ㛤Ⓨ
㔞Ꮚ᝟ሗฎ⌮ࢹࣂ࢖ࢫࡣࠊ㠉᪂ⓗ࡞᝟ሗฎ⌮ࢆྍ⬟࡟ࡍࡿ₯ᅾຊࢆ᭷ࡋ࡚࠸ࡿࠋ㔞Ꮚ≧ែࡣࠊ⫼ᚋࡢ
≀⌮ⓗ࣓࢝ࢽࢬ࣒࡟ࡼࡗ࡚༙ṇᐃᛶ࡜࠸࠺ᩘᏛⓗᛶ㉁ࢆ‶ࡓࡍࠋᮏ◊✲࡛ࡣࡇࢀࢆ฼⏝ࡋ࡚ࠊ」㞧࡞㔞
Ꮚ᝟ሗᐇ㦂⤖ᯝ࠿ࡽ㔞Ꮚ≧ែࢆᐇ㦂᮲௳ࡢኚ໬࡟ᑐࡋ࡚୙ኚ࡞㒊ศ࡜ኚ໬ࡍࡿ㒊ศ࡟ศ㞳᥎ᐃࡍࡿ◊
✲ࢆ㐍ࡵࠊࡑࢀࢆୡ⏺࡛ึࡵ࡚ྍ⬟࡟ࡍࡿ⌮ㄽⓗᯟ⤌ࡳࢆᚓࡓࠋ
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ࠕ᪂࢚ࢿࣝࢠ࣮ᮦᩱ࣭ࢹࣂ࢖ࢫࠖ◊✲ࢢ࣮ࣝࣉ
ᩍᤵ㸦ව௵㸧
෸ᩍᤵ㸦ව௵㸧
ᑠᯘ ග㸦ࢢ࣮ࣝࣉ㛗㸧
ࠊⳢ἟ ඞ᫛ࠊ㇂ᮧ ඞᕫࠊ➉⏣ ⢭἞ࠊ἟ᑿ ṇ⾜
㄃⏣ ⩏ⱥࠊ㕥ᮌ ೺அ
a) ᴫせ
ᚑ᮶ࠊ200 °C ௨ୖᚲせ࡛࠶ࡗࡓ㖟ࢼࣀ࣡࢖ࣖ㏱᫂ᑟ㟁⭷ࡢస〇࡟࠾࠸࡚ࠊࣉࣞࢫἲࢆ㛤Ⓨࡍࡿࡇ࡜࡛ࠊ
ᐊ స〇ࢆྍ⬟࡟ࡋࡓࠋࡇࡢ᪉ἲࡣࠊ㏱᫂ᑟ㟁⭷ࡢ⾲㠃⢒ࡉࢆ኱ᖜ࡟ῶᑡࡉࡏࡿ࡜࠸࠺ຠᯝࡶేࡏᣢࡘࠋ
㸦Ⳣ἟㸧
༙ᑟయࢆ⏝࠸ࡓග࢚ࢿࣝࢠ࣮ኚ᥮⣲Ꮚࡢ㧗ຠ⋡໬࡟ࡴࡅ࡚ࠊexcess energy ࡟౫Ꮡࡍࡿගບ㉳࢟ࣕࣜࣖ
ࡢ⾲㠃࣭⏺㠃࡟࠾ࡅࡿືຊᏛⓗᣲືࢆࠊග㟁Ꮚศගࢆ⏝࠸࡚ࣇ࢙࣒ࢺ⛊ࡢ᫬㛫ศゎ⬟࡛┤᥋㏣㊧࣭ゎ᫂
ࡍࡿ◊✲ࢆ⾜ࡗࡓࠋ㸦㇂ᮧ㸧
⎔ቃไᚚᆺ㏱㐣㟁Ꮚ㢧ᚤ㙾ࢆ⏝࠸࡚ࠊ㓟໬ࢭ࣒ࣜ࢘ୖ࡟ᢸᣢࡉࢀࡓ㔠ࢼࣀ⢏Ꮚゐ፹ࡢ୍㓟໬Ⅳ⣲㓟໬
཯ᛂᶵᵓࡢゎ᫂ࢆ┠ᣦࡋ◊✲ࢆ㐍ࡵࡓࠋ㸦➉⏣㸧
⇞ᩱ㟁ụ࡟࠾ࡅࡿ≀⌮ⓗຎ໬ᶵᵓࡢゎ᫂࠾ࡼࡧ┘どࢩࢫࢸ࣒ࡢࡓࡵࡢᇶ┙ᢏ⾡ᵓ⠏࡟ྥࡅ࡚ࠊࢹ࣮ࢱ
࣐࢖ࢽࣥࢢᢏ⾡࡟ᇶ࡙ࡃ▱ⓗᦆയホ౯ἲ࡟㛵ࡍࡿ◊✲ࢆ㐍ࡵࡓࠋ㸦἟ᑿ㸧
┬࢚ࢿࣝࢠ࣮ࠊ⎔ቃㄪ࿴ᆺ㓟໬ࣉࣟࢭࢫࢆ┠ᣦࡋࠊ࢖ࣜࢪ࣒࢘㘒యゐ፹ࢆ⏝࠸ࡿࢪ࣮࢜ࣝࡢ㓟໬ⓗ㠀
ᑐ⛠໬཯ᛂࢆᇶ┙࡜ࡍࡿࢱࣥࢹ࣒ᆺࡢ᪂つ୙ᩧゐ፹཯ᛂࢆ◊✲ࡋࡓࠋ
㸦㕥ᮌ㸧
࣐࢞ࣥ⥺ࡸ㔞Ꮚࣅ࣮࣒ࠊ㝧㟁Ꮚ➼ࢆ⏝࠸ᮦᩱゎᯒࢆ⾜ࡗ࡚࠾ࡾࠊ≉࡟⇞ᩱ㟁ụ⏝㧗ศᏊ㟁ゎ㉁⭷ࡢࣛ
ࢪ࢝ࣝ཯ᛂ㐣⛬ࢆ୰ᚰ࡟◊✲ࢆ⾜ࡗࡓࠋ㸦㄃⏣㸧
ග໬Ꮫⓗ⁐ゎἲࡢ཯ᛂࢆไᚚࡍࡿࡇ࡜࡛ࠊ㔞Ꮚࢧ࢖ࢬຠᯝࢆ♧ࡍࣂࣥࢻࢠࣕࢵࣉࡢᗈ࠸ࢩࣜࢥࣥࢼࣀ
ࣃ࣮ࢸ࢕ࢡࣝࢆຠ⋡ⓗ࡟๰〇ࡋࠊࡉࡽ࡟ࡑࢀࢆ⏝࠸࡚ᙧᡂࡋࡓ pn ᥋ྜኴ㝧㟁ụࡢ≉ᛶࢆྥୖࡉࡏࡿ◊
✲ࢆ⾜ࡗࡓࠋ㸦ᑠᯘ㸧
b) ᡂᯝ
࣭ኴ㝧㟁ụᇶᯈ࡬ࡢ㟁ᴟ࣭㓄⥺ࡢప ᐇ⿦ᢏ⾡ࡢ㛤Ⓨ
㖟ࢼࣀ࣡࢖ࣖ㏱᫂ᑟ㟁⭷ࡣࠊࣇࣞ࢟ࢩࣈࣝᛶࢆ᭷ࡍࡿ㏱᫂ᑟ㟁⭷࡜ࡋ࡚ὀ┠ࡉࢀ࡚࠸ࡿࠋࡋ࠿ࡋࠊ㖟
ࢼࣀ࣡࢖ࣖ㏱᫂ᑟ㟁⭷ࡣ⾲㠃⢒ࡉࡀ኱ࡁ࠸ࡓࡵࠊ㖟ࢼࣀ࣡࢖ࣖ㏱᫂ᑟ㟁⭷ୖ࡟ⷧ⭷ࢹࣂ࢖ࢫࢆస〇ࡍࡿ
㝿࡟㟁ᴟ㛫ࡀᑟ㏻ࡍࡿㄢ㢟ࡀ⏕ࡌ࡚࠸ࡓ(ᕥᅗ)ࠋᡃࠎࡣࠊࣉࣞࢫἲࢆ⏝࠸࡚㖟ࢼࣀ࣡࢖ࣖ㛫ࢆᅽ╔ࡋࠊ
㖟ࢼࣀ࣡࢖ࣖ㏱᫂ᑟ㟁⭷ࢆᐊ స〇ࡋࡓࠋࣉࣞࢫࡋࡓ㖟ࢼࣀ࣡࢖ࣖ㏱᫂ᑟ㟁⭷ࡣᑠࡉ࡞⾲㠃⢒ࡉࢆ᭷ࡋ
࡚࠸ࡿࡓࡵࠊ㖟ࢼࣀ࣡࢖ࣖ㏱᫂ᑟ㟁⭷ୖ࡬ࡢⷧ⭷ࢹࣂ࢖ࢫࡢస〇ࡀᐜ᫆࡟࡞ࡗࡓ㸦ୗᅗ)ࠋ
࣭ࣇ࢙࣒ࢺ⛊᫬㛫ศゎග㟁Ꮚศගἲ࡟ࡼࡿ༙ᑟయ⾲㠃࣭⏺㠃ࡢ㉸㧗㏿࢟ࣕࣜࣖືຊᏛࡢ◊✲
ྍどගບ㉳࡛ Si ࠾ࡼࡧ GaAs ⤖ᬗ୰࡟Ⓨ⏕ࡋࡓບ㉳㟁Ꮚࡢ⦆࿴࣭ᾘ⁛㐣⛬ࢆࠊ100 fs ࡢ᫬㛫ศゎ⬟࡛
ᐇ᫬㛫㏣㊧ࡋࡓࠋගᏛ㑄⛣☜⋡࡛Ỵࡲࡿ㐠ື㔞࡜࢚ࢿࣝࢠ࣮ࡢ≉ᐃⅬ࡟Ⓨ⏕ࡋࡓບ㉳㟁Ꮚࡣࠊᖹ⾮ศᕸ
ࢆ㐩ᡂࡍࡿ௨๓ࡢ࣍ࢵࢺ࡞≧ែࡢࡲࡲࠊ⾲㠃≧ែ࣭⾲㠃Ḟ㝗≧ែ࡬ຠ⋡ⓗ࡟㑄⛣ࡋ࡚෌⤖ྜࡍࡿ஦ࡀ᫂
ࡽ࠿࡟࡞ࡗࡓࠋ
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࣭ゐ፹཯ᛂ⎔ቃୗ࡟࠾ࡅࡿᢸᣢ㔠ࢼࣀ⢏Ꮚゐ፹ࡢᙧែ࡜⾲㠃ᵓ㐀ࡢゎ᫂
㓟໬ࢭ࣒ࣜ࢘ୖ࡟ᢸᣢࡉࢀࡓ㔠ࢼࣀ⢏Ꮚࡢᙧ≧ࡀࠊ཯ᛂ࢞ࢫ୰ࡢ୍㓟໬Ⅳ⣲࡜㓟⣲ࡢศᅽ࡟ᛂࡌ࡚⣔
⤫ⓗ࡟ኚ໬ࡍࡿࡇ࡜ࢆぢฟࡋࡓࠋ୍㓟໬Ⅳ⣲ࡢ྾╔ࡣ{111}㠃ࡸ{100}㠃࡟ᅖࡲࢀࡓከ㠃యᙧ≧ࢆᏳᐃ࡟
ࡋࠊ㓟⣲ࡣ୸ࡳࢆᖏࡧࡓᙧ≧ࢆㄏ㉳ࡍࡿࠋࡉࡽ࡟ࠊ཯ᛂ⎔ቃୗ࡛ࠊ୍㓟໬Ⅳ⣲ࡢ྾╔࡟ࡼࡾ㔠ࢼࣀ⢏Ꮚ
ࡢ{100}⾲㠃ᵓ㐀ࡀභ᪉᱁Ꮚ࡟෌ᵓᡂࡍࡿࡇ࡜ࡶ᫂ࡽ࠿࡟ࡋࡓࠋ௨ୖࡢᡂᯝࡣࠊ㔠ࢼࣀ⢏Ꮚࡢゐ፹ᶵᵓ
ࢆゎ᫂ࡍࡿୖ࡛㔜せ࡞ᡭࡀ࠿ࡾ࡜࡞ࡿࠋ
࣭⇞ᩱ㟁ụࡢᵓᡂ㒊ᮦ㛫ࡢຊᏛⓗᙳ㡪ࡢ᥎ᐃἲࡢ㛤Ⓨ
ᅛయ㓟໬≀⇞ᩱ㟁ụࡢᵓᡂ㒊ᮦ㛫ࡢຊᏛ㛵ಀࢆ᥎ᐃࡍࡿࡓࡵࠊᦆയィ ಙྕ࡛࠶ࡿ Acoustic Emission
(AE)஦㇟ࡢ⣔ิ࠿ࡽࠊ㢖ฟࡍࡿᦆയࣃࢱ࣮ࣥࢆ㧗⢭ᗘ࡟ᢳฟࡍࡿ⊂⮬࢔ࣝࢦࣜࢬ࣒ࡢ᭷⏝ᛶࢆ᳨ドࡋࡓࠋ
ᅛయ㓟໬≀⇞ᩱ㟁ụࡢᵓᡂ㒊ᮦ㛫ࡢຊᏛ㛵ಀ࡟㛵ࡋ࡚ࠊึᮇࡢᑠࡉ࡞ࡁ⿣ࡸᨭᣢᮦ࡛࠶ࡿ࢞ࣛࢫࢩ࣮ࣝ
ᮦࡢ཰⦰ࡀ඲యࡢ◚ቯࡢ㐍ᒎ࡟኱ࡁࡃᙳ㡪ࡋ࡚࠸ࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓࠋࡲࡓࠊᮏᡭἲࡢࣜࢳ࣒࢘࢖࢜
ࣥ㟁ụ࡬ࡢ㐺⏝ࢆ㛤ጞࡋࡓࠋ
࣭㓟໬ⓗ㠀ᑐ⛠໬ࢆᇶ┙࡜ࡍࡿࢱࣥࢹ࣒ゐ፹཯ᛂ
ࢡ࣮ࣜࣥ࡞㓟໬๣ࢆ⏝࠸ࡿゐ፹཯ᛂࡢ㛤Ⓨࡣ᭱㔜せㄢ㢟ࡢ୍ࡘ࡛࠶ࡿࠋࡲࡓᑐ⛠ࢪ࣮࢜ࣝࡢ㠀ᑐ⛠໬
ࡣ࢟ࣛࣝࣅࣝࢹ࢕ࣥࢢࣈࣟࢵࢡࢆྜᡂࡍࡿୖ࡛᭷ຠ࡞ᡭẁ࡛࠶ࡿࠋ௒ᅇࠊ࢟ࣛࣝ࢖ࣜࢪ࣒࢘㘒యࢆ⏝࠸ࠊ
࣓ࢯࢪ࣮࢜ࣝࡢ㓟໬ⓗ㠀ᑐ⛠໬཯ᛂࢆ㘽཯ᛂ࡜ࡍࡿࢱࣥࢹ࣒ᆺࡢゐ፹୙ᩧ཯ᛂࢆ㛤Ⓨࡋࡓࠋࡉࡽ࡟ᮏ཯
ᛂࢆᒎ㛤ࡋࠊ୙ᩧỈ⣲⮬ື⛣ືࣉࣟࢭࢫࡶ㐍⾜ࡍࡿࡇ࡜ࡶぢฟࡋࡓࠋ
࣭ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫ࡟ࡼࡿ㧗ศᏊ㟁ゎ㉁⭷ࡢ◊✲
㧗ศᏊ㟁ゎ㉁⭷࡟ᑐࡍࡿⷧ⭷㟁Ꮚ⥺ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫἲ࡟ࡼࡾࠊᮏᖺᗘࡣྵỈ㔞ࢆㄪᩚࡋࡓ Nafion
࡟࠾࠸࡚ࢻ࣮ࣉࡋࡓᇶ㉁ࢆ⏝࠸࡚ຎ໬㐣⛬ࢆ᳨ウࡋࡓࠋNafion ୰ࡢྵỈ㔞ࡢపୗ࡟ࡼࡾࠊࣄࢻࣟ࢟ࢩࣝ
ࣛࢪ࢝ࣝ(OHƔ)௜ຍ≀ࡢ⏕ᡂࡀᢚไࡉࢀࡓࠋ┤᥋㓟໬࡟ࡼࡿ୍㟁Ꮚ㓟໬≀ࡢ⏕ᡂ㔞ࡣኚ໬ࡋ࡞࠿ࡗࡓࠋ
OHƔࡢ⏕ᡂࡣぶỈᛶࢡࣛࢫࢱ࣮㒊఩ࡢ-SO3-࡟ hydrate ࡋ࡚࠸ࡿỈศᏊ࠿ࡽ⏕ᡂࡉࢀࡿࡇ࡜ࡀ♧၀ࡉࢀࡓࠋ
㟁Ꮚ⥺ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫἲ࡟ࡼࡿ OHƔຎ໬ィ ᡭἲࡢ㛤Ⓨࢆ⾜ࡗࡓࠋ
࣭ࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡࣝࢆ⏝࠸ࡿኴ㝧㟁ụ
ࢩࣜࢥࣥࡢษ⢊ࢆ࣮࣑࣎ࣝࣝ⢊○ᚋࠊගᏛࣇ࢕ࣝࢱ࣮ࢆ⏝࠸ࡓග໬Ꮫ࢚ࢵࢳࣥࢢ࡟ࡼࡾ⁐ゎࡉࡏࡿࡇ
࡜࡛ࠊࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡࣝࢆᙧᡂࡋࡓࠋᙧᡂࡋࡓࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡࣝ࠿ࡽࡣࠊ㹼400nm ࡟
ᙉ࠸㟷Ⰽࡢࣇ࢛ࢺ࣑ࣝࢿࢵࢭࣥࢫࣆ࣮ࢡࡀほ ࡉࢀࠊ㔞Ꮚࢧ࢖ࢬຠᯝ࡟ࡼࡿࣂࣥࢻࢠࣕࢵࣉࡢᗈࡀࡾࡀ
☜ㄆࡉࢀࡓࠋp ᆺࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡࣝ/n ᆺ༢⤖ᬗࢩࣜࢥࣥᵓ㐀ࡣⰋዲ࡞ᩚὶᛶࢆ♧ࡋࠊࡉࡽ࡟◪
㓟㓟໬ἲࢆ⏝࠸ࡿࡇ࡜࡛ࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡࣝࡢᐦ╔ᛶࡀྥୖࡋࠊගᛂ⟅ᛶࡀྥୖࡍࡿࡇ࡜ࡀࢃ࠿
ࡗࡓࠋ
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ࠕ་⒪ᮦᩱ࣭ࢹࣂ࢖ࢫ࣭ࢩࢫࢸ࣒ࠖ◊✲ࢢ࣮ࣝࣉ
ᩍᤵ㸦ව௵㸧
෸ᩍᤵ㸦ව௵㸧
୰㇂ ࿴ᙪ㸦ࢢ࣮ࣝࣉ㛗㸧ࠊඵᮌ ᗣྐࠊຍ⸨ ಟ㞝ࠊᒣཱྀ ᫂ேࠊ㇂ཱྀ ṇ㍤ࠊ
Ọ஭ ೺἞ࠊ㥖㇂ ࿴⠊
ᒸᓥ ಇⱥࠊす Ẏࠊす㔝 㑥ᙪ
a) ᴫせ
་⒪ᮦᩱ࣭ࢹࣂ࢖ࢫ࣭ࢩࢫࢸ࣒࡛ࡣࠊୗグ࡟♧ࡍࡼ࠺࡟ࠊ㑇ఏᏊ㸭⸆๣ࢹࣜࣂ࣮ࣜࢩࢫࢸ࣒ࠊ⏕⌮ά
ᛶ≀㉁ࡢ⭷㍺㏦య࡟ࡼࡿᒁᅾᛶࡢไᚚࠊ᭷ᶵపศᏊ࡟ࡼࡿࢱࣥࣃࢡ㉁ࡢᶵ⬟ไᚚࠊከ㠃య㙾ࢆ⏝࠸ࡓ᧜
ീࢹࣂ࢖ࢫࠊ㑇ఏᏊ᳨ᰝᢏ⾡ࡢ㛤Ⓨࠊ㸯ศᏊ᳨ฟ࣭㆑ูࢹࣂ࢖ࢫࡢ㛤Ⓨࠊ㧗ឤᗘ⺯ගࢱࣥࣃࢡ㉁ࢭࣥࢧ
࣮࡜ࠊே㛫⾜ືࣔࢹࣝࡢグ㏙ᯟ⤌ࡳ࡟㛵ࡍࡿ◊✲ࢆ୰ᚰ࡟⾜ࡗࡓࠋ
≉ᐃࡢ⮚ჾࡸ⤌⧊࡟ࣆ࣏ࣥ࢖ࣥࢺ࡛⸆๣ࡸ㑇ఏᏊࢆ㏦㐩ࡍࡿࣂ࢖࢜ࢼࣀ࢝ࣉࢭࣝࡢᶆⓗ≉␗ᛶࢆኚ
᥮ࡍࡿࡓࡵ࡟ࠊࣉࣟࢸ࢖ࣥ G ࠾ࡼࡧ L ࡢᢠయ⤖ྜ㒊఩ࢆ⾲ᒙ࡟ᥦ♧ࡍࡿࣂ࢖࢜ࢼࣀ࢝ࣉࢭࣝࢆ㛤Ⓨࡋࠊ
ᵝࠎ࡞ື≀✀࡟⏤᮶ࡍࡿ✀ࠎࡢᢠయࢆ⤖ྜ࡛ࡁࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓࠋ㸦㇂⃝㸧
࢔ࢲࣉࢱ࣮ࢱࣥࣃࢡ㉁࡜ࡋ࡚⣽⬊ෆಙྕఏ㐩⤒㊰ୖ࡛㔜せ࡞ᙺ๭ࢆᯝࡓࡋ࡚࠸ࡿ 14-3-3 ࢱࣥࣃࢡ㉁
ࡢࢡࣛ࢖࢔ࣥࢺ࣌ࣉࢳࢻ㑅ᢥⓗࣔࢹ࣮ࣗࣞࢱࡢ๰〇◊✲ࢆᒎ㛤ࡋࡓࠋ
㸦ຍ⸨㸧
༙㏱᫂≀యෆ㒊࡛ほ ࡉࢀࡿ༢୍ᩓ஘ࡢᙉᗘࢆゎᯒࡍࡿࡇ࡜࡛ࠊࡑࡢ⾲㠃ᙧ≧ࢆ᥎ᐃࡍࡿᡭἲࢆ㛤Ⓨ
ࡋࡓࠋ㸦ඵᮌ㸧
ே㛫⾜ືࣔࢹࣝࡢグ㏙ࢶ࣮ࣝ CHARM ࢆࢱࣈࣞࢵࢺࢥࣥࣆ࣮ࣗࢱ࡟⛣᳜ࡋ࡚ CHARM-Pad ࢆ㛤Ⓨࡋࡓࠋ
኱㜰ཌ⏕ᖺ㔠⑓㝔࡟࠾ࡅࡿ ICU ┳ㆤᡭ㡰ࡢ◊ಟࢆᑐ㇟࡟ࡋ࡚㐺⏝ࡋࠊホ౯ᐇドヨ㦂ࢆィ⏬ࡋࡓࠋ(⁁ཱྀ)
ࢫࣇ࢕ࣥࢦࢩࣥ 1 ࣜࣥ㓟ࡢ㍺㏦య SPNS2 ࣀࢵࢡ࢔࢘ࢺ࣐࢘ࢫࡢゎᯒ࡟ࡼࡾࠊච␿ᶵ⬟࡟ᚲ㡲࡞ T ⣽
⬊ࡢ⾑୰࡬ࡢฟ⌧࡟ SPNS2 ࡀᚲ㡲࡛࠶ࡿࡇ࡜ࢆⓎぢࡋࡓࠋࡲࡓࠊୡ⏺ึࡢ㜼ᐖ๣⤖ྜᆺ␗≀᤼ฟࢱࣥࣃ
ࢡᵓ㐀ࡢỴᐃ࡟ᡂຌࡋࠊ≉␗ⓗ࡞㜼ᐖ๣⤖ྜࣆࢵࢺࢆⓎぢࡋ࡚ࠊ␗≀᤼ฟࢱࣥࣃࢡࡢ㜼ᐖ๣≉␗ᛶࡢᵓ
㐀ⓗᇶ┙ࢆ᫂ࡽ࠿࡟ࡋࡓ㸦ᒣཱྀ㸧
㑇ఏᏊࡢ୍ሷᇶከᆺࢆ㎿㏿ࠊ⡆౽࡟᳨ฟࡍࡿࠕ࣊࢔ࣆࣥࣉࣛ࢖࣐࣮PCR ἲࠖࢆᨵⰋࡋࡓࢩࢢࢼࣝቑ኱
ᆺࢆ㛤Ⓨࡋࠊ࢘࢕ࣝࢫ᳨ฟ࡟ࡘ࠸࡚ࡢ◊✲ࢆᒎ㛤ࡋࡓࠋ㸦୰㇂㸧
DNA㸯ศᏊࡢὶື㏿ᗘࢆ㸱᱆ࡢ⠊ᅖ࡛ไᚚࡍࡿࢼࣀࢹࣂ࢖ࢫࢆస〇ࡋࠊ㸯ศᏊ᳨ฟ࣭㆑ูࢹࣂ࢖ࢫࡢ
ࢥ࢔ᢏ⾡࡜࡞ࡿ㸯ศᏊࢲ࢖ࢼ࣑ࢡࢫไᚚᢏ⾡ࢆ㛤Ⓨࡋࡓࠋ
㸦㇂ཱྀ㸧
⺯ගࢱࣥࣃࢡ㉁ࡢ෇㡰ิኚ␗ἲཬࡧ㧗ຠ⋡ࢫࢡ࣮ࣜࢽࣥࢢἲࡢ㛤Ⓨ࡟ࡼࡾࠊ㟷࣭⥳࣭㉥Ⰽࡢ Ca2+ࢭࣥ
ࢧ࣮ࡢ㛤Ⓨ࡟ᡂຌࡋࡓ㸦Ọ஭㸧
b) ᡂᯝ
࣭᪂ࡋ࠸་⒪ᮦᩱ࣭ࢹࣂ࢖ࢫ࡜ࡋ࡚ࡢࣂ࢖࢜ࢼࣀ࢝ࣉࢭࣝࡢ㛤Ⓨ࡜ᛂ⏝㸦㇂⃝㸧
B ᆺ⫢⅖࢘࢕ࣝࢫࡢ⾲㠃ᢠཎ L ࢱࣥࣃࢡ㉁࡛ᵓᡂࡉࢀࡿࣂ࢖࢜ࢼࣀ࢝ࣉࢭࣝ㸦BNC㸧ࡣࠊࡑࡢෆ㒊࡟
ᵝࠎ࡞⸆๣㸦་⸆ࠊࢱࣥࣃࢡ㉁ࠊ㑇ఏᏊ➼㸧ࢆᑒධࡍࡿࡇ࡜࡛ࠊࣄࢺ⫢⮚≉␗ⓗ࡟ࣆ࣏ࣥ࢖ࣥࢺ㏦㐩࡛
ࡁࡿ GDS/DDS ⏝࢟ࣕࣜ࢔࡜ࡋ࡚᭷⏝࡛࠶ࡿࠋᮏᖺᗘࡣࠊBNC ⾲ᒙ࡟ࣉࣟࢸ࢖ࣥ G ࡸࣉࣟࢸ࢖ࣥ L ࡢ
ᢠయ⤖ྜࣔࢪ࣮ࣗࣝࢆᥦ♧ࡉࡏࠊࡇࢀ࡟ᵝࠎ࡞⏕≀✀⏤᮶ࡢ✀ࠎࡢᢠయࢆ⤖ྜࡉࡏࡿࡇ࡜࡛⏕యෆࡢ௵
ពࡢ⣽⬊ࡸ⤌⧊࡟ᶆⓗࢆᨵኚࡍࡿࡇ࡜ࡀྍ⬟࡜࡞ࡗࡓࠋ
࣭ࣇࢩࢥࢡࢩࣥㄏᑟయ࡟ࡼࡿࣜࣥ㓟໬࣌ࣉࢳࢻ㑅ᢥⓗ࡞ 14-3-3 ࢱࣥࣃࢡ㉁ࡢᶵ⬟ไᚚ㸦ຍ⸨㸧
14-3-3 ࢱࣥࣃࢡ㉁ࡣࠊSer/Thr ࢟ࢼ࣮ࢮ౫Ꮡⓗ࡞ಙྕఏ㐩⣔ࡢไᚚ࡟㔜せ࡞ᙺ๭ࢆᢸࡗ࡚࠸ࡿࠋᮏ◊✲
࡛ࡣࠊ14-3-3 ࢱࣥࣃࢡ㉁ࡀ఍ྜࡍࡿᗄࡘ࠿ࡢࣜࣥ㓟໬࣌ࣉࢳࢻࣔࢳ࣮ࣇࡢ୰࡛ࠊmode 3 ࡜࿧ࡤࢀࡿ C ➃
࣌ࣉࢳࢻ࡜ࡢ఍ྜࢆ㑅ᢥⓗ࡟Ᏻᐃ໬ࡍࡿࣇࢩࢥࢡࢩࣥㄏᑟయ㸦FC-THF㸧ࢆ๰〇ࡋࡓࠋࡑࡋ࡚ࠊFC-THF
ࡀ mode 3 ᆺࢱࣥࣃࢡ㉁࡛࠶ࡿ K+-࢖࢜ࣥࢳࣕࣥࢿ࣭ࣝTASK-3 ࢆⓎ⌧ࡉࡏࡓ࢔ࣇࣜ࢝ࢶ࣓࢚࢞ࣝ༸ẕ⣽
⬊࡟࠾࠸࡚ࠊእྥࡁࡢ K+ current ࢆቑ኱ࡉࡏࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
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࣭༢୍ᩓ஘ᙉᗘ࡟ᇶ࡙ࡃ༙㏱᫂≀యࡢᙧ≧᥎ᐃ㸦ඵᮌ㸧
༙㏱᫂≀యෆ㒊࡛ほ ࡉࢀࡿ༢୍ᩓ஘ࡢᙉᗘ࡟ᇶ࡙ࡃࠊ᪂ࡓ࡞ᙧ≧᥎ᐃᡭἲࢆ㛤Ⓨࡋࡓࠋ༢୍ᩓ஘ࡣࠊ
ධᑕගࡀ≀య୰୍࡛ᗘࡔࡅᚤ⢏Ꮚ࡜⾪✺ࡍࡿࡇ࡜࡟ࡼࡗ࡚⏕ࡌࡿ⌧㇟࡛࠶ࡾࠊග※࠿ࡽ࣓࢝ࣛ࡟⮳ࡿࡲ
࡛ࡢග㊰ࡸࠊග㊰㛗࡟ᛂࡌࡓῶ⾶ࡢゎᯒࡀྍ⬟࡛࠶ࡿࠋᮏᡭἲ࡟ࡼࡾࠊⓑ⃮ࡋࡓࣉࣛࢫࢳࢵࢡ࡞࡝ࡢ༙
㏱᫂࡞≀యࡢ⾲㠃ᙧ≧ࡀ኱ࡲ࠿࡟᥎ᐃ࡛ࡁࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓࠋ
࣭ே㛫⾜ືࣔࢹࣝࡢグ㏙ࢶ࣮ࣝ CHARM-Pad ࡢ㛤Ⓨ࡜ࡑࡢᐇドヨ㦂㸦⁁ཱྀ㸧
་⒪ᶵ㛵࡟࠾ࡅࡿ࢞࢖ࢻࣛ࢖ࣥグ㏙ࢆᑐ㇟࡟ࡋ࡚ࠊព࿡ࡀ᫂☜࡛ィ⟬ᶵ⌮ゎྍ⬟࡞⾲⌧ᙧᘧࢆᣢࡕࠊ
⾜Ⅽࡢ┠ⓗࡢ᫂♧໬ࡀ࡛ࡁࠊ࠿ࡘ᪉ᘧࡢẚ㍑ࡀᐜ࡛᫆࠶ࡾ㑅ᢥ⌮⏤ࡢ᫂♧໬ࡀ࡛ࡁࡿே㛫⾜ືࣔࢹࣝࡢ
グ㏙ࢶ࣮ࣝࢆ㛤Ⓨࡋࠊࡑࢀࢆࢱࣈࣞࢵࢺࢥࣥࣆ࣮ࣗࢱ࡟⛣᳜ࡋࡓࠋࡇࡢࢶ࣮࡛ࣝグ㏙ࡉࢀࡓࣔࢹࣝࢆࠊ
ᮇᚅࡉࢀࡿຠᯝ࠿ࡽ CHARM(Convincing Human Action Rationalized Model)࡜࿧ࡧࠊ኱㜰ཌ⏕ᖺ㔠⑓㝔 ICU
┳ㆤᡭ㡰◊ಟ࡟࠾࠸࡚ヨ㦂ⓗ㐠⏝ࡢࡓࡵࡢ‽ഛࢆ᏶஢ࡋࡓ㸦6 ᭶࠿ࡽ㐠⏝㛤ጞணᐃ㸧ࠋ
࣭ࢫࣇ࢕ࣥࢦࢩࣥ 1 ࣜࣥ㓟㍺㏦యࣀࢵࢡ࢔࢘ࢺ࣐࢘ࢫࡢゎᯒ࡜␗≀᤼ฟࢱࣥࣃࢡࡢᵓ㐀Ỵᐃ㸦ᒣཱྀ㸧
SPNS2 ࣀࢵࢡ࢔࢘ࢺ࣐࢘ࢫࢆゎᯒࡋࠊSPNS2 ࡀ⾑⟶࣭ࣜࣥࣃ⟶࡞࡝ࡢ⾲⓶⣽⬊ࡢ S1P ㍺㏦య࡛࠶ࡿࡇ
࡜ࢆ᫂ࡽ࠿࡟ࡋࠊ⾲⓶࠿ࡽࡢ S1P ࡢศἪࡀ↓ࡃ࡞ࡿ࡜ࠊࣜࣥࣃ⌫ࡢ⾑୰⃰ᗘࡀୗࡀࡾࠊ࡜ࡃ࡟ T ⣽⬊ࣜ
ࣥࣃ⌫ࡀ࡯࡜ࢇ࡝ᾘኻࡍࡿࡇ࡜ࢆぢฟࡋࡓࠋࡲࡓࠊ⣽⳦␗≀᤼ฟࢱࣥࣃࢡ࡟࠾࠸࡚ୡ⏺ึ࡜࡞ࡿ㜼ᐖ๣
⤖ྜᵓ㐀ࢆゎࡃࡇ࡜࡟ᡂຌࡋࠊ␗≀᤼ฟࢱࣥࣃࢡࡀ♧ࡍ㜼ᐖ๣≉␗ᛶࡢཎᅉࢆゎ᫂ࡋࡓࡇ࡜࡟ࡼࡾࠊࣘ
ࢽࣂ࣮ࢧࣝ࡞␗≀᤼ฟࢱࣥࣃࢡศᏊタィ࡬ࡢ㐨ࢆษࡾ㛤࠸ࡓࠋ
࣭࣊࢔ࣆࣥࣉࣛ࢖࣐࣮PCR ἲࡢᨵⰋ㸦୰㇂㸧
㑇ఏᏊࡢ୍ሷᇶከᆺࢆ㎿㏿ࠊ⡆౽࡟᳨ฟࡍࡿࠕ࣊࢔ࣆࣥࣉࣛ࢖࣐࣮PCR ἲ࡛ࠖࡣ⺯ගࢩࢢࢼࣝࡢῶᑡ
ࢆほ ࡋ࡚࠸ࡿࠋ࣊࢔ࣆࣥࣉࣛ࢖࣐࣮PCR ἲࡢ㧗ឤᗘ໬ࢆ᳨ウࡋࡓ⤖ᯝࠊࡇࢀࡲู࡛㏵ῧຍࡋ࡚࠸ࡓ⺯
ගⰍ⣲ DANP ࢆ࣊࢔ࣆࣥࣉࣛ࢖࣐࣮࡟ඹ᭷⤖ྜ࡛ᅛᐃ໬ࡍࡿ஦ࢆ᳨ウࡋࡓࠋCíࣂࣝࢪࢆᙧᡂࡍࡿሷᇶ
ࡢ๓ᚋ࡟ DANP ࢆᑟධࡋࡓᡤࠊPCR ࡢ㐍⾜࡟క࠸⺯ගᙉᗘࡀቑ኱ࡍࡿᑟධ఩⨨ࢆぢฟࡋࡓࠋ
࣭㸯ศᏊࢲ࢖ࢼ࣑ࢡࢫไᚚᢏ⾡ࡢ㛤Ⓨ㸦㇂ཱྀ㸧
ࢼࣀ࣓࣮ࢺࣝࢫࢣ࣮ࣝࡢᖜ࡜㧗ࡉࢆᣢࡘὶ㊰㸦ࢼࣀὶ㊰㸧ࢆὶࢀࡿ DNA㸯ศᏊࡢ㏿ᗘࢆࠊࢤ࣮ࢺ㟁
ᅽ࡛ไᚚࡍࡿࢼࣀࢹࣂ࢖ࢫࢆస〇ࡋࡓࠋࢤ࣮ࢺ㟁ᅽ࡟ࡼࡿ DNA㸯ศᏊࡢ㏿ᗘኚ໬ࢆㄪ࡭ࡓ࡜ࡇࢁࠊDNA
㸯ศᏊࡢ㏿ᗘࢆ㸱᱆ࡢ⠊ᅖ࡛ไᚚ࡛ࡁࡿࡇ࡜ࢆ᫂ࡽ࠿࡟ࡋࡓࠋࡉࡽ࡟ࠊస〇ࡋࡓࢼࣀࢹࣂ࢖ࢫࢆ⏝࠸ࡓ
㟁ὶィ ࠿ࡽࠊࢼࣀὶ㊰ෆࢆ㏻㐣ࡍࡿ DNA㸯ศᏊࡢᢡࡾ␚ࡳᵓ㐀ࢆ㆑ู࡛ࡁࡿࡇ࡜ࢆⓎぢࡋࡓࠋ
࣭㟷࣭⥳࣭㉥Ⰽࡢ࣮࢝ࣛࣂ࢚࣮ࣜࢩࣙࣥࢆᣢࡘ㧗ឤᗘ࢝ࣝࢩ࣒࢘࢖࢜ࣥࢭࣥࢧ࣮ࡢ㛤Ⓨ㸦Ọ஭㸧
෇㡰ิኚ␗࡟ࡼࡾ⺯ගࢱࣥࣃࢡ㉁ࢆศ๭ࡋࠊ㛫࡟࢝ࣝࢩ࣒࢘࢖࢜ࣥឤཷᛶࢻ࣓࢖ࣥ CaM ཬࡧᏳᐃ໬ࢻ
࣓࢖ࣥ M13 ࢆᑟධࡋࡓࠊ᪂つ࢝ࣝࢩ࣒࢘࢖࢜ࣥࢭࣥࢧ࣮GECO ࢩ࣮ࣜࢬࡢ㛤Ⓨࢆ⾜ࡗࡓࠋ࢝ࣝࢩ࣒࢘࢖
࢜ࣥ࡟ᑐࡍࡿឤཷᛶࡀ㧗࠸ࢭࣥࢧ࣮ࢆ㧗ຠ⋡࡟᥈⣴ࡍࡿࡓࡵ࡟ࠊ኱⭠⳦ෆ⭷࣭እ⭷㛫࡟┠ⓗࢱࣥࣃࢡ㉁
ࢆⓎ⌧ࡉࡏࠊእ㒊࠿ࡽࡢ࢝ࣝࢩ࣒࢘࢖࢜ࣥ⃰ᗘኚ໬࡟㧗ຠ⋡࡟ᛂ⟅ࡍࡿࢫࢡ࣮ࣜࢽࣥࢢࢩࢫࢸ࣒ࢆᵓ⠏
ࡋࡓࠋࡑࡢ⤖ᯝࠊࢲ࢖ࢼ࣑ࢵࢡࣞࣥࢪࡀ 2,600%࡜㧗࠸⺯ගᙉᗘኚ໬ࢆ♧ࡍ⥳Ⰽ࢝ࣝࢩ࣒࢘࢖࢜ࣥࢭࣥࢧ
࣮G-GECO ࢆ㛤Ⓨࡋࡓࠋࡉࡽ࡟ࠊኚ␗ࢆᑟධࡍࡿࡇ࡜࡟ࡼࡾࠊB-GECO, R-GECO, ࡉࡽ࡟㸯Ἴ㛗㸰Ἴ㛗
ගࢱ࢖ࣉ࡛࠶ࡿ GEM-GECO ࡢ㛤Ⓨ࡟ᡂຌࡋࡓࠋ
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ࠕ⎔ቃㄪ࿴ᮦᩱ࣭ࢹࣂ࢖ࢫࠖࣉࣟࢪ࢙ࢡࢺࢢ࣮ࣝࣉ
ᩍᤵ㸦ව௵㸧
ྜྷ⏣ 㝧୍㸦ࢢ࣮ࣝࣉ㛗㸧ࠊ┿ᔱ ဴᮁࠊ☾ᒣ ᝅᮁࠊ➲஭ ᏹ᫂ࠊ
ྂ⃝ Ꮥᘯࠊ㛵㔝 ᚭ
࣭㔞Ꮚࣅ࣮࣒ࢸࢡࣀࣟࢪ࣮ࢆ⏝࠸ࡓ⎔ቃㄪ࿴ᆺ཯ᛂࣉࣟࢭࢫࡢ◊✲
ྜྷ⏣ 㝧୍ ᩍᤵ㸦⏘◊㸧ඹྠ◊✲⪅㸸᳿ 㔠ᓠࠊ㏆⸨ ᏕᩥࠊⳢ ᫭୍
◊✲ᡂᯝせ᪨: 㔞Ꮚࣅ࣮࣒ࡀ⏕ᡂࡍࡿάᛶ✀࡟ࡼࡿ㓟໬㑏ඖ཯ᛂࡣࠊ⎔ቃ࡟ᨺฟࡉࢀࡿ࡜㠀ᖖ࡟᭷ᐖ࡞
㓟໬๣ࡸ㑏ඖ๣ࢆ⏝࠸ࡿᚲせࡀ↓ࡃࠊప⎔ቃ㈇Ⲵࡢ⎔ቃㄪ࿴ᆺ཯ᛂࣉࣟࢭࢫ࡛࠶ࡿࠋ㔞Ꮚࣅ࣮࣒ㄏ㉳཯
ᛂࡣࠊ㠀ᖖ࡟㧗㏿࡛࠶ࡾࠊࡇࢀࢆゎ᫂ࡍࡿࡓࡵ࡟ࣇ࢙࣒ࢺ⛊㟁Ꮚ⥺ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫࢆ㛤Ⓨࡋࡓࠋ୍
᪉ࠊ࢖࢜ࣥᾮయࡣࠊ୙⇞ᛶ࠿ࡘᴟప⵨Ẽᅽ࡛࠶ࡾࠊᏳ඲࠿ࡘ⎔ቃ࡬ࡢ᤼ฟ㔞ࡀᴟࡵ࡚ᑡ࡞࠸⎔ቃㄪ࿴ᆺ
ᮦᩱ࡛࠶ࡿࠋᮏᖺᗘࡣࠊ࢖࢜ࣥᾮయ࡟㔞Ꮚࣅ࣮࣒ࢆ↷ᑕࡍࡿࡇ࡜࡟ࡼࡗ࡚⁐፹࿴㟁Ꮚࢆ⏕ᡂࡋࠊⰾ㤶᪘
⁐㉁࡬ࡢ㟁Ꮚ⛣ື㸦㑏ඖ㸧཯ᛂࢆ◊✲ࡋࡓࠋ࢖࢜ࣥᾮయࢆ⏝࠸ࡓ㔞Ꮚࣅ࣮࣒ㄏ㉳㓟໬㑏ඖ཯ᛂࡣࠊ᪂ࡋ
࠸⎔ቃㄪ࿴ᆺ཯ᛂࣉࣟࢭࢫ࡛࠶ࡿࠋ
㐃ᦠࡢᐇ⦼ෆᐜࡢせ᪨: ஑኱ඛᑟ◊ከḟඖศᏊ㓄ิศ㔝࡜㐃ᦠࡋࠊศᏊෆ㟁Ⲵ⛣ືࡢ㉸㧗㏿ศග࡟ࡘ࠸
࡚◊✲㐃ᦠࡢ᳨ウࢆጞࡵࡓࠋ஑኱ඛᑟ◊࣑ࢡࣟࣉࣟࢭࢫไᚚศ㔝ࠊ஑኱ඛᑟ◊㧗ศᏊᮦᩱ≀ᛶᏛศ㔝࡜
࢖࢜ࣥᾮయࢆ⏝࠸ࡓ⎔ቃㄪ࿴ᆺ཯ᛂࣉࣟࢭࢫࡢ◊✲࡟ࡘ࠸࡚ࠊ◊✲㐃ᦠࡢ᳨ウࢆጞࡵࡓࠋ
࣭࣐ࢡ࣏࣮ࣟࣛࢫ㔠ᒓ࠾ࡼࡧࢼࣀ࣏࣮ࣛࢫᮦᩱࡢ〇ἲࠊ≀ᛶ࡜ᛂ⏝
୰ᔱ ⱥ㞝 ᩍᤵ㸦⏘◊㸧 ඹྠ◊✲⪅㸸ከ᰿ṇ࿴ࠊ௰ᮧ㱟௓ࠊ஭ᡭᣅဢ
◊✲ᡂᯝせ᪨: ࣐ࢡ࣏࣮ࣟࣛࢫ㔠ᒓ࡜ࡋ୍࡚᪉ྥᛶẼᏍࢆ᭷ࡍࡿ࣮ࣟࢱࢫ㔠ᒓࡢຊᏛ≉ᛶࡢゎ᫂࠾ࡼ
ࡧࢼࣀ࣏࣮ࣛࢫ㓟໬≀ࡢ᪂つ๰〇࡜࣏࣮ࣛࢫ໬ᶵᵓࡢゎ᫂ࢆᐇ᪋ࡋࡓࠋࡑࡢ⤖ᯝࠊ࣮ࣟࢱࢫⅣ⣲㗰ࡣ୍
᪉ྥᛶẼᏍ࡟㉳ᅉࡋࡓඃࢀࡓ⾪ᧁ࢚ࢿࣝࢠ࣮྾཰≉ᛶࢆ♧ࡍࡇ࡜➼ࢆ᫂ࡽ࠿࡟ࡋࡓࠋࡲࡓࠊ࢔ࣔࣝࣇ࢓
ࢫ㓟໬≀ⷧ⭷ࢆ㧗 ࡛࢔ࢽ࣮ࣝࡍࡿࡇ࡜࡟ࡼࡗ࡚ࠊⷧ⭷ෆ࡟㓄ྥᛶࢼࣀ࣎࢖ࢻࢆᙧᡂࡉࡏࡿ࡜࠸࠺᪂つ
ࢼࣀ࣏࣮ࣛࢫ໬ᡭἲࡢᵓ⠏࡟ᡂຌࡋࡓࠋࡲࡓࠊ࢔ࣔࣝࣇ࢓ࢫⷧ⭷ෆࡢᐦᗘࡺࡽࡂࡀ࣎࢖ࢻᙧᡂࡢせᅉ࡛
࠶ࡿࡇ࡜ࢆぢฟࡋࡓࠋ
㐃ᦠࡢᐇ⦼ෆᐜࡢせ᪨: ᮾ໭኱Ꮫከඖ◊୍Ⰽ◊✲ᐊ࡟ࡼࡾ Ar-10%H2 ࡢࣉࣛࢬ࣐࢔࣮ࢡ⁐ゎ࡟ࡼࡗ࡚స
〇ࡉࢀࡓ⣧ᗘ 99.997㸣ࡢ㧗⣧ᗘ Fe-12mass%ྜ㔠ࢆ㐃⥆ᖏ⁐⼥ἲ࡟ࡼࡗ࡚Ỉ⣲ 2.5MPaࠊ⛣ື㏿ᗘ 330
ȝms-1 ࡢ᮲௳୍࡛᪉ྥจᅛࡉࡏࡓࠋࡑࡢ⤖ᯝࠊ㧗⣧ᗘ㕲࡜ྠᵝ࡟⢒኱࡞ẼᏍࡀ⏕ᡂࡋࠊࡇࢀࡣྜ㔠୰ࡢ
୙⣧≀ࡀẼᏍࡢ᰾⏕ᡂࢧ࢖ࢺ࡜࡞ࡿྍ⬟ᛶࢆ♧၀ࡋ࡚࠸ࡿࠋ
࣭ࢼࣀ࣐ࢸࣜ࢔ࣝࡢࣅ࣮࣒ᶵ⬟໬Ꮫ
┿ᔱ ဴᮁ ᩍᤵ㸦⏘◊㸧 ඹྠ◊✲⪅㸸⸨ሯᏲࠊᕝ஭Ύᙪࠊ❧ᕝ㈗ኈࠊᓲṇᶒ
◊✲ᡂᯝせ᪨: ㉸ศᏊࠊ࢜ࣜࢦ࣐࣮ࠊ㧗ศᏊࠊDNAࠊࢱࣥࣃࢡࠊ㔠ᒓ㓟໬≀ࠊ༙ᑟయࠊ㔠ᒓ࡞࡝ࡢࢼ
ࣀ࣐ࢸࣜ࢔ࣝࡢ࣮ࣞࢨ࣮࠶ࡿ࠸ࡣᨺᑕ⥺↷ᑕ࡟ࡼࡿࣅ࣮࣒ᶵ⬟໬Ꮫ࡟㛵ࡍࡿ◊✲ࢆ⾜ࡗ࡚࠸ࡿࠋᮏᖺᗘ
ࡣࠊ DNA ෆ㟁Ⲵ⛣ືࠊTiO2 ගゐ፹཯ᛂࠊ㉸ศᏊෆ࢚ࢿࣝࢠ࣮⛣ື࣭㟁Ⲵ⛣ືࠊࢱࣥࣃࢡࡸ DNA ࡢࢲ
࢖ࢼ࣑ࢡࢫ࡞࡝ࢆゎ᫂ࡋࠊㄽᩥ࡜ࡋ࡚ሗ࿌ࡋࡓࠋ
㐃ᦠࡢᐇ⦼ෆᐜࡢせ᪨: ᫖ᖺ࡟⥆࠸࡚ࠊࢩࢡࣟࣇ࢓ࣥ໬ྜ≀ࡢྜᡂࢆᑓ㛛࡟ࡍࡿ஑኱ඛᑟ◊ࡢ᪂ྡ୺◊
✲ᐊ࡜ࡢ㐃ᦠඹྠ◊✲࡟ࡼࡾࠊࡇࢀࡽ໬ྜ≀ࡢ 77㹉๛య⁐፹୰࡛ࡢ Ȗ ⥺↷ᑕ࠾ࡼࡧࣃࣝࢫࣛࢪ࢜ࣜࢩࢫ
ࢆ⾜࠺ࡇ࡜࡟ࡼࡾࠊࢩࢡࣟࣇ࢓ࣥศᏊෆ㟁Ⲵ㠀ᒁᅾ໬࡟ࡘ࠸᳨࡚ウࡋࡓࠋࡲࡓࠊ⺯ග┦㛵ศගἲ࡟ࡼࡿ
⏕యศᏊࡢ◊✲ࢆ⾜ࡗ࡚࠸ࡿ஑኱ඛᑟ◊ࡢ୸ᒣ◊✲ᐊ࡜ࡢඹྠ◊✲࡟ࡼࡾࠊ୍ศᏊࣞ࣋ࣝ⺯ගほ ࡟ࡼ
ࡿ DNA ෆ㟁Ⲵศ㞳ᑑ࿨ࡢ ᐃࢆ⾜࠸ࠊ୍ሷᇶከᆺࡢㄞࡳฟࡋࢆ᳨ウࡋࡓࠋ
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࣭኱ᙉᗘࢸࣛ࣊ࣝࢶἼ※ࡢ㧗ᗘ໬࡜⎔ቃㄪ࿴ᮦᩱ◊✲࡬ࡢᛂ⏝
☾ᒣ ᝅᮁ ᩍᤵ㸦⏘◊㸧 ඹྠ◊✲⪅㸸ຍ⸨㱟ዲࠊධ⃝᫂඾ࠊᕝ℩ၨᝅ
◊✲ᡂᯝせ᪨: ⮬⏤㟁Ꮚ࣮ࣞࢨ࣮㸦FEL㸧ࢆ⏝࠸ࡓ኱ᙉᗘࢸࣛ࣊ࣝࢶἼ※ࡢ㧗ᗘ໬ࡢ୍⎔࡜ࡋ࡚ࠊ᫖ᖺ
ᗘ㛤Ⓨࡋࡓ FEL ࣃࣝࢫࡢ࢚ࢿࣝࢠ࣮ࢆቑᖜᅇᩘࡢ㛵ᩘ࡜ࡋ࡚ồࡵࡿᡭἲࢆ⏝࠸ࠊFEL ືస࡟኱ࡁ࡞ᙳ㡪
ࢆ୚࠼ࡿ FEL ቑᖜ⋡ࢆ ᐃࡋࡓࠋ㜰኱⏘◊ࡢࢸࣛ࣊ࣝࢶ FEL ࡢቑᖜ⋡ࡣἼ㛗 105ȝm ࡟ᑐࡋ࡚᭱኱ 58㸣
࡛ࠊࡑࡢගඹ᣺ჾ㛗౫Ꮡᛶࡣࢫ࣮ࣃ࣮࣮ࣔࢻ⌮ㄽࡢணゝ࡜Ⰻࡃ୍⮴ࡋࡓࠋFEL ࡢἼ㛗ࢫ࣌ࢡࢺࣝࢆ FEL
ࡢࣃ࣮࣡Ⓨᒎ࡜ඹ࡟ ᐃࡋࠊගඹ᣺ჾ㛗࡟ࡼࡿኚ໬ࢆồࡵࡓࠋࢫࣆࣥ೫ᴟࡋࡓ☢ᛶయࡸ࢝࢖ࣛࣜࢸ࢕࣮
ࢆᣢࡘගᏛ␗ᛶయࡢ◊✲࡟ࢸࣛ࣊ࣝࢶἼࢆ⏝࠸ࡿࡓࡵࠊ┤⥺೫ගࢆᣢࡘ FEL ග࠿ࡽ෇೫ගࢆⓎ⏕ࡍࡿヨ
㦂◊✲ࢆ⾜ࡗࡓࠋ
㐃ᦠࡢᐇ⦼ෆᐜࡢせ᪨: ඹྠ◊✲ࢆ⾜࠺◊✲ࢢ࣮ࣝࣉࢆぢฟࡍࡓࡵ࡟ᘬ⥆ࡁ࢔ࣛ࢖࢔ࣥࢫ඲య఍㆟ࡸ
ศ⛉఍࡛ᡃࠎࡢ◊✲ෆᐜࢆ⤂௓ࡍࡿ࡜ඹ࡟ࠊ௚ࢢ࣮ࣝࣉࡢ◊✲ෆᐜࢆㄪᰝࡋ࡚ࠊḟᖺᗘࡢඹྠ◊✲ࡢྍ
⬟ᛶࢆ᳨ウࡋࡓࠋ
࣭Į̺࢔ࢩࣝ࢜࢟ࢩ࢝ࣝ࣎ࢽࣝ໬ྜ≀ࡢ⎔ቃㄪ࿴ᆺゐ፹ⓗ୙ᩧྜᡂἲࡢ㛤Ⓨ
➲஭ ᏹ᫂ ᩍᤵ㸦⏘◊㸧 ඹྠ◊✲⪅㸸⃝ᚸࠊ➉୰࿴ᾈ
◊✲ᡂᯝせ᪨: ኳ↛⏺࡟ࡶᗈࡃぢࡽࢀࠊ་⸆ရཎᩱ࠾ࡼࡧ᭷ᶵྜᡂ୰㛫య࡜ࡋ࡚᭷⏝࡞ Į̺࢔ࢩࣝ࢜࢟
ࢩ࢝ࣝ࣎ࢽࣝ໬ྜ≀ࡣࠊࡇࢀࡲ࡛࣐ࣥ࢞ࣥࡸ㖄࡞࡝ẘᛶࡢ㧗࠸㔠ᒓ㓟໬๣ࢆ໬Ꮫ㔞ㄽ㔞௨ୖ⏝࠸࡚ྜᡂ
ࡉࢀ࡚࠸ࡓࠋ௒ᅇࠊᙜ◊✲ᐊ࡛㛤Ⓨࡋࡓ࢟ࣛࣝ㓄఩Ꮚ SPRIX ࢆᣢࡘࣃࣛࢪ࣒࢘ゐ፹ࡀ≉␗࡞཯ᛂᛶࢆ♧
ࡍࡇ࡜ࢆぢ࠸ࡔࡋࠊ㓟⣲ࢆ㓟໬๣࡜ࡍࡿ⎔ቃㄪ࿴ᛶ࡟ඃࢀࡓ Į̺࢔ࢩࣝ࢜࢟ࢩ࢝ࣝ࣎ࢽࣝ໬ྜ≀ࡢ᪂つ
ゐ፹ⓗ୙ᩧྜᡂἲࡢ๰ฟ࡟ᡂຌࡋࡓࠋ
㐃ᦠࡢᐇ⦼ෆᐜࡢせ᪨: ᫖ᖺᗘ࡟ᘬࡁ⥆࠸࡚ࠊྜᡂࡋࡓ᪂つ࢟ࣛࣝࢫࣆࣟ໬ྜ≀ࡢ⏕⌮άᛶ࡟㛵ࡍࡿ◊
✲ࢆᮾ໭኱ከඖ◊ࡢỌḟ◊✲ᐊ࡜ඹྠ࡛㐍ࡵ࡚࠸ࡿࠋ
࣭จ⦰┦୰࡟࠾ࡅࡿᨺᑕ⥺໬Ꮫึᮇ㐣⛬ࡢ◊✲
ྂ⃝Ꮥᘯ ᩍᤵ㸦⏘◊㸧ඹྠ◊✲⪅㸸ᑠᯘ୍㞝ࠊᒣᮏὒ᥹
◊✲ᡂᯝせ᪨: 㔞Ꮚࣅ࣮࣒ࡢ࢚ࢿࣝࢠ࣮ࢆ᭷ຠ࡟฼⏝ࡋࡓ┬࢚ࢿࣝࢠ࣮࣭┬㈨※ᕤᴗࣉࣟࢭࢫࡢ㛤Ⓨࢆ
┠ⓗ࡟ࠊᚤ⣽ຍᕤᮦᩱ୰ࡢ㓟ゐ፹཯ᛂࡢ཯ᛂᶵᵓࢆゎ᫂ࡋࡓࠋࡉࡽ࡟ࠊ⎔ቃࢭࣥࢧ࣮ࡢ㛤Ⓨࢆ┠ⓗ࡟ࠊ
⏕య୰࡟Ꮡᅾࡍࡿ⎔ቃᛂ⟅ศᏊࡢᛂ⟅ᶵᵓࢆᨺᑕ⥺໬Ꮫⓗᡭἲ࡟ࡼࡾゎ᫂ࡋࡓࠋ
㐃ᦠࡢᐇ⦼ෆᐜࡢせ᪨: ᮾ໭኱ከඖ◊ࡢ⏕య㧗ศᏊ໬Ꮫ◊✲ศ㔝㸦ΎỈ◊㸧࡜㐃ᦠࡋࠊ㓟⣲ࢭࣥࢧ࣮ࡢ
⎔ቃ㓟⣲⃰ᗘ࡬ࡢᛂ⟅ᶵᵓࢆゎ᫂ࡋࡓࠋ
― 137 ―
［ 附 3 ］ 共通施設、技術室、事務部の組織と活動
ヨసᕤሙ
ᕤሙ㛗㸦ව௵㸧ᩍᤵ Ᏻ⸽ ⰾ㞝
ᢏ⾡⫋ဨ㸦ᢏ⾡ᐊᡤᒓ㸧 ᶵᲔຍᕤᐊ ኱す ᨻ⩏ࠊᯇୗ 㞝㈗ࠊゅ୍ 㐨᫂
࢞ࣛࢫຍᕤᐊ ᯇᕝ ༤᫛ࠊᑠᕝ ⣖அ
a) ᴫせ
ヨసᕤሙࡣᶵᲔຍᕤᐊ࡜࢞ࣛࢫຍᕤᐊ࠿ࡽᵓᡂࡉࢀ࡚࠾ࡾࠊ⏘ᴗ⛉Ꮫ◊✲ᡤタ⨨࡜ྠ᫬࡟௜タࡉࢀࡓࠋ
⌧ᅾࡣࠊᮏ◊✲ᡤࡢ୰ᚰ㒊࡛฼౽ᛶࡢⰋ࠸࢖࣮ࣥ࢟ࣗ࣋ࢩࣙࣥᲷ࡟⨨࠿ࢀ࡚࠸ࡿࠋᮏ◊✲ᡤ࡟࠾ࡅࡿ◊
✲ศ㔝ࡣከᒱ࡟ࢃࡓࡾࠊ౑⏝ࡉࢀࡿᐇ㦂⿦⨨ࡣከᵝ࡛࠿ࡘ᩾᪂࡞⿦⨨ࡀከ࠸ࠋヨసᕤሙࡣࡇࢀࡽࢆ⏝࠸
ࡓ◊✲ᶵ⬟ࢆ᭱኱㝈࡟Ⓨ᥹ࡉࡏࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚࠸ࡿࠋࡑࡢࡓࡵ࡟ࠊ✀ࠎࡢ⌮⛉Ꮫᐇ㦂⿦⨨ࡸᐇ㦂ჾ
ලࢆヨసẁ㝵࠿ࡽ◊✲⪅࡜⥥ᐦ࡞㐃ᦠࢆಖࡕ࡞ࡀࡽࠊタィ࣭〇సࡋࠊ◊✲ᨭ᥼ࢆᒎ㛤ࡋ࡚࠸ࡿࠋCNC ᪕
┙ࠊCNC ෇⟄◊๐┙ࠊ5 ㍈ຍᕤᶵࢆࡣࡌࡵᶵᲔタഛࡢ඘ᐇࢆᅗࡾࠊຍᕤ⠊ᅖࡢᣑ඘࣭㧗⢭ᗘ໬࡞࡝࡟ດ
ࡵ࡚࠸ࡿࠋ
b) ᡂᯝ
௒ᖺᗘࡣࠊ◊✲ᨭ᥼᥎㐍ဨ㸦ᶵᲔຍᕤᐊ㸧ࢆྵࡵ 5 ྡయไ࡛ࠊከࡃࡢ౫㢗ࢆฎ⌮ࡍࡿ஦ࡀฟ᮶ࡓࠋ ࡲ
ࡓࠊᢏ⾡ᐊ࡜ࡋ࡚ྲྀࡾ⤌ࡴࠊ⏘◊࣭㜰኱ࡢ࢖࣋ࣥࢺ㸦Ᏻ඲ㅮ⩦఍࣭࠸ࡕࡻ࠺⚍࣭ࡶࡢ࡙ࡃࡾᩍᐊ㸧࡞࡝
࡟ᐊဨ඲ဨ࡛ཧຍ࣭༠ຊࡋࠊ⏘◊࠾ࡼࡧᆅᇦ࡟㈉⊩࡛ࡁࡓࠋ ࡉࡽ࡟ࠊᢏ⾡ᐊሗ࿌఍ࡢ㛤ദࢆࡣࡌࡵࠊ
ᢏ⾡◊✲఍ࠊࢩ࣏ࣥࢪ࣒࢘ࠊㅮ⩦఍࡞࡝࡟ཧຍࡋࠊ⮬ᕫ◊㛑࡟ດࡵ࡚࠸ࡿࠋ
[ᖺ㛫౫㢗ฎ⌮௳ᩘ]
㸱㸮㸶௳㸦๓ᖺᗘ㸱㸯㸴௳㸧
[ᶵᲔຍᕤᐊ 㸯㸷㸯௳㸦๓ᖺᗘ㸰㸮㸱௳㸧ࠊ࢞ࣛࢫຍᕤᐊ 㸯㸯㸵௳㸦๓ᖺᗘ㸯㸯㸱௳㸧]
― 141 ―
ᨺᑕ⥺ྠ఩ඖ⣲ᐇ㦂ᐊ
ᐊ㛗㸦ව௵㸧ᩍᤵ
☾ᒣ ᝅᮁ
a) ᴫせ
ᮏᐇ㦂ᐊࡣࠊᨺᑕ⥺ྠ఩ඖ⣲ࡢ࠺ࡕࠊ㠀ᐦᑒࡢ 3H, 14C, 32P, 33P, 35S ࢆྵࡴ≀㉁ࢆྲྀࡾᢅ࠺ᐇ㦂ࡢࡓࡵࡢ
᪋タ࡛࠶ࡿࠋᮏᐇ㦂ᐊ࡟ࡣࠊᨺᑕ⥺ィ ࡟⏝࠸ࡿᾮయࢩࣥࢳ࣮ࣞࢩࣙࣥ࢝࢘ࣥࢱ࣮ࡸࣂ࢖࢜࢖࣓࣮ࢪࣥ
ࢢ࢔ࢼࣛ࢖ࢨ࣮㸦FLA3000㸧ࡀタ⨨ࡉࢀ࡚࠸ࡿࠋࡇࢀࡽࡢタഛࢆ⏝࠸ࠊ໬ྜ≀ࡢྠ఩ඖ⣲࡟ࡼࡿᶆ㆑ࡸࠊ
ᶆ㆑໬ྜ≀ࢆ⏝࠸ࡓ⏕໬ᏛⓗࠊศᏊ⏕≀Ꮫⓗཬࡧ⣽⬊⏕≀Ꮫⓗᐇ㦂ࡀ⾜ࢃࢀࠊࢱࣥࣃࢡ㉁ࡸ㑇ఏᏊࡢᵓ
㐀࡜ᶵ⬟ࡢゎ᫂ࡢࡓࡵ࡟኱ࡁ࡞ᙺ๭ࢆᯝࡓࡋ࡚࠸ࡿࠋᩍ⫋ဨࡸᏛ⏕㸦ᨺᑕ⥺ྠ఩ඖ⣲ྲྀᢅᩍ⫱カ⦎ཷㅮ
⪅㸧ࡀᖺ㛫ࢆ㏻ࡋ࡚฼⏝ࡋ࡚࠾ࡾࠊᨺᑕ⥺㞀ᐖண㜵つᐃ࡟๎ࡋࡓ⥔ᣢ⟶⌮ࡀ⾜ࢃࢀ࡚࠸ࡿࠋ
b) ᡂᯝ
ᮏᖺᗘࡣᨺᑕᛶྠ఩ඖ⣲౑⏝ᐇ㦂࡜ࡋ࡚௨ୗࡢ⥅⥆◊✲ㄢ㢟ࡀᐇ᪋ࡉࢀࡓࠋ
᝟ሗఏ㐩≀㉁᤼ฟ㍺㏦యࡢྠᐃ࡜ᶵ⬟ゎᯒ㸦⏕యศᏊไᚚ⛉Ꮫ◊✲ศ㔝㸧
࣐࢘ࢫཬࡧࣛࢵࢺࡢྛ⤌⧊࠿ࡽࡢ cDNA ࣛ࢖ࣈ࣮ࣛࣜࡢᵓ⠏㸦⏕యศᏊไᚚ⛉Ꮫ◊✲ศ㔝㸧
㓟໬ࢫࢺࣞࢫ࡟ࡼࡿ㑇ఏᏊᦆയࡢศᏊᶵᵓ㸦㔞Ꮚࣅ࣮࣒≀㉁⛉Ꮫ◊✲ศ㔝㸧
ᨺᑕ⥺ྠ఩ඖ⣲ᐇ㦂ᐊࢆ౑⏝ࡋ࡚ᚓࡽࢀࡓ◊✲ࡢᡂᯝࡣྛ◊✲ᐊࡢ㡫࡟ࡲ࡜ࡵࡽࢀ࡚࠸ࡿࠋ
― 142 ―
㟁Ꮚࣉࣟࢭࢫᐇ㦂ᐊ
ᐊ㛗㸦ව௵㸧ᩍᤵ
෸ᩍᤵ㸦ව௵㸧 ෸ᩍᤵ㸦ව௵㸧 ෸ᩍᤵ㸦ව௵㸧 ᯇᮏ ࿴ᙪ
㛗㇂ᕝ ⦾ᙪ
㡲⸨ Ꮥ୍
๓ᶫ ව୕
a) ᴫせ
㟁Ꮚࣉࣟࢭࢫᐇ㦂ᐊࡣࠊᖹᡂ 3 ᖺ㸦1991㸧࡟タ⨨ࡉࢀࡓࡶࡢ࡛࠶ࡿࠋᙜᐇ㦂ᐊࡣࠊࢼࣀࢸࢡࣀࣟࢪ࣮
࠾ࡼࡧ㛵㐃ᇶ┙◊✲ࢆ᥎㐍ࡍࡿࡓࡵ࡟ࠊග࣭㟁Ꮚᮦᩱࠊ㔞ᏊศᏊ⣲Ꮚᮦᩱࠊ᭷ᶵ⣲Ꮚᮦᩱ࡞࡝࡟㛵㐃ࡋ
ࡓ◊✲࡛ᚲせ࡜ࡉࢀࡿඹ㏻ࡢࣉࣟࢭࢫ㛵ಀࡢ⿦⨨ࢆタ⨨ࡋࠊ࠸ࢁ࠸ࢁ࡞⣲Ꮚᮦᩱࡢࣉࣟࢭࢫᢏ⾡ࡢྥୖ
ࢆࡣ࠿ࡗ࡚◊✲ࡢᒎ㛤࡟ᙺ❧࡚ࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚࠸ࡿࠋ
タഛ࡜ࡋ࡚ࡣࠊ↓㡪ᐊࠊᑠつᶍࢡ࣮࣮࣒ࣜࣥࣝࠊ⾲㠃ᵓ㐀ࢆㄪ࡭ࡿࡓࡵࡢཎᏊ㛫ຊ㢧ᚤ㙾࣭ࢹࢪࢱࣝ
ගᏛ㢧ᚤ㙾ࠊࣃࢱ࣮ࣥᙧᡂࢆ⾜࠺ࡓࡵࡢࣇ࢛ࢺࣜࢯࢢࣛࣇ࢕⿦⨨࣭⅊໬⿦⨨ࠊྛ✀ࡢ⤯⦕ᒙ࣭㟁ᴟᙧᡂ
ࢆ⾜࠺ࡓࡵࡢࢫࣃࢵࢱⷧ⭷ᙧᡂ⿦⨨࣭┿✵⵨╔⿦⨨࣭㟁Ꮚࣅ࣮࣒⵨╔⿦⨨ࠊᚤ⣽ຍᕤࢆ⾜࠺ࡓࡵࡢ཯ᛂ
ᛶ࢖࢚࢜ࣥࢵࢳࣥࢢ⿦⨨ࠊ➃㠃ᙧᡂࡢࡓࡵࡢ๼㛤ᶵࠊ㓄⥺ࡢࡓࡵࡢ࣡࢖࣮ࣖ࣎ࣥࢲ࣮⿦⨨࡞࡝ࡀタ⨨ࡉ
ࢀ࡚࠸ࡿࠋ
b) ᡂᯝ
ᙜᐇ㦂ᐊࡣࠊࢼࣀࢸࢡࣀࣟࢪ࣮ࢭࣥࢱ࣮࠾ࡼࡧ㛵㐃◊✲ᐊ࡛ࡢྛ✀ᮦᩱ࡟ᑐࡍࡿᵓ㐀ゎᯒࠊ⾲㠃ゎᯒࠊ
㟁ᴟᙧᡂࡢᐇ㦂◊✲ࡸࠊࡇࢀࡽࢆࡶ࡜࡟ྛ✀ᮦᩱࡢ㟁Ẽⓗᛶ㉁➼ࡢ ᐃࠊග⣲Ꮚࠊ㟁Ꮚ⣲ᏊࠊศᏊ⣲Ꮚ
࡞࡝ࡢヨస➼࡟ᐤ୚ࡋ࡚࠸ࡿࠋࡲࡓࠊ࣮ࣘࢨ࡟ᑐࡋ⿦⨨౑⏝᪉ἲࡢᣦᑟࠊྛ⿦⨨ࡢ࣓ࣥࢸࢼࣥࢫࠊಖᏲ
Ⅼ᳨ࠊಟ⌮࡞࡝ࢆ⾜ࡗ࡚࠸ࡿࠋᮏᖺᗘࡣ ◊✲ᐊ࣭ᐊࡢ฼⏝ࡀ࠶ࡗࡓࠋ
― 143 ―
ᅗ᭩ᐊ
ᐊ㛗㸦ව௵㸧ᩍᤵ
Ⳣ἟ ඞ᫛ ᅗ᭩⫋ဨ
࿴⏣ ᏕᏊ
஦ົ⿵బဨ
㧘⏣㤶㒔Ꮚ
ᴫせ
ᮏᅗ᭩ᐊࡣࠊᑓ㛛ⓗᅗ᭩ࢆᡤⶶࡋࠊ⟶⌮Ჷ஧㝵࡟㛤ᯫᅗ᭩ᐊࡀタࡅࡽࢀ࡚࠸ࡿࠋᅗ᭩ࡢⓎὀࠊཷධཬ
ࡧᩥ⊩ࡢᡤᅾㄪᰝࡸ↷఍ࠊ」෗ࡢ⏦ࡋ㎸ࡳࡸཷ௜ᴗົࠊᅗ᭩㤋㛫┦஫㈚೉ࢆ⾜ࡗ࡚࠸ࡿࠋཪࠊ฼⏝᱌ෆ
࡞࡝ࢆ࣮࣒࣮࣍࣌ࢪhttp://www.sanken.osaka-u.ac.jp/labs/lib-web/࡟ᥖ♧ࡋ࡚࠸ࡿࠋ
࠙ⶶ᭩ᩘࠚ ࿴ᩥᅗ᭩ 5,164 ෉ ࿴㞧ㄅ 165 ✀ ᪂⪺ 6 ✀
Ḣᩥᅗ᭩ 19,576 ෉ ὒ㞧ㄅ 502 ✀
࠙ᖹᡂ 26 ᖺᗘཷධᅗ᭩ᩘࠚ 146 ෉
࠙ᖹᡂ 26 ᖺᗘ୙⏝ᅗ᭩㝖༷ᩘࠚ 0 ෉
࠙ᖹᡂ 26 ᖺᗘ฼⏝⤫ィࠚ⏘◊ᅗ᭩ᐊ࡛ࡢ㈚ฟᩘ㸦Ꮫෆ࣭Ꮫእ࠿ࡽࡢྲྀᐤࡏ㈨ᩱྵࡴ㸧785 ෉
Ꮫෆ 9 ᅗ᭩㤋ᐊ࡬ࡢ⏘◊ᡤⶶ㈨ᩱ㈚ฟᩘ 95 ෉
Ꮫෆ࣭Ꮫእ࠿ࡽࡢᩥ⊩」෗ྲྀᐤࡏᩘ33 ௳
Ꮫෆ࡬ࡢᩥ⊩」෗ᥦ౪ᩘ21 ௳
㸦ᖹᡂ 27 ᖺ 3 ᭶ 31 ᪥⌧ᅾ㸧
― 144 ―
᪋タ⟶⌮ᐊ
ᩍᤵ㸦ව௵㸧
ྂ⃝ Ꮥᘯ
≉௵஦ົ⿵బဨ ኱ᶫ ె௦Ꮚ
a) ᴫせ
᪋タ⟶⌮ᐊࡣ⏘ᴗ⛉Ꮫ◊✲ᡤࡢ࣮࢜ࣉࣥࣛ࣎ࣛࢺ࣮ࣜ㸦௨ୗࠕ࣮࢜ࣉࣥࣛ࣎ࠖ࡜࠸࠺ࠋ㸧ཬࡧ◊✲ศ
㔝ᇶ‽ࢫ࣮࣌ࢫࡢ෇⁥࡞⟶⌮୪ࡧ࡟⏘ᴗ⛉Ꮫ◊✲ᡤࡢ᪋タࡢ෇⁥࡞⟶⌮ࡢࡓࡵࠊḟࡢྛྕ࡟ᥭࡆࡿᴗົ
ࢆ⾜ࡗ࡚࠸ࡿࠋ
(1)
(2)
(3)
(4)
(5)
(6)
࣮࢜ࣉࣥࣛ࣎ࡢᩚഛ࡟㛵ࡍࡿࡇ࡜ࠋ
࣮࢜ࣉࣥࣛ࣎ࡢ⥔ᣢ⟶⌮࡟㛵ࡍࡿࡇ࡜ࠋ
࣮࢜ࣉࣥࣛ࣎ࡢ฼⏝⏦ㄳ➼࡟㛵ࡍࡿࡇ࡜ࠋ
◊✲ศ㔝ᇶ‽ࢫ࣮࣌ࢫࡢ⟶⌮࡟㛵ࡍࡿࡇ࡜ࠋ
⏘ᴗ⛉Ꮫ◊✲ᡤ᪋タጤဨ఍ࡀ௻⏬❧᱌ࡍࡿ᪋タࡢ㐠⏝ィ⏬ࡢ⿵ຓ࡟㛵ࡍࡿࡇ࡜ࠋ
ࡑࡢ௚⏘ᴗ⛉Ꮫ◊✲ᡤࡢࢫ࣮࣌ࢫ⟶⌮࡟㛵ࡍࡿࡇ࡜ࠋ
b) ᡂᯝ
2014 ᖺᗘࢼࣀࢸࢡ࣮࢜ࣉࣥࣛ࣎ࡢ฼⏝ࡣࠊ௨ୗ࡟♧ࡍ 15 ࡢ◊✲௦⾲⪅ࠋ
◊✲௦⾲⪅
᳃ຬ௓ ᩍᤵ
᳃ᓥᆂ♸ ᩍᤵ
⃅㇂㝧஧ ᩍᤵ
ᡤᒓ
ᕤᏛ◊✲⛉
ᕤᏛ◊✲⛉
ᕤᏛ◊✲⛉
⟪ᓥᘯ஧ ᩍᤵ
ᕤᏛ◊✲⛉
ᖹཎె⧊ ෸ᩍᤵ
ᕤᏛ◊✲⛉
ྜྷᓮ࿴ᖾ
⸨ཎᗣᩥ
㧗ᶫᖾ⏕
⚟⏣Ṋྖ
໭㔝຾ஂ
ᕤᏛ◊✲⛉
ᕤᏛ◊✲⛉
ᕤᏛ◊✲⛉
ᕤᏛ◊✲⛉
ᕤᏛ◊✲⛉
≉௵ᩍᤵ
ᩍᤵ
෸ᩍᤵ
ᩍᤵ
෸ᩍᤵ
◊✲௦⾲⪅
ఀᮾ୍Ⰻ ≉௵ᩍᤵ
ᑠᯘග ᩍᤵ
ᯇᮏ࿴ᙪ ᩍᤵ
⏣୰⚽࿴ ᩍᤵ
㇂ཱྀṇ㍤ ᩍᤵ
― 145 ―
ᡤᒓ
⏘Ꮫ㐃ᦠᮏ㒊
⏘ᴗ⛉Ꮫ◊✲ᡤ
⏘ᴗ⛉Ꮫ◊✲ᡤ
ࢼࣀࢸࢡࣀࣟࢪ࣮タഛ౪
⏝ᣐⅬ
ࢼࣀࢸࢡࣀࣟࢪ࣮タഛ౪
⏝ᣐⅬ
᝟ሗࢿࢵࢺ࣮࣡ࢡᐊ
ᐊ㛗㸦ව௵㸧ᩍᤵ
ᩍᤵ㸦ව௵㸧
ᩍᤵ㸦ව௵㸧
ᩍᤵ㸦ව௵㸧
ᩍᤵ㸦ව௵㸧
෸ᩍᤵ㸦ව௵㸧 ෸ᩍᤵ㸦ව௵㸧 ᢏ⾡⫋ဨ
ྜྷ⏣
㮖ᑿ
㇂ᮧ
➲஭
ᑠཱྀ
ྂᓮ
ΎỈ
┦ཎ
㝧୍
㝯
ඞᕫ㻌
ᏹ᫂
ከ⨾ኵ
᫭ྖ
ᫀᖹ
༓ᑜ
a) ᴫせ
᝟ሗࢿࢵࢺ࣮࣡ࢡᐊࡣࠊ㏆ᖺࡢ◊✲⎔ቃ࡟࠾ࡅࡿ᝟ሗࢿࢵࢺ࣮࣡ࢡࡢᛴ㏿࡞ᬑཬ࡜㔜せᛶࢆ㚷ࡳࠊ
ࡇࢀࡲ࡛ࡢ࣎ࣛࣥࢸ࢕࢔࣮࣋ࢫࡢᡤෆ᝟ሗࢿࢵࢺ࣮࣡ࢡࡢ㐠Ⴀࢆ⤌⧊໬ࡍࡿⅭ࡟ࠊ1999 ᖺ 3 ᭶࡟Ⓨ㊊ࡋ
ࡓࠋᡤෆ᝟ሗࢿࢵࢺ࣮࣡ࢡࡣࠊ1980 ᖺ௦ᚋ༙࡟▱⬟ࢩࢫࢸ࣒⛉Ꮫ኱㒊㛛ࡢ◊✲ᐊࡀඹྠ࡛ᵓ⠏ࡋࠊ1994
ᖺࡢ ODINS(Osaka Daigaku Information Network System)ࡢ㐠⏝㛤ጞ࡟క࠸◊✲ᡤ඲యつᶍ࡛ᩚഛࡉࢀࡓࠋ
⌧ᅾ࡛ࡣࠊ⏘ᴗ⛉Ꮫ◊✲ᡤ࡟ᦠࢃࡿேࠎ࡟᝟ሗࡢⓎಙ࣭ཷಙࡢሙࢆᥦ౪ࡋ࡚࠸ࡿࠋ᝟ሗࢿࢵࢺ࣮࣡ࢡᐊ
࡛ࡣᐊ㛗ࡢࡶ࡜ࠊᢏ⾡ᐊࡼࡾὴ㐵ࡉࢀࡓᢏ⾡⫋ဨ࡟ࡼࡾ⏘ᴗ⛉Ꮫ◊✲ᡤࢿࢵࢺ࣮࣡ࢡࡢᏳᐃ㐠⏝ࡣࡶ࡜
ࡼࡾࢿࢵࢺ࣮࣡ࢡ࣏ࣜࢩ࣮ࡢ⟇ᐃࠊᩚഛ࡟࠾ࡅࡿᢏ⾡ⓗసᴗࢆࡣࡌࡵࠊྛ✀ࢧ࣮ࣂ࣮ࡢᵓ⠏࣭⟶⌮ࠊྛ
✀ࢩࢫࢸ࣒ࡢᵓ⠏࣭⟶⌮ࠊ฼⏝⪅࣭◊✲⪅ࡢࢧ࣏࣮ࢺ࣭ᩍ⫱ࢆ⾜ࡗ࡚࠸ࡿࠋࡲࡓࠊ⏘ᴗ⛉Ꮫ◊✲ᡤࡢ᪊
ࡅࡿྛ✀ࢩ࣏ࣥࢪ࣒࢘ࠊㅮ₇఍➼ࡢࢧ࣏࣮ࢺࡢ୍⎔࡜ࡋ࡚ WEB సᡂࢆ⾜࠸ࠊࣞࢪࢫࢺ࣮ࣞࢩࣙࣥࠊ࢔
ࣈࢫࢺࣛࢡࢺ཰㞟ࢩࢫࢸ࣒➼ࢆᥦ౪ࡋ࡚࠸ࡿࠋࡲࡓࠊ◊✲ᡤධ㤋⟶⌮ࢩࢫࢸ࣒ࠊ㟁Ꮚᥖ♧ᯈࠊ┘ど࣓࢝
ࣛࡢ㐠⏝࣭⟶⌮ࡶ⾜ࡗ࡚࠸ࡿࠋࡲࡓࠊᴗ⦼ホ౯ࢩࢫࢸ࣒ࠊᖺḟሗ࿌᭩⦅㞟ࢩࢫࢸ࣒ࠊཎⴭㄽᩥ࣭ᅜ㝿఍
㆟ࢹ࣮ࢱ࣮཰㞟ࢩࢫࢸ࣒➼ከᩘࡢᡤෆྥࡅࢩࢫࢸ࣒ࡢ㛤Ⓨ࣭㐠⏝࣭⟶⌮ࢆ⾜ࡗ࡚࠸ࡿࠋࡲࡓࠊ௒ᖺᗘࡼ
ࡾࢢࣛࣇ࢕࢝ࣝࣉࣟࢢ࣑ࣛࣥࢢࢯࣇࢺ࢙࢘࢔࡛࠶ࡿ LabVIEW ࢆ඲Ꮫⓗ࡟ᑟධࡋࠊ࢟ࣕࣥࣃࢫࣛ࢖ࢭࣥ
ࢫࡢ⟶⌮ࠊ࣮ࣘࢨ࣮ࢧ࣏࣮ࢺࢆ⾜ࡗ࡚࠸ࡿࠋ
b) ᡂᯝ
[ ࢩ࣏ࣥࢪ࣒࢘➼ࢧ࣏࣮ࢺ ]
The 18th SANKEN International Symposium, ISIR, Osaka University, The 13th SANKEN
Nanotechnology Symposium, ISIR, Osaka University, 2nd KANSAI Nanoscience and
Nanotechnology International Symposium, 10th Handai Nanoscience and Nanotechnology
International Symposium
㝃⨨◊✲ᡤ㛫࢔ࣛ࢖࢔ࣥࢫ࡟ࡼࡿࢼࣀ࡜࣐ࢡࣟࢆࡘ࡞ࡄ≀㉁࣭ࢹࣂ࢖ࢫ࣭ࢩࢫࢸ࣒๰〇ᡓ␎ࣉࣟࢪ࢙ࢡ
ࢺ㸫ᖹᡂ 25 ᖺᗘᡂᯝሗ࿌఍㸫
2nd SANKEN Core to Core Symposium & 3rd imec Handai International Symposium
ᖹᡂ 26 ᖺᗘ ࢼࣀᕤᏛㅮ⩏
ඹྠ◊✲ᣐⅬ୍⯡◊✲ㄢ㢟⏦㎸
ࡶࡢ࡙ࡃࡾᩍᐊ
[ ࢩࢫࢸ࣒㛵㐃 ]
ࢧ࣮ࣂ࣮ࢭ࢟ࣗࣜࢸ࢕እ㒊┘ᰝ
PKI ࣉࣟࢪ࢙ࢡࢺ(ᅜ❧᝟ሗᏛ◊✲ᡤ)
ᩍဨᴗ⦼ホ౯
[ ࢿࢵࢺ࣮࣡ࢡ㛵㐃 ]
― 146 ―
ODINS ↓⥺ LAN タ⨨
[ ጤဨ఍ ]
ᴗ⦼ホ౯ጤဨ఍
ODINS 㐠⏝㒊఍
[ ࡑࡢ௚ ]
ྛ✀ࢧ࣮ࣂ࣮⟶⌮
LabVIEW ࢟ࣕࣥࣃࢫࣛ࢖ࢭࣥࢫ⟶⌮
࣏ࢫࢱ࣮༳ๅ㸦587 ௳㸧
ISIR(ධ㏥㤋)࣮࢝ࢻⓎ⾜
࣮ࣘࢨ࣮Ⓩ㘓
― 147 ―
⏘Ꮫ㐃ᦠᐊ
ᐊ㛗㸦ව௵㸧ᩍᤵ
ᩍᤵ㸦ව௵㸧
≉௵ᩍᤵ㸦ව௵㸧
Ọ஭ ೺἞
ᯇᮏ ࿴ᙪࠊᑠᯘ ගࠊᑠཱྀ ከ⨾ኵ
ΎỈ ⿱୍ࠊᑠ಴ ᇶḟ
a) ᴫせ
⏘Ꮫ㐃ᦠᐊࡣࠊ⏘ᴗ⛉Ꮫ◊✲ᡤ㸦⏘◊㸧ࡢ◊✲ᡂᯝࢆ♫఍࡟㑏ඖࡍࡿࡇ࡜ࢆ┠ⓗ࡜ࡋ࡚ࠊ⏘◊࡜⏘ᴗ
⏺࡜ࡢ㐃ᦠάືࡢ᥎㐍࣭ᨭ᥼ࢆ⾜ࡗ࡚࠸ࡿࠋ୺࡞ᴗົࡣࠊ⏘◊࡜⏘ᴗ⏺࡜ࡢ⦓ᐦ࡞ࢿࢵࢺ࣮࣡ࢡࡢᵓ⠏ࠊ
⏘ᴗ⏺࠿ࡽࡢせᮃࠊせㄳ࡟ᛂࡌࡿࡼ࠺࡞◊✲ࢩ࣮ࢬࡢ⤂௓ࠊ⏘◊ࡢ◊✲ᡂᯝ࡛࠶ࡿࢩ࣮ࢬ࡜⏘ᴗ⏺ࡢࢽ
࣮ࢬ࡜ࡢᦾࡾྜࢃࡏ➼࡛࠶ࡿࠋࡲࡓࠊ᪂⏘ᴗࡢ๰ฟ࡟ྥࡅ࡚᪂ࡋ࠸ศ㔝ࡢ◊✲㡿ᇦ๰ฟࡢᥦ᱌ࠊࡉࡽ࡟ࠊ
⏘ᴗ⏺࠿ࡽࡢせㄳ࡟ࡼࡿ◊✲㛤Ⓨ༠ຊ஦ᴗࡢ᥎㐍άືࢆ⾜ࡗ࡚࠸ࡿࠋ
b) ᡂᯝ
࣭⏘Ꮫ㐃ᦠಁ㐍㸦◊✲ᡂᯝ࠾ࡼࡧᢏ⾡ࢩ࣮ࢬࡢ⏘ᴗ⏺࡬ࡢ⤂௓㸧
ձ⏘◊ࢸࢡࣀࢧࣟࣥ㛤ദ㸸4 ᅇ
㸺㛤ദᅇ㸼 㸺㛤ദ᪥㸼
㸺ࢸ࣮࣐㸼
㸺ཧຍேᩘ㸼
➨ 1 ᅇ ᖹᡂ 26 ᖺ 5 ᭶ 9 ᪥ ࠕ⏘ᴗ⛉Ꮫࡢ᪂ࡓ࡞ᒎ㛤㸫Ᏻ඲࣭Ᏻᚰࢆᨭ࠼ࡿ㸫ࠖ 70 ྡ
➨ 2 ᅇ ᖹᡂ 26 ᖺ 8 ᭶ 1 ᪥ ࠕ኱Ꮫᩍᤵࡀㄒࡿᮍ᮶ࢆ㛤ࡃ᪂⛉Ꮫᢏ⾡ࠖ
74 ྡ
➨ 3 ᅇ ᖹᡂ 26 ᖺ 11 ᭶ 7 ᪥ ࠕᮍ᮶ࢆᢸ࠺⏘ᴗ⛉Ꮫࡢ㌍㐍ࢆ┠ᣦࡋ࡚ࠖ 84 ྡ
㸦๰❧ 75 ࿘ᖺグᛕ⏘◊ࢸࢡࣀࢧ࣭ࣟࣥࢫ࣌ࢩࣕࣝ㸧
➨ 4 ᅇ ᖹᡂ 27 ᖺ 2 ᭶ 6 ᪥ ࠕ♫఍ࢆኚ࠼ࡿ᪂ᮦᩱࠖ㻌 㻌
㻌
㻌
63 ྡ
ղ⏘Ꮫ㐃ᦠᐊ࣮࣒࣮࣍࣌ࢪ࡟࠾ࡅࡿࠊᢏ⾡ࢩ࣮ࢬ⤂௓ࠋ
http://www.sanken.osaka-u.ac.jp/labs/air/research1.html
ճ◊✲ෆᐜࡢ⏘ᴗ⏺ྥࡅ⤂௓෉Ꮚࠕ◊✲⤂௓ࣜࢧ࣮ࢳ 2015ࠖࡢⓎ⾜ࠋ
մᒎ♧఍ฟᒎࠊ࣐ࢵࢳࣥࢢ࢖࣋ࣥࢺཧຍ㸸8 ௳㸦㛤ദ᪥ࠊ఍ሙ㸧
࢖ࣥࢱ࣮ࣇ࢙ࢵࢡࢫࢪࣕࣃࣥ㸦ᖹᡂ 26 ᖺ 7 ᭶ 2,3,4 ᪥ࠊᮾிࣅࢵࢢࢧ࢖ࢺ㸧
JST ᪂ᢏ⾡ㄝ᫂఍㸦ᖹᡂ 26 ᖺ 7 ᭶ 18 ᪥ࠊJST ᮾிู㤋࣮࣍ࣝ㸧
࢖ࣀ࣮࣋ࢩ࣭ࣙࣥࢪࣕࣃࣥ 2014㸦ᖹᡂ 26 ᖺ 9 ᭶ 11,12 ᪥ࠊᮾிࣅࢵࢢࢧ࢖ࢺ㸧
኱㜰኱Ꮫ࢖ࣀ࣮࣋ࢩࣙࣥࣇ࢙࢔ 2014㸦ᖹᡂ 26 ᖺ 11 ᭶ 20 ᪥ࠊࢢࣛࣥࣇࣟࣥࢺ኱㜰㸧
JST A-STEP Ⓨ ᪂ᢏ⾡ㄝ᫂఍㸦ᖹᡂ 26 ᖺ 11 ᭶ 27 ᪥ࠊJST ᮾிู㤋࣮࣍ࣝ㸧
ᶵ⬟ᛶࢥ࣮ࢸ࢕ࣥࢢࣇ࢙࢔㸦ᖹᡂ 26 ᖺ 12 ᭶ 9 ᪥ࠊ࣐࢖ࢻ࣮࣒኱㜰㸧
ࣅࢪࢿࢫ࣭࢚ࣥ࢝ࣞࢵࢪࣇ࢙࢔㸦ᖹᡂ 26 ᖺ 12 ᭶ 9 ᪥ࠊ኱㜰ᅜ㝿఍㆟ሙ㸧
ᅜ㝿ࢼࣀࢸࢡࣀࣟࢪ࣮⥲ྜᒎ㸦ᖹᡂ 27 ᖺ 1 ᭶ 28,29,30 ᪥ࠊᮾிࣅࢵࢢࢧ࢖ࢺ㸧
࣭௻ᴗࣜࢧ࣮ࢳࣃ࣮ࢡࡢά⏝
௻ᴗ฼⏝㸸20 ♫㸦28 ᐊ㸧>᪂つ฼⏝㸸5 ♫@
࣭ඹྠ◊✲➼ࡢࢥ࣮ࢹ࢕ࢿ࣮ࢩࣙࣥ
ᡂ❧௳ᩘ㸸5 ௳
࣭እ㒊㈨㔠⋓ᚓᨭ᥼
࣭᪂⏘ᴗ๰㐀◊✲఍ᨭ᥼㸸
௳ᩘ㸸3 ◊✲఍㸦㛤ദィ 10 ᅇ㸧
― 148 ―
ᗈሗᐊ
ᐊ㛗㸦ව௵㸧ᩍᤵ
ᩍᤵ㸦ව௵㸧
ᩍᤵ㸦ව௵㸧
ᩍᤵ㸦ව௵㸧
ᩍᤵ㸦ව௵㸧
ᩍᤵ㸦ව௵㸧
ᩍᤵ㸦ව௵㸧
෸ᩍᤵ㸦ව௵㸧
෸ᩍᤵ㸦ව௵㸧
෸ᩍᤵ㸦ව௵㸧
≉௵෸ᩍᤵ㸦ව௵㸧
෸ᩍᤵ㸦ව௵㸧
෸ᩍᤵ㸦ව௵㸧
෸ᩍᤵ㸦ව௵㸧
ຓᩍ㸦ව௵㸧
ຓᩍ㸦ව௵㸧
ຓᩍ㸦ව௵㸧
ຓᩍ㸦ව௵㸧
ຓᩍ㸦ව௵㸧
≉௵஦ົ⫋ဨ
ᢏ⾡⫋ဨ
ὴ㐵⫋ဨ
ὴ㐵⫋ဨ
ྜྷ⏣
἟ᑿ
㇂ཱྀ
☾ᒣ
┿ᔱ
኱ᒾ
Ᏻ⸽
ΎỈ
ᯇ⏣
ྜྷ⏣
㛗ᑿ
᳿ ከ᰿
ᒸᓥ
ᒣᮏ
⚟஭
ᵽཱྀ
ᮡᒣ
ᶓ⏣
ᯇᮏ
ዟᮧ
ఀ⸨
ᓥ⏣
㝧୍
ṇ⾜㸦ᖹᡂ 26 ᖺ 9 ᭶ 30 ᪥ࡲ࡛㸧
ṇ㍤㸦ᖹᡂ 26 ᖺ 9 ᭶ 30 ᪥ࡲ࡛㸧
ᝅᮁ
ဴᮁ
㢧 㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥࠿ࡽ㸧
ⰾ㞝㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥࠿ࡽ㸧
ᫀᖹ㸦ᖹᡂ 26 ᖺ 9 ᭶ 30 ᪥ࡲ࡛㸧
▱ᕫ㸦ᖹᡂ 26 ᖺ 9 ᭶ 30 ᪥ࡲ࡛㸧
⚽ே㸦ᖹᡂ 26 ᖺ 9 ᭶ 30 ᪥ࡲ࡛㸧
⮳ᡂ
㔠ᓠ
ṇ࿴㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥࠿ࡽ㸧
ಇⱥ㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥࠿ࡽ㸧
ὒ᥹㸦ᖹᡂ 26 ᖺ 9 ᭶ 30 ᪥ࡲ࡛㸧
೺୍
㞝௓
㯢ே㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥࠿ࡽ㸧
୍㐨㸦ᖹᡂ 26 ᖺ 10 ᭶ 1 ᪥࠿ࡽ㸧
⣖Ꮚ
⏤㤶
ᩔ⨾
⚽ᶞ㸦ᖹᡂ 26 ᖺ 6 ᭶ 1 ᪥㹼ᖹᡂ 26 ᖺ 9 ᭶ 16 ᪥ࡲ࡛㸧
a) ᴫせ
ᗈሗᐊࡣࠊᗈሗጤဨ఍ࡢ௻⏬࣭ᇶᮏ᪉㔪࡟ἢࡗ࡚ᗈሗάືࢆ✚ᴟⓗ࠿ࡘຠᯝⓗ࡟⾜࠺ࡓࡵࠊᖹᡂ 18
ᖺ 2 ᭶࡟Ⓨ㊊ࡋࡓࠋᗈሗάືࡢᙉ໬ࢆᅗࡿࡓࡵࠊᖹᡂ 25 ᖺᗘ࠿ࡽᗈሗጤဨ఍࡜ᗈሗᐊࡀ⤫ྜࡉࢀࠊ᪂
ࡋ࠸యไ࡟ᨵ⦅ࡉࢀࡓࠋ
୺࡞ᴗົࡣࠊᗈሗᡓ␎ࡢ❧᱌࠾ࡼࡧ᝟ሗ཰㞟ࠊྛ✀ฟ∧≀ࡢ⦅㞟࣭Ⓨ⾜࠾ࡼࡧࡑࡢ⿵ຓࠊ⏘◊࣮࣒࣍
࣮࣌ࢪసᡂ࣭⟶⌮ࠊྛ✀࣏ࢫࢱ࣮࣭ᥖ♧≀ࡢไసࠊ᪋タぢᏛࡢཷࡅධࢀࠊࣉࣞࢫ࣮ࣜࣜࢫ➼ࠊᗈ⠊ᅖ࡟
ࢃࡓࡗ࡚࠸ࡿࠋᖹᡂ 25 ᖺ 7 ᭶࠿ࡽࡣࠊ௻⏬ᐊࠊ⏘Ꮫ㐃ᦠᐊࠊ஦ົ㒊࡜㐃ᦠࡋẖ᭶ᐃ౛グ⪅఍ぢࢆᐇ᪋
ࡋ࡚࠸ࡿࠋ
b) ᡂᯝ
䞉㻌 䛔䛱䜗䛖⚍୍⯡බ㛤ᗈሗ㻌
୍⯡බ㛤᮶ሙ⪅㻌 㻌 㻌 㻌 319 ྡ㻌
䡡㻌 䝇䞊䝟䞊䝃䜲䜶䞁䝇䝝䜲䝇䜽䞊䝹䠄㻿㻿㻴䠅䛸䛾㐃ᦠ㻌
㻌 㻌 㻌 ṊᗜᕝዪᏊ㧗➼Ꮫᰯ䜈䛾ぢᏛㄝ᫂఍ᐇ᪋䛸ኟᏘయ㦂ᐇ⩦ཷ䛡ධ䜜㻌 㻌
䞉㻌 ୰䞉㧗ᰯ⏕➼䛾᪋タぢᏛཷ䛡ධ䜜䠄ᗈሗᐊ☜ㄆศ䠅㻌 㻌 㻌 㻌
ཷ䛡ධ䜜௳ᩘ㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 16 ௳㻌 㻌 㻌 㻌 㻌
ぢᏛ⪅ᩘ㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 㻌 482 ྡ㻌
䞉㻌 䜒䛾䛵䛟䜚ᩍᐊᗈሗᨭ᥼㻌
䞉㻌 䝥䝺䝇䝸䝸䞊䝇㻔㜰኱ᗈሗㄢ⤒⏤㻕㻌 㻌 17 ௳㻌
― 149 ―
䞉㻌
䞉㻌
䞉㻌
䞉㻌
䞉㻌
䞉㻌
䞉㻌
䞉㻌
䞉㻌
䞉㻌
ᐃ౛グ⪅఍ぢ㻌 26 ௳㻌 䠄⏘◊඲య䜢ྵ䜐ሗ㐨௳ᩘ㻌 199 ௳䠅㻌
⏘◊ࢽ࣮ࣗࢫࣞࢱ࣮㸦ᖺ 3 ᅇⓎ⾜㸧
ᖺḟሗ࿌᭩࣭࣓࣮ࣔ࣡ࢬⓎ⾜
⏘◊⤂௓䝟䞁䝣䝺䝑䝖సᡂ㻌
⏘◊๰❧ 㻣㻡 ࿘ᖺグᛕㄅⓎ⾜㻌
ᡤෆ᱌ෆᯈ᭦᪂㻌
⏘◊⤂௓䝡䝕䜸୍㒊᭦᪂㻌
ᡤෆ◊✲ᒎ♧䝁䞊䝘䞊ᩚഛ㻌
⏘◊ 㻴㻼 ᭦᪂㻌 ⣙ 515 ௳㻌 䠄ᡤෆᑓ⏝䝨䞊䝆䜒ྵ䜐䠅㻌
䝫䝇䝍䞊䚸┳ᯈ➼䛾ไస㻌 40 ௳㻌
― 150 ―
௻⏬ᐊ
ᐊ 㛗 ≉௵ᩍᤵ ᘯὠ ⚞ᙪ
๪ᐊ㛗㸦ව௵㸧 ୕⏣ ᩄኵ
≉௵஦ົ⫋ဨ す⏣ ᙬ
a) ᴫせ
௻⏬ᐊࡣࠊᡤ㛗ࡢ࿨ࢆཷࡅࠊᡤෆ㐠Ⴀࡢᨭ᥼ᶵ⬟ࡢᙉ໬࠾ࡼࡧᡤෆᴗົࡢຠ⋡໬ࢆ᥎㐍ࡍࡿࡓࡵࠊ௨
ୗࡢᴗົ࡟㛵ࡍࡿ⿵బࢆ⾜ࡗ࡚࠸ࡿࠋ
ホ౯ጤဨ఍ࡀᐇ᪋ࡍࡿ୰ᮇ┠ᶆ࣭୰ᮇィ⏬ࠊᖺᗘィ⏬ࠊ⮬ᕫⅬ᳨࣭ホ౯ࠊእ㒊ホ౯ཬࡧ➨୕⪅ᶵ
㛵ࡀ⾜࠺ホ౯࡟ಀࡿ௻⏬❧᱌ཬࡧ᝟ሗ཰㞟࡟㛵ࡍࡿࡇ࡜ࠋ
ᢸᙜ๪ᡤ㛗࡜ࡢ㐃ᦠ࡟ࡼࡿᮏ◊✲ᡤࡢᗈሗࠊᅜ㝿ࠊ㈈ົཬࡧ᪋タ࡟ಀࡿ௻⏬❧᱌ཬࡧ᝟ሗ཰㞟࡟
㛵ࡍࡿࡇ࡜ࠋ
ࡑࡢ௚ᮏ◊✲ᡤࡢ㐠Ⴀ࡟ಀࡿ௻⏬❧᱌ཬࡧ᝟ሗ཰㞟࡟㛵ࡍࡿࡇ࡜ࠋ
b) ᡂᯝ
࣭-636 㢌⬻ᚠ⎔ࢆຍ㏿ࡍࡿⱝᡭ◊✲⪅ᡓ␎ⓗᾏእὴ㐵ࣉࣟࢢ࣒ࣛࠖࠊ-636 ◊✲ᣐⅬᙧᡂ஦ᴗࠊ⥲㛗⿢㔞
⤒㈝࡟ࡼࡿᾏእὴ㐵ࡢᨭ᥼
࣭-636 㢌⬻ᚠ⎔ࢆຍ㏿ࡍࡿⱝᡭ◊✲⪅ᡓ␎ⓗᾏእὴ㐵ࣉࣟࢢ࣒ࣛࠊ-636 ◊✲ᣐⅬᙧᡂ஦ᴗᅜ㝿ࢩ࣏ࣥ
ࢪ࣒࢘୪ࡧ࡟ imec-Handai ᅜ㝿ࢩ࣏ࣥࢪ࣒࢘ࡢᨭ᥼ [12/11-12]
࣭⏘◊ⱝᡭ◊✲⪅ேᮦ⫱ᡂὴ㐵࣮࣡ࢡࢩࣙࢵࣉࡢ㛤ദ㸦⏘ᴗ⛉Ꮫ㐃ᦠ᥎㐍ࢭࣥࢱ࣮ࠊ㝔⏕఍㆟ࠊ௻⏬ᐊ
ඹദ㸧[6/20ࠊ3/16]
࣭⏘◊ OB࣭OG㸭Ꮫ⏕஺ὶ఍ࡢ㛤ദ㸦⏘ᴗ⛉Ꮫ㐃ᦠ᥎㐍ࢭࣥࢱ࣮ࠊ㝔⏕఍㆟ࠊ௻⏬ᐊඹദ㸧[11/29]
࣭⏘◊ྠ❆఍⥲఍ࡢᨭ᥼[3/4]
࣭⏘◊ᐃᮇห⾜≀ฟ∧⦅㞟ࡢᨭ᥼㸦ᖺḟሗ࿌᭩ࠊMemoirsࠊせぴࠊࣃࣥࣇࣞࢵࢺࠊ๰❧ 75 ࿘ᖺグᛕㄅ㸧
࣭⏘◊⫋ဨேᮦ⫱ᡂࣉࣟࢢ࣒ࣛࡢ௻⏬࣭ᐇ᪋㸦ⱥㄒㅮᗙ㸧
― 151 ―
ᢏ⾡ᐊ
ᕤస⌜
࣭ᶵᲔᅇ㊰ᕤసಀ
࣭࢞ࣛࢫᕤసಀ
ᐊ 㛗
◊✲ᨭ᥼᥎㐍ဨ
◊✲ᨭ᥼᥎㐍ဨ
◊✲ᨭ᥼᥎㐍ဨ
⏣୰
ᒣᮏ
㇂⏿
㤿ሙ
㸦୺ࡓࡿὴ㐵᪋タ㸧
㧗⣖ 㸦⥲ྜゎᯒࢭࣥࢱ࣮㸧
ಖ 㸦㔞Ꮚࣅ࣮࣒⛉Ꮫ◊✲᪋タ㸧
බ᫛ 㸦ࢼࣀຍᕤᐊ㸧
ஂ⨾Ꮚ㸦ᢏ⾡ᐊ㸧
⌜ 㛗
ಀ 㛗
ᢏ⾡⫋ဨ
ಀ 㛗㸦ව௵㸧
ᑠᕝ
኱す
ᯇୗ
ᑠᕝ
⣖அ 㸦ヨసᐊ㸧
ᨻ⩏ 㸦ヨసᐊ㸧
㞝㈗ 㸦ヨసᐊ㸧
⣖அ 㸦ヨసᐊ㸧
ィ ⌜
⌜ 㛗
࣭ィ ࣭᝟ሗࢩࢫࢸ࣒ಀ ಀ 㛗
ᢏ⾡⫋ဨ
ᢏ⾡⫋ဨ
࣭ศᯒ࣭ࢹ࣮ࢱฎ⌮ಀ
ಀ 㛗
ᢏ⾡⫋ဨ
ᢏ⾡⫋ဨ
ᢏ⾡⫋ဨ
ᯇᕝ ༤᫛ 㸦ヨసᐊ㸧
┦ཎ ༓ᑜ 㸦᝟ሗࢿࢵࢺ࣮࣡ࢡᐊ㸧
ዟᮧ ⏤㤶 㸦ᗈሗᐊ㸧
ྂᕝ ࿴ᘺ 㸦㔞Ꮚࣅ࣮࣒⛉Ꮫ◊✲᪋タ㸧
ᴬཎ ୍᪼ 㸦ࢼࣀຍᕤᐊ㸧
ᯇᓮ ๛ 㸦⥲ྜゎᯒࢭࣥࢱ࣮㸧
