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水素エネルギー利用技術の現状と将来展望
Yíï_ăkȵČɁTȶ ÏĖȀȚȭȅȳ1òİǪìêǥtºwµ zƀ{Ljƀ ÈÀ2ȋȍȔȦs ȵÈÀăkăȶ ƉƇƈƇƈƉ²Ɖ©ȵ·ȶ 1 School of Engineering Tokyo Institute of Technology ¢ƀƀÏĖǧǪǒƀ? ¸ƀƀƀƈƊƀ ƼƷƶƄƓƞƉƆǀƭƩƺ •! ï_QźǪ@ÈøêÒ © ôƀƉƌƇƀ ƼƷƶƄƓƞƉƆǀƭƩƺ ƀƀ( ȇȯȳȜȭƀǑǴǬƀȯȳȂȭƀ) •! =üè¦ȀȚȭȅȳňÞǪ½Ú ƀƀ( ŭǵǸǟ[Įşƀ) ÏĖu%ǫljÏĖȀȚȭȅȳȋȍȔȦ&ǥǚǣljǗǸǵǪ QźǨrǚǣljƀǺ³ǚǧǕǣǫǧǵǧ ǎNJǍǷǎǫljû¶øǨǫǗǸǵǪpǓvǙǕǣdzljȲŧ ¶øǨǫdǔǧpǓ¶ǤǔǷȋȘȬȁǓǖǧǕǣǫǧ ǵǧǎNJLjDžƀ$*'+/&/ !(, 2 School of Engineering Tokyo Institute of Technology ĵ¹ •! Yíï_&rĎ •!ƀ=ü覽ÚŬŮ ƀƀLjƀ(ËNǪpljşøp) ƈƅƀƀÉȀȚȭȅȳǒǵ±Ę×ŇǨĩǷ LjƀƀğJ:ëǪ¿ÌǪKȵȆȬȳȰǧÏĖǪǎ¨ȶ ƀLjLjû¶ȖȬȃȳLjÏĖè¦ŴÐĨ;ŌɈLjmĢòè¦ŴÐȉȌǿȚ Ɖƅƀƀ5ðÏĖǪ1òLjƓƞƉǫǦǏǛǷɈ Ɗƅƀƀ,ðHĥȀȚȭȅȳÞǪdşu% LjLjƀƁfůƃƀŻ7ƃƀȜǾȁȤȍƀǧǦƂ LjLjLjLjȲÏĖȀȚȭȅȳu%ǪćÃǪhljìXǪşøpǫÃv LjLjLjLjȲìnøǧũȋȘȬȁǓĵLj 3 School of Engineering Tokyo Institute of Technology ENAA ōũĦĞòƊČƄĩğĎƒŮÏċľÉĆŵF^1gƓ !³{ƐÁÖĞòƊČÛŋªkŁŶ 2200 (W/L) Ballard 1500 ƄĩŁŶ 0 1200 1000 1000 500 1300 " " " 570 140 " 92 290 " " 94 95 Ballard Mark 900. 80kW 2200 96 98 00 Ï ĞòƊČşƍ fƃúȬÿŜ fĩƊ:<DXƌÛIJĸ IFC Series300. 75kW f7<FzĔƒ5,000Ɩ Ɩ10,000 /kWƓ School of Engineering Tokyo Institute of Technology 4 5 ©¸ǨǑǖǷÏĖu%ǪFǶęǰȵƤƕƄƝƕƢƀƟƺƷƲƭƫƼƃƀƈƐƐƊƄƈƐƐƏƃƀƈƐƐƐƄƉƇƇƉȶ ċľ-J_3g:<DXàőƄĩīĄ Ĥ¦ŋ-J_3g ċ¿Ƈ ċľŕŲPEMċƊř dž90% >_ġƀdž 32,000Nm2/hĽPEMƀƀċƊřR]cF (10,000cm2セル}Ħ) đ¼ċĩƊß ċľĦś ƒĩƊƘĞòƊČƘōũƓ 500MWċľĞĜ@gOc ½ÆſĩƊß ċľōũ Ē{ċľ@c4 ƀƀƀƀƀ50,000m3 ÊŘąĒ{ ċľ*cP] 7g;,J`g:[cċľ<Dg:[c ĞòƊČƘċľE)g?_ School of Engineering ċľ«ŏ©ƀ DŽ 3 wt% <100DŽ ENAA ċľĒ 300 t/day ĒR]cF Ē{ċľ@c0g ƀƀƀƀƀ200,000m3 @c0g zĕüòıĶ Tokyo Institute of Technology 5 6 Schedule and Progress of WE-NET JHFC Project FY2002 But completed FY2002 (Mar. 2003), and succeeded to a new project, JHFC (Japan Hydrogen and Fuel Cell Development Project) ENAA School of Engineering Tokyo Institute of Technology 6 ÏĖŪŔİŨõ;K ÏĖè¦ŴÐĨ;ŌǥÏĖȍȔȳȋȪȰ 7 School of