...

水素エネルギー利用技術の現状と将来展望

by user

on
Category: Documents
18

views

Report

Comments

Transcript

水素エネルギー利用技術の現状と将来展望
Yíï_ăkȵČɁTȶ
ÏĖȀȚȭȅȳ1ò’İǪìêǥtºwµ
zƀ{Ljƀ
ÈÀ2‰ȋȍȔȦs ȵÈÀăkăȶ
ƉƇƈƇƈƉ²Ɖ©ȵ·ȶ
1
School of Engineering
Tokyo Institute of Technology
¢ƀƀÏĖǧǪǒƀ?
¸ƀƀƀƈƊƀ ƼƷƶƄƓƞƉƆǀƭƩƺ
•! ï_QźǪ@ÈøêÒ ©
ôƀƉƌƇƀ ƼƷƶƄƓƞƉƆǀƭƩƺ
ƀƀ( ȇȯȳȜȭƀǑǴǬƀȯȳȂȭƀ)
•! =üè¦ȀȚȭȅȳňÞǪ½Ú
ƀƀ( ŭǵǸǟ[Įşƀ)
ÏĖu%ǫljÏĖȀȚȭȅȳȋȍȔȦ&ǥǚǣljǗǸǵǪ
QźǨrǚǣljƀǺ³ǚǧǕǣǫǧǵǧ
ǎNJǍǷǎǫljû¶øǨǫǗǸǵǪpǓvǙǕǣdzljȲŧ
¶øǨǫdǔǧpǓ¶‡ǤǔǷȋȘȬȁǓšǖǧǕǣǫǧ
ǵǧǎNJLjDžƀ$*'+/&/ !(,
2
School of Engineering
Tokyo Institute of Technology
‹ĵ¹
•! Yíï_&rĎ
•!ƀ=ü覽ÚŬŮ
ƀƀLjƀ(ËNǪpljşøp)
ƈƅƀƀÉȀȚȭȅȳǒǵ±Ę×ŇǨĩǷ
LjƀƀğJ:ëǪ¿ÌǪKȵȆȬȳȰǧÏĖǪǎ¨ȶ
ƀLjLjû¶ȖȬȃȳLjÏĖè¦ŴÐĨ;ŌɈLjmĢòè¦ŴÐȉȌǿȚ
Ɖƅƀƀ5ðÏĖǪ1òLjƓƞƉǫǦǏǛǷɈ
Ɗƅƀƀ,ðHĥȀȚȭȅȳÞǪdşu%
LjLjƀƁfůƃƀŻ7ƃƀȜǾȁȤȍƀǧǦƂ
LjLjLjLjȲÏĖȀȚȭȅȳu%ǪćÃǪhljìXǪşøpǫÊv
LjLjLjLjȲìnøǧũȋȘȬȁǓ‹ĵLj
3
School of Engineering
Tokyo Institute of Technology
ENAA
ō›ũĦĞòƊČƄĩğĎƒŮÏċľÉ‡ĆŵF^1gƓ
!³{Ɛ‘ÁÖĞòƊČÛŋªkŁŶ
2200
(W/L)
Ballard
1500
ƄĩŁŶ
0
1200
1000
1000
500
1300
"
"
"
570
140
"
92
290
"
"
94
95
Ballard Mark 900. 80kW
2200
96
98
00 Ï
ĞòƊČşƍ
fƃúȬÿŜ
fĩƊ:<DX‚ƌÛIJĸ
IFC Series300. 75kW
f7<FzĔƒ5,000Ɩ
Ɩ10,000Œ
Œ/kWƓ
School of Engineering
Tokyo Institute of Technology
4
5
©¸ǨǑǖǷÏĖu%ǪFǶęǰȵƤƕƄƝƕƢƀƟƺƷƲƭƫƼƃƀƈƐƐƊƄƈƐƐƏƃƀƈƐƐƐƄƉƇƇƉȶ
ċľ-J_3g:<DXàőƄĩīĄ
Ĥ¦ŋ-J_3g
ċ—¿Ƈ
ċľŕŲPEMċƊř
dž90%
>_šġƀdž
32,000Nm2/hĽPEMƀƀċƊřR]cF
(10,000cm2セル}Ħ)
đ¼ċ—ĩƊß
ċľ”Ħś„
ƒĩƊƘĞòƊČƘō›ũƓ
500MWċľĞĜ@gOc
½ÆſĩƊß
ċľō›ũ
Ē{ċľ@c4
ƀƀƀƀƀ50,000m3
ÊŘąĒ{
ċľ*cP]
7g;,J`g:[cċľ<Dg:[c
ĞòƊČƘċľE)g?_
School of Engineering
ċľ«ŏ©ƀ
DŽ
3 wt% <100DŽ
ENAA
ċľĒœ
300 t/day
ĒœR]cF
Ē{ċľ@c0g
ƀƀƀƀƀ200,000m3
@c0g
zĕüòıĶ
Tokyo Institute of Technology
5
6
Schedule and Progress of WE-NET
JHFC Project
FY2002
But completed FY2002 (Mar. 2003),
and succeeded to a new project,
JHFC (Japan Hydrogen and Fuel Cell Development Project)
ENAA
School of Engineering
Tokyo Institute of Technology
6
ÏĖŪŔ’İŨõ;K
ÏĖè¦ŴÐĨ;ŌǥÏĖȍȔȳȋȪȰ
7
School of Engineering
Tokyo Institute of Technology
JHFC Demonstration FCVs
Nissan X-TRAIL
Honda FCX
Toyota FCHV
Toyota/Hino FCHV-BUS2
Suzuki wagonR-FCV
DaimlerChrysler F-Cell
General Motors Hydrogen3
School of Engineering
MITSUBISHI FCV
Tokyo Institute of Technology
8
ÏĖěȍ
ȳL
ȋO
ȪȰ
ĢD
ê
Ò
ƀƀ2005
²­ä
%Ȕ1
[Ǫ
Kļ
VY
4²
H14
6
A H15
10
A H16
12
%
%1
1L
LO
O[
[K
KV
VY
Y
(LPG
(LPG
9
9))
=
=!