⩚Ꮚᒸ ோᚿ㸦⥲ྜゎᯒࢭࣥࢱ࣮㸧
ᮧୖ ὒ㍜ 㸦⥲ྜゎᯒࢭࣥࢱ࣮㸧
a) ᴫせ
ᢏ⾡ᐊࡣࠊ᫛࿴ ᖺ ᭶࡟඲ᅜࡢ኱Ꮫ㝃⨨◊✲ᡤ࡟᪊࠸࡚ึࡵ࡚タ⨨ࡉࢀࡓ◊✲ᨭ⦆ࡢࡓࡵࡢ⤌⧊
࡛࠶ࡾࠊ◊✲ᡤࡢᢏ⾡࡟㛵ࡍࡿᑓ㛛ⓗᴗົ㸦◊✲⏝ᐇ㦂⿦⨨ࡸჾල㢮ࡢヨస࣭ຍᕤ࣭ಟ⌮ࠊ◊✲⏝⿦⨨
ࡸᶵჾ㢮ࡢヨస࣭㐠㌿࣭ィ ࠊ◊✲⏝ᮦᩱࡢྛ✀ศᯒ࡜ࡑࡢࢹ࣮ࢱฎ⌮ࠊࢼࣀᮦᩱࡢຍᕤࠊࢧ࣮ࣂࡸࢿ
ࢵࢺ࣮࣡ࢡࡢಖᏲ࣭⟶⌮ࠊ:(% ࢔ࣉࣜࢣ࣮ࢩࣙࣥࡢタィ࣭㛤Ⓨ㹼㐠⏝ಖᏲࠊ:(% ࢧ࢖ࢺࡢタィ࣭ไసࠊ
ᗈሗᢏ⾡㸧ࢆྛὴ㐵ඛ࡟࡚ὶືⓗ࡟ᴟࡵ࡚ຠ⋡ࡼࡃ㐙⾜ࡋ࡚࠸ࡿࠋࡲࡓࠊ┦஫࡟ᢏ⾡◊ಟࢆ⾜࠺࡯࠿ࠊ
ᩍဨࡸ኱Ꮫ㝔⏕➼࡟ᑐࡋ࡚ࠊࡑࢀࡒࢀᑓ㛛࡜ࡍࡿᢏ⾡ⓗᣦᑟࢆ⾜ࡗ࡚࠸ࡿࠋࡉࡽ࡟ࠊὴ㐵ඛࡢᴗົ௨እ
࡟ᢏ⾡ᐊࡢᴗົ࡜ࡋ࡚ࠊᏳ඲⾨⏕㸦ㅮ⩦఍ࡢ㛤ദࠊ⮬⾨ᾘ㜵ࠊ3&% ⟶⌮ࠊ⸆ရ࣭㧗ᅽ࢞ࢫࢩࢫࢸ࣒⟶⌮
➼㸧࢔࢘ࢺ࣮ࣜࢳάື㸦ࡶࡢ࡙ࡃࡾᩍᐊࡢ㛤ㅮ㸧ࢩ࣏ࣥࢪ࣒࢘➼ࡢ㐠Ⴀᨭ᥼➼ࢆ◊✲ᡤࡢ㐠Ⴀ࡟✚ᴟⓗ
࡟༠ຊࡋྲྀࡾ⤌ࢇ࡛࠸ࡿࠋ
b) ᡂᯝ
࣭ᢏ⾡ᐊ୺ദࠊᡤෆㅮ⩦఍ཬࡧሗ࿌఍➼
࣭Ᏻ඲ㅮ⩦఍㸦5 ᭶ 26 ᪥㸧
࣭ࡶࡢ࡙ࡃࡾᩍᐊ㸦8 ᭶ 5 ᪥㹼8 ᭶ 7 ᪥㸧
࣭➨ 3 ᅇ࢔ࣛ࢖࢔ࣥࢫᢏ⾡ᨭ᥼ࢩ࣏ࣥࢪ࣒࣭࢘➨ 27 ᅇᢏ⾡ᐊሗ࿌఍㸦11 ᭶ 26 ᪥㸧
ᡤෆ 9 ྡࠊ௚኱Ꮫ◊✲ᡤࡼࡾ 13 ྡᢏ⾡⫋ဨⓎ⾲
࣭ᙬ㒔ࡲࡕࡧࡽࡁ 10 ࿘ᖺ࢖࣋ࣥࢺฟᒎ(ᕤල㺛㺢㺵㺍㺪㺽సࡾ࣭ᕤලయ㦂➼)㸦11 ᭶ 9 ᪥㸧
࣭◊ಟ㸦ᢏ⾡◊✲఍ࠊᏛ఍➼ࡢཧຍࠊⓎ⾲➼㸧
࣭➨ 3 ᅇ≀㉁࣭ࢹࣂ࢖ࢫ㡿ᇦඹྠ◊✲ᣐⅬάືሗ࿌఍ཧຍ
࣭ᖹᡂ 25 ᖺᗘ኱㜰኱Ꮫ᪂ே⫋ဨ◊ಟཷㅮ
࣭WEB ไసࢭ࣑ࢼ࣮㸦CSS Nite㸧
࣭ᅇ㊰ CAD ㅮ⩦఍ࡢཷㅮ㸦2014.4.25㸧
― 152 ―
45 ྡ
60 ྡ
70 ྡ
186 ྡ
ᐑᇛ㸦14, 4 ᭶㸧
኱㜰㸦14, 4 ᭶㸧
ᮾி㸦14, 4 ᭶㸧
ᇸ⋢㸦14, 4 ᭶㸧
࣭➨ 4 ᅇ≀㉁࣭ࢹࣂ࢖ࢫ㡿ᇦඹྠ◊✲ᣐⅬάືሗ࿌఍
࣭FTIR ࣐ࢡࣟศᯒࢭ࣑ࢼ࣮
࣭➨ 55 ᅇᅛయ NMR࣭ᮦᩱࣇ࢛࣮࣒ࣛ
࣭➨ 64 ᅇ㉁㔞ศᯒ⥲ྜウㄽ఍
࣭➨ 81 ᅇ᪥ᮏศᯒ໬Ꮫ఍᭷ᶵᚤ㔞◊✲᠓ㄯ఍
➨ 95 ᅇィ ⮬ືไᚚᏛ఍ຊᏛ㔞ィ 㒊఍➨ 31 ᅇྜྠࢩ࣏ࣥࢪ࣒࢘
࣭➨ 10 ᅇ㉁㔞ศᯒᢏ⾡⪅㏆␥ࣈࣟࢵࢡ◊✲఍
࣭ThermoFisher ࣮ࣘࢨ࣮ࢬ࣑࣮ࢸࣥࢢ
࣭➨ 11 ᅇ᪥ᮏຍ㏿ჾᏛ఍ᖺ఍
࣭ᖹᡂ 26 ᖺᗘ⥲ྜᢏ⾡◊✲఍
࣭㛵す஧ḟ㟁ụᒎ࣭PVEXPO࣭㺛㺭㺎㺢㺖㺼㺶㺍㺢㺼 EXPO ཧຍ㺃㺜㺮㺣㺎
࣭᝟ሗࢩࢫࢸ࣒⤫୍◊ಟ
࣭኱㜰኱Ꮫᢏ⾡⫋ဨ◊ಟ
࣭᭷ᶵᚤ㔞ศᯒ࣑ࢽࢧࣟࣥ
࣭PMT ୺ദࠕ኱㜰኱Ꮫᮍ᮶ࢭ࣑ࢼ࣮ࠖཷㅮ
࣭㜰኱ e-square ␗ศ㔝⼥ྜ࢝ࣇ࢙㺃ࢭ࣑ࢼ࣮ཷㅮ(CASTEM)
࣭㛵すタィ࣭〇㐀㺝㺶㺋㺎㺚㺌㺻ᒎ࣭㛵す㧗ᶵ⬟㔠ᒓᒎ࣭㺪㺆㺷㺯㺡㺍㺖኱㜰ཧຍ
࣭➨ 53 ᅇ NMR ウㄽ఍
࣭Bruker Daltonics ࣮ࣘࢨ࣮ࢬ࣑࣮ࢸࣥࢢ
࣭MASTERCAM ࢺ࣮ࣞࢽࣥࢢ(5 ㍈ຍᕤᶵ⏝) ࣭➨ 3 ᅇ࢔ࣛ࢖࢔ࣥࢫᢏ⾡ᨭ᥼ࢩ࣏ࣥࢪ࣒࣭࢘➨ 27 ᅇ⏘◊ᢏ⾡ᐊሗ࿌఍
࣭Solidworks ㅮ⩦ཷㅮ(ࢫࢣࢵࢳᇶᮏ㹼ࢩ࢙ࣝ࡜ࣜࣈ)
࣭Solidworks ㅮ⩦ཷㅮ(ಟ᚟㺃タィኚ᭦㹼࢔ࢭࣥࣈࣜ)
࣭
ࠕ኱㜰኱Ꮫ᝟ሗⓎಙຊࢺ࣮ࣞࢽࣥࢢࠖཷㅮ
࣭ᢏ⾡⫋ဨࢩ࣏ࣥࢪ࣒࢘ཧຍ㸦KEK㸧
࣭࢖ࣥࢱ࣮ࣇ࢙ࢵࢡࢫࢪࣕࣃࣥࠊࢼࣀࢸࢵࢡ
࣭ປാᏳ඲⾨⏕࡟㛵ࡍࡿ᝟ሗ஺᥮఍࡟ཧຍ(᰾⼥ྜ)
࣭➨ 10 ᅇ᝟ሗᢏ⾡◊✲఍
࣭ศᏊ◊ᢏ⾡ࢧࣟࣥ
࣭ᐑᓮ኱Ꮫᢏ⾡⫋ဨ࢞ࣛࢫᕤసᢏ⾡ᣍ⪸ᣦᑟ
࣭ᚤ⣽ຍᕤᢏ⾡࡟㛵ࡍࡿ᝟ሗ஺᥮఍㸦ศᏊ◊㸧
࣭ྛ✀චチ࣭㈨᱁ྲྀᚓ➼ࡢ⌧≧
࣭⾨⏕ᕤᏛ⾨⏕⟶⌮⪅ ྡ
࣭➨ ✀ᨺᑕ⥺ྲྀᢅ୺௵⪅ච≧㸦 ྡ㸧
࣭࢚ࢵࢡࢫ⥺సᴗ୺௵⪅㸦 ྡ㸧 ࣭ẘ≀๻≀ྲྀᢅ⪅㸦 ྡ㸧
࣭㓟Ḟ࣭◲໬Ỉ⣲సᴗ୺௵⪅㸦 ྡ㸧
࣭᝟ሗฎ⌮ᢏ⾡⪅ヨ㦂㸦ึ⣭ࢩࢫ࢔ࢻ㸧
㸦 ྡ㸧
࣭➨୕✀㟁Ẽ୺௵ᢏ⾡⪅㸦 ྡ㸧 ࣭పᅽ㟁Ẽ≉ูᩍ⫱㸦 ྡ㸧
࣭ࢡ࣮ࣞࣥࡢ⋢ࡀࡅ㸦 ྡ㸧
࣭◊๐◒▼ࡢྲྀ᭰ࠊྲྀ᭰᫬ࡢヨ㐠㌿ࡢᴗົ㸦 ྡ㸧
࣭࢞ࢫ⁐᥋≉ูᩍ⫱㸦 ྡ㸧
௝ྎ㸦14, 4 ᭶㸧
ᮾி㸦14, 5 ᭶㸧
⚄ዉᕝ㸦14, 5 ᭶㸧
኱㜰㸦14, 5 ᭶㸧
ᮾி㸦14, 6 ᭶㸧
኱㜰㸦14, 7 ᭶㸧
኱㜰㸦14, 7 ᭶㸧
㟷᳃㸦14, 8 ᭶㸧
໭ᾏ㐨㸦14, 9 ᭶㸧
኱㜰(14, 9 ᭶)
ᮾி㸦14, 9 ᭶㸧
኱㜰㸦14, 9 ᭶㸧
኱㜰㸦14, 9 ᭶㸧
኱㜰㸦14, 9㹼11 ᭶㸧
኱㜰㸦14, 9 ᭶㸧
኱㜰㸦14, 10 ᭶㸧
኱㜰㸦14, 11 ᭶㸧
኱㜰㸦14, 11 ᭶㸧
኱㜰㸦14, 11 ᭶㸧
኱㜰㸦14, 11 ᭶㸧
኱㜰㸦14, 12 ᭶㸧
኱㜰㸦14, 12 ᭶㸧
኱㜰㸦14, 12 ᭶ࠊ15, 1 ᭶㸧
Ⲉᇛ㸦15, 1 ᭶㸧
ᮾி㸦15, 1 ᭶㸧
ᒱ㜧㸦15, 2 ᭶㸧
⚟ᒸ㸦15, 3 ᭶㸧
ឡ▱㸦15, 3 ᭶㸧
ᐑᓮ㸦15, 3 ᭶㸧
ឡ▱㸦15, 3 ᭶㸧
࣭➨ ✀⾨⏕⟶⌮⪅㸦 ྡ㸧
࣭➨ ✀ᨺᑕ⥺ྲྀᢅ୺௵⪅ච≧㸦 ྡ㸧
࣭༴㝤≀ྲྀᢅ⪅㸦எ✀ 㢮㹼 㢮චチ㸧
㸦 ྡ㸧
࣭㧗ᅽ࢞ࢫ〇㐀ಖᏳ㈐௵⪅ච≧எ✀໬Ꮫ㸦 ྡ㸧
࣭≉ู⟶⌮⏘ᴗᗫᲠ≀⟶⌮㈐௵⪅㸦 ྡ㸧
࣭⮬⾨ᾘ㜵ᴗົ᪂つㅮ⩦㸦 ྡ㸧
࣭➨஧✀㟁Ẽᕤ஦ኈච≧㸦 ྡ㸧
࣭ᗋୖ᧯సᘧࢡ࣮ࣞࣥ㐠㌿㸦 ྡ㸧
࣭ኳ஭ࢡ࣮ࣞࣥᐃᮇ⮬୺᳨ᰝ⪅㸦 ྡ㸧
࣭࢔࣮ࢡ⁐᥋≉ูᩍ⫱㸦 ྡ㸧
࣭⥲㛗⾲ᙲ㸦6 ྡ㸧
― 153 ―
஦ົ㒊
㸦ᖹᡂ㸰㸵ᖺ㸱᭶㸱㸯᪥⌧ᅾ㸧
⥲ົㄢ 㸦஦ົ㒊㛗㸧 ୕⏣ ᩄኵ
㸦ㄢ㛗㸧 ୰ᕝ ṇ
⥲ົಀ㸦ಀ㛗㸧 㯮ᮺ ⿱
㸦஦ົ⫋ဨ㸧 ⰼぢ ࿴Ꮚ
㸦஦ົ⫋ဨ㸧 ᮾᑿ ᭸㟼
㸦஦ົ⿵బဨ㸧 す㏕ ‶
㸦஦ົ⿵బဨ㸧 ୗỤ ⨾ⱥ
ே஦ಀ (ಀ㛗) ᇼ஭ ዉὠᏊ
㸦≉௵஦ົ⫋ဨ㸧ᯘ ࿴⨾
㸦஦ົ⿵బဨ㸧 ➲ᕝ ᠇Ꮚ
◊✲㐃ᦠㄢ 㸦ㄢ㛗㸧 ྜྷᓮ ⣧Ꮚ
◊✲༠ຊಀ㸦ಀ㛗㸧 すᮧ ἞
㸦୺௵㸧 ᚨᮏ ⨾⣪
㸦≉௵஦ົ⫋ဨ㸧ᜨ㜰 ┿⏤
㸦஦ົ⿵బဨ㸧 ㇂チ ༤Ꮚ
㈈ົಀ㸦ಀ㛗㸧
ሷ⏣ ೺
㸦୺௵㸧 භὠ஭ ὈᏊ
㸦≉௵஦ົ⫋ဨ㸧᳃⏣ ඲Ꮚ
㸦஦ົ⿵బဨ㸧 ࿴⏣ ⏤⨾
ዎ⣙ಀ㸦ಀ㛗㸧 ᳜ᯘ ⋢ᶞ
㸦஦ົ⫋ဨ㸧 బ⸨ ឡᏊ
㸦஦ົ⫋ဨ㸧 ஂಖ ⨾㔛
㸦ᢏ⾡⫋ဨ㸧 Ᏹ㔝 ᝋᏊ
㸦஦ົ⿵బဨ㸧 ኱㇂ ࿴㡢
㸦஦ົ⿵బဨ㸧 すᮏ ࢺ࢟ࢥ
㸦஦ົ⿵బဨ㸧 ෆ⏣ ᗣ༤
㸦஦ົ⿵బဨ㸧 㖭ⱉ ᑦᏊ
― 154 ―
［ 附 4 ］ 各研究部門、附属研究施設における活動実績リスト
㔞Ꮚࢩࢫࢸ࣒๰ᡂ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Electrically tunable spin filtering for electron tunneling between spin-resolved quantum Hall edge
states and a quantum dot, H. Kiyama, T. Fujita, S. Teraoka, A. Oiwa, and S. Tarucha: Applied Physics
Letters, 104 (2014) 263101-1-263101-4.
[2]Single photoelectron detection after selective excitation of electron heavy-hole and electron light-hole
pairs in double quantum dots, K. Morimoto, T. Fujita, G. Allison, S. Teraoka, M. Larsson, H. Kiyama, S.
Haffouz, D. G. Austing, A. Ludwig, A. D. Wieck, A. Oiwa, and S. Tarucha: Physical Review B, 90
(2014) 085306-1-085306-5.
[3]Tuning the electrically evaluated electron Landé g factor in GaAs quantum dots and quantum wells of
different well width, G. Allison, T. Fujita, K. Morimoto, S. Teraoka, M. Larsson, H. Kiyama, A. Oiwa, S.
Haffouz, D. G. Austing, A. Ludwig, A. D. Wieck, and S. Tarucha: Physical Review B, 90 (2014)
235310-1-235310-4.
[4]Ferromagnetic interactions and martensitic transformation in Fe doped Ni-Mn-In shape memory alloys,
D. N. Lobo, K. R. Priolkar, S. Emura, and A. K. Nigam: Journal of Applied Physics, 116 (2014)
183903-1-183903 -8.
[5]Importance of structural distortions in enhancement of transition temperature in FeSe1íxTex
superconductors, Kapil E. Ingle, K. R. Priolkar, Anand Pal, Rayees A. Zargar, V. P. S. Awana and S.
Emura: Superconductor Science and Technology, 28 (2015) 015015-1-015015-6.
[6]Photoluminescence related to Gd3+:N-vacancy complex in GaN:Gd multi-quantum wells, M.
Almokhtar, S. Emura, A. Koide, T. Fujikawa, and H. Asahi: Journal of Alloys and Compounds, 628
(2015) 401-406.
[7]Structural and defect characterization of Gd-doped GaN films by X-ray diffraction and positron
annihilation, A. Yabuuchi, N. Oshima, B. E. O'Rourke, R. Suzuki, K. Ito, S. Sano, K. Higashi, Y.-K. Zhou,
and S. Hasegawa: Journal of Physics: Conference Series, 505 (2014) 012023-1㸫012023-4.
[8]Hall resistivity and transverse magnetoresistivity generated in simultaneous presence of spinpolarized
current and external magnetic field in a nonmagnetic bipolar conductor YH2, Masamichi Sakai, Hiraku
Takao, Tomoyoshi Matsunaga, Yusuke Tanaka, Tatsuya Arai, Shota Haruyama, Takashi Otomo, Hiroaki
Hirama, Takahito Sakuraba, Zentaro Honda, Koji Higuchi, Akira Kitajima, Akihiro Oshima, Shigehiko
Hasegawa, and Hiroyuki Awano: Japanese Journal of Applied Physics, 54 (2015) 013001-1㸫
013001-11.
ᅜ㝿఍㆟
[1]Single-shot readout electron spins in a quantum dot coupled to quantum Hall edge states (poster), H.
Kiyama, A. Oiwa, and S. Tarucha: 8th International Conference on Quantum Dots (QD 2014), Italy May
11-16, 2014.
[2]Angular momentum conversion from single photons to single electron spins in a lateral double
quantum dot (invited), A. Oiwa, T. Fujita, K. Morimoto, H. Kiyama, G. Allison, M. Larsson, A. Ludwig,
A.D. Wieck and S. Tarucha: Solid State Devices and Materials (SSDM2014), Japan,September 11th,
2014.
[3]Conversion from a single photon to a single electron spin using electrically controlled quantum dots
(invited), A. Oiwa, T. Fujita, K. Morimoto, M. Larsson, G. Allison, H. Kiyama, A. Ludwig, A. D. Wieck,
and S. Tarucha: Fujihara Seminar: Real-time Dynamics of Physical Phenomena and Manipulation by
External Fields,Japan, September 23-27, 2014,.
― 157 ―
[4]Unique Behavior of Photoluminescence from Small Size Nanowires (poster), M. Almokuhtar, S.
Emura, and A. Oiwa: The 18th SANKEN International Symposium, Japan,December 10-11, 2014.
[5]Photon-spin coupling using electron spins in quantum dots (poster), A. Oiwa, T. Fujita, K. Morimoto,
M. Larsson, G. Allison, H. Kiyama, A. Ludwig, A. D. Wieck, and S. Tarucha: The 18th SANKEN
International Symposium, Japan,December 10-11, 2014.
[6]Single-shot readout of electron spin states in a quantum dot coupled to quantum Hall edge states
(poster), H. Kiyama, A. Oiwa, and S. Tarucha: The 18th SANKEN International Symposium,
Japan,December 10-11, 2014.
[7]Fabrication and transport properties of InAs self-assembled quantum dots contacted with nanogap
electrodes (poster), H. Kiyama, T. Hirayama, R. Shikishima, S. Baba, N. Nagai, K. Hirakawa, S. Tarucha,
and A. Oiwa: 1st International Workshop on Topological Electronics (Topotronics2015), Japan, March
9-11, 2015,.
[8]Growth and Characterization of Fe Nitride on GaN(0001) (oral), higehiko Hasegawa, Shota Yamauchi,
Masaru Yoneoka, Hiroaki Yamaguchi: 5th International Symposium on Growth of III-Nitrides.
[9]Structural and Mechanical Characterization of BN Films Grown on Si(001) by Magnetically-Enhanced
Plasma Ion Plating (poster), S. Hasegawa, M. Noma, M. Yamashita, and K. Eriguchi: 5th International
Symposium on Growth of III-Nitrides.
[10]Non-local Detection of Spin Injection through a Co/GaN Schottky Barrier (poster), Shigehiko
Hasegawa and Hiroaki Yamaguchi: The 7th International Symposium on Surface Science.
[11]A Novel Reactive Plasma-Assisted Coating Technique (RePAC) for Thin BN/Crystalline-Si
Structures and their Mechanical and Electrical Properties (oral), K. Eriguchi, M. Noma, S. Hasegawa, M.
Yamashita, and K. Ono: AVS 61st International Symposium & Exhibition.
[12]Effects of ion energy on surface and mechanical properties of BN films formed by a reactive
plasma-assisted coating method (oral), M. Noma, K. Eriguchi, S. Hasegawa, M. Yamashita, and K. Ono:
36th International Symposium on Dry Process.
≉チ
[1]ࠕᅜෆ≉チฟ㢪ࠖ☢ᛶ༙ᑟయ⣲Ꮚ, ≉㢪 2014-244212
[2]ࠕᅜෆ≉チฟ㢪ࠖ☢ᛶ༙ᑟయࢹࣂ࢖ࢫ, ≉㢪 2014-244209
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
኱ᒾ 㢧
The 21st International Conference on Electronic Properties of Two-Dimensional
Systems (ㄽᩥጤဨ)
኱ᒾ 㢧
The 9th International Conference on Physics and Applications of Spin-related
Phenomena in Solids (⤌⧊ጤဨ㛗)
㛗㇂ᕝ ⦾ᙪ
The 7th International Symposium on Surface Science (⌧ᆅᐇ⾜ጤဨ఍๪ጤဨ㛗)
኱ᒾ 㢧
The 1st International Workshop on Topological Electronics (㐠Ⴀጤဨ)
ᅜෆᏛ఍
᪥ᮏ≀⌮Ꮫ఍ ⛅ࡢศ⛉఍
᪥ᮏ≀⌮Ꮫ఍ ➨ 70 ᅇᖺḟ኱఍
➨ 75 ᅇᛂ⏝≀⌮Ꮫ఍⛅ᏘᏛ⾡ㅮ₇఍
➨ 62 ᅇᛂ⏝≀⌮Ꮫ఍᫓ᏘᏛ⾡ㅮ₇఍
➨ 38 ᅇ᪥ᮏ☢ẼᏛ఍Ꮫ⾡ㅮ₇఍
᪂Ꮫ⾡㡿ᇦ◊✲ࠕࢼࣀࢫࣆࣥኚ᥮⛉Ꮫࠖᖺḟሗ࿌఍
― 158 ―
3௳
2௳
3௳
6௳
1௳
3௳
➨ 8 ᅇ ≀ᛶ⛉Ꮫ㡿ᇦᶓ᩿◊✲఍ (㡿ᇦྜྠ◊✲఍)2014 8th Joint Research
Meeting of MEXT National Projects on Condensed-Matter Science
ྲྀᚓᏛ఩
Ꮫኈ㸦ᕤᏛ㸧
ᮌᮧ ோ඘
Ꮫኈ㸦ᕤᏛ㸧
ᩜᓥ ⛸⣖
༤ኈ㸦ᕤᏛ㸧
ᮌᒣ ἞ᶞ
1௳
ศᏊ⥺࢚ࣆࢱ࢟ࢩ࣮ἲ࡟ࡼࡿ Fe4N/GaN(0001)⏺㠃ᙧᡂ࡜ࡑࡢᵓ㐀ホ౯
InAs ⮬ᕫᙧᡂࢻࢵࢺࢆ⏝࠸ࡓ༢୍㟁Ꮚࢺࣛࣥࢪࢫ ࢱࡢస〇࡜ఏᑟ ᐃ
㔞Ꮚ࣮࢚࣍ࣝࢵࢪ≧ែ࡜⤖ྜࡋࡓ㔞Ꮚࢻࢵࢺ࡟࠾ࡅࡿࢫࣆࣥ౫Ꮡఏᑟ
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(A)
㔞Ꮚࢻࢵࢺࢆ౑ࡗࡓගᏊ㸫ࢫࣆࣥ㛫ࡢ㔞Ꮚ≧ែ㌿෗࡜㠀ᒁᡤ
኱ᒾ 㢧
ࡶࡘࢀ⏕ᡂࡢ◊✲
᪂Ꮫ⾡㡿ᇦ◊✲ ගᏛⓗࢫࣆࣥኚ᥮
㸦◊✲㡿ᇦᥦ᱌
ᆺ㸧ィ⏬◊✲
኱ᒾ 㢧
᪂Ꮫ⾡㡿ᇦ◊✲ ࢫࣆࣥኚ᥮⥲ᣓ⌜
㸦◊✲㡿ᇦᥦ᱌
ᆺ㸧⥲ᣓ⌜
኱ᒾ 㢧
ᇶ┙◊✲㸦S)
㔞Ꮚᑐࡢ✵㛫ไᚚ࡟ࡼࡿ᪂つᅛయ㟁Ꮚ≀ᛶࡢ◊✲
኱ᒾ 㢧
ᣮᡓⓗⴌⱆ◊✲ 㟁ὶὀධᆺࢫࣆࣥ೫ᴟᗘィࡢࢹࢨ࢖ࣥ࡜ᨃఝ㹖㹍㹐ࢤ࣮ࢺ࡬
㛗㇂ᕝ ⦾ᙪ
ࡢᛂ⏝
ཷク◊✲
኱ᒾ 㢧
⥲ົ┬
㞟✚໬ྍ⬟࡞㟁Ẽไᚚࢫࣆࣥ㔞Ꮚࣅࢵࢺ࡛ᵓ
ᡂࡉࢀࡿ㔞Ꮚ࢖ࣥࢱ࣮ࣇ࢙࣮ࢫࡢ◊✲㛤Ⓨ
༢఩㸸༓෇
6,630
5,681
1,300
4,901
260
455
༙ᑟయ㔞Ꮚ⛉Ꮫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Characterization of reduced graphene oxide field-effect transistor and its application to biosensor,
Masaki Hasegawa, Yuki Hirayama, Yasuhide Ohno, Kenzo Maehash2 and Kazuhiko Matsumoto:
Japanese Journal of Applied Physics, 53 (5S1) (2014) 05FD05-1-4.
[2]Raman spectral mapping of self-aligned carbon nanowalls, Toshio Kawahara, Satarou Yamaguchi,
Yasuhide Ohno, Kenzo Maehashi, Kazuhiko Matsumoto, Kazumasa Okamoto, Risa Utsunomiya, Teruaki
Matsuba, Yuki Matsuoka and Masamichi Yoshimura: Japanese Journal of Applied Physics, 53 (5S1)
(2014) 05FD10-1-6.
[3]Carbon Nanowall Field Effect Transistors Using a Self-Aligned Growth Process, Toshio Kawahara,
Satarou Yamaguchi, Yasuhide Ohno, Kenzo Maehashi, Kazuhiko Matsumoto, Kazumasa Okamoto, Risa
Utsunomiya, Teruaki Matsuba: e-Journal of Surface Science and Nanotechnology, 12 (2014) 225-229.
[4]Direct graphene synthesis on a Si/SiO2 substrate by a simple annealing process, Takashi Ikuta, Kenta
Gumi, Yasuhide Ohno, Kenzo Maehashi, Koichi Inoue and Kazuhiko Matsumoto: Materials Research
Express, 1 (2) (2014) 025028-1-8.
[5]Effect of the inert Gas adsorption on the bilayer graphene to the localized electron magnetotransport, A
Fukuda, D Terasawa, Y Ohno and K Matsumoto: Journal of Physics, 568 (2014) 052009-1-7.
[6]Top gating of epitaxial (Bi1-xSbx)2Te 3 topological insulator thin films, Fan Yang, A. A. Taskin,
― 159 ―
Satoshi Sasaki, Kouji Segawa, Yasuhide Ohno, Kazuhiko Matsumoto and Yoichi Ando: Journal of
Physics, 104 (2014) 161614-1-4.
[7]Optical Observation of Deep Bulk Damage in Amorphous Perfluorocarbon Films Produced by UV
Photons Emitted from Low-Pressure Argon Plasma, Takao Ono, Ryo Iizuka, Takanori Akagi, Takashi
Funatsu and Takanori Ichiki: Journal of Photopolymer Science and Technology, 27 (3) (2014) 393-398.
ᅜ㝿఍㆟
[1]Direct Growth of Graphene on SiO2 Substrate by Thermal & Laser CVDs (oral), Kazuhiko
Matsumoto: Workshop on Compuond Semiconductor Devices and Integrated Circuits & Expert
Evaluation and Control of Compound Semiconductor Materials and Technologies.
[2]Carbon Nanotube Quantum Nano Memory with Ultra-Low Programing Bias (oral), Kazuhiko
Matsumoto: The 6th IEEE International Nanoelectronics Conference.
[3]Graphene Synthesis by Laser-Annealing Technique Using Co Catalyst (oral), : 2014 International
Conference on Solid State Devices and Materials.
[4]Graphene Synthesis by Laser-Annealing Technique and Device Aplications (oral), Yusuke Ishibashi,
Keisuke Koshida, Yasushi Kanai, Yasuhide Ohno, Kenzo Maehashi, Koichi Inoue, and Kazuhiko
Matsumoto: The 6th International Conference on Recent Progress in Graphene Research.
[5]pH Detection Based on Direct Graphene Growth on Si/SiO2 Substrate (oral), Takashi Ikuta, Yasushi
Kanai, Yasuhide Ohno, Kenzo Maehashi, Koichi Inoue, and Kazuhiko Matsumoto: The 6th International
Conference on Recent Progress in Graphene Research.
[6]Memory Operation of Carbon Nanotube Single-Electron Transistors with Charge Storage Structure
(oral), K. Seike, Y. Kanai, Y. Ohno, K. Maehashi, K. Inoue and K. Matsumoto: 27th International
Microprocesses and Nanotechnology Conference.
[7]Graphene-FET-Based Gas-Sensor Properties Depending on Substrate Surface Conditions (oral), M.
Nakamura, Y. Kanai, Y. Ohno, K. Maehashi, K. Inoue and K. Matsumoto: 27th International
Microprocesses and Nanotechnology Conference.
[8]Electrical Detection of Lectin Using Glycan-Modified Graphene Field-Effect Transistors for Highly
Sensitive Influenza Virus Sensor (poster), T. Oe, Y. Kanai, Y. Ohno, K. Maehashi, K. Inoue, K.
Matsumoto, Y. Watanabe, T. Kawahara, Y. Suzuki and S. Nakakita: 27th International Microprocesses and
Nanotechnology Conference.
[9]Reduction of Sheet Resistance in Graphene Conductive Film with Carbon Nanotubes (poster), T. Ikuta,
Y. Kanai, Y. Ohno, K. Maehashi, K. Inoue and K. Matsumoto: 27th International Microprocesses and
Nanotechnology Conference.
[10]Detection of Fluorescence Molecule-DNA Binding Based on a Graphene FET (poster), M. Okano, S.
Norhayati, V. Rajiv, Y. Kanai, Y. Ohno, K. Maehashi, K. Inoue, F. Takei, K. Nakatani and K. Matsumoto:
27th International Microprocesses and Nanotechnology Conference.
[11]Electrical Detection of Binding and Separation between Fluorescence Molecule and DNA Based on
Graphene FETs (poster), M. Okano, S. Norhayati, V. Rajiv, Y. Kanai, Y. Ohno, K. Maehashi, K. Inoue, F.
Takei, K. Nakatani, K. Matsumoto: 1st Kansai Nanoscience and Nanotechnology International
Symposium.
[12]Modification of Graphene Field-Effect Transistor for Biosensor (poster), R. Hayashi, T. Oe, Y. Kanai,
Y. Ohno, K. Maehashi, K. Inoue, A. Tashiro, Y. Ie, Y. Aso, K. Matsumoto: 1st Kansai Nanoscience and
― 160 ―
Nanotechnology International Symposium.
[13]Reduction of Sheet Resistance in Graphene Transparent Conductive Film with Carbon Nanotubes
(poster), T. Ikuta, Y. Kanai, Y. Ohno, K. Maehashi, K. Inoue, K. Matsumoto: 1st Kansai Nanoscience and
Nanotechnology International Symposium.
[14]Selective Detection of Lectins with Glycan-Modified Graphene FET for Highly Sensitive Influenza
Virus Sensor (poster), T. Oe, T. Ikuta, K. Seike, Y. Ishibashi, Y. Kanai, Y. Ohno, K. Maehashi, K. Inoue, K.
Matsumoto, Y. Watanabe, T. Kawahara, Y. Suzuki, S. Nakakita: 1st Kansai Nanoscience and
Nanotechnology International Symposium.
[15]Controlling Graphene Nucleation Density on Copper Surface (poster), Y. Mori, T. Ikuta, Y. Kanai, Y.
Ohno, K. Maehashi, K. Inoue, K. Matsumoto: 1st Kansai Nanoscience and Nanotechnology International
Symposium.
[16]Direct Graphene Synthesis on Glass by Laser-Annealing Technique (poster), Y. Ishibashi, K. Seike, T.
Oe, Y. Kanai, Y. Ohno, K. Maehashi, K. Inoue, K. Matsumoto: 1st Kansai Nanoscience and
Nanotechnology International Symposium.
[17]Fabrication of carbon nanotube single-electron transistors with single-electron charge storage (poster),
K. Seike, Y. Ishibashi, T. Oe, Y. Kanai, Y. Ohno, K. Maehashi, K. Inoue, K. Matsumoto: 1st Kansai
Nanoscience and Nanotechnology International Symposium.
[18]Properties of Graphene-FET-Based Gas-Sensor Depending on Substrate Surface Conditions (poster),
M. Nakamura, Y. Kanai, Y. Ohno, K. Maehashi, K. Inoue, K. Matsumoto: 1st Kansai Nanoscience and
Nanotechnology International Symposium.
[19]Control of qunatum states in single-walled carbon nanotube transistors by electric-double-layer gate
with ionic liquid (poster), K. Kamada, K. Seike, Y. Kanai, Y. Ohno, K. Maehashi, K. Inoue, K.
Matsumoto: 1st Kansai Nanoscience and Nanotechnology International Symposium.
[20]Optical Observation of Deep Bulk Damage in Amorphous Perfluorocarbon Films Produced by UV
Photons Emitted from Low-Pressure Argon Plasma (oral), T. Ono, R. Iizuka, T. Akagi, T. Funatsu and T.
Ichiki: The 31st International Conference of Photopolymer Science and Technology.
[21]Single-molecule assay for tau protein using digital ELISA system (poster), T. Ono, L. Yamauchi, T.
Miyasaka, A. Takashima and H. Noji: The 18th International Conference on Miniaturized Systems for
Chemistry and Life Sciences.
[22]High-speed assay for single-molecule enzyme using attoliter chamber array, Nanocell (poster), T.
Ono, T. Ichiki and H. Noji: Tokyo ATPase Workshop.
ᅜෆᏛ఍
ᛂ⏝≀⌮Ꮫ఍
12 ௳
⛉Ꮫ◊✲㈝⿵ຓ㔠
᪂Ꮫ⾡㡿ᇦ◊✲
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ᇶ┙◊✲(B)
๓ᶫ ව୕
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᪂つࢼࣀ࣮࢝࣎ࣥᮦᩱࡢ⾲㠃㸭⏺㠃ಟ㣭࡟ࡼࡿ≉ᛶไᚚ࡜ࢹࣂ
࢖ࢫᛂ⏝
࢖࢜ࣥᾮయࢤ࣮ࢺ㟁⏺༳ຍࢢࣛࣇ࢙ࣥࡢࣂࣥࢻࢠࣕࢵࣉ⏕ᡂไ
ᚚ࡜ࢼࣀࢹࣂ࢖ࢫࡢ㛤Ⓨ
― 161 ―
༢఩㸸༓෇
26,390
3,380
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ዡᏛᐤ㝃㔠
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ඹྠ◊✲
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ࡢ⫱ᡂ࡜⏘ᴗ➇தຊቑ㐍㸭㇏࠿࡞♫
఍ࡢᵓ⠏
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2,216
2,216
16,376
ඛ㐍㟁Ꮚࢹࣂ࢖ࢫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Mechanically Adaptive Organic Transistors for Implantable Electronics, T.Sekitani, Reeder.Jonathan,
Kaltenburnner.Martin, Ware. Talor, et al.: , 26 (29) (2014) 4967-4973.
[2]A strain-absorbing design for tissue-machine interfaces using a tunable adhesive gel, T.Sekitani,
Lee.Sungwon, Inoue.Yusuke, Kim.Dongmin, et al.: NATURE COMMUNICATIONS, 5 (2014) 5898.