Engineering Tokyo Institute of Technology JHFC Demonstration FCVs Nissan X-TRAIL Honda FCX Toyota FCHV Toyota/Hino FCHV-BUS2 Suzuki wagonR-FCV DaimlerChrysler F-Cell General Motors Hydrogen3 School of Engineering MITSUBISHI FCV Tokyo Institute of Technology 8 ÏĖěȍ ȳL ȋO ȪȰ ĢD ê Ò ƀƀ2005 ²ä %Ȕ1 [Ǫ Kļ VY 4² H14 6 A H15 10 A H16 12 % %1 1L LO O[ [K KV VY Y (LPG (LPG 9 9)) = =! !% %1 1L LO O[ [K KV VY Y (: : (: : I IL L 9 9)) 0 0 % %1 1L LO O[ [K KV VY Y (% % (% %1 1H H[ [Q QX X)) -# # % %1 1L LO O[ [K KV VY Y (E E (E EX XH HW W% %< <6 6)) % %1 1L LO O[ [K KV VY Y@ @ (( ( (( ( % %1 18 84 4)) $ $' 'ZZ % %1 1L LO O[ [K KV VY Y (R R (R RT TJ J 9 9)) % %1 1L LO O[ [K KV VY Y (U U (U UN NS S[ [X X 9 9)) / /; ;% %1 1L LO O[ [K KV VY Y (* * (* *& & 9 9)) $ $' 'ZZ ? ?% %1 1L LO O[ [K KV VY Y (3 3 (3 3. .I IM MW WY Y 9 9)) $ $' 'ZZ> >5 5% %1 1L LO O[ [K KV VY Y (G G (G GT TJ JF FP P% %1 1)) @ :,B%12ab^`\fdg_e]c"C ) ZZ + + % %1 1L LO O[ [K KV VY Y/) /) ) (G G (G GT TJ JF FP P% %1 1)) :H147 ) ZZ + + % %1 1L LO O[ [K KV VY Y/) /) ) (: : (: : I IL L 9 9)) :H167 :H157 9 School of Engineering Tokyo Institute of Technology ÏĖȍȔȳȋȪȰǪFȕȳȐǪÁĻƀȵƈƇȱǪnȕȳȐ'ıƀƉƇƇƌƅƊȶ 'ıȕȳȐFȲ¥îƁH15ɖȶȶ ªJEVAF FȕȳȐȵɖH14ȶȶ ȵLjnÝȕȳȐǨǢǎǣǫlj'ıǤǔǷĐUǤ1òLjȶ nÝȕȳȐ/¼ ŖòȲȕȳȐÁĻWG ÏĖȍȔȳȋȪȰŹ\WG WɄ ɄWell Ĩ;ŌŹ\WG CTɄɄCharge Tank FTɄɄFuel Tank ȍȔȳȋȪȰǤǪ è¦G%ǸȐȰȆ ŌǪè¦ȐȰȆ WɄ ɄWheel 10 School of Engineering Tokyo Institute of Technology Energy Efficiency of on-Site Hydrogen Station Reforming Daikoku (Desulfurized-Gasoline) Asahi(Naphta) Senju(LPG) Kawasaki(Methanol) Hadano(Kerosene) Ome(Natural Gas) ǃ ǃ small & plural reformers applied for mobile type Electrolysis Sagamihara (Water, Electricity) 0 School of Engineering 50 efficiency (LHV) ȵȴȶ 100 Tokyo Institute of Technology 11 Driving Test Result-Energy Consumption Compared