!%
%1
1L
LO
O[
[K
KV
VY
Y
(:
:
(:
:
I
IL
L
9
9))
0
0
%
%1
1L
LO
O[
[K
KV
VY
Y
(%
%
(%
%1
1H
H[
[Q
QX
X))
-#
#
%
%1
1L
LO
O[
[K
KV
VY
Y
(E
E
(E
EX
XH
HW
W%
%<
<6
6))
%
%1
1L
LO
O[
[K
KV
VY
Y@
@
((
(
((
(
%
%1
18
84
4))
$
$'
'ZZ
%
%1
1L
LO
O[
[K
KV
VY
Y
(R
R
(R
RT
TJ
J
9
9))
%
%1
1L
LO
O[
[K
KV
VY
Y
(U
U
(U
UN
NS
S[
[X
X
9
9))
/
/;
;%
%1
1L
LO
O[
[K
KV
VY
Y
(*
*
(*
*&
&
9
9))
$
$'
'ZZ
?
?%
%1
1L
LO
O[
[K
KV
VY
Y
(3
3
(3
3.
.I
IM
MW
WY
Y
9
9))
$
$'
'ZZ>
>5
5%
%1
1L
LO
O[
[K
KV
VY
Y
(G
G
(G
GT
TJ
JF
FP
P%
%1
1))
@ :,B%12ab^`\fdg_e]c"C
)
ZZ
+
+
%
%1
1L
LO
O[
[K
KV
VY
Y/)
/)
)
(G
G
(G
GT
TJ
JF
FP
P%
%1
1))
:H147
)
ZZ
+
+
%
%1
1L
LO
O[
[K
KV
VY
Y/)
/)
)
(:
:
(:
:
I
IL
L
9
9))
:H167
:H157
9
School of Engineering
Tokyo Institute of Technology
ÏĖȍȔȳȋȪȰǪFˆȕȳȐǪÁĻƀȵƈƇȱ‘ǪnȕȳȐ'ıƀƉƇƇƌƅƊȶ
'ıȕȳȐFˆȲ¥îƁH15ɖȶȶ
ªJEVAF
FˆȕȳȐȵɖH14ȶȶ
ȵLjnÝȕȳȐǨǢǎǣǫlj'ıǤǔǷĐUǤ1òLjȶ
nÝȕȳȐ/¼
ŖòȲȕȳȐÁĻWG
ÏĖȍȔȳȋȪȰŹ\WG
WɄ
ɄWell
Ĩ;ŌŹ\WG
CTɄɄCharge Tank
FTɄɄFuel Tank
ȍȔȳȋȪȰǤǪ
è¦G%ǸȐȰȆ
ŌǪè¦ȐȰȆ
WɄ
ɄWheel
10
School of Engineering
Tokyo Institute of Technology
Energy Efficiency of on-Site Hydrogen Station
Reforming
Daikoku
(Desulfurized-Gasoline)
Asahi(Naphta)
Senju(LPG)
Kawasaki(Methanol)
Hadano(Kerosene)
Ome(Natural Gas) ǃ
ǃ small & plural reformers applied for mobile type
Electrolysis
Sagamihara
(Water, Electricity)
0
School of Engineering
50
efficiency (LHV)
ȵȴȶ
100
Tokyo Institute of Technology
11
Driving Test Result-Energy Consumption
Compared with ICV and HEV, FCV showed better energy consumption rate per vehicle weight.