[3]1 ȝm-Thickness Ultra-Flexible and High Electrode-Density Surface Electromygram Mesurement
Sheeet With 2 V Organic Transistors for Prosthetic Hand Control, T.Sekitani, Fuketa.Hiroshi, Yoshioka
Kazuaki, Shinozuka, et al: IEEE TRANSACTIONS ON BIOMEDICAL CORCUITS AND SYSTEMS, 8
(6) (2014) 824-823.
[4]An Imperceptible Plastic Electronic Wrap, T.Sekitani, Drack. Micheal, Graz.Ingrid, et al: ADVANCED
MATERIALS, 27 (1) (2015) 34-40.
[5]Imperceptible magnetoelectronics, T.Sekitani, Melzer.Michael, Kaltenburnneer,Martin,
Makarov.Deny, et al: NATURE COMMUNICATIONS, 6 (2015) 6080.
[6]Alternating current admittance of DNTT-based metal-insulator-semiconductor capacitors, Toshiaki
Hayashi, Naoya Take, H. Tamura, Tsuyoshi Sekitani and Takao Someya: , 115 (2014) 093702.
[7]Silver Nanowire Electrodes: Conductivity Improvement Without Post-treatment and Application in
Capacitive Pressure Sensors, Jun Wang, Jinting Jiu, Teppei Araki, Masaya Nogi, Tohru Sugahara, Shijo
Nagao, Hirotaka Koga, Peng He, Katsuaki Suganuma: Journal of Applied Physics, 7 (2014) 51-58.
[8]Molecularly clean ionic liquid/rubrene single-crystal interfaces revealed by frequency modulation
atomic force microscopy, Y. Yokota, H. Hara, Y. Morino, K. Bando, A. Imanishi, T. Uemura, J. Takeya, K.
Fukui: Phys. Chem. Chem. Phys., 17 (2015) 6794-6800.
ᅜ㝿఍㆟
[1]Ultrathin organic optoelectronics (invited), T. Sekitani: SID Mid-Europe Chapter Spring Meeting
2014.
[2]Flexible organic thin-film devices for biomedical electronics (invited), T. Sekitani: The 18th
International Symposium on Advanced Display Material and Devices.
― 162 ―
[3]Realizing E-skin Pressure Sensor;Beyond High Sensitivity (invited), T. Sekitani: International
Biomedical Engeering Conference 2014,Korea, November 21,2014.
[4]Ultraflexible and Stretchable Organic Thin- Film Devices for Implantable and Wearable Electronics
(invited), T. Sekitani: 2014 MRS Fall Meeting &Exhibit,Boston, Massachusetts,USA December 4 2014.
[5]Imperceptible Organic Electronics Systems for Bio-Medical Applications (invited), T. Sekitani:
2014International Conference on Electronics Packaging.
[6]1-ȝ㹫㸫thick Organic electronics, "Going Thin for Ultraflexible, Stretchable, and Scalable Biomedical
Sensors" (invited), T. Sekitani: Golden Gate Polymer Forum,Palo Alto.
[7]Imperceptible Electronics Skin (invited), T. Sekitani: 2014 Society for Information Display.
[8]Ultraflexible Organic Transistor Active Matrix using Self-assembled Monolayer Gate Dielectrics
(invited), T. Sekitani: The 21st International Worshop on Active-matris Flatpanel Displays and Devices.
[9]Tutorial of AMFPD2014,Organic Transistors and Flexible Electronics-from Materials to Medical
Applications (invited), T. Sekitani: The 21st International Worshop on Active-matris Flatpanel Displays
and Devices.
[10]Large-area,Flexible Active Matrix Sensors and Energy Harvesting Systemsusing Polymer Electrets
(invited), T. Sekitani: 15th International Symposium on Electrets,John Hopkins University.
[11]Ultraflexible Organic Thin-film Transistors on 1-micron Thick Plastic Substrates (invited), T.
Sekitani: Organic Field-Effect Transistors XIII㹼Session 5:Transistor Devices I.
[12]Organic Transistor-based Wireless Sensor System for Biomedical Applications (invited), T. Sekitani:
Organic Semiconductor in Sensors and Bioelectronics VII,SPIE Organic Photonics+Electronics.
[13]Ultraflexible Organic Integrated Circuits on 1 ȝ㹫㸫Thick Plastic Substrates for Imperceptible
Medical Sensors (invited), T. Sekitani: IMID2014.
[14]Ultra-flexible Organic LEDs and Electronics Systems for Inperceptible Medical Sensors (invited), T.
Sekitani: OLEDs World Summit 2014.
[15]1-ȝ㹫㸫Thick Organic Electronics for Biomedical Sensors (invited), T. Sekitani: The 6st
International Worshop on Flexible&Printable Electronics.
[16] Imperceptible Active Matrix Sensors for Bio-medical Applications “Going Thin for
Ultraflexible,Stretchable, and Scalable Biomedical Sensors (invited), T. Sekitani: Holst Center-Osaka
University COI Joint Program.
[17]Imperceptible Active Matrix Sensors for Bio-medical Applications, "Going Thin for
Ultraflexible,Stretchable, and Scalable Biomedical Sensors (invited), T. Sekitani: imec-Osaka University
COI Joint Program.
[18]Ultraflexible Organic Electronics Systems for Imperceptible Bio-medical Sensors (invited), T.
Sekitani: ENGE2014.
[19]Opening Address of "Flexible Electronics" (invited), T. Sekitani: IDW2014.
[20]Ultraflexible Integrated Circuits for Imperceptible Bio-sensors (invited), T. Sekitani: 2nd SANKEN
Core to Core Symposium,3rd imec Handai International Symposium,2nd Symposium of SANKEN Brain
― 163 ―
Circulation Program.
[21]Ultraflexible Organic Integrated Circuits for Imperceptible Medical Sensors (invited), T. Sekitani:
11th International Conference on Nano-Molecular Electronics,Session.
[22]Large-area, ultra-flexible organic electronics (invited), T. Sekitani: 581.Wilhelm und
Heraeus-Seminar Flexible,Stretchable and Printable High Performance Electronics.
[23]Abou t development of wearble sensor which utilized flexible electronics (invited), T. Sekitani:
JEITA.
[24]Large-area,ultra-flexible organic electronics for biomedical applications (plenary), T. Sekitani:
Innovation in Large-area Electronics Conference(innoLAE)2015.
[25]Suppression of angiogenesis by electric stimulation (oral), T. Sekitani: BioEM2014, BEMS, EBEA.
[26]Mechanically-Adaptive Organic Transistors with Acute In-Vivo Stability (oral), T. Sekitani:
2014Material Research Sociaty Spring Meeting, Symposium Z:Bioelectronics…Materials,Processes and
Applications.
[27]Organic Transistor Based Wireless Sensor System with ESD Protection Circuit (oral), T. Sekitani:
2014Material Research Sociaty Spring Meeting,Symposium Z:Bioelectronics…MaterialsࠊProcesses and
Applications.
[28]Imperceptible Magnetoelectronics (invited), T. Sekitani: IEEE International Magnetics
Conference,INTERMAG Europe 2014,International Congress Center Dresden,.
[29]Heat Protection Circuit with Polymer PTC for Flexible Electronics (oral), T. Sekitani: SSDM2014.
[30]RF pulse design for MRI of samples including conductive implants (oral), T. Sekitani: 2014URSI
General Assembly and Scientific Symposium.
[31]MRI-CompatibleࠊUltra-thin, and Flexible Stimulator Array for Functional Neuroimaging by Direct
Stimulation to the Rat Brain (oral), T. Sekitani: 36th Annual International Cxonference of the IEEE
Engineering in Medicine and Biology Society.
[32]Suppression of angiogenesis by electric stimulation (oral), T. Sekitani: BEMS and the EBEA.
[33]Basic Characteristics of Implantable Flexible Pressure Sensor for Wireless Readout using MRI (oral),
T. Sekitani: 36th Annual International Conference of the IEEE Engineering in Medicine and Biology
Society.
[34]Sensitive Range Controllable Temperature Sensor Based on Polymer (oral), T. Sekitani: 2014MRS
Fall Meeting 㸤Exhibit.
[35]Ultraflexible organic devices and electrodes for implantable electronics (oral), T. Sekitani: ICOE
satellite Workshop on Implantable Organic Electronics.
[36]Ultrathin,short channel,thermally-stable organic transistors for neural interface systems (poster), T.
Sekitani: IEEE2014 Biomedical Circuits and Systems Conferencs.
[37]Fabrication of Flexible OLED display using printed reflection electrode placed on the reverse side of
OTFT array (oral), T. Sekitani: The 5th International Conference on Flexible and Printed Electronics.
― 164 ―
[38]Ultra Light-Weight and Highly Stretchable Magnetoelectronics for Imperceptible on-Skin Sensorics
(oral), T. Sekitani: The 59th Annual Magnetism and Magnetic Materials Conference.
[39]Priintable,highly conductive elastic conductors for stretchable organic transistor (oral), T. Sekitani:
2014 MRSFall Meeting & Exhibit.
[40]Organic ultrathin-film photonic and electronics devices on 1ȝm thick ultra-flexible substrate (oral), T.
Sekitani: SPIE.PHOTONICS WEST BIOS.
[41]Stretchable and imperceptible magnetoelectronics (invited), T. Sekitani: Wilhelm und Else
Heraeus-Seminar on Flexible,Stretchable and Printable High Performance Electronics.
[42]Energy-Autonomous Fever Alarm Armband Integrating Fully Flexible Solar Cells,Piezoelectric
Speaker,Temperature Detector,and 12V Organic Complementary FET Cirusuits (oral), T. Sekitani: 2015
IEEE ISSCC.
[43]Printed silver nanowires track by laser process (oral), T. Sekitani: The 2014International Conference
on Flexible and Printed Electronics.
[44]Non-contact printing of silver nanowires for stretchable/transparent electrodes (oral), T. Sekitani:
LOPEC 7th International Exhibition and Conference for the Printed Electronics Industry.
[45]Printed silver nanowires track by laser process (oral), T.Araki, Rajesh Mandamparambil, Iryna
Yakimets, Jeroen van den Brand, M.Nogi, H.Koga, Jinting Jiu, T.Sekitani,S.Katsuaki: The 2014
International Conference on Flexible and Printed Electronics.
[46]Non-contact printing of silver nanowires for stretchable/ transparent electrodes (oral), T.Araki, Rajesh
Mandamparambil, Iryna Yakimets, Jeroen van den Brand, M.Nogi, H.Koga, Jinting Jiu,
T.Sekitani,S.Katsuaki: LOPEC 7th International Exhibition and Conference for the Printed Electronics
Industry.
[47]ULTRAFLEXIBLE INTEGRATED CIRCUITS FOR IMPERCEPTIBLE BIO-SENSORS (invited),
T.Araki: Design, Automation & Test in Europe (DATE) 2015.
[48]Void Formation by Surface-Diffusion-Driven Evolution of Hole Patterns on Si(001) (invited),
K.Sudoh: The Korean Physical Society Spring Meeting, Daejeon, Korea, April 23-25, 2014.
ゎㄝࠊ⥲ㄝ
㉸ⷧ⭷ࡢ᭷ᶵ࢚ࣞࢡࢺࣟࢽࢡࢫ, 㛵㇂Ẏ, ᛂ⏝≀⌮, ᛂ⏝≀⌮Ꮫ఍, 83 (2014), 464.
ⴭ᭩
[1]㏱࣏࣐࣮᫂ࣜࡢᮦᩱ㛤Ⓨ࡜㧗ᛶ⬟໬ , 㛵㇂ Ẏ, ࢩ࣮࢚࣒ࢩ࣮, 21 (271-284) 2015.
≉チ
[1]ࠕᅜ㝿≉チฟ㢪ࠖࢼࣀ࣡࢖ࣖࢿࢵࢺ࣮࣡ࢡࡢග㌿෗ἲ, PCT/NL2014/050218
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
㛵㇂ Ẏ
2014nternational Conference on Solid State Devices and Materials (ㄽᩥጤဨ఍⥲
ົ)
㛵㇂ Ẏ
2015nternational Conference on Solid State Devices and Materials (ㄽᩥጤဨ఍⥲
ົ)
㛵㇂ Ẏ
Printed Memory and Circuits at SPIE Optics+Photonics 201㸳 (ㄽᩥጤဨ)
㛵㇂ Ẏ
International Conference on Microelectronic Test Structure (ㄽᩥጤဨ)
㛵㇂ Ẏ
2015 Material Research Society Spring Meeting (ࢭࢵࢩࣙࣥ⤌⧊ጤဨ)
― 165 ―
ᅜෆᏛ఍
LSI ࡜ࢩࢫࢸ࣒ࡢ࣮࣡ࢡࢩࣙࢵࣉ
ICD ⱝᡭ◊✲఍
ࢯࣇࢺ࢚࣮ࣛຮᙉ఍
᪥ᮏ໬Ꮫ఍➨ 95 ᫓Ꮨᖺ఍ 2015
㟁Ẽ໬Ꮫ఍➨ 82 ᅇ኱఍
➨ 62 ᅇᛂ⏝≀⌮Ꮫ఍᫓ᏘᏛ⾡ㅮ₇఍
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᳜ᮧ 㝯ᩥ
࡜㧗㏿ࢹࣂ࢖ࢫ㛤Ⓨ
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ࢩࢫࢸ࣒ࡢヨస
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⾡᣺⯆ᶵᵓ㸦JST)
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(බ㈈)᪥❧㔠ᒓ࣭ᮦᩱ⛉Ꮫ㈈ᅋ
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㛵㇂ Ẏ
බ┈㈈ᅋἲே ᪥᥹࣭ᐇྜྷዡᏛ఍ ⌮஦㛗 ➉ෆᩗ௓
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᪥ᮏゐ፹
ࣇࣞ࢟ࢩࣈࣝࢭࣥࢧ࣮ࡢࡓࡵࡢ⮬
ᕫ⤌⧊໬⬟ࢆ᭷ࡍࡿ᭷ᶵ㉸ศᏊ⣔
⤯⦕ᮦᩱࡢ㛤Ⓨ
Ꮫᰯἲே ⏥༡Ꮫᅬ
ࢩࣜࢥࣥᇶ┙ࢆ฼⏝ࡋࡓ㉸ᖹᆠࢩ
㡲⸨ Ꮥ୍
ࣜࢥ࣭ࣥࢼࣀ࣓ࣥࣈࣞࣥࡢᙧᡂ
༢఩㸸༓෇
6,370
3,240
11,570
900
130
24,700
49,982
46,815
800
2,261
2,000
900
3,000
500
490
1,000
0
」ྜ▱⬟࣓ࢹ࢕࢔◊✲ศ㔝
ཎⴭㄽᩥ
[1]Phase Estimation of a Single Quasi-Periodic Signal, Y. Makihara, M.R. Aqmar, T.T. Ngo, H. Nagahara,
R. Sagawa, Y. Mukaigawa, and Y. Yagi: IEEE Transactions on Signal Processing, 62 (8) (2014)
2066-2079.
― 166 ―
[2]Multiplexed Spatiotemporal Communication Model in Artificial Neural Networks, S. Tamura, Y.
Nishitani, T. Kamimura, Y. Yagi, C. Hosokawa, T. Miyoshi, H. Sawai, Y. Mizuno-Matsumoto, and Y.-W.
Chen: Automation, Control and Intelligent Systems, 1 (6) (2014) 121-130.
[3]Quality-dependent Score-level Fusion of Face, Gait, and the Height Biometrics, T. Kimura, Y.
Makihara, D. Muramatsu, and Y. Yagi: IPSJ Trans. on Computer Vision and Applications, 6 (2014) 53-57.
[4]୰㛫᪉ྥ࡬ࡢ᪉ྥኚ᥮ࣔࢹࣝࢆ⏝࠸ࡓṌᐜㄆド, ᮧᯇ ኱࿃ࠊᵐཎ 㟹ࠊඵᮌ ᗣྐ: 㟁Ꮚ᝟ሗ
㏻ಙᏛ఍ㄽᩥㄅ A ࣂ࢖࣓࢜ࢺࣜࢡࢫᑠ≉㞟, J97-A (12) (2014) 749-752.
[5]୍Ṍ⾜ᫎീ࠿ࡽྲྀᚓࡉࢀࡿ」ᩘ≉ᚩࢆ⏝࠸ࡓಶேㄆド, ᮧᯇ ኱࿃ࠊᒾ㛫 ᬕஅࠊᮌᮧ ༟ᘯࠊ
ᵐཎ 㟹ࠊඵᮌ ᗣྐ: 㟁Ꮚ᝟ሗ㏻ಙᏛ఍ㄽᩥㄅ A, J97-A (12) (2014) 735-748.
[6]Head Orientation Estimation using Gait Observation, M. Nakazawa, I. Mitsugami, H. Yamazoe, and Y.
Yagi: IPSJ Trans. on Computer Vision and Applications, 6 (2014) 63-67.
[7]Many-to-Many Superpixel Matching for Robust Tracking, J. Wang and Y. Yagi: IEEE Trans. on
Cybernetics, 44 (7) (2014) 1237-1248.
[8]Extraction of Potential Sunny Region for Background Subtraction under Sudden Illumination Changes,
I. Mitsugami, H. Fukui, and M. Minoh: International Journal of Computer Vision and Signal Processing,
4 (2014) 22-28.
[9]Gait-based Person Recognition Using Arbitrary View Transformation Model, D. Muramatsu, A.
Shiraishi, Y. Makihara, M.Z. Uddin, and Y. Yagi: IEEE Trans. on Image Processing, 24 (1) (2015)
140-154.
[10]Lensless imaging for wide field of view, H. Nagahara and Y. Yagi: Optical Engineering, 54 (2) (2015)
025114.
[11]Mixed-Reality World Exploration Using Image-Based Rendering, F. Okura, M. Kanbara, and N.
Yokoya: ACM Journal on Compuiting and Cultural Heritage, 8 (2) (2015) 9:1-9:26.
[12]Background estimation for a single omnidirectional image sequence captured with a moving camera,
N. Kawai, N. Inoue, T. Sato, F. Okura, Y. Nakashima, and N. Yokoya: IPSJ Trans. on Computer Vision
and Applications, 6 (2014) 68-72.
[13]Aerial full spherical HDR imaging and display, F. Okura, M. Kanbara, and N. Yokoya: Virtual Reality
(Springer), 18 (4) (2014) 255-269.
ᅜ㝿఍㆟
[1]Indirect augmented reality considering real-world illumination change, F. Okura, T. Akaguma, T. Sato,
and N. Yokoya: Proc. of the 13th IEEE Int'l Symp. on Mixed and Augmented Reality (ISMAR'14), (2014)
287-288.
[2]Gait Recognition under Speed Transition, A. Mansur, Y. Makihara, M.R. Aqmar, and Y. Yagi: Proc. of
the 27th IEEE Conf. on Computer Vision and Pattern Recognition (CVPR 2014), (2014) 2521-2528.
[3]Score-Level Fusion by Generalized Delaunay Triangulation, Y. Makihara, D. Muramatsu, M.A.
Hossain, H. Iwama, T.T. Ngo, and Y. Yagi: Proc. of the 2nd IEEE/IAPR International Joint Conference on
Biometrics (IJCB 2014), (O18) (2014) 1-8.
[4]Cross-view Gait Recognition using View-dependent Discriminative Analysis, A. Mansur, Y. Makihara,
D. Muramatsu, and Y. Yagi: Proc. of the 2nd IEEE/IAPR International Joint Conference on Biometrics
― 167 ―
(IJCB 2014), (O20) (2014) 1-7.
[5]Surface Normal Deconvolution: Photometric Stereo for Optically Thick Translucent Objects, C.
Inoshita, Y. Mukaigawa, Y. Matsushita, and Y. Yagi: Proc. of the 13th European Conference on Computer
Vision (ECCV 2014), (2014) 371-384.
[6]Estimating depth of layered struture based on multispetral spekle correlation, T. Matsumura, Y.
Mukaigawa, and Y. Yagi: Proc. of the 4th Joint 3DIM/3DPVT Conf. (3DV 2014), (2014) 217 - 223.
[7]Segmenting Reddish Lesions in Capsule Endoscopy Images Using a Gastrointestinal Color Space, H.
Vu, T. Echigo, Y. Imura, Y. Yanagawa, and Y. Yagi: Proc. of the 22nd Int. Conf. on Pattern Recognition
(ICPR 2014), (2014) 3263-3268.
[8]Light Transport Refocusing for Unknown Scattering Medium, Md. A. Mannan, S. Tagawa, T. Tamaki,
H. Nagahara, Y. Mukaigawa, and Y. Yagi: Proc. of the 22nd Int. Conf. on Pattern Recognition (ICPR
2014), (2014) 4382-4387.
[9]A new gait-based identification method using local Gauss maps, H. El-Alfy, I. Mitsugami, and Y. Yagi:
Proc. of the ACCV 2014 Workshop on Human Gait and Action Analysis in the Wild: Challenges and
Applications, (2014) 3-18.
[10]Robust Gait Recognition, Y. Makihara: Proc. of the ACCV 2014 Workshop on Human Gait and
Action Analysis in the Wild: Challenges and Applications, (2014) .
[11]Surface Reconstruction of Glossy Objects, I. Mitsugami: Proc. of the 17th Int. Conf. on Computing
and Information Technology (ICCIT 2014), (2014) .
[12]3-D Measurement and Analysis of Walking Person by Range Sensing, I. Mitsugami: Proc. of the 3rd
Int. Conf. on Informatics, Electronics & Vision (ICIEV 2014), (2014) .
ゎㄝࠊ⥲ㄝ
Ṍ⾜⪅ㄆド࡟࠾ࡅࡿ࣐ࣝࢳ࣮ࣔࢲࣝࣂ࢖࣓࢜ࢺࣜࢡࢫ, ᮧᯇ ኱࿃ࠊᵐཎ 㟹ࠊᒾ㛫 ᬕஅࠊඵᮌ ᗣ
ྐ, ⮬ືㄆ㆑, ᪥ᮏᕤᴗฟ∧ᰴᘧ఍♫, 27[7] (2014), 21-25.
㜵≢࣓࢝ࣛᫎീࡢရ㉁ࢆ⪃៖ࡋࡓṌᐜ࣭㢌㒊࣭㌟㛗࡟ࡼࡿಶேㄆド, ᵐཎ 㟹ࠊᮌᮧ ༟ᘯࠊᮧᯇ
኱࿃ࠊඵᮌ ᗣྐ, ⏬ീࣛ࣎, ᪥ᮏᕤᴗฟ∧ᰴᘧ఍♫, 26[3] (2015), 37-42.
ⴭ᭩
[1]Ṍᐜ࡟ࡼࡿ㧗⢭ᗘಶேㄆドᢏ⾡ࡢ㛤Ⓨ “㧗⢭ᗘ໬ࡍࡿಶேㄆドᢏ⾡”, ᵐཎ 㟹, ᮧᯇ ኱࿃,
ඵᮌ ᗣྐ, NTS ฟ∧, (181-191) 2014.
[2]཯ᑕගᏛ⣔࣭཯ᑕᒅᢡගᏛ⣔ࢆ⏝࠸ࡓ᪂ࡓ࡞඲᪉఩࣓࢝ࣛ “ឤぬࢹࣂ࢖ࢫ㛤Ⓨ”, ඵᮌ ᗣྐ,
㛗ཎ ୍, NTS ฟ∧, (52-64) 2014.
≉チ
[1]ࠕᅜෆ≉チฟ㢪ࠖ⢭⚄㞀ᐖホ౯᪉ἲࠊཬࡧ⢭⚄㞀ᐖホ౯ࢩࢫࢸ࣒, ≉㢪 2015-052205
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
ඵᮌ ᗣྐ
2014 IEEE Int. Conf. on Robotics and Automation (ICRA 2014) (⦅㞟ጤဨ)
ඵᮌ ᗣྐ
The 2014 Int. Conf. on Informatics, Electronics & Vision (ICIEV 2014) (ㅎၥጤဨ)
ඵᮌ ᗣྐ
2014 IEEE/RSJ Int. Conf. on Intelligent Robots and Systems (IROS 2014) (⦅㞟ጤ
ဨ)
ඵᮌ ᗣྐ
The 13th European Conf. on Computer Vision (ECCV 2014) (ᰝㄞጤဨ)
ඵᮌ ᗣྐ
The 12th Asian Conf. on Computer Vision Workshop (ࣉࣟࢢ࣒ࣛጤဨ)
― 168 ―
ඵᮌ
ඵᮌ
ඵᮌ
ඵᮌ
ᗣྐ
ᗣྐ
ᗣྐ
ᗣྐ
ඵᮌ
ඵᮌ
ඵᮌ
ඵᮌ
ᗣྐ
ᗣྐ
ᗣྐ
ᗣྐ
ඵᮌ ᗣྐ
ᵐཎ 㟹
ᵐཎ 㟹
ᵐཎ 㟹
ᵐཎ
ᵐཎ
ᵐཎ
ᵐཎ
ᵐཎ
㟹
㟹
㟹
㟹
㟹
ᵐཎ 㟹
ᵐཎ 㟹
ᵐཎ 㟹
ᵐཎ 㟹
ᵐཎ 㟹
ᵐཎ
ᵐཎ
ᵐཎ
‶ୖ
‶ୖ
㟹
㟹
㟹
⫱ஂ
⫱ஂ
‶ୖ ⫱ஂ
The 2015 Int. Conf. on Informatics, Electronics & Vision (ICIEV 2015) (ㅎၥጤဨ)
Information Security and Biometric Authentication 2015 (ࣉࣟࢢ࣒ࣛጤဨ)
The 13th Asian Conf. on Computer Vision (ACCV 2016) (㐠Ⴀጤဨ)
2015 IEEE 8th International Workshop on Computational Intelligence and
Applications (IWCIA 2015) (ࣉࣟࢢ࣒ࣛጤဨ)
The 8th IAPR Int. Conf. on Biometrics (ICB 2015) (ࣉࣟࢢ࣒ࣛጤဨ)
IEEE Int. Conf. on Information and Automation 2015 (ࣉࣟࢢ࣒ࣛጤဨ)
The 7th IEEE Int. Conf. on Biometrics, Applications, and Systems (ࣉࣟࢢ࣒ࣛጤဨ)
2015 IEEE/RSJ Int. Conf. on Intelligent Robots and Systems (IROS 2015) (⦅㞟ጤ
ဨ)
The 15th Int. Conf. on Computer Vision (ICCV 2015) (ᰝㄞጤဨ)
The 27th IEEE Conf. on Computer Vision and Pattern Recognition (CVPR 2014) (ࣉ
ࣟࢢ࣒ࣛጤဨ)
The 13th European Conf. on Computer Vision (ECCV 2014) (ᰝㄞጤဨ)
The 22nd Int. Conf. on Pattern Recognition (ICPR 2014) (ࢸࢡࢽ࣭࢝ࣝࣉࣟࢢ࣒ࣛጤ
ဨ)
The 2nd IEEE/IAPR Int. Joint. Conf. on Biometrics (IJCB 2014) (ᰝㄞጤဨ)
The 12th Asian Conf. on Computer Vision (ACCV 2014) (ࣉࣟࢢ࣒ࣛጤဨ)
The 12th Asian Conf. on Computer Vision Workshop (ࣉࣟࢢ࣒ࣛጤဨ㛗)
The 2014 Pacific-Rim Conf. on Multimedia (PCM 2014) (ࣉࣟࢢ࣒ࣛጤဨ)
The 10th Int. Conf. on Signal Image Technology and Internet-based Systems (SITIS
2014) (ࣉࣟࢢ࣒ࣛጤဨ)
The 11th IEEE Conf. on Automatic Face and Gesture Recognition (FG 2015) (ࣉࣟࢢ
࣒ࣛጤဨ)
The 3rd IAPR Asian Conf. on Pattern Recognition (ACPR 2015) (ࣉࣟࢢ࣒ࣛጤဨ)
3D Vision 2014 (3DV 2014) (ᰝㄞጤဨ)
The 28th IEEE Conf. on Computer Vision and Pattern Recognition (CVPR 2015) (ᰝ
ㄞጤဨ)
The 7th Pacific-Rim Symposium on Image and Video Technology (PSIVT 2015) (ᰝ
ㄞጤဨ)
2015 ACM Int. Conf. on Multimedia Retrieval (ICMR 2015) (ࣉࣟࢢ࣒ࣛጤဨ)
The 26th British Machine Vision Conf. (BMVC 2015) (ᰝㄞጤဨ)
IEICE Trans. on Information and Systems (⦅㞟ጤဨ)
The 12th Asian Conf. on Computer Vision (ACCV 2014) (ࣉࣟࢢ࣒ࣛጤဨ)
The 10th Int. Conf. on Signal Image Technology and Internet-based Systems (SITIS
2014) (ࣉࣟࢢ࣒ࣛጤဨ)
The 3rd IAPR Asian Conf. on Pattern Recognition (ACPR 2015) (ࣉࣟࢢ࣒ࣛጤဨ)
ᅜෆᏛ఍
➨ 17 ᅇ⏬ീࡢㄆ㆑࣭⌮ゎࢩ࣏ࣥࢪ࣒࢘
᝟ሗฎ⌮Ꮫ఍ ࢥࣥࣆ࣮ࣗࢱࣅࢪࣙࣥ࡜࢖࣓࣮ࢪ࣓ࢹ࢕࢔◊✲఍
➨ 4 ᅇࣂ࢖࣓࢜ࢺࣜࢡࢫ࡜ㄆ㆑࣭ㄆドࢩ࣏ࣥࢪ࣒࢘
㟁Ꮚ᝟ሗ㏻ಙᏛ఍ ࣂ࢖࣓࢜ࢺࣜࢡࢫ◊✲఍
➨ 19 ᅇ⏬ീࢭࣥࢩࣥࢢࢩ࣏ࣥࢪ࣒࢘
⢭ᐦᕤᏛ఍ ኱つᶍ⎔ቃ 3 ḟඖィ ࣔࢹࣜࣥࢢᑓ㛛ጤဨ఍ ➨ 14 ᅇᐃ౛◊✲఍
㧗ゎീᗘᆅᙧ᝟ሗࢩ࣏ࣥࢪ࣒࢘
ྲྀᚓᏛ఩
༤ኈ(᝟ሗ⛉Ꮫ)
஭ୗ ᬛຍ
ಟኈ(᝟ሗ⛉Ꮫ)
஭ᮧ ♸‶
ಟኈ(᝟ሗ⛉Ꮫ)
ᒸ⏣ ඾
Shape from Scattering: Shape Estimation Based on Light Transport Analysis in
Translucent Objects
࢝ࣉࢭࣝෆど㙾ᫎീࡢ⑓ኚᒁᡤᵓ㐀࡟࠾ࡅࡿඹ㉳᝟ሗࢆ⏝࠸ࡓ⑓ኚ᳨ฟ
ὀど᪉ྥኚ໬࡟㉳ᅉࡍࡿṌ⾜㐠ືኚ໬ࡢศᯒ
― 169 ―
12 ௳
6௳
3௳
2௳
1௳
1௳
1௳
ಟኈ(᝟ሗ⛉Ꮫ)
⏣ୖ ᣅᘺ
ಟኈ(᝟ሗ⛉Ꮫ)
ᯇᮧ 㝯ᘯ
Ṍᐜㄆドࡢࡓࡵࡢᶆ‽Ṍᐜࣔࢹࣝ࡜ࡢ↷ྜ࡟ᇶ࡙ࡃṌ⾜⪅㡿ᇦᢳฟ
ࡰࡅ⏬ീࢆ⏝࠸ࡓࢫ࣌ࢵࢡࣝ┦㛵ἲ࡟ࡼࡿᒙᵓ㐀ࡢ῝ࡉ᥎ᐃ
⛉Ꮫ◊✲㈝⿵ຓ㔠
ⱝᡭ◊✲(A)
ᵐཎ 㟹
ᣮᡓⓗⴌⱆ◊
✲
ᵐཎ 㟹
ཷク◊✲
ඵᮌ ᗣྐ
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
ඵᮌ ᗣྐ
ᩥ㒊⛉Ꮫ┬
ඵᮌ ᗣྐ
ᩥ㒊⛉Ꮫ┬
ዡᏛᐤ㝃㔠
ඵᮌ ᗣྐ
ඹྠ◊✲
ඵᮌ ᗣྐ
ඵᮌ ᗣྐ
ඵᮌ ᗣྐ
Ṍᐜࡺࡽࡂゎᯒ࡟ᇶ࡙ࡃṌᐜㄆドࡢ㧗⢭ᗘ໬
ࢡࣟࢫ࣮ࣔࢲࣝࣂ࢖࣓࢜ࢺࣜࢡࢫࡢᥦ᱌
Ṍᐜពᅗ⾜ືࣔࢹࣝ࡟ᇶ࡙࠸ࡓ
ே≀⾜ືゎᯒ࡜ᚰࢆ෗ࡍ᝟ሗ⎔
ቃࡢᵓ⠏
ே≀ᫎീゎᯒ࡟ࡼࡿ≢⨥ᤚᰝᨭ
᥼ࢩࢫࢸ࣒ 㸦Ᏻ඲࣭Ᏻᚰ࡞♫఍
ࡢࡓࡵࡢ≢⨥࣭ࢸࣟᑐ⟇ᢏ⾡➼
ࢆᐇ⏝໬ࡍࡿࣉࣟࢢ࣒ࣛ㸧
ே≀ᫎീゎᯒ࡟ࡼࡿ≢⨥ᤚᰝᨭ
᥼ࢩࢫࢸ࣒ 㸦Ᏻ඲࣭Ᏻᚰ࡞♫఍
ࡢࡓࡵࡢ≢⨥࣭ࢸࣟᑐ⟇ᢏ⾡➼
ࢆᐇ⏝໬ࡍࡿࣉࣟࢢ࣒ࣛ㸧
ᰴᘧ఍♫ᐩኈ㏻◊✲ᡤ㸪࣓ࢹ࢕࢔ฎ⌮ࢩࢫࢸ࣒◊✲ᡤ㸪ᡤ
㛗 㕥ᮌ ⚈἞
࢜ࣜࣥࣃࢫᰴᘧ఍♫ ᅜ
❧኱ᏛἲேዉⰋඛ➃⛉
Ꮫᢏ⾡኱Ꮫ㝔኱Ꮫ
බ❧኱Ꮫἲே኱㜰ᗓ❧
኱Ꮫࠊᅜ❧኱Ꮫἲே࿴ḷ
ᒣ኱ᏛࠊओᮾⰪ
⊂❧⾜ᨻἲே᝟ሗ㏻ಙ
◊✲ᶵᵓ
༢఩㸸༓෇
2,990
1,300
54,538
6,587
9,293
500
⓶⭵ࡢගᏛ≉ᛶࡢ᥎ᐃ࡟㛵ࡍࡿ
◊✲
1,000
ே≀ᫎീゎᯒ࡟ࡼࡿ≢⨥ᤚᰝᨭ
᥼ࢩࢫࢸ࣒
0
⩌㞟ᫎീ࠿ࡽࡢ⛣ື⤒㊰ᢳฟࡢ
ࡓࡵࡢṌᐜゎᯒᢏ⾡ࡢ᳨ウ
0
▱⬟᥎ㄽ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Bayesian estimation of causal direction in acyclic structural equation models with individual-specific
confounder variables and non-Gaussian distributions, S. Shimizu, K. Bollen: Journal of Machine
Learning Research, 15 (-) (2014) 2629-2652.
[2]A novel approach to predict toxicity from toxicogenomic data based on class association rule mining,
K. Nagata, T. Washio, Y. Kawahara and A. Unami: Toxicology Reports, 1 (-) (2014) 1133-1142.
[3]Application of continuous and structural ARMA modeling for noise analysis of a BWR coupled core
and plant instability event, M. Demeshko, A. Dokhane, T. Washio, H. Ferroukhi, Y. Kawahara and C.
Aguirre: Annals of Nuclear Energy, 75 (-) (2015) 645-657.
[4]Scatterplot layout for high-dimensional data visulaization, Y. Zheng, H. Suematsu, T. Itoh, R. Fujimaki,
S. Morinaga and Y. Kawahara: Journal of Visualization, 18 (1) (2015) 111-119.
[5]ሜኴ㝧ගⓎ㟁ᡤࡢᐇ ࢹ࣮ࢱ࡟ᇶ࡙ࡃ PV ศᕸࡢᖹ⁥໬ຠᯝ࡬ࡢᙳ㡪ศᯒ, Ᏻ୪ ୍ᾈ㸪㮖ᑿ
― 170 ―
㝯: 㟁ẼᏛ఍ㄽᩥㄅ B, 134 (10) (2014) 856-865.
[6]Toxicity prediction from toxicogenomic data based on class association rule mining, K. Nagata, T.
Washio, Y. Kawahara and A. Unamia: Toxicology Reports, 1 (-) (2014) 1133–1142.
ᅜ㝿఍㆟
[1]Multi-Task Feature Selection on Multiple Networks via Maximum Flows, M. Sugiyama, C.-A.
Azencott, D. Grimm, Y. Kawahara and K. M. Borgwardt: Proceedings of the 2014 SIAM International
Conference on Data Mining, (2014) 199–207.
[2]Efficient Generalized Fused Lasso with Application to the Diagnosis of Alzheimer’s Disease, B. Xin, Y.
Kawahara, Y. Wang and W. Gao: Proc. of the 28th AAAI Conf. on Artificial Intelligence (AAAI’14),
(2014) 2163-2169.
[3]Improving iForest with relative mass, S. Aryal, K. M. Ting, J. Wells and T. Washio: Proc. of
PAKDD2014: 18th Pacific-Asia Conference on Knowledge Discovery and Data Mining, Advances in
Knowledge Discovery and Data Mining, Lecture Notes in Computer Science, 8444 (2014) 510-521.
[4]mp-dissimilarity: A data dependent dissimilarity measure, S. Aryal, K. M. Ting, G. Haffari and T.
Washio: Proc. of ICDM2014:IEEE International Conference on Data Mining 2014, 1 (2014) DM570.
[5]A non-Gaussian approach for estimating possible causal direction in the presence of latent confounders
(invited), S. Shimizu: Conference on Statistics and Causality 2014.
[6]Estimation of causal direction in the presence of latent confounders and linear non-Gaussian structural
equation models (invited), S. Shimizu: Causal Modeling and Machine Learning.
[7]A performance comparison of generative and discriminative models in causal and anticausal problems
(poster), P. Blöbaum, S. Shimizu and T. Washio: 17th International Conference on Artificial Intelligence
and Statistics.
[8]On approximate non-submodular minimization via tree-structured supermodularity (poster), Y.
Kawahara, R. Iyer and J. Bilmes: Proc. of NIPS 2014 Workshop on Discrete and Combinatoria.
[9]Outliers on Concept Lattices (oral), M. Sugiyama: Workshop on Data Discretization and Segmentation
for Knowledge Discovery.
[10]Detecting Anomalous Subgraphs on Attributed Graphs via Parametric Flow (oral), M. Sugiyama, K.
Otaki: Workshop on Graph-based Algorithms for Big Data and its Applications.
[11]Multiple Testing Correction in Graph Mining (invited), M. Sugiyama: Tokyo Workshop on
Statistically Sound Data Mining.
ゎㄝࠊ⥲ㄝ
ᶵᲔᏛ⩦࡟ࡼࡿ᝟ሗㄽⓗ㔞Ꮚ≧ែࡢ␗ᖖ᳨▱, ⚟஭ ೺୍, ேᕤ▱⬟, ேᕤ▱⬟Ꮫ఍, 30 (2015),
217-223.
≉チ
[1]ࠕฟ㢪๓ㆡΏ≉チ㸦ᅜෆ࣭ᅜ㝿㸧ุูࠖࣔࢹࣝᏛ⩦⿦⨨ࠊุูࣔࢹࣝᏛ⩦᪉ἲ࠾ࡼࡧุูࣔࢹ
ࣝᏛ⩦ࣉࣟࢢ࣒ࣛ, K20110229
[2]ࠕฟ㢪๓ㆡΏ≉チ㸦ᅜෆ࣭ᅜ㝿㸧ࠖ᭱㐺ࢡ࢚ࣜ⏕ᡂ⿦⨨ࠊ᭱㐺ࢡ࢚ࣜᢳฟ᪉ἲ࠾ࡼࡧุูࣔࢹ
ࣝᏛ⩦᪉ἲ, K20110230
― 171 ―
[3]ࠕฟ㢪๓ㆡΏ≉チ㸦ᅜෆ࣭ᅜ㝿㸧
ࠖከḟඖࢹ࣮ࢱྍど໬⿦⨨ࠊ᪉ἲ࠾ࡼࡧࣉࣟࢢ࣒ࣛ, K20110251
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
ᮡᒣ 㯢ே
The 25th European Conference on Machine Learning and 18th Principles and Practice
of Knowledge Discovery in Databases (ࣉࣟࢢ࣒ࣛጤဨ)
ᮡᒣ 㯢ே
The 6th Asian Conference on Machine Learning (ࣉࣟࢢ࣒ࣛጤဨ)
㮖ᑿ 㝯
Neural Information Processing Systems Foundation 2014 (NIPS 2014) (ࣉࣟࢢ࣒ࣛ
ጤဨ)
㮖ᑿ 㝯
The European Conference on Machine Learning and Principles and Practice of
Knowledge Discovery in Databases (ECML/PKDD 2015) (ㄽᩥㄅ㒊㛛ᐈဨ⦅㞟ဨ)
㮖ᑿ 㝯
IEEE International Conference on Data Mining 2015 (ICDM2015) (ࢥࣥࢸࢫࢺጤဨ
㛗)
㮖ᑿ 㝯
The 19th Pacific-Asia Conference on Knowledge Discovery and Data Mining 2015
(PAKDD2015) (ᗈሗጤဨ㛗)
㮖ᑿ 㝯
ACM SIG-KDD'15: The 21st ACM SIGKDD Conference on Knowledge Discovery
and Data Mining (ࣉࣟࢢ࣒ࣛጤဨ)
㮖ᑿ 㝯
The 19th Pacific-Asia Conference on Knowledge Discovery and Data Mining
(PAKDD2014) (ࢩࢽ࢔ࣉࣟࢢ࣒ࣛጤဨ)
㮖ᑿ 㝯
The 2015 SIAM Data Mining Conference (SDM 2015) (ࣉࣟࢢ࣒ࣛጤဨ)
㮖ᑿ 㝯
IEEE International Conference on Data Mining 2015 (ICDM2015) (ࣉࣟࢢ࣒ࣛጤ
ဨ)
㮖ᑿ 㝯
Society for Industrial and Applied Mathematics, Division of Data Mining and
Analytics, Society for Industrial and Applied Mathematics (ࣉࣟࢢ࣒ࣛᣦ᥹⪅)
㮖ᑿ 㝯
DS-2014: the Seventeenth International Conference on Discovery Science (ࣉࣟࢢࣛ
࣒ጤဨ)
㮖ᑿ 㝯
ேᕤ▱⬟Ꮫ఍ᅜ㝿ࢩ࣏ࣥࢪ࣒࢘(JSAI-isAI 2014) (࢔ࢻࣂ࢖ࢨ࣮ࣜጤဨ)
㮖ᑿ 㝯
ACM SIGKDD'14: The 20th ACM SIGKDD Conference on Knowledge Discovery
and Data Mining (ࣉࣟࢢ࣒ࣛጤဨ)
㮖ᑿ 㝯
ECML/PKDD 2014: The European Conference on Machine Learning and Principles
and Practice of Knowledge Discovery in Databases 2014 (ࣉࣟࢢ࣒ࣛጤဨ)
㮖ᑿ 㝯
The Second IEEE ICDM (IEEE International Conference on Data Mining) Workshop
on Causal Discovery (CD 2014) (⤌⧊ጤဨ)
㮖ᑿ 㝯
ேᕤ▱⬟Ꮫ఍ேᕤ▱⬟Ꮫ஦඾᪂∧⦅㞟ጤဨ఍ (⦅㞟ጤဨ)
㮖ᑿ 㝯
ேᕤ▱⬟Ꮫ఍඲ᅜ኱఍ (ࣉࣟࢢ࣒ࣛጤဨ㛗)
Ἑཎ ྜྷఙ
Workshop on Graph-based Algorithms for Big Data and its Applications (ඹྠࣉࣟࢢ
࣒ࣛጤဨ㛗)
Ἑཎ ྜྷఙ
The 6th Asian Conference on Machine Learning (ࣉࣟࢢ࣒ࣛጤဨ)
Ἑཎ ྜྷఙ
The 17th International Conference on Artificial Intelligence and Statistics (ࣉࣟࢢࣛ
࣒ጤဨ)
Ἑཎ ྜྷఙ
The 23rd International World Wide Web Conference (ࣉࣟࢢ࣒ࣛጤဨ)
Ἑཎ ྜྷఙ
2014 SIAM International Conference on Data Mining (ࣉࣟࢢ࣒ࣛጤဨ)
ᅜෆᏛ఍
➨ 28 ᅇேᕤ▱⬟Ꮫ఍඲ᅜ኱఍
ேᕤ▱⬟Ꮫ఍ ➨ 95 ᅇ ேᕤ▱⬟ᇶᮏၥ㢟◊✲఍
ேᕤ▱⬟Ꮫ఍ ➨ 94 ᅇ ேᕤ▱⬟ᇶᮏၥ㢟◊✲఍
ᩘᏛ༠ാࣉࣟࢢ࣒࣮ࣛ࣡ࢡࢩࣙࢵࣉ ☜⋡ⓗࢢࣛࣇ࢕࢝ࣝࣔࢹࣝ
➨ 28 ᅇேᕤ▱⬟Ꮫ఍඲ᅜ኱఍
ᖹᡂ 26 ᖺ㟁ẼᏛ఍㟁ຊ࣭࢚ࢿࣝࢠ࣮㒊㛛኱఍
➨ 18 ᅇ᪥ᮏᚰ୙඲Ꮫ఍Ꮫ⾡㞟఍
ྲྀᚓᏛ఩
ಟኈ㸦ᕤᏛ㸧
⏣୰ ┤ᶞ
⏕ᡂ㐣⛬ࡢ␗࡞ࡿࢹ࣮ࢱࡀΰᅾࡍࡿሙྜࡢ㠀࢞࢘ࢫᅉᯝᵓ㐀᥎ᐃἲ
― 172 ―
5௳
1௳
1௳
1௳
3௳
1௳
1௳
Ꮫኈ㸦ᕤᏛ㸧
ᒸ ⁞
Ꮫኈ㸦ᕤᏛ㸧
㤿ሙ 㷋ே
ኚ໬Ⅼ᳨▱࡜ࢫࣃ࣮ࢫ᥎ᐃ࡟ᇶ࡙ࡃ࣏࣮ࢺࣇ࢛ࣜ࢜㑅ᢥ
ࣛࣥࢲ࣒ࢧࣥࣉࣜࣥࢢࢆ⏝࠸ࡓ㧗㏿㢖ฟࣃࢱ࣮࣐ࣥ࢖ࢽࣥࢢ
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(A)
㉸㧗ḟඖࢹ࣮ࢱ✵㛫࡟࠾ࡅࡿ⤫ィⓗ᥎ᐃ࣭ࢩ࣑࣮ࣗࣞࢩࣙ
㮖ᑿ 㝯
ࣥཎ⌮ࡢ㛤Ⓨ࡜ᛂ⏝ᒎ㛤
ᣮᡓⓗⴌⱆ◊✲ ࣔࢹ࣐ࣝ࢖ࢽࣥࢢ㸸㉸㧗ḟඖ኱つᶍࢹ࣮ࢱ࠿ࡽࡢᒁᡤࣔࢹ
㮖ᑿ 㝯
ࣝ᥈⣴ิᣲᡭἲࡢ᥈ồ
ⱝᡭ◊✲(B)
」ᩘࢹ࣮ࢱࢭࢵࢺ࠿ࡽࡢ㧗ḟඖᅉᯝࢿࢵࢺ࣮࣡ࢡ᥎ᐃἲࡢ
ΎỈ ᫀᖹ
㛤Ⓨ࡜⏕࿨⛉Ꮫ࡬ࡢᛂ⏝
᪂Ꮫ⾡㡿ᇦ◊✲ ␯ᛶࣔࢹࣜࣥࢢ࡬ࡢ⤌ྜࡏㄽⓗ࢔ࣉ࣮ࣟࢳ࡜᭱㐺໬
㸦◊✲㡿ᇦᥦ᱌
ᆺ㸧බເ◊✲
Ἑཎ ྜྷఙ
ᣮᡓⓗⴌⱆ◊✲ 㞳ᩓฝᛶ࡟ᇶ࡙ࡃᩚᩘࣃ࣓࣮ࣛࢱṇ๎໬Ꮫ⩦࡟ࡼࡿࣁ࣮ࢻ
Ἑཎ ྜྷఙ
࢙࢘࢔࣭ࣇࣞࣥࢻࣜ࡞ᶵᲔᏛ⩦
ᇶ┙◊✲(B)
㞳ᩓฝゎᯒ࡟ᇶ࡙ࡃᶵᲔᏛ⩦࢔ࣝࢦࣜࢬ࣒య⣔ࡢᵓ⠏࡜ࡑ
Ἑཎ ྜྷఙ
ࡢᛂ⏝
◊✲άືࢫࢱ࣮ ࢢࣛࣇᵓ㐀ࢹ࣮ࢱ࠿ࡽ⤫ィⓗ࡟᭷ព࡟㢖ฟࡍࡿ㒊ศᵓ㐀ࢆ
ࢺᨭ᥼
Ⓨぢࡍࡿᡭẁࡢ◊✲
ᮡᒣ 㯢ே
ཷク◊✲
㮖ᑿ 㝯
ᰴᘧ఍♫ᐩኈ㏻◊✲ᡤ
ศᯒᇶ┙ᢏ⾡ࡢ◊✲
㮖ᑿ 㝯
㸦⊂)ᚠ⎔ჾ⑓◊✲ࢭࣥ
៏ᛶᚰ୙඲ࡢணᚋࡢᩘᘧ໬࡜ࡑ
ࢱ࣮
ࡢጇᙜᛶ࡟㛵ࡍࡿከ᪋タ⮫ᗋ◊
✲
㸦⊂)ᚠ⎔ჾ⑓◊✲ࢭࣥ
៏ᛶᚰ୙඲ᝈ⪅࡟࠾ࡅࡿᚰ୙඲
㮖ᑿ 㝯
ࢱ࣮㸦ཌປ⛉◊㸦ศᢸ㸧㸧 ෌ධ㝔ண ࣔࢹࣝࡢᵓ⠏࡜἞⒪
ἲࡢᶆ‽໬࡟㛵ࡍࡿ◊✲
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ ⤫ィⓗ᭷ពᛶࢆᢸಖࡍࡿ㉸㧗㏿
ᮡᒣ 㯢ே
ࣃࢱ࣮ࣥⓎぢᢏ⾡ࡢ๰ฟ
ඹྠ◊✲
㮖ᑿ 㝯
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ ⤫ィ࣭ࢹ࣮ࢱ࣐࢖ࢽࣥࢢศ㔝࡟
࠾ࡅࡿ㞳ᩓᵓ㐀ฎ⌮ᛂ⏝ྍ⬟ᛶ
ࡢホ౯᳨࣭ド
ᰴᘧ఍♫ᮏ⏣ᢏ⾡◊✲
ኚศ᥎ㄽࢆᛂ⏝ࡋࡓ㌶㐨᭱㐺໬
Ἑཎ ྜྷఙ
ᡤ
࡟ࡼࡿࣟ࣎ࢵࢺືస⏕ᡂᡭἲࡢ
ඹྠ◊✲
⨾ὠ⃰ᰴᘧ఍♫ ⟃Ἴ኱
ࢫ࣏࣮ࢶ࡟㛵ࡍࡿࣅࢵࢢࢹ࣮ࢱ
Ἑཎ ྜྷఙ
Ꮫ
ࡢ᭷ຠά⏝࡟㛵ࡍࡿ◊✲
Ἑཎ ྜྷఙ
᪥ᮏ㟁ಙ㟁ヰᰴᘧ఍♫
㞳ᩓฝゎᯒ࡟ᇶ࡙ࡃᶵᲔᏛ⩦࢔
ࣝࢦࣜࢬ࣒య⣔ࡢᵓ⠏࡜ࡑࡢᛂ
⏝
༢఩㸸༓෇
13,520
2,080
650
2,210
1,430
4,810
1,300
2,000
50
500
4,875
1,032
2,000
300
0
▱㆑⛉Ꮫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]An ontological modeling approach for abnormal states and its application in the medical domain, Y.
Yamagata, K. Kozaki, T. Imai, K. Ohe and R.Mizoguchi: J. of Biomed Sem, 5 (1) (2014) 14pages.
[2]་⒪▱㆑ᇶ┙ࡢᵓ⠏࡟ྥࡅࡓ⑌ᝈ࢜ࣥࢺࣟࢪ࣮ࡢ Linked Open Data ໬ࠊྂᓮ ᫭ྖࠊᒣ⦩ ཭
⣖ࠊᅜᗓ ⿱Ꮚࠊ௒஭ ೺ࠊ኱Ụ ࿴ᙪࠊ⁁ཱྀ ⌮୍㑻: ேᕤ▱⬟Ꮫ఍ㄽᩥㄅ, 29 (4) (2014) 396-405.
― 173 ―
[3]⾲ᒙ㢮ఝᗘ࡟ᇶ࡙ࡃࢭࣥࢱ࣮ヨ㦂ࠗᅜㄒ࠘⌧௦ᩥഐ⥺㒊ၥ㢟ࢯࣝࣂ࣮, బ⸨ ⌮ྐࠊຍ⣡ 㞙ேࠊ
すᮧ ⩧ᖹࠊ㥖㇂ ࿴⠊: ⮬↛ゝㄒฎ⌮, 21 (3) (2014) 465-483.
[4]⾲ᒙ㢮ఝᗘ࡟ᇶ࡙ࡃ᪥ᮏㄒࢸ࢟ࢫࢺྵពㄆ㆑, ᭹㒊 ᪼ᖹࠊబ⸨ ⌮ྐࠊ㥖㇂ ࿴⠊: ேᕤ▱⬟
Ꮫ఍ㄽᩥㄅ, 29 (4) (2014) 416-426.
[5]⑌ᝈ࡟࠾ࡅࡿ␗ᖖ≧ែ࢜ࣥࢺࣟࢪ࣮ࡢᵓ⠏, ᒣ⦩཭⣖ࠊྂᓮ᫭ྖࠊ௒஭೺ࠊ኱Ụ࿴ᙪࠊ⁁ཱྀ⌮
୍㑻: ་⒪᝟ሗᏛ, 34 (3) (2014) 101-117.
[6]Technical Artifacts: An Integrated Perspective, S. Borgo, M. Franssen, P. Garbacz,Y. Kitamura, R.
Mizoguchi and P. E.Vermaas: J. of Applied Ontology, 9 (3-4) (2014) 217-235.
[7]┠ⓗᣦྥࡢ┳ㆤᡭ㡰Ꮫ⩦࡟ྥࡅࡓ」ᩘほⅬ࠿ࡽࡢ▱㆑㜀ぴࢩࢫࢸ࣒ CHARM Pad ࡜᪂ே┳ㆤ
ᖌ◊ಟ࡬ࡢᐇ㊶ⓗά⏝, すᮧᝅྐࠊ➲ᔱ᐀ᙪࠊ౗ᮧᚨಙࠊ୰ᮧ᫂⨾ࠊ㧗ᶫᘯᯞࠊᖹᑿ᫂⨾ࠊ᭹㒊
වᩄࠊ⁁ཱྀ⌮୍㑻: ேᕤ▱⬟Ꮫ఍ㄽᩥㄅ, 30 (1) (2015) 22-36.
ᅜ㝿఍㆟
[1]Systematic Description of Nursing Actions Based on Goal Realization Model (oral), S. Nishimura, Y.
Kitamura, M. Sasajima and R. Mizoguchi: Proc. of 15th European Conf. on Knowledge Management
(ECKM 2014), (2014) 730-739.
[2]Detecting Incorrectly-Segmented Utterances for Posteriori Restoration of Turn-Taking and ASR
Results (oral), N. Hotta, K. Komatani, S. Sato, M. Nakano: Proc. of 15th Annual Conference of the
International Speech Communication Association (Interspeech 2014), (2014) 313-317.
[3]Towards the Integration of Abnormality in Diseases (oral), Y. Yamagata, K. Kozaki and R. Mizoguchi:
Proc. of 5th International Conference on Biomedical Ontology (ICBO 2014), (2014) 7-12.
[4]An Intelligent SPARQL Query Builder for Exploration of Various Life-science Databases (oral), A.
Yamaguchi, K. Kozaki, K. Lenz, H. Wu and N. Kobayashi: Proc. of 3rd Intelligent Exploration of
Semantic Data (IESD2014), (2014) 12pages.
[5]A Keyword Exploration for Retrieval from Biomimetics Databases (oral), K. Kozaki and R.
Mizoguchi: Proc. of 4th Joint International Semantic Technology (JIST2014), (2014) 361-377.
[6]Choosing Related Concepts for Intelligent Exploration (oral), K. Kozaki: Proc. of 4th Joint
International Semantic Technology (JIST2014), (2014) 378-386.
[7]An Information Literacy Ontology and its Use for Guidance Plan Design -An Example on Problem
Solving- (oral), K. Kozaki, H. Kanoh, T. Hishida and M. Hasegawa: Proc. of 4th Joint International
Semantic Technology (JIST2014), (2014) 469-472.
[8]Boundary Contraction Training for Acoustic Models based on Discrete Deep Neural Networks (poster),
R. Takeda, N. Kanda and N. Nukaga: Proc. of 15th Annual Conference of the International Speech
Communication Association (Interspeech 2014), (2014) 1063-1067.
[9]An Ontology Explorer for Biomimetics Database (poster), K. Kozaki, R.Mizoguchi: Poster and Demo
Notes of 13th International Semantic Web Conference (ISWC2014), (2014).
[10]Ontology Building and its Application using Hozo (invited), K. Kozaki: 4th Joint International
Semantic Technology (JIST2014), (2014).
ⴭ᭩
[1]ᑐヰࢩࢫࢸ࣒ (ዟᮧ Ꮫ ⦅), ୰㔝ᖿ⏕ࠊ㥖㇂࿴⠊ࠊ⯪㉺Ꮥኴ㑻ࠊ୰㔝᭷⣖Ꮚ, ࢥࣟࢼ♫, (඲ 296
― 174 ―
࣮࣌ࢪ) 2015. .
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
㥖㇂ ࿴⠊
Special Interest Group on Discourse and Dialogue (SIGdial)㸦ᙺဨ㸧
The 15th Annual SIGdial Meeting on Discourse and Dialogue (SIGDIAL 2014)㸦ࣉࣟ
㥖㇂ ࿴⠊
ࢢ࣒ࣛጤဨ㸧
15th Annual Conference of the International Speech Communication Association
㥖㇂ ࿴⠊
(Interspeech 2014)㸦ᰝㄞጤဨ㸧
AAAI Workshop on Machine Learning for Interactive Systems (MLIS'14)㸦ࣉࣟࢢࣛ
㥖㇂ ࿴⠊
࣒ጤဨ㸧
6th International Workshop on Spoken Dialog Systems, IWSDS̓2015㸦ࣉࣟࢢ࣒ࣛ
㥖㇂ ࿴⠊
ጤဨ㸧
2015 Conference of the North American Chapter of the Association for
㥖㇂ ࿴⠊
Computational Linguistics ̽ Human Language Technologies (NAACL HLT 2015)
㸦ࣉࣟࢢ࣒ࣛጤဨ㸧
The 53rd Annual Meeting of the Association for Computational Linguistics and The
㥖㇂ ࿴⠊
7th International Joint Conference of the Asian Federation of Natural Language
Processing (ACL IJCNLP 2015)㸦ࣉࣟࢢ࣒ࣛጤဨ㸧
౗ᮧ ᚨಙ
International Journal of Advanced Engineering Informatics㸦⦅㞟ጤဨ㸧
౗ᮧ ᚨಙ
The 6th International Conference on Design Computing and Cognition㸦ㅎၥጤဨ㸧
The 4th Joint International Semantic Technology Conference (JIST2014) 㸦ࣉ
౗ᮧ ᚨಙ
ࣟࢢ࣒ࣛጤဨ㸧
౗ᮧ ᚨಙ
ྂᓮ ᫭ྖ
ྂᓮ ᫭ྖ
ྂᓮ ᫭ྖ
The 10th International Symposium on Tools and Methods of Competitive
Engineering (TMCE 2014) 㸦ࣉࣟࢢ࣒ࣛጤဨ㸧
The 4th Joint International Semantic Technology Conference (JIST2014) 㸦ࣉࣟࢢࣛ
࣒ጤဨ㸧
The International Workshop on Intelligent Exploration of Semantic Data (IESD2014)
㸦⤌⧊ጤဨ㸧
Journal of Information Processing㸦⦅㞟ጤဨ㸧
ᅜෆᏛ఍
ேᕤ▱⬟Ꮫ఍
᝟ሗฎ⌮Ꮫ఍
ゝㄒฎ⌮Ꮫ఍
ྲྀᚓᏛ఩
Ꮫኈ㸦ᕤᏛ㸧
㫽ᮧ ໶
Ꮫኈ㸦ᕤᏛ㸧
୰㔝 㡿♸
Ꮫኈ㸦ᕤᏛ㸧
ᒾᮏ ಇ㍜
ಟኈ㸦ᕤᏛ㸧
ቑ⏣ ኊᚿ
ಟኈ㸦ᕤᏛ㸧
ᑠᯘ 㝧
༤ኈ㸦ᕤᏛ㸧
すᮧ ᝅྐ
13 ௳
6௳
1௳
ᶵ⬟ᐇ⌧᪉ἲࢆ୰ᚰ࡜ࡋࡓ⏕≀つ⠊ᕤᏛ࢜ࣥࢺࣟࢪ࣮ࡢᵓ⠏࡜ࡑ ࡢ࢞࢖ࢻ
ࣛ࢖ࣥ࡟㛵ࡍࡿ⪃ᐹ
ᮍ▱ㄒ࡟㛵ࡍࡿ᝟ሗ⋓ᚓࡢࡓࡵࡢ༢ㄒ㛫㢮ఝᗘ࡟ᇶ࡙ࡃ㉁ၥ⏕ᡂ
ㄒᙡ⟶⌮᪉ἲࡢ⪃ᐹ࡟ᇶ࡙ࡃ⮬἞యᗈሗ᝟ሗࡢᑐヰⓗ㡢ኌ᳨⣴ࢩࢫࢸ࣒ࡢᵓ
⠏
ཧ↷㛵ಀ࡟࠶ࡿ is-a 㝵ᒙ㛫ࡢᴫᛕᐃ⩏ࡢ୍㈏ᛶ࡟╔┠ࡋࡓ࢜ࣥࢺࣟࢪ࣮ෆᐜ
Ὑ⦎ᨭ᥼ࢩࢫࢸ࣒ࡢ㛤Ⓨ
᝟ሗ࣭ឤ᝟⾜Ⅽ࡟㛵ࡍࡿㄒᙡࡢయ⣔ⓗᐃ⩏࡜㐩ᡂ᪉ᘧࡢࣔࢹࣝ໬࡟ࡘ࠸࡚ࡢ
⪃ᐹ
┠ⓗࢆᣦྥࡋࡓ⾜Ⅽⓗ▱㆑ࡢ⤫ྜ⟶⌮ᯟ⤌ࡳ࡜ࡑࡢ་⒪⌧ሙ࡟࠾ࡅࡿᐇ㊶ⓗ
㐺⏝
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(B)
ྂᓮ ᫭ྖ
ᇶ┙◊✲(B)
࢜ࣥࢺࣟࢪ࣮ࡢከḟඖⓗどⅬ⟶⌮࡟ᇶ࡙ࡃ㡿ᇦᶓ᩿ᆺࢭ࣐
ࣥࢸ࢕ࢵࢡࢹ࣮ࢱࡢ▱ⓗ᥈⣴
⑓㝔⤌⧊࡟࠾ࡅࡿ⾜ື࣐ࢽࣗ࢔ࣝᵓ㐀໬࡜ࡑࡢ㜀ぴࢩࢫࢸ
― 175 ―
༢఩㸸༓෇
4,290
3,250
➲ᔱ ᐀ᙪ
࣒ࡢ◊✲
ᇶ┙◊✲(B)
␗✀ࡢᶵ⬟ⓗᵓᡂ≀ࣔࢹࣝࡢࡓࡵࡢඹ㏻ᯟ⤌ࡳ࡜⤫ྜࣔࢹ
౗ᮧ ᚨಙ
ࣜࣥࢢࢶ࣮ࣝࡢ㛤Ⓨ
≉ู◊✲ဨዡບ ᛂ⏝࢜ࣥࢺࣟࢪ࣮࡟࠾ࡅࡿ☜⋡ࠊᅉᯝᛶࠊࣜࢫࢡࡢᐃᘧ໬
㈝
ྂᓮ ᫭ྖ
᪂Ꮫ⾡㡿ᇦ◊✲ ࣂ࢖࣑࣓࢜ࢸ࢕ࢡࢫ࣭ࢹ࣮ࢱ࣮࣋ࢫᵓ⠏
౗ᮧ ᚨಙ
᪂Ꮫ⾡㡿ᇦ◊✲ ࣂ࢖࣑࣓࢜ࢸ࢕ࢡࢫ࣭ࢹ࣮ࢱ࣮࣋ࢫᵓ⠏
ྂᓮ ᫭ྖ
ᇶ┙◊✲(A)
࢜ࣥࢺࣟࢪ࣮ᕤᏛ࡟ᇶ࡙ࡃḟୡ௦▱㆑ࢩࢫࢸ࣒ᵓ⠏᪉ἲㄽ
౗ᮧ ᚨಙ
ࡢ㛤Ⓨ
ᇶ┙◊✲(A)
࢜ࣥࢺࣟࢪ࣮ᕤᏛ࡟ᇶ࡙ࡃḟୡ௦▱㆑ࢩࢫࢸ࣒ᵓ⠏᪉ἲㄽ
ྂᓮ ᫭ྖ
ࡢ㛤Ⓨ
ᇶ┙◊✲㸦B㸧
ᅜ㝿ẚ㍑࡟ᇶ࡙࠸ࡓ᝟ሗࣜࢸࣛࢩ࣮࡟㛵ࡍࡿ࢜ࣥࢺࣟࢪ࣮
ྂᓮ ᫭ྖ
ࡢᵓ⠏࡜┠ᶆࡢศ㢮
≉ู◊✲ဨዡບ ♫఍ⓗไ⣙ࢆ⪃៖ࡋࡓࣟ࣎ࢵࢺ⏝㡢ኌᑐヰࢩࢫࢸ࣒ࡢᐇ⌧
㈝
ᮡᒣ ㈗᫛
ཷク◊✲
ྂᓮ ᫭ྖ
ᅜ❧኱Ꮫἲேᮾி኱Ꮫ
་⒪᝟ሗࢩࢫࢸ࣒ࡢࡓࡵࡢ་⒪
(ཌປ┬)
▱㆑ᇶ┙ࢹ࣮ࢱ࣮࣋ࢫ◊✲㛤
Ⓨ㸹ព࿡㛵ಀࣔࢹࣝタィ㛤Ⓨ
ዡᏛᐤ㝃㔠
㥖㇂ ࿴⠊
බ┈㈈ᅋἲே࢝ࢩ࢜⛉Ꮫ᣺⯆㈈ᅋ ⌮஦㛗 ᶔᑿ㝯ྖ
Honda Research Institute USA,Inc. President Hiroshi Kawagishi
㥖㇂ ࿴⠊
ඹྠ◊✲
㥖㇂ ࿴⠊
ᰴᘧ఍♫࣍ࣥࢲ࣭ࣜࢧ࣮ ᑐヰࢩࢫࢸ࣒࡟ࡼࡿ▱㆑⋓ᚓ࡜
ࢳ࣭࢖ࣥࢫࢸ࢕ࢳ࣮ࣗ
Ⓨヰ᳨ฟㄗࡾᅇ᚟ᡭἲ
ࢺ࣭ࢪࣕࣃࣥ
3,770
700
1,000
4,400
1,200
400
350
900
6,500
1,000
3,035
2,580
▱⬟࢔࣮࢟ࢸࢡࢳࣕ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Effects of Individual Health Topic Familiarity on the Activity Pattern during Health Information
Searches, I. Puspitasari, K. Moriyama, K. Fukui and M. Numao: JMIR Medical Informatics, 3 (1) (2015)
e16.
[2]An Intelligent Fighting Videogame Opponent Adapting to Behavior Patterns of the User, K. Moriyama,
S. E. O. Branco, M. Matsumoto, K. Fukui, S. Kurihara and M. Numao: IEICE Transactions on
Information and Systems, E97-D (4) (2014) 842-851.
[3]An Analysis of Player Affect Transitions in Survival Horror Games, V. Vachiratamporn and R. Legaspi
and K. Moriyama and K. Fukui and M. Numao: Journal on Multimodal User Interfaces, 9 (1) (2015)
43-54.
[4]SIR-Extended Information Diffusion Model of False Rumor and its Prevention Strategy for Twitter, Y.
Okada, K. Ikeda, K. Shinoda, F. Toriumi, T. Sakaki, K. Kazama, M. Numao, I. Noda and S. Kurihara:
Journal of Advanced Computational Intelligence and Intelligent Informatics, 18 (4) (2014) 598-607.
[5]Discovering Seismic Interactions after the 2011 Tohoku Earthquake by Co-occurring Cluster Mining,
K. Fukui, D. Inaba and M. Numao: Transactions of Japanese Society for Artificial Intelligence, 29 (6)
(2014) 493-502.
[6]Sidekick: A Tool for Helping Students Manage Behavior in Self-initiated Learning Scenarios, P. S.
― 176 ―
Inventado, R. Legaspi, K. Moriyama, K. Fukui and M. Numao: International Journal of Distance
Education Technologies, 12 (4) (2014) 32-54.
[7]Predicting Research Trends Identified by Research Histories via Breakthrough Researches, N.
Yamashita, M. Numao and R. Ichise: IEICE Transactions on Information and Systems, E98-D (2) (2015)
355-362.
ᅜ㝿఍㆟
[1]Cooperation-Eliciting Prisoner’s Dilemma Payoffs for Reinforcement Learning Agents, K. Moriyama,
S. Kurihara and M. Numao: Proc. The 13th International Conference on Autonomous Agents and
Multiagent Systems (AAMAS 2014), (2014) 1619-1620.
[2]Discovery of Damage Patterns in Fuel Cell and Earthquake Occurrence Patterns by Co-occurring
Cluster Mining, K. Fukui, D. Inaba and M. Numao: Proc. The 2014 AAAI Workshop for Discovery
Informatics, (2014) 19-26.
[3]An Implementation of Affective Adaptation in Survival Horror Games, V. Vachiratamporn, K.
Moriyama, K. Fukui and M. Numao: Proc. the 2014 IEEE Conference on Computational Intelligence and
Games (CIG 2014), (2014) 263-270.
[4]A First-Order Logic Representation Based Distance Function, N. Khamsemanan, C. Nattee and M.
Numao: Proc. 24th International Conference on Inductive Logic Programming, (2014) .
[5]Visualizations of First-Order Logic Representation Based Dataset, N. Khamsemanan, C. Nattee and M.
Numao: Proc. 24th International Conference on Inductive Logic Programming, (2014) .
[6]Fighter or Explorer? – Classifying Player Types in a Japanese-Style Role-Playing Game from Game
Metrics, K. Fischer, K. Moriyama, K. Fukui and M. Numao: Proc. Workshop on Computation: Theory
and Practice (WCTP-2014), (2014) 55-66.
[7]Learning better strategies with a combination of complementary reinforcement learning algorithms, W.
Fujita, K. Moriyama, K. Fukui and M. Numao: Proc. Workshop on Computation: Theory and Practice
(WCTP-2014), (2014) 43-54.
[8]Dynamic and Individual Emotion Recognition Based on EEG during Music Listening, N. Thammasan,
K. Fukui, K. Moriyama and M. Numao: Proc. Workshop on Computation: Theory and Practice
(WCTP-2014), (2014) 87-98.
[9]Predicting Consumer Familiarity with Health Topics by Query formulation and Search Result
Interaction, I. Puspitasari, K. Fukui, K. Moriyama and M. Numao: Lecture Notes in Artificial Intelligence,
8862 (2014) 1016-1022.
[10]Symbiotic Evolution to Generate Chord Progression Consisting of Four Parts for a Music
Composition System, N. Otani, S. Shirakawa and M. Numao: Lecture Notes in Artificial Intelligence,
8862 (2014) 849-855.
[11]Item-Based Learning for Music Emotion Prediction Using EEG Data, P. Vateekul, N. Thammasan, K.
Moriyama, K. Fukui and M. Numao: Proc. 5th International Workshop on Empathic Computing
(IWEC’14), (2014) .
[12]Design of Populations in Symbiotic Evolution to Generate Chord Progression in Consideration of the
Entire Music Structure, N. Otani, S. Shirakawa and M. Numao: Proc. 5th International Workshop on
Empathic Computing (IWEC’14), (2014) .
― 177 ―
[13]Emotion detection from several physiological sensors and its application to music and games
(invited), M. Numao: The 2nd International Workshop on Emotional Materials and Components, Seoul,
Korea, Sep. 26, 2014.
[14]Detection of Concept Drift on an Adaptive Monitoring System (oral), Y. Sakamoto, K. Fukui, D.
Nicklas, K. Moriyama and M. Numao: Workshop on Computation: Theory and Practice (WCTP-2014),
Manila, Philippines, Oct. 6-7, 2014.
ゎㄝࠊ⥲ㄝ
஦㇟⣔ิࢹ࣮ࢱ࠿ࡽࡢඹ㉳ᛶ࣐࢖ࢽࣥࢢ-⇞ᩱ㟁ụࡢᦆയ㛫࠾ࡼࡧᆅ㟈㛫ࡢ┦஫స⏝ᢳฟ-, ⚟஭
೺୍ࠊ἟ᑿṇ⾜, ேᕤ▱⬟, ேᕤ▱⬟Ꮫ఍, 30[2] (2014), 238-246.