with ICV and HEV, FCV showed better energy consumption rate per vehicle weight. ƕƶƭƺƯǀƀƫƷƶƻƽƵƸƼƱƷƶƀƺƩƼƭƀƀ ƁƳƵƆƛƀƯƩƻƷƴƱƶƭƀƭƹƽƱƾƩƴƭƶƼƂ ƌƇ ƋƇ ƖƓƣȲƙƓƣȲƘƕƣLjƓƷƵƸƩƺƱƻƷƶƀƠƭƻƽƴƼLjƁƿƱƼưƀƣƭưƱƫƴƭƀƤƭƱƯưƼƀƜƷƬƱƮƱƫƩƼƱƷƶƂ ƗƩƻƷƴƱƶƭƀƔƭƶƻƱƼǀLjLjLjLjƀƀƀƀƀƀƀƀƀɄƀƇƅƎƉƐƀƳƯƆƛ ƗƩƻƷƴƱƶƭƀƕƶƭƺƯǀƀƁƛƘƣƂƀƀƀƀƀƀƀƀƀƀɄƀƋƌƅƈƀƜƚƆƳƯ ƘǀƬƺƷƯƭƶƀƕƶƭƺƯǀƀƁƛƘƣƂƀƀƀƀƀƀƀƀƀɄƀƈƉƇƀƜƚƆƳƯ ƖƓƣƀƩƾƭƺƩƯƭƬƀƾƭưƱƫƴƭƀƿƭƱƯưƼLjɄƀƈƎƈƎƀƳƯ ƢƭƻƼƀƠƷƽƼƭƀƑƀƔƱƻƱƯƶƩƼƭƬ Air Conditioner : ON ƖƓƣƀƒƾƭƺƩƯƭƀƛƱƶƭƀƀ ƁƔƩƼƩƀƝƽƵƪƭƺɆƉƇƇƍƂ ƊƇ ƉƇ ƘƕƣƀƒƾƭƺƩƯƭƀƛƱƶƭ ƀƁƔƩƼƩƀƝƽƵƪƭƺɆƎƍƌƂ ƈƇ ƙƓƣƀƒƾƭƺƩƯƭƀƛƱƶƭ ƀƁƔƩƼƩƀƝƽƵƪƭƺɆƏƋƊƂ Ƈ ƉƇ ƋƇ ƍƇ ƣƭưƱƫƴƭƀơƸƭƭƬƀƀƧƳƵƆưƨ ƏƇ ƈƇƇ ƀɄƀƢƷǀƷƼƩƀƓƺƽƯƩƺƃƀƝƱƻƻƩƶƀƥƄƢƠƒƙƛljƘƷƶƬƩƀɊɑȹɒƃƀƞƸƭƴƀƦƩƮƱƴƩƃƀƜƱƼƻƽƪƱƻưƱƀƗƺƩƶƬƱƻƃƀơƽǁƽƳƱƀƿƩƯƷƶƠ ƀɄƀƢƷǀƷƼƩƀƟƺƱƽƻƃƀƖƷƺƵƭƺƀƟƺƱƽƻƃƀƕƻƼƱƵƩƀƘǀƪƺƱƬƃƀƝƱƻƻƩƶƀƢƱƶƷƀƘǀƪƺƱƬƃƀƘƷƶƬƩƀƙƶƻƱƯưƼƀ ƀɄƀƢƷǀƷƼƩƀƖƓɎƣƃƀƝƱƻƻƩƶƀƥƄƢƠƒƙƛƀƖƓƣƃƀƘƷƶƬƩƀƖƓƥƃƀƗƜƀƘǀƬƺƷƗƭɔƊƃƀƔƩƱƵƴƭƺƓưƴǀƻƴƭƺƀƖƄƓƭƴƴƃ ƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƜƱƼƻƽƪƱƻưƱƀƖƓƣƃƀLjơƽǁƽƳƱƀƿƩƯƷƶƠƄƖƓƣ School of Engineering Tokyo Institute of Technology ƈƉƇ 12 (2006.4 - ) 13 School of Engineering Tokyo Institute of Technology (2006.4 - ) 14 School of Engineering Tokyo Institute of Technology (2006.4 - ) (Phase-II) 15 School of Engineering Tokyo Institute of Technology ÄĦŵŪoĞòƊČũĞòƊČM< F\@ƀFCHVLj LjLjLjƀƀƀƀƀöĥƀƀX-TRAIL FCV UcA FCX ƘƕơơƀzŞÙÍ ǪǘAǨǴǷ LjLjjŎFCV A*LCMove FCV <=2 MR Wagon FCV GM/OPEL HydroGen3 Daimler F-Cell Lj Ford Focus FCV F\@öžƀƀFCHV- BUS2 Ljƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀƀ School of Engineering Daimler FC Bus MAN FC Bus Tokyo Institute of Technology 16 ¯ĀĦ&Ýšđ¼ċľ<Dg:[c !¯ĀĦ&ݲ<Dg:[c~ 0gGŞšœň a9c?_<ķĖ ċƊřÔ Ěuċľ<Dg:[c ARAL CAÌĴÔ ċľ<Dg:[c SHELL b:cFcDCGS|śċľ <Dg:[c ĒċţŏÔ HF-150·ċľŻůºœň 150kgţŏ35MPa TOTAL CEPS_^c >_PºH-CUTES_^c >_Pº Ē{ċľţŏÔċƊřÔĒ{ċľţŏLPGìť School of Engineering ƘƕơơƀzŞÙÍ ǪǘAǨǴǷ MgMc4 z7<F· PEMċƊř Ěu Tokyo Institute of Technology 17 HyFleet : CUTEċľRa;,4F ƘƕơơƀzŞÙÍ ǪǘAǨǴǷ !