ƕƶƭƺƯǀƀƫƷƶƻƽƵƸƼƱƷƶƀƺƩƼƭƀƀ
ƁƳƵƆƛƀƯƩƻƷƴƱƶƭƀƭƹƽƱƾƩƴƭƶƼƂ
ƌƇ
ƋƇ
ƖƓƣȲƙƓƣȲƘƕƣLjƓƷƵƸƩƺƱƻƷƶƀƠƭƻƽƴƼLjƁƿƱƼưƀƣƭưƱƫƴƭƀƤƭƱƯưƼƀƜƷƬƱƮƱƫƩƼƱƷƶƂ
ƗƩƻƷƴƱƶƭƀƔƭƶƻƱƼǀLjLjLjLjƀƀƀƀƀƀƀƀƀɄƀƇƅƎƉƐƀƳƯƆƛ
ƗƩƻƷƴƱƶƭƀƕƶƭƺƯǀƀƁƛƘƣƂƀƀƀƀƀƀƀƀƀƀɄƀƋƌƅƈƀƜƚƆƳƯ
ƘǀƬƺƷƯƭƶƀƕƶƭƺƯǀƀƁƛƘƣƂƀƀƀƀƀƀƀƀƀɄƀƈƉƇƀƜƚƆƳƯ
ƖƓƣƀƩƾƭƺƩƯƭƬƀƾƭưƱƫƴƭƀƿƭƱƯưƼLjɄƀƈƎƈƎƀƳƯ
ƢƭƻƼƀƠƷƽƼƭƀƑƀƔƱƻƱƯƶƩƼƭƬ
Air Conditioner : ON
ƖƓƣƀƒƾƭƺƩƯƭƀƛƱƶƭƀƀ
ƁƔƩƼƩƀƝƽƵƪƭƺɆƉƇƇƍƂ
ƊƇ
ƉƇ
ƘƕƣƀƒƾƭƺƩƯƭƀƛƱƶƭ
ƀƁƔƩƼƩƀƝƽƵƪƭƺɆƎƍƌƂ
ƈƇ
ƙƓƣƀƒƾƭƺƩƯƭƀƛƱƶƭ
ƀƁƔƩƼƩƀƝƽƵƪƭƺɆƏƋƊƂ
Ƈ
ƉƇ
ƋƇ
ƍƇ
ƣƭưƱƫƴƭƀơƸƭƭƬƀƀƧƳƵƆưƨ
ƏƇ
ƈƇƇ
ƀɄƀƢƷǀƷƼƩƀƓƺƽƯƩƺƃƀƝƱƻƻƩƶƀƥƄƢƠƒƙƛljƘƷƶƬƩƀɊɑȹɒƃƀƞƸƭƴƀƦƩƮƱƴƩƃƀƜƱƼƻƽƪƱƻưƱƀƗƺƩƶƬƱƻƃƀơƽǁƽƳƱƀƿƩƯƷƶƠ
ƀɄƀƢƷǀƷƼƩƀƟƺƱƽƻƃƀƖƷƺƵƭƺƀƟƺƱƽƻƃƀƕƻƼƱƵƩƀƘǀƪƺƱƬƃƀƝƱƻƻƩƶƀƢƱƶƷƀƘǀƪƺƱƬƃƀƘƷƶƬƩƀƙƶƻƱƯưƼƀ
ƀɄƀƢƷǀƷƼƩƀƖƓɎƣƃƀƝƱƻƻƩƶƀƥƄƢƠƒƙƛƀƖƓƣƃƀƘƷƶƬƩƀƖƓƥƃƀƗƜƀƘǀƬƺƷƗƭɔƊƃƀƔƩƱƵƴƭƺƓưƴǀƻƴƭƺƀƖƄƓƭƴƴƃ
ƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƜƱƼƻƽƪƱƻưƱƀƖƓƣƃƀLjơƽǁƽƳƱƀƿƩƯƷƶƠƄƖƓƣ
School of Engineering
Tokyo Institute of Technology
ƈƉƇ
12
(2006.4 - )
13
School of Engineering
Tokyo Institute of Technology
(2006.4 - )
14
School of Engineering
Tokyo Institute of Technology
(2006.4 - )
(Phase-II)
15
School of Engineering
Tokyo Institute of Technology
ÄĦŵŪoĞòƊČũĞòƊČM<
F\@ƀFCHVLj
LjLjLjƀƀƀƀƀöĥƀƀX-TRAIL FCV
UcA
FCX
ƘƕơơƀzŞÙÍ
ǪǘAǨǴǷ
LjLjjŎFCV
A*LCMove FCV <=2
MR Wagon FCV GM/OPEL HydroGen3 Daimler F-Cell Lj
Ford Focus FCV F\@öžƀƀFCHV- BUS2
Ljƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀ
School of Engineering
Daimler FC Bus
MAN FC Bus
Tokyo Institute of Technology
16
¯ĀĦ&Ýšđ¼ċľ<Dg:[c
!¯ĀĦ&ݲ<Dg:[c~
0gGŞšœň
a9c?_<ķĖ
ċƊřÔ
Ěuċľ<Dg:[c
ARAL
CAÌĴ›Ô
ċľ<Dg:[c
SHELL
b:cFcDCGS|śċľ
<Dg:[c
ĒċţŏÔ
HF-150·ċľŻů†ºœň
150kgţŏ35MPa
TOTAL
CEPS_^c
>_P†ºH-CUTES_^c
>_P†º
Ē{ċľţŏÔċƊřÔĒ{ċľţŏLPGìť
School of Engineering
ƘƕơơƀzŞÙÍ
ǪǘAǨǴǷ
MgMc4
z7<F·
PEMċƊř
Ěu
Tokyo Institute of Technology
17
HyFleet : CUTEċľRa;,4F
ƘƕơơƀzŞÙÍ
ǪǘAǨǴǷ
!\gaBN9 źÍĞòƊČM<27§&ŦŐCUTE
Ra;,4FĿp06Ï1ùHyfleet:CUTEĩŧ
!Hyfleet:CUTEāŗ