ⴭ᭩
[1]Predictability Analysis of Aperiodic and Periodic Model for Long-Term Human Mobility Using
Ambient Sensors (M. Atzmueller, A. Chin, C. Scholz, and C. Trattner)“Mining, Modeling, and
Recommending ‘Things’ in Social Media (LNCS)”, D. Sodkomkham, R. Legaspi, K. Fukui, K. Moriyama,
S. Kurihara and M. Numao, Springer, 8940 (131-149) 2015.
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
἟ᑿ ṇ⾜
New Generation Computing (࢚ࣜ࢔࢚ࢹ࢕ࢱ)
἟ᑿ ṇ⾜
Frontiers of Science Symposium (஦ᴗጤဨ)
἟ᑿ ṇ⾜
Pacific Rim International Conference on Artificial Inteligence (ࣉࣟࢢ࣒ࣛጤဨ)
἟ᑿ ṇ⾜
International Workshop on Empathic Computing (࣮࢜࢞ࢼ࢖ࢨ/ࣉࣟࢢ࣒ࣛጤ㛗
㛗)
἟ᑿ ṇ⾜
Workshop on Computing Theory and Practice (⤌⧊ጤဨ㛗)
἟ᑿ ṇ⾜
ICT4 Aging Well (ࣉࣟࢢ࣒ࣛጤဨ)
἟ᑿ ṇ⾜
5th International Conference on E-Service and Knowledge Management (ESKM
2014) (ࣉࣟࢢ࣒ࣛጤဨ)
᳃ᒣ ⏥୍
IEICE Transactions on Information and Systems (⦅㞟ጤဨ)
᳃ᒣ ⏥୍
The 14th International Conference on Autonomous Agents and Multiagent
Systems (AAMAS2015) (ࣉࣟࢢ࣒ࣛጤဨ)
᳃ᒣ ⏥୍
International Journal of Organizational and Collective Intelligence (ᰝㄞጤဨ)
᳃ᒣ ⏥୍
IEEE Computational Intelligence Society, the Adaptive Dynamic Programming and
Reinforcement Learning Technical Committee (ADPRLTC) (ጤဨ)
⚟஭ ೺୍
IPSJ Journal of Information Processing (⦅㞟ጤဨ)
⚟஭ ೺୍
Workshop on Computation: Theory and Practice (WCTP-2014) (ࣉࣟࢢ࣒ࣛጤဨ)
ᅜෆᏛ఍
ேᕤ▱⬟Ꮫ఍඲ᅜ኱఍
6௳
2௳
᝟ሗฎ⌮Ꮫ఍ᩘ⌮ࣔࢹࣝ໬࡜ၥ㢟ゎỴ◊✲఍
1௳
ேᕤ▱⬟Ꮫ఍▱㆑࣮࣋ࢫࢩࢫࢸ࣒◊✲఍
1௳
ィ ⮬ືไᚚᏛ఍▱⬟ࢩࢫࢸ࣒ࢩ࣏ࣥࢪ࣒࢘
ྲྀᚓᏛ఩
ಟኈ㸦᝟ሗ⛉Ꮫ㸧
ᒸ⏣ ెஅ
ಟኈ㸦᝟ሗ⛉Ꮫ㸧
ᆏᮏ ᝆ㍜
ಟኈ㸦᝟ሗ⛉Ꮫ㸧
ࢱ࣐ࣥࢧࣥ ࢼ
ࢵࢱ࣏ࣥ
ࢡࣛࢫࢱ⣔ิ࣐࢖ࢽࣥࢢ-ᩘ್ほ 㔞ࡢ஦㇟⣔ิ࡟ᑐࡍࡿࢡࣛࢫࢱ⣔ิࣃࢱ
࣮ࣥᢳฟᩍᖌ࡞ࡋᏛ⩦࡟࠾ࡅࡿࢹ࣮ࢱศᕸ㠀౫Ꮡᆺࢥࣥࢭࣉࢺࢻࣜࣇࢺ᳨ฟᡭἲࡢ᳨
ド
㡢ᴦ⫈ྲྀ᫬ࡢ⬻Ἴ࠿ࡽࡢືⓗ࠿ࡘಶேⓗ࡞ឤ᝟ㄆ㆑
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᣮᡓⓗⴌⱆ◊
㛫୺ほࡢᙧᘧ໬ࢆᨭ᥼ࡍࡿࡓࡵࡢศᩓ᥎ㄽᶵᵓ࡜ࢭࣥࢧ࣮
― 178 ―
༢఩㸸༓෇
1,300
✲
἟ᑿ ṇ⾜
ᣮᡓⓗⴌⱆ◊
✲
⚟஭ ೺୍
ඹྠ◊✲
἟ᑿ ṇ⾜
ࢿࢵࢺ࣮࣡ࢡ࡬ࡢᛂ⏝
ඹ㉳ࢡࣛࢫࢱ࣐࢖ࢽࣥࢢἲࡢ☜❧࡜ࡑࡢ⎔ቃ㈉⊩
1,300
ᰴᘧ఍♫ࣇ࢓࣮ࢫࢺࢩ
ࢫࢸ࣒
2,428
⏕యࢭࣥࢧ࠾ࡼࡧ᳨ᰝࡀ୙せ࡞
ࢫࢺࣞࢫࢳ࢙ࢵࢡࢩࢫࢸ࣒
㔞Ꮚᶵ⬟ᮦᩱ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Robust protection from backscattering in the topological insulator Bi1.5Sb0.5Te1.7Se1.3, Sunghun Kim,
Shunsuke Yoshizawa, Yukiaki Ishida, Kazuma Eto, Kouji Segawa, Yoichi Ando, Shik Shin, and Fumio
Komori: Phys. Rev. Lett., 112 (13) (2014) 136802/1-5.
[2]Top gating of epitaxial (Bi1-xSbx)2Te3 Topological insulator thin films, Fan Yang, A. A. Taskin, Satoshi
Sasaki, Kouji Segawa, Yasuhide Ohno, Kazuhiko Matsumoto, and Yoichi Ando: Appl. Phys. Lett., 104
(16) (2014) 161614/1-5.
[3]Infrared pseudogap in cuprate and pnictide high-temperature superconductors, S. J. Moon, Y. S. Lee, A.
A. Schafgans, A. V. Chubukov, S. Kasahara, T. Shibauchi, T. Terashima, Y. Matsuda, M. A. Tanatar, R.
Prozorov, A. Thaler, P. C. Canfield, S. L. Bud'ko, A. S. Sefat, D. Mandrus, K. Segawa, Y. Ando, and D. N.
Basov: Phys. Rev. B, 90 (1) (2014) 014503/1-16.
[4]Doping-dependent charge dynamics in CuxBi2Se3, Luke J. Sandilands, Anjan A. Reijnders, Markus
Kriener, Kouji Segawa, Satoshi Sasaki, Yoichi Ando, and Kenneth S. Burch: Phys. Rev. B, 90 (9) (2014)
094503/1-6.
[5]Pb5Bi24Se41: A New Member of the Homologous Series Forming Topological Insulator
Heterostructures, Kouji Segawa, A. A. Taskin, and Yoichi Ando: J. Solid State Chem., 221 (2014)
196-201.
[6]Electrical Detection of the Spin Polarization Due to Charge Flow in the Surface State of the
Topological Insulator Bi1.5Sb0.5Te1.7Se1.3, Yuichiro Ando, Takahiro Hamasaki, Takayuki Kurokawa, Kouki
Ichiba, Fan Yang, Mario Novak, Satoshi Sasaki, Kouji Segawa, Yoichi Ando, and Masashi Shiraishi:
Nano Lett., 14 (11) (2014) 6226-6230.
[7]Spin-Electricity Conversion Induced by Spin Injection into Topological Insulators, Y. Shiomi, K.
Nomura, Y. Kajiwara, K. Eto, M. Novak, Kouji Segawa, Yoichi Ando, and E. Saitoh: Phys. Rev. Lett., 113
(19) (2014) 196601/1-5.
[8]Superconductor derived from a topological insulator heterostructure, Satoshi Sasaki, Kouji Segawa,
and Yoichi Ando: Phys. Rev. B, 90 (22) (2014) 220504(R)/1-5.
[9]Scanning tunneling spectroscopy study of quasiparticle interference on the dual topological insulator
Bi1-xSbx, Shunsuke Yoshizawa, Fumitaka Nakamura, Alexey A. Taskin, Takushi Iimori, Kan Nakatsuji,
Iwao Matsuda, Yoichi Ando, and Fumio Komori: Phys. Rev. B, 91 (4) (2015) 045423/1-6.
[10]Large linear magnetoresistance in the Dirac semimetal TlBiSSe, Mario Novak, Satoshi Sasaki, Kouji
Segawa, and Yoichi Ando: Phys. Rev. B, 91 (4) (2015) 041203(R)/1-4.
[11]Topological Crystalline Insulators and Topological Superconductors: From Concepts to Materials,
Yoichi Ando and Liang Fu: Annu. Rev. Condens. Matter Phys., 6 (2015) 361-381.
[12]Ultrafast carrier relaxation through Auger recombination in the topological insulator
― 179 ―
Bi1.5Sb0.5Te1.7Se1.3, Yoshito Onishi, Zhi Ren, Kouji Segawa, Wawrzyniec Kaszub, Macieg Lorenc, Yoichi
Ando, and Koichiro Tanaka: Phys. Rev. B, 91 (8) (2015) 085306/1-12.
[13]Topological proximity effect in a topological insulator hybrid, T. Shoman, A. Takayama, T. Sato, S.
Souma, T. Takahashi, T. Oguchi, Kouji Segawa, and Yoichi Ando: Nature Communications, 6 (2015)
6547/1-6.
ᅜ㝿఍㆟
[1]Topological Insulators and Superconductors (invited), Y. Ando: OIST International Workshop on
Novel Quantum Materials and Phases (NQMP2014).
[2]Topological Insulators and Superconductors (invited), Y. Ando: New Trends in Topological Inslators
(NTTI) 2014.
[3]Progress toward Topological Insulator Devices (invited), Y. Ando: 32nd International Conference on
the Physics of Semiconductors (ICPS 2014).
[4]Topological Insulators and Superconductors (invited), Y. Ando: Workshop on Novel Quantum States in
Condensed Matter (NQS2014).
[5]Topological Superconductivity Based on Topological Insulators (invited), Y. Ando: International
Conference on Topological Quantum Phenomena (TQP2014).
[6]Experimental Research on Topological Insulators (invited), K. Segawa: International Conference on
Topological Quantum Phenomena (TQP2014).
[7]Superconducting Sn1-xInxTe Nanoplates (poster), S. Sasaki and Y. Ando: International Conference on
Topological Quantum Phenomena (TQP2014).
[8]Highly Gate-tunable Topological-Inslator Devices (poster), F. Yang, A. A. Taskin, S. Sasaki, K.
Segawa, Y. Ohno, K. Matsumoto, Y. Ando: International Conference on Topological Quantum Phenomena
(TQP2014).
[9]Electrical injection and extraction of spin polarized current through a ferromagnetic metal / topological
insulator interface (poster), Y. Ando, T. Hamasaki, F. Yang, M. Novak, S. Sasaki, K. Segawa, Y. Ando, M.
Shiraishi: International Conference on Topological Quantum Phenomena (TQP2014).
[10]Manipulation of topological states in a topological-insulator heterostructure (poster), T. Sato, K.
Nakayama, Y. Tanaka, S. Souma, T. Takahashi, K. Eto, S. Sasaki, K. Segawa, and Y. Ando: International
Conference on Topological Quantum Phenomena (TQP2014).
[11]Efficient Dual-Gate Tuning of Fermi Level in Thin-Film Topological Insulator (oral), A. Taskin, Fan
Yang, Satoshi Sasaki, Kouji Segawa, Yasuhide Ohno, Kazuhiko Matsumoto, Yoichi Ando: APS March
Meeting 2015.
[12]Manipulation of topological states in a topological-insulator heterostructure (oral), Yusuke Tanaka,
Kosuke Nakayama, Takafumi Sato, Seigo Souma, Takashi Takahashi, Kazuma Eto, Satoshi Sasaki, Kouji
Segawa, Yoichi Ando: APS March Meeting 2015.
ゎㄝࠊ⥲ㄝ
ࢺ࣏ࣟࢪ࢝ࣝ㉸ఏᑟయ㸸᥈⣴࡜᳨ドࡢヨࡳ, Ᏻ⸨㝧୍, ࣃࣜࢸ࢕, ୸ၿ, 30 (2015), 16-17.
ⴭ᭩
[1]ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యධ㛛 “ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యධ㛛”, Ᏻ⸨ 㝧୍, ㅮㄯ♫, (1-236) 2014.
― 180 ―
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
Ᏻ⸨㝧୍
International Conference on Topological Quantum Phenomena (TQP2014) (⤌⧊ጤ
ဨ)
ᅜෆᏛ఍
᪥ᮏ≀⌮Ꮫ఍ 2014 ᖺ⛅Ꮨ኱఍
᪥ᮏ≀⌮Ꮫ఍➨ 70 ᅇᖺḟ኱఍
ྲྀᚓᏛ఩
ಟኈ㸦ᕤᏛ㸧
బ⸨ ுኴ
ಟኈ㸦ᕤᏛ㸧
㢗 ᬂ
9௳
3௳
࢝ࣝࢥࢤࣥ໬ྜ≀ࢺ࣏ࣟࢪ࢝ࣝ≀㉁ࡢ㧗ရ㉁༢⤖ᬗᡂ㛗࡜ホ౯
ศᏊ⥺࢚ࣆࢱ࢟ࢩʊἲ࡟ࡼࡿࢺ࣏ࣟࢪ࢝ࣝ⤖ᬗ⤯⦕య SnTe ࡢస〇
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(S)
Ᏻ⸨ 㝧୍
ᇶ┙◊✲(C)
℩ᕝ ⪔ྖ
ዡᏛᐤ㝃㔠
బࠎᮌ ⪽
ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య㺃㉸ఏᑟయ࡟࠾ࡅࡿ᪂ወ࡞㔞Ꮚ⌧㇟ࡢ᥈ồ
༢఩㸸༓෇
25,740
㟁Ẽ໬Ꮫⓗᡭἲࢆ⏝࠸ࡓࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య࣭㉸ఏᑟయࡢ⢭ᐦ
≀ᛶไᚚ
1,040
බ┈㈈ᅋἲே ᮧ⏣Ꮫ⾡᣺⯆㈈ᅋ ⌮஦㛗 ᮧ⏣ᜏኵ
1,238
༙ᑟయᮦᩱ࣭ࣉࣟࢭࢫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]FT IR spectroscopy of nitric acid oxidation of silicon with hafnium oxide very thin layer, M. Kopani,
M. Mikula, E. Pinþík, H. Kobayashi, M. Takahashi: Appl. Surf. Sci., 301 (2014) 24-27.
[2]Properties of HfO2/ultrathin SiO2/Si structures and their comparison with Si MOS structures
passivated in KCN solution, E. Pinþík, H. Kobayashi, T. Matsumoto, M. Takahashi, M. Milan, R.
Brunner: Appl. Surf. Sci., 301 (2014) 34-39.
[3]Multifractal analysis of textured silicon surfaces, S. Jurecka, H. Angermann, H. Kobayashi, M.
Takahashi, E. Pinþík: Appl. Surf. Sci., 301 (2014) 46-50.
[4]Improvement of minority carrier lifetime and Si solar cell characteristics by nitric acid oxidation
method, F. Shibata, D. Ishibashi, S. Ogawara, T. Matsumoto, C.-H. Kim, H. Kobayashi: ECS J. Solid
State Sci. Technol., 3 (2014) Q137-Q141.
[5]Hydrogen effect on nanostructural features of nanocrystalline silicon thin films deposited at 200ÛC by
PECVD, D. Yano, M. Murayama, H. Kobayashi, K. Yamanaka: Solid State Phenom., 219 (2014)
221-224.
[6]Nitric acid oxidation of Si method for improvement of crystalline Si solar cell characteristics by
surface passivation effect, M. Maeda, K. Imamura, T. Matsumoto, H. Kobayashi: Appl. Surf. Sci., 312
(2014) 39-42.
[7]Si nanoparticles fabricated from Si swarf by photochemical method, T. Matsumoto, R. Hirose, F.
Shibata, D. Ishibashi, S. Ogawara, H. Kobayashi: Sol. Energ. Mat. Sol. C., 134 (2015) 298-304.
[8]Ultra-low power poly-Si TFTs with 10 nm stacked gate oxide fabricated by nitric acid oxidation of
silicon (NAOS) method, T. Matsumoto, H. Tsuji, S. Terakawa, H. Kobayashi: ECS J. Solid State Sci.
Technol., 4 (2015) N36-N40.
― 181 ―
ᅜ㝿఍㆟
[1]Improvement in conversion efficiencies of crystalline Si solar cells by surface technologies (invited),
H. Kobayashi: European Conference on Surface Science (ECOSS) 30.
[2]Fabrication of Si nanoparticles from Si swarf and the application to hydrogen generation source
(poster), T. Matsumoto, M. Maeda, T. Akai, S. Imai, H. Kobayashi: International Symposium on Small
Particles and Inorganic Clusters (ISPIC) XVII.
[3]Photoluminescence properties of Si nanoparticles fabricated from Si swarf: fluorescence enhancement
by organic molecules (poster), H. Kobayashi: International Symposium on Small Particles and Inorganic
Clusters (ISPIC) XVII.
[4]Surface modification technologies for improvement of crystalline Si solar cell efficiencies (invited), H.
Kobayashi, T. Matsumoto, K. Imamura: 7th Vacuum and Surface Sciences Conference of Asia and
Australia.
[5]Developments of crystalline Si solar cells using chemical methods (invited), H. Kobayashi:
Tunisia-Japan symposium, R&D on Energy and Materials Sciences for Sustainable Society.
[6]Fabrication of luminescent Si nanoparticles from Si swarf and fluorescence enhancement of adsorbed
molecules (poster), M. Maeda, T. Matsumoto, H. Kobayashi: KANSAI Nanoscience and Nanotechnology,
Handai Nanoscience and Nanotechnology International Symposium.
[7]Hydrogen generation from Si nanoparticles fabricated from Si swarf (poster), K. Kimura, M.
Takahashi, T. Matsumoto, Y. Kanatani, T. Higo, H. Kobayashi: KANSAI Nanoscience and
Nanotechnology, Handai Nanoscience and Nanotechnology International Symposium.
[8]Ultralow reflectivity surfaces by formation of nanocrystalline Si layer for crystalline Si solar cells and
achievement of high efficiency (poster), M. Maeda, T. Matsumoto, H. Kobayashi: KANSAI Nanoscience
and Nanotechnology, Handai Nanoscience and Nanotechnology International Symposium.
[9]High aspect ratio Si micro-holes formed by wet etching using Pt needles (poster), T. Akai, K. Imamura,
H. Kobayashi: KANSAI Nanoscience and Nanotechnology, Handai Nanoscience and Nanotechnology
International Symposium.
[10]New chemical methods for improvement of conversion efficiency of crystalline Si solar cells
(invited), H. Kobayashi: The 16th international symposium on eco-materials processing and design.
[11]New chemical methods to form Si nanocrystals for applications to Si Solar cells, Light emitting
materials, and… (poster), K. Imamura, T. Matsumoto, H. Kobayashi: Opto Osaka.
≉チ
[1]ࠕᅜෆ≉チฟ㢪ࠖኴ㝧㟁ụࠊኴ㝧㟁ụࡢ〇㐀᪉ἲཬࡧࡑࡢ〇㐀⿦⨨, ≉㢪 2014-173616
[2]ࠕᅜෆ≉チฟ㢪༙ࠖᑟయᇶᯈࠊ༙ᑟయ⿦⨨ࠊ༙ᑟయ⿦⨨ࡢ〇㐀᪉ἲཬࡧࡑࡢ〇㐀⿦⨨, ≉㢪
2014-173617
[3]ࠕᅜෆ≉チฟ㢪ࠖࢩࣜࢥࣥᇶᯈࠊኴ㝧㟁ụ࠾ࡼࡧࡑࡢ〇㐀᪉ἲ, ≉㢪 2014-173618
[4]ࠕᅜෆ≉チฟ㢪ࠖࣜࢳ࣒࢘࢖࢜ࣥ㟁ụࡢ㈇ᴟᮦᩱࠊࣜࢳ࣒࢘࢖࢜ࣥ㟁ụࠊࣜࢳ࣒࢘࢖࢜ࣥ㟁
ụࡢ㈇ᴟཪࡣ㈇ᴟᮦᩱࡢ〇㐀᪉ἲཬࡧࡑࡢ〇㐀⿦⨨, ≉㢪 2014-207397
[5]ࠕᅜෆ≉チฟ㢪༙ࠖᑟయᇶᯈࠊኴ㝧㟁ụࠊኴ㝧㟁ụࡢ〇㐀᪉ἲཬࡧࡑࡢ〇㐀⿦⨨, ≉㢪
2015-029211
― 182 ―
[6]ࠕᅜෆ≉チฟ㢪ࠖⅣ໬ࢣ࢖⣲ᇶᯈࠊⅣ໬ࢣ࢖⣲ᇶᯈࡢᖹᆠ໬ฎ⌮᪉ἲཬࡧࡑࡢ〇㐀⿦⨨, ≉㢪
2015-033475
[7]ࠕᅜෆ≉チฟ㢪༙ࠖᑟయᇶᯈࠊኴ㝧㟁ụࠊኴ㝧㟁ụࡢ〇㐀᪉ἲཬࡧࡑࡢ〇㐀⿦⨨, ≉㢪
2015-033506
[8]ࠕᅜෆ≉チฟ㢪ࠖࢩࣜࢥࣥᇶᯈࠊኴ㝧㟁ụ࠾ࡼࡧࡑࡢ〇㐀᪉ἲ, ≉㢪 2015-033564
[9]ࠕᅜෆ≉チฟ㢪ࠖỈ⣲Ỉࠊࡑࡢ〇㐀᪉ἲཬࡧ〇㐀⿦⨨, ≉㢪 2015-033643
[10]ࠕᅜ㝿≉チฟ㢪ࠖࣜࢳ࣒࢘㟁ụ⏝㈇ᴟᮦཬࡧࡑࡢ〇㐀᪉ἲཬࡧࡑࡢ〇㐀⿦⨨,୪ࡧ࡟ࣜࢳ࣒࢘
㟁ụ, PCT/JP2014/65432
[11]ࠕᅜ㝿≉チฟ㢪ࠖỈ⣲〇㐀⿦⨨ࠊỈ⣲〇㐀᪉ἲࠊỈ⣲〇㐀⏝ࢩࣜࢥࣥᚤ⣽⢏ᏊࠊཬࡧỈ⣲〇
㐀⏝ࢩࣜࢥࣥᚤ⣽⢏Ꮚࡢ〇㐀᪉ἲ, PCT/JP2014/72219/WO2015/033815
[12]ࠕ ᅜෆ≉チᡂ❧ࠖኴ㝧㟁ụཬࡧࡑࡢ〇㐀᪉ἲࠊ୪ࡧ࡟ኴ㝧
㟁ụࡢ〇㐀⿦⨨, ≉チ➨ 5717743 ྕ(Ⓩ㘓᪥:2015.3.27㸧
[13]ࠕᅜෆ≉チᡂ❧ࠖኴ㝧㟁ụཬࡧࡑࡢ〇㐀᪉ἲࠊ୪ࡧ࡟ኴ㝧㟁ụࡢ〇㐀⿦⨨, ≉チ➨ 5666552
ྕ(Ⓩ㘓᪥:2014.12.19)
[14]ࠕᅜෆ≉チᡂ❧༙ࠖᑟయᇶᯈࡢฎ⌮᪉ἲ࠾ࡼࡧ༙ᑟయ⿦⨨ࡢ〇㐀᪉ἲ, ≉チ➨ 5633838 ྕ(Ⓩ
㘓᪥:2014.10.24)
[15]ࠕᅜෆ≉チᡂ❧༙ࠖᑟయ⿦⨨ࡢ〇㐀᪉ἲࠊ༙ᑟయ⿦⨨ࡢ〇㐀⿦⨨ࠊ༙ᑟయ⿦⨨ࠊ୪ࡧ࡟㌿෗
⏝㒊ᮦ, ≉チ➨ 5698684 ྕ(Ⓩ㘓᪥:2015. 2.20)
[16]ࠕᅜෆ≉チᡂ❧༙ࠖᑟయ⿦⨨ࡢ〇㐀⿦⨨ཬࡧ༙ᑟయ⿦⨨ࡢ〇㐀᪉ἲ, ≉チ➨ 5620996 ྕ(Ⓩ㘓
᪥:2014. 9.26)
[17]ࠕ࢔࣓ࣜ࢝≉チᡂ❧༙ࠖᑟయ⿦⨨ཬࡧࡑࡢ〇㐀᪉ἲ, US8728941 B2
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
ᑠᯘ ග
Applied Surface Science (⦅㞟ጤဨ)
ᑠᯘ ග
European Conference on Surface Science (ECOSS) 30 (ᅜ㝿㢳ၥጤဨ)
ᅜෆᏛ఍
ᛂ⏝≀⌮Ꮫ఍
≀⌮Ꮫ఍
11 ௳
2௳
ྲྀᚓᏛ఩
ಟኈ㸦⌮Ꮫ㸧
୰ᓥ ᐶグ
ಟኈ㸦⌮Ꮫ㸧
㔝୰ ၨ❶
ಟኈ㸦⌮Ꮫ㸧
ᯇ⏣ ┿㍜
◪㓟㓟໬ἲ࡟ࡼࡿ⾲㠃ࣃࢵࢩ࣮࣋ࢩࣙࣥ࡜ ⿬㠃ࣂࢵࢡࢧ࣮ࣇ࢙࢖ࢫࣇ࢕࣮
ࣝࢻࡢ ⤖ᬗࢩࣜࢥࣥኴ㝧㟁ụ࡬ࡢᛂ⏝
໬Ꮫⓗ㌿෗ἲ࡟ࡼࡿ⤖ᬗࢩࣜࢥࣥᇶᯈࡢᴟప཯ᑕ⋡໬࡜ග㛢ࡌ㎸ࡵᵓ㐀ࡢే
⏝࡟ࡼࡿ㧗ຠ⋡ⷧᆺ༢⤖ᬗࢩࣜࢥࣥኴ㝧㟁ụ
ࢩࣜࢥࣥࢼࣀ⢏Ꮚ࡟ࡼࡿỈࡢศゎ࡜Ỉ⣲Ỉ
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᣮᡓⓗⴌⱆ◊
✲
ᑠᯘ ග
ษ⢊࠿ࡽග໬Ꮫⓗ⁐ゎἲ࡟ࡼࡿࢩࣜࢥࣥࢼࣀࣃ࣮ࢸ࢕ࢡࣝࡢ๰
〇࡜ኴ㝧㟁ụ࡬ࡢᛂ⏝
― 183 ―
༢఩㸸༓෇
650
ᇶ┙◊✲(C)
ᯇᮏ ೺ಇ
ⱝᡭ◊✲(B)
௒ᮧ ೺ኴ㑻
ཷク◊✲
ᑠᯘ ග
᭱ඛ➃࣭ḟୡ௦༙ᑟయࢹࣂ࢖ࢫᐇ⏝໬ࡢࡓࡵࡢࣁ࢖ࢻ࣮ࣉ Si ⾲㠃
ࡢ⾲㠃⛉Ꮫⓗ◊✲
໬Ꮫⓗ㌿෗ἲ࡟ࡼࡿ㉸㧗ຠ⋡ග㛢ࡌ㎸ࡵⷧᆺከ⤖ᬗࢩࣜࢥࣥኴ
㝧㟁ụࡢస〇
⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
┦⏺㠃ไᚚἲ࡟ࡼࡿᴟప཯ᑕ⋡ࡢ㐩ᡂ
࡜⤖ᬗࢩࣜࢥࣥኴ㝧㟁ụࡢ㉸㧗ຠ⋡໬
72,501
ඹྠ◊✲
ᑠᯘ ග
㹇㹂㹃㹁ᰴᘧ఍♫
1,928
ᑠᯘ ග
ओ᪥᪂໬ᡂ
࣮ࣞࢨග※฼⏝↷᫂ࡢ㧗㞟ග⋡࡞ᢞᑕ
ගᏛ⣔ࡢ㛤Ⓨ
ࢩࣜࢥ࣮ࣥ࣌ࢫࢺࡢ๰〇࡟㛵ࡍࡿ◊✲
1,300
2,340
0
ඛ➃ࣁ࣮ࢻᮦᩱ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Diffusion of oxygen in amorphous Al2O3, Ta2O5, and Nb2O5, R. Nakamura, T. Toda, S. Tsukui, M.
Tane, M. Ishimaru, T. Suzuki, H. Nakajima: J. Appl. Phys., 116 (2014) 033504.
[2]Effect of Crystallographic Texture on Mechanical Properties in Porous Magnesium with Oriented
Cylindrical Pores, M. Tane, T. Mayama, A. Oda, H. Nakajima: Acta Mater., 84 (2015) 80–94.
[3]Crystallographic nature of deformation bands shown in Zn and Mg-based long-period stacking ordered
(LPSO) phase, K. Hagihara, M. Yamasaki, M. Honnami, H. Izuno, M. Tane, T. Nakano, Y. Kawamura:
Philos. Mag., 95 (2015) 132–157.
[4]Effect of Porphyromonas gingivalis lipopolysaccharide on bone marrow mesenchymal stem cell
osteogenesis on a titanium nanosurface, H. Xing, Y. Taguchi, S. Komasa, I. Yamawaki, T. Sekino, M.
Umeda, and J. Okazaki: J. Periodontol., 86 (34) (2015) 448-455.
[5]Er3+ loaded barium molybdate nanoparticles: IR to visible spectral upconversion, R. Adhikari, B.
Joshi, R. Narro-García, E. De La Rosa, T. Sekino, and S.W. Lee: Mater. Lett., 142 (2015) 7-10.
[6]Application of Titanium Dioxide Nanotubes to Tooth Whitening, Obito Komatsu, Hisataka Nishida,
Tohru Sekino, and Kazuyo Yamamoto: Nano Biomed., 6 (2) (2014) 63-72.
[7]໬Ꮫ཯ᛂሙไᚚ࡟ࡼࡿపḟඖࢼࣀᵓ㐀ࢳࢱࢽ࢔ࡢ๰〇࡜㧗ḟᶵ⬟, 㛵㔝 ᚭࠊ⏣୰ಇ୍㑻: ࡲ
࡚ࡾ࠶, 53 (11) (2014) 546-549.
[8]EDTA mediated microwave hydrothermal synthesis of WO3 hierarchical structure and its photoactivity
under simulated solar light, R. Adhikari, G. Gyawali, T.H. Kim, T. Sekino, and S.W. Lee: J. Environ.
Chem. Eng., 2 (3) (2014) 1365-1370.
[9]Understanding the infrared to visible upconversion luminescence properties of Er3+/Yb3+ co-doped
BaMoO4 nanocrystals, R. Adhikari, J. Choi, R. Narro-García, E. De La Rosa, T. Sekino, and S.W. Lee: J.
Sol. State Chem., 216 (2014) 36-41.
[10]Electrospray deposition and characterization of Cu2O thin films with ring-shaped 2-D network
structure, H. Itoh, Y. Suzuki, T. Sekino, J.-C. Valmalette, and S. Tohno: J. Ceram. Soc. Japan, 122 (1425)
(2014) 361-366.
[11]Effect of Nanosheet Surface Structure of Titanium Alloys on Cell Differentiation, Satoshi Komasa,
Tetsuji Kusumoto, Yoichiro Taguchi, Hiroshi Nishizaki, Tohru Sekino, Makoto Umeda, Joji Okazaki, and
Takayoshi Kawazoe: J. Nanomater., 2014 (2014) Article ID 642527 (11 pages).
[12]Osteogenic activity of titanium surfaces with nanonetwork structures, Helin Xing, Satoshi Komasa,
Yoichiro Taguchi, Tohru Sekino, and Joji Okazaki: Int. J. Nanomed., 9 (2014) 1741-1755.
― 184 ―
[13]Shear bond strength of veneering porcelain to porous zirconia, T. Nakamura, T. Sugano, H. Usami, K.
Wakabayashi, H. Ohnishi, T. Sekino, and H. Yatani: Dental Materials Journal, 33 (2) (2014) 220-225.
[14]Effects of trace elements in fish bones on crystal characteristics of hydroxyapatite obtained by
calcination, T. Goto, K. Sasaki: Ceram. Int., 40 (2014) 10777-10785.
[15]Immobilization of Sr2+ on naturally derived hydroxyapatite by calcination of different species of fish
bones and influence of calcination on ion-exchange efficiency, K. Sasaki, T. Goto: Ceram. Int., 40 (2014)
11649-11656.
[16]Fitting accuracy and fracture resistance of crowns using a hybrid zirconia frame made of both porous
and dense zirconia, T. Nakamura, T. Sugano, H. Usami, K. Wakabayashi, H. Ohnishi, T. Sekino, and H.
Yatani: Dental Materials Journal, 34 (2) (2015) 257-262.
ᅜ㝿఍㆟
[1]Elastic properties of Mg-Zn-Y alloys with a long-period stacking ordered structure (oral), M. Tane, Y.
Nagai, H. Kimizuka, K. Hagihara, Y. Kawamura: International Symposium on Long-Period Stacking
Ordered Structure and Its Related Materials 2014.
[2]Deformation behavior of the synchronized LPSO phases accompanied by the formation of deformation
bands (oral), K. Hagihara, M. Honnami, T. Okamoto, M. Yamasaki, H. Izuno, M. Tane, T. Nakano, Y.
Kawamura: International Symposium on Long-Period Stacking Ordered Structure and Its Related
Materials 2014.
[3]Effect of enrichment of Zn and Y atoms on elastic properties of a Mg–Zn–Y alloy: analyses by inverse
Voigt-Reuss-Hill approximation and micromechanics modeling (poster), M. Tane, Y. Nagai, H. Kimizuka,
K. Hagihara, Y. Kawamura: The 18th SANKEN International Symposium 2014.
[4]Structure Tuning of Titania Nanotubes for Physical-photochemical Multi-functionalization (invited), T.
Sekino: TMS2015 144th Annual Meeting & Exhibition, Orlando, FL, USA, March 15-19, 2015.
[5]Materials Tuning of Titania Nanotubes and their Energy Applications (invited), T. Sekino: Materials
Challenges in Alternative & Renewable Energy (MCARE 2015), Jeju, Korea, February 24-27, 2015.
[6]Enhanced Spinodal Phase Separation of SnO2-TiO2 Ceramics by Iron Doping and their Electrical
Properties (invited), T. Sekino, T. Kusunose, and S.-I. Tanaka: The 39th Intl. Conf. on Adv. Ceram. and
Exposition (ICACC’15), Daytona Beach, FL, USA, January 25-30 2015.
[7]Synthesis of Electrical Conductive Organic and Organic/Inorganic Nanoparticles and Their
Application to Nanohybrid Pressure Sensors (oral), Tohru Sekino, and Youn-Gyu Han: The 16th
International Symposium on Eco-materials Processing and Design (ISEPD2015), Kathmandu, Nepal,
January 12-15, 2015.
[8]Structure Tuning of Titania Nanotubes for Solar Energy Conversion (invited), T. Sekino: International
Conference on Sustainable Energy Technology, Coimbatore, India, December 11-13, 2014.
[9]Structure Tuning of Titania Nanotubes for Physical-photochemical Multi-functionalization (oral), T.
Sekino: Nanomaterials Workshop in IGCAR, December 12-13, 2014, Kalpakkam, India.
[10]Modification of Titania Nanotubes by Metal-doping and their Physico- and Photo-chemical Functions
(poster), Hisataka Nishida, Hiroaki Sugiyama, Shun-Ichiro Tanaka, and Tohru Sekino: The 18th
SANKEN International Symposium, Osaka, Japan, December 10-11, 2014.
[11]Nanoscale Hybridization of Oxide Nanotubes for Multi-functionalization (plenary), T. Sekino: The
― 185 ―
3rd International Symposium on Hybrid Materials and Processing, Busan, Korea, November 10-13, 2014.
[12]Photophysical-chemial Multifunctionalization of Low-dimensional Oxides Nanostructures via
Advanced Fusional Structure Control (poster), T. Sekino, H. Nishida, and K. Kuremoto: The 2nd
International Symposium on Fusion Materials, November 2 – 4, 2014, Takeda Hall, University of Tokyo,
JAPAN.
[13]Hetero-structure Formation and Properties of SnO2-TiO2 Ceramic Composites via Spinodal Phase
Separation (invited), T. Sekino, S.-I. Tanaka, and T. Kusunose: The 3rd International Conference on
Competitive Materials and Technology Processes (IC-CMTP3), Miskolc, Hungary, October 6-11, 2014.
[14]Modofication of Titania Nanotubes by Ru-doping and Their Optical and Physico-chemical Properties
(oral), H. Sugiyama, and T. Sekino: The 3rd International Conference on Competitive Materials and
Technology Processes (IC-CMTP3), Miskolc, Hungary, October 6-11, 2014.
[15]Direct Formation of Porous Nano-architectures on Ti-based Metal Surfaces by Solution Chemical
Processing and Their Biocompatible Functions (invited), Tohru Sekino, Koki Kaga, Hisataka Nishida,
Koh-Ichi Kuremoto, and Shun-Ichiro Tanaka: The 15th IUMRS-International Conference in Asia
(IUMRS-ICA 2014), Fukuoka, Japan, August 24-30, 2014.
[16]Physico-photochemical and Biocompatible Functions of Low-dimensional Titania-based
Nanostructures (oral), T. Sekino: CJK2014 Lanzhou-China Conference, Lanzhou University, Lanzhou,
China, August 21-25, 2014.
[17]Materials Tuning of Titania Nanotubes and their Physico-photochemical Multifunctions (plenary), T.
Sekino: The 5th International Congress on Ceramics (ICC5), Beijing, China, August 17-21, 2014.
[18]Materials Tuning of Titania Nanotubes for Physicochemical and Photochemical
Multifunctionalization (invited), Tohru Sekino, Hiroki Tsukamoto, Hiroaki Sugiyama, Tae-Ho Kim, Soo
Wohn Lee, and Shun-Ichiro Tanaka: The 6th International Symposium on Functional Materials
(ISFM2014), Singapore, August 4-7, 2014.
[19]Development of Multifunctional Titania Nanotubes for Energy and Environmental Applications
(invited), T. Sekino: Energy Material Nanotechnology (EMN) Summer Meeting 2014, Westin Resort &
Spa, Cancun, Mexico, June 9-12, 2014.
[20]Monitoring of breath gas using thermoelectric gas sensor (poster), W. Shin, T. Nakashima, T. Goto,
T. Itoh, T. Kondo, K. Sato: 8th International Conference on Breath Research & Cancer Diagnosis
(Breath’2014).
ⴭ᭩
[1]Ti–Nb–Ta–Zr–O ྜ㔠࡟࠾ࡅࡿపࣖࣥࢢ⋡໬ (ᡂᓥᑦஅࠊ୰㔝㈗⏤)“ࣂ࢖࣐࢜ࢸࣜ࢔ࣝ◊✲ࡢ᭱
๓⥺”, ከ᰿ṇ࿴, ᪥ᮏ㔠ᒓᏛ఍, (19-20) 2014.
[2]Ti–Nb–Ta–Zr–ྜ㔠༢⤖ᬗࡢᙎᛶ≉ᛶ (ᡂᓥᑦஅࠊ୰㔝㈗⏤)“ࣂ࢖࣐࢜ࢸࣜ࢔ࣝ◊✲ࡢ᭱๓⥺”,
ከ᰿ṇ࿴, ᪥ᮏ㔠ᒓᏛ఍, (27-28) 2014.
≉チ
[1]ࠕฟ㢪ᚋㆡΏ≉チ㸦ᅜෆ㸧ࠖ㓟໬ࢳࢱࣥࢼࣀࢳ࣮ࣗࣈཬࡧࡑࡢ〇㐀᪉ἲ, ≉チ➨ 4868366 ྕ
[2]ࠕฟ㢪ᚋㆡΏ≉チ㸦ᅜෆ㸧ࠖ࢔࣑ࣝࢽ࣒࢘ྵ᭷ཧຍள㖄↝⤖యཬࡧࡑࡢ〇㐀᪉ἲ, ≉チ➨
4900569 ྕ
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
㛵㔝 ᚭ
International Journal of Applied Ceramic Technology (ඹྠ⦅㞟⪅)
― 186 ―
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
㛵㔝 ᚭ
Journal of the Ceramic Society of Japan (⦅㞟ጤဨ)
Materials Transactions (⦅㞟ጤဨ)
The 6th International Symposium on Functional Materials (ISFM2014) (ᅜ㝿࢔ࢻࣂ
࢖ࢨ࣮ࣜጤဨ)
The International Symposium on Advanced Functional Materials (ISAFM2014) (ᅜ㝿
࢔ࢻࣂ࢖ࢨ࣮ࣜጤဨ)
The 5th International Congress on Ceramics (ICC5) Symposium: Novel Processing
Technology (๪࣮࢜࢞ࢼ࢖ࢨ࣮)
CJK2014 Lanzhou-China Conference (⤌⧊ጤဨ)
The 15th IUMRS-ICA Symposium C-4 (ࢩ࣏ࣥࢪ࣒࢘๪ᗙ㛗)
The 3rd International Conference on Competitive Materials and Technology Processes
(IC-CMTP3) (⤌⧊ጤဨ)
The 3rd International Symposium on Hybrid Materials and Processing (HyMaP 2014)
(ᅜ㝿࢔ࢻࣂ࢖ࢨ࣮ࣜጤဨ)
The Korea-Japan International Seminar on Ceramics (⤌⧊ጤဨ)
The International Symposium on Eco-Materials Processing and Design (ISEPD㸧 (Ꮫ
⾡ጤဨ࣭⦅㞟ጤဨ)
Materials Challenges in Alternative and Renewable Energy 2015 (MCARE2015) (ᅜ
㝿࢔ࢻࣂ࢖ࢨ࣮ࣜጤဨ)
The 40th International Conference & Exposition on Advanced Ceramics &
Composites (ICACC) (ࢩ࣏ࣥࢪ࣒࢘๪ᐇ⾜ጤဨ)
The 11th International Conference on Ceramic Materials and Components for Energy
and Environmental Applications (11th CMCEE) (ࢩ࣏ࣥࢪ࣒࢘ᐇ⾜ጤဨ)
International Conference on Characterization and Control of Interfaces for High
Quality Advanced Materials (ICCCI) (⤌⧊ጤဨ)
The 14th International Union of Materials Research Societies-International
Conference on Advanced Materials (IUMRS-ICAM) (ࣉࣟࢢ࣒ࣛ/ฟ∧ጤဨ)
Advanced Ceramics and Technologies for Sustainable Energy Applications toward a
Low Carbon Society (ACTSEA) (ᅜ㝿࢔ࢻࣂ࢖ࢨ࣮ࣜጤဨ)
ᅜෆᏛ఍
᪥ᮏ㔠ᒓᏛ఍ 2014 ᖺ⛅ᮇㅮ₇኱఍
᪥ᮏ㔠ᒓᏛ఍ 2015 ᖺ᫓ᮇㅮ₇኱఍
㍍㔠ᒓᏛ఍㛵すᨭ㒊 ⱝᡭ◊✲⪅࣭㝔⏕࡟ࡼࡿ◊✲Ⓨ⾲఍
᪥ᮏᶵᲔᏛ఍ M&M2014 ᮦᩱຊᏛ࢝ࣥࣇ࢓ࣞࣥࢫ
➨ 58 ᅇ᪥ᮏᏛ⾡఍㆟ᮦᩱᕤᏛ㐃ྜㅮ₇఍
➨ 53 ᅇࢭ࣑ࣛࢵࢡࢫᇶ♏⛉Ꮫウㄽ఍
᪥ᮏࢭ࣑ࣛࢵࢡࢫ༠఍➨ 27 ᅇ⛅Ꮨࢩ࣏ࣥࢪ࣒࢘
⢊య⢊ᮎ෬㔠༠఍ᖹᡂ 26 ᖺᗘ⛅Ꮨㅮ₇኱఍
2014 ᖺᗘࢭ࣑ࣛࢵࢡࢫ⥲ྜ◊✲఍
᪥ᮏࢭ࣑ࣛࢵࢡࢫ༠఍ 2015 ᖺᖺ఍
➨ 23 ᅇ⣲ᮦᕤᏛ◊✲᠓ㄯ఍
⢊య⢊ᮎ෬㔠༠఍ᖹᡂ 26 ᖺᗘ᫓Ꮨㅮ₇኱఍
➨ 58 ᅇ໬Ꮫࢭࣥࢧ◊✲Ⓨ⾲఍
➨㸴ᅇ ᪥ᮏᏳᐃྠ఩య࣭⏕య࢞ࢫ་Ꮫᛂ⏝Ꮫ఍኱఍
ᖹᡂ 26 ᖺᗘ ᪥ᮏࢭ࣑ࣛࢵࢡࢫ༠఍ᮾᾏᨭ㒊Ꮫ⾡◊✲Ⓨ⾲఍
➨ 55 ᅇ㧗ᛶ⬟ Mg ྜ㔠๰ᡂຍᕤ◊✲఍
ྲྀᚓᏛ఩
ಟኈ㸦ᕤᏛ㸧
㕥ᮌ ⩧ᝅ
3௳
2௳
1௳
1௳
2௳
2௳
3௳
1௳
1௳
3௳
1௳
1௳
1௳
3௳
1௳
1௳
Mg-Zn-Y ྜ㔠ࡢ 18R ᆺ࠾ࡼࡧ 10H ᆺ LPSO ┦ࡢᙎᛶ≉ᛶ
⛉Ꮫ◊✲㈝⿵ຓ㔠
᪂Ꮫ⾡㡿ᇦ◊✲
పḟඖ㓟໬≀ࢼࣀᮦᩱࡢ㧗ḟᵓ㐀࡜ᶵ⬟ࡢ⼥ྜ
― 187 ―
༢఩㸸༓෇
2,990
㸦◊✲㡿ᇦᥦ᱌
ᆺ㸧බເ◊✲
㛵㔝 ᚭ
᪂Ꮫ⾡㡿ᇦ◊✲ ⃰໬ᒙ࡟࠾ࡅࡿࢡࣛࢫࢱ࣮ᵓ㐀ࢆ཯ᫎࡋࡓ㹊㹎㹑㹍┦ࡢᙎ
㸦◊✲㡿ᇦᥦ᱌ ᛶ⋡࠾ࡼࡧ⇕⭾ᙇࡢゎ᫂
ᆺ㸧බເ◊✲
ከ᰿ ṇ࿴
ⱝᡭ◊✲(A)
"༢⤖ᬗ⫱ᡂࢆᚲせ࡜ࡋ࡞࠸༢⤖ᬗᙎᛶ⋡ࡢỴᐃ᪉ἲ"ࡢᵓ
ከ᰿ ṇ࿴
⠏࡜⏕య⏝㔠ᒓᮦᩱ࡬ࡢᛂ⏝
ዡᏛᐤ㝃㔠
㛵㔝 ᚭ
࢖ࢼࣂࢦ࣒ᰴᘧ఍♫ ௦⾲ྲྀ⥾ᙺ ᒸᮏྜྷஂ
ᰴᘧ఍♫ࢽࢵ࢝ࢺ࣮ ௦⾲ྲྀ⥾ᙺ♫㛗 すᮧ㝯
㛵㔝 ᚭ
බ┈㈈ᅋἲே㍍㔠ᒓዡᏛ఍ ⌮஦㛗 ௒㡲⪷㞝
ከ᰿ ṇ࿴
୍⯡♫ᅋἲே ᪥ᮏࢳࢱࣥ༠఍ ఍㛗 ᵽཱྀ┾ဢ
ከ᰿ ṇ࿴
ඹྠ◊✲
㛵㔝 ᚭ
ᰴᘧ఍♫ࢹࣥࢯ࣮
❅⣲ཬࡧࣛࢪ࢝ࣝ✀ࡀᐤ୚ࡍࡿ
ග໬Ꮫ཯ᛂ࣓࢝ࢽࢬ࣒ࡢᇶ♏ⓗ
ゎᯒ
࣮ࣟࢱࢫ࢔ࣟ࢖ᰴᘧ఍
࣮ࣟࢱࢫᆺ࣏࣮ࣛࢫ㔠ᒓࡢ〇ἲ
㛵㔝 ᚭ
♫
㛤Ⓨ࡟㛵ࡍࡿඹྠ◊✲
㛵㔝 ᚭ
Sun Moon University
Development of Multifunctional
Nanomaterials and Processing
Technology for Eco-friendly
Applications
ከ᰿ ṇ࿴
ᮾࣞᰴᘧ఍♫
Ⅳ⣲⧄⥔ࡢᙎᛶಀᩘゎᯒ
4,680
13,910
1,500
500
150
400
1,000
864
6,923
800
ඛ➃ᐇ⿦ᮦᩱ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Pressureless wafer bonding by turning hillocks into abnormal grain growths in Ag films, C. Oh, S.
Nagao, T. Kunimune, K. Suganuma: Appl. Phys. Letters, 104 (2014) 161603.
[2]Enhanced reliability of Sn-Ag-Bi-In joint under electric current stress by adding Co/Ni elements, Y.
Kim, S. Nagaoࠊ T. Sugaharaࠊ K. Suganumaࠊ M. Ueshimaࠊ H.-J. Albrechtࠊ K. Wilke: J. Mater. Sci.:
Mater. Electron, 25 (7) (2014) 3090–3095.
[3]Hillock growth dynamics for Ag stress migration bonding, C. Oh, S. Nagao, T. Sugahara, K.
Suganuma: Materials Letters, 137 (2014) 170-173.
[4]Refinement of the microstructure of Sn-Ag-Bi-In solder, by addition of SiC nanoparticles, to reduce
electromigration damage under high electric current, Y. Kim, S. Nagao, T. Sugahara, K. Suganuma, M.
Ueshima, H.-J. Albrecht, K. Wilke: J. Electron. Mater., 43 (12) (2014) 4428-4434.
[5]Using Ozawa method to study the curing kinetics of electrically conductive adhesives, H.-W. Cui, J.-T.
Jiu, S. Nagao, T. Sugahara, K. Suganuma, H. Uchida: J. Thermal Analysis and Calorimetry, 117 (3)
(2014) 1365-1373.
[6]Photonic sintering of thin film prepared by dodecylamine capped CuInxGa1 ï xSe2 nanoparticles for
printed photovoltaics, M. Singh, J.-T. Jiu, T. Sugahara, K. Suganuma: Thin Solid Films, 565 (2014)
11-18.
[7]Thin Film CIGS Solar Cell Based on Low Temperature and All Printing Process, M. Singh, J.-T. Jiu, T.
Sugahara, K. Suganuma: ACS Appl. Mater. Interfaces, (2014) 16297-16303.
[8]Sol–Gel-Derived High-Performance Stacked Transparent Conductive Oxide Thin Films, T. Sugahara,
― 188 ―
Y. Hirose, S. Cong, H. Koga, J. Jiu, M. Nogi, S. Nagao, K. Suganuma: J. Am. Ceram. Soc., 97 (10)
(2014) 3238-3243.
[9]Pressureless Bonding Using Sputtered Ag Thin Films, C. Oh, S. Nagao, K. Suganuma: J. Electron.
Mater., 43 (12) (2014) 4406-4412/26.
[10]‘Chrysanthemum petal’ arrangements of silver nano wires, H.-W. Cui, J.-T. Jiu, T. Sugahara1, S.
Nagao, K. Suganuma, H. Uchida: Nanotechnology, 25 (48) (2014) 485705.
[11]Silver Nanowire Electrodes: Conductivity Improvement Without Post-treatment and Application in
Capacitive Pressure Sensors, J. Wang, J.-T. Jiu, T. Araki, M. Nogi, T. Sugahara, S. Nagao, H. Koga, P. He,
K. Suganuma: Nano-Micro Letters, 7 (1) (2015) 51-58.
[12]A Miniaturized Flexible Antenna Printed on a High Dielectric Constant Nanopaper Composite, T.
Inui, H. Koga, M. Nogi, N. Komoda, K. Suganuma: Advanced Materials, 27 (6) (2015) 1112-1116.
[13]Highly sensitive and flexible pressure sensor based on silver nanowires filled elastomeric interlayer
and silver nanowires electrodes, J. Wang, J.-T. Jiu, M. Nogi, T. Sugahara, S. Nagao, H. Koga, P. He, K.
Suganuma: Nanoscale, 7 (2014) 2926-2932.
[14]The role of Zn precipitates and Clï anions in pitting corrosion of Sn̽Zn solder alloys, J.-C. Liu, S.-W.
Park, S. Nagao, M. Nogi, H. Koga, J.-S. Ma, G. Zhang, K. Suganumaa: Corrosion Science, 92 (2015)
263-271.
[15]The effect of light and humidity on the stability of silver nanowire transparent electrodes, J.-T. Jiu, J.
Wang, T. Sugahara, S. Nagao, M. Nogi, H. Koga, K. Suganuma, M. Hara, E. Nakazawa, H. Uchida: RSC
Advances, 5 (2015) 27657-27664.
ᅜ㝿఍㆟
[1]Silver sinter joining and new thin film bonding for WBG die-attach (invited), K. Suganuma, S. Nagao,
T. Sugahara, C. Oh, H. Zhang, S. Koga, S. Park: 2nd International Conference on Nanojoining and
Microjoining, Emmetten, Switzerland, Dec. 7-10, 2014.
[2]Towards high reliability interconnections for advanced electronic (invited), K. Suganuma, S. Nagao, T.
Sugahara: 67th IIW Annual Assembly & International Conference (IIW2014), Seoul, July 17-18, 2014.
[3]Interconnection materials for high-temperature electronics applications (oral), K. Suganuma:
International Conference on Electronic Materials 2014 (IUMRS), Taipei, June 10-14, 2014.
[4]From lead-free soldering to new interconnections for advanced electronics (oral), K. Suganuma:
International Conference on Brazing, Soldering and Special Joining Technology, Chinese Welding Society,
Beijing, June 9-13, 2014.
[5]Microimpact testing for miniaturized electronic component packaging (oral), S. Nagao, Y.-S. Kim, T.
Sugahara, Y. Onishi, K. Suganuma: 20th European conference of fracture (ECF20), Trondheim, Norway |
June 30- July 4.
[6]Low-pressure sintering bonding with Cu and CuO flake paste for power devices (oral), S.W. Park, R.
Uwataki, S. Nagao, T. Sugahara, Y. Katoh, H.Ishino, K. Sugiura, K. Tsuruta, K. Suganuma: The 64th
IEEE Electronic Components and Technology Conference (ECTC2014), Lake Buena Vista, FL,
USA, May 27-30 (2014).
[7]Pressure-Less Plasma Sintering of Cu Paste for SiC Die-Attach of High-Temperature Power Device
Manufacturing (poster), S. Nagao, K. Kodani, S. Sakamoto, S. W. Park, T. Sugahara, K. Suganuma:
― 189 ―
European Conference of Silicon Carbide & Repated Materials (ECSCRM) 2014.
[8]Nanoscale Dynamic Mechanical Analysis on Heat-Resistant Silsesquioxane Nanocomposite for
Power-Device Packaging (poster), S. Nagao, N. Fujisawa , T. Sugioka, S. Ogawa, T. Fujibayashi, T.
Wada, T. Sugahara, K. Suganuma: European Conference of Silicon Carbide & Repated Materials
(ECSCRM) 2014.
[9]Sol-Gel-Derived Amorphous Semiconductor TFT Fabrication (invited), Tohru Sugahara, Takuro
Matsuo, Yukiko Hirose, Jinting Jiu, Shijo Nagao, and Katsuaki Suganuma: EMN Ceramics Meeting 2015.
[10]Photoelectrical and microphysical properties of Sol-Gel derived IGZO thin films for printed TFTs
(poster), T. Matsuo, T. Sugahara, Y. Hirose, J. Jiu, S. Nagao, K. Suganuma, Jianying He, Zhiliang Zhang:
ESTC 2014.
[11]Ultrasonic bonding of Cu/Al clad ribbon interconnections in power electronic modules (oral), Semin
Park 1, Shijo Nagao 1, Tohru Sugahara 1, Emi Yokoi 1, Osami Iizuka 2, and Katsuaki Suganuma: 67th
IIW Annual Assembly & International Conference.
[12]Nano-SiC added Ag paste sintering die-attach for SiC power devices (oral), Hao Zhang, Shijo
Nagao, Sungwon Park, Shunsuke Koga, Tohru Sugahara, and Katsuaki Suganuma: 5th Electronics
System-Integration Technology Conference.
[13]SiC die-attch on DBA substrate with ceramic nano-particles added hybrid Ag particle paste (oral),
Hao Zhang, Shijo Nagao, Katsuaki Suganuma: Materials Science & Technology 2014 .
[14]High-Dielectric Paper Composite Consisting of Cellulose Nanofiber and Silver Nanowire (oral),
Tetsuji Inui, Hirotaka Koga, Masaya Nogi, Natsuki Komoda, Katsuaki Suganuma: 14th International
Conference on Nanotechnology (IEEE NANO 2014).
[15]Synthesis and application of silver nanowires (oral), J. Jiu1,T. Araki1, J. Wang1, M. Nogi1, T.
Sugahara1, S. Nagao1, H. Koga1 , K. Suganuma1,E. Nakazawa2, M. Hara2, H. Uchida2: 1st International
Conference on Polyol Mediated Synthesis (IC-PMS), Paris, France | June 22-25.
[16]Sol-Gel-Derived Amorphous Semiconductor TFT Fabrication and its Performance (invited), Tohru
Sugahara, Takuro Matsuo, Yukiko Hirose, Jinting Jiu, Shijo Nagao, and Katsuaki Suganuma: EMN
Ceramics Meeting 2015.
ゎㄝࠊ⥲ㄝ
ࣉࣜࣥࢸࢵࢻ࣭࢚ࣞࢡࢺࣟࢽࢡࢫᢏ⾡ࡢືྥ, Ⳣ἟ ඞ᫛, ࣉࣛࢫࢳࢵࢡࢫ࣭࢚࣮ࢪ, ᰴᘧ఍♫ࣉ
ࣛࢫࢳࢵࢡࢫ࣭࢚࣮ࢪ, 㸯᭶ྕ (2015), 82-87.
ᑟ㟁ᛶ᥋╔๣ᢏ⾡, Ⳣ἟ ඞ᫛, ᮦᩱࡢ⛉Ꮫ࡜ᕤᏛ, ⳹ᡣ, 51[2] (2014), 42-47.
㖄ࣇ࣮ࣜࡣࢇࡔ௜ࡅᐇ⿦࠿ࡽඛ➃ᐇ⿦࡬ࡢᒎ㛤, Ⳣ἟ ඞ᫛, ࣟ࣎ࢵࢺ, ᪥ᮏࣟ࣎ࢵࢺᕤᴗ఍,
221 (2014), 1-8.
᪥ᮏ⇕㟁Ꮫ఍ㄅࠕ⩚ࡤࡓࡅⱝᡭࠖ
ࠊ᭤㠃᤼⇕※࡟㐺ᛂࡍࡿࣇࣞ࢟ࢩࣈࣝ⇕㟁ࣔࢪ࣮ࣗࣝࡢ㛤Ⓨ
2014 ᖺ 12 ᭶ྕ(Vol. 11 No.2:ISSN 1349-4279, Ⳣཎ ᚭ, ᪥ᮏ⇕㟁Ꮫ఍ㄅ, ᪥ᮏ⇕㟁Ꮫ఍, Vol. 11
No.2:ISSN 1349-4279 (2014), 9-11.
ⴭ᭩
[1]SiC/GaN ࣃ࣮༙࣡ᑟయࡢᐇ⿦࡜ಙ㢗ᛶホ౯ᢏ⾡ , Ⳣ἟ඞ᫛, ᪥หᕤᴗ᪂⪺♫, 2014.
[2]ᑟ㟁ᛶ᥋╔๣ධ㛛 , Ⳣ἟ඞ᫛, ⛉Ꮫᢏ⾡ฟ∧♫, 2014.
― 190 ―
[3]᭱᪂ᮦᩱࡢᛶ⬟࣭ホ౯ᢏ⾡ ➨ 8 ❶ , Ⳣ἟ඞ᫛, ⏘ᴗᢏ⾡ࢧ࣮ࣅࢫࢭࣥࢱ࣮, (514-557) 2014.
[4]㌴㍕ᶵჾᐇ⿦ࡢ᥋⥆ಙ㢗ᛶྥୖ , Ⳣ἟ඞ᫛, ࢩ࣮࢚࣒ࢩ࣮ฟ∧, (125-137) 2014.
[5]Sn ࢘࢕ࢫ࢝࡟ࡼࡿᶵჾᨾ㞀ࡢṔྐ , Ⳣ἟ඞ᫛, ࢩ࣮࢚࣒ࢩ࣮ฟ∧, (133-142) 2014.
≉チ
[1]ࠕᅜෆ≉チฟ㢪ࠖᑟ㟁ᛶ⧄⥔ࡢ〇㐀᪉ἲࠊࢩ࣮ࢺ≧㟁ᴟࡢ〇㐀᪉ἲࠊᑟ㟁ᛶ⧄⥔ࠊཬࡧࢩ࣮
ࢺ≧㟁ᴟ, 2014-106142
[2]ࠕᅜෆ≉チฟ㢪ࠖ㖟⢏Ꮚࡢྜᡂ᪉ἲࠊ㖟⢏Ꮚࠊᑟ㟁ᛶ࣮࣌ࢫࢺࡢ〇㐀᪉ἲࠊ࠾ࡼࡧᑟ㟁ᛶ࣌
࣮ࢫࢺ, 2014-123394
[3]ࠕᅜෆ≉チฟ㢪ࠖᑟ㟁ᛶࢆ᭷ࡍࡿ⧄⥔㞟ྜయ, 2014-232872
[4]ࠕᅜෆ≉チฟ㢪ࠖ᥋ྜᵓ㐀యࠊཬࡧࠊ᥋ྜᵓ㐀యࡢ〇㐀᪉ἲ, 2014-248918
[5]ࠕᅜෆ≉チฟ㢪ࠖ᥋ྜᵓ㐀య࠾ࡼࡧ᥋ྜᵓ㐀యࡢ〇㐀᪉ἲ, 2015-041268
[6]ࠕᅜෆ≉チฟ㢪༙ࠖᑟయⷧ⭷ࡢ〇㐀᪉ἲ, 2015-056004
[7]ࠕᅜෆ≉チฟ㢪ࠖ㏱᫂ᑟ㟁⭷ᙧᡂ᪉ἲࠊ㏱᫂ᑟ㟁⭷࠾ࡼࡧ㏱᫂ᑟ㟁ᛶᇶᯈ, 2015-030821
[8]ࠕᅜෆ≉チฟ㢪ࠖᅇ㊰ᇶᯈࡢ〇㐀᪉ἲ࡜ᅇ㊰ᇶᯈ࠾ࡼࡧࣉࣛࢬ࣐⿦⨨, 2015-043856
[9]ࠕᅜෆ≉チฟ㢪ࠖ㖡⢏Ꮚࡢ〇㐀᪉ἲࠊ㖡⢏Ꮚཬࡧ㖡࣮࣌ࢫࢺ, 2015-043640
[10]ࠕᅜෆ≉チฟ㢪༙ࠖᑟయ⿦⨨, 2015-067438
[11]ࠕᅜ㝿≉チฟ㢪ࠖ⤯⦕ᮦᩱࠊཷື⣲Ꮚࠊᅇ㊰ᇶᯈࠊ࠾ࡼࡧ⤯⦕ࢩ࣮ࢺ〇㐀᪉ἲ, 14/311546
[12]ࠕᅜ㝿≉チฟ㢪ࠖMethod of producing a patterned nanowires network, PCT/NL2014/050218
[13]ࠕᅜ㝿≉チฟ㢪ࠖ㔠ᒓࢼࣀ࣡࢖ࣖࡢ〇㐀᪉ἲཬࡧ㔠ᒓࢼࣀ࣡࢖ࣖ୪ࡧ࡟㖟ࢼࣀ࣡࢖ࣖࡢ〇㐀
᪉ἲཬࡧ㖟ࢼࣀ࣡࢖ࣖ, PCT/JP2014/063851
[14]ࠕᅜ㝿≉チฟ㢪ࠖ࢝ࣝࢥࣃ࢖ࣛ࢖ࢺࢼࣀ⢏Ꮚࡢ〇㐀᪉ἲ, PCT/JP2014/069197
[15]ࠕᅜ㝿≉チฟ㢪ࠖ᥋ྜᵓ㐀యࠊཬࡧ᥋ྜᵓ㐀యࡢ〇㐀᪉ἲ, PCT/JP2015/052999
[16]ࠕᅜෆᡂ❧≉チࠖ⇕㟁ኚ᥮ࣔࢪ࣮ࣗࣝཬࡧ⇕㟁ኚ᥮ࣔࢪ࣮ࣗࣝస〇᪉ἲ, 2009-244350
[17]ࠕᅜෆᡂ❧≉チࠖᑟ㟁ᛶ࣡࢖ࣖࡢ〇㐀⿦⨨ࠊᑟ㟁ᛶ࣡࢖ࣖࡢ〇㐀᪉ἲཬࡧ㓄⥺ᇶᯈࡢ〇㐀᪉
ἲ, 2010-163455
[18]ࠕᅜෆᡂ❧≉チࠖ㏱᫂ᑟ㟁ࣃࢱ࣮ࣥࡢ〇㐀᪉ἲ, 2014-503564
[19]ࠕᅜෆᡂ❧≉チࠖ㏱᫂ᑟ㟁ᛶ࢖ࣥࢡཬࡧ㏱᫂ᑟ㟁ࣃࢱ࣮ࣥᙧᡂ᪉ἲ, 2014-512709
[20]ࠕᅜ㝿ᡂ❧≉チࠖ࢘࢕ࢫ࢝ᢚไ⾲㠃ฎ⌮᪉ἲ, 12/089,025
[21]ࠕฟ㢪๓ㆡΏ≉チ㸦ᅜෆ࣭ᅜ㝿㸧ࠖࡣࢇࡔᮦࡢ〇㐀᪉ἲཬࡧࡣࢇࡔ᥋ྜ㒊, K20080084
[22]ࠕฟ㢪๓ㆡΏ≉チ㸦ᅜෆ࣭ᅜ㝿㸧ࠖᑟ㟁ᛶᮦᩱࡢ〇㐀᪉ἲࠊࡑࡢ᪉ἲ࡟ࡼࡾᚓࡽࢀࡓᑟ㟁ᛶ
― 191 ―
ᮦᩱࠊࡑࡢᑟ㟁ᛶᮦᩱࢆྵࡴ㟁ᏊᶵჾࠊⓎග⿦⨨, K20080371
[23]ࠕฟ㢪๓ㆡΏ≉チ㸦ᅜෆ࣭ᅜ㝿㸧࣏ࠖࣜ࢘ࣞࢱࣥࢆ⏝࠸ࡓఙ⦰ᛶ㓄⥺࡞ࡽࡧ࡟ᇶᯈᮦᩱ,
K20090402
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
Ⳣ἟ඞ᫛
Electronics System-Integration Technology Conference (ESTC 2014) (⤌⧊ጤဨ)
Ⳣ἟ඞ᫛
The 65th Electronic Components and Technology Conference (ECTC) (ࣉࣟࢢ࣒ࣛ
ጤဨ)
ᅜෆᏛ఍
࢚ࣞࢡࢺࣟࢽࢡࢫᐇ⿦Ꮫ఍
ࢭ࣑ࣛࢵࢡࢫ༠఍
ᛂ⏝≀⌮Ꮫ఍
ྲྀᚓᏛ఩
ಟኈ㸦ᕤᏛ㸧
ᯇᑿ⌶ᮁ
ಟኈ㸦ᕤᏛ㸧
እᮧⱥႹ
༤ኈ(ᕤᏛ)
࣒࢟ࣚࣥࢯࢡ
༤ኈ(ᕤᏛ)
࿋ࢳ࣑ࣙࣝࣥ
༤ኈ(ᕤᏛ)
ᅜ᐀ဴᖹ
༤ኈ(ᕤᏛ)
Ⲩᮌᚭᖹ
3௳
3௳
1௳
ࢰࣝࢤࣝ๓㥑య࢖ࣥࢡࡢ㛤Ⓨ࡜ TFT ᵓ㐀ࡢస〇
ᢒ⣬࡜ග㑏ඖᢏ⾡࡟ࡼࡿ࣮࣌ࣃ࣮࢟ࣕࣃࢩࢱ㟁ᴟࡢ㛤Ⓨ
㖄ࣇ࣮ࣜSABI ࡣࢇࡔ᥋ྜࡢ⤌⧊ᚤ⣽໬࡟ࡼࡿ࢚ࣞࢡࢺ࣐ࣟ࢖ࢢ࣮ࣞࢩࣙࣥ
࡜ᶵᲔⓗ≉ᛶࡢᨵၿ
Solid-state bonding by stress migration in Ag thin films
LED ᐇ⿦࡟ྥࡅࡓ㖟ప ↓ຍᅽࢲ࢖࣎ࣥࢻ࡟㛵ࡍࡿ◊✲
ᰂ㌾࢚ࣞࢡࢺࣟࢽࢡࢫ࡟ࡴࡅࡓ㓄⥺ᢏ⾡㛤Ⓨ
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(S)
Ⳣ἟ ඞ᫛
ⱝᡭ◊✲(B)
Ⳣཎ ᚭ
ཷク◊✲
Ⳣ἟ ඞ᫛
Ⳣ἟ ඞ᫛
Ⳣ἟ ඞ᫛
ዡᏛᐤ㝃㔠
Ⳣ἟ඞ᫛
Ⳣ἟ඞ᫛
Ⳣ἟ඞ᫛
Ⳣ἟ඞ᫛
Ⳣ἟ඞ᫛
Ⳣ἟ඞ᫛
Ⳣ἟ඞ᫛
ඹྠ◊✲
Ⳣ἟ ඞ᫛
Ⳣ἟ ඞ᫛
Ⳣ἟ ඞ᫛
Ⳣ἟ ඞ᫛
Ⳣ἟ ඞ᫛
Ⳣ἟ ඞ᫛
ᴟ㝈⎔ቃࣃ࣮༙࣡ᑟయࡢ␗┦⏺㠃⛉Ꮫ
༳ๅἲࢆ⏝࠸ࡓࢫࢺࣞࢵࢳࣕࣈࣝ⇕㟁ኚ᥮⣲Ꮚࡢ㛤Ⓨ
ḟୡ௦ࣉࣜࣥࢸࢵࢻ࢚ࣞࢡࢺࣟࢽࢡࢫ
㹁㹍㹇
㹑㹇㹎
༢఩㸸༓෇
32,500
1,635
3,479
7,692
13,700
ᰴᘧ఍♫ࢲ࢖ࢭࣝ
ࢭ࣓ࢲ࢖ࣥᰴᘧ఍♫
᫛࿴㟁ᕤᰴᘧ఍♫
㸦ᰴ㸧E 㺙㺎㺱㺚㺼㺈㺻㺡㺍㺖
ୖᮧᕤᴗओ
ᰴᘧ఍♫ᐩኈ㏻◊✲ᡤ
᪂᪥㕲ఫ㔠໬Ꮫ㸦ᰴ㸧
455
455
910
364
910
455
455
ᐩኈ㏻ࢸࣥ
᫛࿴㟁ᕤ
⣖ᕞᢏ◊ᕤᴗ㸦ᰴ㸧
ࣃ࢖ࢡࣜࢫࢱࣝ
ୖᮧᕤᴗ
ࢺࢵࣃ࣭ࣥࣇ࢛࣮࣒ࢬ
823
13,200
4,940
353
432
2,625
― 192 ―
Ⳣ἟ ඞ᫛
Ⳣ἟ ඞ᫛
Ⳣ἟ ඞ᫛
Ⳣ἟ ඞ᫛
㛗ᑿ⮳ᡂ
Ⳣ἟ ඞ᫛
(ᰴ)ࢹࣥࢯ࣮
ࢩ࣮ࣕࣉ(ᰴ)
(ᰴ)᪥ᮏゐ፹
༓ఫ㔠ᒓᕤᴗओ
༓ఫ㔠ᒓᕤᴗओ
ࢭ࣓ࢲ࢖ࣥᰴᘧ఍♫
4,166
35,345
3,588
0
80
420
ບ㉳≀ᛶ⛉Ꮫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Crucial roles of holes in electronic bond rupture on semiconductor surfaces, J. Tsuruta, E. Inami, J.
Kanasaki and K. Tanimura: Surf. Sci., 626 (2014) 49-52.
[2]State-resolved ultrafast dynamics of impact ionization in InSb, H. Tanimura, J. Kanasaki and K.
Tanimura: Scientific Reports, 4 (2014) 06849-1-4.
[3]Imaging energy-, momentum-, time-resolved distributions of photoinjected hot electrons in GaAs, J.
Kanasaki, H. Tanimura and K. Tanimura: Phy. Rev. Lett., 113 (23) (2014) 237401-1-4.
[4]Ultrafast scattering processes of hot electrons in InSb studied by time- and angle-resolved
photoemission spectroscopy, H. Tanimura, J. Kanasaki and K. Tanimura: Phys. Rev. B, 91 (4) (2015)
045201-1-16.
[5]What Does the Angle-Integrated Photoelectron Spectrum Show? :A Comparison between
First-Principles Calculation and Experiments for Graphite, Shin-ichiro Tanaka, Yusaku Takano, Makoto
Okusawa, and Kazuhiko Mase: J. Phys.Soc. Jpn, 83 (8) (2014) 084705-1-4.
ᅜ㝿఍㆟
[1]Ultrafast electron dynamics in photo-excited semiconductors studied by time- and angle-resolved
two-photon photoelectron spectroscopy (invited), J. Kanasaki: Conference on Lasers and Electro-Optics
(CLEO-2014).
[2]Dynamics of the Secondary Electron Emission from the Graphite Surface Excited by the Soft-X ray:
Investigation by the Electron-Electron Coincidence Spectroscop (oral), S. Tanaka and Kazuhiko Mase:
The 7th International Symposium on Surface Science.
[3]Electron-Phonon Scattering between Unoccupied Electronic States of Graphite Probed by AngleResolved Photoelectron and Electron Energy Loss Spectroscopies (oral), S. Tanaka,, M. Matsunami, S.
Kimura, M. Arita, K. Shimada, S. Shimizu, K. Mukai and J. Yoshinobu: The 7th
International Symposium on Surface Science.
[4]State-resolved ultrafast dynamics of impact ionization in InSb (poster), H. Tanimura, J. Kanasaki, K.
Tanimura: The 18th SANKEN International symposium.
ゎㄝࠊ⥲ㄝ
┦ᑐㄽⓗ㉸▷㟁Ꮚࣃࣝࢫ࡟ࡼࡿ㉸㧗㏿ᅛయᵓ㐀ືຊᏛࡢ◊✲, ᡂ℩ᘏᗣࠊYvlin GIRETࠊ᳿㔠ᓠࠊ
㇂ᮧඞᕫ, ࣮ࣞࢨ࣮◊✲, ࣮ࣞࢨ࣮Ꮫ఍, 43[3] (2015), 114-.
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
⏣୰ៅ୍㑻
Scientific Reports (⦅㞟ጤဨ)
㔠㷂㡰୍
The 9th International Sympopsium on Ultrafast Surface Dynamics (ᐇ⾜ጤဨ)
㇂ᮧඞᕫ
The 9th International Sympopsium on Ultrafast Surface Dynamics (ඹྠ㆟㛗)
ᅜෆᏛ఍
᪥ᮏ≀⌮Ꮫ఍
9௳
― 193 ―
ศᏊ◊ࢩ࣏ࣥࢪ࣒࢘
᪥ᮏ⾲㠃⛉Ꮫ఍ᨺᑕග⾲㠃⛉Ꮫ◊✲㒊఍
ࣇ࣮࣭ࣛࣞࣥࢼࣀࢳ࣮ࣗࣈ࣭ࢢࣛࣇ࢙ࣥ⥲ྜࢩ࣏ࣥࢪ࣒࢘
᪥ᮏᨺᑕගᏛ఍
≀ᵓ◊ࢧ࢖࢚ࣥࢫࣇ࢙ࢫࢱ
ᛂ⏝≀⌮Ꮫ఍ ບ㉳ࢼࣀࣉࣟࢭࢫ◊✲఍
ྲྀᚓᏛ఩
༤ኈ㸦ᕤᏛ㸧
㇂ᮧ ὒ
1௳
1௳
2௳
2௳
2௳
2௳
ࣇ࢙࣒ࢺ⛊᫬㛫ศゎศගἲ࡟ࡼࡿ༙ᑟయ࡟࠾ࡅࡿບ㉳㟁Ꮚࡢ㉸㧗㏿⦆࿴㐣⛬
ࡢ◊✲
⛉Ꮫ◊✲㈝⿵ຓ㔠
≉ู᥎㐍◊✲
㇂ᮧ ඞᕫ
ᇶ┙◊✲(C)
⏣୰ ៅ୍㑻
ⱝᡭ◊✲(B)
ᡂ℩ ᘏᗣ
ዡᏛᐤ㝃㔠
㔠ᓮ 㡰୍
≀㉁ᵓ㐀⛉Ꮫࡢ᪂ᒎ㛤㸸ࣇ࢙࣒ࢺ⛊᫬㛫ศゎཎᏊ࢖࣓࣮ࢪ
ࣥࢢ
࣮࢝࣎ࣥࢼࣀ࣐ࢸࣜ࢔ࣝ࡟࠾ࡅࡿ㟁Ꮚ᱁Ꮚ┦஫స⏝ࡢ⣲㐣
⛬
㉸㧗㏿᫬㛫ศゎ㟁Ꮚᅇᢡἲ࡟࠾ࡅࡿཎᏊᩓ஘ᅉᏊࡢ෌᳨ウ
༢఩㸸༓෇
7,800
1,430
3,120
බ┈㈈ᅋἲேụ㇂⛉Ꮫᢏ⾡᣺⯆㈈ᅋ ⌮஦㛗 ụ㇂ṇᡂ
300
㔞Ꮚࣅ࣮࣒Ⓨ⏕⛉Ꮫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Grid pulser for an electron gun with a thermionic cathode for the high-power operation of a terahertz
free-electron laser, S.Suemine, K.Kawase, N.Sugimoto, S.Kashiwagi, K.Furuakwa, R.Kato, A.Irizawa,
M.Fujimoto, H.Ohsumi, M.Yaguchi, S.Funakoshi, R.Tsutsumi, K.Kubo, A.Tokuchi, G.Isoyama: Nuclear
Instruments and Methods in Physics Research A, 773 (2015) 97-103.
[2]Excitation of giant monopole resonance in 208Pb and 116Sn using inelastic deuteron scattering, D.
Patel, U. Garg, M. Itoh, H. Akimune, G.P.A. Berg, M. Fujiwara, M.N. Harakeh, C. Iwamoto, T. Kawabata,
K. Kawase, J.T. Matta, T. Murakami, A. Okamoto, T. Sako, K.W. Schlax, F. Takahashi, M. White, M.
Yosoi: Physics Letters B, 735 (2014) 386-390.
[3]Development of a high-power solid-state switch using static inductio nthyristors for a klystron
modulator, A.Tokuchi, F.Kamitsukasa, K.Furukawa, K.Kawase, R.Kato, A.Irizawa, M.Fujimoto, H.Osumi,
S.Funakoshi, R.Tsutsumi, S.Suemine, Y.Honda, G.Isoyama: Nuclear Instruments and Methods in Physics
Research A, 769 (2015) 72-78.
[4]Spin-Polarized Angle-Resolved Photoelectron Spectroscopy of the So-Predicted Kondo Topological
Insulator SmB6, S.Suga, K.Sakamoto, T.Okuda, K.Miyamoto, K.Kuroda, A.Sekiyama, J.Yamaguchi,
H.Fujiwara, A.Irizawa, T.Ito, S.Kimura, T. Balashov, W. Wulfhekel, S. Yeo, F.Iga,S.Imada: Journal of the
Physical Society of Japan, 83 (2014) 014705 1-6.
[5]Bulk nature of layered perovskite iridates beyond the Mott scenario: An approach from a
bulk-sensitive photoemission study, A. Yamasaki, S. Tachibana, H. Fujiwara, A. Higashiya, A. Irizawa,
O. Kirilmaz, F. Pfaff, P. Scheiderer, J. Gabel, M. Sing, T. Muro, M. Yabashi, K. Tamasaku, H. Sato, H.
Namatame, M. Taniguchi, A. Hloskovskyy, H. Yoshida, H. Okabe, M. Isobe, J. Akimitsu, W. Drube, R.
Claessen, T. Ishikawa, S. Imada, A. Sekiyama, and S. Suga: Physical Review B, 89 (2014) 121111 1-5.
ᅜ㝿఍㆟
[1]SOLID-STATE SWITCH FOR A KLYSTRON MODULATOR FOR STABLE OPERATION OF A
THZ-FEL (poster), G. Isoyama, M. Fujimoto, S. Funakoshi, K. Furukawa, A. Irizawa, R. Kato, K.
Kawase, K. Miyazaki, A. Tokuchi, R. Tsutsumi, M. Yaguchi: FEL2014, Basel, Switzerland.
― 194 ―
[2]Ablation of organic crystals using picosecond THz free electron laser pulses. (oral), M. Nagai, E.
Matsubara, M. Ashida, K. Kawase, A. Irizawa, R. Kato and G. Isoyama: Infrared, Millimeter, and
Terahertz waves (IRMMW-THz), 2014 39th International Conference.
[3]HIGH POWER OPERATION OF THE THz FEL AT ISIR, OSAKA UNIVERSITY. (poster), K.
Kawase, S. Suemine, R. Kato, A. Irizawa, M. Fujimoto, M. Yaguchi, S. Funakoshi, R. Tsutsumi, K.
Miyazaki, K. Furukawa, K. Kubo, A. Tokuchi, G. Isoyama: FEL2014, Basel, Switzerland.
ⴭ᭩
[1]ᗈ࠸ศ㔝࡛ά㌍ࡍࡿᨺᑕග࡜⮬⏤㟁Ꮚ࣮ࣞࢨ࣮ (኱㜰኱Ꮫග⛉Ꮫࢭࣥࢱ࣮)“ග⛉Ꮫࡢୡ⏺”,
Ᏻ㣗༤ᚿࠊ஭ୖᜤࠊ☾ᒣᝅᮁࠊᐿ㔝ᏕஂࠊᐑỌ᠇᫂ࠊᮅ᪥୍ࠊᯇᮏṇ⾜ࠊཎ⏣㝯ྐࠊᯇᮧ㐨㞝ࠊ
᳃┤ࠊᖹ஭㝯அࠊ༨㒊ఙ஧ࠊྜྷᮧᨻᚿࠊ㧗㇂⿱ᾈࠊఀ㒔ᑗྖࠊᐑᆏ༤ࠊⰱ⏣ᫀ᫂ࠊ⏣ᓥ⠇Ꮚ, ᮅ
಴᭩ᗑ, (15-30) .
≉チ
[1]ࠕᅜ㝿≉チฟ㢪ࠖ,
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(B)
☾ᒣ ᝅᮁ
⮬⏤㟁Ꮚ࣮ࣞࢨ࣮ࡢ᪂ࡋ࠸ືస㡿ᇦࡢ㛤ᣅ
༢఩㸸༓෇
2,860
㔞Ꮚࣅ࣮࣒≀㉁⛉Ꮫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Theoretical relationship between quencher diffusion constant and effective reaction radius for
neutralization in contact hole imaging using chemically amplified extreme ultraviolet resists, Takahiro
Kozawa, Taku Hirayama: Japanese Journal of Applied Physics, 53 (2014) 066502.
[2]Theoretical study on stochastic defect generation in chemically amplified resist process for extreme
ultraviolet lithography, Takahiro Kozawa, Julius Joseph Santillan, Toshiro Itani: Japanese Journal of
Applied Physics, 53 (2014) 066504.
[3]Relationship between stochasticity and wavelength of exposure source in lithography, Takahiro
Kozawa: Japanese Journal of Applied Physics, 53 (2014) 066505.
[4]Effect of photodecomposable quencher on latent image quality in extreme ultraviolet lithography,
Takahiro Kozawa: Japanese Journal of Applied Physics, 53 (2014) 066508.
[5]Effects of effective reaction radius for neutralization on performance of chemically amplified resists,
Takahiro Kozawa, Julius Joseph Santillan, Toshiro Itani: Japanese Journal of Applied Physics, 53 (2014)
06JC02.
[6]Dependence of stochastic defect generation on quantum efficiency of acid generation and effective
reaction radius for deprotection in chemically amplified resist process using extreme ultraviolet
lithography, Takahiro Kozawa, Julius Joseph Santillan, Toshiro Itani: Japanese Journal of Applied Physics,
53 (2014) 076502.
[7]Effect of molecular weight and protection ratio on line edge roughness and stochastic defect generation
in chemically amplified resist processes of extreme ultraviolet lithography, Takahiro Kozawa, Julius
Joseph Santillan, Toshiro Itani: Japanese Journal of Applied Physics, 53 (2014) 084002.
[8]Relationship between Stochastic Phenomena and Optical Contrast in Chemically Amplifield Resist
Process of Extreme Ultraviolet Lithography, Takahiro Kozawa, Julius Joseph Santillan, and Toshiro Itani:
Journal of Photopolymer Science and Technology, 27 (2014) 11-19.
― 195 ―
[9]Feasibility study of sub-10 nm half-pitch fabrication using chemically amplified resist processes of
extreme ultraviolet lithography: I. Latent image quality predicted by probability density model, Takahiro
Kozawa, Julius Joseph Santillan, Toshiro Itani: Japanese Journal of Applied Physics, 53 (2014) 106501.
[10]Effect of deprotonation efficiency of protected units on line edge roughness and stochastic defect
generation in chemically amplified resist processes for 11 nm node of extreme ultraviolet lithography,
Takahiro Kozawa, Julius Joseph Santillan, Toshiro Itani: Japanese Journal of Applied Physics, 53 (2014)
116504.
[11]Relationship between quencher diffusion constant and exposure dose dependence of line width, line
edge roughness, and stochastic defect generation in extreme ultraviolet lithography, Takahiro Kozawa:
Japanese Journal of Applied Physics, 54 (2014) 016502.
[12]Effects of dose shift on line width, line edge roughness, and stochastic defect generation in
chemically amplified extreme ultraviolet resist with photodecomposable quencher, Takahiro Kozawa:
Japanese Journal of Applied Physics, 54 (2014) 016503.
[13]Feasibility study of sub-10-nm-half-pitch fabrication by chemically amplified resist processes of
extreme ultraviolet lithography: II. Stochastic effects, Takahiro Kozawa, Julius Joseph Santillan, and
Toshiro Itani: Japanese Journal of Applied Physics, 54 (2015) 036507.
[14]Organic solvent-free water-developable sugar resist material derived from biomass in green
lithography, Satoshi Takei, Akihiro Oshima, Takumi Ichikawa, Atsushi Sekiguchi, Miki Kashiwakura,
Takahiro Kozawa, Seiichi Tagawa, Tomoko G. Oyama, Syoji Ito, Hiroshi Miyasaka: Microelectronic
Engineering, 122 (2014) 70-76.
[15]Application of natural linear polysaccharide to green resist polymers for electron beam and
extreme-ultraviolet lithography, Satoshi Takei, Akihiro Oshima, Tomoko G. Oyama, Kenta Ito, Kigen
Sugahara, Miki Kashiwakura, Takahiro Kozawa, Seiichi Tagawa and Makoto Hanabata: Japanese Journal
of Applied Physics, 53 (2014) 116505.
[16]Modeling and simulation of acid generation in anion-bound chemically amplified resists used for
extreme ultraviolet lithography, Yoshitaka Komuro, Daisuke Kawana, Taku Hirayama, Katsumi Ohomori,
and Takahiro Kozawa: Japanese Journal of Applied Physics, 54 (2015) 036506.
[17]Controlled arrangement of nanoparticles capped with protecting ligand on Au nanopatterns, Hiroki
Yamamotoa,Akira Ohnumab,Bunsho Ohtanib,Takahiro Kozawa: Microelectronic Engineering, 121
(2014) 108-112.
[18]Study on dissolution behavior of polymer-bound and polymer-blended photo acid generator (PAG)
resists by using quartz crystal microbalance (QCM) method, Hiroki Yamamoto,Takahiro Kozawa,Seiichi
Tagawa: Microelectronic Engineering, 129 (2014) 65-69.
[19]Position Control of Metal Nanoparticles by Self-Assembly, Hiroki Yamamoto, Akira Ohnuma,
Bunsho Ohtani, Takahiro Kozawa: Journal of Photopolymer Science and Technology, 27 (2014) 243-247.
[20]Pulse radiolysis study of polystyrene-based polymers with added photoacid generators: Reaction
mechanism of extreme-ultraviolet and electron-beam chemically amplified resist, Kazumasa Okamoto,
Hiroki Yamamoto, Takahiro Kozawa, Ryoko Fujiyoshi, Kikuo Umegaki: Japanese Journal of Applied
Physics, 54 (2015) 026501.
[21]Study on resist performance of chemically amplified molecular resists based on cyclic oligomers,
Hiroki Yamamoto, Hiroto Kudob, Takahiro Kozawa: Microelectronic Engineering, 133 (2015) 16-22.
― 196 ―
[22]High-aspect-ratio patterning by ClF3-Ar neutral cluster etching, Hiroki Yamamotoa, , , Toshio
Sekib, Jiro Matsuoc, Kunihiko Koiked, Takahiro Kozawaa: Microelectronic Engineering, 141 (2015)
145-149.
[23]Acid generation mechanism in anion-bound chemically amplified resists used for extreme ultraviolet
lithography, Yoshitaka Komuro, Hiroki Yamamoto, Kazuo Kobayashi, Yoshiyuki Utsumi, Katsumi
Ohomori, Takahiro Kozawa: Japanese Journal of Applied Physics, 53 (2014) 116503.
[24]Sensitivity of a Chemically Amplified Three-component Resist Containing a Dissolution Inhibitor for
Extreme Ultraviolet Lithography, Hideo Horibe, Keita Ishiguro, Takashi Nishiyama, Akihiko Kono,
Kazuyuki Enomoto, Hiroki Yamamoto, Masayuki Endo and Seiichi Tagawa: Polymer Journa, 46 (2014)
234-238.
[25]Conductivity of poly(2-methoxyaniline-5-phosphonic acid)/amine complex and its charge dissipation
property in electron-beam lithography, Toru Amayaa, Yasushi Abea, Hiroki Yamamoto, Takahiro
Kozawac, Toshikazu Hiraoa, ,: Synthetic Metals, 198 (2014) 88-92.
[26]Oxidative stress sensing by the iron–sulfur cluster in the transcription factor, SoxR, Kobayashi K,
Fujikawa M, Kozawa T: Journal of Inorganic Biochemistry, 133 (2014) 87-91.
[27]A Pulse Radiolysis Study of the Dynamics of Ascorbic Acid Free Radicals within a Liposomal
Environment, Kazuo Kobayashi, Yumiko Seike, Akinori Saeki, Takahiro Kozawa, Fusako
Takeuchi, Motonari Tsubaki: ChemPhysChem, 15 (2014) 2994-2997.
[28]Binding of promoter DNA to SoxR protein decreases the reduction potential of the [2Fe-2S] cluster,
Kobayashi K, Fujikawa M, Kozawa T: Biochemistry, 54 (2015) 334-339.
[29]Mechanistic studies on formation of the dinitrosyl iron complex of the [2Fe-2S] cluster of SoxR
protein, Mayu Fujikawa, Kazuo Kobayashi and Takahiro Kozawa: The Journal of Biochemistry, 156
(2014) 163-172.
[30]Redox-dependent DNA distortion in a SoxR protein-promoter complex studied using fluorescent
probes, Fujikawa M, Kobayashi K, Kozawa T: J. Bio㹡hem., 157 (2015) 389-397.
[31]The Radical S-Adenosyl-L-methionine Enzyme QhpD Catalyzes Sequential Formation of
Intra-protein Sulfur-to-Methylene Carbon Thioether Bonds, T. Nakai, H. Ito, K. Kobayashi, Y. Takahashi,
H. Hori, M. Tsubaki, K. Tanizawa, and T. Okajima: J. Biol. Chem., 290 (2015) 11144-11166.
[32]Chemical repair activity of free radical scavenger edaravone: reduction reactions with dGMP
hydroxyl radical adducts and suppression of base lesions and AP sites on irradiated plasmid DNA, Hata K,
Urushibara A, Yamashita S, Lin M, Muroya Y, Shikazono N, Yokoya A, Fu H, Katsumura Y.: J. Radiat.
Res., 56 (2015) 59.
[33]Sequential radiation chemical reactions in aqueous bromide solutions: pulse radiolysis experiment
and spur model simulation, S. Yamashita, K. Iwamatsu, Y. Maehashi, M. Taguchi, K. Hata, Y. Muroya
and Y. Katsumura: RSC Adv., 5 (2015) 25877.
ᅜ㝿఍㆟
[1]Fundamental Study on Dissolution Behavior of Chemically Amplified Resists for Extreme Ultraviolet
Lithography (poster), Masaki Mitsuyasu, Hiroki Yamamoto, and Takahiro Kozawa: Photomask Japan
2014 .
[2]Theoretical Study on Stochastic Effects in Chemically Amplified Resist Process for Extreme
Ultraviolet Lithography (invited), Takahiro Kozawa, Julius Joseph Santillan, Toshiro Itani: 2014
― 197 ―
International Workshop on EUV Lithography.
[3]Relationships between Stochastic Phenomena and Optical Contrast in Chemically Amplified Resist
Process of Extreme Ultraviolet Lithography (invited), Takahiro Kozawa, Julius Joseph Santillan and
Toshiro Itani: 31st International Conference of Photopolymer Science and Technology (ICPST-31).
[4] Position Control of Metal Nano Particle by Self Assembly (oral), Hiroki Yamanoto, Akira Onuma,
Fumiaki Otani and Takahiro Kozawa: 31st International Conference of Photopolymer Science and
Technology (ICPST-31) .
[5]A Picosecond Pulse Radiolysis Study of Methanol and Ethanol at Extreme Conditions up to
Supercritical State (poster), Yusa MUROYA, Daisuke HATOMOTO, Testuro YOSHIDA, Shinichi
YAMASHITA, Yosuke KATSUMURA, and Takahiro KOZAWA: The 5th Asia Pacific Symposium on
Radiation Chemistry.
[6]A Picosecond Pulse Radiolysis Study of Water at Extreme Conditions up to Supercritical State (oral),
Yusa MUROYA, Daisuke HATOMOTO, Testuro YOSHIDA, Shinichi YAMASHITA, Mingzhang LIN,
Yosuke KATSUMURA, and Takahiro KOZAWA: The 5th Asia Pacific Symposium on Radiation
Chemistry.
[7]Reactivity of Hydrated Electron Formed by Radiolysis of Water at High Temprature (poster), Daisuke
HATOMOTO, Yusa MUROYA, Yosuke KATSUMURA, Shinichi YAMASHITA, and Takahiro
KOZAWA: The 5th Asia Pacific Symposium on Radiation Chemistry.
[8]Fundamental Study on Dissolution Behavior of Chemically Amplified Resists for Extreme Ultraviolet
Lithography (poster), Masaki Mitsuyasu, Hiroki Yamamoto, and Takahiro Kozawa: The 5th Asia Pacific
Symposium on Radiation Chemistry.
[9]Radiation-induced Synthesis of Metal Nanoparticles in Ethers THF and PGMEA (poster),
Hiroki YAMAMOTO, Takahiro KOZAWA, Seiichi TAGAWA, Muneyuki NAITO, Jean-Louis
MARIGNIER, Mehran MOSTAFAVI, and Jacqueline BELLONI: The 5th Asia Pacific Symposium on
Radiation Chemistry.
[10]Theoretical study on stochastic effects in chemically amplified resist process for extreme ultraviolet
lithography (oral), Takahiro Kozawa, J.J. Santillan, T. Itani: 12th FRAUNHOFER IISB LITHOGRAPHY
SIMULATION WORKSHOP.
[11]High Aspect Ratio Patterning by Using ClF3-Ar Neutral Cluster Etching (poster), H. Yamamoto, T.
Seki, J. Matsuo, K. Koike, T. Kozawa: The 40th International Conference on Micro and Nano
Engineering.
[12]Fast Process of Water Radiolysis at High Temperature and High Pressure (oral), Yusa Muroya,
Daisuke Hatomoto, Yosuke Katsumura, Mingzhang Lin, Shinichi Yamashita, Jean-Paul Jay-Gerin,
Takahiro Kozawa: Nuclear Plant Chemistry Conference Sapporo.
[13]Feasibility Study of sub-10 nm half-pitch Fabrication Using Chemically Amplified Resist Processes
of Extreme Ultraviolet Lithography (oral), Takahiro Kozawa: 2014 International Symposium on Extreme
Ultraviolet Lithography.
[14]Study on Dissolution Behavior of Chemically Amplified Resists for Extreme Ultraviolet Lithography
(oral), M. Mitsuyasu, H. Yamamoto and T. Kozawa: 27㹲㹦 International Microprocesses and
Nanotechnology Conference.
[15]Effect of Molecular Weight on Dissolution Behavior of Poly(methyl methacrylate) (poster), A. Konda,
― 198 ―
H. Yamamoto, M. Mitsuyasu, T. Kozawa, S. Yoshitake: 27㹲㹦 International Microprocesses and
Nanotechnology Conference.
[16]Relationship between information and energy carried by extreme-ultraviolet photons: consideration
from the viewpoint of sensitivity enhancement (oral), Takahiro Kozawa, Shinya Fujii, Julius Joseph S.
Santillan, Toshiro Itani,: SPIE Advanced Lithography 2015.
[17]Acid generation mechanism in anion-bound chemically amplified resists used for extreme ultraviolet
lithography (oral), Yoshitaka Komuro, Hiroki Yamamoto, Kazuo Kobayashi, Katsumi Ohomori, Takahiro
Kozawa: SPIE Advanced Lithography 2015.
ⴭ᭩
[1]ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫἲ -୰㛫άᛶ✀ࡢ᳨ฟᡭἲ (Y. Muroya)“ཎᏊຊ࣭㔞Ꮚ࣭᰾⼥ྜ஦඾”, ᐊ
ᒇ ⿱బ, ୸ၿฟ∧, ➨ IV ศ෉ (102-103) 2014.
[2]Ỉ⁐ᾮࡢᨺᑕ⥺໬Ꮫ -Ỉ࠾ࡼࡧᕼⷧỈ⁐ᾮࡢᨺᑕ⥺ศゎ (Y. Muroya)“ཎᏊຊ࣭㔞Ꮚ࣭᰾⼥ྜ஦
඾”, ᯘ 㖭❶ࠊᐊᒇ ⿱బ, ୸ၿฟ∧, ➨ IV ศ෉ (104-105) 2014.
[3]Material–Coolant Interactions (Y. Oka and H. Mori)“Supercritical-Pressure Light Water Cooled
Reactors”, Yosuke Katsumura and Yusa Muroya, Springer Japan, (347-375) 2014.
≉チ
[1]ࠕฟ㢪๓ㆡΏ≉チ㸦ᅜෆ࣭ᅜ㝿㸧ࠖᴟ➃⣸እග࡟ࡼࡿⷧ⭷ࡢ྾཰ಀᩘࢆ ᐃࡍࡿᨭᣢ⭷ᙧᡂ⤌
ᡂ≀ཬࡧ ᐃ᪉ἲ, K20080228
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
ྂ⃝ Ꮥᘯ
2014 International Symposium on Extreme Ultraviolet Lithography (ㄽᩥጤဨ)
ྂ⃝ Ꮥᘯ
27㹲㹦 International Microprocesses and Nanotechnology Conference (⤌⧊ጤဨ)
ྂ⃝ Ꮥᘯ
28㹲㹦 International Microprocesses and Nanotechnology Conference (⤌⧊ጤဨ)
ᐊᒇ ⿱బ
The 5th Asia Pacific Symposium on Radiation Chemistry (㐠Ⴀጤဨ)
ᒣᮏ ὒ᥹
28㹲㹦 International Microprocesses and Nanotechnology Conference (ㄽᩥጤဨ)
ᅜෆᏛ఍
➨ 41 ᅇ⏕యศᏊ⛉Ꮫウㄽ఍ 2014
➨ 51 ᅇ㺏㺐㺝㺢㺎㺪㺽࣭ᨺᑕ⥺◊✲Ⓨ⾲఍
➨ 75 ᅇᛂ⏝≀⌮Ꮫ఍⛅ᏘᏛ⾡ㅮ₇఍
➨ 87 ᅇ᪥ᮏ⏕໬Ꮫ఍኱఍
➨ 12 ᅇ㧗㍤ᗘ㧗࿘Ἴ㟁Ꮚ㖠◊✲఍
➨ 62 ᅇᛂ⏝≀⌮Ꮫ఍᫓ᏘᏛ⾡ㅮ₇఍
᪥ᮏ໬Ꮫ఍➨ 95 ᅇ᫓Ꮨᖺ఍
ྲྀᚓᏛ఩
ಟኈ㸦ᕤᏛ㸧
㬀ᮏ ኱♸
ಟኈ㸦ᕤᏛ㸧
ගᏳ ᑘ㥽
༤ኈ㸦ᕤᏛ㸧
⸨ᕝ 㯞⏤
༤ኈ㸦ᕤᏛ㸧
ᑠᐊ ჆ᓫ
1௳
2௳
4௳
2௳
1௳
1௳
1௳
㧗 Ỉࡢᨺᑕ⥺ศゎ࡟࠾ࡅࡿỈ࿴㟁Ꮚ⏤᮶ࡢỈ⣲Ⓨ⏕཯ᛂ࡟㛵ࡍࡿ◊✲
Ỉᬗ᣺ືᏊ࣐࢖ࢡࣟࣂࣛࣥࢫἲࢆ⏝࠸ࡓࣞࢪࢫࢺⷧ⭷ࡢ⁐ゎ㐣⛬࡟㛵ࡍࡿ◊
✲
㕲◲㯤ࢡࣛࢫࢱ࣮ࢆᣢࡘ㓟໬ࢫࢺࣞࢫࢭࣥࢧ࣮⺮ⓑ㉁ࡢᛂ⟅ᶵᵓ࡟㛵ࡍࡿ◊
✲
࢜ࢽ࣒࢘ሷࢆഃ㙐࡟ᣢࡘࣞࢪࢫࢺ㧗ศᏊࡢᴟ➃⣸እග࡟ᑐࡍࡿឤගᶵᵓ࡟㛵
ࡍࡿ◊✲
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(A)
㔞Ꮚࣅ࣮࣒」ྜ฼⏝࡟ࡼࡿ᭱ඛ➃ᚤ⣽ຍᕤᮦᩱࡢࢼࣀ໬Ꮫࡢ◊
― 199 ―
༢఩㸸༓෇
8,060
ྂ⃝ Ꮥᘯ
ᣮᡓⓗⴌⱆ◊
✲
ᐊᒇ ⿱బ
ᣮᡓⓗⴌⱆ◊
✲
ᒣᮏ ὒ᥹
ⱝᡭ◊✲(A)
ᒣᮏ ὒ᥹
ཷク◊✲
ᐊᒇ ⿱బ
ᐊᒇ ⿱బ
ዡᏛᐤ㝃㔠
ྂ⃝ Ꮥᘯ
ᒣᮏ ὒ᥹
ඹྠ◊✲
ྂ⃝ Ꮥᘯ
ྂ⃝ Ꮥᘯ
ྂ⃝ Ꮥᘯ
ྂ⃝ Ꮥᘯ
ྂ⃝ Ꮥᘯ
ྂ⃝ Ꮥᘯ
✲
Ỉ୰࡟࠾ࡅࡿ㟁Ꮚ஧㔞యᙧᡂ࣓࢝ࢽࢬ࣒ࡢゎ᫂
780
ࢺࢵࣉࢲ࣭࢘ࣥ࣎ࢺ࣒࢔ࢵࣉ⼥ྜᆺᚤ⣽ຍᕤ࡟ࡼࡿ㔠ᒓࢼࣀᵓ
㐀యࡢ๰ᡂ࡜ไᚚ
1,300
᭷ᶵ࣭↓ᶵࣁ࢖ࣈࣜࢵࢻࢼࣀ⢏Ꮚࢆ⏝࠸ࡓᴟ㝈㔞Ꮚࣅ࣮࣒ᚤ⣽
ຍᕤࣉࣟࢭࢫࡢ๰ᡂ
15,730
୍⯡㈈ᅋἲே㟁ຊ୰ኸ
◊✲ᡤ
୍⯡㈈ᅋἲே㟁ຊ୰ኸ
◊✲ᡤ
PWR ᮲௳࡟࠾ࡅࡿ࣏ࣜ࢔ࢡࣜࣝ㓟ࡢ
ᨺᑕ⥺࣓࢝ࢽࢬ࣒ࡢㄪᰝ
ሬ⿦㗰ᯈ࡬ࡢ྾཰⥺㔞࡜ ᗘୖ᪼ࡢ
᳨ウ
኱ඵ໬Ꮫᕤᴗᰴᘧ఍♫ ᢏ⾡㛤Ⓨᮏ㒊 ᖖົྲྀ⥾ᙺ ᮏ㒊㛗
ụᓥ࿴ኵ
ࣇࣟࣥࢸ࢕࢔ᕤᶵᰴᘧ఍♫ ௦⾲ྲྀ⥾ᙺ ஧⎼ⱱ
᪥⏘໬Ꮫᕤᴗओ
Taiwan Semiconductor
Manufacturing Conductor
(TSMC)
ᮾிᛂ໬ᕤᴗᰴᘧ఍♫
୕⳻࢞ࢫ໬Ꮫᰴᘧ఍♫
ᰴᘧ఍♫ࢽ࣮ࣗࣇࣞ࢔ࢸ
ࢡࣀࣟࢪ࣮
ᰴᘧ఍♫ᮾⰪ
EUV ග↷ᑕ࡟ࡼࡿࣞࢪࢫࢺୗᒙ⭷ࡢ
≉ᛶ࡜྾཰ಀᩘ ᐃἲࡢ◊✲
Electron beam resist characterizations
EUV ⏝ࣇ࢛ࢺࣞࢪࢫࢺࡢホ౯࡟㛵ࡍ
ࡿ◊✲
᪂つࣞࢪࢫࢺᮦᩱࡢࣜࢯホ౯
㟁Ꮚ⥺ࣞࢪࢫࢺ࡟࠾ࡅࡿ཯ᛂ⏕ᡂ≀
ࡢ୕ḟඖ✵㛫ศᕸࡢ◊✲
໬Ꮫቑᖜᆺ㟁Ꮚ⥺ࣞࢪࢫࢺ࡟ࡼࡿ
7nm ࣃࢱ࣮ࣥゎീᢏ⾡ࡢ◊✲
562
143
200
1,000
0
2,816
417
416
0
2,083
ບ㉳ศᏊ໬Ꮫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Single-Particle Study of Pt-Modified Au Nanorods for Plasmon-Enhanced Hydrogen Generation in
Visible to Near Infrared Region, Z. Zheng, T.Tachikawa, and T. Majima: J. Am. Chem. Soc., 136 (19)
(2014) 6870-6873.
[2]Far-Red Fluorescence Probe for Monitoring Singlet Oxygen during Photodynamic Therapy, S. Kim, T.
Tachikawa, M. Fujitsuka, and T. Majima: J. Am. Chem. Soc., 136 (33) (2014) 11707-11715.
[3]Photocurrent generation enhanced by charge delocalization over stacked perylenediimide
chromophores inside DNA, T. Takada, A. Ashida, M. Nakamura,M. Fujitsuka, T. Majima, K. Yamana: J.
Am. Chem. Soc., 136 (19) (2014) 6814-6817.
[4]Radical Ions of Cycloparaphenylenes: Size-Dependence Contrary to the Neutral Molecules, M.
Fujitsuka, S. Tojo, T. Iwamoto, E. Kayahara, S. Yamago, and T. Majima: J. Phys. Chem. Lett, 5 (13)
(2014) 2302-2305.
[5]Solvent Dynamics Regulated Electron Transfer in S2-Excited Sb- and Ge Tetraphenylporphyrins with
an Electron Donor Substituent at Meso-Position, M.Fujitsuka, T. Shiragami, D. W. Cho, S. Tojo, M.
Yasuda, and T. Majima: J.Phys. Chem. A, 118 (22) (2014) 3926-3933.
― 200 ―
[6]Properties of Triplet-Excited [n]Cycloparaphenylenes (n = 8 – 12): Excitation Energies Lower Than
Linear Oligomers and Polymers, M. Fujitsuka, C. Lu, T. Iwamoto, E. Kayahara, S. Yamago, and T.
Majima: J. Phys. Chem. A, 118 (25) (2014) 4527-4532.
[7]Driving force dependence of charge separation and recombination processes in dyads of nucleotides
and strongly electron-donating Oligothiophenes, S.-H. Lin, M. Fujitsuka, M. Ishikawa, and T. Majima,: J.
Phys. Chem. B, 118 (42) (2014) 12186-12191.
[8]Molecular-level understanding of the photocatalytic activity difference between anatase and rutile
nanoparticles, W. Kim, T. Tachikawa, T. Majima, and W. Choi: Angew. Chem. Int. Ed, 53 (51) (2014)
14036-14041.
[9]Blinking triggered by the change in the solvent accessibility of the fluorescent molecule, K. Kawai, T.
Koshimo, A. Maruyama, and T. Majima: ChemComm, 50 (72) (2014) 10478-10481.
[10]Folding and Structural Polymorphism of G-quadruplex Formed from a Long Telomeric Sequence
Containing Six GGG Tracts, A. Tanaka, J. Choi, and T. Majima: RSC Advances, 4 (103) (2014)
59071-59077.
[11]Visible Light Photocatalytic Activities of Nitrogen and Platinum-Doped TiO2: Synergistic Effects of
Co-dopants, W. Kim, T. Tachikawa, H. Kim, N. Lakshminarasimhan, P. Murugan, H. Park, T. Majima,
and W. Choi: Appl. Catal. B Environ., 147 (2014) 642-650.
[12]Dynamics in the Heme Geometry of Myoglobin Induced by the One-electron Reduction, J. Choi, S.
Tojo, M. Fujitsuka, and T. Majima: Int. J. Radiat. Biol., 90 (6) (2014) 459-467.
[13]Configurational Changes of a Heme Followed by Cytochrome c Folding Reaction, J. Choi, D. W. Cho,
S. Tojo, M. Fujitsuka, and T. Majima: Mol. BioSystems, 11 (1) (2014) 218-222.
[14]Inter and Intramolecular Electron Transfer Processes from Excited Naphthaldiimide Radical Anion,
M. Fujitsuka, S. S. Kim, C. Lu, S. Tojo, and T. Majima: J. Phys. Chem. B, 119 (24) (2015) 7275-7282.
[15]Plasmon-Enhanced Formic Acid Dehydrogenation Using Anisotropic Pd–Au Nanorods Studied at the
Single-Particle Level, Z. Zheng, T. Tachikawa, and T. Majima: J. Am. Chem. Soc., 137 (2) (2015)
948-957.
[16]Structural Study on Biphenyl with Various Substituents and Its Radical Anions Based on the
Time-resolved Resonance Raman Spectroscopy Combined with Pulse Radiolysis, J. Choi, D. W. Cho, S.
Tojo, M. Fujitsuka, and T. Majima: J. Phys. Chem. A, 119 (5) (2015) 851-856.
[17]Se-Se Bond Cleavage of Diaryl Diselenide Radical Anions during Pulse Radiolysis, S. Tojo, M.
Fujitsuka, A. Ouchi, and T. Majima: ChemPlusChem., 80 (1) (2015) 68-73.
[18]Single-particle Study of Plasmon-Enhanced Formic Acid Dehydrogenation using Anisotropic Pd-Au
Nanorods, Z. Zheng, T. Tachikawa, and T. Majima: J. Am. Chem. Soc., 137 (2) (2015) 948-957.
[19]Efficient charge separation on 3D architectures of TiO2 mesocrystals packed with a chemically
exfoliated MoS2 shell in synergetic hydrogen evolution, P. Zhang, T. Tachikawa, M. Fujitsuka, and T.
Majima: Chemical Communications, 51 (33) (2015) 7187-7190.
[20]Photocurrent generation through charge-transfer processes in noncovalent perylenediimide/DNA
complexes, T. Takada, M. Ido, A. Ashida, M. Nakamura, M. Fujitsuka, K. Kawai, T. Majima, and K.
Yamana: Chemistry-A European Journal, 21 (18) (2015) 6846–6851.
― 201 ―
ᅜ㝿఍㆟
[1]Charge Delocalization in Cyclophanes (invited), T. Majima: International Symposium on Reactive
Intermediates and Unusual Molecules (ISRIUM), Hiroshima, Japan, April 1-6, 2014.
[2]Superstructure of metal oxide crystalline nanoparticles with effective charge transfer pathways
(invited), T. Majima: Korea Japan Symposium on Frontier Photoscience, Seoul, Korea, June 21-23, 2014.
[3]Photoinduced Electron Transfer Processes in Supramolecular Donor Acceptor Dyads using Porphyrin
Isomers (invited), M. Fujitsuka, H. Shimakoshi, Y. Hisaeda, and T. Majima: Korea Japan Symposium on
Frontier Photoscience, Seoul, Korea, June 21-23, 2014.
[4]Size-Dependent Fluorescence Properties of [n]Cycloparaphenylenes (n = 8 - 13), Hoop-Shaped
S-Conjugated Molecules (poster), M. Fujitsuka, D. W. Cho, T. Iwamoto, S. Yamago, and T. Majima:
Korea Japan Symposium on Frontier Photoscience, Seoul, Korea, June 21-23, 2014.
[5]Radical Cation of Star-Shaped Condensed Oligofluorenes Having Isotruxene as a Core: Importance of
Rigid Planar Structure on Charge Delocalization (poster), M. Fujitsuka, D. W. Cho, J. Choi, J-S. Yang,
and T. Majima: Korea Japan Symposium on Frontier Photoscience, Seoul, Korea, June 21-23, 2014.
[6]Superstructure of TiO2 crystalline nanoparticles with effective charge transfer pathway (invited), T.
Majima: Urumqi Symposium on Recent Advances and Applications in Nanoengineering and
Nanosystems, Urumqi, Xinjian Autonomous Region, Xinjian, China, June 27-30, 2014.
[7]Photocatalytic Reactions using Superstructure TiO2 Crystalline Nanoparticles with Effective Charge
Transfer Pathways (oral), T. Majima: 25th IUPAC symposium on Photochemistry, Bordeaux, France,
July13-18, 2014.
[8]Nanoscale Visualization of TiO2 Photocatalytic Reactions (plenary), T. Majima: 14th National
Conference on Solar Energy Photochemistry and Photocatalysis (SEPP14), Harbin, China, July 27-31,
2014.
[9]Superstructure of TiO2 crystalline nanoparticles with effective charge transfer pathways (invited), T.
Majima: UNIST (Ulsan National Institute of Science and Technology) Annual international conference on
energy materials, Ulsan, Korea, August 19-22, 2014.
[10]Recent Approach in Radiation Chemistry toward Material and Biological Science (invited), T.
Majima: 2014APSRC (Asian Pacific Symposium on Radiation Chemistry) , Tokyo, Japan, September
8-11, 2014.
[11]Time-resolved Raman Spectroscopic Measurement during Pulse Radiolysis of Supramolecules and
Biomolecules (oral), M. Fujitsuka, J. Choi, and T. Majima: 2014APSRC (Asian Pacific Symposium on
Radiation Chemistry) , Tokyo, Japan, September 8-11, 2014.
[12]Metal oxide mesocrystals with efficient charge transport properties (invited), T. Majima: Fall E-MRS
Conference, Warsaw University of Technology, Warsaw, Poland, 9 ᭶ 14-25 ᪥.
[13]Metal oxide mesocrystals with effective charge transfer pathways (plenary), T. Majima: 4th
TKU-ECUST-OPU-KIST Joint Symposium on Advanced Materials and their Applications, Taipei,
Taiwan, September 24-26, 2014.
[14]Solvent accessibility of the fluorescent molecule monitored by fluorescence blinking (oral), K. Kawai,
T. Koshimo,A. Maruyama, T. Majima: 41st International Symposium on Nucleic Acids Chemistry
(ISNAC2014), Fukuoka, Japan, November 5-7, 2014.
― 202 ―
[15]Single-Particle Study of Pt-Modified Au Nanorods for Plasmon-Enhanced Hydrogen Generation in
Visible to Near Infrared Region (poster), Z. Zheng, T. Tachikawa, and T. Majima: SANKEN International
SymposiumࠊOsaka, Japan, December 10-11, 2014.
[16]Development of 㹬ew photocatalysts (plenary), T. Majima: International Workshop on Resource
Chemistry in Shanghai Normal University, Shanghai, China, December 23, 2014.
[17]Pulse radiolysis (oral), T. Majima: 2015 1st Workshop of Collaboration Laboratory between
SANKEN, Osaka, Japan, January 26, 2015.
[18]Pulse radiolysis of nanomaterials (oral), M. Fujitsuka and T. Majima: 2015 1st Workshop of
Collaboration Laboratory between SANKEN, Osaka, Japan, January 26, 2015.
[19]Introduction of SANKEN and Quantum Beam Laboratory (oral), T. Majima: 2015 Japan-Korea
Bilateral Symposium on Quantum Beam Science, Osaka, Japan, February 25, 2015.
[20]Radiation Chemistry of Nanomaterials (oral), M. Fujitsuka and T. Majima: 2015 Japan-Korea
Bilateral Symposium on Quantum Beam Science, Osaka, Japan, February 25, 2015.
[21]Electron transfer from excited radical ions in functionalized organic molecular systems (invited), M.
Fujitsuka and T. Majima: Kobe mini-symposium on functionalized organic molecules, Kobe, Japan,
November 10, 2014.
ゎㄝࠊ⥲ㄝ
Developing a new fluorescence probe of singlet oxygen during photodynamic therapy, S. Kim, M.
Fujitsuka, and T. Majima, EPA Newslett., 86 (2014), 92-95.
㉥እග໬Ꮫ, ┿ᔱ ဴᮁ, ග໬Ꮫࡢ஦඾, ᮅ಴᭩ᗑ, N (2014), 74-75.
ບ㉳࢚ࢿࣝࢠ࣮ࡢ⛣ື࣭ఏ㐩࣭ᣑᩓ, ⸨ሯ Ᏺ, ග໬Ꮫࡢ஦඾, ᮅ಴᭩ᗑ, (2014), 46-47.
DNA ࡢගᦆയ࣭ගᅇ᚟, ᕝ஭ Ύᙪ, ග໬Ꮫࡢ஦඾, ᮅ಴᭩ᗑ, (2014), 338-339.
ⴭ᭩
[1]Single-molecule reactive oxygen species detection in photocatalytic reactions (Alexander Greer and
Joel F. Liebman)“The Chemistry of Peroxides”, T. Majima, John Wiley & Sons, (421-436) 2014.
[2]Fundamental reaction mechanisms in radiation chemistry and recent examples” in “Applications of
EPR in Radiation Research (Anders Lund and Masaru Shiotani)“Applications of EPR in Radiation
Research”, M. Fujitsuka and T. Majima, Springer Cham Heidelberg New York Dordrecht London, (3-32)
2014.
[3]Photoinduced charge-separation in DNA (Mario Barbatti, Antonio C. Borin, and Susanne
Ullrich)“Photoinduced Phenomena in Nucleic Acids for Topics in Current Chemistry”, K. Kawai and T.
Majima, Springer-Verlag, Inc., (165-182) 2014.
[4]Charge Transfer in Non-B DNA with a tetraplex structures (Eugen Stulz and Guido Clever)“DNA in
supramolecular chemistry and nanotechnology”, J. Choi and T. Majima, Wiley & Sons, Chichester UK,
(121-136) 2014.
≉チ
[1]ࠕᅜෆ≉チฟ㢪ࠖ⺯ගࣉ࣮ࣟࣈࠊ୍㔜㡯㓟⣲᳨ฟ๣ࠊཪࡣ୍㔜㡯㓟⣲᳨ฟ᪉ἲ, 2014-124543
[2]ࠕPCTࠖ⺯ගࣉ࣮ࣟࣈࠊ୍㔜㡯㓟⣲᳨ฟ๣ࠊཪࡣ୍㔜㡯㓟⣲᳨ฟ᪉ἲ, PCT Int. Appl.
― 203 ―
PCT/JP2015/67522.
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
┿ᔱဴᮁ
Korean Japan Symosium on Photoscinece (⤌⧊ጤဨ㛗)
┿ᔱဴᮁ
Asian Pacific Symposium on Radiation Chemistry (⤌⧊ጤဨ)
┿ᔱဴᮁ
25th IUPAC Symposium on Photochemistry, (⤌⧊ጤဨ)
┿ᔱဴᮁ
Urumqi Symposium on Recent Advances and Applications in Nanoengineering and
Nanosystems (⤌⧊ጤဨ)
┿ᔱဴᮁ
Langmuir, American Chemical Society (Senior Editor)
┿ᔱဴᮁ
ACS Applied Materials & Interfaces, American Chemical Society (Editorial Advisory
Board)
┿ᔱဴᮁ
ChemPlusChem, union of 16 European Chemical Societies, Wiley VHC (Editorial
Board)
┿ᔱဴᮁ
Rapid Communication in Photoscienece, Korean Society of Photoscience
(International Editorial Board)
┿ᔱဴᮁ
Photochemistry and Photobiology, Wiley VHC (Associate Editor)
ᅜෆᏛ఍
➨ 35 ᅇ᪥ᮏග་Ꮫ࣭ග⏕≀Ꮫ఍
2014 ᖺග໬Ꮫウㄽ఍
᪥ᮏ໬Ꮫ఍➨ 94 ᫓Ꮨᖺ఍
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ಟኈ㸦ᕤᏛ㸧
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㜿㔝 㥴௓
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㔠 Ỉ⦕
2௳
3௳
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ࣇ࣮ࣛࣞࣥㄏᑟయࢆ⏝࠸ࡓࣛࢪ࢝ࣝ࢔ࢽ࢜ࣥບ㉳≧ែ࠿ࡽࡢศᏊෆ㟁Ꮚ⛣ື
ࡢ◊✲
࣌ࣜࣞࣥࢪ࢖࣑ࢻࣛࢪ࢝ࣝ࢔ࢽ࢜ࣥບ㉳≧ែࢆ㟁Ꮚࢻࢼ࣮ ࡟⏝࠸ࡓศᏊෆ
㟁Ꮚ⛣ືࡢ◊✲
ⰾ㤶⎔ࢆ᭷ࡍࡿ໬ྜ≀ࡢỈ⇕཯ᛂ࡟ࡼࡿ ࣮࢝࣎ࣥࢻࢵࢺࡢྜᡂ
⺯ගࣉ࣮ࣟࣈࢆ⏝࠸ࡓ⏕࿨⌧㇟ࡢ༢୍ศᏊゎᯒཬࡧ ྍど໬࡟㛵ࡍࡿ◊✲
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(S)
┿ᔱ ဴᮁ
ᇶ┙◊✲(B)
⸨ሯ Ᏺ
ᇶ┙◊✲(B)
ᕝ஭ Ύᙪ
≉ู◊✲ဨዡ
ບ㈝
┿ᔱ ဴᮁ
◊✲άືࢫࢱ
࣮ࢺᨭ᥼
ᑠ㜰⏣ ὈᏊ
ཷク◊✲
┿ᔱ ဴᮁ
ග࢚ࢿࣝࢠ࣮ኚ᥮⣔࡟࠾ࡅࡿࢼࣀゐ፹ࡢ༢୍ศᏊ໬Ꮫ
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
ᕝ஭ Ύᙪ
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ዡᏛᐤ㝃㔠
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ATI බ┈㈈ᅋἲே ᪂ୡ௦◊✲ᡤ
༢఩㸸༓෇
44,850
㉸ศᏊ࠾ࡼࡧ㧗ศᏊ࡟࠾ࡅࡿ཯ᛂ୰㛫యບ㉳≧ែࡢࢲ࢖ࢼ
࣑ࢡࢫ
㹐㹌㸿ࡢ⦅㞟ࠊ໬Ꮫಟ㣭᝟ሗࡢ㸯ศᏊࣞ࣋ࣝゎᯒᢏ⾡ࡢ㛤
Ⓨ
᫬㛫࣭✵㛫ศゎศගἲࢆ⏝࠸ࡓ㓟໬ࢳࢱࣥගゐ፹཯ᛂࡢᵓ
㐀≉␗ᛶࡢゎ᫂
4,030
༢୍ศᏊ࡛ࣞ࣋ࣝࡢ⚄⤒ኚᛶ iPS ⣽⬊࡟࠾ࡅࡿᑡᩘ᰾㓟࢖
࣓࣮ࢪࣥࢢ
1,300
CPP 㢮ࡢ୙Ᏻᐃάᛶ✀≧ែࡢゎ
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⺯ගࡢ blinking ࢆ⮬ᅾ࡟᧯ࡿศ
Ꮚᢏ⾡ࡢ๰ฟ
― 204 ―
4,290
1,100
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7,579
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ᶵ⬟≀㉁໬Ꮫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Enantioselective Organocatalyzed Formal [4+2] Cycloaddition of Ketimines with Allenoates: Easy
Access to a Tetrahydropyridine Framework with a Chiral Tetrasubstituted Stereogenic Carbon Center, S.
Takizawa, F. A. Arteaga, Y. Yoshida, M. Suzuki, H. Sasai: Asian J. Org. Chem., 3 (2014) 412-415.
[2]Palladium Enolate Umpolung: Cyclative Diacetoxylation of Alkynyl Cyclohexadienones Promoted by
a Pd/SPRIX Catalyst, K. Takenaka, S. C. Mohanta, H. Sasai: Angew. Chem. Int. Ed., 53 (2014)
4675-4679.
[3]C3-Symmetric Chiral Trisimidazoline-Catalyzed Friedel-Crafts (FC)-Type Reaction, S. Takizawa, S.
Hirata, K. Murai, H. Fujioka, H. Sasai: Org. Biomol. Chem., 12 (2014) 5827-5830.
[4]Facile Regio- and Stereo-Selective Metal-Free Synthesis of All-Carbon Tetrasubstituted Alkenes
Bearing a C(sp3)-F Unit via Dehydroxyfluorination of Morita-Baylis-Hillman (MBH) Adducts, S.
Takizawa, F. A. Arteaga, K. Kishi, S. Hirata, H. Sasai: Org. Lett., 16 (2014) 4162-4165.
[5]Enantioselective Construction of C2-Symmetric Spiro Skeleton through Intramolecular
Copper-Catalyzed N-Arylation, K. Takenaka, M. Sako, S. Takatani, H. Sasai: ARKIVOC, 2015 (2014)
52-63.
[6]Alkylamines-Intercalated Į-Zirconium Phosphate as Latent Thermal Anionic Initiators, O. Shimomura,
K. Maeno, A. Ohtaka, S. Yamaguchi, J. Ichihara, K. Sakamoto, R. Nomura: Journal of Polymer Science,
Part A: Polymer Chemistry, 52 (2014) 1854-1861.
ᅜ㝿఍㆟
[1]Enantioselective Synthesis of Į-Methylidene-Ȗ-Butyrolactones and Ȗ-Butyrolactams: Intramolecular
Rauhut-Currier Reaction Promoted by Bifunctional Organocatalysts (poster), S. Takizawa, T. M.-N.
Nguyen, K. Kishi, F. A. Arteaga, M. Suzuki, H. Sasai: 15th Tetrahedron Symposium, London, UK, June
24-27, 2014.
[2]Enantioselective Organocatalyzed Formal [n+2] Cycloaddition Using Allenoates (poster), S. Takizawa,
F. A. Arteaga, Y. Yoshida, M. Suzuki, T. M.-N. Nguyen, H. Sasai: 15th Tetrahedron Symposium, London,
UK, June 24-27, 2014.
[3]Ir Catalyzed Asymmetric Tandem Reaction of meso-Diols and Aldehydes (poster), T. Suzuki, Y.
Ishizaka, K. Ghozati, D.-Y. Zhou, K. Asano, H. Sasai: 2nd International Symposium on C-H Activation,
Rennes, France, June 30 – July 3, 2014.
[4]Catalytic Enantioselective Pd(II)/Pd(IV) Reactions Using SPRIX Ligand (oral), H. Sasai: 20th
International Conference on Organic Synthesis, Budapest, Hungary, June 29-July 4, 2014.
[5]Ir Catalyzed Asymmetric Tandem Reaction of meso-Diols and Aldehydes (oral), T. Suzuki, Y. Ishizaka,
K. Ghozati, D.-Y. Zhou, K. Asano, H. Sasai: The 26th International Conference on Organometallic
Chemistry (ICOMC2014), Sapporo, Japan, July 13-18, 2014.
[6]Recent Progress in Enantioselective Reactions Catalyzed by Pd-SPRIX: Pd Enolate Umpolung and
Pd(II)/Pd(IV) Catalysis (oral), K. Takenaka, S. C. Mohanta, Y. D. Dhage, H. Sasai: The 26th International
Conference on Organometallic Chemistry (ICOMC2014), Sapporo, Japan, July 13-18, 2014.
[7]Enantioselective Synthesis of Chiral Spiro Compounds and Their Applications to Organocatalysis
(poster), Y. Takeuchi, L. Fan, S. Takizawa, H. Sasai: The 26th International Conference on
Organometallic Chemistry (ICOMC2014), Sapporo, Japan, July 13-18, 2014.
― 205 ―
[8]Recent Progress in Enantioselective Reactions Catalyzed by Pd-SPRIX: Pd Enolate Umpolung and
Pd(II)/Pd(IV) Catalysis (invited), K. Takenaka: ICOMC 2014 Post-Symposium in Osaka: New Aspects of
Reactive Organometallic Complexes of Transition Metals, Osaka, Japan, July 19, 2014.
[9]Development of Novel Chiral Spiro Ligands Bearing Imidazoles Coordination Sites (poster), S.
Takatani, K. Sawada, K. Takenaka, H. Sasai: ICOMC 2014 Post-Symposium in Osaka: New Aspects of
Reactive Organometallic Complexes of Transition Metals, Osaka, Japan, July 19, 2014.
[10]Enantioselective C-C Bond Forming Reactions Catalyzed by Vanadium(V) Complex (poster), M.
Sako, S. Takizawa, Y. Yoshida, J. Kodera, T. Doi, H. Sasai: ICOMC 2014 Post-Symposium in Osaka:
New Aspects of Reactive Organometallic Complexes of Transition Metals, Osaka, Japan, July 19, 2014.
[11]Palladium-Catalyzed Direct C–H Arylation of Isoxazoles at Their 5-Position (poster), M. Shigenobu,
K. Takenaka, H. Sasai: ICOMC 2014 Post-Symposium in Osaka: New Aspects of Reactive
Organometallic Complexes of Transition Metals, Osaka, Japan, July 19, 2014.
[12]Recent Progress of Enantioselective Catalysis Promoted by Pd-SPRIX (poster), S. C. Mohanta, Y. D.
Dhage, K. Takenaka, H. Sasai: 248th ACS National Meeting & Exposition, San Francisco, USA, August
10-14, 2014.
[13]Enantioselective Organocatalyzed Domino Process Based on aza-Morita-Baylis-Hillman-Type
(aza-MBH) Reaction (poster), S. Hirata, S. Takizawa, N. Inoue, F. A. Arteaga, Y. Yoshida, M. Suzuki, H.
Sasai: 248th ACS National Meeting & Exposition, San Francisco, USA, August 10-14, 2014.
[14]Enantioselective Palladium(II) Catalyzed Cyclization-Cycloaddition Cascade Reactions of Alkenyl
Oximes (poster), M. A. Abozeid, S. Takizawa, H. Sasai: 248th ACS National Meeting & Exposition, San
Francisco, USA, August 10-14, 2014.
[15]Organocatalyzed Enantioselective Reactions of Ketimines with Allenoates (oral), S. Takizawa, F. A.
Arteaga, Y. Yoshida, M. Suzuki, H. Sasai: Aachen-Osaka Joint Symposium, Aachen, Germany, September
3-5, 2014.
[16]Palladium-Catalyzed Direct C–H Arylation of Isoxazoles at Their 5-Position (oral), M. Shigenobu, K.
Takenaka, H. Sasai: Aachen-Osaka Joint Symposium, Aachen, Germany, September 3-5, 2014.
[17]Enantioselective C–C Bond Forming Reactions Catalyzed by Vanadium(V) Complex (oral), M. Sako,
S. Takizawa, Y. Yoshida, J. Kodera, H. Sasai: Aachen-Osaka Joint Symposium, Aachen, Germany,
September 3-5, 2014.
[18]Recent Progress of Enantioselective Catalysis Promoted by Pd-SPRIX (poster), S. C. Mohanta, X.
Lin, K. Takenaka, H. Sasai: ETH Zürich-Osaka Univ. Joint Symposium, Osaka, Japan, October 9-10,
2014.
[19]Enantioselective C–C Bond Forming Reactions Catalyzed by Vanadium(V) Complex (poster), M.
Sako, S. Takizawa, T. Tsujihara, Y. Yoshida, J. Kodera, T. Kawano, H. Sasai: ETH Zürich-Osaka Univ.
Joint Symposium, Osaka, Japan, October 9-10, 2014.
[20]Recent Progress in Enantioselective Reactions Catalyzed by Pd-SPRIX: Pd Enolate Umpolung and
Pd(II)/Pd(IV) Catalysis (poster), S. C. Mohanta, Y. D. Dhage, K. Takenaka, H. Sasai: The 2nd
International Conference on Organometallics and Catalysis, Nara, Japan, October 26-29, 2014.
[21]Development of Novel Chiral Spiro Ligands Bearing Imidazole Coordination Sites (poster), K.
Sawada, S. Takatani, K. Takenaka, H. Sasai: The 2nd International Conference on Organometallics and
Catalysis, Nara, Japan, October 26-29, 2014.
― 206 ―
[22]Palladium-Catalyzed Direct C–H Arylation of Isoxazoles at Their 5-Position (poster), M. Shigenobu,
K. Takenaka, H. Sasai: The 2nd International Conference on Organometallics and Catalysis, Nara, Japan,
October 26-29, 2014.
[23]Novel Enantioselective Reactions Promoted by Pd-SPRIX; Pd(II)/Pd(IV) Catalyses and Umpolung of
Pd-Enolates (invited), H. Sasai: Molecular Chirality Asia 2014, Beijing, China, October 29-31, 2014.
[24]Enantioselective Palladium(II) Catalyzed Cyclization-Cycloaddition Cascade Reactions of Alkenyl
Oximes (poster), M. A. Abozeid, S. Takizawa, H. Sasai: Molecular Chirality Asia 2014, Beijing, China,
October 29-31, 2014.
[25]Development of New SPRIX Ligands Having an effective Asymmetric Environment (poster), X. Lin,
K. Takenaka, H. Sasai: Molecular Chirality Asia 2014, Beijing, China, October 29-31, 2014.
[26]Enantioselective C–C Bond Forming Reactions Catalyzed by Vanadium(V) Complex (poster), S.
Takizawa, Y. Yoshida, M. Sako, J. Kodera, T. Sakai, H. Sasai: Molecular Chirality Asia 2014, Beijing,
China, October 29-31, 2014.
[27]Enantioselective Organocatalyzed Formal [n+2] Cycloaddition Using Allenoates (poster), S.
Takizawa, F. A. Arteaga, Y. Yoshida, M. Suzuki, K. Kishi, T. M.-N. Nguyen, H, Sasai: Molecular
Chirality Asia 2014, Beijing, China, October 29-31, 2014.
[28]Enantio- and Diastereoselective Rauhut-Currier Reaction: Facile Synthesis of
Į-Methylidene-Ȗ-Butyrolactones and Ȗ-Butyrolactams (poster), S. Takizawa, K. Kishi, T. M.-N Nguyen, S.
A. Arteaga, M. Suzuki, H. Sasai: Advanced Molecular Transformations by Organocatalysts 2nd
International Conference & 7th Symposium on Organocatalysis, Tokyo, Japan, November 21-22, 2014.
[29]Ir Catalyzed Asymmetric Tandem Reaction of meso-Diols and Aldehydes (poster), T. Suzuki,
Ismiyarto, Y. Ishizaka, K. Ghozati, D.-Y. Zhou, K. Asano, H. Sasai: The 18th SANKEN and The 13th
SANKEN Nanotechnology Symposium, Osaka, Japan, December 10-11, 2014.
[30]Carbon Nanotubes(CNTs)-Supported Vanadium(V) Catalyst (poster), M. Sako, S. Takizawa, T.
Tsujihara, Y. Yoshida, J. Kodera, T. Kawano, H. Sasai: The 18th SANKEN and The 13th SANKEN
Nanotechnology Symposium, Osaka, Japan, December 10-11, 2014.
[31]Palladium-Catalyzed Direct C5 Arylation of Isoxazoles: Mechanistic Study and Application (oral), M.
Shigenobu, K. Takenaka, H. Sasai: Biotechnology and Chemistry for Green Growth (Aachen-Osaka Joint
Symposium), Osaka, Japan, March 10-11, 2015.
ゎㄝࠊ⥲ㄝ
㓟㸫ሷᇶᆺ୙ᩧ᭷ᶵศᏊゐ፹ࢆ⏝࠸ࡿ࢚ࢼࣥࢳ࢜㑅ᢥⓗ aza㸫᳃⏣㸫Baylis㸫Hillman ᆺࢻ࣑ࣀ཯
ᛂࡢ㛤Ⓨ, ⃝ᚸࠊ➲஭ᏹ᫂, ᭷ᶵྜᡂ໬Ꮫ༠఍ㄅ, ᭷ᶵྜᡂ໬Ꮫ༠఍, 72[7] (2014), 781-796.
“duel”ࡢ࡞࠸“dual”࡞㛵ಀ — ஧ࡘࡢゐ፹ࡀ⧊ࡾᡂࡍ࢚ࢼࣥࢳ࢜㑅ᢥⓗྜᡂ, ➉୰࿴ᾈࠊ➲஭ᏹ
᫂, ໬Ꮫ, ໬Ꮫྠே, 69[10] (2014), 66-67.
ⴭ᭩
[1]The Henry (Nitroaldol) Reaction (P. Knochel, G. A. Molander)“Comprehensive Organic Syntheses,
Second Edition”, ➲஭ᏹ᫂, Elsevier, 2[2-13] (543-570) 2014.
[2]Addition Reactions with Formation of Carbon–Oxygen Bonds: (iv) The Wacker Oxidation and Related
Reactions (P. Knochel, G. A. Molander)“Comprehensive Organic Syntheses, Second Edition”, ➉୰࿴ᾈࠊ
➲஭ᏹ᫂, Elsevier, 7[7-17] (431-491) 2014.
― 207 ―
≉チ
[1]ࠕᅜ㝿≉チฟ㢪ࠖᅛయゐ፹ࢆ⏝࠸ࡓ࢚࣏࢟ࢩ໬ྜ≀ࡢ〇㐀᪉ἲ, PCT/JP2014/080375
[2]ࠕᅜෆᡂ❧≉チ࣏࣐࣮ࠖࣜࡢ㓟໬᪉ἲ, 2009-115073
[3]ࠕฟ㢪๓ㆡΏ≉チ㸦ᅜෆ࣭ᅜ㝿㸧ࠖ㉸ཎᏊ౯ࣚ࢘⣲཯ᛂ๣ࢆ⏝࠸ࡿⰾ㤶᪘໬ྜ≀࠾ࡼࡧ」⣲⎔
ᘧⰾ㤶᪘໬ྜ≀ࡢ࣏࣐࣮ࣜࡢ〇㐀᪉ἲ, K20080099
[4]ࠕฟ㢪๓ㆡΏ≉チ㸦ᅜෆ࣭ᅜ㝿㸧ࠖ᪂つ」⣲⎔ᘧⰾ㤶᪘໬ྜ≀, K20080100
[5]ࠕฟ㢪๓ㆡΏ≉チ㸦ᅜෆ࣭ᅜ㝿㸧ࠖ᪂つ」⣲⎔ᘧⰾ㤶᪘࣏࣐࣮ࣜ, K20080101
[6]ࠕฟ㢪๓ㆡΏ≉チ㸦ᅜෆ࣭ᅜ㝿㸧ࠖࢩࢫࢸ࢖ࣥ⣔㓟⣲྾཰๣, K20090300
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
➲஭ ᏹ᫂
The 26th International Conference on Organometallic Chemistry (ICOMC2014) (⤌
⧊ጤဨ)
➉୰ ࿴ᾈ
The 26th International Conference on Organometallic Chemistry (ICOMC2014) (⤌
⧊ጤဨ)
➲஭ ᏹ᫂
ICOMC 2014 Post-Symposium in Osaka: New Aspects of Reactive Organometallic
Complexes of Transition Metals (⤌⧊ጤဨ)
ᅜෆᏛ఍
ࢩ࣏ࣥࢪ࣒࢘ ࣮࣭ࣔࣞ࢟ࣗࣛ࢟ࣛࣜࢸ࢕࣮2014
ศᏊάᛶ໬ - ᭷ᶵศᏊゐ፹ྜྠࢩ࣏ࣥࢪ࣒࢘
᪥ᮏࣉࣟࢭࢫ໬Ꮫ఍ 2014 ࢧ࣐࣮ࢩ࣏ࣥࢪ࣒࢘
➨ 34 ᅇ᭷ᶵྜᡂⱝᡭࢭ࣑ࢼ࣮
➨ 44 ᅇ」⣲⎔໬Ꮫウㄽ఍
➨ 61 ᅇ᭷ᶵ㔠ᒓ໬Ꮫウㄽ఍
➨ 22 ᅇศᏊྜᡂ໬Ꮫࢭ࣑ࢼ࣮
➨ 40 ཯ᛂ࡜ྜᡂࡢ㐍Ṍࢩ࣏ࣥࢪ࣒࢘
᪥ᮏ⸆Ꮫ఍➨ 135 ᖺ఍
➨ 95 ᅇ᪥ᮏ໬Ꮫ఍᫓Ꮨᖺ఍
ྲྀᚓᏛ఩
༤ኈ㸦⌮Ꮫ㸧
Tue Minh-Nhat
Nguyen
༤ኈ㸦⌮Ꮫ㸧
Fernando Arteaga
Arteaga
༤ኈ㸦⌮Ꮫ㸧
㧗㇂ ಟᖹ
༤ኈ㸦⌮Ꮫ㸧
ྜྷ⏣ Ὀᚿ
ಟኈ㸦⌮Ꮫ㸧
Ṋෆ ⰾᶞ
ಟኈ㸦⌮Ꮫ㸧
ᓊ 㕲㤿
1௳
1௳
1௳
3௳
1௳
1௳
1௳
2௳
2௳
10 ௳
᭷ᶵศᏊゐ፹࡟ࡼࡿ࢚ࢼࣥࢳ࢜㑅ᢥⓗ Rauhut-Currier ཯ᛂ࡜ᙧᘧⓗ[3+2]⎔໬
௜ຍ཯ᛂࡢ㛤Ⓨ㸸Į-࢔ࣝ࢟ࣜࢹࣥ-Ȗ-ࣈࢳࣟࣛࢡࢺࣥཬࡧࠊ࣋ࣥࢰࣇࣛࣀࣥྜ
ᡂ࡬ࡢᛂ⏝
᭷ᶵศᏊ୙ᩧゐ፹࡟ࡼࡿࢣࢳ࣑ࣥࢆᇶ㉁࡜ࡍࡿ࢔ࢨ-᳃⏣-࣋࢖ࣜࢫ-ࣄ࣐ࣝࣥ
཯ᛂ࡜ᙧᘧⓗ[n+2]⎔໬௜ຍ཯ᛂࡢ㛤Ⓨ
ࢫࣆࣟࣅࣛࢡࢱ࣒ࡢ࢚ࢼࣥࢳ࢜㑅ᢥⓗᵓ⠏ࢆᇶ┙࡜ࡍࡿ᪂つ࢟ࣛࣝ㓄఩Ꮚࡢ
㛤Ⓨ
1,2,3-ࢺࣜ࢔ࢰ࣮ࣝࡢᶵ⬟໬ࢆᇶ┙࡜ࡍࡿ࢟ࣛࣝ࡞᪂つࢫࣆࣟᆺ᭷ᶵሷ ࠾ࡼ
ࡧ࣊ࣜࢭࣥ㢮ࡢ㛤Ⓨ◊✲
࢜࢟ࢧ[9]࣊ࣜࢭࣥཬࡧ ࢫࣆࣟ[4.4]ࣀࢼࣀࣥ㢮ࡢ ゐ፹ⓗ୙ᩧྜᡂἲࡢ㛤Ⓨ
᭷ᶵศᏊ୙ᩧゐ፹ࢆ⏝࠸ࡿศᏊෆཬࡧ ศᏊ㛫⎔໬཯ᛂ࡟ࡼࡿᅄ⨨᥮Ⅳ⣲ࡢ
ᵓ⠏
⛉Ꮫ◊✲㈝⿵ຓ㔠
᪂Ꮫ⾡㡿ᇦ◊✲
㸦◊✲㡿ᇦᥦ᱌
ከᶵ⬟᭷ᶵศᏊゐ፹ࡢ㛤Ⓨ࡜୙ᩧࢻ࣑ࣀ཯ᛂ࡬ࡢᛂ⏝
― 208 ―
༢఩㸸༓෇
3,510
ᆺ㸧බເ◊✲
⃝ ᚸ
ᇶ┙◊✲(C)
⃝ ᚸ
ᇶ┙◊✲(C)
ᕷཎ ₶Ꮚ
ཷク◊✲
➲஭ ᏹ᫂
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
➲஭ ᏹ᫂
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
ዡᏛᐤ㝃㔠
➲஭ ᏹ᫂
➲஭ ᏹ᫂
ࢫࣆࣟ࢟ࣛࣜࢸ࢕࣮ࢆά⏝ࡍࡿ⎔ቃㄪ࿴ᆺ୙ᩧゐ፹ࡢ㛤Ⓨ
1,430
⎔ቃㄪ࿴ᆺ⢊య཯ᛂ࡟ࡼࡿࣁࣟࢤࣥࣇ࣮࢚࣏ࣜ࢟ࢩ໬཯ᛂ
ࡢ཯ᛂᶵᵓ
1,300
㔠ᒓᯫᶫ㧗ศᏊ㓄఩Ꮚࡢタィ࡜
ᅛᐃ໬୙ᩧ㓄఩Ꮚ࡟ࡼࡿ࢟ࣛࣜ
ࢸ࢕࣮ไᚚ
ゐ፹ⓗ୙ᩧࢻ࣑ࣀ཯ᛂࢆᇶ┙࡜
ࡍࡿᐇ⏝ⓗศᏊኚ᥮
10,920
ࢼ࢞ࢭࢣ࣒ࢸࢵࢡࢫᰴᘧ఍♫ ௦⾲ྲྀ⥾ᙺ♫㛗 ୕ᶫ୍ኵ
᪥⏘໬Ꮫᕤᴗᰴᘧ఍♫ ᇳ⾜ᙺဨ ≀㉁⛉Ꮫ◊✲ᡤ㛗 Ώ
㑔 ῟୍
1,200
400
ඹྠ◊✲
ᕷཎ ₶Ꮚ
ᰴᘧ఍♫኱ᕝཎ〇సᡤ
ᕷཎ ₶Ꮚ
኱ᕝཎ〇సᡤ
ࡑࡢ௚ࡢ➇தⓗ◊✲㈨㔠
➲஭ ᏹ᫂
኱Ꮫඹྠ฼⏝ᶵ㛵ἲே⮬
↛⛉Ꮫ◊✲ᶵᵓศᏊ⛉Ꮫ
◊✲ᡤ
7,800
ࣀࣥࣁࣛ࢖ࢺἲ࡟ࡼࡿ࢚࣏࢟ࢩ໬ྜ≀〇㐀
⿦⨨ࡢ㛤Ⓨ
ࣀࣥࣁࣛ࢖ࢺἲ࡟ࡼࡿ࢚࣏࢟ࢩ໬ྜ≀〇㐀
⿦⨨ࡢ㛤Ⓨ
ᶵ⬟ᛶศᏊࡢᵓ㐀ホ౯
864
0
3,000
⢭ᐦไᚚ໬Ꮫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Formation of Ligand-Assisted Complex of Two RNA Hairpin Loops, C. Hong, T. Otabe, S. Matsumoto,
C. Dohno, A. Murata, M. Hagihara, K. Nakatani: Chem. Eur. J., 20 (2014) 5244-5252.
[2]Modulation of binding properties of amphiphilic DNA containing multiple dodecyl phosphotriester
linkages to lipid bilayer membrane, S. Makishi, T. Shibata, M. Okazaki, C. Dohno, K. Nakatani: Bioorg.