\gaBN9 źÍĞòƊČM<27§&ŦŐCUTE Ra;,4FĿp06Ï1ùHyfleet:CUTEĩŧ !Hyfleet:CUTEāŗ f2006Ï1ù#7źÍƒAmsterdam, Barcelona, Hamburg, London, Luxembourg, Madrid, ReykjavikƓM<&ŵŐ fóŘċľ-c;cM<14§&S_^ctűËBVGŵŐ fS_^ctűËBVGM<Ħċľ<Dg:[c&śň f÷¢!ŠþıĶîŊ´ƉèŴ S_^cċľ-c;cM< School of Engineering (X<D_AXacGcLcQ_5 Tokyo Institute of Technology 18 S_^cCEPċľōũÄŜRa;,4F ƘƕơơƀzŞÙÍ ǪǘAǨǴǷ CEPClean Energy PartnershipS_^cÍċľōũ& ŦŐ%íÑëé½·Ra;,4F ƒúƅ: 2002ÏƖ2007ÏƓ ōũyij Daimler/Chrysler Ford, GM, BMW ĞòƘĆ°Ƙtűyij Aral, Total, Vattenfall Linde, Hydro/GHW, BVG Daimler: F-Cell,10§. Ford: Focus,3§ Opel: HydroGen3,1§(LH2) BMW: Series7,2§(LH2) ©Ś16§ ARALċľ<Dg:[c(04.11Â) ƒċƊřĒ{ċľţŏƓ TOTALċľ<Dg:[c(06.3ÂƓ ƒLPGìťĒ{ċľţŏƓ Ford: Focus Opel: HydroGen3 Daimler: F-Cell BMW: Series7 School of Engineering Tokyo Institute of Technology 19 0^P._I(ÌċľL*+-gJBFbg4 ƘƕơơƀzŞÙÍ ǪǘAǨǴǷ Schwarzenegger ĮrCAÌHydrogen Highway Network ƓĂÜ&2004.4ĩŒ2005.3ùøĿŚĨÂÞ ƒCaH2NetƓ !ċľ<Dg:[cũnÉīĄ Phase Ph.12010Ï Ph.2, Ph.3 ċľ<Dg:[cï ÷űũ ½·ũ 50Ɩ100ƒ½źÍoÙƓ 2,000 10 20,000 300 250 !ģ»īĄÉëé ƙĕÅý1<ĔƔ2010ÏƘ30Ƒ ƙ¨<Dg:[cċľ20Ƒ Ĥ¦ŋ-J_3gŕŲ% ƙ<Dg:[cŔƀƔ$1.25M fĞòƊČũ1§ŔƀƔ$10,000 èŴãÕƔCal/EPAƒÌģ»ËƓ School of Engineering 2004.4.20 UC-DAVISċľ<Dg :[cƄßÔÎSĮr Tokyo Institute of Technology 20 0^P._I(ÌċľL*+-gŚĨ !0^P._I(<Dg:[c 94]YcF 9cP] c:<7 ŚĨīĄ ƘƕơơƀzŞÙÍ ǪǘAǨǴǷ 2004Ïĩŧ ċľ<Dg:[cƔ250dß ċľōũƔ2i§ ĕÅý1<ĔƔ30Ƒ Ƒ !źÍƅ&łÐńŷŨƒ18eßƓ 94]YcF !0^P._I(<Dg:[c NgX<R^c5< 9cP] c:<7 a9c;,_< 9cE)-8 School of Engineering a9c;,_< Source: Homepage of Hydrogen highway Tokyo Institute of Technology 21 ƘƕơơƀzŞÙÍ ǪǘAǨǴǷ 0HAċľL*+-gŚĨ 2010Ïúsū ċľL*+-g&Ăĺ !Ra;,4F¡ʼn fNRCanƒōěŤėĭƓ fNRCƒ´ĸıĶßƓ fFuel Cell Canada fBallard Power Systems fBC Hydro fQuestAir !H2 HighwayRa;,4F ċľĦŚĨhģ ċľ&Ħ%ŬůĆƆƘĞò ƊČÚĦŕ®ƘÃňĦƘĴĦƘ W*4aĞòƊČEZc< F`g:[c&Ő