f2006Ï1ù#7źÍƒAmsterdam, Barcelona, Hamburg,
London, Luxembourg, Madrid, ReykjavikƓM<&ŵŐ
fóŘċľ-c;cM<14§&S_^ctűËBVGŵŐ
fS_^ctűËBVGM<Ħċľ<Dg:[c&śň
f÷¢!ŠþıĶîŊ´Ɖž—èŴ
S_^cċľ-c;cM<
School of Engineering
(X<D_AXacGcLcQ_5
Tokyo Institute of Technology
18
S_^cCEPċľō›ũÄŜRa;,4F
ƘƕơơƀzŞÙÍ
ǪǘAǨǴǷ
CEPClean Energy PartnershipS_^c͋ċľō›ũ&
ŦŐ%íÑëé½·Ra;,4F
ƒúƅ: 2002ÏƖ2007ÏƓ
ō›ũyij
Daimler/Chrysler
Ford, GM, BMW
ĞòƘĆ°Ƙtűyij
Aral, Total, Vattenfall
Linde, Hydro/GHW,
BVG
Daimler: F-Cell,10§. Ford: Focus,3§
Opel: HydroGen3,1§(LH2)
BMW: Series7,2§(LH2)
©Ś16§
ARALċľ<Dg:[c(04.11Â)
ƒċƊřĒ{ċľţŏƓ
TOTALċľ<Dg:[c(06.3ÂƓ
ƒLPGìťĒ{ċľţŏƓ
Ford: Focus Opel: HydroGen3
Daimler: F-Cell
BMW: Series7
School of Engineering
Tokyo Institute of Technology
19
0^P._I(ÌċľL*+-gJBFbg4
ƘƕơơƀzŞÙÍ
ǪǘAǨǴǷ
Schwarzenegger ĮrCAÌHydrogen Highway Network
ƓĂÜ&2004.4ĩŒ2005.3ùøĿŚĨÂÞ
ƒCaH2NetƓ
!ċľ<Dg:[cũnɇīĄ
Phase
Ph.12010Ï
Ph.2, Ph.3
ċľ<Dg:[cï
÷űũ
½·ũ
50Ɩ100ƒ½źÍoÙƓ
2,000
10
20,000
300
250
!ģ»īĄÉ‡ëé
ƙĕŚý1<–ĔƔ2010ÏƘ30Ƒ
ƙ¨<Dg:[cċľ20Ƒ
Ĥ¦ŋ-J_3gŕŲ%
ƙ<Dg:[cŔ™ƀƔ$1.25M
fĞòƊČũ1§Ŕ™ƀƔ$10,000
èŴãÕƔCal/EPAƒÌģ»ËƓ
School of Engineering
2004.4.20 UC-DAVISċľ<Dg
:[cƄßԐÎSĮr
Tokyo Institute of Technology
20
0^P._I(ÌċľL*+-gŚĨ
!0^P._I(<Dg:[c
94]YcF
9cP]
c:<7
ŚĨīĄ
ƘƕơơƀzŞÙÍ
ǪǘAǨǴǷ
2004Ïĩŧ
ċľ<Dg:[cƔ250dß
ċľō›ũƔ2i§
ĕŚý1<–ĔƔ30Ƒ
Ƒ
!źÍƅ&łÐńŷŨƒ18eßƓ
94]YcF
!Ÿ0^P._I(<Dg:[c
NgX<R^c5<
9cP]
c:<7
a9c;,_<
9cE)-8
School of Engineering
a9c;,_<
Source: Homepage of Hydrogen highway
Tokyo Institute of Technology
21
ƘƕơơƀzŞÙÍ
ǪǘAǨǴǷ
0HAċľL*+-gŚĨ
2010ώúsū
ċľL*+-g&Ăĺ
!Ra;,4F¡˜ʼn
fNRCanƒōěŤėĭƓ
fNRCƒ´ĸıĶßƓ
fFuel Cell Canada
fBallard Power Systems
fBC Hydro
fQuestAir
!H2 HighwayRa;,4F
ċľ”ĦŚĨhģ
ċľ&”Ħ%ŬůĆƆƘĞò
ƊČÚĦŕ®ƘÃňĦƘĴ›ĦƘ
W*4aĞòƊČEZc<
F`g:[c&Ő
School of Engineering
Whistler
ƒsūy¹Ɠ
North
Vancouver
"
NRC/UBC
"
Vancouver
"
Surrey
"
Airport
"
"
"
Victoria
British ColumbiaÌ
ċľ”Ħ¦ŋ-^(
Tokyo Institute of Technology
22
ƘƕơơƀzŞÙÍ
ǪǘAǨǴǷ
<0c;HO(ċľL*+-gŚĨ
!K_+-gEcWg4<-gEc
Ĉ3´ŸŖŹċľL*+-g&