Med. Chem. Lett., 24 (2014) 3578-3581.
[3]Synthesis of 8-substituted adenine and adenosine libraries and the binding to pre-miR-29a, T.
Fukuzumi, H. Aikawa, Y. Harada, A. Sugai, A. Murata, K. Nakatani: Bull. Chem. Soc. Jpn., 87 (2014)
1013-1015.
[4]Cytosine-bulge dependent fluorescence quenching for real-time hairpin primer PCR, F. Takei, C. Chen,
G. Yu, T. Shibata, C. Dohno, K. Nakatani: Chem. Commun., 50 (2014) 15195-15198.
[5]Recognition of Chelerythrine to Human Telomeric DNA and RNA G-quadruplexes, L. Bai, M.
Hagihara, K. Nakatani, Z. H. Jiang: Sci. Rep., 4 (2014) 6767.
[6]2-Aminophenanthroline dimer stabilized the C-C mismatched duplex DNA, J. Li, J. Matsumoto, K.
Otabe, C. Dohno, K. Nakatani: Bioorg. Med. Chem., 23 (2015) 753-758.
ᅜ㝿఍㆟
[1]Synthesis and Evaluation of 8-substituted Adenine Derivatives as RNA Binding Molecules (poster), H.
Aikawa, T. Fukuzumi, A. Murata, Y. Harada, K. Nakatani: RNA 2014 The 19th Annual Meeting of the
RNA Society.
[2]Synthesis and design of RNA binding molecules in enthalpy-driven manner (poster), N. Natsuhara, Y.
― 209 ―
Di, T. Tsuda, S. Mukherjee, K. Nakatani: RNA 2014 The 19th Annual Meeting of the RNA Society.
[3]Regulation of DNA/RNA structure and function by small molecules (invited), K. Nakatani: JSPS
UK-Japan Meeting: From Duplexes to Quadruplexes –Understanding DNA Structure and Function.
[4]Synthetic DNA that works in lipid membrane system (oral), C. Dohno, K. Nakatani: Next Generation
Sensor Devices for a Healthier, Safer Society International Networking Workshop.
[5]Regulation of –1ribosomal frameshifting by ligand-induced RNA pseudoknot formation (poster), K.
Nakatani: XXI Round Table on Nucleosides, Nucleotides and Nucleic acids.
[6]Novel PCR Monitoring System Using Hairpin Primer Having Cytosine-Bulge and Covalent Binding
Fluorescence Molecule (poster), F. Takei, C. Chen, G. Yu, C. Dohno, K. Nakatani: XXI Round Table on
Nucleosides, Nucleotides and Nucleic acids.
[7]Development of Novel PCR Primers for Facile Gene Detection (invited), K. Nakatani: A3RONA 2014
China.
[8]Synthetic RNA switches controlled by a photoresponsive ligand (poster), C. Dohno, M. Kimura, I.
Kohyama, K. Nakatani: ISNAC2014.
[9]Synthesis of amphiphilic i-motif DNAs (poster), H. Yamaguchi, K. Matsuzaki, S. Makishi, T. Shibata,
C. Dohno, K. Nakatani: ISNAC2014.
[10]In vitro selection of pre-miR-29a loop mutant library against the restrained naphthyridine dimer
(poster), Y. Mori, Y. Di, A. Sugai, T. Otabe, J. Li, H. Aikawa, A. Murata, K. Nakatani: ISNAC2014.
[11]Targeting CUG trinucleotide repeats with synthetic ligands (poster), J. Li, J. Matsumoto, K. Nakatani:
ISNAC2014.
[12]Suppression of miR-29a maturation by synthetic ligand (oral), T. Otabe, J. Li, A. Murata, K.
Nakatani: ISNAC2014.
[13]Toward new FET devices detecting DNA (oral), R. K. Verma, A. Michikawa, N. Sabani, F. Takei, K.
Nakatani: 3rd imec Handai International Symposium.
[14]Regulation of Structure and Function of Nucleic Acids by Small Molecules (oral), K. Nakatani: 2015
IMCE International Symposium.
ᅜෆᏛ఍
᪥ᮏ໬Ꮫ఍➨㸷㸳᫓Ꮨᖺ఍
᪥ᮏ⸆Ꮫ఍➨㸯㸱㸳ᖺ఍
᪥ᮏࢣ࣑࢝ࣝࣂ࢖࢜ࣟࢪ࣮Ꮫ఍ ➨㸷ᅇᖺ఍
➨ 62 ᅇᛂ⏝≀⌮Ꮫ఍᫓ᏘᏛ⾡ㅮ₇఍
ྲྀᚓᏛ఩
ಟኈ㸦⌮Ꮫ㸧
ᒸ⏣ Ὀᖾ
ಟኈ㸦⌮Ꮫ㸧
ኟཎ ᮃ
༤ኈ㸦⌮Ꮫ㸧
┿႐ᚿ ⤀࿃
13 ௳
1௳
3௳
1௳
࢔࣑ࣀ⢾ࢆᑟධࡋࡓࢼࣇࢳࣜࢪࣥࡢྜᡂ࡜᰾㓟࡜ࡢ┦஫స⏝
࢚ࣥࢱࣝࣆ࣮㥑ືࢆᣦྥࡋࡓ RNA ⤖ྜᛶศᏊࡢタィ࡜ྜᡂ
␯Ỉᛶᐁ⬟ᇶࢆᑟධࡋࡓ DNA ࢼࣀᵓ㐀࡜⬡㉁⭷࡜ࡢ┦஫స⏝࡟㛵ࡍࡿ◊✲
― 210 ―
⛉Ꮫ◊✲㈝⿵ຓ㔠
≉ู᥎㐍◊✲
୰㇂ ࿴ᙪ
ᇶ┙◊✲(B)
Ṋ஭ ྐᜨ
ⱝᡭ◊✲(B)
ᮧ⏣ ளἋᏊ
ⱝᡭ◊✲(B)
┦ᕝ ᫓ኵ
ཷク◊✲
୰㇂ ࿴ᙪ
୰㇂ ࿴ᙪ
ඹྠ◊✲
୰㇂ ࿴ᙪ
୰㇂ ࿴ᙪ
ࣜࣆ࣮ࢺ⤖ྜศᏊࢆࣉ࣮ࣟࣈ࡜ࡋࡓࢺࣜࢾࢡࣞ࢜ࢳࢻࣜࣆ
࣮ࢺ⑓ࡢ໬Ꮫ⏕≀Ꮫ◊✲
࣊࢔ࣆࣥࣉࣛ࢖࣐࣮㹎㹁㹐ἲࢆ⏝࠸ࡓ࢘࢖ࣝࢫࡢ㧗ឤᗘ᳨
ฟἲ࡟㛵ࡍࡿ◊✲
ᑠศᏊ໬ྜ≀࡟ࡼࡿ࣐࢖ࢡࣟ RNA ⏕ᡂຠ⋡ࡢㄪ⠇
༢఩㸸༓෇
123,760
࢔࣑ࣀ㓟࣭࣌ࣉࢳࢻࡢ᪂つಟ㣭ἲࡢ㛤Ⓨ࡜᪂つ࢔࣑ࢻ࢖ࢯ
ࢫࢱ࣮ࡢ㛤Ⓨ
⊂❧⾜ᨻἲே་⸆ᇶ┙
◊✲ᡤ
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
᪥ᮾ໬ᡂओ
ᰴᘧ఍♫ྂἙ㟁ᕤ࢔ࢻ
ࣂࣥࢫࢺ࢚ࣥࢪࢽ࢔ࣜ
ࣥࢢ
ᶵ⬟ᛶ ncRNA ࢆᶆⓗ࡜ࡋࡓ๰⸆
ࢆ᥎㐍ࠊຍ㏿ࡉࡏࡿᢏ⾡ᇶ┙ࡢ
ᵓ⠏
࣊࢔ࣆࣥ㹎㹁㹐ἲ࡟ࡼࡿࢹࢪࢱ
ࣝ⫢⅖᳨ᰝᢏ⾡ࡢ㛤Ⓨ
6,500
1,950
1,950
48,000
9,185
ᶵ⬟ᛶศᏊࡢྜᡂ
⺯ගࢩࢢࢼࣝቑ኱ᆺࣉࣛ࢖࣐࣮
ἲࡢ㛤Ⓨ
864
0
་⸆ရ໬Ꮫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]RNA-Directed Amino Acid Coupling as a Model Reaction for Primitive Coded Translation, K. Harada,
S. Aoyama, A. Matsugami, P. K. R. Kumar, M. Katahira, N. Kato, J. Ohkanda: ChemBioChem, 15 (6)
(2014) 794-798.
[2]Virus purification and enrichment by hydroxyapatite chromatography on a chip, M Niimia, T. Masuda,
K Kaihatsu, N. Kato, S. Nakamura, T. Nakaya, F. Arai: Sens. Actut. B, 201 (2014) 185-190.
[3]Alkylamines-intercalated Į-zirconium phosphate as latent thermal anionic initiators, O. Shimomura, K.
Maeno, A. Ohtaka, S. Yamaguchi, J. Ichihara, K. Sakamoto, R. Nomura: J. Polymer Sci., Part A: Polymer
Chem., 52 (13) (2014) 1854-1861.
[4]Significant roles of the (pro)renin receptor in integrity of vascular smooth muscle cells., A.
Kurauchi-Mito, A. Ichihara, K. Bokuda, M. Sakoda, K. Kinouchi, T. Yaguchi, T. Yamada, G. H.
Sun-Wada, Y. Wada, H. Itoh: Hypertens Res., 37 (9) (2014) 830-835.
[5]Cotylenin A and arsenic trioxide cooperatively suppress cell proliferation and cell invasion activity in
human breast cancer cells, T. Kasukabe, J. Okabe-Kado, N. Kato, Y. Honma, S. Kumakura: Int. J. Oncol.,
46 (2) (2015) 841-848.
[6]An EGCG derivative effectively induces apoptosis via SHP-1-mediated suppression of BCR-ABL and
STAT3 signalling in chronic myelogenous leukaemia., JH. Jung, M. Yun, EJ. Choo, SH. Kim, MS. Jeong,
DB. Jung, H. Lee, EO. Kim, N. Kato, B. Kim, SK. Srivastava, K. Kaihatsu, SH. Kim.: Br. J. Pharmacol.,
in press (2015) .
ᅜ㝿఍㆟
[1]Effect of Non-natural Amino Acids on the Functions of Peptide and Peptide Nucleic Acid (oral), K.
Kaihatsu, N. Kato: BIT's 7th Annual World Protein & Peptide Conference.
[2]Diagnosis of influenza virus gene by peptide nucleic acid-immobilized device.Current problems and
solutions. Microbiology & Infections Disease Asia Congress. (oral), K. Kaihatsu: BIT's Annual World
― 211 ―
Congress of Microbes 2014.
[3]Rapid identification of influenza A virus gene by peptide nucleic acid-chromatography (oral), K.
Kaihatsu: 2nd Annual Microbiology & Infections Disease Asia Congress.
[4]Upregulation of Vacuolar-type ATPase G1 Subunit by a Genetic Loss of Subunit G2 in Neuron (poster),
Nobuyuki Kawamura, 1 Ge-Hong Sun-Wada, and 2 Yoh Wada: 15th IUBMB International Conference.
[5]Effect of terminal functional group of peptide nucleic acid on its sequence specificity (oral), K.
Kaihatsu, N. Kato: the 41st International Symposium on Nucleic Acids Chemistry.
[6]Association behavior of tolane-modified peptide nucleic acid with ssDNA (poster), K. Kaihatsu, N.
Kato: the 41st International Symposium on Nucleic Acids Chemistry.
[7]Effect of terminal tolane group of peptide nucleic acid on its sequence specificity (poster), K. Kaihatsu,
T. Hayashi, M. Okazaki, K. Takagi, S. Sawada, N. Kato: The 18th SANKEN International Symposium.
[8]Structure function relationship of fusicoccin derivatives as protein-protein interaction stabilizers
(poster), : The 19th SANKEN International Symposium.
[9]Structure-based drug design of novel inhibitors of the bacterial multidrug efflux transporters (poster), :
The 20th SANKEN International Symposium.
[10]Microautophagy, a unique membrane dynamics, in rodent visceral endoderm is involved in the
regulation of canonical Wnt pathway and morphogenesis (poster), Yoh Wada, Minako Aoyama, Nobuyuki
Kawamura, Ge-Hong Sun-Wada: Endoderm Lineages in Development and Disease, Keystone
Symposium.
[11]Embryonic defect in ATP6Voc mutant mice lacking the vacuolar-type H+-ATPase c subunit (poster),
Yoh Wada, Minako Aoyama, Nobuyuki Kawamura, Ge-Hong Sun-Wada: Endoderm Lineages in
Development and Disease, Keystone Symposium.
ゎㄝࠊ⥲ㄝ
Role of autophagy in embryogenesis., Wada, Y., Sun-Wada, G.H., Kawamura, N. & Aoyama, M, Curr
Opin Genet Dev, Elsevier, 27 (2014), 60-66.
࣐࢘ࢫึᮇ⬇Ⓨ⏕࡟࠾࠸࡚ᰤ㣴౪⤥࣭ศ໬ࢩࢢࢼࣝࢆไᚚࡍࡿ࣑ࢡ࣮ࣟ࢜ࢺࣇ࢓ࢪ࣮ࡢᶵ⬟, ᕝ
ᮧᬸᖾ㸪Ꮮ(࿴⏣㸧ᠼ⹿ࠊ࿴⏣ ὒ, ⏕໬Ꮫ, ᪥ᮏ⏕໬Ꮫ఍, 86 (2014), 778-782.
≉チ
[1]ࠕฟ㢪๓ㆡΏ≉チ㸦ᅜෆ࣭ᅜ㝿㸧ࠖ࢔ࣞࣝࢤࣥάᛶࡢᢚไ๣࠾ࡼࡧࡑࡢ⏝㏵, ≉㢪 2014-151095
[2]ࠕᅜ㝿ᡂ❧≉チࠖᢠ⳦๣, 5279054㸦᪥ᮏ㸧
ࠊ201080033912.9(୰ᅜ㸧ࠊ13/388,015 㸦⡿ᅜ㸧
[3]ࠕᅜ㝿≉チฟ㢪ࠖᅛయゐ፹ࢆ⏝࠸ࡓ࢚࣏࢟ࢩ໬ྜ≀ࡢ〇㐀᪉ἲ, PCT/JP2014/080375
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
㛤ⓐ 㑥ᏹ
Journal of Antivirals and Antiretrovirals (⦅㞟ጤဨ)
ᅜෆᏛ఍
᪥ᮏ໬Ꮫ఍
᪥ᮏࢣ࣑࢝ࣝࣂ࢖࢜ࣟࢪ࣮Ꮫ఍
᪥ᮏ࢝ࢸ࢟ࣥᏛ఍
᪥ᮏⓎ⏕⏕≀Ꮫ఍
2௳
3௳
3௳
1௳
― 212 ―
㜵⳦㜵㰄Ꮫ఍
㧗ศᏊᏛ఍
ࣂ࢖࢜࢜ࣉࢸ࢕ࢡࢫ◊✲఍
ⲔᏛ⾡఍㆟
ྲྀᚓᏛ఩
ಟኈ㸦⌮Ꮫ㸧
㧗ᮌ ㈼἞
1௳
1௳
1௳
1௳
N ᮎ➃ࢺࣛࣥಟ㣭࣌ࣉࢳࢻ᰾㓟ࡢ୍ሷᇶ࣑ࢫ࣐ࢵࢳ㆑ู⬟
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(B)
࿴⏣ ὒ
ᇶ┙◊✲(B)
㛤ⓐ 㑥ᏹ
ᣮᡓⓗⴌⱆ
࿴⏣ ὒ
ᣮᡓⓗⴌⱆ
㛤ⓐ 㑥ᏹ
ᇶ┙◊✲(B) ศ
ᢸ
㛤ⓐ 㑥ᏹ
ᇶ┙◊✲(C) ศ
ᢸ
㛤ⓐ 㑥ᏹ
ཷク◊✲
ຍ⸨ ಟ㞝
ዡᏛᐤ㝃㔠
㛤ⓐ 㑥ᏹ
㛤ⓐ 㑥ᏹ
ᵽཱྀ 㞝௓
ඹྠ◊✲
㛤ⓐ 㑥ᏹ
㛤ⓐ 㑥ᏹ
㛤ⓐ 㑥ᏹ
ึᮇ⬇⤌⧊ᵓ⠏ࢆไᚚࡍࡿ࣑ࢡ࣮ࣟ࢜ࢺࣇ࢓ࢪ࣮ࡢ◊✲
໬Ꮫಟ㣭࣌ࣉࢳࢻ᰾㓟࡟ࡼࡿ࢘࢖ࣝࢫࢤࣀ࣒㸯ሷᇶኚ␗ࡢ㧗
ឤᗘデ᩿ἲࡢ㛤Ⓨ
࣑ࢡ࣮ࣟ࢜ࢺࣇ࢓ࢪ࣮࡟ࡼࡿ᪂つ࢚ࣥࢻࢧ࢖ࢺ࣮ࢩࢫ⤒㊰ࡢ
◊✲
ேᕤࢾࢡࣞ࢜ࢱࣥࣃࢡࢆ⏝࠸ࡓ RNA ࢘࢖ࣝࢫࡢ㧗ឤᗘ᳨ฟ⣔
ࡢ㛤Ⓨ
࿧྾ჾ࢘࢖ࣝࢫ᳨ฟ⏝࢜ࣥࢳࢵࣉࢹࣂ࢖ࢫࡢ㛤Ⓨ࡜デ᩿࡬ࡢ
ᛂ⏝
࢖ࣥࣇ࢚ࣝࣥࢨឤᰁࢆ㜼ᐖࡍࡿࢩ࢔ࣝ㓟ಟ㣭㸱ʊ㹵㹟㹷 㹨
㹳㹬㹡㹲㹧㹭㹬᰾㓟ࡢ๰〇
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
␗≀᤼ฟࢱࣥࣃࢡ࡟ᑐࡍࡿࣘࢽࣂ
࣮ࢧࣝ㜼ᐖ๣ࡢศᏊタィ࠾ࡼࡧ໬
Ꮫྜᡂ
ᮾὒ⣳ᰴᘧ఍♫ ࣂ࢖࢜஦ᴗ㛤Ⓨ㒊㛗 ᭹㒊 㟼ኵ
࢔࣮ࢡࣞ࢖ᰴᘧ఍♫ ၟရ㛤Ⓨ㒊㛗 ⟄஭ ࿴඾
୍⯡㈈ᅋἲே ⺮ⓑ㉁◊✲ዡບ఍
ᰴᘧ఍♫ࣉࣟࢸࢡࢸ࢕
࢔
ᰴᘧ఍♫ࣉࣟࢸࢡࢸ࢕
࢔
ᰴᘧ఍♫ࣜࢥ࣮
࢝ࢸ࢟ࣥㄏᑟయࡢᇶᮏ≉ᛶホ౯࡟
㛵ࡍࡿ◊✲
࢝ࢸ࢟ࣥㄏᑟࢆ⏝࠸ࡓᢠ࢔ࣞࣝࢤ
ࣥ〇๣ࡢ≉ᛶ࡟㛵ࡍࡿ◊✲
༳ๅ࡟ࡼࡿデ᩿ࢹࣂ࢖ࢫࢆ฼⏝ࡋ
ࡓ࢘࢖ࣝࢫࢤࣀ࣒デ᩿ἲ࡟㛵ࡍࡿ
◊✲
༢఩㸸༓෇
6,500
5,590
1,170
1,950
1,300
260
12,484
1,200
199
800
108
872
1,500
⏕యศᏊ཯ᛂ⛉Ꮫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]High-throughput de novo screening of receptor agonists with an automated single-cell analysis and
isolation system, N. Yoshimoto, K. Tatematsu, M. Iijima, T. Niimi, A.D. Maturana, I. Fujii, A. Kondo, K.
Tanizawa, and S. Kuroda: Sci. Rep., 4 (2014) 4242.
[2]Oligomerization-induced conformational change in the C-terminal region of Nel-like molecule 1
(NELL1) protein is necessary for the efficient mediation of murine MC3T3-E1 cell adhesion and
spreading, Y. Nakamura, A. Hasebe, K. Takahashi, M. Iijima, N. Yoshimoto, A.D. Maturana, K. Ting, S.
Kuroda, and T. Niimi: J. Biol. Chem., 289 (2014) 9781-9794.
[3]Enhanced OH radical generation by dual-frequency ultrasound with TiO2 nanoparticles: Its application
― 213 ―
to targeted sonodynamic therapy, K. Ninomiya, K. Noda, C. Ogino, S. Kuroda, and N. Shimizu: Ultrason.
Sonochem., 21 (2014) 289-294.
[4]Specific delivery of microRNA93 into HBV-replicating hepatocytes downregulates protein expression
of liver cancer susceptible gene MICA, M. Ohno, M. Otsuka, T. Kishikawa, C. Shibata, T. Yoshikawa, A.
Takata, R. Muroyama, N. Kowatari, M. Sato, N. Kato, S. Kuroda, and K. Koike: Oncotarget, 5 (2014)
5581-5590.
[5]A cisplatin-incorporated liposome that targets the epidermal growth factor receptor enhances
radiotherapeutic efficacy without nephrotoxicity, J. Jung, S.Y. Jeong, S.S. Park, S.H. Shin, E.J. Ju, J. Choi,
J. Park, J.H. Lee, I. Kim, Y.A. Suh, J.J. Hwang, S. Kuroda, J.S. Lee, S.Y. Song, and E.K. Choi: Int. J.
Oncology, 46 (2015) 1268-1274.
[6]Single-cell-based breeding: Rational strategy for the establishment of cell lines from a single cell with
the most favorable properties, N. Yoshimoto, and S. Kuroda: J. Biotechnol. Bioeng., 117 (2014) 394-400.
[7]Studies on an acetylcholine binding protein identify a basic residue on the ȕ1-strand as a new structural
determinant of neonicotinoid actions, M. Ihara*, T. Okajima*, A. Yamashita*, T. Oda, T. Asano, M.
Matsui, D. B. Sattelle, and K. Matsuda: Mol. Pharmacol., 86 (2014) 736-746.
[8]The radical S-adenosyl-L-methionine enzyme QhpD catalyzes sequential formation of intra-protein
sulfur-to-methylene carbon thioether bonds., T. Nakai, H. Ito, K. Kobayashi, Y. Takahashi, H. Hori, M.
Tsubaki, K. Tanizawa, and T. Okajima: J. Biol. Chem., 290 (2015) 11144-11166.
ᅜ㝿఍㆟
[1]Bio-nanocapsule scaffold for oriented immobilization and clustering of sensing molecules on biosensor
surfaces (poster), M. Iijima, and S. Kuroda: Biosensors2014, Melbourne, Australia, May 27-31, 2014.
[2]Mechanical cell sorting using antibody-immobilized nanoneedle array (poster), M. Miyazaki, R.
Kawamura, S.R. Rao, T. Kobayashi, M. Iijima, S. Kuroda, F. Iwata, and C. Nakamura: Biosensors2014,
Melbourne, Australia, May 27-31, 2014.
[3]Enhancement of mass-detection sensitivity in wireless-electrodeless QCM biosensors by
bio-nanocapsules (poster), K. Noi, H. Ogi, M. Iijima, S. Kuroda, and M. Hirao: Biosensors2014,
Melbourne, Australia, May 27-31, 2014.
[4]Sub-atomic resolution structure of bacterial copper amine oxidase shows binding of O2-like diatomic
molecules under atmospheric conditions (oral), T. Okajima, T. Murakawa, H. Hayashi, and K. Tanizawa:
The 4th International conference on cofactor (ICC-04), Parma, Italy, August 25-28, 2014.
[5]Complete journey of quinohemoprotein amine dehydrogenase from genes to periplasm (oral), T. Nakai,
T. Deguchi, K. Tanizawa, and T. Okajima: The 4th International conference on cofactor (ICC-04), Parma,
Italy, August 25-28, 2014.
[6]Conformational flexibility of the topa quinone cofactor in copper amine oxidase revealed by
site-specific mutagenesis of the neighboring conserved asparagine residue (oral), T. Murakawa, H.
Hayashi, K. Tanizawa, and T. Okajima: The 4th International conference on cofactor (ICC-04), Parma,
Italy, August 25-28, 2014.
ゎㄝࠊ⥲ㄝ
࢘࢖ࣝࢫ⾲㠃ᢠཎࢱࣥࣃࢡ㉁ᥦ♧࡟ࡼࡿ࣏ࣜࢯ࣮࣒࡬ࡢᶆⓗ໬⬟㸪⣽⬊ෆ౵ධ⬟㸪࠾ࡼࡧࢫࢸࣝ
ࢫ⬟ࡢ௜୚, ⭷, ᪥ᮏ⭷Ꮫ఍, 39 (2014), 283-289.
඲⮬ື㸯⣽⬊ゎᯒ༢㞳⿦⨨㸦ASONECell Picking System㸧ࡢ㛤Ⓨ, 㯮⏣ಇ୍, BB Chubu, ᪥ᮏ⏕≀
― 214 ―
ᕤᏛ఍୰㒊ᨭ㒊, 5 (2014), 15-20.
ⴭ᭩
[1]DDS ࢼࣀ࢟ࣕࣜ࢔㺃ࣂ࢖࢜ࢼࣀ࢝ࣉࢭࣝ࡟ࡼࡿࣂ࢖࢜࢖࣓࣮ࢪࣥࢢ ((ᰴ)ᢏ⾡᝟ሗ༠఍)“࣐࢖
ࢡࣟ/ࢼࣀ࢝ࣉࢭࣝࡢㄪ〇, ᚎᨺᛶไᚚ࡜ᛂ⏝஦౛”, Ⰻඖఙ⏨, 㯮⏣ಇ୍, (ᰴ)ᢏ⾡᝟ሗ༠఍,
(257-263) 2014.
[2]㸯⣽⬊⫱✀ࢆᐇ⌧ࡍࡿ඲⮬ື㸯⣽⬊ゎᯒ༢㞳⿦⨨ࡢ㛤Ⓨ (኱ᨻ ೺ྐ)“ᢠయ་⸆࡟࠾ࡅࡿ⣽
⬊ᵓ⠏࣭ᇵ㣴࣭ࢲ࢘ࣥࢫࢺ࣮࣒ࣜࡢࡍ࡭࡚”, Ⰻඖఙ⏨, 㯮⏣ಇ୍, (ᰴ)CMC ฟ∧, (56-66) 2015.
[3]Bio-nanocapsules: Nanocarriers Harboring Virus-Derived Transfection Machinery for Use as Pinpoint
Drug Delivery Systems (A. Tsuda & P. Gehr)“Nanoparticles: Drug Inhalation Therapy – Events at
Air-Blood Tissue Barrier”, 㯮⏣ಇ୍, (235-246) 2014.
[4]᪂つ㦵ㄏᑟࢱࣥࣃࢡ㉁ NELL1 ࡢⓎぢ࠿ࡽ๓⮫ᗋヨ㦂ࡲ࡛ (ྡྂᒇ኱Ꮫ᭱ඛ➃࣓ࢹ࢕࢚࢝ࣝࣥ
ࢪࢽ࢔ࣜࣥࢢ⦅㞟ጤဨ఍)“᭱ඛ➃࣓ࢹ࢕࢚࢝ࣝࣥࢪࢽ࢔ࣜࣥࢢ”, ᪂⨾཭❶ࠊ㯮⏣ಇ୍, ୍⢏᭩ᡣ,
(㟁Ꮚฟ∧ࡢࡓࡵ㡫࡞ࡋ) 2014.
[5]ࣂ࢖࢜ࢼࣀ࢝ࣉࢭࣝ࡟ࡼࡿ⏕యෆࣆ࣏ࣥ࢖ࣥࢺ⸆≀࣭㑇ఏᏊ㏦㐩ᢏ⾡ (ྡྂᒇ኱Ꮫ᭱ඛ➃࣓ࢹ
࢕࢚࢝ࣝࣥࢪࢽ࢔ࣜࣥࢢ⦅㞟ጤဨ఍)“᭱ඛ➃࣓ࢹ࢕࢚࢝ࣝࣥࢪࢽ࢔ࣜࣥࢢ”, Ⰻඖఙ⏨, 㯮⏣ಇ
୍, ୍⢏᭩ᡣ, (㟁Ꮚฟ∧ࡢࡓࡵ㡫࡞ࡋ) 2014.
≉チ
[1]ࠕᅜ㝿ᡂ❧≉チࠖ⸆≀㏦㐩ࢩࢫࢸ࣒, ୰ᅜ ZL2008 8 012784.9
[2]ࠕᅜෆᡂ❧≉チ࣏ࠖࣜࢯ࣮࣒」ྜయ, ࡑࡢ〇㐀᪉ἲ, ཬࡧࡑࡢ౑⏝, 5713311
[3]ࠕᅜෆ≉チฟ㢪ࠖ᰾㓟ࢆෆᑒࡋ࡚࡞ࡿ୰ᛶཪࡣ࢔ࢽ࢜ࣥᛶ࣏ࣜࢯ࣮࣒ཬࡧࡑࡢ〇㐀᪉ἲ, ≉㢪
2014-170680
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
㯮⏣ ಇ୍
The Journal of Biochemistry (Tokyo) (Associate Editor)
㯮⏣ ಇ୍
The Open Veterinary Science Journal (Editorial Board Member)
㯮⏣ ಇ୍
The Open Nanomedicine Journal (Editorial Board Member)
ᒸᓥ ಇⱥ
The Journal of Biochemistry (Advisory Board)
ᅜෆᏛ఍
➨ 14 ᅇ᪥ᮏ⺮ⓑ㉁⛉Ꮫ఍ᖺ఍
➨ 30 ᅇ᪥ᮏ DDS Ꮫ఍Ꮫ⾡㞟఍
➨ 157 ᅇ᪥ᮏ⋇་Ꮫ఍Ꮫ⾡㞟఍
➨ 66 ᅇ᪥ᮏ⏕≀ᕤᏛ఍኱఍
➨ 8 ᅇࣂ࢖࢜㛵㐃໬Ꮫࢩ࣏ࣥࢪ࣒࢘
➨ 37 ᅇ᪥ᮏศᏊ⏕≀Ꮫ఍ᖺ఍
㟁Ẽ໬Ꮫ఍➨ 82 ᅇ኱఍
᪥ᮏ㎰ⱁ໬Ꮫ఍ 2015 ᖺᗘ኱఍
➨ 32 ᅇື≀⣽⬊ᕤᏛࢩ࣏ࣥࢪ࣒࢘ࠕ᪥ᮏࡢࣂ࢖࢜་⸆ရ㛤Ⓨࢆᨭ࠼ࡿඛ➃ᢏ
⾡ࠖ
➨ 87 ᅇ᪥ᮏ⏕໬Ꮫ఍኱఍
᪥ᮏ㎰ⱁ໬Ꮫ఍㛵すᨭ㒊኱఍(➨ 486 ᅇㅮ₇఍)
2௳
1௳
1௳
3௳
1௳
3௳
1௳
4௳
1௳
4௳
1௳
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᣮᡓⓗⴌⱆ◊✲
ᒸᓥ ಇⱥ
㕲◲㯤ࢡࣛࢫࢱ࣮ྵ᭷ᯫᶫ㓝⣲ࡢᶵ⬟ゎᯒ࡜᪂つ⎔≧⏕⌮
άᛶ࣌ࣉࢳࢻࡢ๰〇
― 215 ―
༢఩㸸༓෇
1,040
ᇶ┙◊✲㸦㸿㸧 ࢘࢖ࣝࢫ⾲ᒙᶵ⬟ࢻ࣓࢖ࣥゎᯒ࡟ᇶ࡙ࡃ᪂ḟඖ DDS ࢟ࣕ
㯮⏣ ಇ୍
ࣜ࢔ࡢ㛤Ⓨ
ⱝᡭ◊✲㸦B㸧
ࢭࣥࢩࣥࢢ⏝⏕యศᏊࡢࢼࣀࣞ࣋ࣝᩚิ໬ᢏ⾡ࡢ㛤Ⓨ
㣤ᔱ ┈ᕭ
ཷク◊✲
❧ᯇ ೺ྖ
ᅜ❧኱Ꮫἲேྡྂᒇ኱
ࣂ࢖࢜ࢼࣀ࢝ࣉࢭࣝࡢᨵኚయస
Ꮫ㸦௦⾲ᶵ㛵࣭ྡ኱ࡀ㎰ 〇ཬࡧ㔞⏘໬ᢏ⾡ࡢ☜❧
ᯘỈ⏘┬࡜ࢥࣥࢯ࣮ࢩ
࢔࣒༢఩࡛ዎ⣙㸧
㯮⏣ ಇ୍
㎰ᯘỈ⏘ᴗ࣭㣗ရ⏘ᴗ⛉ ⏕యෆࣆ࣏ࣥ࢖ࣥࢺ DDS ᢏ⾡࡟
Ꮫᢏ⾡◊✲᥎㐍஦ᴗጤ
ࡼࡿᐙ␆⑌⑓㜵ᚚ࣡ࢡࢳࣥࡢ๰
ク஦ᴗ
〇
ཌ⏕ປാ┬
Ⓨ⌧࣭⢭〇ࡋࡓ HBV ⭷⺮ⓑࢆࣉ
㯮⏣ ಇ୍
࣮ࣟࣈ࡜ࡋࡓ┦஫స⏝ᅉᏊࡢ⥙
⨶ⓗศ㞳࡟ࡼࡿ HBV ឤᰁཷᐜయ
ࡢศ㞳࣭ྠᐃ
㯮⏣ ಇ୍
ओ࣐ࢡࢩࢫࢩࣥࢺ࣮㸦௦ ࢹࢪࢱ࣭ࣝ࣍ࣟࢢࣛࣇ࢕࣮㢧ᚤ
⾲ᶵ㛵࣭ࡶࡢ࡙ࡃࡾ୰ᑠ 㙾ࢆ⏝࠸ࡓỈ࣭㣗ရศ㔝ྥࡅᚤ
௻ᴗ࣭ᑠつᶍ஦ᴗ⪅➼㐃 ⏕≀᳨ᰝ⿦⨨ࡢ㛤Ⓨ
ᦠ஦ᴗ๰㐀ಁ㐍஦ᴗᶫ
Ώࡋ◊✲஦ᴗ㸧
ዡᏛᐤ㝃㔠
㯮⏣ ಇ୍
ෆ⸨グᛕ⛉Ꮫ᣺⯆㈈ᅋ
බ┈㈈ᅋἲே ኱ᕝ᝟ሗ㏻ಙᇶ㔠
㯮⏣ ಇ୍
ඹྠ◊✲
ᒸᓥ ಇⱥ
ᅜ❧኱Ꮫἲேᒸᒣ኱Ꮫࠊ పศᏊ໬ྜ≀ࡢᵓ㐀ᒎ㛤࡟ࡼࡿ
Ꮫᰯἲே㏆␥኱Ꮫࠊබ┈ ࢡࣟࢫࢺࣜࢪ࣒࣭࢘ࢹ࢕ࣇ࢕ࢩࣝ
㈈ᅋἲேᚤ⏕≀໬Ꮫ◊
ឤᰁ⑕἞⒪⸆࡟㛵ࡍࡿ㛤Ⓨ໬ྜ
✲఍ࠊࣘ࢖࣓ࢹ࢕ࢵࢡᰴ ≀ࡢ๰ฟ
ᘧ఍♫
14,560
2,730
2,670
62,900
11,000
650
3,000
1,000
0
⏕యศᏊไᚚᏛ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Effect of methylglyoxal on multidrug-resistant Pseudomonas aeruginosa, K. Hayashi, A. Fukushima,
M. Hayashi-Nishino and K. Nishino: Front. Microbiol., 5 (2014) Airticle Number 180.
[2]Salmonella enterica serovar Typhimurium multidrug efflux pumps EmrAB and AcrEF support the
major efflux system AcrAB in decreased susceptibility to triclosan, U. Rensch, K. Nishino, G. Klein and
C. Kehrenberg: Int. J. Antimicrob. Agents, 44 (2) (2014) 179-180.
[3]Bile-mediated activation of the acrAB and tolC multidrug efflux genes occurs mainly through
transcriptional derepression of ramA in Salmonella enterica serovar Typhimurium, S. Baucheron, K.
Nishino, I. Monchaux, S. Canepa, M. C. Maurel, F. Coste, A. Roussel, A. Cloeckaert and E. Giraud: J.
Antimicrob. Chemother., 69 (9) (2014) 2400-2406.
[4]AcrB, AcrD, and MdtABC multidrug efflux systems are involved in enterobactin export in Escherichia
coli, T. Horiyama and K. Nishino: PLoS One, 9 (9) (2014) e108642.
ᅜ㝿఍㆟
[1]Structural basis for the inhibition of bacterial multidrug efflux pumps (oral), S. Yamasaki: ISIR and
INRA International Joint Symposium.
[2]Structural Analysis of the AcrAB-TolC Multidrug Efflux System (oral), K. Hayashi: ISIR and INRA
International Joint Symposium.
― 216 ―
[3]Effects of Bile Acids and Toxic Compounds on Promoter Activities of the acrAB Operon and the ramA
Gene (oral), K. Nishino: ISIR and INRA International Joint Symposium.
[4]Structural basis for the inhibition of bacterial multidrug efflux pumps (oral), S. Yamasaki: JSPS and
DAAD International Joint Symposium.
[5]Structural Analysis of the AcrAB-TolC Multidrug Efflux System (oral), K. Hayashi: JSPS and DAAD
International Joint Symposium.
[6]Rapid Detection of ESBL Producing Strains by the New Rapid Susceptibility Testing Method via
Microscopy Using a Novel Microfluidic Device (poster), Y. Matsumoto, S. Sakakihara, R. Iino, A. Yan, K.
Nishino: ICAAC2014.
[7]Regulation and Physiological Function of Bacterial Multidrug Efflux Pumps (invited), K. Nishino: The
52nd Annual Meeting of th eBiophysical Society of Japan.
[8]Rapid Detection of ESBL in Enterobacteriaceae --- Application of the New Rapid Drug-Susceptibility
Testing Method via Microscopy Using a Novel Microfluidic Device --- (poster), Y. Matsumoto, S.
Sakakihara, R. Iino, A. Yan, A. Yamaguchi, K. Nishino: The 18th SANKEN International Symposium /
The 3rd International Symposium of Nano-Macro Materials, Devices, and System Research Alliance
Project.
ゎㄝࠊ⥲ㄝ
Mechanisms of antibiotic resistance, J. Lin, K. Nishino, M. C. Roberts, M. Tolmasky, R. I. Aminov and L.
Zhang, Front. Microbiol., Frontiers Media S.A., 6 (2015), Article Number 34.
⸆๣᤼ฟࢺࣛࣥࢫ࣏࣮ࢱ࣮ࡢศᏊ⏕≀Ꮫ, ᒣᓮ⪷ྖࠊす㔝㑥ᙪ, ໬Ꮫ⒪ἲࡢ㡿ᇦ, ་⸆ࢪ࣮ࣕࢼ
ࣝ♫, 31[3] (2015), 433-439.
Functional roles of sphingosine-1-phosphate (S1P) transporter in mammals., Nishi T., Kobayashi N.,
Hisano Y., Kawahara A. and Yamaguchi A., Biochim. Biophys. Acta, Elsevier, 1841 (2014), 759-765.
㍺㏦యࡢࡼࡿࢫࣇ࢕ࣥࢦࢩࣥ㸯ࣜࣥ㓟ࡢᒁᡤ⃰ᗘไᚚᶵᵓ࡜⏕⌮ⓗᙺ๭ࡢゎ᫂, す Ẏ, ⣽⬊⛉
Ꮫ◊✲㈈ᅋຓᡂ◊✲ሗ࿌㞟, ⣽⬊⛉Ꮫ◊✲㈈ᅋ, 25 (2014), 72-80.
≉チ
[1]ࠕᅜ㝿ᡂ❧≉チࠖᢠ⳦๣, 201080033912.89999
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
す㔝 㑥ᙪ
Frontiers in Micirobiology (Antimicrobials, Resistance and Chemotherapy) (⦅㞟ḟ
㛗)
す㔝 㑥ᙪ
Journal of Infection and Chemotherapy (ㄽᩥᑂᰝဨ)
す㔝 㑥ᙪ
Journal of Antimicrobial Chemotherapy (ㄽᩥᑂᰝဨ)
す㔝 㑥ᙪ
PLoS One (ㄽᩥᑂᰝဨ)
す㔝 㑥ᙪ
Journal of Biochemistry (ㄽᩥᑂᰝဨ)
す㔝 㑥ᙪ
Institut Pasteur, Evaluation of the Head of the Research Unit in Baterial Resistance to
Antibiotics (እ㒊ホ౯ጤဨ)
ᅜෆᏛ఍
ᖹᡂ 26 ᖺᗘ⫱ᚿ㈹◊✲Ⓨ⾲఍
➨ 88 ᅇ᪥ᮏ⣽⳦Ꮫ఍⥲఍
➨ 62 ᅇ᪥ᮏ໬Ꮫ⒪ἲᏛ఍⥲఍
㝃⨨◊✲ᡤ㛫࢔ࣛ࢖࢔ࣥࢫ࡟ࡼࡿࢼࣀ࡜࣐ࢡࣟࢆࡘ࡞ࡄ≀㉁㺃ࢹࣂ࢖ࢫ㺃ࢩࢫࢸ࣒๰
ᡂᡓ␎ࣉࣟࢪ࢙ࢡࢺᖹᡂ 25 ᖺᗘᡂᯝሗ࿌఍
― 217 ―
1௳
2௳
3௳
1௳
࠸ࡕࡻ࠺⚍኱㜰኱Ꮫ⏘ᴗ⛉Ꮫ◊✲ᡤ୍⯡බ㛤
⏘◊ࢸࢡࣀࢧࣟࣥ in ࢖ࣥࢱ࣮ࣇ࢙ࢵࢡࢫࢪࣕࣃࣥ
➨ 12 ᅇḟୡ௦ࢆᢸ࠺ⱝᡭࡢࡓࡵࡢࣇ࢕ࢪ࣭࢝ࣝࣇ࢓࣮࣐ࣇ࢛࣮࣒ࣛ㸦PPF2014㸧
᪥ᮏ໬Ꮫ⒪ἲᏛ఍す᪥ᮏᨭ㒊⥲఍
➨ 43 ᅇ⸆๣⪏ᛶ⳦◊✲఍
㝃⨨◊✲ᡤ㛫࢔ࣛ࢖࢔ࣥࢫ࡟ࡼࡿࢼࣀ࡜࣐ࢡࣟࢆࡘ࡞ࡄ≀㉁㺃ࢹࣂ࢖ࢫ㺃ࢩࢫࢸ࣒๰
ᡂᡓ␎ࣉࣟࢪ࢙ࢡࢺ་⒪ᮦᩱ㺃ࢹࣂ࢖ࢫ㺃ࢩࢫࢸ࣒ࢢ࣮ࣝࣉ G3 ศ⛉఍
኱㜰኱Ꮫᅜ㝿ඹྠ◊✲ಁ㐍ࣉࣟࢢ࣒ࣛሗ࿌఍
➨ 5 ᅇࠕ⏘࡜Ꮫࢆࡘ࡞ࡄ SENRI ࡢ఍ࠖ
᪥ᮏ⮫ᗋᚤ⏕≀Ꮫ఍
⥳⮋⳦ឤᰁ⑕◊✲఍
᪥ᮏ⺮ⓑ㉁⛉Ꮫ఍
᪥ᮏ໬Ꮫ఍➨㸷㸳᫓Ꮨᖺ఍
ᮏ⸆Ꮫ఍➨ 135 ᖺ఍
ྲྀᚓᏛ఩
༤ኈ㸦⸆⛉Ꮫ㸧
ᒣᓮ ⪷ྖ
1௳
1௳
1௳
1௳
1௳
1௳
1௳
1௳
3௳
1௳
1௳
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1௳
๰⸆ࢱ࣮ࢤࢵࢺ࡜ࡋ࡚ࡢ⣽⳦␗≀᤼ฟࢺࣛࣥࢫ࣏࣮ࢱ࣮
⛉Ꮫ◊✲㈝⿵ຓ㔠
ABC ᆺࢺࣛࣥࢫ࣏࣮ࢱ࣮࡟ࡼࡿ⣽⳦⑓ཎᛶไᚚᶵᵓࡢゎ᫂
1,560
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
1,932
す㔝 㑥ᙪ
ᩥ㒊⛉Ꮫ┬
す㔝 㑥ᙪ
ᩥ㒊⛉Ꮫ┬
ዡᏛᐤ㝃㔠
ᯇᮏ ెᕭ
ᰴᘧ఍♫ࣇࢥࢡ ᢏ⾡ᮏ㒊 ᇳ⾜ᙺဨᮏ㒊㛗 ᯇ⃝ ㇏
ඹྠ◊✲
す㔝 㑥ᙪ
ሷ㔝⩏〇⸆ᰴᘧ఍♫
ᯇᮏ ెᕭ
ᰴᘧ఍♫ࣇࢥࢡ
ᯇᮏ ెᕭ
ࢣ࢖ࣞࢵࢡࢫ࣭ࢸࢡࣀࣟ
ࢪ࣮ᰴᘧ఍♫
Corinna Kehrenberg㸦ࣁࣀ
࣮ࣂ࣮኱Ꮫ㸧
Axel Cloeckaert 㸦ᅜ❧㎰
ᴗ◊✲ᡤࠊࣇࣛࣥࢫ㸧
す㔝 㑥ᙪ
す㔝 㑥ᙪ
ࢺࣛࣥࢫ࣏࣮ࢱ࣮ไᚚ࡟ࡼࡿ⣽⳦ᜏᖖᛶ⥔ᣢᶵᵓࡢゎ᫂࡜᪂つ
἞⒪ᡓ␎ࡢ㛤Ⓨ
ࢡࣜࢵࢡࢣ࣑ࢫࢺ࣮ࣜࢆ⏝࠸ࡓ⬡㉁ືែࡢ⡆౽࡞ ᐃ⣔ࡢᵓ⠏
༢఩㸸༓෇
12,220
ⱝᡭ◊✲(A)
す㔝 㑥ᙪ
ᣮᡓⓗⴌⱆ◊
✲
す Ẏ
ᇶ┙◊✲(C)
す㔝 ⨾㒔Ꮚ
ཷク◊✲
ᯇᮏ ెᕭ
㎿㏿࡞ᢠ⳦⸆ឤཷᛶ ᐃࢩࢫࢸ࣒ࡢ㛤
Ⓨ
ࢺࣛࣥࢫ࣏࣮ࢱ࣮ไᚚ࡟ࡼࡿ⣽⳦ᜏᖖ
ᛶ⥔ᣢᶵᵓࡢゎ᫂࡜᪂つ἞⒪ᡓ␎ࡢ㛤
Ⓨ
ࢺࣛࣥࢫ࣏࣮ࢱ࣮ไᚚ࡟ࡼࡿ⣽⳦ᜏᖖ
ᛶ⥔ᣢᶵᵓࡢゎ᫂࡜᪂つ἞⒪ᡓ␎ࡢ㛤
Ⓨ
࣐࢖ࢡࣟࢹࣂ࢖ࢫࢆ⏝࠸ࡓᚤ⏕≀ࣇ࢙
ࣀࢱ࢖ࣉ࢔ࢵࢭ࢖ἲ࡜ᚤ⏕≀⏤᮶⺮ⓑ
㉁ࡢ㧗ឤᗘ ᐃἲࡢ㛤Ⓨ
࣐࢖ࢡࣟࢹࣂ࢖ࢫ DSTM(Drug
Susceptibility Testing Microfluidic devise)
ࢆ⏝࠸ࡓ㎿㏿ᢠ⳦⸆ឤཷᛶ ᐃἲࡢ㛤
Ⓨ
㎿㏿࡞ᢠ⳦⸆ឤཷᛶ ᐃࢩࢫࢸ࣒ࡢ㛤
Ⓨ
ࢺࣜࢡࣟ㓟⪏ᛶᅉᏊࡢゎᯒ
⎔ቃࢩࢢࢼࣝ࡟ࡼࡿࢧࣝࣔࢿࣛ⸆๣⪏
ᛶㄏᑟ࡜ Ram ไᚚᅉᏊࡢゎᯒ
― 218 ―
1,560
9,200
743
3,000
304
2,320
0
0
0
す㔝 㑥ᙪ
ࢧࣝࣔࢿࣛከ๣᤼ฟ࣏ࣥࣉ࡟ࡼࡿ࢜࣎
ࢺࣛࣥࢫࣇ࢙ࣜࣥ⏤᮶ᢠ⳦࣌ࣉࢳࢻ⪏
ᛶᶵᵓࡢゎ᫂
ྂ⃝ ຊ㸦⌮໬Ꮫ◊✲ᡤ㸧 ኱⭠⳦㐍໬ᐇ㦂ࢆ⏝࠸ࡓᢠ⏕≀㉁⪏ᛶ
す㔝 㑥ᙪ
ᶵᵓࡢゎᯒ
す㔝 㑥ᙪ
బ⸨ ࠶ࡸࡢ㸦ᒸᒣ኱Ꮫ㸧 ࢦࣝࢪయࡢࣜ࣎ࣥᵓ㐀ᙧᡂ࡟࠾ࡅࡿࢦ
ࣝࢪࣥࢱࣥࣃࢡ㉁ࡢᶵ⬟ゎᯒ
す㔝 㑥ᙪ
ᒣᓊ ⣧୍㸦᪥ᮏ⸆⛉኱ ⸆๣᤼ฟ⣔ࢆ୰ᚰ࡜ࡋࡓ࢟ࣀࣟࣥ⪏ᛶ
Ꮫ㸧
࢔ࢩࢿࢺࣂࢡࢱ࣮ࡢ⪏ᛶᶵᵓࡢゎ᫂
す㔝 㑥ᙪ
᳃⏣ 㞝஧㸦ឡ▱Ꮫ㝔኱ ࢢ࣒ࣛ㝜ᛶ⳦ࡢᢠ⳦⸆⪏ᛶᶵᵓࡢゎᯒ
Ꮫ㸧
࡜⪏ᛶඞ᭹⸆ࡢ᥈⣴
ࡑࡢ௚ࡢ➇தⓗ◊✲㈨㔠
す㔝 㑥ᙪ
㸦⊂㸧᪥ᮏᏛ⾡᣺⯆఍
⣽⳦ከ๣⪏ᛶ໬࡟㛵୚ࡍࡿከ๣᤼ฟࢩ
ࢫࢸ࣒ࡢᵓ㐀࠾ࡼࡧᶵ⬟ࡢゎ᫂
Filip Van Immerseel㸦ࢤࣥ
ࢺ኱Ꮫ㸧
0
100
150
150
100
2,500
⏕యศᏊᶵ⬟⛉Ꮫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Statistical characterisation of single-stranded DNA motion near glass surface beyond diffusion
coefficient., Uehara S, Hanasaki I, Arai Y, Nagai T, Kawano S.: Micro and Nano Letters, 9 (2014)
257–260.
[2]Optical control of the Ca2+ concentration in a live specimen with a genetically encoded
Ca2+-releasing molecular tool., Fukuda N, Matsuda T, Nagai T.: ACS Chem Biol., 9 (2014) 1197-1203.
[3]In vivo visualization of subtle, transient and local activity of astrocytes using an ultrasensitive Ca2+
indicator., Kanemaru K, Sekiya H, Xu M, Satoh K, Kitajima N, Yoshida K, Okubo Y, Sasaki T, Moritoh S,
Hasuwa H, Mimura M, Horikawa K, Matsui K, Nagai T, Iino M, Tanaka KF.: Cell Rep., 8 (2014)
311–318.
[4]Arl3 and LC8 regulate dissociation of dynactin from dynein., Jin M, Yamada M, Arai Y, Nagai T,
Hirotsune S.: Nat Commun., 24 (2014) 5295.
[5]Ultrasensitive imaging of Ca2+ dynamics in pancreatic acinar cells of Yellow Cameleon-Nano
transgenic mice., Oshima Y, Imamura T, Shintani A, Kajiura-Kobayashi H, Hibi T, Nagai T, Nonaka S,
Nemoto T.: Int J Mol Sci., 15 (2014) 19971-19986.
[6]Nicotine exposure alters human vascular smooth muscle cell phenotype from a contractile to a
synthetic type., Yoshiyama S, Chen Z, Okagaki T, Kohama K, Nasu-Kawaharada R, Izumi T, Ohshima N,
Nagai T, Nakamura A.: Atherosclerosis., 237 (2014) 464-470.
[7]Dynamic transformations of self-assembled polymeric microspheres induced by AC voltage and shear
flow., Morimoto, N., Wazawa, T., Inoue, Y., Suzuki, M.: RSC Adv., 5 (2015) 14851-14857.
[8]Redox sensor proteins for highly sensitive direct imaging of intracellular redox state., Sugiura K,
Nagai T, Nakano M, Ichinose H, Nakabayashi T, Ohta N, Hisabori T.: Biochem Biophys Res Commun.,
457 (2015) 242-248.
[9]Lever arm extension of myosin VI is unnecessary for the adjacent binding state., Ikezaki K, Komori T,
Arai Y, Yanagida T.: BIOPHYSICS, 11 (2015) 47-53.
[10]Expanded palette of Nano-lantern for real-time muliti-color luminescence imaging., Takai A, Nakano
M, Saito K, Haruno R, Watanabe TM, Ohyanagi T, Jin T, Okada Y, Nagai T.: Proc Natl Acad Sci U S A.,
112 (2015) 4352-4356.
― 219 ―
ᅜ㝿఍㆟
[1]Cellular individualty observed by cavity enhanced light absorption microscpy. (poster), Y. Arai, T.
Yamamoto & T. Nagai: FOM2014(Forcus On Microscopy 2014).
[2]Genetically encoded photoactivatable Ca2+ indicator for hilighted imaging in arbitrary single cell.
(oral), T. Matsuda & T. Nagai: FOM2014(Forcus On Microscopy 2014).
[3]A novel photoswitchable fluorescent protein for nanoscopy. (oral), D.K. Tiwari, Y. Arai, M. Yamanaka,
K. Fujita & T. Nagai: FOM2014(Forcus On Microscopy 2014).
[4]Genetically-encoded tools to optically control and image calcium dynamics. (invited), T. Nagai: the
2014 FASEB SRC on Calcium and Cell Function.
[5]Genetically-encoded photosensitizer for light-dependent perturbation of biological function. (invited),
T. Nagai: iCeMS International Symposium: "Light Control in Cell Biology".
[6]Genetically-encoded chemiluminescent voltage indicator applicable in conjunction with multiple
optogenetic tools. (oral), S. Inagaki, T. Matsuda, Y. Arai, Y. Jinno, H. Tsutsui, Y. Okamura, T. Nagai: Next
Generation Sensor Devices for a Healthier, Safer Society International Networking Workshop.
[7]Photochromic fluorescent protein with fast on-off switching for versatile nanoscopy. (oral), T. Nagai:
IUPAB Congress 2014 (2014 International Biophysics Congress).
[8]Multi-modal superduper chemiluminescent proteins enabling multicolor functional imaging and
manipulation. (poster), K. Suzuki, Y. Arai, T. Nagai: IMC 2014(The International Microscopy Congress
2014).
[9]Expanded palette of super-duper luminescent proteins for real-time multi-color long-term imaging.
(oral), T. Nagai: Joint Meeting of the 1st Africa International Biotechnology & Biomedical Conference
and the 8th International Workshop on Approaches to Single-Cell Analysis.
[10]Expanded palette of bright luminescent proteins for real-time multi-color luminescence imaging.
(invited), T. Nagai: Janelia Conference: Fluorescent Proteins and Biological Sensors IV.
[11]Genetically-encoded chemiluminescent voltage indicator applicable in conjunction with multiple
optogenetic tools. (poster), S. Inagaki, T. Matsuda, Y. Arai, Y. Jinno, H. Tsutsui, Y. Okamura, T. Nagai:
Janelia Conference: Fluorescent Proteins and Biological Sensors IV.
[12]Genetically-encoded tools to optically control and image Ca2+ dynamics. (invited), T. Nagai: the 16th
International Conference on Retinal Proteins (ICRP2014).
[13]Bioimaging by means of engineered fluorescent/chemiluminescent proteins. (invited), T. Nagai:
Special Lecture.
[14]Luminescent Ca2+ imaging in Marchantia polymorpha. (oral), M. Iwano: Marchantia Workshop
2014.
[15]Basics of genetically-encoded fluorescent/chemiluminescentprobes. (invited), T. Nagai: 2nd AIST
International Imaging Workshop.
[16]Flow Stimulation of Hela Cells Induces Transient [Mg2+]Cyt Increase as Reported by a Novel
Genetically Encoded Mg2+ Indicator. (poster), V. P. Koldenkova, T. Matsuda, T. Nagai: The 18th
SANKEN International Symposium.
[17]A fast positive photoswitching fluorescent protein for quantitative PALM and other live cell
― 220 ―
superresolution microscopy imaging. (poster), D. K. Tiwari, Y. Arai, M. Yamanaka, T. Dertinger, K. Fujita,
T. Nagai: The 18th SANKEN International Symposium.
[18]Genetically-encoded chemiluminescent sensor for membrane voltage to monitor neuronal activity.
(invited), T. Nagai: 2nd Conference of SANKEN Core to Core, 3rd imec Handai International
Symposium (2nd Symposium of SANKEN BrainCirculation Program).
[19]Genetically-encoded tools to optically control and image Ca2+ dynamics. (invited), T. Nagai:
International Symposium on Bio-imaging and Gene Targeting Sciences in Okayama.
[20]Toward long term single molecule imaging in live cells with luminescent probes. (invited), T. Nagai:
The 15th International Membrane Research Forum.
[21]Genetically-encoded tools to optically control and image Ca2+ and Mg2+ dynamics. (invited), T.
Nagai: The 2nd International Symposium on Plant Environmental Sensing.
[22]Monitoring temperature inside a single cell with a novel genetically encoded fluorescent temperature
indicator. (poster), M. Nakano, Y. Arai, I. Kotera, T. Iwasaki, Y. Kamei & T. Nagai: Focus on Microscopy
FOM 2015.
[23]Development of a ratiometric Mg2 indicator with expanded dynamic range. (poster), T. Nagai, S.
Kawakami, T. Matsuda, M. Nakano & V.P. Koldenkova: Focus on Microscopy FOM 2015.
ゎㄝࠊ⥲ㄝ
CCD ࣓࢝ࣛࡢࢹࢵࢻࢱ࢖࣒ࢆ฼⏝ࡋࡓග่⃭ἲࡀྍ⬟࡟ࡍࡿ⺯ග࣭໬ᏛⓎග࢖࣓࣮ࢪࣥࢢ࡜࢜
ࣉࢺࢪ࢙ࢿࢸ࢕ࢡࢫࡢ㧗᫬㛫ศゎే⏝, ᪂஭⏤அࠊỌ஭೺἞, ⏕໬Ꮫ, ᪥ᮏ⏕໬Ꮫ఍, 86[2] (2014),
167-173.
ගࢫ࢖ࢵࢳࣥࢢᶵ⬟ࣉ࣮ࣟࣈ࡛ᣮࡴ⣽⬊ࡢಶᛶ, ᯇ⏣▱ᕫࠊỌ஭೺἞, ⏕యࡢ⛉Ꮫ, ་Ꮫ᭩㝔,
65[2] (2014), 101-106.
㧗㍤ᗘ໬ᏛⓎගࢱࣥࣃࢡ㉁ Nano-lantern ࡢ㛤Ⓨ, 㰻⸨೺ኴࠊỌ஭೺἞, ໬Ꮫ࡜⏕≀, ᅜ㝿ᩥ⊩♫,
52[10] (2014), 646-650.
ᅇᢡ㝈⏺ࢆ㉸࠼ࡓ㉸ゎീ⺯ග㢧ᚤ㙾, Ọ஭೺἞, ໬Ꮫ, ໬Ꮫྠே, 69 (2014), 21-26.
Genetically encoded Ca2+ indicators; expanded affinity range, color hue and compatibility with
optogenetics., T. Nagai, K. Horikawa, K. Saito, T. Matsuda, Frontiers in Neuroscience, Frontiers, 7[90]
(2014), 25.
Real-Time chemiluminescence imaging using Nano-Lantern probes., Y. Arai, T. Nagai, Current Protocols
in Chemical Biology, John Wiley & Sons, 6[4] (2014), 221-236.
Quantitative measurement of intracellular protein dynamics using photobleaching or photoactivation of
fluorescent proteins., T. Matsuda, T. Nagai, Microscopy, Oxford Journals, 63[6] (2014), 403-408.
➨ 10 ᅇ ࣉࣛࢢ࢖ࣥ࡟ࡼࡿ⮬ศᑓ⏝ゎᯒࢶ࣮ࣝࡢసᡂ㸸⮬ື㍤Ⅼ㏣㊧ࢶ࣮ࣝ PTA ࢆ౛࡟, ᪂஭
⏤அ, ⣽⬊ᕤᏛ, Ꮫ◊࣓ࢹ࢕࢝ࣝ⚽₶♫, 33 (2014), 994-1001.
Real time imaging of biological phenomena with super-duper luminescent proteins., T. Nagai,
CYTOLOGIA, The Japan Mendel Society, 80[1] (2015), 1-2.
ⴭ᭩
[1]15 ❶ ⺯ගࢱࣥࣃࢡ㉁ࡀᣅࡃ㉸ゎീᢏ⾡ (㔝ᆅ ༤⾜)“1 ศᏊࢼࣀࣂ࢖࢜ィ ”, Ọ஭೺἞ࠊᯇ⏣
― 221 ―
▱ᕫ, ໬Ꮫྠே, (190-199) 2014.
[2]㸳㸧 ImageJ ࡟ࡼࡿ⡆༢࡞⏬ീゎᯒ (ᑠᯘᚭஓࠊ㟷ᮌ୍ὒ)“ࣂ࢖࢜⏬ീゎᯒᡭ࡜ࡾ㊊࡜ࡾ࢞࢖
ࢻ”, ᪂஭ ⏤அ, ⨺ᅵ♫, (103-113) 2014.
[3]㸴㸧 ImageJ ࡟ࡼࡿ⏬ീゎᯒࣉࣟࢢ࣑ࣛࣥࢢ (ᑠᯘᚭஓࠊ㟷ᮌ୍ὒ)“ࣂ࢖࢜⏬ീゎᯒᡭ࡜ࡾ㊊
࡜ࡾ࢞࢖ࢻ”, ᪂஭ ⏤அ, ⨺ᅵ♫, (114-126) 2014.
≉チ
[1]ࠕᅜ㝿≉チฟ㢪ࠖ⺯ග⺮ⓑ㉁, PCT/JP2014/074121
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
Ọ஭ ೺἞
BIOPHYSICS (Editorial Board)
Ọ஭ ೺἞
Microscope (Editorial Board)
ᅜෆᏛ఍
᪥ᮏ㢧ᚤ㙾Ꮫ఍➨ 70 ᅇグᛕᏛ⾡ㅮ₇఍
᪥ᮏᐇ㦂ື≀⛉Ꮫᢏ⾡ࡉࡗࡱࢁ 2014
➨ 14 ᅇ᪥ᮏ⺮ⓑ㉁⛉Ꮫ఍ᖺ఍
➨ 23 ᅇ᪥ᮏࣂ࢖࢜࢖࣓࣮ࢪࣥࢢᏛ఍Ꮫ⾡㞟఍
➨㸱ᅇ ⺯ග࢖࣓࣮ࢪࣥࢢ࣭࣑ࢽࢩ࣏ࣥࢪ࣒࢘
➨ 52 ᅇ᪥ᮏ⏕≀≀⌮Ꮫ఍ᖺ఍
➨ 37 ᅇ᪥ᮏศᏊ⏕≀Ꮫ఍ᖺ఍
➨㸷ᅇ NIBB ࣂ࢖࢜࢖࣓࣮ࢪࣥࢢࣇ࢛࣮࣒ࣛ ࠕ≀⌮≉ᛶࡢ࢖࣓࣮ࢪࣥࢢࠖ
➨ 120 ᅇ᪥ᮏゎ๗Ꮫ఍⥲఍㺃඲ᅜᏛ⾡㞟఍࣭➨ 92 ᅇ᪥ᮏ⏕⌮Ꮫ఍኱఍ ྜྠ኱఍
➨ 87 ᅇ᪥ᮏ⏕໬Ꮫ఍኱఍
ྲྀᚓᏛ఩
ಟኈ㸦ᕤᏛ㸧
✄ᇉ ᡂ▴
ಟኈ㸦ᕤᏛ㸧
ᕝୖ ⚈ྖ
Ꮫኈ㸦ᕤᏛ㸧
ⰱ㇂ ⯙
Ꮫኈ㸦ᕤᏛ㸧
ୡᡞ ⰋᏊ
2௳
1௳
1௳
2௳
1௳
7௳
4௳
1௳
1௳
1௳
」ᩘࡢග㑇ఏᏛࢶ࣮ࣝ࡜ే⏝ྍ⬟࡞໬ᏛⓎග⭷㟁఩ࢭࣥࢧ࣮ࡢ㛤Ⓨ
㧗ឤᗘ⺯ග Mg2+ࢭࣥࢧ࣮ࡢ㛤Ⓨ࡜⣽⬊ෆ Mg2+ືែࡢྍど໬
ᐃ㔞ィ ࢆྍ⬟࡟ࡍࡿࣞࢩ࣓࢜ࢺࣜࢵࢡ࡞㧗ගᗘⓎග Ca2+ࢭࣥࢧ࣮ࡢ㛤Ⓨ
ࣖࢥ࢘ࢱࢣ⏤᮶Ⓨගࢱࣥࣃࢡ㉁ࡢࢡ࣮ࣟࢽࣥࢢ
⛉Ꮫ◊✲㈝⿵ຓ㔠
᪂Ꮫ⾡㡿ᇦ◊✲
㸦◊✲㡿ᇦᥦ᱌
ᆺ㸧ィ⏬◊✲
Ọ஭ ೺἞
᪂Ꮫ⾡㡿ᇦ◊✲
㸦◊✲㡿ᇦᥦ᱌
ᆺ㸧ィ⏬◊✲
Ọ஭ ೺἞
ᇶ┙◊✲(A)
Ọ஭ ೺἞
ᣮᡓⓗⴌⱆ◊✲
᪂஭ ⏤அ
ᇶ┙◊✲(C)
࿴ἑ 㕲୍
ᇶ┙◊✲(C)
ᒾ㔝 ᝴
ᑡᩘᛶ⏕≀Ꮫ࣮ಶ࡜ከᩘࡢ⊃㛫ࡀ⧊ࡾ࡞ࡍ⏕࿨⌧㇟ࡢ᥈ồ࣮
༢఩㸸༓෇
14,170
ศᏊࣉ࣮ࣟࣈ࡜ගᦤືࢶ࣮ࣝࡢ㛤Ⓨ㸫ᑡᩘ⏕యศᏊࡢྍど໬࣭
᧯సᢏ⾡㸫
54,340
ಶయ῝㒊ࡢ⏕࿨ᶵ⬟ࢆ㠀౵くⓗ࡟᧯సྍ⬟࡞ࢣ࣑࣑ࣝࣀࢪ࢙ࢿ
ࢸ࢕ࢡࢫᢏ⾡ࡢ๰ᡂ
໬ᏛⓎග࡟࠾ࡅࡿගᏛ᩿ᒙീィ 㢧ᚤ㙾ࡢ㛤Ⓨ
22,880
࿘Ἴᩘ㡿ᇦ⺯ග೫ගἲ࡟ࡼࡿ࢔ࢡࢺ࣑࢜ࢩࣥືస୰ࡢỈ࿴ᒙ⢓
ᛶኚ໬ࡢ཯ᛂ㏿ᗘㄽⓗゎᯒ
࢔ࣈࣛࢼ⛉᳜≀ࡢ࿴ྜⰼ⢊ཷᐜࢩࢫࢸ࣒ࡢゎᯒ
650
― 222 ―
650
1,690
ཷク◊✲
Ọ஭ ೺἞
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
ᯇ⏣ ▱ᕫ
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
ዡᏛᐤ㝃㔠
Ọ஭ ೺἞
ඹྠ◊✲
Ọ஭ ೺἞
ᰴᘧ఍♫࢜ࣉࢺࣛ࢖ࣥ
Ọ஭ ೺἞
Ọ஭ ೺἞
ࣃࢼࢯࢽࢵࢡᰴᘧ఍♫
Ọ஭ ೺἞
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
Ọ஭ ೺἞
⊂❧⾜ᨻἲே⌮໬Ꮫ◊
✲ᡤ
⊂❧⾜ᨻἲே⌮໬Ꮫ◊
✲ᡤ
὾ᯇ࣍ࢺࢽࢡࢫᰴᘧ఍
♫
Ọ஭ ೺἞
Ọ஭ ೺἞
21,437
13,367
୍⯡♫ᅋἲேᅜ㝿ṑ࿘ෆ⛉Ꮫ◊✲఍ ௦⾲⌮஦ ὠᓥඞṇ
ᰴᘧ఍♫ࢽࢥࣥ࢖ࣥࢫ
ࢸࢵࢡ
ᰴᘧ఍♫ࢽࢥࣥ
Ọ஭ ೺἞
࣐ࣝࢳ࣮ࣔࢲࣝⓎග࢖࣓࣮ࢪࣥࢢࢩ
ࢫࢸ࣒ࡢ㛤Ⓨ
␗≀᤼ฟࢱࣥࣃࢡ㉁ཬࡧ᤼ฟ⸆๣ࡢ
ືែゎᯒ
ࡑࡢ௚ࡢ➇தⓗ◊✲㈨㔠
Ọ஭ ೺἞
㸦⊂㸧᪥ᮏᏛ⾡᣺⯆఍
100
࢖ࣥࢥࣄ࣮ࣞࣥࢺග※ࢆ฼⏝ࡋࡓඹ
↔Ⅼ㢧ᚤ㙾ࡢ㧗ຠ⋡໬࣭ከᶵ⬟໬࡟
㛵ࡍࡿ◊✲
⏕యศᏊࡢග᧯స࡜ྍど໬ࢆྠ᫬࡟
ྍ⬟࡟ࡍࡿ㢧ᚤ㙾ࢩࢫࢸ࣒㛤Ⓨ
iPS ⣽⬊⏤᮶ศ໬ㄏᑟ⣽⬊ࡢ⸆๣స
⏝ᶵᗎࢫࢡ࣮ࣜࢽࣥࢢ⏝⺯ග࣐࣮࢝
ᮦᩱࡢసᡂ࡜ホ౯࡟㛵ࡍࡿ◊✲
㧗㍤ᗘⓎග࣭⺯ගࢱࣥࣃࢡࢆ⏝࠸ࡓ
ࢣ࣑࢝ࣝࢭࣥࢧ࡟㛵ࡍࡿ◊✲
㧗ḟ⬻ᶵ⬟᝟ሗฎ⌮ࡢ෌ᵓᡂ࡟ྥࡅ
ࡓᜍᛧグ᠈ࡢㄞࡳྲྀࡾ࡜᧯స
㑇ఏᏊⓎ⌧ࣔࢽࢱࣜࣥࢢࡢࡓࡵࡢ᪂
つ࣏࣮ࣞࢱ࣮ࡢ㛤Ⓨ
᪂つගኚ᥮⺯ගࢱࣥࣃࢡ㉁ࢆ⏝࠸ࡓ
㉸ゎീἲࡢ㛤Ⓨ
cAMP Ⓨගࣉ࣮ࣟࣈࡢᛂ⟅㏿ᗘホ౯
࠾ࡼࡧྛ✀⣽⬊࡬ࡢᛂ⏝࡟㛵ࡍࡿ◊
✲
5,896
㉸㧗ឤᗘᣦ♧⸆࡟ࡼࡿ⣽⬊ᛶ⢓⳦Ⓨ
⏕㐣⛬ࡢ᫬✵㛫࢝ࣝࢩ࣒࢘࢖࢜ࣥほ
ᐹ
1,500
0
7,584
800
9,932
0
0
0
➨ 2 ࣉࣟࢪ࢙ࢡࢺ◊✲ศ㔝㸦ឤᰁไᚚᏛ◊✲ศ㔝㸧
ཎⴭㄽᩥ
[1]Effect of methylglyoxal on multidrug-resistant Pseudomonas aeruginosa, K. Hayashi, A. Fukushima,
M. Hayashi-Nishino and K. Nishino: Front. Microbiol., 5 (2014) Airticle Number 180.
[2]Salmonella enterica serovar Typhimurium multidrug efflux pumps EmrAB and AcrEF support the
major efflux system AcrAB in decreased susceptibility to triclosan, U. Rensch, K. Nishino, G. Klein and
C. Kehrenberg: Int. J. Antimicrob. Agents, 44 (2) (2014) 179-180.
[3]Bile-mediated activation of the acrAB and tolC multidrug efflux genes occurs mainly through
transcriptional derepression of ramA in Salmonella enterica serovar Typhimurium, S. Baucheron, K.
Nishino, I. Monchaux, S. Canepa, M. C. Maurel, F. Coste, A. Roussel, A. Cloeckaert and E. Giraud: J.
Antimicrob. Chemother., 69 (9) (2014) 2400-2406.
[4]AcrB, AcrD, and MdtABC multidrug efflux systems are involved in enterobactin export in Escherichia
coli, T. Horiyama and K. Nishino: PLoS One, 9 (9) (2014) e108642.
ᅜ㝿఍㆟
[1]Structural basis for the inhibition of bacterial multidrug efflux pumps (oral), S. Yamasaki: ISIR and
INRA International Joint Symposium.
[2]Structural Analysis of the AcrAB-TolC Multidrug Efflux System (oral), K. Hayashi: ISIR and INRA
International Joint Symposium.