School of Engineering Whistler ƒsūy¹Ɠ North Vancouver " NRC/UBC " Vancouver " Surrey " Airport " " " Victoria British ColumbiaÌ ċľĦ¦ŋ-^( Tokyo Institute of Technology 22 ƘƕơơƀzŞÙÍ ǪǘAǨǴǷ <0c;HO(ċľL*+-gŚĨ !K_+-gEcWg4<-gEc Ĉ3´ŖŹċľL*+-g& Ăĺ%ŀŇScandinabian Hydrogen Highway Partnership (SHHP)2006 Ï6ùĩŧ õĈ3´ĩŧ%Ra ;,4F&ųêèŴ% ´Ra;, 4Fųê • S_6c •K_+-g • • • •• • • <-gEc • EcWg4 • •• •• • • •• • • • • • G*CŹ"ų /<a <@Mc1g *-gDV^ <0c;HO(SHHP /gP< W_Z HyNor Äôĉƈ Hydrogen LinkĂÜ HyFuture úĉƈ K_+-gEcWg4Lj LjLjƀ<-gEc • Ʉċľ<Dg:[cqÃ¹ß School of Engineering Tokyo Institute of Technology 23 Vſ/jè¦ŴÐ*ǪȥȆȯìłĸ¬ǥſĥ= PEFC® ®CǪǟDzǪŸĿź •! ĤǪKƀȵ5000 - 80000 hȶȶLjȵ9=Ǫ$´ȶ •!ƀſ:ë=ȵ> 60 %ȶ ȶ •!ƀſ.7q=ȵ> 2.0 MW/m3ȶ •!öŠòşǪdÛȸdzǚǕǫöŠ°Ĺi •!ȉȍȖ=ȵ< 1/100ȶ ȶ 24 School of Engineering Tokyo Institute of Technology è¦ŴÐĨ;ŌȵFCV)Ǒ ǑǴǬmĢZè¦ŴÐǪu%ȋȘȬȁȵŨõùÆȶ AIST ċRƀǨǴǷLjɅè¦ŴÐnò=ŕ?Łň¦ǴǶɇ ȽȻȻɀLjLjLjLjɅu%¶ɇLjLjƀLjȽȻȼȻLjLjLjLjƀɅ®C¶ɇLjLjLjLjȽȻȽȻLjLjLjLjɅ¸¿®C¶ɇLjLjƀȽȻȾȻ FCVu %I¤ ɀI ɀȻȻI ũȼȽȻI 'òŌljȜȍ u% Ōą ȼɀȻȻI vZńéljÂ<ò òŌ Ī òŌ ɀȻȻȂ ȵȿɕȶ ÏĖȍȐȰȗ¤ȵÏ Ėŵĵȶ mĢòFC ®CĶÇ Ĥ ùÆ ȉȍȖù Æ |ŅŨg ȽȽȻɓW ȾɀȻȻȂ ȵɀɂɕȶ ȼȻȻȻɓW ɂɀȻȻȂ ȵȼɀȼɕȶ ȼȽɀȻɓW NjȤǾȆȯȇȬȓȗnjǓ®C Ⱦ>ũȵĨ;Ōòȶ ɀ>ũ ȾŊ;ÊȵĨ;òȶ ɁT ɖȿũȵmĢòȶ Ƀũ ¤÷+ȺɓWȵĨ;ŌòljȍȐȓȆȉȍȖȶ ȿȻȻȻ+ȺɓW ¤÷+ȵmĢòljȋȍȔȦ¿ȶ ȿȻ+ School of Engineering Tokyo Institute of Technology 25 nűǪFCǪÅœ(ìXǪPEFC) ȍȐȓȆ Ȏȭ Ǽțȳȗ #- 0 0 0" 0#).1% Ȃȏȳȗ ȃȍ£x Ŵĸʼnħ(ſ/jħǓLÏ) Ĺi ȎȝȮȳȐ (ȜǾȣȳȫȢȮȳȖ or û) ſ/jħȷĹi #- School of Engineering MEA(ħŴÃJ or Membrane Electrode Assembly) ȃȍ£x (ȃȍ£Ŵà or ŲŴȶ Tokyo Institute of Technology 26 þćǪÄĵ Ńī Vſ/jŴĸʼn*ǨǑǖǷéʼnŎŏìł CF2 e- H+ CF2 CF CF2 CF2 O CF CF2 CF2 O CF2 CF2 CF2 SO3- H2O SO3++ X++ HX H2O H CF2 - H 2O HX+ + SO3 CF2 CF2 CF2 CF2 CF2 O CF2 CF2 CF2 CF Vſ/jŴĸʼn*ǨǑǖǷȥ ȆȯéʼnŎŏÈÅ ȵȄȨȟȫȬȳȧȕȭǨǴǷŴĸʼn* éʼnŎŏìłǨŪǛǷ/j;7k øÁĻȶ Ŵĸʼn*éʼnŎŏÈÅǪĸ¬ ǥſǾȁȰuħŨõǭǪ šǪā ȂȏȳȗŴÃĹiǨǑǖǷśĖř!D ČBî/j;7kÓǨǴǷȂ ȏȳȗôŶDĖŗĄǪĸ¬ǥ ſÕJŠĹiǪė H+ O2 Pt C School of Engineering DÈÅǪĸ¬ǥ ſÕĹiļĺǭǪš RFȤ ȤȇȚȖȯȰȍȝȓȐÓǨ ǴǷȂȏȳȗòſÕJŠ ĹiǪŨõ ſÕJŠĹiǪŨõ In-situ XAFS ĺÝ Tokyo Institute of Technology 27 =üè¦ȵeåȃȍljüãȶǒǵǪÏĖijœİ Ś|ȃȍǒǵǪĔÏĖijœ ȜȓȠǻȳȐȰȆ ìįȋȍȔȦ ÏĭÎȵH2Oȶ ƘƉLj ɄƎƍȴ ƓƞƉ Ʉƈƈȴ Ɠƞ ɄƈƉȴ ƓƘƋ Ʉƀȼȴ Ś|ȃȍȵCH4ȶ ƘƉ ɄƎƏȴ ƓƞƉ ɄƉƇȴ Ɠƞ Ʉƀƀƈȴ ƓƘƋ Ʉƀƀƈȴ ĔÏĖ ĦÿS ÏĖ/ųZʼnȋȍȔȦ ʼnS ȵÏĭÎʼnDȶ COaS ÏĖĒijIJĢƀ ȵȋȠȖDȶ ȵPSA:W7ȍǾȰȇMúȶ CH4 +H2OLjLjLjCO + 3H2 CO +H2O LjLjƀCO2 + H2 700ɖ800DŽ 180ɖ220DŽ H2Ʉ>99.99ȴ ȴ •! ȉȰȝȆȖ ÏĭÎȵH2Oȶ ǂ!ƀȋȰȢȭ Ś|ȃȍȵCH4ȶ ĔÏĖ ĦÿS School of Engineering ÏĖ/ųZʼnS ȵÏĭÎʼnDȶ ȵ/ųȶ 550DŽ H2Ʉ>99.99ȴ ȴ ǂ!ƀſ:ë 28 Tokyo Institute of Technology ÏĖ/ųZʼnSǪBî ÏĖ/ųďƀ(PdJŠħ) Ĺi 8ç H2 Ś|ȃȍƀ(CH4) CO2 ÏĖ CH4 H2 H2 H2O ÏĭÎ CH4 CO ÏĭÎʼnD CH4 + H2O ȲȉȰȝȆȖ CO + 3H2 ɊɐaD CO + H2O CO2 + H2 /ų ȲȋȰȢȭ Ȳſ:ë /ų ȁȰȊǾȖÏĖijœǤǪ-îǫɈ School of Engineering Tokyo Institute of Technology 29 mĢ FCǥǪęǰJǹǜ Ŵ7 ɌɊ ʼnS ĔÏĖijœ ȊȡȋȍȔ Ȧ ç ÏĖ 1kWĕȋȍȔȦnĽ ĔÏĖņĮȊȡȋȍȔȦ LJÏĖǪſ1ò ÏĖěȎȰȐȳ ÏĖȝǾȢȫǾȰǭǪwŨ ……… 30 ĔÏĖŽ;ZPEFC School of Engineering Tokyo Institute of Technology üãǒǵǪCO2TEZÏĖijœİ(HyPr-RING) (H2 > 90%,+CH4) HyPr-RING ������ ��� $ # !" $ � �����(923 K) (3.0 MPa) ���� �������(CaCO3) ��(CO ���) 2 CO2Ǫ-îǫɈ ������ ɅJCOAL, AIST, IHI, ©, Ĭɨɤɪɛɫ, yūdk, ģżdkɇ 31 School of Engineering Tokyo Institute of Technology ƓƞƗǒǵǪØÏĖijœěnĽľž ŎLjŏ TEĒij ɠɚɟɢâɞɯɢ Ɋɐɍ 4-î ſâɞɯ ɢɉɌɍ 4-îȺa Ɵơƒ «LjW ɠɚɟɢ ɠɚɟɢâ 4-îȺa ĦãśɗĉĖ WġÏĖɥɬɚɩɚ àŤ æ Ě ţ ÏĖɢɤɚɡɘɮ ƖƓƣȜȍ Ɓ'(ɧɪɚɥƂ ťœ W ØLj= ØÏĖɭɚɪɚ ōâ æĚɧɰɩɮɥ ƖƓƣ «W ɗ"^ ɢɟɩəɧɰ ſâ Ţţü ɦɰɜɧɰɩɜɮ ĦãśɗĉĖ ōâɞɯɢ ɏɋɍ üLjã ȢȫȍȒȓȆ 1Ljò Ø=ÏĖɣɮɟ ŢŦijP mĢòè¦ŴÐ ȵçŴěȶ ijŢɜɮɧ ɩ ÏĖɞɯɢɝɮɡɯɮ 32 School of Engineering Tokyo Institute of Technology üÑĒijȢȫȰȖǒǵõð ǛǷCO2şǪĺ ȘȠȊʼnÏĖijœ ȠȭĆǤ ũ5300 ȖȰǪCO2õð ÏĖijœɄũ80 Nm3 School of Engineering Tokyo Institute of Technology 33 ĞòƊČũ͹ÉīĄċľßŗſƘáŤƎ ƘƕơơƀzŞÙÍ ǪǘAǨǴǷ ŁēĥĀĭ͹ÉīĄ Ï 2005- 2010 ĞòƊČũ ċľƋŗſċľ<Dg:[cï 2010- 2020 500i§ 65 Nm3 3,500dß 2020- 2030 1,500i§ 170 Nm3 8,500dß Lj5i§ƀƀ 4 Nm3 Ljƀƀƀƀƀƀƀƀ500dß !