Ăĺ%ŀŇScandinabian Hydrogen
Highway Partnership (SHHP)2006
Ï6ùĩŧ
õĈ3´ƒ“ĩŧ%Ra
;,4F&ųêèŴ%
´“Ra;,
4Fųê
•
S_6c
•K_+-g
•
•
•
••
• • <-gEc
•
EcWg4
• ••
•• •
•
••
• • •
• •
G*CŹ"ų
/<a
<@Mc1g
*-gDV^
<0c;HO(SHHP
/gP<
W_Z
HyNor
Äôĉƈ
Hydrogen
LinkĂÜ
HyFuture
’úĉƈ
K_+-gEcWg4Lj
LjLjƀ<-gEc
• Ʉċľ<Dg:[cqùß
School of Engineering
Tokyo Institute of Technology
23
Vſ/j†è¦ŴÐ*ǪȥȆȯìłĸ¬ǥſĥ=
PEFC®
®CǪǟDzǪ‹ŸĿź
•! ĤǪKƀȵ5000 - 80000 hȶȶLjȵ9=Ǫ$´ȶ
•!ƀſ:ë=ȵ> 60 %ȶ
ȶ
•!ƀſ.7q‚=ȵ> 2.0 MW/m3ȶ
•!öŠòşǪdÛȸdzǚǕǫöŠ°Ĺi
•!ȉȍȖ=ȵ< 1/100ȶ
ȶ
24
School of Engineering
Tokyo Institute of Technology
è¦ŴÐĨ;ŌȵFCV)Ǒ
ǑǴǬmĢZè¦ŴÐǪu%ȋȘȬȁȵŨõùÆȶ
AIST ċRŽƀǨǴǷLjɅè¦ŴÐnò=˜ŕ?Łň¦ǴǶɇ
ȽȻȻɀLjLjLjLjɅu%¶ɇLjLjƀLjȽȻȼȻLjLjLjLjƀɅ®C¶ɇLjLjLjLjȽȻȽȻLjLjLjLjɅ¸¿®C¶ɇLjLjƀȽȻȾȻ
FCVu
%I¤
ɀI
ɀȻȻI
ũȼȽȻI
'òŌljȜȍ
u%
Ōą
ȼɀȻȻI
vZńéljÂ<ò
òŌ
Ī
òŌ
ɀȻȻȂ‘
ȵȿɕȶ
ÏĖȍȐȰȗ¤ȵÏ
Ėŵĵȶ
mĢòFC
®CĶÇ
Ĥ
ùÆ
ȉȍȖù
Æ
|ŅŨg
ȽȽȻɓW
ȾɀȻȻȂ‘
ȵɀɂɕȶ
ȼȻȻȻɓW
ɂɀȻȻȂ‘
ȵȼɀȼɕȶ
ȼȽɀȻɓW
NjȤǾȆȯȇȬȓȗnjǓ®C
Ⱦ>­ũȵĨ;Ōòȶ
ɀ>­ũ
ȾŊ;ÊȵĨ;òȶ
ɁT
ɖȿ­ũȵmĢòȶ
Ƀ­ũ
¤÷+ȺɓWȵĨ;ŌòljȍȐȓȆȉȍȖȶ
ȿȻȻȻ+ȺɓW
¤÷+ȵmĢòljȋȍȔȦ¿ȶ
ȿȻ+
School of Engineering
Tokyo Institute of Technology
25
nűǪFCǪÅœ(ìXǪPEFC)
ȍȐȓȆ
Ȏȭ
Ǽțȳȗ
#-
0
0
0"
0#).1%
Ȃȏȳȗ
ȃȍ“£x
Ŵĸʼnħ(ſ/jħǓLÏ)
Ĺi
ȎȝȮȳȐ
(ȜǾȣȳȫȢȮȳȖ
or û)
ſ/jħȷĹi
#-
School of Engineering
MEA(ħŴ×J
or Membrane Electrode Assembly)
ȃȍ“£x
(ȃȍ“£ŴÃ
or ŲŴȶ
Tokyo Institute of Technology
26
þćǪÄĵ
Ńī
Vſ/jŴĸʼn*ǨǑǖǷéʼnŎŏìł
CF2
e-
H+
CF2
CF
CF2
CF2
O
CF
CF2
CF2 O
CF2
CF2
CF2
SO3- H2O SO3++
X++ HX
H2O H
CF2
- H 2O
HX+ + SO3
CF2
CF2
CF2
CF2
CF2
O
CF2
CF2
CF2
CF
Vſ/jŴĸʼn*ǨǑǖǷȥ
ȆȯéʼnŎŏÈÅ
ȵȄȨȟȫȬȳȧȕȭǨǴǷŴĸʼn*
éʼnŎŏìłǨŪǛǷ/j;7k
øÁĻȶ
Ŵĸʼn*éʼnŎŏÈÅǪĸ¬
ǥſǾȁȰuħŨõǭǪ•
šǪ›ā
ȂȏȳȗŴÃĹiǨǑǖǷśĖř!DŒ
ČBî/j;7kÓǨǴǷȂ
ȏȳȗôŶDŒĖŗĄǪĸ¬ǥ
ſՍJŠĹiǪ–ė
H+
O2
Pt
C
School of Engineering
DŒÈÅǪĸ¬ǥ
ſՍĹiļĺǭǪ•š
RFȤ
ȤȇȚȖȯȰȍȝȓȐÓǨ
ǴǷȂȏȳȗòſՍJŠ
ĹiǪŨõ
ſՍJŠĹiǪŨõ
In-situ XAFS ĺÝ
Tokyo Institute of Technology
27
=üè¦ȵeåȃȍljüãȶǒǵǪÏĖijœ’İ
Ś|ȃȍǒǵǪĔÏĖijœ
ȜȓȠǻȳȐȰȆ
ìįȋȍȔȦ
ÏĭÎȵH2Oȶ
ƘƉLj ɄƎƍȴ
ƓƞƉ Ʉƈƈȴ
Ɠƞ ɄƈƉȴ
ƓƘƋ Ʉƀȼȴ
Ś|ȃȍȵCH4ȶ
ƘƉ ɄƎƏȴ
ƓƞƉ ɄƉƇȴ
Ɠƞ Ʉƀƀƈȴ
ƓƘƋ Ʉƀƀƈȴ
ĔÏĖ
ĦÿS