― 223 ―
[3]Effects of Bile Acids and Toxic Compounds on Promoter Activities of the acrAB Operon and the ramA
Gene (oral), K. Nishino: ISIR and INRA International Joint Symposium.
[4]Structural basis for the inhibition of bacterial multidrug efflux pumps (oral), S. Yamasaki: JSPS and
DAAD International Joint Symposium.
[5]Structural Analysis of the AcrAB-TolC Multidrug Efflux System (oral), K. Hayashi: JSPS and DAAD
International Joint Symposium.
[6]Rapid Detection of ESBL Producing Strains by the New Rapid Susceptibility Testing Method via
Microscopy Using a Novel Microfluidic Device (poster), Y. Matsumoto, S. Sakakihara, R. Iino, A. Yan, K.
Nishino: ICAAC2014.
[7]Regulation and Physiological Function of Bacterial Multidrug Efflux Pumps (invited), K. Nishino: The
52nd Annual Meeting of th eBiophysical Society of Japan.
[8]Rapid Detection of ESBL in Enterobacteriaceae --- Application of the New Rapid Drug-Susceptibility
Testing Method via Microscopy Using a Novel Microfluidic Device --- (poster), Y. Matsumoto, S.
Sakakihara, R. Iino, A. Yan, A. Yamaguchi, K. Nishino: The 18th SANKEN International Symposium /
The 3rd International Symposium of Nano-Macro Materials, Devices, and System Research Alliance
Project.
ゎㄝࠊ⥲ㄝ
Mechanisms of antibiotic resistance, J. Lin, K. Nishino, M. C. Roberts, M. Tolmasky, R. I. Aminov and L.
Zhang, Front. Microbiol., Frontiers Media S.A., 6 (2015), Article Number 34.
⸆๣᤼ฟࢺࣛࣥࢫ࣏࣮ࢱ࣮ࡢศᏊ⏕≀Ꮫ, ᒣᓮ⪷ྖࠊす㔝㑥ᙪ, ໬Ꮫ⒪ἲࡢ㡿ᇦ, ་⸆ࢪ࣮ࣕࢼ
ࣝ♫, 31[3] (2015), 433-439.
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
す㔝 㑥ᙪ
Frontiers in Micirobiology (Antimicrobials, Resistance and Chemotherapy) (⦅㞟ḟ
㛗)
す㔝 㑥ᙪ
Journal of Infection and Chemotherapy (ㄽᩥᑂᰝဨ)
す㔝 㑥ᙪ
Journal of Antimicrobial Chemotherapy (ㄽᩥᑂᰝဨ)
す㔝 㑥ᙪ
PLoS One (ㄽᩥᑂᰝဨ)
す㔝 㑥ᙪ
Journal of Biochemistry (ㄽᩥᑂᰝဨ)
す㔝 㑥ᙪ
Institut Pasteur, Evaluation of the Head of the Research Unit in Baterial Resistance to
Antibiotics (እ㒊ホ౯ጤဨ)
ᅜෆᏛ఍
ᖹᡂ 26 ᖺᗘ⫱ᚿ㈹◊✲Ⓨ⾲఍
➨ 88 ᅇ᪥ᮏ⣽⳦Ꮫ఍⥲఍
➨ 62 ᅇ᪥ᮏ໬Ꮫ⒪ἲᏛ఍⥲఍
㝃⨨◊✲ᡤ㛫࢔ࣛ࢖࢔ࣥࢫ࡟ࡼࡿࢼࣀ࡜࣐ࢡࣟࢆࡘ࡞ࡄ≀㉁㺃ࢹࣂ࢖ࢫ㺃ࢩࢫࢸ࣒
๰ᡂᡓ␎ࣉࣟࢪ࢙ࢡࢺᖹᡂ 25 ᖺᗘᡂᯝሗ࿌఍
࠸ࡕࡻ࠺⚍኱㜰኱Ꮫ⏘ᴗ⛉Ꮫ◊✲ᡤ୍⯡බ㛤
⏘◊ࢸࢡࣀࢧࣟࣥ in ࢖ࣥࢱ࣮ࣇ࢙ࢵࢡࢫࢪࣕࣃࣥ
➨ 12 ᅇḟୡ௦ࢆᢸ࠺ⱝᡭࡢࡓࡵࡢࣇ࢕ࢪ࣭࢝ࣝࣇ࢓࣮࣐ࣇ࢛࣮࣒ࣛ㸦PPF2014㸧
᪥ᮏ໬Ꮫ⒪ἲᏛ఍す᪥ᮏᨭ㒊⥲఍
➨ 43 ᅇ⸆๣⪏ᛶ⳦◊✲఍
㝃⨨◊✲ᡤ㛫࢔ࣛ࢖࢔ࣥࢫ࡟ࡼࡿࢼࣀ࡜࣐ࢡࣟࢆࡘ࡞ࡄ≀㉁㺃ࢹࣂ࢖ࢫ㺃ࢩࢫࢸ࣒
๰ᡂᡓ␎ࣉࣟࢪ࢙ࢡࢺ་⒪ᮦᩱ㺃ࢹࣂ࢖ࢫ㺃ࢩࢫࢸ࣒ࢢ࣮ࣝࣉ G3 ศ⛉఍
኱㜰኱Ꮫᅜ㝿ඹྠ◊✲ಁ㐍ࣉࣟࢢ࣒ࣛሗ࿌఍
➨ 5 ᅇࠕ⏘࡜Ꮫࢆࡘ࡞ࡄ SENRI ࡢ఍ࠖ
― 224 ―
1௳
2௳
3௳
1௳
1௳
1௳
1௳
1௳
1௳
1௳
1௳
1௳
᪥ᮏ⮫ᗋᚤ⏕≀Ꮫ఍
⥳⮋⳦ឤᰁ⑕◊✲఍
᪥ᮏ⺮ⓑ㉁⛉Ꮫ఍
ྲྀᚓᏛ఩
༤ኈ㸦⸆⛉Ꮫ㸧
ᒣᓮ ⪷ྖ
3௳
1௳
1௳
๰⸆ࢱ࣮ࢤࢵࢺ࡜ࡋ࡚ࡢ⣽⳦␗≀᤼ฟࢺࣛࣥࢫ࣏࣮ࢱ࣮
⛉Ꮫ◊✲㈝⿵ຓ㔠
ⱝᡭ◊✲(A)
す㔝 㑥ᙪ
ᇶ┙◊✲(C)
す㔝 ⨾㒔Ꮚ
ཷク◊✲
ᯇᮏ ెᕭ
ࢺࣛࣥࢫ࣏࣮ࢱ࣮ไᚚ࡟ࡼࡿ⣽⳦ᜏᖖᛶ⥔ᣢᶵᵓࡢゎ᫂࡜᪂つ
἞⒪ᡓ␎ࡢ㛤Ⓨ
ABC ᆺࢺࣛࣥࢫ࣏࣮ࢱ࣮࡟ࡼࡿ⣽⳦⑓ཎᛶไᚚᶵᵓࡢゎ᫂
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
す㔝 㑥ᙪ
ᩥ㒊⛉Ꮫ┬
す㔝 㑥ᙪ
ᩥ㒊⛉Ꮫ┬
ዡᏛᐤ㝃㔠
ᯇᮏ ెᕭ
ඹྠ◊✲
す㔝 㑥ᙪ
ሷ㔝⩏〇⸆ᰴᘧ఍♫
ᯇᮏ ెᕭ
ᰴᘧ఍♫ࣇࢥࢡ
ᯇᮏ ెᕭ
ࢣ࢖ࣞࢵࢡࢫ࣭ࢸࢡࣀࣟ
ࢪ࣮ᰴᘧ఍♫
Corinna Kehrenberg㸦ࣁࣀ
࣮ࣂ࣮኱Ꮫ㸧
Axel Cloeckaert 㸦ᅜ❧㎰
ᴗ◊✲ᡤࠊࣇࣛࣥࢫ㸧
Filip Van Immerseel㸦ࢤࣥ
ࢺ኱Ꮫ㸧
す㔝 㑥ᙪ
す㔝 㑥ᙪ
㎿㏿࡞ᢠ⳦⸆ឤཷᛶ ᐃࢩࢫࢸ࣒ࡢ
㛤Ⓨ
ࢺࣛࣥࢫ࣏࣮ࢱ࣮ไᚚ࡟ࡼࡿ⣽⳦ᜏ
ᖖᛶ⥔ᣢᶵᵓࡢゎ᫂࡜᪂つ἞⒪ᡓ␎
ࡢ㛤Ⓨ
ࢺࣛࣥࢫ࣏࣮ࢱ࣮ไᚚ࡟ࡼࡿ⣽⳦ᜏ
ᖖᛶ⥔ᣢᶵᵓࡢゎ᫂࡜᪂つ἞⒪ᡓ␎
ࡢ㛤Ⓨ
ᰴᘧ఍♫ࣇࢥࢡ ᢏ⾡ᮏ㒊 ᇳ⾜ᙺဨᮏ㒊㛗 ᯇ⃝ ㇏
࣐࢖ࢡࣟࢹࣂ࢖ࢫࢆ⏝࠸ࡓᚤ⏕≀ࣇ
࢙ࣀࢱ࢖ࣉ࢔ࢵࢭ࢖ἲ࡜ᚤ⏕≀⏤᮶
⺮ⓑ㉁ࡢ㧗ឤᗘ ᐃἲࡢ㛤Ⓨ
࣐࢖ࢡࣟࢹࣂ࢖ࢫ DSTM(Drug
Susceptibility Testing Microfluidic
devise)ࢆ⏝࠸ࡓ㎿㏿ᢠ⳦⸆ឤཷᛶ ᐃἲࡢ㛤Ⓨ
㎿㏿࡞ᢠ⳦⸆ឤཷᛶ ᐃࢩࢫࢸ࣒ࡢ
㛤Ⓨ
ࢺࣜࢡࣟ㓟⪏ᛶᅉᏊࡢゎᯒ
⎔ቃࢩࢢࢼࣝ࡟ࡼࡿࢧࣝࣔࢿࣛ⸆๣
⪏ᛶㄏᑟ࡜ Ram ไᚚᅉᏊࡢゎᯒ
す㔝 㑥ᙪ
ࢧࣝࣔࢿࣛከ๣᤼ฟ࣏ࣥࣉ࡟ࡼࡿ࢜
࣎ࢺࣛࣥࢫࣇ࢙ࣜࣥ⏤᮶ᢠ⳦࣌ࣉࢳ
ࢻ⪏ᛶᶵᵓࡢゎ᫂
ྂ⃝ ຊ㸦⌮໬Ꮫ◊✲ᡤ㸧 ኱⭠⳦㐍໬ᐇ㦂ࢆ⏝࠸ࡓᢠ⏕≀㉁⪏
す㔝 㑥ᙪ
ᛶᶵᵓࡢゎᯒ
す㔝 㑥ᙪ
బ⸨ ࠶ࡸࡢ㸦ᒸᒣ኱Ꮫ㸧 ࢦࣝࢪయࡢࣜ࣎ࣥᵓ㐀ᙧᡂ࡟࠾ࡅࡿ
ࢦࣝࢪࣥࢱࣥࣃࢡ㉁ࡢᶵ⬟ゎᯒ
す㔝 㑥ᙪ
ᒣᓊ ⣧୍㸦᪥ᮏ⸆⛉኱ ⸆๣᤼ฟ⣔ࢆ୰ᚰ࡜ࡋࡓ࢟ࣀࣟࣥ⪏
Ꮫ㸧
ᛶ࢔ࢩࢿࢺࣂࢡࢱ࣮ࡢ⪏ᛶᶵᵓࡢゎ
᫂
᳃⏣ 㞝஧㸦ឡ▱Ꮫ㝔኱ ࢢ࣒ࣛ㝜ᛶ⳦ࡢᢠ⳦⸆⪏ᛶᶵᵓࡢゎ
す㔝 㑥ᙪ
Ꮫ㸧
ᯒ࡜⪏ᛶඞ᭹⸆ࡢ᥈⣴
ࡑࡢ௚ࡢ➇தⓗ◊✲㈨㔠
す㔝 㑥ᙪ
㸦⊂㸧᪥ᮏᏛ⾡᣺⯆఍
⣽⳦ከ๣⪏ᛶ໬࡟㛵୚ࡍࡿከ๣᤼ฟ
ࢩࢫࢸ࣒ࡢᵓ㐀࠾ࡼࡧᶵ⬟ࡢゎ᫂
― 225 ―
༢఩㸸༓෇
12,220
1,560
1,932
9,200
743
3,000
304
2,320
0
0
0
0
100
150
150
100
2,500
➨ 2 ࣉࣟࢪ࢙ࢡࢺ◊✲ศ㔝㸦ᴟᚤᮦᩱࣉࣟࢭࢫ◊✲ศ㔝㸧
ཎⴭㄽᩥ
[1]A flux induced crystal phase transition in the vapor-liquid-solid growth of indium-tin oxide nanowires,
G. Meng, T. Yanagida, H. Yoshida, K. Nagashima, M. Kanai, F. W. Zhuge, Y. He, S. Takeda and T.
Kawai: Nanoscale, 6 (2014) 7033-7038.
[2]Ultrafast and Wide Range Analysis of DNA Molecules Using Rigid Network Structure of Solid
Nanowires, T. Yanagida, K. Nagashima, M. Kanai, G. Meng, Y. He, F. W. Zhuge and T. Kawai: Sci. Rep.,
4 (2014) 5252.
[3]Cellulose Nanofiber Paper as an Ultra Flexible Nonvolatile Memory, K. Nagashima, H. Koga, F. W.
Zhuge, M. Kanai, G. Meng, Y. He, M. Nogi and T. Yanagida: Sci. Rep., 4 (2014) 5532.
[4]Nanoscale Size-Selective Deposition of Nanowires by Micrometer Scale Hydrophilic Patterns, Y. He,
K. Nagashima, M. Kanai, G. Meng, F. W. Zhuge, T. Kawai and T. Yanagida: Sci. Rep., 4 (2014) 5943.
[5]Modulation of Thermoelectric Power Factor via Radial Dopant Inhomogeneity in B-doped Si
Nanowires, F. W. Zhuge, T. Yanagida, M. Kanai, K. Nagashima, G. Meng, Y. He and T. Kawai: J. Am.
Chem. Soc., 136 (2014) 14100-14106.
ᅜ㝿఍㆟
[1]Cellulose Nanofiber Paper as an Ultra Flexible Nonvolatile Memory (poster), K. Nagashima, H. Koga,
F. W. Zhuge, M. Kanai, G. Meng, Y. He, M. Nogi and T. Yanagida: 2014 MRS Fall Meeting.
[2]Nanoscale Size-Selective Assembly of Nanowires by Micrometer Scale Hydrophilic Patterns (poster),
Y. He, K. Nagashima, M. Kanai, G. Meng, F. W. Zhuge, T. Kawai and T. Yanagida: 2014 MRS Fall
Meeting.
[3]Composition and Crystal Phase Engineering of VLS Nanowires: Impact of Element Nucleation
Competitions at Liquid-Solid Interface (poster), G. Meng, K. Nagashima, H. Yoshida, M. Kanai, F. W.
Zhuge, Y. He, S. Takeda, T. Kawai and T. Yanagida: 2014 MRS Fall Meeting.
[4]Fundamental Design Rule for Nanowire Alignment on Water Favorable Pattern (poster), Y. He, K.
Nagashima, M. Kanai, G. Meng, F. W. Zhuge, T. Kawai and T. Yanagida: 2014 MRS Fall Meeting.
[5]Modulating Transport Properties in B-Doped Si Nanowires via Rationally Designed Dopant
Inhomogeneity and Its Application in Thermoelectrics (oral), F. W. Zhuge, M. Kanai, K. Nagashima, G.
Meng, Y. He, T. Kawai and T. Yanagida: 2014 MRS Fall Meeting.
[6]Modulation of Thermoelectric Power Factor via Radial Dopant Inhomogeneity in B-Doped Si
Nanowires (oral), F. W. Zhuge, M. Kanai, K. Nagashima, G. Meng, Y. He, T. Kawai and T. Yanagida:
2014 MRS Fall Meeting.
[7]Doping in VLS Metal Oxide Nanowires: Manipulation of Conductivity and Crystal Phase (oral), G.
Meng, K. Nagashima, M. Kanai, H. Yoshida, F. W. Zhuge, Y. He, S. Takeda, T. Kawai and T. Yanagida:
2014 MRS Fall Meeting.
≉チ
[1]ࠕᅜෆ≉チฟ㢪ࠖ㔠ᒓ㓟໬≀༙ᑟయࢭࣥࢧࠊ࠾ࡼࡧࠊࡑࡢ〇㐀᪉ἲ, ≉㢪 2014-242191
ᅜෆᏛ఍
ᛂ⏝≀⌮Ꮫ఍
⛉Ꮫ◊✲㈝⿵ຓ㔠
᪂Ꮫ⾡㡿ᇦ◊✲
6௳
ࢼࣀᵓ㐀᝟ሗ࡟ᇶ࡙ࡃ༢⤖ᬗ㓟໬≀ࢼࣀ࣡࢖ࣖࡢᮦᩱ๰〇
― 226 ―
༢఩㸸༓෇
2,860
㸦◊✲㡿ᇦᥦ᱌
ᆺ㸧බເ◊✲
ᰗ⏣ ๛
᪂Ꮫ⾡㡿ᇦ◊✲ ࣊ࢸࣟࢼࣀ࣡࢖ࣖࢆ⏝࠸ࡓศᏊ⣲Ꮚ
㸦◊✲㡿ᇦᥦ᱌
ᆺ㸧බເ◊✲
ᰗ⏣ ๛
ᣮᡓⓗⴌⱆ◊✲ ⮬ᕫ⤌⧊໬㓟໬≀㸯ḟඖࢼࣀᵓ㐀య࡟ࡼࡿ㓟໬㑏ඖࢼࣀࢫࢣ࣮
㛗ᓥ ୍ᶞ
ࣝࢫ࢖ࢵࢳࣥࢢ⣲Ꮚࡢ๰ᡂ
ⱝᡭ◊✲(A)
㓟໬≀ࢼࣀᶵ⬟≀ᛶࡢᢳฟࢆ┠ᣦࡋࡓ⤯⦕ᛶ༢⤖ᬗ㓟໬≀ࢼࣀ
㛗ᓥ ୍ᶞ
࣡࢖ࣖࡢ๰ᡂ
ཷク◊✲
ᰗ⏣ ๛
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ 㓟໬≀ࢳࣕࢿࣝ࡜ࢼࣀ⇕⟶⌮ᕤᏛ࡟ࡼ
ࡿᴟᑠ࢚ࢿࣝࢠ࣮࣭ከᶵ⬟ࢭࣥࢧࡢ๰
〇
ዡᏛᐤ㝃㔠
ᰗ⏣ ๛
බ┈㈈ᅋἲே᪫◪Ꮚ㈈ᅋ ⌮஦㛗 ⏣୰㚩஧
୍⯡㈈ᅋἲேࢸࣞࢥ࣒ඛ➃ᢏ⾡◊✲ᨭ᥼ࢭࣥࢱ࣮ ఍㛗 Ᏻ⏣㟹
ᰗ⏣ ๛
ᙪ
ඹྠ◊✲
ᰗ⏣ ๛
ࣃࢼࢯࢽࢵࢡᰴᘧ఍♫
ࠕ๰࣭⵳࣭┬࢚ࢿࢹࣂ࢖ࢫ⏕⏘ᢏ⾡ࠖ
ඹྠ◊✲ㅮᗙ࡟ಀࡿᏛෆண⟬㓄ศ㸦ᕤ
ࡼࡾ㸧
ࣃࢼࢯࢽࢵࢡᰴᘧ఍♫
ᾮ┦ྜᡂࢼࣀ࣡࢖ࣖࢆ⏝࠸ࡓࣉࣟࢸ࢖
ᰗ⏣ ๛
ࣥ࢔ࣞ࢖ࡢ㛤Ⓨ
2,990
1,560
3,510
25,220
2,000
500
500
905
➨ 2 ࣉࣟࢪ࢙ࢡࢺ◊✲ศ㔝㸦ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ᮦᩱ◊✲ศ㔝㸧
ཎⴭㄽᩥ
[1]Cellulose nanofiber paper as an ultra flexible nonvolatile memory, K. Nagashima, H. Koga, U. Celano,
F. Zhuge, M. Kanai, S. Rahong, G. Meng, Y. He, J. D. Boeck, M. Jurczak, W. Vandervorst, T. Kitaoka, M.
Nogi, T. Yanagida: Sci. Rep., 4 (2014) 5532.
[2]Nanofibrillar chitin aerogels as renewable base catalysts, Y. Tsutsumi, H. Koga, Z.-D. Qi, T. Saito, A.
Isogai: Biomacromolecules, 15 (11) (2014) 4314-4319.
[3]Silver nanowire electrodes: Conductivity improvement without post-treatment and application in
capacitive pressure sensors, J. Wang, J. Jiu, T. Araki, M. Nogi, T. Sugahara, S. Nagao, H. Koga, P. He, K.
Suganuma: Nano-Micro Lett., 7 (1) (2015) 51-58.
[4]A Miniaturized flexible antenna printed on high dielectric constant nanopaper composite, T. Inui, H.
Koga, M. Nogi, N. Komoda, K. Suganuma: Adv. Mater., 27 (6) (2015) 1112-1116.
[5]The role of Zn precipitates and Cl㸫 anions in pitting corrosion of Sn-Zn solder alloys, J.-C. Liu, S. W.
Park, S. Nagao, H. Koga, M. Nogi, J.-S. Ma, G. Zhang, K. Suganuma: Corros. Sci., 92 (2015) 263-271.
[6]Sol-gel-derived high-performance stacked transparent conductive oxide thin films, T. Sugahara, Y.
Hirose, S. Cong, H. Koga, J. Jiu, M. Nogi, S. Nagao, K. Suganuma: J. Am. Ceram. Sci., 97 (10) (2014)
3238-3243.
[7]Highly sensitive and flexible pressure sensor based on silver nanowires filled elastomeric interlayer
and silver nanowires electrodes, J. Wang, J. Jiu, M. Nogi, T. Sugahara, S. Nagao, H. Koga, P. He,K.
Suganuma: Nanoscale, 7 (2015) 2926-2932.
[8]Facile identification of the critical content of multi-layer graphene oxide for epoxy composite with the
― 227 ―
optimal thermal properties, T. Zhou,S. Nagao, T. Sugahara, H. Koga, M. Nogi, K. Suganuma, T. T. Nge, Y.
Nishina: RSC Adv., 5 (2015) 20376-20385.
[9]The effect of light and humidity on the stability of silver nanowire transparent electrodes, J. Jiu, J.
Wang, T. Sugahara, S. Nagao, M. Nogi, H. Koga, K. Suganuma, M. Hara, E. Nakazawa, H. Uchida: RSC
Adv., 5 (2015) 27657-27664.
ᅜ㝿఍㆟
[1]Uniform coating of conductive nanomaterials on cellulose nanofiber paper through a Papermaking
Process (oral), H. Koga, M. Nogi, K. Suganuma: 6th Asian Coating Workshop (ACW2014), Kobe, Japan,
May 8-9 (2014).
[2]Synthesis and application of silver nanowires (oral), J. Jiu, T. Araki, J. Wang, M. Nogi, T. Sugahara, S.
Nagao, H. Koga, K. Suganuma, E. Nakazawa, M. Hara, H. Uchida: 1st International Conference on
Polyol Mediated Synthesis (IC-PMS), Paris, France, June 22-25 (2014).
[3]High-Dielectric Paper Composite Consisting of Cellulose Nanofiber and Silver Nanowire (oral), T.
Inui, H. Koga, M. Nogi, N. Komoda, K. Suganuma: IEEE NANO 2014, Toronto, Canada, August 18-21
(2014).
[4]Silver Nanowire: Synthesis, Conductivity Improvement and Application to Pressure Sensor (oral), J.
Wang, T. Araki, J. Jiu, T. Sugahara, M. Nogi, S. Nagao, H. Koga, K. Suganuma: IEEE NANO 2014,
Toronto, Canada, August 18-21 (2014).
[5]Printed silver nanowires track by laser process (oral), T. Araki, R. Mandamparambil, I. Yakimets, J.
Brand, M. Nogi, H. Koga, J. Jiu, T. Sekitani, K. Suganuma: ICFPE 2014 (5th International Conference on
Flexible and Printed Electronics), Beijing, China, October 21-23 (2014).
[6]Thermal stability of optical transparency in cellulose nanopaper using chemical nanofibrillated
cellulose nanofibers (poster), H. Yagyu, T. Wu, M.-C. Hsieh, H. Koga, M. Nogi: ICFPE 2014 (5th
International Conference on Flexible and Printed Electronics), Beijing, China, October 21-23 (2014).
[7]Transparent electrodes printed on transparent nanopaper (poster), A. Tanaka, M. Nogi, H. Yagyu, T.
Horie, M.-C. Hsieh, H. Koga, K. Suganuma: ICFPE 2014 (5th International Conference on Flexible and
Printed Electronics), Beijing, China, October 21-23 (2014).
[8]Paper-based supercapacitor electrodes prepared by a papermaking technique (oral), : ICFPE 2014 (5th
International Conference on Flexible and Printed Electronics), Beijing, China, October 21-23 (2014).
[9]Highly heat-resistant bio-based nanofiber substrate for flexible electronics (oral), M.-C. Hsieh, H.
Koga, M. Nogi, K. Suganuma: CPMT Symposium Japan (ICSJ), Kyoto, Japan, November 4-6 (2014).
[10]Cellulose Nanofiber Paper as an Ultra Flexible Nonvolatile Memory (oral), K. Nagashima, H. Koga,
U. Celano, F. W. Zhuge, M. Kanai, S. Rahong, G. Meng, Y. He, J. D. Boeck, M. Jurczak, W. Vandervorst,
T. Kitaoka, M. Nogi, T. Yanagida: 2014 MRS Fall Meeting & Exhibit, Boston, USA, November
30-December 5 (2014).
[11]Flexible Paper Electronics Based on Cellulose Nanofiber Paper (invited), H. Koga, M. Nogi, K.
Suganuma: IDW'14, Niigata, Japan, December 3-5 (2014).
[12]High-speed photo-reduction of graphene oxide for paper-based flexible supercapacitor (poster), H.
Tonomura, H. Koga, Y. Nishina, M. Nogi, K. Suganuma: The 18th SANKEN International Symposium
2014, Osaka, Japan, December 10-11 (2014).
― 228 ―
[13]Non-contact printing of silver nanowires for stretchable/ transparent electrodes (oral), T. Araki, R.
Mandamparambil, I. Yakimets, J. Brand, M. Nogi, H. Koga, J. Jiu, T. Sekitani, K. Suganuma: LOPEC,
Munich, Germany, March 3-5 (2015).
[14]Flexible Paper Electronics Prepared by using a Papermaking Technique (oral), H. Koga, M. Nogi:
IAWPS2015, Tokyo, March 15-17 (2015).
[15]Small and Flexible Nanopaper Antenna for Wearable Electronics (oral), T. Inui, H. Koga, M. Nogi, K.
Suganuma: IAWPS2015, Tokyo, March 15-17 (2015).
ゎㄝࠊ⥲ㄝ
Ⰽᮦࢧࣟࣥ ኱Ꮫ࣭◊✲ᡤࡵࡄࡾ, ⬟ᮌ㞞ஓ, Ⰽᮦ༠఍ㄅ, Ⰽᮦ༠఍, 87[5] (2014), 183-184.
㏱᫂ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ࣇ࢕࣒ࣝ࡞ࡽࡧ࡟㟁Ꮚࢹࣂ࢖ࢫ࡬ࡢᛂ⏝, ⬟ᮌ㞞ஓࠊྂ㈡኱ᑦ,
࢜ࣉࢺࢽ࣮ࣗࢬ, ග⏘ᴗᢏ⾡᣺⯆఍, 9[1] (2014), 9-12.
㟁Ẽࢆὶࡍ㏱᫂࡞⣬, ྂ㈡኱ᑦࠊ⬟ᮌ㞞ஓ, Cellulose Communications, ࢭ࣮ࣝࣟࢫᏛ఍, 21[3]
(2014), 112-116.
㏱᫂࡞⣬࡟ࢹࣂ࢖ࢫࢆᦚ㍕ࡍࡿ᪉ἲ, ⬟ᮌ㞞ஓ, ໬Ꮫᕤᴗ, ໬Ꮫᕤᴗ♫, 9 (2014), 65-70.
࢚ࣞࢡࢺࣟࢽࢡࢫศ㔝࡛ࡢࢭ࣮ࣝࣟࢫࢼࣀ࣮࣌ࣃ࣮ࡢᛂ⏝◊✲, ⬟ᮌ㞞ஓ, ᕤᴗᮦᩱ, ᪥หᕤᴗ
᪂⪺♫, 10 (2014), 35-39.
Chemically-Modified Cellulose Paper as a Microstructured Catalytic Reactor, H. Koga, T. Kitaoka, A.
Isogai, molecules, MDPI AG, 20[1] (2015), 1495-1508.
ᢒ⣬ᢏ⾡ࡢᛂ⏝࡟ࡼࡿ࣮࣌ࣃ࣮㟁Ꮚࢹࣂ࢖ࢫࡢ๰〇, ྂ㈡኱ᑦࠊ⬟ᮌ㞞ஓ, ᶵ⬟⣬◊✲఍ㄅ, ᶵ
⬟⣬◊✲఍, 53 (2015), 39-44.
ⴭ᭩
[1]㖟ࢼࣀ࣡࢖ࣖ㏱᫂ᑟ㟁⭷ “ࣉࣜࣥࢸࢵࢻ࢚ࣞࢡࢺࣟࢽࢡࢫ⏝ᑟ㟁ᛶ(ࢼࣀ)࢖ࣥࢡࡢタィ࣭㛤Ⓨ
࡜ࣉࣟࢭࢫ᭱㐺໬”, ྂ㈡኱ᑦࠊ⬟ᮌ㞞ஓࠊⳢ἟ඞ᫛, ࢧ࢖࢚ࣥࢫ㸤ࢸࢡࣀࣟࢪ࣮, (➨ 8 ❶) 2014.
[2]ࣉࣛࢫࢳࢵࢡࢆ⏝࠸࡞࠸㏱᫂ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ᇶᯈ “ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ࡢ
ㄪ〇ࠊศᩓ࣭」ྜ໬࡜〇ရᛂ⏝”, ⬟ᮌ㞞ஓࠊྂ㈡኱ᑦ, ᢏ⾡᝟ሗ༠఍, (➨ 7 ❶࣭2 ⠇) 2014.
[3]ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮࡜㔠ᒓゐ፹ࡢ⼥ྜ࣐ࢸࣜ࢔ࣝ “ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ࡢㄪ〇ࠊ
ศᩓ࣭」ྜ໬࡜〇ရᛂ⏝”, ྂ㈡኱ᑦࠊ໭ᒸ༟ஓ, ᢏ⾡᝟ሗ༠఍, (➨ 7 ❶࣭10 ⠇) 2014.
[4]ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮࡜㖟ࢼࣀ࣡࢖࡛ࣖࡘࡃࡿ㏱᫂ᑟ㟁⣬ “ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮
ࡢㄪ〇ࠊศᩓ࣭」ྜ໬࡜〇ရᛂ⏝”, ྂ㈡኱ᑦࠊ⬟ᮌ㞞ஓ, ᢏ⾡᝟ሗ༠఍, (➨ 7 ❶࣭16 ⠇) 2014.
[5]ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮࡜࣮࢝࣎ࣥࢼࣀࢳ࣮ࣗࣈ࠿ࡽ࡞ࡿࣉࣜࣥࢱࣈࣝ㏱᫂ᑟ㟁ࢼࣀࢥࣥ
࣏ࢪࢵࢺ “ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ࡢㄪ〇ࠊศᩓ࣭」ྜ໬࡜〇ရᛂ⏝”, ྂ㈡኱ᑦࠊ㰻⸨⥅அࠊ
☾㈅᫂, ᢏ⾡᝟ሗ༠఍, (➨ 7 ❶࣭17 ⠇) 2014.
[6]ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ᇶᯈࢆ⏝࠸ࡓᢡࡾ␚ࡳྍ⬟࡞༳ๅ࢔ࣥࢸࢼ “ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓
࢖ࣂ࣮ࡢㄪ〇ࠊศᩓ࣭」ྜ໬࡜〇ရᛂ⏝”, ⬟ᮌ㞞ஓࠊྂ㈡኱ᑦ, ᢏ⾡᝟ሗ༠఍, (➨ 7 ❶࣭18 ⠇) 2014.
[7]ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ᇶᯈࢆ⏝࠸ࡓ༳ๅ㟁Ẽ㓄⥺ “ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ࡢㄪ〇ࠊ
ศᩓ࣭」ྜ໬࡜〇ရᛂ⏝”, ⬟ᮌ㞞ஓࠊྂ㈡኱ᑦ, ᢏ⾡᝟ሗ༠఍, (➨ 7 ❶࣭19 ⠇) 2014.
[8]㏱᫂ࢼࣀ࣮࣌ࣃ࣮㸸ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ࢆ⏝࠸ࡓ㏱᫂ࣇ࢕࣒ࣝ “㏱᫂ᶞ⬡࣭ࣇ࢕࣒ࣝ
― 229 ―
࡬ࡢᶵ⬟ᛶ௜୚࡜ᛂ⏝ᢏ⾡”, ⬟ᮌ㞞ஓ, ᢏ⾡᝟ሗ༠఍, (➨ 1 ❶࣭23 ⠇) 2014.
[9]ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ࢆ⏝࠸ࡓప⇕⭾ᙇᛶ㏱᫂ᮦᩱ (㇂ᑿᐉஂ)“㏱࣏࣐࣮᫂ࣜࡢᮦᩱ㛤
Ⓨ࡜㧗ᛶ⬟໬”, ⬟ᮌ㞞ஓ, ࢩ࣮࢚࣒ࢩ࣮ฟ∧, (➨ 2 ⦅࣭8 ❶) 2014.
≉チ
[1]ࠕᅜෆ≉チฟ㢪ࠖᑟ㟁ᛶ⧄⥔ࡢ〇㐀᪉ἲࠊࢩ࣮ࢺ≧㟁ᴟࡢ〇㐀᪉ἲࠊᑟ㟁ᛶ⧄⥔ࠊཬࡧࢩ࣮
ࢺ≧㟁ᴟ, ≉㢪 2014-106142
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
ྂ㈡ ኱ᑦ
International Symposium on Wood Science and Technology 2015 (ᐇ⾜ጤဨ)
ᅜෆᏛ఍
ࢭ࣮ࣝࣟࢫᏛ఍➨ 21 ᅇᖺḟ኱఍
3௳
1௳
➨ 53 ᅇᶵ⬟⣬◊✲Ⓨ⾲࣭ㅮ₇఍
1௳
➨ 65 ᅇ᪥ᮏᮌᮦᏛ఍
⛉Ꮫ◊✲㈝⿵ຓ㔠
༢఩㸸༓෇
ᇶ┙◊✲(A)
ኚ᥮ຠ⋡᭱኱໬࡟ྥࡅࡓ࣮࣌ࣃ࣮ኴ㝧㟁ụࡢ෌ᵓ⠏
17,810
⬟ᮌ 㞞ஓ
ᇶ┙◊✲(S)
ࢭ࣮ࣝࣟࢫࢼࣀ࣮࣌ࣃ࣮ࢆ⏝࠸ࡓ୙᥹Ⓨᛶ࣓ࣔࣜࡢ๰〇
54,600
⬟ᮌ 㞞ஓ
ᣮᡓⓗⴌⱆ◊
ḟୡ௦≀㉁ኚ᥮࡟ྥࡅࡓࣉࣜࣥࢸࢵࢻ࣭࣮࣌ࣃ࣮ࣜ࢔ࢡࢱ࣮ࡢ
2,210
✲
๰ฟ
ྂ㈡ ኱ᑦ
ዡᏛᐤ㝃㔠
⬟ᮌ 㞞ஓ
බ┈㈈ᅋἲே ᮧ⏣Ꮫ⾡᣺⯆㈈ᅋ ⌮஦㛗 ᮧ⏣ᜏኵ
2,421
ඹྠ◊✲
⬟ᮌ 㞞ஓ
ᰴᘧ఍♫࢔ࣝࣅ࢜ࣥ
ࢭ࣮ࣝࣟࢫࢼࣀࣇ࢓࢖ࣂ࣮ࡢ໬⢝ရ
833
࡬ࡢᛂ⏝໬◊✲
➨ 3 ࣉࣟࢪ࢙ࢡࢺ◊✲ศ㔝㸦⏕య㜵ᚚᏛ◊✲ศ㔝㸧
ཎⴭㄽᩥ
[1]Molecular and physiological functions of sphingosine 1-phosphate transporters, T. Nishi, N. Kobayashi,
Y. Hisano, A. Kawahara, A. Yamaguchi: Biochimica et Biophisica Acta (BBA) -Molecular and Cell
Biology of Lipids, 1841 (5) (2014) 759-765.
[2]ȕ-Lactam Selectivity of Multidrug Transporters AcrB and AcrD Resides in the Proximal Binding
Pocket, N. Kobayashi, N. Tamura, HW. van Veen, A. Yamaguchi, S. Murakami: The Journal of Biological
Chemistry, 289 (15) (2014) 10680-10690.
ゎㄝࠊ⥲ㄝ
␗≀᤼ฟ㍺㏦, ୰ᓥⰋ௓ࠊḈ஭ၨ௓ࠊᒣཱྀ᫂ே, ᐇ㦂་Ꮫቑหྕ ᵓ㐀⏕࿨⛉Ꮫ࡛ఱࡀࢃ࠿ࡿࡢ࠿㸪
ఱࡀ࡛ࡁࡿࡢ࠿, ⨺ᅵ♫, 132[10] (2014), 106-112.
ᅜෆᏛ఍
⏕య࢚ࢿࣝࢠ࣮◊✲఍ ➨ 40 ᅇウㄽ఍
➨ 36 ᅇ ⏕య⭷࡜⸆≀ࡢ┦஫స⏝ࢩ࣏ࣥࢪ࣒࢘
➨ 12 ᅇḟୡ௦ࢆᢸ࠺ⱝᡭࡢࡓࡵࡢࣇ࢕ࢪ࣭࢝ࣝࣇ࢓࣮࣐ࣇ࢛࣮࣒ࣛ
➨ 14 ᅇ ᪥ᮏ⺮ⓑ㉁⛉Ꮫ఍ᖺ఍
➨ 9 ᅇࢺࣛࣥࢫ࣏࣮ࢱ࣮◊✲఍
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(B)
⣽⳦ࡢ㹒㹭㹪㹁ඹᙺᆺ␗≀᤼ฟࢱࣥࣃࢡࡢ㹖⥺⤖ᬗᵓ㐀ゎᯒ
― 230 ―
1௳
1௳
1௳
1௳
1௳
༢఩㸸༓෇
4,030
୰ᓥ Ⰻ௓
ཷク◊✲
ᒣཱྀ ᫂ே
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
␗≀᤼ฟ㍺㏦ࡢᵓ㐀ⓗᇶ┙ゎ᫂࡜㜼
ᐖ๣ࡢ㛤Ⓨ
58,650
ඹྠ◊✲
ᒣཱྀ ᫂ே
ओࣇ࢓࢖ࣥ
Ⓨ㓝ἲ࡟ࡼࡿ࣒࣊㕲࣭ࣄ࢔ࣝࣟࣥ㓟
ࡢᐇ⏝໬
0
⌮໬Ꮫ◊✲ᡤ㸫⏘ᴗ⛉Ꮫ◊✲ᡤ࢔ࣛ࢖࢔ࣥࢫࣛ࣎㸦⑌ᝈ⢾㙐ࢆ୰ᚰ࡜ࡋࡓࢣ࣑࢝ࣝࣂ࢖
࢜ࣟࢪ࣮ศ㔝㸧
ཎⴭㄽᩥ
[1]Core fucosylation of IgG-BCR is required for antigen recognition and antibody production., Wenzhe
Li, Rui Yu, Biao Ma, Yan Yang, Xinyan Jiao, Yang Liu, Hongyu Cao, Weijie Dong, Linhua Liu, Keli Ma,
Tomohiko Fukuda, Qingping Liu, Tonghui Ma, Zhongfu Wang, Jianguo Gu, Jianing Zhang and Naoyuki
Taniguchi: J Immunol., 194 (6) (2015) 2596-606.
[2]Loss of Į1,6-fucosyltransferase suppressed liver regeneration: implication of core fucose in the
regulation of growth factor receptor-mediated cellular signaling., Wang Y, Fukuda T, Isaji T, Lu J, Gu W,
Lee HH, Ohkubo Y, Kamada Y, Taniguchi N, Miyoshi E, Gu J.: Sci Rep., 5 (2015) 8264.
[3]An aberrant sugar modification of BACE1 blocks its lysosomal targeting in Alzheimer's disease.,
Kizuka Y, Kitazume S, Fujinawa R, Saito T, Iwata N, Saido TC, Nakano M, Yamaguchi Y, Hashimoto Y,
Staufenbiel M, Hatsuta H, Murayama S, Manya H, Endo T, Taniguchi N.: EMBO Mol Med., 7 (2015)
175-89.
[4]Expression of Fucosyltransferase 8 Is Associated with an Unfavorable Clinical Outcome in Non-Small
Cell Lung Cancers., Honma R, Kinoshita I, Miyoshi E, Tomaru U, Matsuno Y, Shimizu Y, Takeuchi S,
Kobayashi Y, Kaga K, Taniguchi N, Dosaka-Akita H.: Oncology., 88 (5) (2015) .
[5]Ceramide galactosyltransferase expression is regulated positively by Nkx2.2 and negatively by OLIG2.,
Okahara K, Kizuka Y, Kitazume S, Ota F, Nakajima K, Hirabayashi Y, Maekawa M, Yoshikawa T and
Taniguchi N.: Glycobiology, 24 (10) (2014) 926-934.
[6]Golgi N-glycan branching N-acetylglucosaminyltransferases I, V and VI promote nutrient uptake and
metabolism., Abdel Rahman AM, Ryczko M, Nakano M, Pawling J, Rodrigues T, Johswich A, Taniguchi
N and Dennis JW.: Glycobiology, 25 (2) (2014) 225-240.
[7]Synthesis of N-glycan units for assessment of substrate structural requirements of
N-acetylglucosaminyltransferase III., Hanashima S, Korekane H, Taniguchi N and Yamaguchi Y.: Med
Chem Lett., 24 (18) (2014) 4533-4537.
[8]Interaction of platelet endothelial cell adhesion molecule (PECAM) with Į2,6-sialylated glycan
regulates its cell surface residency and anti-apoptotic role., Kitazume S, Imamaki R, Kurimoto A, Ogawa
K, Kato M, Yamaguchi Y, Tanaka K, Ishida H, Ando H, Kiso M, Hashii N, Kawasaki N and Taniguchi N.:
J Biol Chem., 289 (40) (2014) 27604-27613.
[9]Association of serum interleukin-27 with the exacerbation of chronic obstructive pulmonary disease.,
Angata T, Ishii T, Gao C, Ohtsubo K, Kitazume S, Gemma A, Kida K and Taniguchi N.: Physiol Rep., 2
(7) (2014) e12069.
[10]Polyamine modification by acrolein exclusively produces 1,5-diazacyclooctanes: a previously
unrecognized mechanism for acrolein-mediated oxidative stress., Tsutsui A, Imamaki R, Kitazume S,
Hanashima S, Yamaguchi Y, Kaneda M, Oishi S, Fujii N, Kurbangalieva A, Taniguchi N and Tanaka K.:
Org Biomol Chem., 12 (28) (2014) 5151-5157.
― 231 ―
[11]࢚ࣛࢫࢱ࣮ࢮㄏᑟ⫵Ẽ⭘ࣔࢹࣝࢆ⏝࠸ࡓ LPS ࡟ࡼࡿቑᝏࣔࢹ࣐ࣝ࢘ࢫࡢసᡂ, ⸨⦖⋹Ꮚࠊᑠ
ᯘ⪽ࠊ໭∎ࡋࡢࡪࠊ㇂ཱྀ┤அ: THE LUNG perspectives, 22 (3) (2014) 180-185.
ᅜ㝿఍㆟
[1]Identification of ectonucleotide pyrophosphatase/phosphodiesterase 3 as a new modifier of glycan
biosynthesis (oral), Naoyuki Taniguchi: Experimental Biology 2014, San Diego (USA).
[2]From Glycobiology to Systems Glycobiology for understanding the underlying mechanism of disease
onset, biomarker and therapeutics (oral), Naoyuki Taniguchi: RIKEN-Max Planck Joint Research Center
for Systems Chemical Biology, The 3rd symposium, Munich (Germany).
[3]Loss of Bisected glycan ameliorates Alzheimer’s disease pathology in mouse brain (poster), Yasuhiko
Kizuka, Shinobu Kitazume, Reiko Fujinawa, Takashi Saito, Nobuhisa Iwata, Takaomi Saido, Miyako
Nakano, Yoshiki Yamaguchi, Yasuhiro Hashimoto, Matthias Staufenbiel, Hiroyuki Hatsuta, Shigeo
Murayama, Hiroshi Manya, Tamao Endo, Naoyuki Taniguchi: RIKEN-Max Planck Joint Research Center
for Systems Chemical Biology, The 4rd symposium, Munich (Germany).
[4]Systems Glycobiology Approach for Understating the Disease Onset, Biomarker and Therapeutics
(invited), Naoyuki Taniguchi: Kyoto Sangyo University (KSU) International Symposium㸸 Cutting-edge
of Life Sciences, Kyoto (Japan).
[5]Upregulation of GnT-III and Wnt target genes in Fut8 null mice: A possible adaptive and compensation
mechanism for glycan function (invited), Naoyuki Taniguchi: 9th International Symposium on
Glycosyltransferases (Glyco-T 2014), Porto(Portugal).
[6]Chronic Obstructive pulmonary disease (COPD) meets glycobiology: the development of new
therapeutics, keratin sulfate oligosaccharides (invited), Naoyuki Taniguchi: 7th AOHUPO/ 0th PST,
Bangkok (Thailand).
[7]Systems glycobiology for understanding the underlying mechanism of disease onset, biomarker and
therapeutics (invited), Naoyuki Taniguchi: 7th Santorini Conference Biologie Prospective, Santorini
(Greece).
[8]Fut8-/- mice which lack the core fucose structure show the upregulated GnT-III gene and its product, a
bisecting GlcNAc: A possible adaptive and compensatory mechanism for glycan function (invited),
Naoyuki Taniguchi: 13th Human Proteome Organization World Congress (HUPO2014), Madrid
(Spain).
[9]Systems Glycobiology Approach for Understating the Role of Glycans in Disease Onset, Biomarker
and Therapeutics (invited), Naoyuki Taniguchi: 15th IUBMB-24th FAOBMB-TSBMB Conference,
Taipei (Taiwan).
[10]Binding of Langerin/CD207 to keratan sulfate disaccharide, Gal (6SO3) ȕ1, 4-GlcNAc (6SO3) and
its triangle derivative in vitro and in vivo: possible drug targets for COPD (chronic obstructive pulmonary
disease) (poster), Reiko Fujinawa, Fumi Ota, Congxiao Gao, Tetsuya Hirayama, Hiroki Kabata, Hiroaki
Korekane, Shinobu Kitazume, Kazuaki Ohtsubo, Keiichi Yoshida, Yoshiki Yamaguchi, Bernd Lepenies,
Christoph Rademacher, Tomoko Betsuyaku, Naoyuki Taniguchi: Joint Meeting of the Society for
Glycobiology and the Japanese Society of Carbohydrate Research, Honolulu(USA).
[11]Development of a sensitive assay method of keratan sulfate disaccharide levels in mice plasma and
bronchoalveolar lavage fluid (poster), Fumi Ota, Reiko Fujinawa, Hiroaki Korekane, Keiichi Yoshida,
Naoyuki Taniguchi: Joint Meeting of the Society for Glycobiology and the Japanese Society of
Carbohydrate Research, Honolulu(USA).
― 232 ―
[12]Suppression of inflammatory response by Keratan sulfate disaccharide in the development of COPD
model mice (poster), Congxiao Gao, Takayuki Yoshida, Fumi Ota, Reiko Fujinawa, Keiichi Yoshida,
Tomoko Betsuyaku, Naoyuki Taniguchi: Joint Meeting of the Society for Glycobiology and the Japanese
Society of Carbohydrate Research, Honolulu(USA).
[13]Epigenetic regulation of glycosyltransferase (poster), Yasuhiko Kizuka, Shinobu Kitazume, Naoyuki
Taniguchi: Joint Meeting of the Society for Glycobiology and the Japanese Society of Carbohydrate
Research, Honolulu(USA).
[14]High-throughput screening of GnT-III inhibitors using UDP-Glo system to develop a novel drug
candidate for Alzheimer’s disease (poster), Yasuhiko Kizuka, Shinobu Kitazume, Keiko Sato, Tetsuo
Ohnuki, Mutsuko Kukimoto-Niino, Mikako Shirouzu, Minoru Yoshida, Laurie Engel, Hicham Zegzouti,
Naoyuki Taniguchi: Joint Meeting of the Society for Glycobiology and the Japanese Society of
Carbohydrate Research, Honolulu(USA).
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
㇂ཱྀ ┤அ
Glycobiology (⦅㞟ጤဨ)
㇂ཱྀ ┤அ
IUBMB life (⦅㞟ጤဨ)
㇂ཱྀ ┤அ
IUBMB Biochemistry and Molecular Biology Education (⦅㞟ጤဨ)
㇂ཱྀ ┤அ
Nitric Oxide (⦅㞟ጤဨ)
㇂ཱྀ ┤அ
Protein Expression and Purification (⦅㞟ጤဨ)
㇂ཱྀ ┤அ
Biochemical and Biophysical Research Communications (⦅㞟⪅)
㇂ཱྀ ┤அ
International Journal of Oncology (⦅㞟ጤဨ)
㇂ཱྀ ┤அ
Glycoconjugate Journal (⦅㞟⪅)
㇂ཱྀ ┤அ
Proteomics/ Proteomics-Clinical Applications (⦅㞟⪅)
㇂ཱྀ ┤அ
GlycoT (⛉Ꮫㅎၥጤဨ)
㇂ཱྀ ┤அ
Cellular and Molecular Lide Sciences (⦅㞟ጤဨ)
㇂ཱྀ ┤அ
Journal of Proteome Research (⦅㞟ጤဨ)
㇂ཱྀ ┤அ
Clinical Proteomics (⦅㞟ጤဨ)
㇂ཱྀ ┤அ
Antioxidants and Redox Signaling (⦅㞟ጤဨ)
㇂ཱྀ ┤அ
Society for Glycobiology (఍㛗)
ᅜෆᏛ఍
➨㸱㸱ᅇẼ㐨ศἪ◊✲఍㸦኱ὠ㸧
㸶㸵ᅇ᪥ᮏ⏕໬Ꮫ఍኱఍(ி㒔)
➨㸯㸰ᅇ⢾㙐⛉Ꮫࢥࣥࢯ࣮ࢩ࢔࣒㸦㹈㹁㹅㹅㸧ࢩ࣏ࣥࢪ࣒࢘㸦ᮾி㸧
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲ C
᫝㔠 ᏹ᫛
⢾㌿⛣㓝⣲ไᚚᅉᏊ࡜ࡋ࡚ྠᐃࡋࡓ ENPP3 ࡜⢾ࢾࢡࣞ࢜ࢳࢻ௦ㅰ
ࡢ⏕≀Ꮫⓗព⩏
ࡑࡢ௚ࡢ➇தⓗ◊✲㈨㔠
㧗 ྀ➗
(ᰴ㸧ࢢࣛࢯ࣭ࣥࢫ࣑ࢫࢡࣛ
࢖ࣥ
1௳
1௳
1௳
༢఩㸸༓෇
5,070
࢚ࣆࢪ࢙ࢿࢸ࢕ࢡࢫࢆ⏝࠸ࡓ៏ᛶ㛢
ሰᛶ⫵⑌ᝈឤཷᅉᏊ࡛࠶ࡿ⢾㌿⛣㓝
⣲ alpha1,6fucosyltransferase(Fut8)ࡢⓎ
⌧ไᚚᶵᵓࡢゎ᫂
2,000
ࢼࣀᶵ⬟ᮦᩱࢹࣂ࢖ࢫ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Electrical oscillation in Pt/VO2 bilayer strips, Ying Wang, Jianwei Chai, Shijie Wang, Long Qi,
Yumeng Yang, Yanjun Xu, Hidekazu Tanaka and Yihong Wu J. Appl. Phys. 117 (2015) 064502.: J. Appl.
Phys., 117 (6) (2015) 064502㸦1-7㸧.
[2]Estimation of dc transport dynamics in strongly correlated (La,Pr,Ca)MnO3 film using an
― 233 ―
insulator-metal composite model for terahertz conductivity, T. V. A. Nguyen, A. N. Hattori, M. Nagai, T.
Nakamura, K. Fujiwara, M. Ashida, and H. Tanaka: Appl. Phys. Lett., 105 (2) (2014) 023502㸦1-5㸧.
[3]Noise-driven signal transmission device using molecular dynamics of organic polymers, N. Asakawa,
K. Umemura, S. Fujise, K. Yazawa, T. Shimizu, M. Tansho, T. Kanki and H. Tanaka: J. Nanophotonics, 8
(2) (2014) 083077(1-15).
[4]Formation mechanism of a microscale domain and effect on transport properties in strained VO2 thin
films on TiO2(001), K. Kawatani, T. Kanki and H. Tanaka: Phys. Rev. B, 90 (5) (2014) 054203(1-5).
[5]Dual field effects in electrolyte-gated spinel ferrite: electrostatic carrier doping and redox reactions, T.
Ichimura, K. Fujiwara and H. Tanaka: Sci. Rep., 4 (2014) 5818-1-5.
[6]Artificial 㹲hree Dimensional Oxide Nanostructures for High Performance Correlated Oxide
Nanoelectronics, H. Tanaka, H. Takami, T. Kanki, A. N. Hattori, and K. Fujiwara: Jpn. J. Appl. Phys., 53
(5S1) (2014) 㸦p1-5㸧.
[7]Local atomic configuration of graphene, buffer layer, and precursor layer on SiC(0001) by
photoelectron diffraction, H. Matsui, F. Matsui, N. Maejima, T. Matsushita, T. Okamoto, A. N. Hattori, Y.
Sano, K. Yamauchi, H. Daimon: Surf. Sci., 632 (2014) 98-102.
ᅜ㝿఍㆟
[1]Nonvolatile Transport Properties Induced by a Field Effect Accompanying Redox Processes in Ferrite
Thin Films (invited), H.Tanaka, Kohei Fujiwara: Collaborative Conference on 3D & Materials Research
㸦CC3DMR2014㸧.
[2]Nano-confinement effect in the extremely small 3D oxide nanostructures (invited), H.Tanaka: The 15th
IUMRS-ICA (International Union of Materials Research Societies, International Conference in Asia).
[3]Functinal oxide nanoelectrnics and spintornics using Vanadate and Ferrite (oral), H.Tanaka: Academic
Visit.
[4]Temperature and voltage induced multistep metal insulator transition in artificial VO2 nanowires on
Al2O3 (0001) substrates (oral), H.Tanaka, H.Takami, T. Kanki: 2014 MRS Fall Meeting & Exhibit.
[5]Nanoimprint based directed self-assembly for production of heterostructured functional oxide nano dot
arrays. (poster), K.Okada, T.Sakamoto, H.Tanaka: 2014 MRS Fall Meeting & Exhibit.
[6]Focus Session: Magnetic Oxide Thin Films and Heterostructures: Electric Field and Magnetoelectric
Effects (invited), H.Tanaka: American Physical Society .
[7]Reversible and Memristive Modulation of Transport Property in VO2 Nano-Wires by an Electric Field
via Air Nano-Gap (invited), T. Kanki: The 15th IUMRS-ICA (International Union of Materials Research
Societies, International Conference in Asia).
[8]Low Power Operation of Metal-Insulator Transition in Oxide Nano-Structures (oral), T. Kanki and H.
Tanaka: The 1st International Symposium on Interactive Materials Science Cadet Program.
[9]Memristive Metal-Insulator Switch in Correlated Electron Oxide Nanowires Using Electric
Field-Induced Redox Reaction (invited), T. Kanki: 4th international conference Nanotek & Expo.
[10]Reversible Control of Metal-Insulator Transition by the Local Peltier Effect in VO2 Nanowires
(poster), T. Kanki, H.Takami, H.Tanaka: 2014 MRS Fall Meeting & Exhibit.
― 234 ―
[11]Tunable Electrochemical Doping into VO2 Nanowires Using Planer-Type Field Effect Transistor
(poster), T. Kanki, T. Sasaki , H. Tanaka: 2014 MRS Fall Meeting & Exhibit.
[12]Designing Transport Characteristics by Manipulating Metal-Insulator Domains through Oxide
Nanostructures (invited), T. Kanki, H. Tanaka: The 18th SANKEN International Symposium & The
13th SANKEN Nanotechnology Symposium.
[13]Fabrication of the programmable three-dimensional nanostructures of functional metal oxides (poster),
A. N. Hattori and H. Tanaka: European Conference on Surface Science (ECOSS30).
[14]Fabrication of three-dimensional epitaxial spinel ferrite nanowall wire structures by 3D-nanotemplate
PLD technique (poster), A. N. Hattori, Y. Fujiwara, K. Fujiwara, and H. Tanaka: The 13th International
Conference on Nanoimprint and Nanoprint Technology.
[15]Fabrication of Si nanoguide structures with a few tens of nm pitch using ultraviolet nanoimprint
lithography (oral), A. N. Hattori, S. Ito, R. Okubo, M. Nakagawa, and H. Tanaka: The 7th International
Symposium on Surface Science (ISSS-7).
[16]Identification of giant phase transition of single electric domain in (La,Pr,Ca)MnO3 epitaxial
nanowall wire (poster), A. N. Hattori, Y. Fujiwara, T. V. A. Nguyen, K. Fujiwara, and H. Tanaka: The 7th
International Symposium on Surface Science (ISSS-7).
[17]Control of transition properties in nanoscale phase-separated(La,Pr,Ca)MnO3 film by electric double
layer gating (poster), A. N. Hattori, T. Nakamura, T. V. A. Nguyen, K. Fujiwara, H. Tanaka: 2014 MRS
Fall Meeting & Exhibit.
[18]Gate-induced nonvolatile changes in the transport properties of spinel ferrite thin films (oral), K.
Fujiwara and H. Tanaka: International Union of Materials Research Society–International Conference in
Asia 2014.
[19]Growth of Complex Nanostructures of Metal Oxides Using a Shadow Effect (invited), K. Fujiwara, K.
Okada, A. N. Hattori, and H. Tanaka: International Union of Materials Research Society–International
Conference on Electronic Materials 2014.
[20]Electric-Field Devices Based on Ferrite Compounds (poster), K. Fujiwara and H. Tanaka:
International Union of Materials Research Society–International Conference on Electronic Materials
2014.
[21]Field-Effect Carrier Doping in KTaO3 via Organic Parylene-C Insulator (poster), T. T. Wei, K.
Fujiwara, and H. Tanaka: The 18th SANKEN International Symposium.
[22]Electric-Field Control of the Charge-Ordered Phase in YbFe2O4 Thin Films (poster), T. Hori, K.
Fujiwara, and H. Tanaka: The 18th SANKEN International Symposium.
[23]Fabrication of Fe3O4 Thin Film-Based Resistors for Power Electronics (poster), S. Tsubota, K.
Fujiwara, and H. Tanaka: The 18th SANKEN International Symposium.
[24]Characterization of Fe3O4 Thin Films as High-Temperature Resistive Materials (poster), S. Tsubota,
K. Fujiwara, and H. Tanaka: 1st E-MRS/MRS-J Bilateral Symposia.
ゎㄝࠊ⥲ㄝ
㓟໬≀ࢼࣀᵓ㐀࡛㟁Ꮚࢫࣆࣥࢆ᧯ࡿ, ⏣୰ ⚽࿴, ⏕⏘࡜ᢏ⾡, ♫ᅋἲே ⏕⏘ᢏ⾡᣺⯆༠఍,
66[4] (2014), 33-37.
― 235 ―
༢୍㟁Ꮚ┦㞟ᅋࡢ┦㌿⛣ࢆ฼⏝ࡋࡓ㓟໬≀ࢼࣀ࢚ࣞࢡࢺࣟࢽࢡࢫ, ⚄ྜྷ ㍤ኵࠊ⏣୰ ⚽࿴, ⏕
⏘࡜ᢏ⾡, ♫ᅋἲே ⏕⏘ᢏ⾡᣺⯆༠఍, 66[3] (2014), 110-114.
ⴭ᭩
[1]Thin Films and Epitaxy:Basic Techniques (Thomas F. Kuech)“Handbook of Crystal Growth”, ⏣୰
⚽࿴, ELSEVIER, 3 2015.
≉チ
[1]ࠕᅜෆᡂ❧≉チࠖ㟁ὶ㸫ࢫࣆࣥὶኚ᥮⣲Ꮚ, ≉チ➨ 5590488
[2]ࠕᅜෆᡂ❧≉チࠖSiC ᇶᯈ࡬ࡢࢢࣛࣇ࢙ࣥᡂ⭷᪉ἲ, ≉チ➨ 5644175
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
⸨ཎ ᏹᖹ
International Union of Materials Research Societies - International Conference in
Electronic Materials (㐠Ⴀጤဨ)
ᅜෆᏛ఍
ᛂ⏝≀⌮Ꮫ఍
᪥ᮏ MRS
➨ 2 ᅇⱝᡭ࢔ࣛ࢖࢔ࣥࢫ◊✲஺ὶ఍
ᩥ㒊⛉Ꮫ┬ࢼࣀࢸࢡࣀࣟࢪ࣮ࣉࣛࢵࢺࣇ࢛࣮࣒ᖹᡂ 26 ᖺᗘࢭ࣑ࢼ࣮ᡂ⭷ࣉࣟࢭࢫ
ᢏ⾡ᐇ㊶ࢭ࣑ࢼ࣮
ᖹᡂ 26 ᖺᗘᮾ໭኱㏻◊/㜰኱⏘◊◊✲஺ὶ఍
3௳
1௳
2௳
1௳
1௳
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(A)
⏣୰ ⚽࿴
ᣮᡓⓗⴌⱆ◊
✲
⏣୰ ⚽࿴
ᇶ┙◊✲(B)
⚄ྜྷ ㍤ኵ
ⱝᡭ◊✲(B)
᭹㒊 ᱻ
ⱝᡭ◊✲(B)
⸨ཎ ᏹᖹ
ཷク◊✲
⚄ྜྷ ㍤ኵ
ዡᏛᐤ㝃㔠
᭹㒊 ᱻ
⸨ཎ ᏹᖹ
⸨ཎ ᏹᖹ
ඹྠ◊✲
⏣୰ ⚽࿴
⏣୰ ⚽࿴
ᙉ┦㛵㓟໬≀㸱D ࢼࣀᵓ㐀ࢫࢣ࣮ࣜࣥࢢ≀ᛶゎ᫂࡜㟁Ꮚ┦ኚ໬
ࢹࣂ࢖ࢫᛂ⏝
ᶵ⬟ᛶ㓟໬≀ࢼࣀ㟁ẼᶵᲔ⣲Ꮚࡢస〇࡜⎔ቃ㐺ᛂᆺ㉸㧗ឤᗘࢭ
ࣥࢧᛂ⏝
ࢼࣀࢫࢣ࣮ࣝᙉ┦㛵㟁Ꮚ┦ࢻ࣓࢖ࣥࡢ┦㌿⛣࣭ືⓗ࣭✵㛫㓄ิ
ࢺ࣮ࢱࣝไᚚ
3d 㑄⛣㔠ᒓ㓟໬≀ࡢࢼࣀ㉸ᵓ㐀໬ᢏ⾡ᵓ⠏࡜ᕧ኱☢Ẽᛂ⟅ᛶホ
౯
㕲⣔㓟໬≀ࡢᐊ 㟁Ꮚᅛయ≧ែ࡟࠾ࡅࡿ㟁Ꮚ┦ኚ໬ᶵ⬟ࡢᐇド
ᰴᘧ఍♫࢔ࢡࢭࣝ බ❧
኱Ꮫἲேරᗜ┴❧኱Ꮫ
ࢥࣥࣆ࣮ࣗࢱ⏬㠃ୖ࡟௬᝿ LED ࢆࡺ
ࡽࡀࡏ࡚⾲♧ࡍࡿࢩࢫࢸ࣒ࡢヨస
༢఩㸸༓෇
15,730
2,340
7,410
1,690
1,040
325
ᰴᘧ఍♫㈨⏕ᇽ ◊✲᥎㐍㒊 㒊㛗 ᑠཪ᫛ᙪ
බ┈㈈ᅋἲேụ㇂⛉Ꮫᢏ⾡᣺⯆㈈ᅋ ⌮஦㛗 ụ㇂ṇᡂ
බ┈㈈ᅋἲே⇃㇂⛉Ꮫᢏ⾡᣺⯆㈈ᅋ ⌮஦㛗 ⇃㇂ኴ୍㑻
1,000
1,000
1,000
ᰴᘧ఍♫ᮧ⏣〇సᡤ
1,670
㓟໬≀୕ḟඖࢼࣀ࣊ࢸࣟᵓ㐀ᙧᡂ࡜
ᛂ⏝࡟㛵ࡍࡿ◊✲
◳ X ⥺ග㟁Ꮚศග࡟ࡼࡿᙉ┦㛵㓟໬
≀ᶵ⬟ᛶࢼࣀᮦᩱࡢ◊✲
⊂❧⾜ᨻἲே≀㉁࣭ᮦᩱ
◊✲ᶵᵓ
ࡑࡢ௚ࡢ➇தⓗ◊✲㈨㔠
⏣୰ ⚽࿴
኱Ꮫඹྠ฼⏝ᶵ㛵ἲே⮬ ศᏊ࣭≀㉁ྜᡂࣉࣛࢵࢺࣇ࢛࣮࣒ᐇ᪋
↛⛉Ꮫ◊✲ᶵᵓศᏊ⛉Ꮫ ᶵ㛵
◊✲ᡤ 㸦ᩥ㒊⛉Ꮫ┬ࡢ෌
ጤク㸧
― 236 ―
0
32,800
⏣୰ ⚽࿴
බ┈㈈ᅋἲே᪥ᮏᯈ◪Ꮚ
ᮦᩱᕤᏛຓᡂ఍
ᙉㄏ㟁య࠾ࡼࡧ࢖࢜ࣥᾮࢤ࣮ࢸ࢕ࢢ
ࢆ฼⏝ࡋࡓᩍ☢ᛶࢫࣆࣝࢿࣝࣇ࢙ࣛ
࢖ࢺⷧ⭷ࡢ㟁⏺ຠᯝ
100
ࢼࣀᴟ㝈ࣇ࢓ࣈࣜࢣ࣮ࢩࣙࣥศ㔝
ཎⴭㄽᩥ
[1]Twin-peaks absorption spectra of excess electron in ionic liquids, R. M. Musat, T. Kondoh, Y. Yoshida,
Kenji Takahashi: , 100 (2014) 32-37.
[2]Measurement of < 20 fs bunch length using coherent transition radiation, I. Nozawa, K. Kan, J. Yang,
A. Ogata, T. Kondoh, M. Gohdo, K. Norizawa, H. Kobayashi, H. Shibata, S. Gonda, and Y. Yoshida: , 17
(2014) 072803.
ᅜ㝿఍㆟
[1]Femtosecond time-resolved electron diffraction and microscopy (invited), J. Yang: Advanced Lasers
and Their Applications (ALTA) 2014.
[2]Possibility of Attosecond Pulse Radiolysis (invited), Y. Yoshida: the 6th Asian Forum for Accelerators
and Detectors (AFAD2015).
[3]RF gun based Ultrafast Electron Microscopy (invited), J. Yang: the 6th Asian Forum for Accelerators
and Detectors (AFAD2015).
[4]Pulse radiolysis using terahertz pulse (oral), K. Kan, J. Yang, A. Ogata, T. Kondoh, M. Gohdo, I.
Nozawa, T. Toigawa, K. Norizawa, H. Kobayashi, Y. Yoshida: Advanced Lasers and Their Applications
(ALTA) 2014.
[5]Pulse radiolysis using terahertz probe pulses (poster), K. Kan, J. Yang, A. Ogata, T. Kondoh, M. Gohdo,
I. Nozawa, T. Toigawa, K. Norizawa, Y. Yoshida: the 5th International Particle Accelerator Conference
(IPAC’14).
[6]Simulation study on electron beam acceleration using coherent Cherenkov radiation (poster), K. Kan, J.
Yang, A. Ogata, T. Kondoh, M. Gohdo, I. Nozawa, T. Toigawa, K. Norizawa, Y. Yoshida, M. Hangyo, R.
Kuroda, H. Toyokawa: the 5th International Particle Accelerator Conference (IPAC’14).
[7]Femtosecond time-resolved transmission electron microscopy using RF gun (poster), J. Yang, M.
Gohdo, K. Kan, T. Kondoh, K. Tanimura, Y. Yoshida, J. Urakawa: the 5th International Particle
Accelerator Conference (IPAC’14).
[8]Generation and diagnosis of ultrashort electron bunches from a photocathode RF gun linac (poster), I.
Nozawa, K. Kan, J. Yang, A. Ogata, T. Kondoh, M. Gohdo, K. Norizawa, Y. Yoshida, H. Kobayashi,: the
5th International Particle Accelerator Conference (IPAC’14).
[9]Possibility of Attosecond Pulse Radiolysis (oral), Y. Yoshida: The 5th Asia Pacific Symposium on
Radiation Chemistry, The 57th Annual Meeting of The Japanese Society of Radiation Chemistry.
[10]Development and Perspective of the Atto-second Pulse Radiolysis (oral), M. Gohdo, K. Kan, T.
Kondoh, J. Yang, Y. Yoshida: The 5th Asia Pacific Symposium on Radiation Chemistry, The 57th Annual
Meeting of The Japanese Society of Radiation Chemistry.
[11]Femtosecond Pulse Radiolysis Study on Spectrum and Reactivity of Solvated/Pre-solvated Electrons
in n-alcohols (oral), T. Toigawa, K. Norizawa, T. Kondoh, M. Gohdo, K. Kan, J. Yang, Y. Yoshida: The
5th Asia Pacific Symposium on Radiation Chemistry, The 57th Annual Meeting of The Japanese Society
of Radiation Chemistry.
― 237 ―
[12]Formation of Dimer Radical Cation of Poly-Į-methylstyrene by Direct Ionization in Solution (oral), T.
Igahara, M. Gohdo, T. Kondoh, S. Tagawa, J. Yang, K. Kan, A. Ogata, Y. Yoshida: The 5th Asia Pacific
Symposium on Radiation Chemistry, The 57th Annual Meeting of The Japanese Society of Radiation
Chemistry.
[13]Time Dependent Behaviors of Electron in n-dodecane Studied by the Femtosecond Pulse Radiolysis
(oral), T. Kondoh, S. Nishii, K. Norizawa, K. Kan, J. Yang, M. Gohdo, S. Tagawa, Y. Yoshida,: The 5th
Asia Pacific Symposium on Radiation Chemistry, The 57th Annual Meeting of The Japanese Society of
Radiation Chemistry.
[14]Femtosecond Pulse Radiolysis Study of the Radiation Decomposition Process of n-dodecane (oral), S.
Nishii, T. Kondoh, M. Gohdo, K. Kan, J. Yang, S. Tagawa, Y. Yoshida: The 5th Asia Pacific Symposium
on Radiation Chemistry, The 57th Annual Meeting of The Japanese Society of Radiation Chemistry.
[15]Formation Process Study of Hydrated Electron in Water by Femtosecond Pulse Radiolysis (poster), S.
Yamaso, T. Toigawa, T. Kondoh, M. Gohdo, K. Kan, J. Yang, Y. Yoshida: The 5th Asia Pacific
Symposium on Radiation Chemistry, The 57th Annual Meeting of The Japanese Society of Radiation
Chemistry.
[16]Radiation-Induced Decomposition Process of N-Dodecane Studied by Femtosecond Pulse Radiolysis
(oral), Y. Yoshida: The 11th meeting of the ionizing radiation and polymers symposium (IRaP 2014).
[17]Initial Ionization G-Value of N-Dodecan Studies by a Femtosecond Pulse Radiolysis (poster), T.
Kondoh, S. Nishii, M. Gohdo, K. Kan, J. Yang, K. Norizawa, S. Tagawa, Y. Yoshida: The 11th meeting of
the ionizing radiation and polymers symposium (IRaP 2014).
[18]Formation of Dimer Radical Cation of Poly-Į-Methylstyrene by Direct Ionization in Solution (poster),
T. Igahara, T. Kondoh, M. Gohdo, K. Kan, J. Yang, S. Tagawa, Y. Yoshida: The 11th meeting of the
ionizing radiation and polymers symposium (IRaP 2014).
[19]Generation and Bunch Length Measurement of Femtosecond and Attosecond Electron
Bunches (poster), I. Nozawa, K. Kan, J. Yang, A. Ogata, T. Kondoh, M. Gohdo, Y. Yoshida: The 18th
SANKEN International Symposium, The 13th SANKEN Nanotechnology Symposium, 10th Handai
Nanoscience and Nanotechnology International Symposium, 2nd KANSAI Nanoscience and
Nanotechnology.
[20]Measurement of Electron Beam Using a Photoconductive Antenna (poster), K. Kan, J. Yang, A. Ogata,
M. Gohdo, T. Kondoh, S. Sakakihara, I. Nozawa, K. Norizawa, Y. Yoshida: The 18th SANKEN
International Symposium, The 13th SANKEN Nanotechnology Symposium, 10th Handai Nanoscience
and Nanotechnology International Symposium, 2nd KANSAI Nanoscience and Nanotechnology.
[21]Radiation induced initial process and decomposition process of n-dodecane as a model compound of
polymer-resists using a femtosecond pulse radiolysis (poster), T. Kondoh, S. Nishii, M. Gohdo, K. Kan, J.
Yang, K. Norizawa, S. Tagawa, Y. Yoshida: The 18th SANKEN International Symposium, The 13th
SANKEN Nanotechnology Symposium, 10th Handai Nanoscience and Nanotechnology International
Symposium, 2nd KANSAI Nanoscience and Nanotechnology.