ċľ<Dg:[cÓśáŤ Ï 2005- 2010 2010- 2020 2020- 2030 ċľ<Dg:[cï Lj500dß 3,500dß 8,500dß áŤƎ 1,500 ƒƕ3 Ɠ 7,000 ƒƕ2 Ɠƀƀƀ 17,000 ƒƕ2 Ɠ Đ 2020-2030Ï<Dg:[cŘą½$7<F Ɛ%7<FzĔ&â$ŭ' åň School of Engineering Tokyo Institute of Technology 34 ƘƕơơƀzŞÙÍ ǪǘAǨǴǷ ƓƞƉTEZÏĖȐȳȞȰõŴ Ļ´500MWċľ@gOcĩƊß rĀʼnƔBPEdison Mission Gr. śň¹ßƔ0^P._I(Ìa<ŮŸCarson ĩƊśƔ500MWċľ@gOcƒ250MW"2 Ɠ ċľŕŲƔTFa7g45,000t/day&1< CO2ĢƔCO2ĔÏƅ400i itƒũ100i§ æſĬÕ OccidentalčħĐƓ śň¹ßBPŕčß ŵŪƄÀƔ2011ÏáŤƎƔ10 G_ Ɗ ċľ@gOc CO2±£ 1< ċľ CO2ĐĹ School of Engineering TFa7g4 İčç¤Ĺ Tokyo Institute of Technology 35 ÏĖǪśĖèæǨǴǷ§ȊǾȆȭ ȲƀèæðéɄÏĭÎǪǰȵ}ŝȃȍǓÏĭÎǪǰǪ]Jȶ ȲƀȃȍȐȳȞȰǥĭÎȐȳȞȰǪŧǺ)ǩǐǟĴJȊǾȆȭǪĥ LjȵȡȮǾȖȰȊǾȆȭȷȫȰȄȰȊǾȆȭǪĨ;ĴJ=ȶ ő~ǪȃȍȐȳȞȰ ÏĖȐȳȞȰ 36 School of Engineering Tokyo Institute of Technology ÏĖǺȀȚȭȅȳȄȨȬǼǥǚǟ ŋ/£ZȀȚȭȅȳȉȥȩșȔǽȳ ȵĬğþ ƀŠóǵǨǴǷȶ 37 School of Engineering Tokyo Institute of Technology HŐȎȭȍȐȓȆǺòǎǟŴ7Ńīß=ȋȍȔȦ & " $ ) + O2 K< J?nEDn_#(0 p1g !q 9H!93fie 1Y p100&%1MPa&%q PEM4J?nEodRhB pkO/@')A0FPq "ZT4 Q8 p+N1Y "7*q !( jVc\ O2 ) * & Reversible Cell Stack Dn_iP H2 J?nEiP DVc\ H2 * & #)'% kWU&$PEM41g !lQ X2nC5>/M r45%&$ DV,Pn.b[:I0W2a`=^L; X2 ",P/M r75%&$ "! r20%-G ȵſýçkƀváǵǨǴǷȶ n.6mS]M r50%&$ 38 School of Engineering Tokyo Institute of Technology 業務用建物設備における水素/電力供給ステーション∼ FWXIDN=?%/EOUGY & +8,>ABFWXIDN$ 04&?,\9-KMYJTW D:4E $ #*84 #25=, #2 384 #?&9 @ -+ C"5=, C84 " &* Z'2<-([ ;4 @C. " &* Z'2([ // 9HYRU 9HYRU ;4KSYK 9 :&9 ?& 9HYRU A2<7: ,7) ?;6 &, + ( C$ # ;4QVC # \5?931! !;6 &, - Z6)>.[ 1#9>84 #2<7: ',0 ' ?;6 &, !;6 &, School of Engineering )84 #B 84 %',0 ' PLN " &* 7) ȵſýçkƀváǵǨǴǷȶ 39 Tokyo Institute of Technology ğJøYíܯ=rĎ ȵ,ȶ üãȃȍ=ȲƓƞƉŰųȲÏĖ1òİǪĜJ CO + H2 ȃȍ= =üè¦ (ü üã, üÑƀ..) O2/CO2 śĖèæ ,ðHĥȀȚȭȅȳ (Ż Ż7, fů#ƀ..) FutureGen (U.S.) ȋȠȖD ÏĭÎʼn Ʌŧ¶tºɇ CO2 + H H22 $ "%& (Ȁ ȀȆȎȭȅȳ`ŕ) ĈÎèæ ÏĖǪſ 1òȋȍȔȦ H2 + O2 Ŵ7 H2O (è è¦ŴÐ ÏĖȐȳȞȰƀ..) CO2 TE CO2 /ųȲTE ƀƀƀƀƀƀ(MEA .. ) Ʌû¶ɇ CO2 '( CO2 Űų (Ö ÖÔ, Yƀ..) Ʌ¶ɇ !" School of Engineering CO2 '(# Tokyo Institute of Technology 40 ƘƕơơƀzŞÙÍ ǪǘAǨǴǷ ÏĖĂnìǪĿźȵĵēȶ įúşƍoƃúşƍ ċľĦàő¯® ĞòƊČōũ Ê·ĞòƊČÚĦŕ® ´ĪōũĦċľ*c P]Ăĺ ċľĦ ƚƛƜƝàő ű şƍ ½ſċľĦàőƄĩ ĊĤƘĥĀĦŰä½ƘũĦ Űä½ƘĩƊĦĝĆƆ ½Řąċľ*cP]Ăĺ ƒCO2P^gċľŃ ċľN*R]*cŃƓ ŕŲàőŬůàőţŏàőĦ àő fŁēÛIJĸfŘŅďðƒƆ6ďØƓ fàőĄĘfijy¥ÆÛŽÞƒÍĊîŊƓ School of Engineering Tokyo Institute of Technology 41 ƘƕơơƀzŞÙÍ ǪǘAǨǴǷ ċľN*R]*c ċľN*R]*cċľ½ſŻům¦ćƗđ¼ÄņŢÇ öû Ļ´ EU ƙ10kmĵÒN*R]*c ŕƁßĂƘ7cOHgF ƙ¨ß©Ś1,320km Texas, Louisiana, LA ƙv-S_3gƅ900km ƙĠ) Ruhr 200km, Luena 135km µƔ60 bar ŻĹ×Ɣ100mm üťƔęľƂƂĹ ñśƔ¶l¸ś S_3g ƙ/]cA*3^< űwă3Ɩ12inµŻĹĦęľƂƂĹ }Ħµ2Ɩ12MPa şƍ ƙÓś7<FzĔ ƙµŻĹĦęľƂƂĹċľŌÛ ŝƏEg@mŧƒöûƓ ƙ¾ě1<fċľĦN*R]*c School of Engineering ċľ żľ P]c< Air LiquidijŤò S_3gP]c<ƅļ900km ƒ}ĦÄņ30ÏxkƓ Tokyo Institute of Technology 42 ĞHĥĂǭǪìnøǧũȋȘȬȁǪÅđǥĴJ=ȋȍȔȦİŨõ 0İŨõ LjLjijœ LjLjŎŏ LjLjņĮ LjLj1ò ÏĖǪſ1òǺ¾ǥǚǟ ĴJ=ȋȍȔȦİŨõ ȵǾȰȐȳȠǿǾȍljşøȲŒŀøȤȓȒȰȇȶ ȵñÂũŔljȉȢȯȑȆȋȪȰȶ ǝǸǞǸǪſ:ë=ǠǖǤǫ ,ðHĥȀȚȭȅȳu%ŕ =üè¦ǒǵǪÏĖijœ ǥƓƞƉTEȲŰųǪĜJ ȵğJøYíܯ=rĎȶ ȵſ:ë=ǠǖǤǫƓƞƉ3Ûǫŭôȶ ǧǕljȋȍȔȦǥǚǣǪſ=Ǔlj ÏĖǠǒǵǗǝǤǔǷdǔǧȡ ȮȳȆȍȭȳǺðDZ ÏĖǪcķøÈĥǺÕòǚǟ ʼnȀȚȭȅȳǪſʼn=,1ò ȵȀȆȎȭȅȳ`ŕȶ ƉƇƈƇƄƉƇƉƇŷǪnìǨKǖǣljǒǵİŨõǪį;ǺŊǗǛǮǔ School of Engineering Tokyo Institute of Technology 43 ÏĖĂǨKǖǟȞȌȪȰȵǯǥDzȶ ŧ¶ȍȖȫȔȌȳ •!,ðHĥȀȚȭȅȳǪdşu%ƀ( ! 100-1000 ) •!ÖbǪ6ĨåȀȚȭȅȳǪ1òLjȵȀȚȭȅȳȄȨȬǼƀ?) ìnøǧũȋȘȬȁƀ( ũȍȈȳȭljĈũȍȈȳȭ) (ǟ ǟǥǐljìXǪËNpǓvǙǎǒljȤǾȘȍǤǍǡǣdz) •!ÏĖĨ;Ōƀ(IC-engine, PEFC)LjȲvZ/£ȉȌǿȚ •!ǾȰȠȫ¥ljŎŏȲņĮȲěȋȍȔȦljÏĖȉȥȩșȔǽȳ •!ȀȚȭȅȳȄȨȬǼǥǚǣǪÏĖǪcķøÈĥǪÕòİ LjLj(Ȁ ȀȚȭȅȳaljŎŏljņĮȵȀȚȭȅȳȲéʼnƀñÂȉȰȢȮȓȆȍȶ •!ÏĖ1ò/£ȀȚȭȅȳȋȍȔȦǪ±Ř=ƀ(PEFC, MGT) •!=üè¦ljȜǾȁȤȍčǒǵǪſ:ëljſŒljdşƀÏĖijœ ƀƀǑǴǬ5ðÏĖǪÕòLjȵCO2TEŰųǥǪǾȰȔȇȮȳȋȪȰȶ •!PEFCǪ ǪȉȍȖdÛljĤǪ¿ÌǪK •!l&ǪĀĊljÏĖǪĶ2ĠOljĂGoǪŜljĝĞø¡Ď 44 School of Engineering Tokyo Institute of Technology