ÏĖ/ųZŸʼnȋȍȔȦ
ŸʼnS
ȵÏĭΟʼnDŒȶ
COaS
ÏĖĒijIJĢƀ
ȵȋȠȖDŒȶ ȵPSA:W7ȍǾȰȇMúȶ
CH4 +H2OLjLjLjCO + 3H2
CO +H2O LjLjƀCO2 + H2
700ɖ800DŽ
180ɖ220DŽ
H2Ʉ>99.99ȴ
ȴ
•! ȉȰȝȆȖ
ÏĭÎȵH2Oȶ
ǂ!ƀȋȰȢȭ
Ś|ȃȍȵCH4ȶ
ĔÏĖ
ĦÿS
School of Engineering
ÏĖ/ųZŸʼnS
ȵÏĭΟʼnDŒȶ
ȵ/ųȶ
550DŽ
H2Ʉ>99.99ȴ
ȴ
ǂ!ƀſ:ë
28
Tokyo Institute of Technology
ÏĖ/ųZŸʼnSǪBî
ÏĖ/ųďƀ(PdJŠħ)
Ĺi
8ç
H2
Ś|ȃȍƀ(CH4)
CO2
ÏĖ
CH4
H2
H2
H2O
ÏĭÎ
CH4
CO
ÏĭΟʼnDŒ
CH4 + H2O
ȲȉȰȝȆȖ
CO + 3H2
ɊɐaDŒ
CO + H2O
CO2 + H2
/ų
ȲȋȰȢȭ
Ȳſ:ë
/ų
ȁȰȊǾȖÏĖijœǤǪ-îǫɈ
School of Engineering
Tokyo Institute of Technology
29
mĢ…FCǥǪęǰJǹǜ
Ŵ7
ɌɊ
ŸʼnS
ĔÏĖijœ
ȊȡȋȍȔ
Ȧ
ç
ÏĖ
1kWĕȋȍȔȦnĽ
ĔÏĖņĮȊȡȋȍȔȦ
LJÏĖǪſ‚1ò
ÏĖěȎȰȐȳ
ÏĖȝǾȢȫǾȰǭǪwŨ
………
30
ĔÏĖŽ;ZPEFC
School of Engineering
Tokyo Institute of Technology
üãǒǵǪCO2TEZÏĖijœ’İ(HyPr-RING)
(H2 > 90%,+CH4)
HyPr-RING
������
���
$
# !"
$
�
�����(923 K)
(3.0 MPa)
����
�������(CaCO3)
��(CO ���)
2
CO2Ǫ-îǫɈ
������
ɅJCOAL, AIST, IHI, ©, Ĭɨɤɪɛɫ, yūdk, ģżdkɇ 31
School of Engineering
Tokyo Institute of Technology
ƓƞƗǒǵǪØÏĖijœěnĽľž
ŎLjŏ
TEĒij
ɠɚɟɢâɞɯɢ
Ɋɐɍ
4-î
ſâɞɯ
ɢɉɌɍ
4-îȺa
Ɵơƒ
«LjW
ɠɚɟɢ
ɠɚɟɢâ
4-îȺa
ĦãśɗĉĖ
WġÏĖɥɬɚɩɚ
àŤ
æ
Ě
ţ
ÏĖɢɤɚɡɘɮ
ƖƓƣȜȍ
Ɓ'(ɧɪɚɥƂ
ťœ
W„
ØLj=
ØÏĖɭɚɪɚ
ōâ
æĚɧɰɩɮɥ
ƖƓƣ
«W
ɗ"^
ɢɟɩəɧɰ
ſâ
Ţţü
ɦɰɜɧɰɩɜɮ
ĦãśɗĉĖ
ōâɞɯɢ
ɏɋɍ
üLjã
ƒȢȫȍȒȓȆ
1Ljò
Ø=ÏĖɣɮɟ
ŢŦijP
mĢòè¦ŴÐ
ȵçŴěȶ
ijޑɜɮɧ
ɩ
ÏĖɞɯɢɝɮɡɯɮ
32
School of Engineering
Tokyo Institute of Technology
üÑĒijȢȫȰȖǒǵõð
ǛǷCO2şǪ˜ĺ
ȘȠȊŸʼnÏĖijœ
ȠȭĆǤ
ũ5300
ȖȰǪCO2õð
ÏĖijœɄũ80 Nm3
School of Engineering
Tokyo Institute of Technology
33
ĞòƊČũ͹ɇīĄċľßŗſƘáŤƎ
ƘƕơơƀzŞÙÍ
ǪǘAǨǴǷ
ŁēĥĀĭ͹ɇīĄ
Ï
2005- 2010
ĞòƊČũ
ċľƋŗſċľ<Dg:[cï
2010- 2020
500i§
65…Nm3
3,500dß
2020- 2030
1,500i§
170…Nm3
8,500dß
Lj5i§ƀƀ
4…Nm3 Ljƀƀƀƀƀƀƀƀ500dß
!ċľ<Dg:[cÓśáŤ
Ï
2005- 2010
2010- 2020
2020- 2030
ċľ<Dg:[cï
Lj500dß
3,500dß
8,500dß
áŤƎ
1,500…Œƒƕ3…ŒƓ
7,000…Œƒƕ2…ŒƓƀƀƀ
17,000…Œƒƕ2…ŒƓ
Đ
2020-2030Ï<Dg:[cŘą½$7<F
Ɛ%7<FzĔ&â$ŭ' €åň
School of Engineering
Tokyo Institute of Technology
34
ƘƕơơƀzŞÙÍ
ǪǘAǨǴǷ
ƓƞƉTEZÏĖȐȳȞȰõŴ‘
Ļ´500MWċľ@gOcĩƊß
rĀʼnƔBPEdison Mission Gr.