[22]Design and demonstrations of RF gun based Ultrafast Electron Microscopy (poster), J. Yang, K. Kan,
T. Kondoh, M. Gohdo, Y. Yoshida: The 18th SANKEN International Symposium, The 13th SANKEN
Nanotechnology Symposium, 10th Handai Nanoscience and Nanotechnology International Symposium,
2nd KANSAI Nanoscience and Nanotechnology.
[23]UV Femtosecond Pulse Radiolysis Study of the Formation Process of Alkyl Radicals in n-Dodecane
(poster), S. Nishii, T. Kondoh, M. Gohdo, K. Kan, J. Yang, S. Tagawa, Y. Yoshida: The 18th SANKEN
International Symposium, The 13th SANKEN Nanotechnology Symposium, 10th Handai Nanoscience
― 238 ―
and Nanotechnology International Symposium, 2nd KANSAI Nanoscience and Nanotechnology.
[24]Development and perspective of the atto-second pulse radiolysis (poster), Masao Gohdo, Koichi Kan,
Takafumi Kondoh, Jinfeng Yang, Yoichi Yoshida: The 29th Miller Conference.
[25]Pulse radiolysis study of polystyrene dimer phenyl cation radical in THF (poster), Masao Gohdo,
Takafumi Kondoh, Koichi Kan, Jinfeng Yang, Hiromi Shibata, Seiichi Tagawa, Yoichi Yoshida: The 29th
Miller Conference.
[26]Accelerator based femtosecond time-resolved electron microscopy (invited), J. Yang: OPIC &
PHOTONICS International Congress 2014.
[27]Development of femtosecond time-resolved relativistic-energy electron microscopy (poster), J. Yang,
K. Tanimura, Y. Yoshida, J. Urakawa: 18th International Microscopy Congress.
ゎㄝࠊ⥲ㄝ
ࣇ࢛ࢺ࢝ࢯ࣮ࢻ㧗࿘Ἴ㟁Ꮚ㖠ࣛ࢖ࢼࢵࢡ࠿ࡽࡢ㉸▷ࣃࣝࢫ㟁Ꮚࣅ࣮࣒ࢆ⏝࠸ࡓࢸࣛ࣊ࣝࢶἼⓎ
⏕, Ⳣ᫭୍ࠊ᳿㔠ᓠࠊᑠ᪉ཌࠊ㏆⸨Ꮥᩥࠊ⚄ᡞṇ㞝ࠊᰘ⏣⿱ᐇࠊྜྷ⏣㝧୍, IEEJ transactions on
electronics, information and systems, 㟁ẼᏛ఍, 134 (2014), 502-509.
ࣇ࢙࣒ࢺ⛊᫬㛫ศゎ㟁Ꮚ㢧ᚤ㙾ࡢ◊✲, ᳿㔠ᓠࠊྜྷ⏣㝧୍ࠊᰘ⏣⿱ᐇ, IEEJ transactions on
electronics, information and systems, 㟁ẼᏛ఍, 134 (2014), 515-520.
ࣇ࢙࣒ࢺ⛊ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫ, ㏆⸨Ꮥᩥࠊ᳿㔠ᓠࠊⳢ᫭୍ࠊ⚄ᡞṇ㞝ࠊᰘ⏣⿱ᐇࠊྜྷ⏣㝧୍, IEEJ
transactions on electronics, information and systems, 㟁ẼᏛ఍, 134 (2014), 664-669.
┦ᑐㄽⓗ㉸▷㟁Ꮚࣃࣝࢫ࡟ࡼࡿ㉸㧗㏿ᅛయᵓ㐀ືຊᏛࡢ◊✲, ᡂ℩ᘏᗣࠊYvelin Giretࠊ᳿㔠ᓠࠊ
㇂ᮧඞᕫ, ࣮ࣞࢨ࣮◊✲, ᪥ᮏ࣮ࣞࢨ࣮Ꮫ఍, 43 (2015), 144-148.
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
ྜྷ⏣ 㝧୍
The 15th International Congress of Radiation Research (ICRR 2015) (⛉Ꮫጤဨ఍)
ᅜෆᏛ఍
ᨺᑕ⥺ࣉࣟࢭࢫࢩ࣏ࣥࢪ࣒࢘
࢔࢖ࢯࢺ࣮ࣉ࣭ᨺᑕ⥺◊✲Ⓨ⾲఍
᪥ᮏຍ㏿ჾᏛ఍ᖺ఍
᪥ᮏཎᏊຊᏛ఍
㧗ᓮ㔞Ꮚᛂ⏝◊✲ࢩ࣏ࣥࢪ࣒࢘
ග໬Ꮫウㄽ఍
㧗㍤ᗘ࣭㧗࿘Ἴ㟁Ꮚ㖠◊✲఍
ྲྀᚓᏛ఩
ಟኈ㸦ᕤᏛ㸧
஭Ἑཎ኱ᶞ
ಟኈ㸦ᕤᏛ㸧
㔝⃝୍ኴ
ಟኈ㸦ᕤᏛ㸧
ᮤு
2௳
2௳
8௳
7௳
1௳
1௳
2௳
ࣇ࢙࣒ࢺ⛊ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫࢆ⏝࠸ࡓࣞࢪࢫࢺ㧗ศᏊᮦᩱࡢᨺᑕ⥺໬Ꮫึ
ᮇ㐣⛬࡟㛵ࡍࡿ◊✲
ࣇ࢙࣒ࢺ⛊࣭࢔ࢺ⛊㉸▷ࣃࣝࢫ㟁Ꮚࣅ࣮࣒Ⓨ⏕࣭ィ ࡢ◊✲
㉸㧗㏿㟁Ꮚ㢧ᚤ㙾⏝㧗⧞㏉ࡋࣇ࢛ࢺ࢝ࢯ࣮ࢻ RF 㟁Ꮚ㖠ࡢ㛤Ⓨ
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(A)
ྜྷ⏣ 㝧୍
ᇶ┙◊✲(A)
࢔ࢺ⛊ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫࡢᵓ⠏
ࣇ࢙࣒ࢺ⛊᫬㛫ศゎ㟁Ꮚ㢧ᚤ㙾࡟㛵ࡍࡿ◊✲
― 239 ―
༢఩㸸༓෇
21,060
14,300
᳿ 㔠ᓠ
ⱝᡭ◊✲(B)
Ⳣ ᫭୍
ⱝᡭ◊✲(B)
⚄ᡞ ṇ㞝
ዡᏛᐤ㝃㔠
ྜྷ⏣ 㝧୍
Ⳣ᫭୍
ඹྠ◊✲
ྜྷ⏣ 㝧୍
ྜྷ⏣ 㝧୍
᪥ಙᅜ㝿ᰴᘧ఍♫
ྜྷ⏣ 㝧୍
⊂❧⾜ᨻἲே᪥ᮏཎᏊຊ◊
✲㛤Ⓨᶵᵓ
ྜྷ⏣ 㝧୍
⊂❧⾜ᨻἲே᪥ᮏཎᏊຊ◊
✲㛤Ⓨᶵᵓ
㸦⊂㸧⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ
᳿ 㔠ᓠ
ࢸࣛ࣊ࣝࢶ㡿ᇦࡢࣃࣝࢫࣛࢪ࢜ࣜࢩࢫ࡟㛵ࡍࡿ◊✲
2,080
✵㛫᫬㛫ศゎࢩࣥࢢࣝࢩࣙࢵࢺࣃࣝࢫࣛࢪ࢜ࣜࢩࢫࡢ㛤Ⓨ
2,080
᪥ಙᅜ㝿ᰴᘧ఍♫ ௦⾲ྲྀ⥾ᙺ♫㛗 ᳃⏣៞⚈
㸦㈈㸧ᮾ㟁グᛕ㈈ᅋ
1,000
200
ࢲ࢖࢟ࣥᕤᴗᰴᘧ఍♫
4,320
㔞Ꮚࣅ࣮࣒↷ᑕ࡟ࡼࡿࣇࢵ⣲⣔ᶞ
⬡ࡢᚤ⣽ຍᕤ࡜ࡑࡢᶵ⬟ไᚚ
ᴟ▷㟁Ꮚࣃࣝࢫࢆ฼⏝ࡋࡓ㞟ᅋ࢖
࢜ࣥ໬⌧㇟ࡢᛂ⏝ᒎ㛤ࡢྍ⬟ᛶ᥈
ồ
ࣃࣝࢫࣛࢪ࢜ࣜࢩࢫἲࢆ⏝࠸ࡓᶵ
⬟ᛶ཯ᛂሙ࡛ࡢ㐣Ώ⌧㇟࡟㛵ࡍࡿ
◊✲
Ỉ୰࡟࠾ࡅࡿ㟁Ꮚࡢ⇕໬㐣⛬࡟㛵
ࡍࡿ◊✲
ࣇ࢛ࢺ࢝ࢯ࣮ࢻ RF 㟁Ꮚ㖠ࢆ⏝࠸ࡓ
㟁Ꮚ㢧ᚤ㙾ࡢ㛤Ⓨ
416
0
0
0
ࢼࣀᵓ㐀࣭ᶵ⬟ホ౯◊✲ศ㔝
ཎⴭㄽᩥ
[1]Elucidation of the Origin of Grown-in Defects in Carbon Nanotubes, Hideto Yoshida, Seiji Takeda:
Carbon, 70 (2014) 266-272.
[2]A Flux Induced Crystal Phase Transition in the Vapor-Liquid-Solid Growth of Indium-Tin Oxide
Nanowires, Gang Meng, Takeshi Yanagida, Hideto Yoshida, Kazuki Nagashima, Masaki Kanai, Fuwei
Zhuge, Yong He, Annop Klamchuen, Sakon Rahong, Xiaodong Fang, Seiji Takeda, Tomoji Kawai:
Nanoscale, 6 (12) (2014) 7033-7038.
[3]Electron diffraction study of the sillenites Bi12SiO20, Bi25FeO39 and Bi25InO39: Evidence of short-range
ordering of oxygen-vacancies in the trivalent sillenites, Craig A. Scurti, Nicolas Auvray, Michael W.
Lufaso, Seiji Takeda, Hideo Kohno, D. J. Arenas: AIP Adv., 4 (8) (2014) 087125-1--087125-10.
[4]Structurally Inhomogeneous Nanoparticulate Catalysts in Cobalt-catalyzed Carbon Nanotube Growth,
Yusuke Kohigashi, Hideto Yoshida, Yoshikzu Homma, Seiji Takeda: Appl. Phys. Lett., 105 (7) (2014)
073108-1--073108-4.
[5]In situ Transmission Electron Microscopy of Individual Carbon Nanotetrahedron/nanoribbon
Structures in Joule Heating, Yusuke Masuda, Hideto Yoshida, Seiji Takeda, Hideo Kohno: Appl. Phys.
Lett., 105 (8) (2014) 083107-1--083107-5.
[6]Oxidation and Reduction Processes of Platinum Nanoparticles Observed at the Atomic Scale by
Environmental Transmission Electron Microscopy, Hideto Yoshida, Hiroki Omote, Seiji Takeda:
Nanoscale, 6 (21) (2014) 13113-13118.
ᅜ㝿఍㆟
[1]Surface and interface structures in metal nanoparticulate catalysts in reaction environments (invited), S.
Takeda: TAILOR 2014 Workshop "Tailored Surfaces in Operando Conditions: Structure and Reactivity"
Les Oliviers, Saint Paul de Vence, France, April 8-11, 2014.
[2]Structures of the gold nanoparticulate catalysts in reaction environments (invited), S. Takeda: TMU
International Kick Off Workshop for the Research Center for Gold Chemistry, International House, Tokyo
― 240 ―
Metropolitan University, Tokyo, Japan, May 14–15, 2014.
[3]Effect of Pretreatment on CO Oxidation over Palladium Catalysts Supported on Zr-rich Ceria Zirconia
(poster), N. Kamiuchi, M. Haneda, M. Ozawa: The 7th Tokyo Conference on Advanced Catalytic Science
and Technology (TOCAT7).
[4]Catalytically active atomic-structures in metal nanoparticulate catalysts studied by quantitative
environmental TEM (invited), S.Takeda, H. Yoshida, Y. Kuwauchi: 248th ACS National Meeting &
Exposition, San Francisco, USA, August 10-14, 2014.
[5]Quantitative Environmental TEM in Gold Nanoparticulate Catalysts (invited), S. Takeda: The 3rd
International Symposium on Advanced Electron Microscopy for Catalysis, Seeon Monastery, Germany,
September 3-6, 2014.
[6]Catalytically active structures in Au nanoparticulate catalysts studied by quantitative environmental
TEM (oral), Y. Kuwauchi, H. Yoshida, S. Takeda: 18th International Microscopy Congress, Prague, Czech
Republic, September 7-12, 2014.
[7]Phase Control in Transition-Metal Oxide Films through Interfacial Octahedral Connections (poster), R.
Aso, D. Kan, Y. Shimakawa, H. Kurata: 18th International Microscopy Congress, Prague, Czech Republic,
September 7-12, 2014.
[8]In-Situ Environmental TEM Observation of the Formation of Defects in Growing Carbon Nanotubes
(poster), H. Yoshida, S. Takeda: 18th International Microscopy Congress, Prague, Czech Republic,
September 7-12, 2014.
[9]Formation Mechanism of Grown-in Defects in Carbon Nanotubes (poster), H. Yoshida, S. Takeda: The
18th SANKEN International Symposium / The 13th SANKEN Nanotechnology Symposium, The
Congrès Convention Center, Osaka, Japan, December 10-11, 2014.
[10]In-situ TEM observation of an all-solid-state lithium-ion secondary battery (poster), K. Soma, H.
Yoshida, G. Kobayashi, S. Takeda: The 18th SANKEN International Symposium / The 13th SANKEN
Nanotechnology Symposium, The Congrès Convention Center, Osaka, Japan, December 10-11, 2014.
[11]Oxidation and Reduction Processes of Platinum Nanoparticles observed by Atomic-Scale
Environmental Transmission Electron Microscopy (poster), H. Yoshida, H. Omote, S. Takeda: The 18th
SANKEN International Symposium / The 13th SANKEN Nanotechnology Symposium, The Congrès
Convention Center, Osaka, Japan, December 10-11, 2014.
ᅜෆᏛ఍
᪥ᮏ㢧ᚤ㙾Ꮫ఍➨ 70 ᅇᏛ⾡ㅮ₇఍
㝃⨨◊✲ᡤ㛫࢔ࣛ࢖࢔ࣥࢫ࡟ࡼࡿࢼࣀ࡜࣐࢖ࢡࣟࢆࡘ࡞ࡄ≀㉁࣭ࢹࣂ࢖ࢫ࣭
ࢩࢫࢸ࣒๰〇ᡓ␎ࣉࣟࢪ࢙ࢡࢺ ᖹᡂ 25 ᖺᗘᡂᯝሗ࿌఍
➨ 75 ᅇᛂ⏝≀⌮Ꮫ఍⛅ᏘᏛ⾡ㅮ₇఍
᪥ᮏ㢧ᚤ㙾Ꮫ఍ ḟୡ௦㢧ᚤࢧ࢖࢚ࣥࢫⱝᡭ◊✲㒊఍๰タグᛕᅜ㝿ࢩ࣏ࣥࢪ
࣒࢘
ᮾி⌮⛉኱Ꮫ⥲ྜ◊✲ᶵᵓࢼࣀ࣮࢝࣎ࣥ◊✲㒊㛛࣮࣡ࢡࢩࣙࢵࣉ
2014 ᖺᗘ ㉸㧗ศゎ⬟㢧ᚤ㙾ἲศ⛉఍
ྲྀᚓᏛ఩
ಟኈ㸦ᕤᏛ㸧
ᑠᕝ ὒᖹ
ಟኈ㸦ᕤᏛ㸧
⋢ᒸ ṊὈ
࢞ࢫ㞺ᅖẼୗ࡟࠾ࡅࡿ㔠ࢼࣀࢠࣕࢵࣉ㟁ᴟ㛫ࡢᵓ㐀࡜㟁Ẽఏᑟ≉ᛶ
Pd ࢼࣀࢠࣕࢵࣉỈ⣲ࢭࣥࢧᵓ㐀ࡢస〇࡜ືస୰ࡑࡢሙほᐹ
― 241 ―
3௳
1௳
3௳
1௳
1௳
1௳
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(A)
➉⏣ ⢭἞
ⱝᡭ◊✲(B)
⚄ෆ ┤ே
ዡᏛᐤ㝃㔠
➉⏣ ⢭἞
➉⏣ ⢭἞
ඹྠ◊✲
➉⏣ ⢭἞
ẼయศᏊ࡜┦஫స⏝ࡍࡿࢼࣀࢠࣕࢵࣉ㟁ᴟࡢཎᏊࢫࢣ࣮ࣝ
ືⓗゎᯒ
ᢸᣢ㔠ᒓゐ፹࡟࠾ࡅࡿゐ፹άᛶࡢⓎ⌧࠾ࡼࡧຎ໬ᶵᵓࡢ⎔
ቃไᚚ TEM ࡟ࡼࡿゎ᫂
༢఩㸸༓෇
6,500
2,600
ᰴᘧ఍♫ UBE ⛉Ꮫศᯒࢭࣥࢱ࣮ ௦⾲ྲྀ⥾ᙺ♫㛗 ὸ⏣⚽
グ
᪂᪥㕲ఫ㔠ᰴᘧ఍♫ ᢏ⾡㛤Ⓨᮏ㒊 ඛ➃ᢏ⾡◊✲ᡤ㛗
஬༑ᔒṇ᫭
2,000
ศᯒ㟁Ꮚ㢧ᚤ㙾ࢆ⏝࠸ࡓపḟඖ
ࢼࣀᮦᩱࡢᵓ㐀ゎᯒ
0
(⊂)⏘ᴗᢏ⾡⥲ྜ◊✲ᡤ
500
ࢼࣀᶵ⬟ண ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Quasi-One-Dimensional Nature of the Rashba States of Au Wires on Si(557) Surface, T. Oguchi: J.
Electron Spectrosc. Relat. Phenom., 201 (2015) 18-22.
[2]One-dimensional edge states with giant spin splitting in a bismuth thin film, A. Takayama, T. Sato, S.
Souma, T. Oguchi, and T. Takahashi: Phys. Rev. Lett., 114 (2015) 066402/1-5.
[3]Topological proximity effect in a topological insulator hybrid, T. Shoman, A. Takayama, T. Sato, S.
Souma, T. Takahashi, T. Oguchi, K. Segawa, and Y. Ando: Nature Commun., 6 (2015) 6547/1-6.
[4]Signature of high $T_c$ around 25K in higher quality heavily boron-doped diamond, H. Okazaki, T.
Wakita, T. Muro, T. Nakamura, Y. Muraoka, T. Yokoya, S. Kurihara, H. Kawarada, T. Oguchi, and Y.
Takano: Appl. Phys. Lett., 106 (2015) 052691/1-4.
[5]Theoretical study of the structure of boron carbide B12C2, K. Shirai, K. Sakuma, and N. Uemura: Phys.
Rev. B, 90 (2014) 064109/1-10.
[6]Origin of the band dispersion in a metal phthalocyanine crystal, S. Yanagisawa, K. Yamauchi, T.
Inaoka, T. Oguchi, I. Hamada: Phys. Rev. B, 90 (2014) 245141/1-6.
[7]Ab-initio Prediction of Magnetoelectricity in Infinite-Layer CaFeO2 and MgFeO2, K. Yamauchi, T.
Oguchi, S. Picozzi: J. Phys. Soc. Jpn., 83 (2014) 094712/1-6.
[8]Giant spin-driven ferroelectric polarization in TbMnO3 under high pressure, T. Aoyama, K. Yamauchi,
A. Iyama, S. Picozzi, K. Shimizu, T. Kimura: Nature Commun., 5 (2014) 5927/1-7.
[9]First-principles study on structural and electronic properties ofD-S and Na-S crystals, H. Momida, T.
Yamashita and T. Oguchi: J. Phys. Soc. Jpn., 83 (2014) 124713/1-8.
[10]Ab initio study of electronic, magnetic, and spectroscopic properties in A- and B-site-ordered
perovskite CaCu3Fe2Sb2O12, H. Fujii, M. Toyoda, H. Momida, M. Mizumaki, S. Kimura, and T.
Oguchi: Physical Review B, 90 (1) (2014) 014430/1-8.
[11]Symmetry-breaking 60°-spin order in the A-site-ordered perovskite LaMn3V4O12, T. Saito, M.
Toyoda, C. Ritter, S. Zhang, T. Oguchi, J. P. Attfield, and Y. Shimakawa: Physical Review B, 90 (21)
(2014) 214405/1-6.
[12]Ab Initio Study on Pressure-Induced Phase Transition in LaCu3Fe4O12, K. Isoyama, M. Toyoda, K.
― 242 ―
Yamauchi, and T. Oguchi: J. Phys. Soc. Jpn., 84 (2015) 034709/1-5.
ᅜ㝿఍㆟
[1]Defect structure of boron carbides (invited), K. Shirai, K. Sakuma, and N. Uemura: Materials Science
& Technology 2014 (MS&T14).
[2]Defect states of boron carbide B13C2 (invited), K. Shirai, K. Sakuma, and N. Uemura: The 18th
International Symposium on Boron, Borides and Related Materials.
[3]First Principles study on a new structure of Į-tetragonal boron (poster), Naoki Uemura1, Koun Shirai1,
Hagen Eckert2, Jens Kunstmann: The 18th International Symposium on Boron, Borides and Related
Materials.
[4]First-principles calculation of single copper impurity in silicon (poster), T. Fujimura and K. Shirai: The
7th Forum on the Science and Technology of Silicon Materials 2014 (Hamamatsu).
[5]Effect of Dynamics on The Elastic Softening of Vacancy in Si (poster), Koun Shirai and Jun Ishisada:
The 7th Forum on the Science and Technology of Silicon Materials 2014 (Hamamatsu).
[6]First-principles study of Na2C6O6 as a sodium-ion battery cathode (poster), T. Yamashita, H. Momida
and T. Oguchi: MRS 2014 Spring Meeting, San Francisco, USA, April 21-25, 2014.
[7]First-principles study of discharge reactions in Na/FeS2 battery systems (poster), H. Momida and T.
Oguchi: MRS 2014 Spring Meeting, San Francisco, USA, April 21-25, 2014.
[8]Theoretical investigation on the structural stability of Na2+xC6O6 as a sodium-ion battery cathode
(poster), T. Yamashita, H. Momida and T. Oguchi: The 17th International Meeting on Lithium Batteries
(IMLB2014), Como, Italy, June 10-14, 2014.
[9]Discharge reaction mechanism of FeS2 cathodes in Na batteries: First-principles calculations (poster),
H. Momida and T. Oguchi: The 17th International Meeting on Lithium Batteries (IMLB2014), Como,
Italy, June 10-14, 2014.
[10]First-principles study of piezoelectricity in AlN-based materials (invited), H. Momida: The 31st
International Korea-Japan Seminar on Ceramics (KJ-Ceramics 31), Changwon, Korea, November 26-29,
2014.
[11]First-principles study of reaction mechanism in sodium batteries (oral), H. Momida: One-day
Symposium of Computational Nano-Materials Design: New Strategic Materials, Osaka, Japan, January
26, 2015.
[12]A-site magnetic ordering in quadruple perovskite oxides (invited), M. Toyoda, K. Yamauchi, T.
Oguchi: The 18th SANKEN International Symposium and the 13th SANKEN Nanotechnology
Symposium.
[13]A-site magnetic ordering in quadruple perovskite oxides (oral), M. Toyoda, K. Yamauchi, T. Oguchi:
APS March Meeting 2015.
[14]Structural determination of a ternary compound (BN)8C2 by first-principles calculations (poster),
Sho-hei Komori and Koun Shirai: The 18th SANKEN International Symposium, and The 13th SANKEN
Manotechnology Symposium.
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
ᑠཱྀ ከ⨾ኵ
The 17th Asian Workshop on First-Principles Electronic Structure Calculation (ᅜ㝿
― 243 ―
ⓑ஭ ග㞼
ᑠཱྀ ከ⨾ኵ
⤌⧊ጤဨ)
The 18th International Symposium on Boron, Borides and Related Materials
(ISBB-2014) (ᅜ㝿⤌⧊ጤဨ)
NPJ Computational Materials (⦅㞟ጤဨ)
ᅜෆᏛ఍
᪥ᮏ≀⌮Ꮫ఍
ᛂ⏝≀⌮Ꮫ఍
᪥ᮏ㟁Ẽ໬Ꮫ఍
9௳
1௳
1௳
ྲྀᚓᏛ఩
ಟኈ㸦⌮Ꮫ㸧
ᑠ᳃ ᑦᖹ
ಟኈ㸦ᕤᏛ㸧
すᲄ Ὀ⤂
༤ኈ㸦⌮Ꮫ㸧
☾ᒣ ె⏠
➨୍ཎ⌮ィ⟬࡟ࡼࡿ୕ඖ໬ྜ≀ (BN)4C ࡢᵓ㐀Ỵᐃ
➨୍ཎ⌮ィ⟬ࢆ⏝࠸ࡓ ATiO3 (A = Ca,Ba) ࡢṍࡳࡀࡶࡓࡽࡍ⇕㟁≉ᛶ࡬ࡢᙳ
㡪
Ab initio study on electronic states in ACu3Fe4O12 (A=Ca, Sr, La)
⛉Ꮫ◊✲㈝⿵ຓ㔠
ⱝᡭ◊✲(B)
ᒣෆ 㑥ᙪ
ཷク◊✲
ᑠཱྀ ከ⨾ኵ
ඹྠ◊✲
ᑠཱྀ ከ⨾ኵ
㑄⛣㔠ᒓ㓟໬≀ࢆ⏝࠸ࡓࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యࡢࣂࣥࢻ࢚ࣥࢪࢽ
࢔ࣜࣥࢢ
༢఩㸸༓෇
1,560
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
➨୍ཎ⌮ィ⟬࡟ࡼࡿ㟁Ꮚ≧ែゎᯒ
ᰴᘧ఍♫ࢹࣥࢯ࣮
➨୍ཎ⌮ィ⟬ࢆ⏝࠸ࡓ᪂つᅽ㟁ᮦᩱ
ࡢ᥈⣴
1,068
ඖ⣲ᡓ␎◊✲ᣐⅬᙧᡂࣉࣟࢢ࣒ࣛࠕゐ
፹࣭㟁ụᮦᩱඖ⣲ᡓ␎◊✲ᣐⅬࠖ஧ḟ
㟁ụṇᴟᮦᩱࡢᅛయ㟁Ꮚㄽ
4,600
ࡑࡢ௚ࡢ➇தⓗ◊✲㈨㔠
ᑠཱྀከ⨾ኵ
ᩥ㒊⛉Ꮫ┬
14,950
ࢯࣇࢺࢼࣀ࣐ࢸࣜ࢔ࣝ◊✲ศ㔝
ཎⴭㄽᩥ
[1]Electron-Donor Function of Methanofullerenes in Donor–Acceptor Bulk Heterojunction Systems, Y. Ie,
M. Karakawa, S. Jinnai, H. Yoshida, A. Saeki, S. Seki, S. Yamamoto, H. Ohkita, Y. Aso: Chem. Commun,
50 (31) (2014) 4123-4125.
[2]Solution-Processable n-Type Semiconducting Materials Containing a Carbonyl-Bridged
Thiazole-Fused System, Y. Ie, C. Sato, M. Nitani, H. Tada, Y. Aso: Chem. Lett., 43 (10) (2014)
1640-1642.
[3]Synthesis, Properties, and n-Type Transistor Characteristics of ʌ-Conjugated Compounds Having a
Carbonyl-Bridged Thiazole-Fused Polycyclic System, Y. Ie, C. Sato, M. Nitani, H. Tada, Y. Aso: J.
Fluorine Chem., 174 (2015) 75-80.
[4]Synthesis, Properties, and n-Type Transistor Characteristics of ʌ-Conjugated Compounds Having a
Carbonyl-Bridged Thiazole-Fused Polycyclic System, Y. Ie, C. Sato, M. Nitani, H. Tada, Y. Aso: Chem.
Eur. J., 20 (50) (2014) 16509-16515.
[5]Enhanced Photovoltaic Performance of Amorphous Copolymers Based on Dithienosilole and
Dioxocycloalkene-annelated Thiophene, J. Huang, Y. Ie, M. Karakawa, M. Saito, I. Osaka, Y. Aso: Chem.
Mater., 26 (24) (2014) 6971-6978.
― 244 ―
[6]Air-Stable n-Type Organic Field-Effect Transistors Based on
4,9-Dihydro-s-indaceno[1,2-b:5,6-b']dithiazole-4,9-dione Unit, Y. Ie, M. Ueta, M. Nitani, N. Tohnai, M.
Miyata, H. Tada, Y. Aso: Chem. Mater., 27 (2) (2015) 648.
[7]A Series of ʌ-Extended Thiadiazoles Fused with Electron-Donating Heteroaromatic Moieties:
Synthesis, Properties, and Polymorphic Crystals, S.-i. Kato, T. Furuya, M. Nitani, N. Hasebe, Y. Ie, Y. Aso,
T. Yoshihara, S. Tobita, Y. Nakamura: Chem. Eur. J., 21 (7) (2015) 3115-3118.
[8]N-phenyl[60]fulleropyrrolidines: Alternative Acceptor Materials to PC61BM for High Performance
Organic Photovoltaic Cells, M. Karakawa, T. Nagai, K. Adachi, Y. Ie, Y. Aso: J. Mater. Chem. A, 2 (48)
(2014) 20889-20895.
ᅜ㝿఍㆟
[1]Synthesis, Properties, and Photovoltaic Performance of Low-Bandgap Copolymers Based on
Dithienosilole and Dioxocycloalkene-annelated Thiophene (oral), Y. Ie, J. Huang, M. Karakawa, Y. Aso:
2014 MRS Fall Meeting.
[2]Development of Organic Semiconducting Materials for Organic Photovoltaics (invited), Y. Ie, Y. Aso:
The 18th SANKEN International the 13th SANKEN Nanotechnology Symposium.
[3]Naphthalene bis(dicarboximide)- and Perylene bis(dicarboximide)-based Acceptors: Synthesis,
Properties, and Solar Cell Performance (poster), S. Chatterjee, Y. Ie, M. Karakawa, Y. Aso: The 18th
SANKEN International the 13th SANKEN Nanotechnology Symposium.
[4]Novel Naphtho[2,3-c]thiophene-4,9-dione-Based Copolymers as p-Type Semiconductors for
Bulk-Heterojunction Organic Photovoltaic Devices (oral), J. Huang, Y. Ie, M. Karakawa, Y. Aso: KJF
International Conference on Organic Materials for Electronics and Photonics.
[5]Fluorine Atoms Containing Fulleropyrrolidine Derivatives for Organic Solar Cells (poster), M.
Karakawa, T. Nagai, K. Adachi, Y. Ie, Y. Aso: KJF International Conference on Organic Materials for
Electronics and Photonics.
[6]N-Phenyl-substituted Fulleropyrrolidine Derivatives for High Performance Organic Photovoltaics
(oral), M. Karakawa, T. Nagai, K. Adachi, Y. Ie, Y. Aso: The 22nd International Conference for Science
and Technology of Synthetic Metals (ICSM2014).
[7]Photovoltaic Performances of Novel Donor–Acceptor Copolymers Based on
Naphtho[2,3-c]thiophene-4,9-dione as Acceptor Units (poster), J. Huang, Y. Ie, M. Karakawa, Y. Aso: The
22nd International Conference for Science and Technology of Synthetic Metals (ICSM2014).
[8]Synthesis, Properties, and n-Type Performances of Electronegative ʌ-Conjugated Systems Having
Fluorine Substituents (invited), Y. Ie: International Conference on Fluorine Chemistry 2014 Tokyo.
[9]Fulleropyrrolidine Derivatives for Organic Photovoltaics: Influence of Introduced Fluorine Atoms on
Device Performance (poster), T. Nagai, M. Karakawa, Y. Ie, K. Adachi, Y. Aso: International Conference
on Fluorine Chemistry 2014 Tokyo.
[10]Synthesis, Properties, and n-Type Organic Photovoltaic Performances of Three-dimensional
Electron-accepting Compounds Containing Perylene Bis(dicarboxyimide)s (oral), Y. Ie, T. Sakurai, S.
Jinnai, M. Karakawa, Y. Aso: Grand Renewable Energy 2014.
[11]Development of New pi-Conjugated Systems towards Organic Semiconducting Materials (invited), Y.
Ie: 8th Singapore International Chemistry Conference (SICC-8).
― 245 ―
[12]Novel Donor–Acceptor p-Type Copolymers Based on Dioxoring-Annelated [c]Thiophene Units for
Bulk-Heterojunction Organic Photovoltaics (plenary), J. Huang, Y. Ie, M. Karakawa, Y. Aso: International
Symposium on Polymer Science and Technology (MACRO2015).
ゎㄝࠊ⥲ㄝ
㟁Ꮚ㍺㏦ᆺ ʌ ඹᙺ໬ྜ≀ࡢ㛤Ⓨ࡜ሬᕸᆺ᭷ᶵ㟁⏺ຠᯝࢺࣛࣥࢪࢫࢱ࡬ࡢᛂ⏝, ᐙ ⿱㝯ࠊᏳ⸽ⰾ
㞝, ໬Ꮫᕤᴗ, ໬Ꮫᕤᴗ♫, 65 (2014), 30-36.
ⴭ᭩
[1]᭷ᶵⷧ⭷ኴ㝧㟁ụᮦᩱ㸸ࣇࣞࣟࣆࣟࣜࢪࣥㄏᑟయࡢኴ㝧㟁ụᛂ⏝ (ᯇᑿ ㇏)“ࣇ࣮ࣛࣞࣥㄏᑟ
య࣭ෆໟᢏ⾡ࡢ᭱๓⥺”, ㎞ᕝ ㄔࠊᏳ⸽ⰾ㞝, ࢩ࣮࢚࣒ࢩ࣮ฟ∧, (178–186) 2014.
ᅜෆᏛ఍
᪥ᮏ໬Ꮫ఍
᭷ᶵ ʌ 㟁Ꮚࢩ࣏ࣥࢪ࣒࢘
᭷ᶵ඾ᆺඖ⣲໬Ꮫウㄽ఍
ᇶ♏᭷ᶵ໬Ꮫウㄽ఍
ᛂ⏝≀⌮Ꮫ఍
㧗ศᏊウㄽ఍
ྲྀᚓᏛ఩
ಟኈ㸦ᕤᏛ㸧
➲⏣ ⩧ᖹ
ಟኈ㸦ᕤᏛ㸧
⏣௦ ᙬ
9௳
2௳
1௳
3௳
2௳
1௳
᪂つࣆࣛࢪࣀࢪࢳ࢔ࢰ࣮ࣝㄏᑟయࡢྜᡂ࡜≀ᛶࠊ࠾ࡼࡧࡇࢀࢆྵࡴ ʌ ඹᙺࢥ
࣏࣐࣮ࣜࡢ༙ᑟయ≉ᛶ
ʌ ᥋ྜࢆᣦྥࡋࡓ୕⬮ᆺ࢔࣮ࣥ࢝໬ྜ≀ࡢ㛤Ⓨ࡜㔠࠾ࡼࡧࢢࣛࣇ࢓࢖ࢺ㟁ᴟ
ୖ༢ศᏊ⭷ࡢ≉ᛶホ౯
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(A)
⢭⦓タィࢼࣀඹᙺศᏊ࣡࢖ࣖࡢ๰〇࡟ᇶ࡙ࡃศᏊࢹࣂ࢖ࢫ㛤Ⓨ
Ᏻ⸽ ⰾ㞝
᪂Ꮫ⾡㡿ᇦ◊✲ ศᏊ࢔࣮࢟ࢸࢡࢺࢽࢡࢫ࡟ྥࡅࡓᶵ⬟ᛶศᏊྜᡂ࡜ᵓ㐀≀ᛶ┦
㸦◊✲㡿ᇦᥦ᱌ 㛵ゎ᫂
ᆺ㸧ィ⏬◊✲
ᐙ ⿱㝯
ᣮᡓⓗⴌⱆ◊✲ ༢ศᏊ࡛ࡢග㟁ኚ᥮ほ ࡟ྥࡅࡓᶵ⬟ᛶ ʌ 㟁Ꮚ⣔ศᏊࡢ๰ฟ
ᐙ ⿱㝯
ᇶ┙◊✲(B)
༢ศᏊ⣲Ꮚࡢᶵᵓゎ᫂ࢆඛᑟࡍࡿᶵ⬟ᛶ ʌ 㟁Ꮚ⣔ࡢ๰〇
ᐙ ⿱㝯
ཷク◊✲
Ᏻ⸽ ⰾ㞝
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ ᭷ᶵⷧ⭷ኴ㝧㟁ụ⏝࢔ࢡࢭࣉࢱ࣮ᮦᩱ
ࡢᐇ⏝໬
ᐙ ⿱㝯
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ ᭷ᶵ㟁ゎຠᯝࢺࣛࣥࢪࢫࢱ⣲Ꮚࡢ≀ᛶ
ホ౯
ඹྠ◊✲
Ᏻ⸽ ⰾ㞝
ࢲ࢖࢟ࣥᕤᴗᰴᘧ఍♫
᭷ᶵⷧ⭷ኴ㝧㟁ụ⏝᭷ᶵ༙ᑟయࡢ㛤Ⓨ
▼ཎ⏘ᴗᰴᘧ఍♫
᭷ᶵ༙ᑟయᮦᩱࡢస〇࡜ࡑࡢホ౯࡟㛵
Ᏻ⸽ ⰾ㞝
ࡍࡿ◊✲
Ᏻ⸽ ⰾ㞝
ఫ཭໬Ꮫᰴᘧ఍♫
᭷ᶵ࢚ࣞࢡࢺࣟࢽࢡࢫᮦᩱࡢ㛤Ⓨ
ᮾὒ࢖ࣥ࢟ SC ࣮࣍ࣝࢹ ࣇ࢛ࢺ࢚ࣞࢡࢺࣟࢽࢡࢫᶵ⬟ᛶⰍ⣲ᮦ
㎞ᕝ ㄔ
࢕ࣥࢢࢫᰴᘧ఍♫
ᩱ࡟㛵ࡍࡿ◊✲
ࣂ࢖࢜ࢼࣀࢸࢡࣀࣟࢪ࣮◊✲ศ㔝
ཎⴭㄽᩥ
― 246 ―
༢఩㸸༓෇
10,400
10,140
1,300
3,640
3,172
4,160
2,500
3,654
833
0
[1]Detection of post-translational modifications in single peptides using electron tunnelling currents, T.
Ohshiro, M Tsutsui, K. Yokota, M. Furuhashi, M. Taniguchi, T. Kawai: Nature Nanotechnology, 9 (2014)
835-840.
[2]Molecular Wiring Method Based on Polymerization or Copolymerization of an Insulated
pi-Conjugated Monomer, J. Terao, K. Homma, Y. Konoshima, M. Taniguchi, M. Kiguchi, Y. Komoto, M.
Horikawa, Y. Naito, T. Fujihara, Y. Tsuji: Bulletin of the Chemical Society of Japan, 87 (2014) 871-873.
[3]Graphene/hexagonal boron nitride/graphene nanopore for electrical detection of single molecules, Y.
He, M. Tsutsui, S. Ryuzaki, K. Yokota, M. Taniguchi and T. Kawai: NPG Asia Materials, 6 (2014) 1-9.
[4]Discrimination of equi-sized nanoparticles by surface charge state using low-aspect-ratio pore sensors,
A. Arima, M. Tsutsui, and M. Taniguchi: Applied Physics Letters, 104 (2014) 163112- 163115.
[5]Fabrications of insulator-protected nanometer-sized electrode gaps, A. Arima, M. Tsutsui, T. Morikawa,
K. Yokota and M. Taniguchi: Journal of Applied Physics, 115 (2014) 11431-11434.
[6]Nonequilibrium Ionic Response of Biased Mechanically Controllable Break Junction (MCBJ)
Electrodes, K. Doi, M. Tsutsui, T. Ohshiro, CC Chien, M. Zwolak, M. Taniguchi, T. Kawai, S. Kawano,
and M. Di Ventra: The Journal of Physical Chemistry C, 118 (2014) 3758–3765.
[7]Thermoelectric Voltage Measurements of Atomic and Molecular Wires Using Microheater-Embedded
Mechanically-Controllable Break Junctions, T. Morikawa, A. Arima, M. Tsutsui and M. Taniguchi:
Nanoscale, 6 (2014) 8235-8241.
[8]Electrode-embedded nanopores for label-free single-molecule sequencing by electric currents, K.
Yokota, M. Tsutsui and M. Taniguchi: RSC Advances, 4 (2014) 15886–15899.
[9]Selective Multidetection Using Nanopores, M. Taniguchi: Analytical Chemistry, 87 (2014) 188-199.
ᅜ㝿఍㆟
[1]Single Molecular Technologies to Identify Central Dogma (invited), ㇂ཱྀ ṇ㍤: The 6th IEEE
International Nanoelectronics Conference 2014 (IEEE INEC 2014).
[2]Single-molecule electrical sequencing of biomolecules (invited), ㇂ཱྀ ṇ㍤: The 7th International
Symposium on Surface Science (ISSS-7).
[3]Tunneling current measurements for single-molecule DNA sequencing (invited), ⟄஭ ┿ᴋ: NCTS
– NCTU Seminar.
[4]Single Molecule Electrical Sequencing Technology (invited), ㇂ཱྀ ṇ㍤: PITTOCON 2015
CONFERENCE & EXPO.
[5]STM and Gating Nanopores for Single Molecule DNA and RNA Electrical Sequencing (invited), ᕝྜ
▱஧: DIPC School “Scanning Probe Microscopy (Tribute to Heinrich Roher)”.
[6]SINGLE-MOLECULE SEQUENCING TECHNOLOGIES OF BIOMOLECULES VIA ELECTRIC
CURRENTS (plenary), ㇂ཱྀ ṇ㍤: The 18th International Conference on Miniaturized Systems for
Chemistry and Life Sciences (MicroTAS 2014).
[7]Single Molecule DNA and RNA Sequencing by Gating Nanopore systems (invited), ᕝྜ ▱஧: The
7th International Symposium on Surface Science (ISSS-7).
[8]Future of Nanotechnology - Dreams and Sciences - (invited), ᕝྜ ▱஧: 18th SANKEN
International Symposium and the 13th SANKEN Nanotechnology Symposium.
― 247 ―
ゎㄝࠊ⥲ㄝ
㸯ศᏊ᳨ฟᢏ⾡ࢆ⏝࠸ࡓ DNA࣭RNA ሷᇶ㓄ิࡢ㉸㧗㏿ィ , ᕝྜ▱஧ࠊ㇂ཱྀṇ㍤, ᛂ⏝≀⌮, බ
┈♫ᅋἲேᛂ⏝≀⌮Ꮫ఍, 83 (2014), 363-365.
㸯ศᏊࢩ࣮ࢡ࢚ࣥࢧ࣮ 㹼DNA࣭RNA࣭࣌ࣉࢳࢻࡢゎㄞ㹼, ㇂ཱྀṇ㍤, ⏕࿨໬Ꮫࣞࢱ࣮, ࣇࣟࣥ
ࢸ࢕࢔⏕࿨໬Ꮫ◊✲఍, 47 (2015), 9-14.
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(A)
㇂ཱྀ ṇ㍤
ᇶ┙◊✲(S)
㇂ཱྀ ṇ㍤
ᣮᡓⓗⴌⱆ◊
✲
⟄஭ ┿ᴋ
ⱝᡭ◊✲(A)
⟄஭ ┿ᴋ
ᇶ┙◊✲(B)
⏣୰ ⿱⾜
ⱝᡭ◊✲(B)
ᶓ⏣ ୍㐨
ᇶ┙◊✲(A)
ᕝྜ ▱஧
ཷク◊✲
⟄஭ ┿ᴋ
⥲ົ┬
ᕝྜ ▱஧
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
ዡᏛᐤ㝃㔠
⟄஭ ┿ᴋ
⟄஭ ┿ᴋ
ඹྠ◊✲
㇂ཱྀ ṇ㍤
㸯ศᏊ࣌ࣉࢳࢻࢩ࣮ࢡ࢚ࣥࢩࣥࢢἲࡢ㛤Ⓨ
༢఩㸸༓෇
15,210
ࢺࣥࢿࣝ㟁ὶ࡟ࡼࡿ㸯ศᏊࢩ࣮ࢡ࢚ࣥࢩࣥࢢἲ
42,510
1 ḟඖ㔞Ꮚᵓ㐀ᮦᩱࡢ⇕㟁ᛶ⬟ホ౯ἲࡢ๰ᡂ
3,900
Ὃື㏿ᗘไᚚᶵ⬟ࢆ᭷ࡍࡿ༢୍ศᏊ㆑ูࢹࣂ࢖ࢫࡢ๰〇
5,850
ࢢࣛࣇ࢙ࣥࢆ⏝࠸ࡓ㸯ศᏊࢩ࣮ࢣࣥࢩࣥࢢ
2,470
ࢼࣀ✵㛫ෆ≀㉁㍺㏦⌧㇟ࡢゎ᫂࡜୍ศᏊ࢖ࣥࣆ࣮ࢲࣥࢫィ 3,250
ࢼࣀࢳࣕࢿࣝ㟁ᴟࢹࣂ࢖ࢫ࡟ࡼࡿ㛗㙐 DNA ࡢ࢚ࣆࢪ࢙ࢿࢸ࢕
ࢵࢡ≀ᛶࡢ㉸㧗㏿᳨ฟ
17,810
᭷ᶵศᏊ⇕㟁Ⓨ㟁ࢩ࣮ࢺࣔࢪ࣮ࣗ
ࣝࡢ◊✲㛤Ⓨ
ࢼࣀ࣭࣐࢖ࢡ࣏ࣟ࢔ࢆ⏝࠸ࡓ I㹬
SECT ࢩࢫࢸ࣒ࡢ㛤Ⓨ
බ┈㈈ᅋἲே✄┒㈈ᅋ ⌮஦㛗 ✄┒࿴ኵ
බ┈㈈ᅋἲே᪫◪Ꮚ㈈ᅋ ⌮஦㛗 ⏣୰㚩஧
ࢡ࢜ࣥࢱ࣒ࣂ࢖࢜ࢩࢫ
୍ศᏊゎᯒᢏ⾡࡟ᇶ࡙ࡃ⏕≀ヨ
ࢸ࣒ࢬᰴᘧ఍♫
ᩱゎᯒ⿦⨨࣭ࢹࣂ࢖ࢫࡢホ౯
ࡑࡢ௚ࡢ➇தⓗ◊✲㈨㔠
㇂ཱྀ ṇ㍤
ᅜ❧኱Ꮫἲேி㒔኱Ꮫ 㸦ᩥ㒊⛉Ꮫ┬ࡢ෌ጤク㸧
ᚤ⣽ຍᕤࣉࣛ
ࢵࢺࣇ࢛࣮࣒
ᐇ᪋ᶵ㛵
8,632
25,300
1,000
2,000
0
36,000
⎔ቃ࣭࢚ࢿࣝࢠ࣮ࢼࣀᛂ⏝ศ㔝
ཎⴭㄽᩥ
[1]Robust protection from backscattering in the topological insulator Bi1.5Sb0.5Te1.7Se1.3, Sunghun Kim,
Shunsuke Yoshizawa, Yukiaki Ishida, Kazuma Eto, Kouji Segawa, Yoichi Ando, Shik Shin, and Fumio
Komori: Phys. Rev. Lett., 112 (13) (2014) 136802/1-5.
[2]Top gating of epitaxial (Bi1-xSbx)2Te3 Topological insulator thin films, Fan Yang, A. A. Taskin, Satoshi
Sasaki, Kouji Segawa, Yasuhide Ohno, Kazuhiko Matsumoto, and Yoichi Ando: Appl. Phys. Lett., 104
(16) (2014) 161614/1-5.
[3]Infrared pseudogap in cuprate and pnictide high-temperature superconductors, S. J. Moon, Y. S. Lee, A.
A. Schafgans, A. V. Chubukov, S. Kasahara, T. Shibauchi, T. Terashima, Y. Matsuda, M. A. Tanatar, R.
Prozorov, A. Thaler, P. C. Canfield, S. L. Bud'ko, A. S. Sefat, D. Mandrus, K. Segawa, Y. Ando, and D. N.
― 248 ―
Basov: Phys. Rev. B, 90 (1) (2014) 014503/1-16.
[4]Doping-dependent charge dynamics in CuxBi2Se3, Luke J. Sandilands, Anjan A. Reijnders, Markus
Kriener, Kouji Segawa, Satoshi Sasaki, Yoichi Ando, and Kenneth S. Burch: Phys. Rev. B, 90 (9) (2014)
094503/1-6.
[5]Pb5Bi24Se41: A New Member of the Homologous Series Forming Topological Insulator
Heterostructures, Kouji Segawa, A. A. Taskin, and Yoichi Ando: J. Solid State Chem., 221 (2014)
196-201.
[6]Electrical Detection of the Spin Polarization Due to Charge Flow in the Surface State of the
Topological Insulator Bi1.5Sb0.5Te1.7Se1.3, Yuichiro Ando, Takahiro Hamasaki, Takayuki Kurokawa, Kouki
Ichiba, Fan Yang, Mario Novak, Satoshi Sasaki, Kouji Segawa, Yoichi Ando, and Masashi Shiraishi:
Nano Lett., 14 (11) (2014) 6226-6230.
[7]Spin-Electricity Conversion Induced by Spin Injection into Topological Insulators, Y. Shiomi, K.
Nomura, Y. Kajiwara, K. Eto, M. Novak, Kouji Segawa, Yoichi Ando, and E. Saitoh: Phys. Rev. Lett., 113
(19) (2014) 196601/1-5.
[8]Superconductor derived from a topological insulator heterostructure, Satoshi Sasaki, Kouji Segawa,
and Yoichi Ando: Phys. Rev. B, 90 (22) (2014) 220504(R)/1-5.
[9]Scanning tunneling spectroscopy study of quasiparticle interference on the dual topological insulator
Bi1-xSbx, Shunsuke Yoshizawa, Fumitaka Nakamura, Alexey A. Taskin, Takushi Iimori, Kan Nakatsuji,
Iwao Matsuda, Yoichi Ando, and Fumio Komori: Phys. Rev. B, 91 (4) (2015) 045423/1-6.
[10]Large linear magnetoresistance in the Dirac semimetal TlBiSSe, Mario Novak, Satoshi Sasaki, Kouji
Segawa, and Yoichi Ando: Phys. Rev. B, 91 (4) (2015) 041203(R)/1-4.
[11]Topological Crystalline Insulators and Topological Superconductors: From Concepts to Materials,
Yoichi Ando and Liang Fu: Annu. Rev. Condens. Matter Phys., 6 (2015) 361-381.
[12]Ultrafast carrier relaxation through Auger recombination in the topological insulator
Bi1.5Sb0.5Te1.7Se1.3, Yoshito Onishi, Zhi Ren, Kouji Segawa, Wawrzyniec Kaszub, Macieg Lorenc, Yoichi
Ando, and Koichiro Tanaka: Phys. Rev. B, 91 (8) (2015) 085306/1-12.
[13]Topological proximity effect in a topological insulator hybrid, T. Shoman, A. Takayama, T. Sato, S.
Souma, T. Takahashi, T. Oguchi, Kouji Segawa, and Yoichi Ando: Nature Communications, 6 (2015)
6547/1-6.
ᅜ㝿఍㆟
[1]Topological Insulators and Superconductors (invited), Y. Ando: OIST International Workshop on
Novel Quantum Materials and Phases (NQMP2014).
[2]Topological Insulators and Superconductors (invited), Y. Ando: New Trends in Topological Inslators
(NTTI) 2014.
[3]Progress toward Topological Insulator Devices (invited), Y. Ando: 32nd International Conference on
the Physics of Semiconductors (ICPS 2014).
[4]Topological Insulators and Superconductors (invited), Y. Ando: Workshop on Novel Quantum States in
Condensed Matter (NQS2014).
[5]Topological Superconductivity Based on Topological Insulators (invited), Y. Ando: International
― 249 ―
Conference on Topological Quantum Phenomena (TQP2014).
[6]Superconducting Sn1-xInxTe Nanoplates (poster), S. Sasaki and Y. Ando: International Conference on
Topological Quantum Phenomena (TQP2014).
[7]Highly Gate-tunable Topological-Inslator Devices (poster), F. Yang, A. A. Taskin, S. Sasaki, K.
Segawa, Y. Ohno, K. Matsumoto, Y. Ando: International Conference on Topological Quantum Phenomena
(TQP2014).
[8]Electrical injection and extraction of spin polarized current through a ferromagnetic metal / topological
insulator interface (poster), Y. Ando, T. Hamasaki, F. Yang, M. Novak, S. Sasaki, K. Segawa, Y. Ando, M.
Shiraishi: International Conference on Topological Quantum Phenomena (TQP2014).
[9]Manipulation of topological states in a topological-insulator heterostructure (poster), T. Sato, K.
Nakayama, Y. Tanaka, S. Souma, T. Takahashi, K. Eto, S. Sasaki, K. Segawa, and Y. Ando: International
Conference on Topological Quantum Phenomena (TQP2014).
[10]Efficient Dual-Gate Tuning of Fermi Level in Thin-Film Topological Insulator (oral), A. Taskin, Fan
Yang, Satoshi Sasaki, Kouji Segawa, Yasuhide Ohno, Kazuhiko Matsumoto, Yoichi Ando: APS March
Meeting 2015.
[11]Manipulation of topological states in a topological-insulator heterostructure (oral), Yusuke Tanaka,
Kosuke Nakayama, Takafumi Sato, Seigo Souma, Takashi Takahashi, Kazuma Eto, Satoshi Sasaki, Kouji
Segawa, Yoichi Ando: APS March Meeting 2015.
ゎㄝࠊ⥲ㄝ
ࢺ࣏ࣟࢪ࢝ࣝ㉸ఏᑟయ㸸᥈⣴࡜᳨ドࡢヨࡳ, Ᏻ⸨㝧୍, ࣃࣜࢸ࢕, ୸ၿ, 30 (2015), 16-17.
ⴭ᭩
[1]ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యධ㛛 “ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕యධ㛛”, Ᏻ⸨ 㝧୍, ㅮㄯ♫, (1-236) 2014.
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
Ᏻ⸨㝧୍
International Conference on Topological Quantum Phenomena (TQP2014) (⤌⧊ጤ
ဨ)
ᅜෆᏛ఍
᪥ᮏ≀⌮Ꮫ఍ 2014 ᖺ⛅Ꮨ኱఍
᪥ᮏ≀⌮Ꮫ఍➨ 70 ᅇᖺḟ኱఍
9௳
3௳
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(S)
Ᏻ⸨ 㝧୍
ࢺ࣏ࣟࢪ࢝ࣝ⤯⦕య㺃㉸ఏᑟయ࡟࠾ࡅࡿ᪂ወ࡞㔞Ꮚ⌧㇟ࡢ᥈ồ
༢఩㸸༓෇
25,740
ࢼࣀ▱⬟ࢩࢫࢸ࣒ศ㔝
ཎⴭㄽᩥ
[1]Bayesian estimation of causal direction in acyclic structural equation models with individual-specific
confounder variables and non-Gaussian distributions, S. Shimizu, K. Bollen: Journal of Machine
Learning Research, 15 (-) (2014) 2629-2652.
[2]Application of continuous and structural ARMA modeling for noise analysis of a BWR coupled core
and plant instability event, M. Demeshko, A. Dokhane, T. Washio, H. Ferroukhi, Y. Kawahara and C.
Aguirre: Annals of Nuclear Energy, 75 (-) (2015) 645-657.
― 250 ―
ᅜ㝿఍㆟
[1]Improving iForest with relative mass, S. Aryal, K. M. Ting, J. Wells and T. Washio: Proc. of
PAKDD2014: 18th Pacific-Asia Conference on Knowledge Discovery and Data Mining, Advances in
Knowledge Discovery and Data Mining, Lecture Notes in Computer Science, 8444 (2014) 510-521.
[2]mp-dissimilarity: A data dependent dissimilarity measure, S. Aryal, K. M. Ting, G. Haffari and T.
Washio: Proc. of ICDM2014:IEEE International Conference on Data Mining 2014, 1 (2014) DM570.
[3]A non-Gaussian approach for estimating possible causal direction in the presence of latent confounders
(invited), S. Shimizu: Conference on Statistics and Causality 2014.
[4]Estimation of causal direction in the presence of latent confounders and linear non-Gaussian structural
equation models (invited), S. Shimizu: Causal Modeling and Machine Learning.
[5]A performance comparison of generative and discriminative models in causal and anticausal problems
(poster), P. Blöbaum, S. Shimizu and T. Washio: 17th International Conference on Artificial Intelligence
and Statistics.
[6]On approximate non-submodular minimization via tree-structured supermodularity (poster), Y.
Kawahara, R. Iyer and J. Bilmes: Proc. of NIPS 2014 Workshop on Discrete and Combinatoria.
[7]Multiple Testing Correction in Graph Mining (invited), M. Sugiyama: Tokyo Workshop on Statistically
Sound Data Mining.
ゎㄝࠊ⥲ㄝ
ᶵᲔᏛ⩦࡟ࡼࡿ᝟ሗㄽⓗ㔞Ꮚ≧ែࡢ␗ᖖ᳨▱, ⚟஭೺୍, ேᕤ▱⬟, ேᕤ▱⬟Ꮫ఍, 30 (2015),
217-223.
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
ᮡᒣ 㯢ே
The 25th European Conference on Machine Learning and 18th Principles and Practice
of Knowledge Discovery in Databases (ࣉࣟࢢ࣒ࣛጤဨ)
ᮡᒣ 㯢ே
The 6th Asian Conference on Machine Learning (ࣉࣟࢢ࣒ࣛጤဨ)
㮖ᑿ 㝯
Neural Information Processing Systems Foundation 2014 (NIPS 2014) (ࣉࣟࢢ࣒ࣛ
ጤဨ)
㮖ᑿ 㝯
The European Conference on Machine Learning and Principles and Practice of
Knowledge Discovery in Databases (ECML/PKDD 2015) (ㄽᩥㄅ㒊㛛ᐈဨ⦅㞟ဨ)
㮖ᑿ 㝯
IEEE International Conference on Data Mining 2015 (ICDM2015) (ࢥࣥࢸࢫࢺጤဨ
㛗)
㮖ᑿ 㝯
The 19th Pacific-Asia Conference on Knowledge Discovery and Data Mining 2015
(PAKDD2015) (ᗈሗጤဨ㛗)
㮖ᑿ 㝯
ACM SIG-KDD'15: The 21st ACM SIGKDD Conference on Knowledge Discovery
and Data Mining (ࣉࣟࢢ࣒ࣛጤဨ)
㮖ᑿ 㝯
The 19th Pacific-Asia Conference on Knowledge Discovery and Data Mining
(PAKDD2014) (ࢩࢽ࢔ࣉࣟࢢ࣒ࣛጤဨ)
㮖ᑿ 㝯
The 2015 SIAM Data Mining Conference (SDM 2015) (ࣉࣟࢢ࣒ࣛጤဨ)
㮖ᑿ 㝯
IEEE International Conference on Data Mining 2015 (ICDM2015) (ࣉࣟࢢ࣒ࣛጤ
ဨ)
㮖ᑿ 㝯
Society for Industrial and Applied Mathematics, Division of Data Mining and
Analytics, Society for Industrial and Applied Mathematics (ࣉࣟࢢ࣒ࣛᣦ᥹⪅)
㮖ᑿ 㝯
DS-2014: the Seventeenth International Conference on Discovery Science (ࣉࣟࢢࣛ
࣒ጤဨ)
㮖ᑿ 㝯
ேᕤ▱⬟Ꮫ఍ᅜ㝿ࢩ࣏ࣥࢪ࣒࢘(JSAI-isAI 2014) (࢔ࢻࣂ࢖ࢨ࣮ࣜጤဨ)
㮖ᑿ 㝯
ACM SIGKDD'14: The 20th ACM SIGKDD Conference on Knowledge Discovery
and Data Mining (ࣉࣟࢢ࣒ࣛጤဨ)
― 251 ―
㮖ᑿ 㝯
㮖ᑿ 㝯
㮖ᑿ 㝯
㮖ᑿ 㝯
Ἑཎ ྜྷఙ
Ἑཎ ྜྷఙ
Ἑཎ ྜྷఙ
Ἑཎ ྜྷఙ
Ἑཎ ྜྷఙ
ECML/PKDD 2014: The European Conference on Machine Learning and Principles
and Practice of Knowledge Discovery in Databases 2014 (ࣉࣟࢢ࣒ࣛጤဨ)
The Second IEEE ICDM (IEEE International Conference on Data Mining) Workshop
on Causal Discovery (CD 2014) (⤌⧊ጤဨ)
ேᕤ▱⬟Ꮫ఍ேᕤ▱⬟Ꮫ஦඾᪂∧⦅㞟ጤဨ఍ (⦅㞟ጤဨ)
ேᕤ▱⬟Ꮫ఍඲ᅜ኱఍ (ࣉࣟࢢ࣒ࣛጤဨ㛗)
Workshop on Graph-based Algorithms for Big Data and its Applications (ඹྠࣉࣟࢢ
࣒ࣛጤဨ㛗)
The 6th Asian Conference on Machine Learning (ࣉࣟࢢ࣒ࣛጤဨ)
The 17th International Conference on Artificial Intelligence and Statistics (ࣉࣟࢢࣛ
࣒ጤဨ)
The 23rd International World Wide Web Conference (ࣉࣟࢢ࣒ࣛጤဨ)
2014 SIAM International Conference on Data Mining (ࣉࣟࢢ࣒ࣛጤဨ)
ᅜෆᏛ఍
➨ 28 ᅇேᕤ▱⬟Ꮫ఍඲ᅜ኱఍
ேᕤ▱⬟Ꮫ఍ ➨ 95 ᅇ ேᕤ▱⬟ᇶᮏၥ㢟◊✲఍
ேᕤ▱⬟Ꮫ఍ ➨ 94 ᅇ ேᕤ▱⬟ᇶᮏၥ㢟◊✲఍
ᩘᏛ༠ാࣉࣟࢢ࣒࣮ࣛ࣡ࢡࢩࣙࢵࣉ ☜⋡ⓗࢢࣛࣇ࢕࢝ࣝࣔࢹࣝ
➨ 28 ᅇேᕤ▱⬟Ꮫ఍඲ᅜ኱఍
5௳
1௳
1௳
1௳
3௳
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(A)
㮖ᑿ 㝯
ᣮᡓⓗⴌⱆ◊
✲
㮖ᑿ 㝯
㉸㧗ḟඖࢹ࣮ࢱ✵㛫࡟࠾ࡅࡿ⤫ィⓗ᥎ᐃ࣭ࢩ࣑࣮ࣗࣞࢩࣙࣥཎ
⌮ࡢ㛤Ⓨ࡜ᛂ⏝ᒎ㛤
ࣔࢹ࣐ࣝ࢖ࢽࣥࢢ㸸㉸㧗ḟඖ኱つᶍࢹ࣮ࢱ࠿ࡽࡢᒁᡤࣔࢹࣝ᥈
⣴ิᣲᡭἲࡢ᥈ồ
༢఩㸸༓෇
13,520
2,080
ࢼࣀ་⒪ᛂ⏝ࢹࣂ࢖ࢫศ㔝
ཎⴭㄽᩥ
[1]Cytosine-bulge dependent fluorescence quenching for real-time hairpin primer PCR, F. Takei, C. Chen,
G. Yu, T. Shibata, C. Dohno, K. Nakatani: Chem. Commun., 50 (2014) 15195-15198.
ᅜ㝿఍㆟
[1]Novel PCR Monitoring System Using Hairpin Primer Having Cytosine-Bulge and Covalent Binding
Fluorescence Molecule (poster), F. Takei, C. Chen, G. Yu, C. Dohno, K. Nakatani: XXI Round Table on
Nucleosides, Nucleotides and Nucleic acids.
[2]Development of Novel PCR Primers for Facile Gene Detection (invited), K. Nakatani: A3RONA 2014
China.
[3]Toward new FET devices detecting DNA (oral), R. K. Verma, A. Michikawa, N. Sabani, F. Takei, K.
Nakatani: 3rd imec Handai International Symposium.
ᅜෆᏛ఍
᪥ᮏ໬Ꮫ఍➨㸷㸳᫓Ꮨᖺ఍
➨ 62 ᅇᛂ⏝≀⌮Ꮫ఍᫓ᏘᏛ⾡ㅮ₇఍
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(B)
Ṋ஭ ྐᜨ
ཷク◊✲
୰㇂ ࿴ᙪ
3௳
1௳
࣊࢔ࣆࣥࣉࣛ࢖࣐࣮㹎㹁㹐ἲࢆ⏝࠸ࡓ࢘࢖ࣝࢫࡢ㧗ឤᗘ᳨ฟἲ
࡟㛵ࡍࡿ◊✲
㸦⊂㸧⛉Ꮫᢏ⾡᣺⯆ᶵᵓ
࣊࢔ࣆࣥ㹎㹁㹐ἲ࡟ࡼࡿࢹࢪࢱࣝ⫢
⅖᳨ᰝᢏ⾡ࡢ㛤Ⓨ
― 252 ―
༢఩㸸༓෇
6,500
9,185
ඹྠ◊✲
୰㇂ ࿴ᙪ
୰㇂ ࿴ᙪ
᪥ᮾ໬ᡂओ
ᰴᘧ఍♫ྂἙ㟁ᕤ࢔ࢻ
ࣂࣥࢫࢺ࢚ࣥࢪࢽ࢔ࣜ
ࣥࢢ
ᶵ⬟ᛶศᏊࡢྜᡂ
⺯ගࢩࢢࢼࣝቑ኱ᆺࣉࣛ࢖࣐࣮ἲࡢ
㛤Ⓨ
864
0
ࢼࣀࢸࢡࣀࣟࢪ࣮タഛ౪⏝ᣐⅬ
ᅜ㝿఍㆟
[1]Introduction about Nanotechnology Open Facilities, Osaka University , K. Norizawa, A. Kitajima, K.
Higuchi, M. Kashiwakura: KANSAI Nanoscience and Nanotechnology Handai Nanoscience and
Nanotechnology international Symposium.
ゎㄝࠊ⥲ㄝ
኱㜰኱Ꮫࠕᚤ⣽ຍᕤࣉࣛࢵࢺࣇ࢛࣮࣒ࠖࡢάື, ἲ⃝ බᐶ, ᕤᴗᮦᩱ, ᪥หᕤᴗ᪂⪺♫, 62[9]
(2014), 81-83.
኱㜰኱Ꮫࢼࣀࢸࢡࣀࣟࢪ࣮タഛ౪⏝ᣐⅬศᏊ࣭≀㉁ྜᡂࣉࣛࢵࢺࣇ࢛࣮࣒ ┬࢚ࢿࣝࢠ࣮ࢼࣀࢹ
ࣂ࢖ࢫᐇ⏝໬ࡲ࡛ࡢ⥲ྜᨭ᥼, ໭ᓥ ᙲࠊ⏣୰ ⚽࿴, ᕤᴗᮦᩱ, ᪥หᕤᴗ᪂⪺♫, 62[9] (2014),
84-86.
≉チ
[1]ࠕᅜෆᡂ❧≉チࠖࢫࣆࣥࢺࣟࢽࢡࢫ⿦⨨࠾ࡼࡧㄽ⌮₇⟬⣲Ꮚ, ≉チ➨ 5601976 ྕ
⥲ྜゎᯒࢭࣥࢱ࣮
ཎⴭㄽᩥ
[1]Diffusion of oxygen in amorphous Al2O3, Ta2O5, and Nb2O5, M. Tane, T. Suzuki: J. Appl. Phys, 116
(2014) 033504.
[2]Synthesis, Electronic, and Crystal Structures of Methoxycarbonyl-substituted
2,5-Di(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione Derivatives, T. Suzuki: Chem. Lett., 43 (2014)
1224-1226.
[3]Manipulating Ȗ-cyclodextrin-mediated photocyclodimerization of anthracenecarboxylate by
wavelength, temperature, solvent and host, D. Zhou: Photochem. Photobiol. Sci., 13 (2014) 190-198.
ᅜ㝿఍㆟
[1]Ir Catalyzed Asymmetric Tandem Reaction of meso-Diols and Aldehydes (poster), T.Suzuki,
D.Y.Zhou,K.Asano,H.Sasai: nd International Synposium on C-H activation.
[2]Ir Catalyzed Asymmetric Tandem Reaction of meso-Diols and Aldehydes (oral), T.Suzuki,
D.Y.Zhou,K.Asano,H.Sasai: ICOMC 2014.
[3]Ir Catalyzed Asymmetric Tandem Reaction of meso-Diols and Aldehydes (poster), T.Suzuki,
D.Y.Zhou,K.Asano,H.Sasai: 18th SANKEN international Symposium.
ᅜ㝿఍㆟ࡢ⤌⧊ጤဨࠊᅜ㝿㞧ㄅࡢ⦅㞟ጤဨ
㕥ᮌ ೺அ
2014 ICOMC (⤌⧊ጤဨ)
࿘ ኱㝧
2014 ICOMC (⤌⧊ጤဨ)
ᅜෆᏛ఍
➨ 40 ᅇ཯ᛂ࡜ྜᡂࡢ㐍Ṍࢩ࣏ࣥࢪ࣒࢘
ᇶ♏᭷ᶵ໬Ꮫ㐃ྜウㄽ఍
― 253 ―
1௳
1௳
⛉Ꮫ◊✲㈝⿵ຓ㔠
ᇶ┙◊✲(C)
㕥ᮌ ೺அ
ዡᏛᐤ㝃㔠
㕥ᮌ ೺அ
ඹྠ◊✲
㕥ᮌ ೺அ
㕥ᮌ ೺அ
Ỉ⣲೉⏝཯ᛂ࡟ᇶ࡙ࡃ་⸆㛵㐃≀㉁ࡢ✲ᴟⓗ୙ᩧྜᡂ
༢఩㸸༓෇
2,210
JSR ᰴᘧ఍♫ ◊✲㛤Ⓨ㒊㛗 ᕝᶫಙኵ
500
panasonic Corporation
ࣃࢼࢯࢽࢵࢡᰴᘧ఍♫
500
487
᭷ᶵ໬ྜ≀ࡢศゎ㐣⛬ࡢ NMR ࡟ࡼ
ࡿᵓ㐀ゎᯒᡭἲࡢ◊✲
㔞Ꮚࣅ࣮࣒⛉Ꮫ◊✲᪋タ
ཎⴭㄽᩥ
[1]Development of a high-power solid-state switch using static induction thyristors for a klystron
modulator, A. Tokuchi, F. Kamitsukasa, K. Furukawa, K. Kawase, R. Kato, A. Irizawa, M. Fujimoto, H.
Osumi, S. Funakoshi, R. Tsutsumi, S. Suemine, Y. Honda, G. Isoyama: Nucl. Instrum. Meth A, 769
(2015) 72-78.
[2]Selenium-Selenium Bond Cleavage of Diaryl Diselenide Radical Anions During Pulse Radiolysis, :
ChemPlusChem, 80 (1) (2015) 68-73.
[3]Structural Study of Various Substituted Biphenyls and Their Radical Anions Based on Time-Resolved
Resonance Raman Spectroscopy Combined with Pulse Radiolysis, J. Choi, W. Dae, S. Tojo, M. Fujitsuka,
T. Majima: Journal of Physical Chemistry A, 119 (5) (2015) 851-856.
[4]Configurational changes of heme followed by cytochrome c folding reaction, J. Choi, W. Dae, S. Tojo,
M. Fujitsuka, T. Majima: Molecular BioSystems, 11 (1) (2015) 218-222.
[5]Solvent Dynamics Regulated Electron Transfer in S2-Excited Sb and Ge Tetraphenylporphyrins with
an Electron Donor Substituent at the Meso-Position, M. Fujitsuka, T. Shiragami, W. Cho, S.Tojo, M.
Yasuda, T. Majima: Journal of Physical Chemistry A, 118 (22) (2014) 3926-3933.
[6]Dynamics in the heme geometry of myoglobin induced by the one-electron reduction, J. Choi, S. Tojo,
M. Fujitsuka, T. Majima: International Journal of Radiation Biology, 90 (6) (2014) 459-467.
ᅜ㝿఍㆟
[1]Characterization of melting process of PTFE using positron annihilation spectroscopy (invited), Y.
Honda, S. Nishijima: 11th International Workshop on Positron and Positronium Chemistry.
[2]Feasibility of classification of clay minerals by using PAS (poster), Y. Honda, Y. Yoshida, Y. Akiyama,
S. Nishijima: 11th International Workshop on Positron and Positronium Chemistry.
⛉Ꮫ◊✲㈝⿵ຓ㔠
✵㛫ไᚚᆺ㔞Ꮚࣅ࣮࣒ㄏ㉳཯ᛂࡼࡿ᭷ᶵởᰁ≀㉁ࡢศゎ
༢఩㸸༓෇
780
ᇶ┙◊✲(C)
⸨஌ ᖾᏊ
ཷク◊✲
㄃⏣ ⩏ⱥ
⎔ቃ┬
ࢭࢩ࣒࢘ࡢᑟయゎᯒ࡟ᇶ࡙ࡃ㝖ᰁࢩ
ࢼࣜ࢜ࡢᵓ⠏࡜☢Ẽຊไᚚᆺ㝖ᰁἲ
ࡢ㛤Ⓨ
2,106
ඹྠ◊✲
㄃⏣ ⩏ⱥ
ࢲ࢖࢟ࣥᕤᴗᰴᘧ఍♫
㝧㟁Ꮚᾘ⁛ἲࢆ⏝࠸ࡓࣇࢵ⣲ᶞ⬡ࡢ
ゎᯒ
2,500
― 254 ―
ᖹᡂ 28 ᖺ 2 ᭶Ⓨ⾜
⦅㞟࣭Ⓨ⾜ ኱㜰኱Ꮫ ⏘ᴗ⛉Ꮫ◊✲ᡤ
ᗈሗᐊ
ࠛ567-0047 ኱㜰ᗓⲈᮌᕷ⨾✑ࣨୣ㸶㸫㸯