śň¹ßƔ0^P._I(Ìa<ŮŸCarson
ĩƊś„Ɣ500MWċľ@gOcƒ250MW"2 Ɠ
ċľŕŲƔTFa7g45,000t/day&1<œ
CO2ĢƔCO2–ĔÏƅ400i
itƒũ100i§
æſĬÕ
OccidentalčħЇƓ
śň¹ßBPŕčß
ŵŪƄÀƔ2011ÏáŤƎƔ10…G_
Ɗ—
ċľ@gOc
CO2±£
1<œ
ċľ
CO2ЇĹ
School of Engineering
TFa7g4
İčç¤Ĺ
Tokyo Institute of Technology
35
ÏĖǪśĖèæǨǴǷ§ȊǾȆȭ
ȲƀèæðéɄÏĭÎǪǰȵ}ŝȃȍǓÏĭÎǪǰǪ]Jȶ
ȲƀȃȍȐȳȞȰǥĭÎȐȳȞȰǪŧ‘Ǻ)ǩǐǟĴJȊǾȆȭǪĥ
LjȵȡȮǾȖȰȊǾȆȭȷȫȰȄȰȊǾȆȭǪĨ;ĴJ=ȶ
ő~ǪȃȍȐȳȞȰ
ÏĖȐȳȞȰ
36
School of Engineering
Tokyo Institute of Technology
ÏĖǺȀȚȭȅȳȄȨȬǼǥǚǟ
ŋ/£ZȀȚȭȅȳȉȥȩșȔǽȳ
ȵĬğþ
ƀŠóǵǨǴǷȶ
37
School of Engineering
Tokyo Institute of Technology
HŐȎȭȍȐȓȆǺòǎǟŴ7Ńī€ß=ȋȍȔȦ
&
"
$
)
+
O2
K<
J?nEDn_#(0
p1g !q
9H!93fie
1Y
p100&%1MPa&%q
PEM4J?nEodRhB
pkO/@')A0FPq
"ZT4 Q8
p+N1Y "7*q
!(
jVc\
O2
)
*
&
Reversible Cell Stack
Dn_iP
H2
J?nEiP
DVc\
H2
*
&
#)'%
kWU&$PEM41g !lQ
X2nC5>/M
r45%&$
DV,Pn.b[:I0W2a`=^L;
X2 ",P/M r75%&$
"!
r20%-G
ȵſýçkƀváǵǨǴǷȶ
n.6mS]M
r50%&$
38
School of Engineering
Tokyo Institute of Technology
業務用建物設備における水素/電力供給ステーション∼
FWXIDN=?%/EOUGY
&
+8,>ABFWXIDN$
04&?,\9-KMYJTW
D:4E
$
#*84
#25=,
#2
384
#?&9 @
-+
C"5=,
C84
"
&*
Z'2<-([
;4
@C.
"
&*
Z'2([
//
9HYRU
9HYRU
;4KSYK
9
:&9 ?&
9HYRU
A2<7:
,7)
?;6
&,
+
( C$
#
;4QVC
#
\5?931!
!;6
&,
-
Z6)>.[
1#9>84
#2<7:
',0
'
?;6
&,
!;6
&,
School of Engineering
)84
#B
84
%',0
'
PLN
"
&*
7)
ȵſýçkƀváǵǨǴǷȶ
39
Tokyo Institute of Technology
ğJøYíܯ=rĎ
ȵ,™ȶ
üãȃȍ=ȲƓƞƉŰųȲÏĖ1ò’İǪĜJ
CO + H2
ȃȍ=
=üè¦
(ü
üã, üÑƀ..)
O2/CO2
śĖèæ
,ðHĥȀȚȭȅȳ
(Ż
Ż7, fů#ƀ..)
FutureGen (U.S.)
ȋȠȖDŒ
ÏĭΟʼn
Ʌŧ¶tºɇ
CO2 + H
H22
$
"%&
(Ȁ
ȀȆȎȭȅȳ`ŕ)
ĈÎèæ
ÏĖǪſ‚
1òȋȍȔȦ
H2 + O2
Ŵ7
H2O
(è
è¦ŴÐ
ÏĖȐȳȞȰƀ..)
CO2 TE
CO2 /ųȲTE
ƀƀƀƀƀƀ(MEA .. )
Ʌû¶ɇ
CO2 '(
CO2 Űų
(Ö
ÖÔ, Yƀ..)
Ʌ¶ɇ
!"
School of Engineering
CO2 '(#
Tokyo Institute of Technology
40
ƘƕơơƀzŞÙÍ
ǪǘAǨǴǷ
ÏĖĂnìǪĿźȵĵēȶ
įúşƍoƃúşƍ
ċľ”Ħàő¯®œ
ĞòƊČō›ũ
Ê·ĞòƊČÚĦŕ®
ˆ´Īō›ũĦċľ*c
P]Ăĺ
ċľ”Ħ
ƚƛƜƝàő
‰ű
şƍ
½ſċľ”ĦàőƄĩ
ĊĤƘĥĀĦŰä½ƘũĦ
Űä½ƘĩƊĦĝĆƆ
½Řąċľ*cP]Ăĺ
ƒCO2P^gċľŃ
ċľN*R]*cŃƓ
ŕŲàőŬůàőţŏàő”Ħ
àő
fŁēÛIJĸfؕŅ­ďð„ƒƆ6ďØƓ
fàőĄĘœfijy¥ÆÛŽÞƒÍĊîŊƓ
School of Engineering
Tokyo Institute of Technology
41
ƘƕơơƀzŞÙÍ
ǪǘAǨǴǷ
ċľN*R]*c
ċľN*R]*cċľ½ſŻům¦ćƗđ¼ÄņŢÇ
öû
Ļ´
EU
ƙ10kmĵÒN*R]*c
ŕƁßËƘ7cOHgF‹
ƙ¨ß©Ś1,320km
Texas, Louisiana, LA
ƙv-S_3gƅ900km
ƙĠ) Ruhr 200km, Luena 135km
µ—Ɣ60 bar
ŻĹ×Ɣ100mm
üťƔęľƂƂĹ
ñśƔ¶l¸ś
S_3g
ƙ/]cA*3^<
‰űwă3Ɩ12inµ—ŻĹĦęľƂƂĹ
}Ħµ—2Ɩ12MPa
şƍ
ƙÓś7<FzĔ
ƙµ—ŻĹĦęľƂƂĹċľŌÛ
ŝƏEg@mŧƒöûƓ
ƙ¾ě1<fċľŠĦN*R]*c
School of Engineering
ċľ
żľ
P]c<
Air LiquidijŤò
S_3gP]c<ƅļ900km
ƒ}ĦÄņ30ÏxkƓ
Tokyo Institute of Technology
42
”ĞHĥĂǭǪìnøǧũȋȘȬȁǪÅđǥĴJ=ȋȍȔȦ’İŨõ
0’İŨõ
LjLjijœ
LjLjŎŏ
LjLjņĮ
LjLj1ò
ÏĖǪſ‚1òǺ¾ǥǚǟ
ĴJ=ȋȍȔȦ’İŨõ
ȵǾȰȐȳȠǿǾȍljşøȲŒ‚ŀøȤȓȒȰȇȶ
ȵñÂũŔžljȉȢȯȑȆȋȪȰȶ
ǝǸǞǸǪſ:ë=ǠǖǤǫ
,ðHĥȀȚȭȅȳu%ŕ
=üè¦ǒǵǪÏĖijœ
ǥƓƞƉTEȲŰųǪĜJ
ȵğJøYíܯ=rĎȶ
ȵſ:ë=ǠǖǤǫƓƞƉ3Ûǫŭôȶ
ǧǕljȋȍȔȦǥǚǣǪſ‚=Ǔlj
ÏĖǠǒǵǗǝǤǔǷdǔǧȡ
ȮȳȆȍȭȳǺðDZ
ÏĖǪcķøÈĥǺÕòǚǟ
ʼnȀȚȭȅȳǪſʼn=,1ò
ȵȀȆȎȭȅȳ`ŕȶ
ƉƇƈƇƄƉƇƉƇŷǪnìǨKǖǣljǒǵ’İŨõǪį;ǺŊǗǛǮǔ
School of Engineering
Tokyo Institute of Technology
43
ÏĖĂǨKǖǟȞȌȪȰȵǯǥDzȶ
ŧ¶ȍȖȫȔȌȳ
•!,ðHĥȀȚȭȅȳǪdşu%ƀ( ! 100-1000 )
•!ÖbǪ6ĨåȀȚȭȅȳǪ1òLjȵȀȚȭȅȳȄȨȬǼƀ?)
ìnøǧũȋȘȬȁƀ(­
­ũȍȈȳȭljĈũȍȈȳȭ)
(ǟ
ǟǥǐljìXǪËNpǓvǙǎǒljȤǾȘȍǤǍǡǣdz)
•!ÏĖĨ;Ōƀ(IC-engine, PEFC)LjȲvZ/£ȉȌǿȚ
•!ǾȰȠȫ¥ljŎŏȲņĮȲěȋȍȔȦljÏĖȉȥȩșȔǽȳ
•!ȀȚȭȅȳȄȨȬǼǥǚǣǪÏĖǪcķøÈĥǪÕò’İ
LjLj(Ȁ
ȀȚȭȅȳaœljŎŏljņĮȵȀȚȭȅȳȲéʼnƀñÂȉȰȢȮȓȆȍȶ
•!ÏĖ1ò/£ȀȚȭȅȳȋȍȔȦǪ±Ř=ƀ(PEFC, MGT)
•!=üè¦ljȜǾȁȤȍčǒǵǪſ:ëljſŒljdşƀÏĖijœ
ƀƀǑǴǬ5ðÏĖǪÕòLjȵCO2TEŰųǥǪǾȰȔȇȮȳȋȪȰȶ
•!PEFCǪ
ǪȉȍȖdÛljĤǪ¿ÌǪK
•!l&ǪĀĊljÏĖǪĶ2ĠOljĂGoǪŜljĝĞø¡Ď
44
School of Engineering
Tokyo Institute of Technology
Fly UP